Along‐track compositional and textural variation in extensively melted grains returned from comet 81P/Wild 2 by the Stardust mission: Implications for capture‐melting process

Abstract— Five amorphous (extensively melted) grains from Stardust aerogel capture Track 35 were examined by transmission electron microscopy (TEM); two from the bulb, two from near the bulb‐stylus transition, and one from near the terminal particle. Melted grains consist largely of a texturally and compositionally heterogeneous emulsion of immiscible metal/sulfide beads nanometers to tens of nanometers in diameter in a silica‐rich vesicular glass. Most metal/sulfide beads are spherical, but textures of non‐spherical beads indicate that some solidified as large drops during stretching and breaking while in translational and rotational motion, and others solidified from lenses of immiscible liquid at the silicate‐melt/vesicle (vapor) interface. Melted grains appear to become richer in Fe relative to Mg, and depleted in S relative to Fe and Ni with increasing penetration distance along the aerogel capture track. Fe/S ratios are near unity in grains from the bulb of Track 35, consistent with the dominance of Fe‐monosulfide minerals inferred by previous research on Stardust materials. Near‐stoichiometric Fe/S in melted grains from the bulb suggests that Fe‐sulfides in the bulb were dispersed and melted during formation of the bulb but did not lose S. Along‐track increases in Fe/S in melted grains from the bulb through the bulb‐stylus transition and continuing into the stylus indicate that S initially present as iron monosulfide may have been progressively partially volatilized and lost from the melted grains with greater penetration of the grains deeper into the aerogel during capture‐melting of comet dust. Extensively melted grains from the bulbs of aerogel capture tracks may preserve better primary compositional information with less capture‐related modification than grains from farther along the same capture tracks.     

Isotopes of samarium in the sun

Terrestrial samarium consists of seven isotopes. Some spectral lines from Sm have isotope shifts and hyperfine structures that will modify the profile of the absorption lines in the Fraunhofer spectrum. The photospheric spectrum around the Sm ii lines at 4467 and 4519 Å has been studied. Although it is impossible to derive the solar abundance of each individual isotope, it is shown that a terrestrial isotopic composition can account for the anomal line width and asymmetry of the observed solar lines. The solar abundance found from the two lines is A(Sm) = 1.54 in the logarithmic A(H) = 12.00 scale.     

Shock and thermal history of Northwest Africa 4859, an annealed impact‐melt breccia of LL chondrite parentage containing unusual igneous features and pentlandite

Abstract– Northwest Africa 4859 (NWA 4859) is a meteorite of LL chondrite parentage that shows unusual igneous features and contains widely distributed pentlandite. The most obvious unusual feature is a high proportion of large (≤3 cm diameter) igneous‐textured enclaves (LITEs), interpreted as shock melts that were intruded into an LL chondrite host. One such LITE appears to have been produced by whole rock melting of LL chondrite, initial rapid partial crystallization, and subsequent slow cooling of the residual melt in the host to produce a differentiated object. Other unusual features include mm‐sized “overgrowth objects,” fine‐grained plagioclase‐rich bands, and coarse troilite (≤7 mm across) grains. All these features are interpreted as having crystallized from melts produced by a single transient shock event, followed by slow cooling. A subsequent shock event of moderate (S3) intensity produced veining and transformed some of the pyroxene into the clinoenstatite polytype. Pentlandite (together with associated troilite) in NWA 4859 probably formed by the breakdown of a monosulfide precursor phase at low temperature (≤230 °C) following the second shock event. NWA 4859 is interpreted to be an unusual impact‐melt breccia that contains shock melt which crystallized in different forms at depth within the parent body.     

Primary iron sulfides in CM and CR carbonaceous chondrites: Insights into nebular processes

We have carried out a systematic study involving SEM, EPMA, and TEM analyses to determine the textures and compositions of sulfides and sulfide–metal assemblages in a suite of minimally to weakly altered CM and CR carbonaceous chondrites. We have attempted to constrain the distribution and origin of primary sulfides that formed in the solar nebula, rather than by secondary asteroidal alteration processes. Our study focused primarily on sulfide assemblages associated with chondrules, but also examined some occurrences of sulfides within the matrices of these meteorites. Although sulfides are a minor phase in carbonaceous chondrites, we have determined that primary sulfide grains are actually a major proportion of the sulfide grains in weakly altered CM chondrites and have survived aqueous alteration relatively unscathed. In minimally altered CR chondrites, we have determined that essentially all of the sulfides are of primary origin, confirming the observations of Schrader et al. ( 2015 ). The pyrrhotite–pentlandite intergrowth (PPI) grains formed from crystallization of monosulfide solid solution (mss) melts, while sulfide-rimmed metal (SRM) grains formed from sulfidization of Fe,Ni metal. Micron-sized metal inclusions in some PPI grains may have formed by co-crystallization of metal and sulfide from a sulfide melt that experienced S volatilization during the chondrule formation event, or alternatively, may be a remnant of sulfidization of Fe,Ni metal that also occurred during chondrule formation. Sulfur fugacity for SRM grains ranged from −18 to −10 (log units) largely in agreement with predicted solar nebular values. Our observations show that understanding the formation mechanisms of primary sulfide grains provides clues to solar nebular conditions, such as the sulfur fugacity during chondrule formation.     

Mineralogy of iron sulfides in CM1 and CI1 lithologies of the Kaidun breccia: Records of extreme to intense hydrothermal alteration

The polymict Kaidun microbreccia contains lithologies of C‐type chondrites with euhedral iron sulfide crystals of hydrothermal origin. Our FIB‐TEM study reveals that acicular sulfides in a CM1 lithology are composed of Fe‐rich pyrrhotite with nonintegral vacancy superstructures (NC‐pyrrhotite), troilite, and pentlandite, all showing distinct exsolution textures. Based on phase relations in the Fe‐Ni‐S system, we constrain the temperature of formation of the originally homogeneous monosulfide solid solution to the range of 100–300 °C. In some crystals the exsolution of pentlandite and the microtextural equilibration was incomplete, probably due to rapid cooling. We use thermodynamic modeling to constrain the physicochemical conditions of the extreme hydrothermal alteration in this lithology. Unless the CM1 lithology was sourced from a large depth in the parent body (internal pressure >85 bar) or the temperatures were in the lower range of the interval determined, the water was likely present as vapor. Previously described light δ³⁴S compositions of sulfides in Kaidun's CM1 lithology are likely due to the loss of ³⁴S‐enriched H₂S during boiling. Platy sulfide crystals in an adjacent, intensely altered CI1 lithology are composed of Fe‐poor, monoclinic 4C‐pyrrhotite and NC‐pyrrhotite and probably formed at lower temperatures and higher fS₂ relative to the CM1 lithology. However, a better understanding of the stability of Fe‐poor pyrrhotites at temperatures below 300 °C is required to better constrain these conditions.     

Kamacite sulfurization in the solar nebula

Abstract— The kinetics and mechanisms of kamacite sulfurization were studied experimentally at temperatures and H₂S/H₂ ratios relevant to the solar nebula. Pieces of the Canyon Diablo meteorite were heated at 558 K, 613 K, and 643 K in 50 parts per million by volume (ppmv) H₂S-H₂ gas mixtures for up to one month. Optical microscopy and x-ray diffraction analyses show that the morphology and crystal orientation of the resulting sulfide layers vary with both time and temperature. Electron microprobe analyses reveal three distinct phases in the reaction products: monosulfide solid solution (mss), (Fe, Ni, Co)_1-xS, pentlandite (Fe, Ni, Co)_9-xS₈, and a P-rich phase. The bulk composition of the remnant metal was not significantly changed by sulfurization. Kamacite sulfurization at 558 K followed parabolic kinetics for the entire duration of the experiments. Sulfide layers that formed at 613 K grew linearly with time, while those that formed at 643 K initially grew linearly with time then switched to parabolic kinetics upon reaching a critical thickness. The experimental results suggest that a variety of thermodynamic, kinetic, and physical processes control the final composition and morphology of the sulfide layers. We combine morphological, x-ray diffraction, electron microprobe, and kinetic data to produce a comprehensive model of sulfide formation in the solar nebula. Then, we present a set of criteria to assist in the identification of solar nebula condensate sulfides in primitive meteorites.     

MINERALOGY AND PETROLOGY OF THE YILMIA ENSTATITE CHONDRITE

Yilmia, a new enstatite chondrite contains moderately well defined radiating and granular chondrules. The plagioclase to enstatite ratio is appreciably higher within than outside of the two granular chondrules in our microprobe sections. Osbornite was observed within the granular chondrules, but not in the rayed chondrules or surrounding matrix Major phases include enstatite, plagioclase (Ab₈₀ An₁₆ Or₄), silica, silicon-rich kamacite and titanian troilite. Minor phases are many and varied: sinoite, silicon-rich taenite, schreibersite, graphite, osbornite, oldhamite, “normal” and zincian daubreelite, ferroan alabandite and a new FeZnMn monosulfide The new mineral (Fe_.538 Zn_.246 Mn_.159 Mg_.004 S) closely resembles albandite and could easily have been overlooked in other meteorites unless a microprobe was used. A new form of oldhamite was also found. Indarch oldhamite, analyzed for comparative purposes, consists of two similar but distinct species: Ca_.96 Mn_.005 Mg_.04 Fe_.01 S and Ca_1.000 Mn_.004 Mg_.02 Fe_.005 S. These have not been reported from other meteorites Based on its mineralogy and texture this is a type II (E6) enstatite chondrite that is transitional toward the intermediate type (E5). It is unique in its mineralogical complexity, abundance of taenite, diversity of zincian minerals and monosulfides, and restriction of osbornite to certain chondrules     

The formation and alteration of the Renazzo‐like carbonaceous chondrites III: Toward understanding the genesis of ferromagnesian chondrules

To better understand the formation conditions of ferromagnesian chondrules from the Renazzo‐like carbonaceous (CR) chondrites, a systematic study of 210 chondrules from 15 CR chondrites was conducted. The texture and composition of silicate and opaque minerals from each observed FeO‐rich (type II) chondrule, and a representative number of FeO‐poor (type I) chondrules, were studied to build a substantial and self‐consistent data set. The average abundances and standard deviations of Cr₂O₃ in FeO‐rich olivine phenocrysts are consistent with previous work that the CR chondrites are among the least thermally altered samples from the early solar system. Type II chondrules from the CR chondrites formed under highly variable conditions (e.g., precursor composition, redox conditions, cooling rate), with each chondrule recording a distinct igneous history. The opaque minerals within type II chondrules are consistent with formation during chondrule melting and cooling, starting as S‐ and Ni‐rich liquids at 988–1350 °C, then cooling to form monosulfide solid solution (mss) that crystallized around olivine/pyroxene phenocrysts. During cooling, Fe,Ni‐metal crystallized from the S‐ and Ni‐rich liquid, and upon further cooling mss decomposed into pentlandite and pyrrhotite, with pentlandite exsolving from mss at 400–600 °C. The composition, texture, and inferred formation temperature of pentlandite within chondrules studied here is inconsistent with formation via aqueous alteration. However, some opaque minerals (Fe,Ni‐metal versus magnetite and panethite) present in type II chondrules are a proxy for the degree of whole‐rock aqueous alteration. The texture and composition of sulfide‐bearing opaque minerals in Graves Nunataks 06100 and Grosvenor Mountains 03116 suggest that they are the most thermally altered CR chondrites.     

The effects of strain localization on the formation of Ganymede’s grooved terrain

We investigate the effects of strain localization on the formation of Ganymede’s grooved terrain by numerically modeling the extension of an ice lithosphere in which the yield strength of the ice decreases as the magnitude of the plastic strain increases. We do this to more realistically model fault strength, which is expected to vary with slip during initial fault development. We find that the inclusion of strain weakening leads to the formation of periodic structures with amplitudes of 200-500 m, consistent with the observed amplitudes of Ganymede’s large-scale grooves. The morphology of the deformation that results from extension depends both on the thermal gradient, which sets the lithospheric thickness, and on the rate at which the yield strength of the ice decreases with increasing plastic strain. Slow weakening with strain leads to low-amplitude, periodic structures, whereas moderate to rapid weakening with strain leads to large-amplitude, non-periodic structures. The combined influence of the thermal gradient and the weakening rate leads to the formation of complex surface deformation and may help explain the variety of surface morphologies observed within the grooved terrain.     

Modeling damage and deformation in impact simulations

Abstract— Numerical modeling is a powerful tool for investigating the formation of large impact craters but is one that must be validated with observational evidence. Quantitative analysis of damage and deformation in the target surrounding an impact event provides a promising means of validation for numerical models of terrestrial impact craters, particularly in cases where the final pristine crater morphology is ambiguous or unknown. In this paper, we discuss the aspects of the behavior of brittle materials important for the accurate simulation of damage and deformation surrounding an impact event and the care required to interpret the results. We demonstrate this with an example simulation of an impact into a terrestrial, granite target that produces a 10 km‐diameter transient crater. The results of the simulation are shown in terms of damage (a scalar quantity that reflects the totality of fragmentation) and plastic strain, both total plastic strain (the accumulated amount of permanent shear deformation, regardless of the sense of shear) and net plastic strain (the amount of permanent shear deformation where the sense of shear is accounted for). Damage and plastic strain are both greatest close to the impact site and decline with radial distance. However, the reversal in flow patterns from the downward and outward excavation flow to the inward and upward collapse flow implies that net plastic strains may be significantly lower than total plastic strains. Plastic strain in brittle rocks is very heterogeneous; however, continuum modeling requires that the deformation of the target during an impact event be described in terms of an average strain that applies over a large volume of rock (large compared to the spacing between individual zones of sliding). This paper demonstrates that model predictions of smooth average strain are entirely consistent with an actual strain concentrated along very narrow zones. Furthermore, we suggest that model predictions of total accumulated strain should correlate with observable variations in bulk density and seismic velocity.     

The evolution of tectonic features on Ganymede

The bands of bright resurfaced terrain on Ganymede are probably broad grabens formed by global expansion and filled with deposits of ice. Grooves within the bands are thought to be extensional features formed during the same episode of expansion. The crust of Ganymede is modeled as a viscoelastic material subjected to extensional strain. With sufficiently high strain rates and stresses, deep normal faulting will occur, creating broad grabens that may then be filled. Continuing deformation at high strain rates and stresses will cause propagation of deep faults up into the flood deposits and normal faulting at the surface, while lower strain rates and stresses will cause formation of open extension fractures or, if the crustal strength is very low, grabens at the surface. The spacing between adjacent fractures may reflect the geothermal gradient at the time of deformation. Surface topography resulting from fracturing and normal faulting will decay with time as a result of viscous relaxation and mass-wasting.     

Determination of crustal strain in the northern region of Ukraine based on the analysis of GNSS observations

Crustal strain for the northern region of Ukraine is determined at the GNSS Data Analysis Center of the Main Astronomical Observatory of the National Academy of Sciences of Ukraine based on the triangular method with GNSS stations as vertices. Crustal strain was calculated using the GPS Triangle Strain Calculator software developed by UNAVCO.     

Use of cyanobacteria for in-situ resource use in space applications

The regolith of other planetary bodies, such as the Moon and Mars, is rich in inorganic elements that could potentially be exploited for space applications. Lithotrophic microorganisms that are capable of utilising rocks as a growth substrate, and facilitate the extraction of elements, are ideal candidates for in-situ resource use. Of particular interest are the cyanobacteria, which have been suggested for applications, such as oxygen, fuel and biomass production, nutrient acquisition, and feedstock provisions. In this study, Gloeocapsa strain OU_20, isolated from a rock-dwelling community exposed to low Earth orbit; Leptolyngbya strain OU_13 and Phormidium strain OU_10, both isolated from a rock-dwelling community exposed to Mars simulated conditions; Chroococcidiopsis 029; Arthrospira platensis; Synechococcus elongatus; and Anabaena cylindrica, were examined as potential organisms for space in-situ resource use. Volcanic rocks, including basalt (low in SiO₂) analogous to martian and lunar basalt, rhyolite (high in SiO₂), and anorthosite analogous to lunar regolith were used as growth substrates. The growth rate and rock dissolution were significantly lower with rhyolite demonstrating the importance of silica content in defining the potential for in-situ resource use. Biological weathering resulted in the release of bio-essential elements from the rock matrix, highlighting the potential of cyanobacteria for applications such as bio-mining and nutrient acquisition, on other planets. A. cylindrica produced the maximum biomass with the three rock-types and the optimal value was obtained with the basalt. Exposure experiments demonstrated that A. cylindrica, Chroococcidiopsis 029, Gloeocapsa strain OU_20, Phormidium strain OU_10, and Leptolyngbya strain OU_13 were able to survive 28 days of exposure to desiccation and Mars simulated conditions, which is beneficial in case of system malfunction and for storage. The results from this study indicate that cyanobacteria can potentially be used for in-situ planetary resource acquisition.     

Analysis of a Thaumasia Planum rift through automatic mapping and strain characterization of normal faults

A new semi-automatic technique is presented to map and characterize tectonic features on Mars. Automatic strain estimation associated with normal faults is achieved for synthetic and real fault scarps on Mars.The application of this new technique to a small rift located in Thaumasia Planum allowed the segmentation of the rift. The defined segmentation corresponds to changes in the strikes of faults that delimitate rift areas with different architecture.The rift is formed by several pull-apart basins developed due to the reactivation of previously formed tectonic structures. The strain spatial distribution and the overall geometry are consistent with a roughly East–West left-lateral shear transfer zone between two different lithospheric blocks.     

Quantitative in situ XRD measurement of shock metamorphism in Martian meteorites using lattice strain and strain‐related mosaicity in olivine

All Martian meteorites have experienced shock metamorphism to some degree. We quantitatively determined shock‐related strain in olivine crystals to measure shock level and peak shock pressure experienced by five Martian meteorites. Two independent methods employing nondestructive in situ micro X‐ray diffraction (μXRD) are applied, i.e., (1) the lattice strain method, in which the lattice strain value (ε) for each olivine grain is derived from a Williamson–Hall plot using its diffraction pattern (peak width variation with diffraction angle) with reference to a best fit calibration curve of ε values obtained from experimentally shocked olivine grains; (2) the strain‐related mosaicity method, allowing shock stage to be estimated by measuring the streaking along the Debye rings of olivine grain diffraction spots to define their strain‐related mosaic spread, which can then be compared with olivine mosaicity in ordinary chondrites of known shock stage. In this study, both the calculated peak shock pressures and the estimated shock stages for Dar al Gani 476 (45.6 ± 0.6 GPa), Sayh al Uhaymir 005/8 (46.1 ± 2.2 GPa), and Nakhla (18.0 ± 0.6 GPa) compare well with literature values. Formal shock assessments for North West Africa 1068/1110 (53.9 ± 2.1 GPa) and North West Africa 6234 (44.6 ± 3.1 GPa) have not been reported within the literature; however, their calculated peak shock pressures fall within the range of peak shock pressures defining their estimated shock stages. The availability of nondestructive and quantitative μXRD methods to determine shock stage and peak shock pressure from olivine crystals provides a key tool for shock metamorphism analysis.     

Origin of Petrofabrics and Magnetic Anisotropy in Ordinary Chondrites

Abstract— Three-dimensional finite strain and magnetic susceptibility anisotropy have been determined for 15 ordinary chondrites. The axes of strain and magnetic ellipsoids roughly correlate in both magnitude and orientation. The shapes of these ellipsoids are generally oblate spheroids that define a dominant foliation and a weak lineation. These characteristics suggest deformation involving uniaxial compaction. The degree of uniaxial deformation correlates with intensity of shock, as indicated by optical, TEM and chemical criteria. These data, plus the lack of a relationship between foliation and metamorphic history, indicate that dynamic processes, i.e., impacts, produced planar deformation fabrics in chondrites.     

The formation of Ganymede's grooved terrain: Numerical modeling of extensional necking instabilities

Ganymede's grooved terrain likely formed during an epoch of global expansion, when unstable extension of the lithosphere resulted in the development of periodic necking instabilities. Linear, infinitesimal-strain models of extensional necking support this model of groove formation, finding that the fastest growing modes of an instability have wavelengths and growth rates consistent with Ganymede's grooves. However, several questions remain unanswered, including how nonlinearities affect instability growth at large strains, and what role instabilities play in tectonically resurfacing preexisting terrain. To address these questions we numerically model the extension of an icy lithosphere to examine the growth of periodic necking instabilities over a broad range of strain rates and temperature gradients. We explored thermal gradients up to 45 K km⁻¹ and found that, at infinitesimal strain, maximum growth rates occur at high temperature gradients (45 K km⁻¹) and moderate strain rates (10⁻¹³ s⁻¹). Dominant wavelengths range from 1.8 to 16.4 km (post extension). Our infinitesimal growth rates are qualitatively consistent with, but an order of magnitude lower than, previous linearized calculations. When strain exceeds ∼10% growth rates decrease, limiting the total amount of amplification that can result from unstable extension. This fall-off in growth occurs at lower groove amplitudes for high-temperature-gradient, thin-lithosphere simulations than for low-temperature-gradient, thick-lithosphere simulations. At large strains, this shifts the ideal conditions for producing large amplitude grooves from high temperature gradients to more moderate temperature gradients (15 K km⁻¹). We find that the formation of periodic necking instabilities can modify preexisting terrain, replacing semi-random topography up to 100 m in amplitude with periodic ridges and troughs, assisting the tectonic resurfacing process. Despite this success, the small topographic amplification produced by our model presents a formidable challenge to the necking instability mechanism for groove formation. Success of the necking instability mechanism may require rheological weakening or strain localization by faulting, effects not included in our analysis.     

基于应变的变形副反射面位姿形貌快速重构方法

随着双反射面天线口径的增大、工作频段的升高,天线对副反射面的精度要求也越来越高.当天线受到自重以及风荷、温度等外界因素的影响时,为了更好地保证满足天线的高指向精度等电性能要求,基于应变传感器和模态叠加原理,分别利用天线变形后副反射面支撑腿与副反射面自身结构的应变值来快速重构副反射面的位姿、形貌,便于副反射面调整机构对其进行实时修正,以实现更加精准的主副反射面位置匹配,降低因天线结构变形造成的波束指向误差和增益损失.     

The librational dynamics of deformable bodies

The volume average of the strain tensor in a body moving in an inverse-square force field is evaluated. The calculation is carried out assuming the satellite to be an isotropic elastic body whose center of mass moves in a planar orbit. An approximate expression, in terms of its volume and elastic properties, is presented for the strain energy in the satellite. Using this expression the equation of planar librational motion is written explicity. This equation is discussed for both circular and elliptic orbits and is modified to include the effects of energy dissipation in the body. It is shown that the concept of Adiabatic Invariants allows one to analyze the influence of slow changes in the material volume and elasticity.This work was supported by NASA Grant No. NGR 05-010-020.