Emission Flux and Carbon Isotopic Composition of Methane from Rice Paddies in Guizhou Province

Methane emission flux from rice paddies in Guizhou province shows obvious three stage diurnal variations;It is relatively low from the morning to the noon,then successively increases in the afternoon and at night,and finally follows a gradual decrease.The δ13C values of trace methane emitted from rice paddies in Guizhou Province range from-64.5‰to -54.1‰ with an average of -60.7‰,very close to the reported values from America or Kenya.     

Daily Variation of Natural Emission of Methane to the Atmosphere and Source Identification in the Luntai Fault Region of the Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang, China

The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern China. Using an online method, which couples together a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry （GC/C/MS）, 13^C/12^C ratios of methane in flux chambers were measured and showed that methane gases are liable to migrate from deep oil/gas reservoirs to the surface through fault regions and that a part of the migrated methane, which remains unoxidized can be emitted into the atmosphere. Methane emission rates were found to be highest in the mornings, lowest in the afternoons and then increase gradually in the evenings. Methane emission rates varied dramatically in different locations in the fault region. The highest methane emission rate was 10.96 mg/m^2·d, the lowest 4.38 mg/m^2, and the average 7.55 mg/ m^2·d. The 13^C/12^C ratios of the methane in the flux chambers became heavier as the enclosed methane concentrations increased gradually, which reveals that methane released from the fault region might come from thermogenic methane of the deep condensed oil/gas reservoir.     

青藏高原冷湿地生态系统CH4排放量估算

The areal extent of cold freshwater wetlands on the Tibetan Plateau is estimated to be 0.133×10 6 km 2, suggesting a significant methane potential. Methane fluxes from wet alpine meadows, peatlands, Hippuris vulgaris mires and secondary marshes were 43.18,12.96,-0.28 and 45.90 mg·m -2 ·d -1 , respectively, based on the transection studies at the Huashixia Permafrost Station from July to August 1996. Average CH 4 flux in the thaw season was extrapolated to be 5.68 g·m -2 according to the areal percentage of wetland areas in the Huashixia region. CH 4 fluxes at four fixed sites, representative of similar ecosystems, ranged from -19.384 to 347.15 mg·m -2 ·d -1 , and the average CH 4 fluxes varied from 6.54 to 71.97 mg·m -2 ·d -1 at each site from April to September 1997. CH 4 emissions at each site during the entire thaw season was estimated from 1.21 to 10.65 g·m -2 , displaying strong spatial variations. Seasonal variations of CH 4 fluxes were also observed at the four sites. It is found that CH 4 bursted in the early thaw season, and increased afterwards with rising soil temperatures. Episodic fluxes were observed in summer, which influenced the average CH 4 flux considerably. Annual CH 4 emissions from cold wetlands on the plateau were estimated at about 0.7～0.9 Tg based on the distribution of wetlands, representative CH 4 fluxes, and number of thaw days. The centers of CH 4 releasing are located in the sources of the Yangtze and Yellow Rivers, and Zoige Peatlands.     

Permafrost and taliks and their changes on the south and north banks of the Tuotuo River in the Qinghai-Tibet Plateau under the climate warming北大核心CSCD

The distribution of permafrost and taliks is very complex in the Tuotuo River Basin(TRB), which is located in interior of the Qinghai-Tibet Plateau. Characterizing the spatial distribution and the thermal stability of permafrost and taliks is of great significance to community activities and engineering construction in TRB. Based on the zonation of permafrost and talik distribution around TRB conducted in the 1980s, the soil temperature and its variation process of permafrost and taliks in the south and north banks of the Tuotuo River were analyzed by using the observation data of five boreholes(N1~N5)along the Qinghai-Tibet Railway in the north bank and five boreholes(S1~S5)on the first terrace in the south bank. The results showed that, under the climate warming, permafrost and taliks in the north banks experienced significant degradation and warming process. From 2005 to 2020, the permafrost at the N1 borehole has undergone a significant down-draw degradation process, from extremely unstable and high-temperature permafrost to thawed zone. From 2005 to 2013, the annual average ground temperature of the talik at N2 increased at a rate of 0. 3~0. 4 °C·(10a)-1. At Maqutang on the south bank, permafrost prevails from the first-class terrace to the gentle slope of the Kaixinling Mountain, with both through and non-through taliks on the first-class terrace. The spatial distribution and the thermal stability of permafrost and talik in the TRB are further promoted by analyzing the changes in temperatures at boreholes in the basin. However, to meet the requirements of mapping and engineering construction of permafrost and taliks in the TRB, it is still necessary to carry out geological investigation with multiple methods and in-depth research on development mechanism of taliks in the future. © 2022 Nanjing Forestry University. All rights reserved.     

Factors Affecting Methane Emission from Rice Paddies

A comparative study of rice paddies and the uncovered water field in Taoyuan(Hunan) showed that methane emission from rice-vegetated paddy fields in 1993 was different from that in 1992(I,e,lower in rates and irregular in pattern).Climate has obvious influence on methane emission .And ebullition made a considerable contribution to the total flux of methane emission from rice paddies (45%).This implies that the intensification of paddy cultivation of rice might not be,as was proposed,the main con-tributor to the observed gradual increasing of atmospheric methane.24-hour automatic measurements of atmospheric temperature,air temperature and methane concentration in the static sampling boxes revealed that temperature,in addition to fertilization and irrigation style,is one of the most important factors that control the emission of methane from rice paddies.     

青藏高原多年冻土区地温监测结果分析

Ground temperatures monitored at four observation sites in permafrost regions on the Tibetan Plateau was analyzed. It was found that the ground temperature at the depth of 12～20 m increased 0.2～0.4 K and the permafrost thickness decreased 4～5 m from the base in Xidatan Site from 1975 to 1989; and the ground temperature at the depth of 6～15 m increased 0.2～0.4 K in Kunlun Pass Site from 1982 to 1997. Contrast observations show that a sand cover, 15～20 cm in depth, can result in a ground temperature decrease of 0.1～ 0.2 K in MS66 Site; and a removal of vegetation can result in a ground temperature decrease of some 0.2 K in Hoh Xil Site. The monitor demonstrates that many factors that control permafrost developing have duality, e.g., sand and vegetation are able to increase or decrease the ground temperature. These factors, in conjunction with permafrost behaviour, play different roles under different conditions. Therefore, it is necessary to study, understand and evaluate permafrost and its engineering geological properties taking the viewpoint of dynamic variation.     

Carbon cycle variability in tropical Atlantic across two Early Eocene hyperthermals

Early Eocene hyperthermals are geologically short-lived global warming events and represent fundamental perturbations to the global carbon cycle and the Earth’s ecosystem due to massive additions of isotopically light carbon to the ocean-atmosphere system.They serve as ancient analogs for understanding how the oceanic carbonate system and surface-ocean ecosystem would respond to ongoing and future climate change.Here,we present a continuous carbonate record across the Eocene Thermal Maximum 2(ETM2 or H1,ca.54.1 Ma)and H2(ca.54 Ma)events from an expanded section at Ocean Drilling Program Site 1258 in tropical Atlantic.The abundant calcareous nannofossils and moderate carbonate content throughout the studied interval suggest this record was deposited above the calcite compensation depth(CCD),but below the lysocline and under the influence of terrestrial dilution.An Earth system model cGENIE is used to simulate the carbon cycle dynamics across the ETM2 and H2 to offer insights on the mechanism of the rapid warming and subsequent recovery in climate and ecosystem.The model suggests moderate changes in ocean pH(0.1–0.2 unit)for the two scenarios,biogenic methane from a rechargeable methane capacitor and organic matter oxidation from thawing of the permafrost.These pH changes are consistent with a recent independent pH estimate across the ETM2 using boron isotopes.The carbon emission flux during the ETM2 is at least an order of magnitude smaller than that during the Paleocene–Eocene Thermal Maximum(PETM)(0.015–0.05 Pg C yr^-1vs.0.3–1.7 Pg C yr^-1).The comparable pre-and post-event carbonate contents suggest the lysocline did not over deepen following the ETM2 at this tropical Atlantic site,indicating spatial heterogeneity in the carbonate system due to strong dilution influence from terrestrial weathering and riverine discharge at Site 1258.     

A multi-methodological approach to determine CO2 and CH4 fluxes and concentrations in solid waste disposal

The municipal solid waste （MSW） landfills are the significant sources of atmospheric contamination, due to biogas production by anaerobic decomposition of organic matter via bacterial activity. Biogas released from landfills is commonly composed of a mixture of methane （55%-60%） and carbon dioxide （40%-45%）, with minor contents of N2, H2, CO and traces of toxic and bad smelling inorganic and organic compounds. Particular attention has to be paid to CH4 and CO2 because of their liability for the greenhouse effect. Presently, the U.S. methane emission from landfills is considered to be about 25% of the total methane released to the atmosphere. Accordingly, field measurements should be planned in order to verify and, eventually, optimize the amount of gases released from waste disposals to the atmosphere. Simultaneous measurements of methane and carbon dioxide fluxes are an effective tool to better evaluate： （1） the amount of biogas released, （2） the real efficiency of the impervious cover, and （3） the presence of anomalous degassing zones or of newly formed fractures. Static closed-chamber methods for CH4 and CO2 flux measurements have been developed and used in both natural and artificial systems. Furthermore, portable gas-chromatographers equipped with flame ionization detector （FID） and accumulation chamber connected to infrared detectors （IR） .have been utilized for measuring CH4 and CO2 fluxes, respectively. This paper deals with a detailed investigation that combines （1） CH4 and CO2 flux measurements from solid waste disposal and surrounding areas （determined by an accumulation chamber equipped with two IR detectors, respectively）, （2） chemical composition of soil and piezometer gases （collected in pre-evacuated glass tubes and analyzed by gas-chromatography）, and （3） CO2 linear concentration measurements on optical air paths with IR laser devices. This multi-methodological approach was successfully applied to an active MSW in Tuscany （Central Italy）. The analytical results have shown that the CO2/CH4 ratios of the piezometer gases have large variations, likely related to the different stage of decomposition processes affecting the heterogeneous solid material of the waste landfill. Significant contents of light hydrocarbons and BTX were also detected.     

Effects of tree species and soil depths on ethylene and methane consumption in tropical and temperate forest soils

To date our knowledge is limited with regard to the responses of ethylene and methane consumption by forest soils to tree species and soil types, and to the effect of presence of ethylene on atmospheric methane consumption. The soils at depths from tropical and temperate forests in China were used to study the responses of ethylene and methane consumption to tree species and soil types. The ethylene and methane consumption by soils beneath each forest floor was measured under the same oxic conditions, along with main properties of forest soils. The accumulation of ethylene was studied in the soil slurry （soil/water, 1/2.5）. In temperate soils under spruce and birch forests, maximal consumption rates of ethylene and methane were observed in the 2.5-5.0 cm and 5.0-7.5 cm soil layers, respectively （P〈0.05）. However, a maximal consumption of both occurred in the 0-2.5 cm soil layer under temperate Korean pine forest （P〈0.05）. Contrary to temperate forest soils, there was a significant lower consumption of ethylene and methane in tropical forest soils at less than 20 cm depths under a seasonal rainforest and secondary rubber forest （P〈0.05）. Hence, the potential of ethylene and methane consumption in the 0-20 cm soil profile was variable with tree species and soil types. According to ethylene formation in the soil slurry, there was greater accumulation of ethylene in the 0-2.5 cm soil under temperate forests than under tropical forests, and its accumulation under spruce and birch forests was more than under Korean pine forest （P〈0.05）. The presence of extrinsic ethylene can significantly inhibit the consumption of atmospheric methane by forest soils.     

Oxygen and Hydrogen Isotopes of Waters in the Ordos Basin,China: Implications for Recharge of Groundwater in the North of Cretaceous Groundwater Basin

Hundreds of precipitation samples collected from meteorological stations in the Ordos Basin from January 1988 to December 2005 were used to set up a local meteoric water line and to calculate weighted average isotopic compositions of modern precipitation. Oxygen and hydrogen isotopes, with averages of ?7.8‰ and ?53.0‰ for δ18O and δD, respectively, are depleted in winter and rich in spring, and gradually decrease in summer and fall, illustrating that the seasonal effect is considerable. They also show that the isotopic difference between south portion and north portion of the Ordos Basin are not obvious, and the isotope in the middle portion is normally depleted. The isotope compositions of 32 samples collected from shallow groundwater (less than a depth of 150 m) in desert plateau range from ?10.6‰ to ?6.0‰ with an average of ?8.4‰ for δ18O and from ?85‰ to ?46‰ with an average of ?63‰ for δD. Most of them are identical with modern precipitation. The isotope compositions of 22 middle and deep groundwaters (greater than a depth of 275 m) fall in ranges from ?11.6‰ to ?8.8‰ with an average of ?10.2‰ for δ18O and from ?89‰ to ?63‰ with an average of ?76‰ for δD. The average values are significantly less than those of modern precipitation, illustrating that the middle and deep groundwaters were recharged at comparatively lower air temperatures. Primary analysis of 14C shows that the recharge of the middle and deep groundwaters started at late Pleistocene. The isotopes of 13 lake water samples collected from eight lakes define a local evaporation trend, with a relatively flat slope of 3.77, and show that the lake waters were mainly fed by modern precipitation and shallow groundwater.     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861