Transport of nonmethane hydrocarbons to Jupiter's troposphere by descent of smog particles

Ethane and other C₂ and C₃ nonmethane hydrocarbons were observed by the Galileo Probe Mass Spectrometer to have a deep minimum in mixing ratio near and below the tropopause, rising to much larger values at and below the 15 bar level. This minimum requires that these hydrocarbons condense on smog particles at low temperatures. The large amounts at deeper levels were produced in the pumping system of the instrument and any contribution from the ambient atmosphere cannot be resolved, although evaporation from the smog particles is proposed and incorporated in a model. In the stratosphere some of the ethane is released by photon-stimulated desorption. The other light nonmethane hydrocarbons are not modeled, but can be expected to show the same behavior as ethane.     

Improved Determination of Ethane (C2H6) Abundance in Titan's Stratosphere

Ethane spectral lines were observed in emission from Titan in August 1993, October 1995, and September 1996, at a spectral resolution of λ/Δλ≈10⁶, at wavelength 11.7−11.9 μm using the Goddard Infrared Heterodyne Spectrometer at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. The ethane mole fraction is determined to be (8.8±2.2)×10⁻⁶ (68.3% confidence limits, “1σ”), averaging the retrievals from each observing run obtained using the “recommended” thermal profile of R. V. Yelle, D. Strobel, E. Lellouch, and D. Gautier (1997, in Huygens: Science, Payload, and Mission (J.-P. Lebreton, Ed.), pp. 243-256, European Space Agency SP-1177).     

Microphysical modeling of ethane ice clouds in titan’s atmosphere

A time-dependent microphysical model is used to study the evolution of ethane ice clouds in Titan’s atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles. For a critical saturation of 1.15 (a lower limit, determined by laboratory experiments), we find that ethane clouds can be sustained between altitudes of 8 and 50 km. Growth due to coalescence is inefficient, limiting the peak in the size distribution (by number) to 10 μm. These clouds vary with a period of about 20 days. This periodicity disappears for higher critical saturation values where clouds remain subvisible. Rainout of ethane due to methane cloud formation raises the altitude of the ethane cloud bottom to near the tropopause and may eliminate ethane clouds entirely if methane cloud formation occurs up to 30 km. However, clouds formed above the troposphere from other gases in Titan’s atmosphere could be sustained even with rainout up to 30 km. Although the optical depth of ethane clouds above 20 km is typically low, short-lived clouds with optical depths of order 0.1-1 can be created sporadically by dynamically driven atmospheric cooling. Ethane cloud particles larger than 25 μm can fall to the surface before total evaporation. However, ethane clouds remain only a small sink for tholin particles. At the peak of their cycle, the optical depth of ethane clouds could be comparable to that of tholin in the near-infrared, resulting in a 5% increase in Titan’s albedo for wavelengths between 1 and 2 μm. A number of factors limit our ablility to predict the ethane cloud properties. These factors include the mixing time in the troposphere, the critical saturation ratio for ethane ice, the existence of a surface reservoir of ethane, the magnitude and timing of dynamically driven temperature perturbations, and the abundance and life cycle of methane clouds.     

Methane, ethane, and mixed clouds in Titan's atmosphere: Properties derived from microphysical modeling

Theoretical arguments point to and recent observations confirm the existence of clouds in Titan's atmosphere, yet we possess very little data on their particle size, composition and formation mechanism. A time-dependent microphysical model is used to study the evolution of ice clouds in Titan's atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles in a column of atmosphere. A variety of cloud compositions are studied, including pure ethane clouds, pure methane clouds, and mixed methane-ethane clouds (all with tholin cores). The abundance of methane cloud particles may be limited by the number of ethane coated tholin nuclei rather than the number of tholins with hydrocarbon coatings. However, even the condensation of methane onto these relatively sparse ethane/tholin cloud particles is sufficient to keep the methane close to saturation. Typical methane supersaturations are of order 0.06 on the average. For simulations which take into account recent lab measurements indicating it is relatively easy for methane to nucleate onto tholin particles without an ethane-layer present, the three types of clouds (methane, ethane, and mixed) exist simultaneously. Pure methane clouds are the most abundant cloud type and serve to lower the supersaturation to about 0.04. Cloud production does not require a continuous surface source of methane. However, clouds produced by mean motions are not the visible methane clouds seen in recent Cassini and ground-based observations. Ethane clouds in the troposphere almost instantaneously nucleate methane to form mixed clouds. However, a thin ethane ‘haze’ remains just above the tropopause for some scenarios and the mixed clouds at the tropopause remain ?50% ethane by mass. Also, evaporation of methane from the mixed cloud particles near the surface leaves a thicker layer of ethane cloud particles at ∼10 km. Nevertheless, the precipitation rate of methane to Titan's surface is between 0.001 and 0.5 cm/terrestrial-year, depending on various initial conditions such as critical saturation, size and abundance of cloud condensation nuclei, surface sources and eddy diffusion.     

Meridional variations in stratospheric acetylene and ethane in the southern hemisphere of the saturnian atmosphere as determined from Cassini/CIRS measurements

These are the first results from nadir studies of meridional variations in the abundance of stratospheric acetylene and ethane from Cassini/CIRS data in the southern hemisphere of Saturn. High resolution, 0.5 cm⁻¹, CIRS data was used from three data sets taken in June-November 2004 and binned into 2° wide latitudinal strips to increase the signal-to-noise ratio. Tropospheric and stratospheric temperatures were initially retrieved to determine the temperature profile for each latitude bin. The stratospheric temperature at 2 mbar increased by 14 K from 9° to 68° S, including a steep 4 K rise between 60° and 68° S. The tropospheric temperatures showed significantly more meridional variation than the stratospheric ones, the locations of which are strongly correlated to that of the zonal jets. Stratospheric acetylene abundance decreases steadily from 30 to 68° S, by a factor of 1.8 at 2.0 mbar. Between 18° and 30° S the acetylene abundance increases at 2.0 mbar. Global values for acetylene have been calculated as (1.9±0.19)×¹⁰⁻⁷ at 2.0 mbar, (2.6±0.27)×¹⁰⁻⁷ at 1.6 mbar and (3.1±0.32)×¹⁰⁻⁷ at 1.4 mbar. Global values for ethane are also determined and found to be (1.6±0.25)×¹⁰⁻⁵ at 0.5 mbar and (1.4±0.19)×¹⁰⁻⁵ at 1.0 mbar. Ethane abundance in the stratosphere increases towards the south pole by a factor of 2.5 at 2.0 mbar. The increase in stratospheric ethane is especially pronounced polewards of 60° S at 2.0 mbar. The increase of stratospheric ethane towards the south pole supports the presence of a meridional wind system in the stratosphere of Saturn.     

Detection of new hydrocarbons in Uranus' atmosphere by infrared spectroscopy

Ethane (C₂H₆), methylacetylene (CH₃C₂H or C₃H₄) and diacetylene (C₄H₂) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×¹⁰⁻⁸, (2.5±0.3)×¹⁰⁻¹⁰, and (1.6±0.2)×¹⁰⁻¹⁰, respectively. These hydrocarbons complement previously detected methane (CH₄) and acetylene (C₂H₂). Carbon dioxide (CO₂) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×¹⁰⁻¹¹. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH₃) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.     

Some problems related to the origin of methane on Mars

The following problems related to the origin of methane on Mars have been considered. (1) Laboratory simulations of the impact phenomena confirm effective heterogeneous chemistry between the products of the fireball. This chemistry lowers the fireball freezing temperature from 2000 to 750 K for methane and to 1100 K for CO/CO₂. Production of methane on Mars by cometary impacts is 0.8% of the total production. A probability that the observed methane on Mars came from impact of a single comet is 0.0011. (2) The PFS observations of variations of methane on Mars require a very effective heterogeneous loss of methane. Heterogeneous effect of dust is half that of the surface rocks. Thermochemical equilibrium requires production, not loss, of methane. Existing kinetic data show a very low efficiency of heterogeneous reactions of methane. Highly reactive superoxide ions generated by the solar UV photons on the martian rocks cannot remove methane. The required efficiency of heterogeneous loss of methane on Mars is higher than that on Earth by a factor of ?1000, although the expected efficiency on Earth is stronger than that on Mars because of the liquid ocean and the abundant oxygen. All these inconsistencies may be removed if variations of the rock reflectivity contribute to the PFS observations of methane on Mars. The PFS data on H₂CO, HCl, HF, and HBr also raise doubts. (3) Although geologic sources of methane are possible, the lack of current volcanism, hydrothermal activity, hot spots, and very low seepage of gases from the interior are not favorable for geologic methane. Any proposed geological source of methane on Mars should address these problems. Some weak points in the suggested geologic sources are discussed. (4) Measurements of ¹³C/¹²C and D/H in methane would be difficult because of the low methane abundance. These ratios are mostly sensitive to a temperature of methane formation and cannot distinguish between biogenic and low-temperature geologic sources. Their analysis requires the carbon isotope ratio in CO₂ on Mars, which is known with the insufficient accuracy, and D/H in water, which is different in the atmosphere, polar caps, regolith and interior. Therefore, the stable isotope ratios may not give a unique answer on the origin of methane. (5) Ethane and propane react with OH much faster than methane. If their production relative to methane is similar to that on Earth, then their expected abundances on Mars are of a few parts per trillion. (6) Loss of SO₂ in the reaction with peroxide on ice is smaller than its gas-phase loss by an order of magnitude. The overall results strengthen the biogenic origin of martian methane and its low variability.     

The influence of ethane and acetylene upon the thermal structure of the Jovian atmosphere

Ethane and acetylene, both of which possess more efficient emission bands than methane, have been incorporated into a thermal structure model for the atmosphere of Jupiter. Choosing for illustrative purposes the mixing ratios $\text{[}\text{C}{}_2\text{H}{}_6\text{]}\text{[}\text{H}{}_2\text{]}\text{= 10}{}^{\mathrm{?5}}$ and $\text{[}\text{C}{}_2\text{H}{}_2\text{]}\text{[}\text{H}{}_2\text{]}\text{= 5 × 10}{}^{\mathrm{?7}}$, it is found that these hydrocarbon gases lower the atmospheric temperature within the thermal inversion region by as much as 20 K, subsequently reducing the emission intensity of the 7.7 μm CH₄ band below the observed result. It is qualitatively shown, however, that this cooling by C₂H₆ and C₂H₂ could be compensated by aerosol heating resulting from a uniformily mixed aerosol which absorbs 15% of the incident solar radiation. Such aerosol heating has been suggested by uv albedo observations.     

Meridional variations of C2H2 and C2H6 in Jupiter's atmosphere from Cassini CIRS infrared spectra

Hydrocarbons such as acetylene (C₂H₂) and ethane (C₂H₆) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm⁻¹ (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm⁻¹) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν₄ band of CH₄, and in the troposphere at 150-400 mbar, via the H₂ absorption at 600-800 cm⁻¹. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C₂H₂ and C₂H₆ by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C₂H₂ν₅ and C₂H₆ν₉ bands, and also emission of the acetylene (ν₄+ν₅)−ν₄ hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×¹⁰⁻⁹. Additionally, the abundance gradient of C₂H₂ between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C₂H₂ and C₂H₆ by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C₂H₆ in the stratosphere (3×¹⁰¹⁰ s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×¹⁰⁸ s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C₂H₂, the opposite occurs, with the relatively short photochemical lifetime (3×¹⁰⁷ s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.     

Dissimilarities in Perseid meteoroids

Abstract— A shutter-chopped, direct photograph of a 1980 Perseid meteor is discussed in which no shutter breaks are apparent. Evidence is considered that it is indeed a Perseid and that the phenomenon is the result of an extraordinary fragmentation of the meteoroid. Tentative evidence is presented for the existence in 1980 of a second radiant from which the apparently unchopped meteor and a second meteor, also showing marked fragmentation, emanated. The fragmentation of these two meteors and the concentration of their radiant are consonant with the concept of their origin from recently released material from the nearby parent comet.     

The X-ray intensity-hardness ratio relation in LMXRB

It is sometimes suggested that the change from the horizontal to the normal branch in the X-ray intensity-hardness ratio diagram of low mass X-ray binaries, is due to a change from a thin to a thick disk. It is shown here that wind from the hot thick disk depletes the amount of matter reaching the neutron star, thus causing the observed reduction of X-ray intensity as hardness ratio decreases in the normal branch.     

Terrestrial microfossils in Antarctic ordinary chondrites

Abstract— Microfossils have been separated and identified in four high metamorphic grade chondrites from Allan Hills and Queen Alexandra Range, Antarctica. Diatoms and opal phytoliths representing both marine and terrestrial flora were recognized among the dust removed from cracks in all meteorites studied. It is likely that contamination of Antarctic meteorites with such biogenic material is ubiquitous. Standard clean room procedures to avoid laboratory introduction of microfossils into the meteorites were followed, and the genera and species identified so far are characteristic of marine, freshwater, and continental environments. The most probable mechanism for introduction of the microfossils into the meteorites is eolian transport to and on the polar ice cap. It is likely that wind-driven systems may sample atmospherically transported material from large portions of the southern hemisphere. Entrainment of terrestrial microfossils is probably a typical interaction of meteorites with the Antarctic environment and must be recognized and accounted for in any attempt to use Antarctic meteorites as sources of extraterrestrial life forms. Organic molecules derived from microfossils are likely to be pervasive throughout any crack network present in a meteorite at all scales from millimeter to submicron. Cracks are a ubiquitous consequence of weathering in and on the Antarctic ice and the probability that crack surfaces contain terrestrial organic materials is high.     

Black Holes in a Violent Universe

“Black Holes in a Violent Universe” is a COST Action (MP0905) connecting scientists from different disciplines – astronomers from all wavelength regimes (i.e. radio to TeV), physicists and particle physicists, theoreticians and observers – from currently 25 countries. The aim is to collaborate in a cross-disciplinary and multi-dimensional approach towards a better understanding of the general Black Hole phenomenon. COST (European Cooperation in Science and Technology) is one of the longest-running European instruments supporting cooperation among scientists and researchers across Europe. The goal of MP0905 is to decipher further the way the Universe and the stars and galaxies evolved and – in particular – the role Black Holes play in this. This Action is an open and flexible program of communication and interchange.     

A problem in resonance

Saturn's satellite Hyperion experiences large perturbations by Titan, the largest of Saturn's satellites, because of the closeness of Hyperion's orbital period to three-quarters of that of Titan.The motion of Hyperion is a superposition of periodic fluctuations (both free and forced) onto a motion which is periodic in a suitable uniformly rotating frame of reference, and in which Hyperion would be at a maximum distance from Saturn at each conjunction with Titan.Successive attempts to determine the mass of Titan from observed perturbations of Hyperion have suffered from omissions in the theory of terms subsequently found to be significant.An attempt is in progress which, it is believed, comprises all long-period changes in the osculating elements which are of second degree in the mass of Titan, and of third degree in the eccentricity of its orbit. Results so far obtained indicate that the period of the free motion of the orbit plane of Hyperion is better determined by Woltjer's reduction of the observations than by his theoretical calculations.Presented at the Conference on Celestial Mechanics, Oberwolfach, Germany, August 27–September 2, 1972.     

Multiple-mirror telescope systems in astronomy

The function of a telescope is to optimize the transfer of the information of interest from a source of finite angular size to the analytical device which is going to extract it. It is far from obvious that the conventional large telescope is the optimum fore-optical system for looking through a turbulent atmosphere. There are considerable scientific and financial advantages in going to multiple-imaging-elements and several groups in different parts of the world are working in this direction.Presented at Primars-1 Conference, held at University of Manchester, June 26–30, 1979.     

The separation of field and fluid in the Sun

The magnetic field at the surface of the Sun is confined to widely separated small, intense magnetic flux bundles or fibrils with most of the gas in a relatively field free state in the interstices. There is evidently a systematic field and fluid separation effect in operation, overriding the tendency for turbulent mixing of the two phases. It is well known that a constantly rotating volume of fluid soon excludes any exterior magnetic field. To take the next theoretical step, this paper examines the exclusion of magnetic field from a circular cylinder with oscillating angular velocity. The result is that the field is effectively excluded from any oscillating or tumbling body of fluid that maintains coherence over a sufficiently long time. However, there is no expectation of such long term coherence in turbulent convection in the Sun, suggesting that the observed separation of field and fluid does not come about by the exclusion of field from convective cells. This leads to the conclusion that the separation of fluid and field is a consequence of extraction of fluid from the field through buoyancy and reconnection.     

Superluminal motion in the parsec-scale jet in 3C 380

We present extensive multi-epoch VLBI observations of the quasar 3C 380 which reveal a bent parsec-scale radio jet with complex substructure which exhibits superluminal motion out to ∼100 pc from the active core. The general characteristics of the jet and its motion are similar to those in several other well-studied superluminal sources, most notably a rapid increase in the opening angle at a projected distance of a few tens of parsecs from the core and apparent acceleration along the jet. This acceleration could be a simple kinematic effect associated with bulk flow at a constant speed, but at a varying angle to the line of sight. The jet is well resolved in the transverse direction for the majority of its length and resembles numerical simulations of a jet disrupted by the rapid growth of sinusoidal 'Kelvin–Helmholtz' modes. Our maps also reveal extremely rapid localized variations in brightness which have not yet been seen in other nuclear jets. We suggest that phase effects, arising from the intersection of oblique shocks, may be the cause of these dramatic changes. 3C 380 is often classified as a compact steep spectrum (CSS) source; however, in contrast to the majority of CSS sources, it is likely that 3C 380 is simply a powerful FRII source seen approximately end-on.     

Self-regulated gravitational accretion in protostellar discs

We present a numerical model for the evolution of a protostellar disc that has formed self-consistently from the collapse of a molecular cloud core. The global evolution of the disc is followed for several million years after its formation. The capture of a wide range of spatial and temporal scales is made possible by use of the thin-disc approximation. We focus on the role of gravitational torques in transporting mass inward and angular momentum outward during different evolutionary phases of a protostellar disc with disc-to-star mass ratio of order 0.1. In the early phase, when the infall of matter from the surrounding envelope is substantial, mass is transported inward by the gravitational torques from spiral arms that are a manifestation of the envelope-induced gravitational instability in the disc. In the late phase, when the gas reservoir of the envelope is depleted, the distinct spiral structure is replaced by ongoing irregular non-axisymmetric density perturbations. The amplitude of these density perturbations decreases with time, though this process is moderated by swing amplification aided by the existence of the disc's sharp outer edge. Our global modelling of the protostellar disc reveals that there is typically a residual non-zero gravitational torque from these density perturbations, i.e. their effects do not exactly cancel out in each region. In particular, the net gravitational torque in the inner disc tends to be negative during first several million years of the evolution, while the outer disc has a net positive gravitational torque. Our global model of a self-consistently formed disc shows that it is also self-regulated in the late phase, so that it is near the Toomre stability limit, with a near-uniform Toomre parameter Q ≈ 1.5–2.0. Since the disc also has near-Keplerian rotation, and comparatively weak temperature variation, it maintains a near-power-law surface density profile proportional to r ^−3/2.     

Magnetic flux separation in photospheric convection

Three-dimensional non-linear magnetoconvection in a strongly stratified compressible layer exhibits different patterns as the strength of the imposed magnetic field is reduced. There is a transition from a magnetically dominated regime, with small-scale convection in slender hexagonal cells, to a convectively dominated regime, with clusters of broad rising plumes that confine the magnetic flux to narrow lanes where fields are locally intense. Both patterns can coexist for intermediate field strengths, giving rise to flux separation: clumps of vigorously convecting plumes, from which magnetic flux has been excluded, are segregated from regions with strong fields and small-scale convection. A systematic numerical investigation of these different states shows that flux separation can occur over a significant parameter range and that there is also hysteresis. The results are related to the fine structure of magnetic fields in sunspots and in the quiet Sun.