Stable isotopes of atmospheric water vapour and precipitation in the northeast Qinghai‐Tibetan Plateau

Stable water isotopes (δ¹⁸O and δ²H) are an important source signature for understanding the hydrological cycle and altered climate regimes. However, the mechanisms underlying atmospheric water vapour isotopes in the northeast Qinghai‐Tibetan Plateau of central Asia remain poorly understood. This study initially investigated water vapour isotopic composition and its controls during the premonsoon and monsoon seasons. Isotopic compositions of water vapour and precipitation exhibited high variability across seasons, with the most negative average δ¹⁸O values of precipitation and the most positive δ¹⁸O values of water vapour found during the premonsoon periods. Temperature effect was significant during the premonsoon period but not the monsoon period. Both a higher slope and intercept of the local meteoric water line were found during the monsoon period as compared with in the premonsoon period, suggesting that raindrops have been experienced a greater kinetic fractionation process such as reevaporation below the cloud during the premonsoon periods. The δ²H and δ¹⁸O signatures in atmospheric water vapour tended to be depleted with the occurrence of precipitation events especially during the monsoon period and probably as a result of rainout processes. The monthly average contribution of evaporation from the lake to local precipitation was 35.2%. High d‐excess values of water vapour were influenced by the high proportion of local moisture mixing, as indicated by the gradually increasing relative humidity along westerly and Asian monsoon trajectories. The daily observation (observed ε) showed deviations from the equilibrium fractionation factors (calculated ε), implying that raindrops experienced substantial evaporative enrichment during their descent. The average fraction of raindrops reevaporation was estimated to be 16.4± 12.9%. These findings provide useful insights for understanding the interaction between water vapour and precipitation, moisture sources, and help in reconstructing the paleoclimate in the alpine regions.     

Snowpack disrupts relationship between young water fraction and isotope amplitude ratio; approximately one fifth of mountain streamflow less than one year old

Previous “fraction of young water” (F_yw) estimates based on relative annual isotopic amplitudes in precipitation (A_p) and streamflow (A_s) produced low F_yw values in mountain catchments, which is contrary to extensive research that reports rapid water transmission in mountains. This study investigated this discrepancy by testing the effect of snow accumulation on the model that underpins the F_yw method. A Monte-Carlo analysis of simulations for 20,000 randomly-generated catchment model configurations used 10 years of precipitation inputs for the Upper Elbow River catchment in the Rocky Mountains (Alberta, Canada) to model discharge with and without snowpack storage of winter precipitation. Neither direct nor modified precipitation input produced a 1:1 relationship between A_s/A_p and F_yw, undermining the applicability of the original F_yw method in mountain watersheds with large seasonal snow accumulation. With snowpack-modified input a given A_s/A_p ratio corresponds to a range of F_yw values, which can still provide semi-quantitative information. In the small (435 km²) Elbow River catchment a F_yw range of 7–23% supports previous findings of rapid transmission in mountain catchments. Further analysis showed that the improved discharge prediction (Nash–Sutcliffe efficiency > 0.9) correlates with higher F_yw values and demonstrated that the interannual shifts in δ¹⁸O can be used to estimate of new water (<1 year) fraction in winter streamflow, and the estimate of 20% for the Elbow River further supports rapid transmission in mountain catchments.     

Seasonal snow cover decreases young water fractions in high Alpine catchments

Estimation of young water fractions (F_yw), defined as the fraction of water in a stream younger than approximately 2–3 months, provides key information for water resource management in catchments where runoff is dominated by snowmelt. Knowing the average dependence of summer flow on winter precipitation is an essential context for comparing regional drought severity and provides the hydrological template for downstream water users and ecosystems. However, F_yw estimation based on seasonal signals of stable isotopes of oxygen and hydrogen has not yet explicitly addressed how to parsimoniously include the seasonal shift of water input from snow. Using experimental data from three high-elevation, Alpine catchments (one dominated by glacier and two by snow), we propose a framework to explicitly include the delays induced by snow storage into estimates of F_yw. Scrutinizing the key methodological choices when estimating F_yw from isotope data, we find that the methods used to construct precipitation input signals from sparse isotope samples can significantly impact F_yw. Given this sensitivity, our revised procedure estimates a distribution of F_yw values that incorporates a wide range of possible methodological choices and their uncertainties; it furthermore compares the commonly used amplitude ratio approach to a direct convolution approach, which circumvents the assumption that the isotopic signals have a sine curve shape, an assumption that is generally violated in snow-dominated environments. Our new estimates confirm that high-elevation Alpine catchments have low F_yw values, spanning from 8 to 11%. Such low values have previously been interpreted as the impact of seasonal snow storage alone, but our comparison of different F_yw estimation methods suggests that these low F_yw values result from a combination of both snow cover effects and longer storage in the subsurface. In contrast, in the highest elevation, glacier dominated catchment, F_yw is 3–4 times greater compared to the other two catchments, due to the lower storage and faster drainage processes. A future challenge, capturing spatio-temporal snowmelt isotope signals during winter baseflow and the snowmelt period, remains to improve constraints on the F_yw estimation technique.     

Investigating young water fractions in a small Mediterranean mountain catchment: Both precipitation forcing and sampling frequency matter

The proportion of water younger than 2–3 months (young water fraction, F_yw) has become increasingly investigated in catchment hydrology. F_yw is typically estimated by comparing seasonal tracer cycles in precipitation and streamflow, through water sampling. However, some open research questions remain, such as: (i) whether part of the summer precipitation should be discarded because the high evapotranspiration demand, (ii) how well F_yw serves as a metric to compare catchments, and (iii) how sampling frequency affects F_yw estimates. To address these questions, we investigated F_yw in soil-, ground- and stream waters for the small Mediterranean Can Vila catchment. Rainfall was sampled at 5-mm intervals. Mobile soil water and groundwater were sampled fortnightly. Stream water was sampled depending on flow at variable time intervals (30 min to 1 week). Over 58 months, this sampling provided 1,529 δ¹⁸O determinations. Isotopic analyses results led us to include summer precipitation in the input signal. We found the highest F_yw in mobile soil waters (34%), while this was almost zero for groundwater except during wet periods. For stream waters, F_yw depended on the discharge variations, so that the flow-weighted young water fraction () was 22.6%, whereas the time-weighted F_yw was just 6.2%. Both and its discharge sensitivity (S_d) varied when different 12-month sampling periods were investigated. The young water fraction that would be obtained from a virtual thorough sampling () was estimated from the S_d and the observed stream flow. This showed an underestimation of by 25% for the frequent dynamic sampling and 66% for weekly sampling, due to missing high flows. Our results confirm that F_yw and its discharge sensitivity are metrics very sensitive to meteorological forcing during the analysed period. Thus, comparisons between catchments need long-term mean annual values and their variability. Our findings also support the dependence of F_yw estimates on the sampling rate and show the advantages of flow-weighted analysis. Finally, catchment water turnover investigations should be accompanied by the analysis of flow duration curves.     

Distinguishing streamflow trends caused by changes in climate,forest cover,and permafrost in a large watershed in northeastern China

Understanding how rivers respond to changes in land cover, climate, and subsurface conditions is critical for sustainably managing water resources and ecosystems. In this study, long‐term hydrologic, climate, and satellite data (1973–2012) from the Upper Tahe River watershed (2359 km²) in the Da Hinggan Mountains of northeast China were analysed to quantify the relative hydrologic effects of climate variability (system input) and the combined influences of forest cover change and permafrost thaw (system characteristics) on average annual streamflow (system response) using 2 methods: the sensitivity‐based method and the Kendall–Theil robust line method. The study period was subdivided into a forest harvesting period (1973–1987), a forest stability period (1988–2001), and a forest recovery period (2002–2012). The results indicated that the combined effects of forest harvesting and permafrost thaw on streamflow (+ 47.0 mm) from the forest harvesting period to the forest stability period was approximately twice as large as the effect associated with climate variability (+20.2 mm). Similarly, from the forest stability period to the forest recovery period, the decrease in average annual streamflow attributed to the combined effects of forest recovery and permafrost thaw (?38.0 mm) was much greater than the decrease due to climate variability (?22.2 mm). A simple method was used to separate the distinct impacts of forest cover change and permafrost thaw, but distinguishing these influences is difficult due to changes in surface and subsurface hydrologic connectivity associated with permafrost thaw. The results highlight the need to consider multiple streamflow drivers in future watershed and aquatic ecosystem management. Due to the ecological and hydrological susceptibility to disturbances in the Da Hinggan Mountains, forest harvesting will likely negatively impact ecohydrological processes in this region, and the effects of forest species transition in the forest recovery process should be further investigated.     

Surface and subsurface water contributions to streamflow from a mesoscale watershed in complex mountain terrain

An understanding of surface and subsurface water contributions to streamflow is essential for accurate predictions of water supply from mountain watersheds that often serve as water towers for downstream communities. As such, this study used the end‐member mixing analysis technique to investigate source water contributions and hydrologic flow paths of the 264 km² Boulder Creek Watershed, which drains the Colorado Front Range, USA. Four conservative hydrochemical tracers were used to describe this watershed as a 3 end‐member system, and tracer concentration reconstruction suggested that the application of end‐member mixing analysis was robust. On average from 2009 to 2011, snowmelt and rainwater from the subalpine zone and groundwater sampled from the upper montane zone contributed 54%, 22%, and 24% of the annual streamflow, respectively. These values demonstrate increased rainwater and decreased snow water contributions to streamflow relative to area‐weighted mean values derived from previous work at the headwater scale. Young water (2.3 ± 0.8 months) fractions of streamflow decreased from 18–22% in the alpine catchment to 8–10% in the lower elevation catchments and the watershed outlet with implications for subsurface storage and hydrological connectivity. These results contribute to a process‐based understanding of the seasonal source water composition of a mesoscale watershed that can be used to extrapolate headwater streamflow generation predictions to larger spatial scales.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.     

Stable isotope fractionations in the evaporation of water: The wind effect

We performed pan evaporation experiments with the objective of exploring the behaviour of the long-standing Craig–Gordon (C–G) stable isotope model for evaporation under different conditions of air turbulence. The water lost through evaporation was automatically replenished so that a steady isotopic composition was reached, the value of which depended on the isotopic composition of the replenishment water and environmental parameters like temperature, relative humidity and isotopic composition of the atmospheric vapour, and the air turbulence index. The pans were exposed to artificial winds ranging from 0 to 2.5 m/s to change the air turbulence index, which governs the repartition between vapour transported by molecular diffusion and turbulent diffusion. Our data revealed that for wind speeds >0.5 m/s the isotopic composition of the evaporating water deviated from that predicted by the C–G model. This deviation was hypothetically attributed to microdroplets of liquid water removed by the wind without any isotopic fractionation. Isotope mass balance equations allowed us to quantify this water loss, which at wind speeds of ~2 m/s reached 10% of the total evaporation losses. An alternative kinetic evaporation model was proposed whereby the equilibrium layer and the atmospheric laminar layer above the evaporating water of the C–G model were destroyed by the wind and evaporated water molecules were directly injected into the atmosphere. In this model, the isotopic fractionations were due to the slower kinetics of hydrogen bond breakage between molecules in liquid water when heavy isotopes are involved. Accordingly, our data suggested that for isotope water balance studies where winds are frequently above 2 m/s, the C–G model may be inadequate without appropriate corrections for spray vaporization, or the introduction of appropriate kinetic isotope fractionation factors.     

Coupled rainfall and water vapour stable isotope time series reveal tropical atmospheric processes on multiple timescales

High-frequency stable isotope data are useful for validating atmospheric moisture circulation models and provide improved understanding of the mechanisms controlling isotopic compositions in tropical rainfall. Here, we present a near-continuous 6-month record of O- and H-isotope compositions in both water vapour and daily rainfall from Northeast Australia measured by laser spectroscopy. The data set spans both wet and dry seasons to help address a significant data and knowledge gap in the southern hemisphere tropics. We interpret the isotopic records for water vapour and rainfall in the context of contemporaneous meteorological observations. Surface air moisture provided near-continuous tracking of the links between isotopic variations and meteorological events on local to regional spatial scales. Power spectrum analysis of the isotopic variation showed a range of significant periodicities, from hourly to monthly scales, and cross-wavelet analysis identified significant regions of common power for hourly averaged water vapour isotopic composition and relative humidity, wind direction, and solar radiation. Relative humidity had the greatest subdiurnal influence on isotopic composition. On longer timescales (weeks to months), isotope variability was strongly correlated with both wind direction and relative humidity. The high-frequency records showed diurnal isotopic variations in O- and H-isotope compositions due to local dew formation and, for deuterium excess, as a result of evapotranspiration. Several significant negative isotope anomalies on a daily scale were associated with the activity of regional mesoscale convective systems and the occurrence of two tropical cyclones. Calculated air parcel back trajectories identified the predominant moisture transport paths from the Southwest Pacific Ocean, whereas moisture transport from northerly directions occurred mainly during the wet season monsoonal airflow. Water vapour isotope compositions reflected the same meteorological events as recorded in rainfall isotopes but provided much more detailed and continuous information on atmospheric moisture cycling than the intermittent isotopic record provided by rainfall. Improved global coverage of stable isotope data for atmospheric water vapour is likely to improve simulations of future changes to climate drivers of the hydrological cycle.     

Ecohydrologic considerations for modeling of stable water isotopes in a small intermittent watershed

Naturally occurring stable water isotope tracers provide useful information for hydrologic model development and calibration. Existing models include varied approaches concerning unsaturated zone percolation mixing (preferential versus matrix flow) and evapotranspiration (ET) partitioning. We assess the impact of unsaturated zone simplifying assumptions when simulating the Shale Hills Watershed, a small (7.9 ha), temperate, forested watershed near Petersburg, Pennsylvania, USA, with a relatively simple model. We found that different model structures/assumptions and parameterizations of unsaturated zone percolation had substantial impacts on the agreement between simulated and observed unsaturated‐zone water isotopic signatures. We show that unsaturated zone percolation mixing primarily affects the unsaturated zone δ¹⁸O and δ²H during winter and spring and that percolation was best represented as a combination of both preferential and matrix flow. We evaluate the importance and implications related to the partitioning of ET into evaporation and transpiration and demonstrated that incorporation of a plant growth model for ET partitioning substantially improved reproduction of observed hydrologic isotopic patterns of the unsaturated zone during the spring season. We show that unsaturated zone percolation mixing and ET partitioning approaches do not substantially influence stream δ¹⁸O and δ²H and conclude that observed streamflow isotopic data is not always a strong predictor of model performance with respect to intrawatershed processes.     

Effects of streamflow isotope sampling strategies on the calibration of a tracer-aided rainfall-runoff model

Isotopes are increasingly used in rainfall-runoff models to constrain conceptualisations of internal catchment functioning and reduce model uncertainty. However, there is little guidance on how much tracer data is required to adequately do this, and different studies use data from different sampling strategies. Here, we used a 7-year time series of daily stable water isotope samples of precipitation and streamflow to derive a range of typical stream sampling regimes and investigate how this impacts calibration of a semi-distributed tracer-aided model in terms of flow, deuterium and flux age simulations. Over the 7 years weekly sampling facilitated an almost identical model performance as daily, and there were only slight deteriorations in performance for fortnightly sampling. Monthly sampling resulted in poorer deuterium simulations and greater uncertainty in the derived parameter sets ability to accurately represent catchment functioning, evidenced by unrealistic reductions in the volumes of water available for mixing in the saturation area causing simulated water age decreases. Reducing sampling effort and restricting data collection to 3 years caused reductions in the accuracy of deuterium simulation, though the deterioration did not occur if sampling continued for 5 years. Analysis was also undertaken to consider the effects of reduced sampling effort over the driest and wettest hydrological years to evaluate effects of more extreme conditions. This showed that the model was particularly sensitive to changes in sampling during dry conditions, when the catchment hydrological response is most non-linear. Across all dataset durations, sampling in relation to flow conditions, rather than time, revealed that samples collected at flows >Q50 could provide calibration results comparable to daily sampling. Targeting only extreme high flows resulted in poor deuterium and low flow simulations. This study suggests sufficient characterization of catchment functioning can be obtained through reduced sampling effort over longer timescales and the targeting of flows >Q50.     

Constraining water age dynamics in a south-eastern Australian catchment using an age-ranked storage and stable isotope approach

Improving our knowledge of the travel times of water through catchments is critical for the management and protection of water resources and to improve our understanding of fundamental catchment behaviour. In this study we use the age-ranked storage framework StorAge Selection (SAS) to investigate travel times in the Corin catchment, a headwater catchment in the south-east of Australia covered by native Eucalyptus species. Few studies have applied the SAS framework globally and in energy-intensive areas where catchment losses are heavily in favour of evapotranspiration relative to streamflow. A combination of observed and modelled values of oxygen-18 (δ¹⁸O ), the stable isotope in water, are used to constrain storage selection preferences of streamflow and evapotranspiration and the size of the catchment active storage. The highest performing parameter combinations that could reproduce δ¹⁸O in streamflow were dependent on a strong preference for young water in evapotranspiration, and a mixture of weak young and old water preference in streamflow. The mean travel time of streamflow over the study period 2007–2019, weighted by the flow rate, is limited to within a probable range of 2.81–9.77 years. The size of the active storage, a key parameter in the SAS framework, was poorly identified, and in combination with the isotopic inputs into the model, contributed to the uncertainty of the results. We discuss the implications of the results with respect to the study area, as well as within the context of SAS research globally and identify ways to improve the modelling process.     

极端降水条件下白洋淀主淀区水化学特征及水质变化

极端降水是影响水环境质量的重要气象因素之一,随着全球气候变暖,极端降水事件的频率和量级呈显著上升的趋势,对湖泊水化学和水环境产生了深刻的影响.白洋淀是华北地区重要的湖泊型湿地和生态功能区,为查明极端降水条件下白洋淀主淀区的水化学和水质特征,本研究利用Piper三线图、Gibbs图和多元统计方法阐明了白洋淀极端降雨后的水化学特征、氢氧稳定同位素特征和水质空间变化,揭示了极端降水条件对白洋淀主淀区水化学和水质的影响.结果表明：(1)在极端降水条件下,白洋淀主淀区湖水呈弱碱性,水化学类型主要为Ca-HCO₃·SO₄型,极端降水减弱了蒸发结晶作用和人类活动等因素对白洋淀主淀区湖水水化学组成的影响.极端降水是导致白洋淀主淀区pH、电导率和总溶解性固体发生大幅度变化的原因之一.(2)极端降水条件下白洋淀主淀区湖水的δ²H和δ¹⁸O值的范围分别为-60.86‰～-35.01‰和-8.84‰～-3.45‰,其值均与水深呈显著负相关.极端降水使得白洋淀主淀区湖水的氢、氧稳定同位素贫化,但对其空间分布的影响不大,湖水氢...     

Thermal effects of lateral supra‐permafrost water flow around a thermokarst lake on the Qinghai–Tibet Plateau

Both the inflow and outflow of supra‐permafrost water to lakes play important roles in the hydrologic process of thermokarst lakes. The accompanying thermal effects on the adjacent permafrost are required for assessing their influences on the development of thermokarst lakes. For these purposes, the lake water level, temperature dynamics, and supra‐permafrost water flow of a lake were monitored on the Qinghai‐Tibet Plateau. In addition, the spatial and temporal variation of the active layer thickness and permafrost distribution around the lake were investigated by combining ground penetrating radar, electrical resistivity tomography, and borehole temperature monitoring. The results revealed that the yearly unfrozen supra‐permafrost water flow around the lake lasted approximately 5 months. The temperature and water level measurements during this period indicate that the lake water was recharged by relatively colder supra‐permafrost water from the north‐western lakeshore and was discharged through the eastern lakeshore. This process, accompanied by heat exchange with the underlying permafrost, might cause a directional difference of the active layer thickness and permafrost characteristics around the lake. Specifically, the active layer thickness variation was minimal, and the ice‐rich permafrost was found adjacent to the lakeshore along the recharge groundwater pathways, whereas a deeper active layer and ice‐poor permafrost were observed close to the lakeshore from which the warm lake water was discharged. This study suggests that the lateral flow of warm lake water can be a major driver for the rapid expansion of thermokarst lakes and provides clues for evaluating the relationships between the thermokarst expansion process and climate warming.     

Dual effects of precipitation and evaporation on lake water stable isotope composition in the monsoon region

We present the results of a 3‐year monitoring programme of the stable isotope composition of lake water and precipitation at Taozi Lake, in the East Asian monsoon region of China. Our aims were to reveal the spatiotemporal pattern of variation of stable isotopes in a small closed‐basin lake and to quantitatively determine the impacts of precipitation and evaporation on the stable isotope composition of lake water under a humid monsoon climate. In the time domain, the stable oxygen isotopic ratio of the lake water (δ¹⁸O_L) exhibited substantial seasonal and interannual variations, but the isotope variations between different precipitation events substantially exceeded seasonal and interannual variations. Compared with the stable isotopes in precipitation, δ¹⁸O_L was substantially positive and d_L was negative. In the space domains, the lake water was homogeneously mixed. Indicated by statistic analyses, precipitation plays a dominant role in dynamic of the lake stable isotope during precipitation events of relatively large magnitude, whereas the effect of evaporation is dominant during smaller precipitation events. Results advance our understanding of the stable isotope change rule in the process of lake water evaporation, and it is helpful to identify the climatic significance recorded in stable isotopic compositions of lake bottom sediments.     

Seasonal variations of stable isotope in precipitation and moisture transport at Yushu,eastern Tibetan Plateau

Precipitation δ 18O at Yushu, eastern Tibetan Plateau, shows strong fluctuation and lack of clear seasonality. The seasonal pattern of precipitation stable isotope at Yushu is apparently different from either that of the southwest monsoon region to the south or that of the inland region to the north. This different seasonal pattern probably reflects the shift of different moisture sources. In this paper, we present the spatial comparison of the seasonal patterns of precipitation δ 18O, and calculate the moisture transport flux by using the NCAR/NCEP reanalysis data. This allows us to discuss the relation between moisture transport flux and precipitation δ 18O. This study shows that both the southwest monsoon from south and inland air mass transport from north affected the seasonal precipitation δ 18O at Yushu, eastern Tibetan Plateau. Southwest monsoon brings the main part of the moisture, but southwest transport flux is weaker than in the southern part of the Tibetan Plateau. However, contribution of the inland moisture from north or local evaporation moisture is enhanced. The combined effect is the strong fluctuation of summer precipitation δ 18O at Yushu and comparatively poor seasonality.     

Isotopic composition of precipitation in a topographically steep,seasonally snow‐dominated watershed and implications of variations from the global meteoric water line

The local meteoric water line (LMWL), the functional relationship between locally measured values of δ¹⁸O and δ²H in precipitation, represents the isotopic composition of water entering hydrologic systems. The degree to which the LMWL departs from the global meteoric water line (GMWL), moreover, can reveal important information about meteoric sources of water (e.g. oceanic or terrestrial) and atmospheric conditions during transport. Here we characterize the isotopic composition of precipitation within an experimental watershed in the Western US that is subject to large topographic and seasonal gradients in precipitation. Interpreting the hydrometeorologic and spatial controls on precipitation, we constructed a seasonally weighted LMWL for southwestern Idaho that is expressed by the equation δ²H = 7.40 × δ¹⁸O ? 2.17. A seasonally weighted LMWL that is based on weighting isotopic concentrations by climatic precipitation volumes is novel, and we argue better represents the significant seasonality of precipitation in the region. The developed LMWL is considerably influenced by the semiarid climate experienced in southwest Idaho, yielding a slope and y‐intercept lower than the GMWL (δ²H = 8 × δ¹⁸O + 10). Moderate to strong correlations exist between the isotopic composition of precipitation from individual events and surface meteorologic variables, specifically surface air temperature, relative humidity, and precipitation amount. A strong negative correlation exists between the annual average isotopic composition of precipitation and elevation at individual collection sites, with a lapse rate of ?0.22‰/100 m. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrologic and water isotope characterization of a regulated Canadian Shield river basin

Stable water isotope surveys have increasingly been integrated into river basins studies, but fewer have used them to evaluate impact of hydropower regulation. This study applies hydrologic and water isotope survey approaches to a Canadian Shield river basin with both regulated and natural flows. Historical streamflow records were used to evaluate the influence of three hydroelectric reservoirs and unregulated portions of the basin on downstream flows and changes in water level management implemented after an extreme flood year (1979). In 2013, water isotope surveys of surface and source waters (e.g., rainfall, groundwater, snowmelt) were conducted to examine spatial and temporal variation in contributions to river flow. Seasonal changes in relative groundwater contribution were assessed using a water‐isotope mass balance approach. Within the basin, two regulated reservoirs exhibited inverted hydrographs with augmented winter flows, whereas a third exhibited a hydrograph dominated by spring snowmelt. In 2013, spatial variation in rain‐on‐snow and air temperatures resulted in a critical lag in snowmelt initiation in the southern and northern portions of the basin resulting in a dispersed, double peak spring hydrograph, contrasting with 1979 when a combination of rain‐on‐snow and coincident snowmelt led to the highest flood on record. Although eastern basin reservoirs become seasonally enriched in δ¹⁸O and δ²H values, unregulated western basin flows remain less variable due to groundwater driven baseflow with increasing influence downstream. Combined analysis of historical streamflow (e.g., flood of 1979, drought of 2010) and the 2013 water isotope surveys illustrate extreme meteorological conditions that current management activities are unable to prevent. In this study, the influence of evaporative fractionation on large surface water reservoirs provides important evidence of streamflow partitioning, illustrating the value of stable water isotope tracers for study of larger catchments.