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1.
This paper is the result of a study which was carried out in order to verify if the traditional methods to evaluate the intrinsic vulnerability or vulnerability related parameters, are able to clarify the problem of nitrate pollution in groundwater. In particular, the aim was to evaluate limitations and problems connected to aquifer vulnerability methods applied to nitrate contamination prevision in groundwater. The investigation was carried out by comparing NO3 concentrations, measured in March and November 2004 in the shallow aquifer, and the vulnerability classes, obtained by using GOD and TOT methods. Moreover, it deals with a comparison between NO3 concentrations and single parameters (depth to water table, land use and nitrogen input). The study area is the plain sector of Piemonte (Northern Italy), where an unconfined aquifer nitrate contamination exists. In this area the anthropogenic presence is remarkable and the input of N-fertilizers and zootechnical effluents to the soil cause a growing amount of nitrates in groundwater. This approach, used in a large area (about 10,000 km2) and in several monitoring wells (about 500), allowed to compare the efficiency of different vulnerability methods and to verify the importance of every parameter on the nitrate concentrations in the aquifer. Furthermore it allowed to obtain interesting correlations in different hydrogeological situations. Correlations between depth to water table, land use and nitrogen input to the soil with nitrate concentrations in groundwater show unclear situations: in fact these comparisons describe the phenomenon trend and highlight the maximum nitrate concentrations for each circumstance but often show wide ranges of possible nitrate concentrations. The same situation could be observed by comparing vulnerability indexes and nitrate concentrations in groundwater. These results suggest that neither single parameters nor vulnerability methods (GOD and TOT) are able to describe individually the complex phenomena affecting nitrate concentrations in soil, subsoil and groundwater. In particular, the traditional methods for vulnerability analysis do not analyze physical processes in aquifers, such as denitrification and nitrate dilution. According to a recent study in the shallow unconfined aquifer of the Piemonte plain, dilution can be considered as the main cause for nitrate attenuation in groundwater.  相似文献   

2.
The potential for contamination of groundwater in an over-exploited system led to this investigation on aspects of aquifer vulnerability in the Toluca Basin, Mexico. This study involved the use of various hydrogeological, geochemical and isotopic tools to better understand the susceptibility to contamination where heavy groundwater extraction along with industrial extensive development is concentrated. Geochemical and isotopic analyses of groundwater from production wells along the mountain boundary show little evidence of contamination at present time. Radiocarbon and tritium data collected in piezometers and wells penetrating the Lower basalt aquifer indicate that the groundwater is of varying age and quality. These data, in addition to stable isotope and chemical data also indicate evidence of contamination in the Lower aquifer; which could be associated with fast recharge in the mountains or injection of waste water by illegal wells. Evidence found in this study of low downward gradients in the valley fill sediments and the presence of low permeability aquitard deposits suggest that the aquifer system is currently not highly threatened by surface sources of contamination. However, where urban and industrial development occurs, in the centre of the valley and along the flanks of the Basin, the vulnerability of the aquifer system increases significantly.  相似文献   

3.
开采条件下河北平原中部咸淡水界面下移   总被引:3,自引:0,他引:3  
河北平原中部上层咸水入侵下层淡水已造成局部地下水污染,本文调查统计了地下水质监测资料和2700多眼深井孔的测井物探资料。以水化学方法和数理统计方法,从水文地质条件和地下水开采利用状况入手,对研究区咸淡水界面下移的机理进行了分析。结果认为,咸淡水界面从20世纪70年代以来年均下移约0.4m,开采地下水造成上下层水头压力变化,加大上部浅层水向下越流是其主要原因之一。  相似文献   

4.
Korba aquifer is one of the most typical examples of overexploited coastal aquifer in the Mediterranean countries. In fact, from 1985, a considerable piezometric level drop, water salinization, and seawater intrusion were registered in the aquifer. In December 2008, Tunisian authorities initiated a general plan to groundwater management in order to augment groundwater resources, restore the piezometric levels, and improve water quality. The plan consists of artificial recharge of groundwater used treated wastewater through three infiltration basins. During the first 4 years (from December 2008 to December 2012), 1.41 Mm3 of treated wastewater was injected to the Korba aquifer. This study presents a hydrogeological assessment of groundwater evolution during the recharge processes. In this study, 32 piezometric and chemical surveys of 70 piezometers and observed wells are used to present hydrogeological investigation and water quality evolution of wastewater reuse through artificial recharge in Korba coastal aquifer. The piezometric evolution maps are used to specify the positive effect in groundwater level that exceeding 1.5 m in some regions. The interpretation of salinity evolution maps are used to indicate the improving of groundwater quality.  相似文献   

5.
 Groundwater samples taken from wells adjacent to a food machinery manufacturing plant in southern Taiwan indicate that there is a serious phenolic contamination. To understand the hydrogeological properties, and to prepare for remedial action, a series of hydrogeological investigations were conducted. Investigative work included collecting background information, analyzing existing data, measuring the groundwater, and conducting a slug test, pumping and recovery test, aerial photography analysis and electrical resistivity survey. Results from these investigations show that the local groundwater aquifer may be classified as an unconfined or confined formation, depending on the thickness of the interbedded clay layer. The direction of local groundwater flow is from southwest to northeast, with high transmissivity. The contaminant moves much more slowly than the average groundwater velocity, and it is limited to an area centered around the plant. The local geology of the contaminated area exhibits significant heterogeneity; it is not likely to have been formed by natural sedimentation. Data from the field aerial photography analysis and electrical resistivity survey also suggest that this shallow formation may result from artificial back-filling. Received: 1 September 1994 · Accepted: 28 December 1995  相似文献   

6.
The construction of emergency water sources is the material basis for ensuring urban water safety, and it is also an inherent requirement for maintaining social stability and development. The hydrogeological characteristics of groundwater in Luoyang City from the aspects of the division of groundwater aquifer groups, water yield property and groundwater dynamics were described in this paper. Two emergency water sources were selected on basis of comprehensively considering groundwater resources and ecological environmental effects, groundwater quality and exploitation technology, etc. Then it further analysed the aquifer types, water yield properties and groundwater recharge, runoff and discharge conditions of the two emergency water sources, and evaluate the groundwater resources quantity of the water sources. The results are that the shallow underground aquifer in Luoyang City is thick, coarse, and stable in lithology and thickness. The two water sources enjoy good exploitation potential and can be used as backup water sources to supply water in the event of a water source crisis.  相似文献   

7.
More than 2.5 billion people on the globe rely on groundwater for drinking and providing high-quality drinking water has become one of the major challenges of human society.Although groundwater is considered as safe,high concentrations of heavy metals like arsenic(As) can pose potential human health concerns and hazards.In this paper, we present an overview of the current scenario of arsenic contamination of groundwater in various countries across the globe with an emphasis on the Indian Peninsula.With several newly affected regions reported during the last decade, a significant increase has been observed in the global scenario of arsenic contamination.It is estimated that nearly 108 countries are affected by arsenic contamination in groundwater(with concentration beyond maximum permissible limit of 10 ppb recommended by the World Health Organization.The highest among these are from Asia(32) and Europe(31), followed by regions like Africa(20), North America(11), South America(9) and Australia(4).More than 230 million people worldwide, which include 180 million from Asia, are at risk of arsenic poisoning.Southeast Asian countries, Bangladesh, India, Pakistan,China, Nepal, Vietnam, Burma, Thailand and Cambodia, are the most affected.In India, 20 states and 4 Union Territories have so far been affected by arsenic contamination in groundwater.An attempt to evaluate the correlation between arsenic poisoning and aquifer type shows that the groundwater extracted from unconsolidated sedimentary aquifers, particularly those which are located within the younger orogenic belts of the world, are the worst affected.More than 90% of arsenic pollution is inferred to be geogenic.We infer that alluvial sediments are the major source for arsenic contamination in groundwater and we postulate a strong relation with plate tectonic processes, mountain building, erosion and sedimentation.Prolonged consumption of arsenic-contaminated groundwater results in severe health issues like skin, lung, kidney and bladder cancer; coronary heart disease;bronchiectasis; hyperkeratosis and arsenicosis.Since the major source of arsenic in groundwater is of geogenic origin, the extend of pollution is complexly linked with aquifer geometry and aquifer properties of a region.Therefore, remedial measures are to be designed based on the source mineral, climatological and hydrogeological scenario of the affected region.The corrective measures available include removing arsenic from groundwater using filters, exploring deeper or alternative aquifers, treatment of the aquifer itself, dilution method by artificial recharge to groundwater, conjunctive use, and installation of nano-filter, among other procedures.The vast majority of people affected by arsenic contamination in the Asian countries are the poor who live in rural areas and are not aware of the arsenic poisoning and treatment protocols.Therefore, creating awareness and providing proper medical care to these people remain as a great challenge.Very few policy actions have been taken at international level over the past decade to reduce arsenic contamination in drinking water, with the goal of preventing toxic impacts on human health.We recommend that that United Nations Environment Programme(UNEP) and WHO should take stock of the global arsenic poisoning situation and launch a global drive to create awareness among people/medical professionals/health workers/administrators on this global concern.  相似文献   

8.
This study demonstrates the application of a stochastic procedure to enhance confidence in the predictions of numerical groundwater flow models. The objective was to assess the hydrogeological conditions and groundwater potential of a semi-confined aquifer system in Legon, Accra. The study applied the parameter randomization procedure in the Groundwater Modelling System (GMS) to evaluate model uncertainties arising from uncertainties in the data of model input parameters. A total of 2500 equally likely solutions of the numerical model were simulated through the Latin hypercube stochastic option. Regarding the size of the terrain and the number of parameters used for calibrating the model, the 2500 model realizations were adjudged to be largely sufficient to represent the possible solutions that could arise from the various permutations of the parameter data. High variances would suggest significant differences in the realizations, indicating high levels of non-uniqueness in the solutions. The 2500 solutions were compared using standard deviations computed from the differences in the estimated horizontal hydraulic conductivity, specific yield and specific storage estimates. The transient model calibrated for this domain suggests very close similarities in the model-computed aquifer parameters for all the 2500 solutions. This suggests that any of the solutions could be used to represent the conditions prevailing in the domain. Risk analyses were then performed on abstractions through all the 2500 solutions. The study shows that the domain is sustained largely by lateral subsurface inflows from adjoining areas amounting to 399,278 m3/day, with direct vertical infiltration and percolation of precipitation accounting for an average of 2450 m3/day. The analysis suggests that at this rate of input, the domain can sustain groundwater abstraction to meet all water needs in the area. In addition, the domain has demonstrated resilience against annual increment in abstraction rates by 5 % over a 20-year period at the current recharge conditions. However, increasing abstraction rates by up to 200 % of the current abstraction rates over the 20-year period (2015–2035) but with a gradual decrease in groundwater recharge by up to 10 % over the period will result in drastic lowering of the hydraulic head especially in the south-central portions of the domain. This situation might induce reversal of the current flow and potentially lead to contamination and/or aquifer dewatering in the domain.  相似文献   

9.
Groundwater vulnerability is a cornerstone in evaluating the risk of groundwater contamination and developing management options to preserve the quality of groundwater. Based on the professional model (DRASTIC model) and geographical information system (GIS) techniques, this paper carries out the shallow groundwater vulnerability assessment in the Zhangye Basin. The DRASTIC model uses seven environmental parameters (depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity) to characterize the hydrogeological setting and evaluate aquifer vulnerability. According to the results of the shallow groundwater vulnerability assessment, the Zhangye Basin can be divided into three zones: low groundwater vulnerability risk zone (risk index <120); middle groundwater vulnerability risk zone (risk indexes 120–140) and high risk zone (risk index >140). Under the natural conditions, the middle and high groundwater vulnerability risk zones of the Zhangye Basin are mainly located in the groundwater recharge zones and the important cities. The high, middle and low groundwater vulnerability risk zones of the Zhangye Basin cover around 17, 21 and 62% of study area, respectively.  相似文献   

10.
 An early indication of groundwater contamination occurs when pollutant concentrations start to fluctuate and exceed background values of ambient fresh groundwater. An analysis of a characteristic situation of this type uses data from Israel's coastal phreatic granular aquifer. The pollutant is generally seawater, and the contamination process involves replacement of freshwater by encroaching sea- or other saltwater, a process augmented by human activity. The contamination process involves three stages: (1) groundwater composition remains relatively stable with small salinity content; (2) small salinity changes are perceptible with reversible fluctuations; and (3) salinity concentration increases at a sharply higher rate. The second stage is a useful early-indicator signal of contamination. Early-indicator signals of groundwater pollutant concentrations involve "minor" fluctuations in water chemistry at the advent of the contamination process. The intensity and magnitude of such a salinization/pollution process at any given location depends upon lithologic matrix, aquifer heterogeneity, and resultant flow domain characteristics, as well as contaminant properties. If such "signs" are detected at a sufficiently early stage, appropriate management steps may be taken to rectify further seawater and/or saltwater encroachment. Received: 23 July 1996 · Accepted: 25 June 1997  相似文献   

11.
Groundwater resources are vulnerable to contamination especially in shallow aquifers. The aquifer hydrogeological parameters and the Land Uses category combinations lead to subdivide areas according to their contamination likelihood. In arid and semi-arid regions, shallow aquifers are more exposed to groundwater contamination due to high population densities (extensive uses) and agricultural activities (nitrate contamination). Moreover, these regions are characterized by low rainfall and high evaporation. Furthermore, the spread of farmland, industrial and domestic sectors, is the principal contaminant producer which threats the groundwater quality. To protect these limited resources, the groundwater vulnerability assessment was developed in Maritime Djeffara shallow aquifer (Southeastern Tunisia). The study area is essentially occupied by agricultural areas (intensive use of chemical fertilizers) in addition to the discharge of industrial zones. The main objective of this study is to assess the aquifer vulnerability using the Susceptibility Index (SI) method as a specific vulnerability model. The results show that the study area is classified into five classes of vulnerability: very low, low, medium, high, and very high (1.54, 20, 41.54, 35.9, and 1.02%, respectively) with an uneven spatial distribution. The risk results exhibit three degrees: low, moderate, and high. The validation of the vulnerability model was performed by using salinity values and nitrate concentrations with a correlation coefficient of about 57 and 55%, respectively. This study could serve as a scientific basis for sustainable land use planning and groundwater management in the study area.  相似文献   

12.
The impact of groundwater withdrawals on the interaction between multi-layered aquifers with different water qualities in the Viterbo geothermal area (central Italy) was studied. In this area, deep thermal waters are used to supply thermal spas and public pools. A shallow overlying aquifer carries cold and fresh water, used for irrigation and the local drinking-water supply. Starting with a conceptual hydrogeological model, two simplified numerical models were implemented: a steady-state flow model of the entire groundwater system, and a steady-state flow and heat transport model of a representative area, which included complex interactions between the aquifers. The impact of increased withdrawals associated with potential future development of the thermal aquifer must be considered in terms of the water temperature of the existing thermal sources. However, withdrawals from the shallow aquifer might also influence the discharge of thermal sources and quality of the water withdrawn from the shallow wells. The exploitation of the two aquifers is dependent on the hydraulic conductivity and thickness of the intervening aquitard, which maintains the delicate hydrogeological equilibrium. Effective methods to control this equilibrium include monitoring the vertical gradient between the two aquifers and the residual discharge of natural thermal springs.  相似文献   

13.
In hardrock terrain where seasonal streams are not perennial source of freshwater, increase in ground water exploitation has already resulted here in declining ground water levels and deteriorating its’ quality. The aquifer system has shown signs of depletion and quality contamination. Thus, to secure water for the future, water resource estimation and management has urgently become the need of the hour. In order to manage groundwater resources, it is vital to have a tool to predict the aquifer response for a given stress (abstraction and recharge). Artificial neural network (ANN) has surfaced as a proven and potential methodology to forecast the groundwater levels. In this paper, Feed-Forward Network based ANN model is used as a method to predict the groundwater levels. The models are trained with the inputs collected from field and then used as prediction tool for various scenarios of stress on aquifer. Such predictions help in developing better strategies for sustainable development of groundwater resources.  相似文献   

14.
Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO4 water type with little contribution of Ca–Mg–HCO3, Na–K–Cl–SO4 and Na–K–HCO3. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO4, HCO3, pCO2, Ca, Mg, Na, K, Cl and NO3). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).  相似文献   

15.
In recent decades, the high population growth has increased the demand for agricultural lands and products. Groundwater offers reliability and flexibility in access to water for irrigation purposes, especially in arid and semi-arid areas, such as Amol-Babol Plain, Iran. However, the quality and quantity of groundwater may not be suitable for irrigation purposes in all areas due to urbanizations, and intensive agricultural and industrial activities. Groundwater suitability zoning for irrigation purposes could be useful to improve water resources and land use planning, mostly in areas with water scarcity. Therefore, a GIS-based indices method is proposed to assess suitable zones for agricultural activities, integrating the irrigation water quality (IWQ) index and hydrogeological factors. IWQ index was utilized to assess groundwater quality based on salinity hazard, infiltration hazard, specific ions, and trace elements hazards, and miscellaneous effects such as pH, bicarbonate, and nitrate. The potential of the aquifer for irrigation water abstraction was investigated using hydrogeological surveys such as slope angle of the plain, hydraulic conductivity, and aquifer thickness. The groundwater suitability index classified most of the study area (more than 90 %) as “excellent” or “good” suitability zones for irrigation purposes. A limited area of around 5.6 % of the total area has moderate suitability for irrigation purposes due to the Caspian Seawater intrusion and the presence of fossil saline water. The proposed methodology provides useful information in order to allow irrigation management to prevent water and soil deterioration.  相似文献   

16.
The phreatic aquifer beneath the Pampean plain, in eastern central Argentina, constitutes a relevant source of water supply in the area. The objective of this work was to assess the significance of the cation exchange processes in the hydrochemical evolution of this aquifer, based on a study case located in the middle and upper basin of the El Pescado creek. Results indicate that Ca2+/Na+ exchange is the main process determining the evolution of groundwater from the recharge areas (Ca–HCO3) towards the local discharge areas (Na–HCO3), as well as representing a source of Na+ contribution to the water in the aquifer. This hydrochemical characteristic is central to the identification of local discharge areas within a plain environment which extends regionally. The ion exchange capacity of these discharge areas has environmental importance, due to its influence on groundwater quality and potential groundwater uses. These results may be applied to any aquifer sharing similar hydrogeological characteristics.  相似文献   

17.
The study of groundwater impact on the hydrochemical characteristic of groundwater within Mullusi aquifer, west Iraq was conducted using the chemical analysis results in 14 production wells and groundwater levels observation in 17 water wells. The interpretation of hydrochemical phenomena related to ions sources was determined based on spatial analysis maps of various hydrochemical ratios using ArcGis software. The study also determined the relation of groundwater velocity and static water levels with the hydrochemical ratios using statistical application of Curve expert v1.3 program. The variations of ion concentration were examined using the statistical significant differences for chemical constituents of water within Mullusi aquifer. The impact of dewatering due to high exploitation was explained by increasing the magnesium and chloride concentrations and lowering static water levels. Magnesium and chloride concentration may reach their maximum limits for drinking at a groundwater level of 485 m asl. Accordingly, any decline in the water level of Mullusi aquifer that occurs from 4.5 to 30.5 m may cause deterioration in groundwater quality. This study modeled the effect of groundwater depletion on the groundwater quality in a theoretical equations approach.  相似文献   

18.
Natural arsenic(As)contamination of groundwater which provides drinking water and/or irrigation supplies remains a major public health issue,particularly in South and Southeast Asia.A number of studies have evaluated various aspects of the biogeochemical controls on As mobilization in aquifers typical to this region,however many are predicated on the assumption that key biogeochemical processes may be deduced by sampled water chemistry.The validity of this assumption has not been clearly established even though the role of sorption/desorption of As and other heavy metals onto Fe/Mn(hydr)oxides is an important control in As mobilization.Here,selective chemical extractions of sand-rich and clay-rich sediments from an As-affected aquifer in Kandal Province,Cambodia,were undertaken to explore the potential role of partial re-equilibrium through sorption/desorption reactions of As and related solutes(Fe,Mn and P)between groundwater and the associated solid aquifer matrix.In general,groundwater As is strongly affected by both pH and Eh throughout the study area.However,contrasting sorption behaviour is observed in two distinct sand-dominated(T-Sand)and clay dominated(T-Clay)transects,and plausibly attributed to differing dominant lithologies,biogeochemical and/or hydrogeological conditions.Sorption/desorption processes appear to be re-setting groundwater As concentrations in both transects,but to varying extents and in different ways.In T-Sand,which is typically highly reducing,correlations suggest that dissolved As may be sequestered by sorption/re-adsorption to Fe-bearing mineral phases and/or sedimentary organic matter;in T-Clay Eh is a major control on As mobilization although binding/occlusion of Fe-bearing minerals to sedimentary organic matter may also occur.Multiple linear regression analysis was conducted with groups categorised by transect and by Eh,and the output correlations support the contrasting sorption behaviours encountered in this study area.Irrespective of transect,however,the key biogeochemical processes which initially control As mobilization in such aquifers,may be "masked" by the re-setting of As concentrations through in-aquifer sorption/desorption processes.  相似文献   

19.
Karst aquifers are particularly vulnerable to bacterial contamination. Especially in developing countries, poor microbial water quality poses a threat to human health. In order to develop effective groundwater protection strategies, a profound understanding of the hydrogeological setting is crucial. The goal of this study was to elucidate the relationships between high spatio-temporal variability in microbial contamination and the hydrogeological conditions. Based on extensive field studies, including mapping, tracer tests and hydrochemical analyses, a conceptual hydrogeological model was developed for a remote and geologically complex karst area in Northern Vietnam called Dong Van. Four different physicochemical water types were identified; the most important ones correspond to the karstified Bac Son and the fractured Na Quan aquifer. Alongside comprehensive investigation of the local hydrogeology, water quality was evaluated by analysis for three types of fecal indicator bacteria (FIB): Escherichia coli, enterococci and thermotolerant coliforms. The major findings are: (1) Springs from the Bac Son formation displayed the highest microbial contamination, while (2) springs that are involved in a polje series with connections to sinking streams were distinctly more contaminated than springs with a catchment area characterized by a more diffuse infiltration. (3) FIB concentrations are dependent on the season, with higher values under wet season conditions. Furthermore, (4) the type of spring capture also affects the water quality. Nevertheless, all studied springs were faecally impacted, along with several shallow wells within the confined karst aquifer. Based on these findings, effective protection strategies can be developed to improve groundwater quality.  相似文献   

20.
马振民  陈鸿汉 《地球科学》2000,25(5):472-476
通过对泰安市第四系水文地质结构研究发现, 浅层地下水的污染受地层结构的控制, 在包气带岩性及含水层岩性相同的条件下, 包气带的厚度越大, 其防污性能越高, 含水层遭受污染的程度越小; 在地面环境质量及包气带岩性和厚度相近的条件下, 粗砂含水层较粉质粘土含水层更易遭受污染   相似文献   

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