Architecture and mineral deposit settings of the Altaid orogenic collage: a revised model

The Altaids are an orogenic collage of Neoproterozoic–Paleozoic rocks located in the center of Eurasia. This collage consists of only three oroclinally bent Neoproterozoic–Early Paleozoic magmatic arcs (Kipchak, Tuva–Mongol, and Mugodzhar–Rudny Altai), separated by sutures of their former backarc basins, which were stitched by new generations of overlapping magmatic arcs. In addition, the Altaids host accreted fragments of the Neoproterozoic to Early Paleozoic oceanic island chains and Neoproterozoic to Cenozoic plume-related magmatic rocks superimposed on the accreted fragments. All these assemblages host important, many world-class, Late Proterozoic to Early Mesozoic gold, copper–molybdenum, lead–zinc, nickel and other deposits of various types.In the Late Proterozoic, during breakup of the supercontinent Rodinia, the Kipchak and Tuva–Mongol magmatic arcs were rifted off Eastern Europe–Siberia and Laurentia to produce oceanic backarc basins. In the Late Ordovician, the Siberian craton began its clockwise rotation with respect to Eastern Europe and this coincides with the beginning of formation of the Mugodzhar–Rudny Altai arc behind the Kipchak arc. These earlier arcs produced mostly Cu–Pb–Zn VMS deposits, although some important intrusion-related orogenic Au deposits formed during arc–arc collision events in the Middle Cambrian and Late Ordovician.The clockwise rotation of Siberia continued through the Paleozoic until the Early Permian producing several episodes of oroclinal bending, strike–slip duplication and reorganization of the magmatic arcs to produce the overlapping Kazakh–Mongol and Zharma-Saur–Valerianov–Beltau-Kurama arcs that welded the extinct Kipchak and Tuva–Mongol arcs. This resulted in amalgamation of the western portion of the Altaid orogenic collage in the Late Paleozoic. Its eastern portion amalgamated only in the early Mesozoic and was overlapped by the Transbaikal magmatic arc, which developed in response to subduction of the oceanic crust of the Paleo-Pacific Ocean. Several world-class Cu–(Mo)-porphyry, Cu–Pb–Zn VMS and intrusion-related Au mineral camps, which formed in the Altaids at this stage, coincided with the episodes of plate reorganization and oroclinal bending of magmatic arcs. Major Pb–Zn and Cu sedimentary rock-hosted deposits of Kazakhstan and Central Asia formed in backarc rifts, which developed on the earlier amalgamated fragments. Major orogenic gold deposits are intrusion-related deposits, often occurring within black shale-bearing sutured backarc basins with oceanic crust.After amalgamation of the western Altaids, this part of the collage and adjacent cratons were affected by the Siberian superplume, which ascended at the Permian–Triassic transition. This plume-related magmatism produced various deposits, such as famous Ni–Cu–PGE deposits of Norilsk in the northwest of the Siberian craton.In the early Mesozoic, the eastern Altaids were oroclinally bent together with the overlapping Transbaikal magmatic arc in response to the northward migration and anti-clockwise rotation of the North China craton. The following collision of the eastern portion of the Altaid collage with the Siberian craton formed the Mongol–Okhotsk suture zone, which still links the accretionary wedges of central Mongolia and Circum-Pacific belts. In the late Mesozoic, a system of continent-scale conjugate northwest-trending and northeast-trending strike–slip faults developed in response to the southward propagation of the Siberian craton with subsequent post-mineral offset of some metallogenic belts for as much as 70–400 km, possibly in response to spreading in the Canadian basin. India–Asia collision rejuvenated some of these faults and generated a system of impact rifts.     

Discovered and undiscovered gold endowment of Turkey: a quantitative mineral resource assessment using GIS and rank statistical analysis

An assessment of the discovered and undiscovered gold endowment of Turkey, a prolific sector in the Tethyan Metallogenic Belt, is developed from a comprehensive Geographic Information System database containing 402 gold deposits and prospects. The majority of the gold deposits and prospects are epithermal, porphyry, volcanic-associated massive sulfides, orogenic gold, and skarn systems. These five major deposit types form more than 90% of the known gold deposits and prospects. Just 87, corresponding to 21.6%, of the deposits and prospects in the data set have current calculated gold reserve and/or resources, containing a total of 54.885 Moz Au. Current gold reserves of the country are 21.447 Moz constituting 39.1% of the total gold resources, of which 17.1 Moz gold are contained in four deposits. Out of these 87 deposits and prospects, only 27 contain significant gold reserve and/or resources (defined as equal to or more than 0.32 Moz or 10 tons Au), and contain 91.8% of the total gold endowment of the country. The cumulative frequency distribution model of the gold endowment of Turkey abides by log-normal distribution. Observed and estimated 10th, 50th (median), and 90th percentiles of the data are 0.0046 Moz [0.0045 Moz estimated], 0.1030 Moz [0.0875 Moz], and 1.4969 Moz [1.6938 Moz], respectively. The 99th percentile of the data is 7.6444 Moz [18.9636 Moz]. The arithmetic mean of the known gold endowment is 0.657 Moz and the Swanson mean size is 0.492 Moz. The arithmetic mean of the 27 significant gold deposit or prospects is 1.94 Moz. Zipf’s law estimates of the undiscovered (residual) gold resources of Turkey are based on the current size of the largest, rank 1, gold deposit of Turkey, which is the Kisladag porphyry deposit that has 17.481 Moz gold endowment (including past production). Zipf’s law estimates a total of 88.261 Moz natural or total gold endowment, 57.133 Moz or 65% of which has already been found. This predicts at least 31.128 Moz residual or undiscovered gold resources to be found in Turkey, though the lack of full delineation of the rank 1 deposit, Kisladag, means that this figure is very conservative.     

Sources of Zircons from Cretaceous and Lower Paleogene Terrigenous Sequences of the Southern Koryak Upland and Western Kamchatka

The mineral composition of sandstones from Cretaceous–Lower Paleocene terrigenous sequences of the western Kamchatka–Ukelayat zone (southern Koryak Upland, western Kamchatka) suggests that the Okhotsk–Chukot volcanogenic belt and fragments of the Uda–Murgal island arc served as the most probable provenance. Fission-track dating of zircon showed that sandstones from this zone contain detrital zircon of several different-age populations. Fission tracks in zircon grains were nor subjected to secondary ignition. The age of young zircon population coincides with the biostratigraphic age of host sequences. Thus, results of dating of detrital zircon grains from sandstones, which did not experience heating above 215–240°C, indicate that this method is appropriate for dating fossil-free terrigenous sequences. The young zircon population in the sandstones is related to erosion of plagiogranite and diorite intrusions of the Uda–Murgal arc and outer zone of the Okhotsk–Chukot volcanic belt exposed at the day surface owing to differential vertical movements and rapid exhumation of blocks.     

Cretaceous Rocks of the Penzhina Bay: Mineralogy,Petrography, and Geodynamic Sedimentation Conditions

Cretaceous sedimentary and volcanosedimentary rocks from northwestern Kamchatka are considered. The stadial analysis has revealed variable impacts of three major provenances upon the Cretaceous Penzhina sedimentary basin. The provenances were composed of volcanic and volcanosedimentary rocks (Uda–Murgal island arc and Okhotsk–Chukotka volcanic belt) and granitic–metamorphic rocks (the mature Asian continental margin). Sediments were largely accumulated owing to the erosion of island-arc volcanics during reactivation of the Uda–Murgal island arc (Hauterivian–Barremian) or the Okhotsk–Chukotka volcanic belt (middle Albian–Cenomanian). Eroded granitic–metamorphic rocks of the mature Asian continental margin (Berriasian–Valanginian) or Asian metamorphic–volcanic rocks (Santonian–Campanian) were supplied to the basin during tectonically quiet periods (Berriasian–Valanginian and late Cenomanian–Campanian). Compositional changes in provenances were related to active tectonic processes at the continental margin, including evolution and closure of the Uda–Murgal island-arc system and origin of the Okhotsk–Chukotka volcanic belt. The postsedimentary modification of Cretaceous rocks deposited in forearc trough beyond the tectonically active accretionary prism is characterized by a low degree of clastic component alteration.     

Gold and silver metallogeny of the South China Fold Belt: a consequence of multiple mineralizing events?

The South China Fold Belt is part of the South China Block that is interpreted to be the result of multiple tectonic and magmatic events that formed a collage of accreted Proterozoic and Phanerozoic terranes. The Jurassic to early Cretaceous Yanshanian period (180–90 Ma), a time of major tectono-thermal events that affected much of eastern and southeastern China, is of great metallogenic importance in the fold belt. This period is linked to subduction of the Pacific plate beneath the Eurasian continent, and is manifested by voluminous volcano-plutonic activity of predominantly calc-alkaline affinity.The distribution of gold and silver deposits in the South China Fold Belt indicates the presence of two distinct metallogenic provinces. A region of basement uplifts, which are controlled by shear zones and form Neoproterozoic inliers of metamorphosed iron-rich rock types, defines the first province. In this province, orogenic lodes and volcanic-related epithermal deposits represent the more significant precious-metal mineralization. The second province is essentially confined to a belt of Yanshanian felsic–intermediate volcanic and subvolcanic rocks that extends along most of the southeastern China coast in an area known as the Coastal Volcanic Belt. Deposits in the Coastal Volcanic Belt are silver- and/or copper-rich, volcanic-hosted and epithermal in character.The precious-metal metallogeny of the South China Fold Belt is interpreted to have developed in at least three stages: one as a result of collision events, during the Caledonian Orogeny (ca. 400 Ma), the second during the Indosinian Orogeny (ca. 200 Ma) and the third during or soon after the formation of the Yanshanian magmatic belt (Yanshanian Orogeny; 180–90 Ma). The latter was responsible for a hydrothermal event that affected large sections of the belt and its Proterozoic substrate. This may have resulted in the redistribution and enrichment of precious metals from preexisting orogenic gold lodes in Neoproterozoic basement rocks, which are now exposed as windows in zones of tectonic uplift. The Yanshanian hydrothermal activity was particularly widespread in the Coastal Volcanic Belt and resulted in the formation of both low- and high-sulfidation epithermal gold and silver, and locally copper and other base-metal mineralization. It is suggested that the Coastal Volcanic Belt has greater potential for world-class epithermal and porphyry deposits than previously realised.     

Petrogenetic character and provenance of metabasalts in the aspiring and Torlesse Terranes, South Island, New Zealand: Implications for the gold endowment of the Otago Schist?

We report quantitative X-ray diffraction, whole-rock geochemical and Sm–Nd isotope data for metabasalts from the Aspiring and Torlesse Terranes in the South Island of New Zealand. These rocks underlie the Mesozoic metasedimentary Otago Schist which is anomalously enriched in gold and host to at least one world-class orogenic gold deposit at Macraes (> 125 t Au). Geochemical and Nd isotopic similarities between the samples point to a common history of the two terranes rather than the amalgamation of one or two allochthonous plate fragments. Furthermore, geochemical and Nd data suggest the metabasalts within both terranes formed in an oceanic but essentially non-subduction-related setting. The origin of the Aspiring and Torlesse basalts can be linked to the formation of an oceanic plateau that had resulted from a (?Permian) mantle plume initiation event proximal to a mid-oceanic rise or triple junction. Given the intrinsically gold-enriched nature of certain oceanic-character mafic rocks, the anomalous gold endowment of the Otago Schist may have been enhanced via the accretion and subduction of a gold-enriched oceanic plateau fragment. The metabasalts are generally enriched in gold (up to 13 ppb) compared to their enclosing metasedimentary rocks (typically ca. 1 ppb), with sulphide-rich metabasaltic rocks having up to 550 ppb Au. However, the relatively small volume of metabasalts in the Otago Schist precludes these rocks as the principal source for Otago Schist orogenic gold, with a primarily metasedimentary source of the gold potentially having a limiting effect on the overall endowment of the Otago Schist. This approach, that employs petrogenetic fingerprinting of potentially fertile source rocks for the assessment of gold endowment, might prove useful in the conceptual exploration targeting of relatively immature and poorly exposed terrains.     

Metallogeny of accretionary orogens — The connection between lithospheric processes and metal endowment

Accretionary orogens throughout space and time represent extremely fertile settings for the formation and preservation of a wide variety of mineral deposit types. These range from those within active magmatic arcs, either in continental margin or intra-oceanic settings, to those that develop in a variety of arc-flanking environments, such as fore-arcs and back-arcs during deformation and exhumation of the continental margin. Deposit types also include those that form in more distal, far back-arc and foreland basin settings. The metallogenic signature and endowment of individual accretionary orogens are, at a fundamental level, controlled by the nature, composition and age of the sub-continental lithosphere, and a complex interplay between formational processes and preservational forces in an evolving Earth. Some deposit types, such as orogenic gold and volcanic massive sulfide (VMS) deposits, have temporal patterns that mimic the major accretionary and crustal growth events in Earth history, whereas others, such as porphyry Cu–Au–Mo and epithermal Au–Ag deposits, have largely preservational patterns. The presence at c. 3.4 Ga of (rare) orogenic gold deposits, whose formation necessitates some form of subduction–accretion, provides strong evidence that accretionary processes operated then at the margins of continental nuclei, while the widespread distribution of orogenic gold and VMS deposits at c. 2.7–2.6 Ga reflects the global distribution of accretionary orogens by this time.     

A Kaapvaal craton debate: Nucleus of an early small supercontinent or affected by an enhanced accretion event?

Incorporation of the Kaapvaal craton within a speculative Neoarchaean–Palaeoproterozoic supercontinent has long been debated, and this idea provides a potential solution to solving the apparently enigmatic provenance of the huge quantities of gold within the famous Witwatersrand auriferous deposits of Kaapvaal. Within a framework of a postulated Neoarchaean “Kenorland” (“northern”; present-day reference) supercontinent, we examine possible “southern” cratons that may have been contiguous with Kaapvaal: Pilbara, Zimbabwe, Dharwar, São Francisco, Amazon, Congo. Brief reviews of their basic geology and inferred evolution in syn-Witwatersrand basin times (c. 3.1–2.8 Ga) show no obvious support for any such supercontinental amalgamations. An alternative idea to explain a measure of gross similarity amongst several Neoarchaean cratons is through global events, such as a c. 3125–3000 Ma cratonic-scale erosive event interpreted for both Pilbara and Kaapvaal, and a much more widespread magmatic event at c. 2760–2680 Ma. We postulate that a global superplume event at c. 3.0 Ga included a plume beneath the Kaapvaal cratonic nucleus, thus halting any subduction around that terrane due to the thermal anomaly. Such a speculative global magmatic event is assumed to have enhanced production of juvenile oceanic crust at mid-ocean ridges, including those “offshore” of the thermally elevated Kaapvaal nucleus. Intra-oceanic obduction complexes may have built up fairly rapidly under such conditions, globally, and once the plume event had abated, “normal” plate tectonics would have resulted in composite (greenstone-tonalite, possibly also including granite) terranes accreting with nuclei such as Kaapvaal. This enhanced plume-related cratonic growth can be seen as a rapid accretion event. Formation of the envisaged ophiolite complexes possibly encompassed deformation-related first-order concentration of gold, and once accretion occurred around Kaapvaal's nucleus, from north and west (present-day frame of reference), a second-order (deformation-related) gold concentration may have resulted. The third order of gold concentration would logically have occurred once placer systems reworked detritus derived from the orogens along the N and W margins of Kaapvaal. Such conditions and placer gold deposits are known from many Neoarchaean cratons. The initial source of gold was presumably from the much hotter Mesoarchaean mantle and may have been related to major changes in Earth's tectonic regime at c. 3.0 Ga. The unique nature of Kaapvaal is probably its early stabilization, enabling formation of a complex flexural foreland basin system, in which vast quantities of placer sediments and heavy minerals could be deposited, and preserved from younger denudation through a unique post-Witwatersrand history.     

Geochemistry and geochronology of the Neoproterozoic Pan-African Transcaucasian Massif (Republic of Georgia) and implications for island arc evolution of the late Precambrian Arabian–Nubian Shield

The Transcaucasian Massif (TCM) in the Republic of Georgia includes Neoproterozoic–Early Cambrian ophiolites and magmatic arc assemblages that are reminiscent of the coeval island arc terranes in the Arabian–Nubian Shield (ANS) and provides essential evidence for Pan-African crustal evolution in Western Gondwana. The metabasite–plagiogneiss–migmatite association in the Oldest Basement Unit (OBU) of TCM represents a Neoproterozoic oceanic lithosphere intruded by gabbro–diorite–quartz diorite plutons of the Gray Granite Basement Complex (GGBC) that constitute the plutonic foundation of an island arc terrane. The Tectonic Mélange Zone (TMZ) within the Middle-Late Carboniferous Microcline Granite Basement Complex includes thrust sheets composed of various lithologies derived from this arc-ophiolite assemblage. The serpentinized peridotites in the OBU and the TMZ have geochemical features and primary spinel composition (0.35) typical of mid-ocean ridge (MOR)-type, cpx-bearing spinel harzburgites. The metabasic rocks from these two tectonic units are characterized by low-K, moderate-to high-Ti, olivine-hypersthene-normative, tholeiitic basalts representing N-MORB to transitional to E-MORB series. The analyzed peridotites and volcanic rocks display a typical melt-residua genetic relationship of MOR-type oceanic lithosphere. The whole-rock Sm–Nd isotopic data from these metabasic rocks define a regression line corresponding to a maximum age limit of 804 ± 100 Ma and εNd_int = 7.37 ± 0.55. Mafic to intermediate plutonic rocks of GGBC show tholeiitic to calc-alkaline evolutionary trends with LILE and LREE enrichment patterns, Y and HREE depletion, and moderately negative anomalies of Ta, Nb, and Ti, characteristic of suprasubduction zone originated magmas. U–Pb zircon dates, Rb–Sr whole-rock isochron, and Sm–Nd mineral isochron ages of these plutonic rocks range between  750 Ma and 540 Ma, constraining the timing of island arc construction as the Neoproterozoic–Early Cambrian. The Nd and Sr isotopic ratios and the model and emplacement ages of massive quartz diorites in GGBC suggest that pre-Pan African continental crust was involved in the evolution of the island arc terrane. This in turn indicates that the ANS may not be made entirely of juvenile continental crust of Neoproterozoic age. Following its separation from ANS in the Early Paleozoic, TCM underwent a period of extensive crustal growth during 330–280 Ma through the emplacement of microcline granite plutons as part of a magmatic arc system above a Paleo-Tethyan subduction zone dipping beneath the southern margin of Eurasia. TCM and other peri-Gondwanan terranes exposed in a series of basement culminations within the Alpine orogenic belt provide essential information on the Pan-African history of Gondwana and the rift-drift stages of the tectonic evolution of Paleo-Tethys as a back-arc basin between Gondwana and Eurasia.     

Geodynamic settings and tectonic model of skarn gold deposits in China: An overview

Seventy skarn-type gold deposits, including 1 super-large, 19 large and 24 medium-sized, are known from different geotectonic units of China. They contain a total resource of approximately 1000 t of gold (625 t in South China), and account for 20% of China's gold reserves. These skarn deposits are sited in collisional orogenic belts, fault-controlled magmatic belts and reactivated cratonic margins. All of the Chinese skarn gold provinces were affected by Phanerozoic collisional orogenesis. The timing of the metallogenic events and the spatial–temporal distribution of the Chinese skarn gold deposits indicates that they were formed during ore-forming processes linked to the transition from shortening to extension in the geodynamic evolution of a collision orogen, and not to subduction systems as is commonly advocated for porphyry copper systems around the Pacific Rim.     

U–Pb SHRIMP monazite ages of the giant Morro Velho and Cuiabá gold deposits, Rio das Velhas greenstone belt, Quadrilátero Ferrífero, Minas Gerais, Brazil

U–Pb SHRIMP results of 2672 ± 14 Ma obtained on hydrothermal monazite crystals, from ore samples of the giant Morro Velho and Cuiabá Archean orogenic deposits, represent the first reliable and precise age of gold mineralization associated with the Rio das Velhas greenstone belt evolution, in the Quadrilátero Ferrífero, Brazil. In the basal Nova Lima Group, of the Rio das Velhas greenstone belt, felsic volcanic and volcaniclastic rocks have been dated between 2792 ± 11 and 2751 ± 9 Ma, coeval with the intrusion of syn-tectonic tonalite and granodiorite plutons, and also with the metamorphic overprint of older tonalite–trondhjemite–granodiorite crust. Since cratonization and stable-shelf sedimentation followed intrusion of Neoarchean granites at 2612 + 3/− 2 Ma, it is clear that like other granite–greenstone terranes in the world, gold mineralization is constrained to the latest stages of greenstone evolution.     

Geochronological framework of the Quadrilátero Ferrífero, with emphasis on the age of gold mineralization hosted in Archean greenstone belts

Archean terrains of the Quadrilátero Ferrífero comprise a greenstone belt association surrounded by granitoid–gneiss complexes, mainly composed of banded TTG gneisses whose igneous protoliths are older than 2900 Ma. This early continental crust was affected by three granitic magmatic episodes during the Neoarchean: ca. 2780 to 2760 Ma; 2720 to 2700 Ma; and 2600 Ma. Dating of felsic volcanic and volcaniclastic rocks defines a felsic magmatic event within the greenstone belt association around 2772 Ma, contemporaneous with emplacement of several of the granitic plutons and constrains a major magmatic and tectonic event in the Quadrilátero Ferrífero. Lead isotopic studies of lode–gold deposits indicate that the main mineralization episode occurred at about 2800 to 2700 Ma.Proterozoic evolution of the Quadrilátero Ferrífero comprises deposition of a continental-margin succession hosting thick, Lake Superior-type banded iron formations, at ca. 2500 to 2400 Ma, followed by deposition of syn-orogenic successions after 2120 Ma. The latter is related to the Transamazonian Orogeny. The western part of the Quadrilátero Ferrífero was also affected by the Brasiliano Orogeny (600 to 560 Ma).     

Anatomy of a Cambrian suture in Gondwana: Pacific-type orogeny in southern India?

Southern India occupies a central position in the Late Neoproterozoic–Cambrian Gondwana supercontinent assembly. The Proterozoic mosaic of southern India comprises a collage of crustal blocks dissected by Late Neoproterozoic–Cambrian crust-scale shear/suture zones. Among these, the Palghat–Cauvery Suture Zone (PCSZ) has been identified as the trace of the Cambrian suture representing Mozambique Ocean closure during the final phase of amalgamation of the Gondwana supercontinent. Here we propose a model involving Pacific-type orogeny to explain the Neoproterozoic evolution of southern India and its final amalgamation within the Gondwana assembly. Our model envisages an early rifting stage which gave birth to the Mozambique Ocean, followed by the initiation of southward subduction of the oceanic plate beneath a thick tectosphere-bearing Archean Dharwar Craton. Slices of the ocean floor carrying dunite–pyroxenite–gabbro sequence intruded by mafic dykes representing a probable ophiolite suite and invaded by plagiogranite are exposed at Manamedu along the southern part the PCSZ. Evidence for the southward subduction and subsequent northward extrusion are preserved in the PCSZ where the orogenic core carries high-pressure and ultrahigh-temperature metamorphic assemblages with ages corresponding to the Cambrian collisional orogeny. Typical eclogites facies rocks with garnet + omphacite + quartz and diagnostic ultrahigh-temperature assemblages with sapphirine + quartz, spinel + quartz and high alumina orthopyroxene + sillimanite + quartz indicate extreme metamorphism during the subduction–collision process. Eclogites and UHT granulites in the orogenic core define P–T maxima of 1000 °C and up to 20 kbar. The close association of eclogites with ultramafic rocks having abyssal signatures together with linear belts of iron formation and metachert in several localities within the PCSZ probably represents subduction–accretion setting. Fragments of the mantle wedge were brought up through extrusion tectonics within the orogenic core, which now occur as suprasubduction zone/arc assemblages including chromitites, highly depleted dunites, and pyroxene bearing ultramafic assemblages around Salem. Extensive CO₂ metasomatism of the ultramafic units generated magnesite deposits such as those around Salem. High temperature ocean floor hydrothermal alteration is also indicated by the occurrence of diopsidite dykes with calcite veining. Thermal metamorphism from the top resulted in the dehydration of the passive margin sediments trapped beneath the orogenic core, releasing copious hydrous fluids which moved upward and caused widespread hydration, as commonly preserved in the Barrovian amphibolite facies units in the PCSZ. The crustal flower structure mapped from PCSZ supports the extrusion model, and the large scale north verging thrusts towards the north of the orogenic core may represent a fold-thrust belt. Towards the south of the PCSZ is the Madurai Block where evidence for extensive magmatism occurs, represented by a number of granitic plutons and igneous charnockite massifs of possible tonalite–trondhjemite–granodiorite (TTG) setting, with ages ranging from ca. 750–560 Ma suggesting a long-lived Neoproterozoic magmatic arc within a > 200 km wide belt. All these magmatic units were subsequently metamorphosed, when the Pacific-type orogeny switched over to collision-type in the Cambrian during the final phase of assembly of the Gondwana supercontinent. One of the most notable aspects is the occurrence of arc magmatic rocks together with high P/T rocks, representing the deeply eroded zone of subduction. The juxtaposition of these contrasting rock units may suggest the root of an evolved Andean-type margin, as in many arc environments the roots of the arc comprise ultramafic/mafic cumulates and the felsic rocks represent the core of the arc. The final phase of the orogeny witnessed the closure of an extensive ocean — the Mozambique Ocean — and the collisional assembly of continental fragments within the Gondwana supercontinent amalgam. The tectonic history of southern India represents a progressive sequence from Pacific-type to collision-type orogeny which finally gave rise to a Himalayan-type Cambrian orogen with characteristic magmatic, metasomatic and metamorphic factories operating in subduction–collision setting.     

Metallogenesis of the Carajás Mineral Province, Southern Amazon Craton, Brazil: Varying styles of Archean through Paleoproterozoic to Neoproterozoic base- and precious-metal mineralisation

The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO₂ and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.     

Neoarchaean high-grade metamorphism in the Central Zone of the Limpopo Belt (South Africa): Combined petrological and geochronological evidence from the Bulai pluton

The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

The world-class Wallaby gold deposit,Laverton, Western Australia: An orogenic-style overprint on a magmatic-hydrothermal magnetite-calcite alteration pipe?

Gold mineralisation at the Wallaby gold deposit is hosted by a 1,200 m thick mafic conglomerate. The conglomerate is intruded by an apparently comagmatic alkaline dyke suite displaying increasing fractionation through mafic-monzonite, monzonite, syenite, syenite porphyry to late-stage carbonatite. In the mine area, a pipe-shaped zone of actinolite-magnetite-epidote-calcite (AMEC) alteration overprints the conglomerate. Gold mineralisation, associated with dolomite-albite-quartz-pyrite alteration, is hosted in a series of sub-horizontal, structurally controlled zones that are largely confined within the magnetite-rich pipe. The deposit has a current ore reserve of 2.0 Moz Au, and a total resource of 7.1 Moz Au.TIMS U–Pb analysis of magmatic titanite and SHRIMP U–Pb analysis of gold-related phosphate minerals are used to constrain the timing of magmatism and gold mineralisation at Wallaby. Monzogranite and carbonatite dykes of the Wallaby syenite intruded at 2,664±3 Ma, at least 5 m.y. and probably 14 m.y. before gold mineralisation at 2,650±6 Ma. The significant hiatus between proximal magmatism and gold mineralisation suggests that gold-bearing fluids were not derived from magmas associated with the Wallaby syenite, particularly since intrusive events are unlikely to drive hydrothermal systems for more than 1 m.y.Analysis of the C and O isotopic compositions of carbonates from regional pre-syenite alteration and AMEC alteration at the Wallaby gold deposit suggests that AMEC alteration formed via interaction between magmatic fluids and the pre-syenite wallrock carbonate. The C and O isotopic composition of gold-bearing fluids, as inferred from ore-carbonate, are isotopically distinct from proximal magmatic fluids, as inferred from magmatic carbonate in carbonatite dykes.Thus, detailed isotopic and geochronological studies negate any direct genetic link between proximal magmatic activity related to the Wallaby syenite and gold mineralisation at Wallaby. The gold endowment of the Wallaby gold deposit, combined with the relatively low solubility of gold as thiosulfide complexes in low-salinity ore fluids at temperatures of about 300°C, implicates the influx of very large volumes of auriferous hydrothermal fluids. No large-scale shear-zones nor faults through which such large fluid-volumes could pass have been identified within the immediate ore environment, so fluid influx most probably occurred largely in a unit-confined, brittle-ductile fracture system. This was the ~500-m diameter AMEC alteration pipe, which was a brittle, iron-enriched zone in an otherwise massive conglomerate. During compressional deformation, the competency contrast between unaltered and AMEC-altered conglomerate created a zone of increased fracture permeability, and geochemically favourable conditions (high Fe/Fe+Mg ratio), for gold mineralisation from a distal source.Editorial Handling: C. Brauhart     

Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).     

Geodynamic setting of gold deposits in Eastern and Central Trans-Baikal (Chita Region, Russia)

It is proposed that there are three types of gold deposits in Eastern and Central Transbaikalia (Trans-Baikal province), namely: (i) high-sulphide intrusion-related deposits with some signs of porphyry deposits, (ii) low-sulphide intrusion-related deposits, and (iii) low-sulphide epithermal Au–Ag deposits. Most of the gold deposits belong to the first two types, and their ages are Middle–Late Jurassic. Deposits of the third type are not numerous, and their age is Early Cretaceous.The majority of the gold mineralization is spatially related to the two branches of the Mongolia–Okhotsk suture, along which Siberia collided, at the Early/Middle Jurassic boundary, with the Mongolia–North China continent and the Onon island-arc terrane located between the two continents. Collision-related thrusting, folding and magmatism lasted until the latest Jurassic, when they gave way to post-collisional rifting that continued until the end of Early Cretaceous.According to their age, relation to magmatism and tectonic framework, the intrusion-related deposits (high- and low-sulphide) were formed in a regional collisional setting. Extensional environments at that time existed only in local areas in the roofs of great magmatic chambers. Low-sulphide epithermal deposits were formed during Early Cretaceous post-collisional rifting.