安徽铜陵矿集区块状硫化物矿床成因模型与成矿流体动力学迁移

根据地质和同位素地球化学特征，建立了铜陵地区赋存于石炭系地层底部的块状硫化物矿床的成因模型；该类型矿床的形成主要与石炭纪海底热水活动有关，属喷流-沉积型(SEDEX)块状硫化物矿床；下伏古生代地层是重要的成矿金属源区，海水硫酸盐是硫化物成矿的主要硫源。成矿热流体循环的动力学数值模拟揭示。该类型矿床底盘岩石中的流体活动和热影响范围主要局限在主排泄通道两侧较小的区域内；温度场和流场决定以沉积岩为容矿岩石的喷流．沉积型块状硫化物矿床底盘岩石中的蚀变和矿化强度不如以火山岩为容矿岩石的块状硫化物矿床。伴随强大深部热流的张性同生断裂是控制喷流一沉积型块状硫化物矿床形成与分布的关键因素。海西期扬子板块北缘的张性构造体制为该时期喷流一沉积型块状硫化物矿床的形成提供了有利的地球动力学环境。     

黑色岩系中海底热液SEDEX矿床的研究概况

黑色岩系是含硫化物和有机质较高的暗色泥质岩、硅岩、碳酸盐岩组合,黑色岩系中以海底热液喷流作用形成的矿床是国际研究热点。因为海陆变化、壳幔作用以及全球构造变动均导致黑色岩系和SEDEX矿床的演化,所以研究湘黔张家界—遵义地区有机物从保存、埋藏、生烃、排气到过成熟,均与微生物的生命代谢、内生地质作用、成矿机制同步谐动,地球化学影响和生物成矿作用与全球性的气候变迁、缺氧事件相关联,而且以上研究集中体现在事件地质学的成因解释、热水喷流沉积作用、生物矿化与金属矿化、矿物成因与环境影响、铂族元素矿物、黑色页岩石煤与金属矿化、元素地球化学影响等方面。研究数据充分显示了特定的地质背景、成矿环境、生物作用机制在黑色岩系SEDEX矿床成岩成矿中的作用。     

吉林省红旗岭茶尖矿区镁铁-超镁铁岩石地球化学特征及找矿意义

红旗岭镍矿田是我国岩浆岩型铜镍硫化矿床的主要矿化集中区之一,茶尖矿区是其重要组成部分之一.在茶尖矿区已往勘查中共发现20余个镁铁-超镁铁质岩体,并在1号、新6号、9号、18号岩体中发现小型铜镍矿床,2号、10号、14号等岩体中发现铜镍矿化.从岩体岩石学及蚀变矿化特征、岩体常量元素、微量元素、稀土元素特征方面进行分析,并与红旗岭镍矿区进行对比,认为其与红旗岭区镁铁-超镁铁岩具同源性,矿床属熔离-贯入型成因,后期热液叠加又是茶尖区独有的成矿特征,通过分析、对比,确定了该区找矿意义和前景区.     

石膏矿床的地质特征及对硫化矿床的指示意义

从研究划分石膏矿化的成因类型入手,进行热液化学成分来源分析和岩石蚀变分带研究,结合典型矿床实例分析,总结出在碳酸盐岩中出现热液交代型石膏矿化体附近,往往伴生有金属硫化矿体或含硫化矿物丰富的岩石,该规律对寻找硫化物型金属自矿体的意义巨大.     

Geology,alteration, age,and origin of iron oxide–apatite deposits in Upper Eocene quartz monzonite,Zanjan district,NW Iran

Iron oxide–apatite deposits are present in Upper Eocene pyroxene-quartz monzonitic rocks of the Zanjan district, northwestern Iran. Mineralization occurred in five stages: (1) deposition of disseminated magnetite and apatite in the host rock; (2) mineralization of massive and banded magnetite ores in veins and stockwork associated with minor brecciation and calcic alteration of host rocks; (3) deposition of sulfide ores together with potassic alteration; (4) formation of quartz and carbonate veins and sericite, chlorite, epidote, silica, carbonate, and tourmaline alteration; and (5) supergene alteration and weathering. U–Pb dating of monazite inclusions in the apatite indicates an age of 39.99?±?0.24 Ma, which is nearly coeval with the time of emplacement of the host quartz monzonite, supporting the genetic connection. Fluid inclusions in the apatite have homogenization temperatures of about 300 °C and oxygen isotopic compositions of the magnetite support precipitation from magmatic fluids. Late-stage quartz resulted from the introduction of a cooler, less saline, and isotopically depleted fluid. The iron oxide–apatite deposits in the Tarom area of the Zanjan district are typical of a magmatic–hydrothermal origin and are similar to the Kiruna-type deposits with respect to mineral assemblages, fabric and structure of the iron ores, occurrence of the ore bodies, and wall rock alteration.     

The use of fluorine as a pathfinder for volcanic-hosted massive sulfide ore deposits

A multi-element geochemical study of the wall rocks of intermediate to felsic volcanic-hosted massive sulfide deposits was carried out to identify pathfinder elements which significantly enlarge the size of exploration targets. Drill core samples from the Crandon massive sulfide deposit in Wisconsin, and outcrop samples from the United Verde and Iron King deposits in Arizona, and from the Captains Flat, Mt. Costigan, and Wiseman Creek deposits in New South Wales, Australia were analyzed. Because anomalously high fluorine values have been described in several volcanic-hosted ore systems, fluorine was included in the study.All of the above deposits have patterns of fluorine enrichment around ore. Drill core samples from two noneconomic prospects within ten miles of the Crandon deposit contain background to only weakly anomalous fluorine values.At the large Crandon deposit (> 50 million tons of zinc, copper ore), fluorine enrichment extends approximately 320 m into the footwall rocks and at least 220 m into the hanging wall rocks. At the large United Verde deposit (> 50 million tons of copper, zinc ore), fluorine enrichment is recognizable in the footwall rocks at least 650 m from the ore. At the smaller Iron King deposit (five million tons production of zinc, lead, copper ore), fluorine enrichment extends for a distance of approximately 60 m into the footwall rocks. At the small deposits in New South Wales (< five million tons production of zinc, lead, copper ore), fluorine enrichment is easily recognizable, but with the samples collected, the limits of the anomalous patterns cannot be defined.Fluorine occurs in some hydrothermal systems unassociated with mineralization and is therefore not a specific signature of ore-forming processes. From the work completed, many massive sulfide deposits in volcanic rocks occur in hydrothermal systems which contain fluorine. On the basis of the data presented, if anomalously high fluorine values do exist in an exploration search area, the chances of finding a massive sulfide ore deposit are improved.Genetic models for volcanic-hosted massive sulfide ore deposits have concentrated on rock textures, alteration mineralogy, and geochemistry of the ore metals. From the data presented, fluorine should be considered as a component of massive sulfide systems in intermediate to felsic volcanic rocks, and should be considered as a possible complexing agent for the ore metals.     

胶东金矿成矿流体性质及其地质意义

胶东地区重要金矿床是以硫化物石英脉为主的和以硫化物蚀变岩为主的两类,对它们的成矿流体组分和温压条件等方面的研究表明,其含矿流体均起源于下地壳,为玄武岩浆底热提供热( 部分流体)作用形成;其含矿流体上升演化成矿过程表现:以硫化物石英脉为主的金矿床是在相对稳定的环境下含矿流体降温降压结晶分异成矿,而以硫化物蚀变岩为主的金矿床则是流体发生沸腾作用成矿;成矿过程的温-压(能量)演化轨迹显示,大型矿床具有完整的P-T演化轨迹或具有沸腾特征,相对小的矿床一般不具完整的P-T轨迹.这项研究对深入认识胶东金矿成因及成矿规律具有重要的价值.     

安徽铜陵桂花冲斑岩铜矿围岩蚀变与矿化作用

桂花冲铜矿为安徽铜陵地区新发现的斑岩型铜矿,斑岩体为准铝质高钾钙碱性的花岗闪长斑岩。围岩蚀变与矿化作用是斑岩型矿床成矿过程研究的一项重要内容,对蚀变带岩石开展元素地球化学成分的迁移研究,是分析热液交代蚀变过程的基础。桂花冲铜矿区内围岩蚀变作用比较强烈,蚀变类型主要有钾化、绢云母化、硅化、绿泥石化和碳酸盐化等。蚀变分带比较明显,由内向外依次为钾化带、绢英岩化带和青磐岩化带,矿体主要产于绢英岩化带内。矿化蚀变自早至晚划分为钾长石、石英-绢云母、石英多金属硫化物和碳酸盐4个阶段。蚀变带物质组分迁移结果表明,在蚀变过程中,岩石的主量元素除TiO₂、MnO、MgO外,其他元素迁移量发生了明显改变;微量元素除Sr和Cu外,迁移量变化较小,稀土元素在矿化强的部位亏损,在矿化弱的地带富集。岩体及蚀变带岩石稀土元素球粒陨石标准化配分模式一致,说明岩体与蚀变岩石经历了相同来源流体的交代蚀变,是岩浆流体连续作用的结果。     

安徽庐枞沙溪斑岩铜矿蚀变及矿化特征研究

沙溪斑岩铜矿是长江中下游成矿带中部庐枞火山岩盆地外围的一个大型铜矿床.本文在前人工作基础上,基于详细的野外观察和系统的岩相学、矿相学工作,详细研究了矿床的蚀变特征及分带.结果表明,矿床的蚀变类型有钾硅酸盐化、青磐岩化、长石分解蚀变和高岭土化,从深到浅依次发育有钾硅酸盐化、长石分解蚀变叠加钾硅酸盐化、长石分解蚀变和高岭土化等蚀变.确定了矿化特征、矿物生成顺序并划分了成矿阶段,即:钾硅酸盐阶段、石英硫化物阶段和石英碳酸盐阶段,其中,石英硫化物阶段又可进一步分为石英硫化物亚阶段和绿帘石-绿泥石亚阶段.基于蚀变及矿化特征认为,沙溪铜矿床的矿化始于钾硅酸盐阶段的晚期,石英硫化物亚阶段是黄铜矿主要的沉淀阶段,石英碳酸盐阶段也对成矿贡献了部分铜质.与世界上不同构造环境的典型斑岩铜矿床对比认为,沙溪矿床总体上与这些矿床的蚀变、矿化特征类似;与陆缘弧、岛弧、陆内碰撞造山后伸展环境矿床在矿体产出位置、蚀变分带方面相似;而由于围岩性质的差异,与板内环境的德兴矿床在矿体位置、蚀变分带方面存在差异,但是二者在脉体类型特别是与矿化关系密切的脉体特征上较为一致.因此,对于斑岩型矿床而言,构造背景可能控制了其岩浆的形成、演化以及含矿性,而岩浆岩最终定位的深度、围岩等条件则控制了其蚀变、矿化特征.     

云南大红山铁铜多金属矿床成因分析及成矿方式厘定

前人对云南大红山铁铜多金属矿床成因研究趋向认为属海底火山块状硫化物矿床(VMS型),但对其成矿方式研究还不够精细。对云南大红山铁铜多金属矿床进一步研究表明,虽然该铁铜多金属矿床可归为火山-沉积型矿床,但其成矿方式并非为火山喷出物质在火山机构附近发生"原位沉积"而成矿,其矿床结构特征、围岩蚀变特征、容矿岩性等方面均与原位沉积形成的火山块状硫化物矿床存在显著差异;基于岩相古地理恢复研究,在早元古代曼岗河组沉积时期的大红山地区的特殊古地理环境,使得携载大量矿质的火山物质沿海底隆洼相间的斜坡水道运移而发生"异位沉积",从而控制了该矿床的形成。     

Metavolcanic host rocks,mineralization, and gossans of the Shaib al Tair and Rabathan volcanogenic massive sulphide deposits of the Wadi Bidah Mineral District,Saudi Arabia

The Wadi Bidah Mineral District of Saudi Arabia contains more than 16 small outcropping stratabound volcanogenic Cu–Zn–(Pb) ± Au-bearing massive sulphide deposits and associated zones of hydrothermal alteration. Here, we use major and trace element analyses of massive sulphides, gossans, and hydrothermally altered and least altered metamorphosed host rock (schist) from two of the deposits (Shaib al Tair and Rabathan) to interpret the geochemical and petrological evolution of the host rocks and gossanization of the mineralization. Tectonic interpretations utilize high-field-strength elements, including the rare earth elements (REE), because they are relatively immobile during hydrothermal alteration, low-grade metamorphism, and supergene weathering and therefore are useful in constraining the source, composition, and physicochemical parameters of the primary igneous rocks, the mineralizing hydrothermal fluid and subsequent supergene weathering processes. Positive Eu anomalies in some of the massive sulphide samples are consistent with a high temperature (>250°C) hydrothermal origin, consistent with the Cu contents (up to 2 wt.%) of the massive sulphides. The REE profiles of the gossans are topologically similar to nearby hydrothermally altered felsic schists (light REE (LREE)-enriched to concave-up REE profiles, with or without positive Eu anomalies) suggesting that the REE experienced little fractionation during metamorphism or supergene weathering. Hydrothermally altered rocks (now schists) close to the massive sulphide deposits have high base metals and Ba contents and have concave-up REE patterns, in contrast to the least altered host rocks, consistent with greater mobility of the middle REE compared to the light and heavy REE during hydrothermal alteration. The gossans are interpreted to represent relict massive sulphides that have undergone supergene weathering; ‘chert’ beds within these massive sulphide deposits may be leached wall-rock gossans that experienced silicification and Pb–Ba–Fe enrichment from acidic groundwaters generated during gossan formation.     

块状硫化物矿床的地球化学找矿标志

近年来国外发现了许多大型块状硫化物矿床，而我国进展还不大。原因之一是我们对这类矿床的地质特征，成矿条件尤其是找矿标志研究还不够。这是一类成矿物质通过热液作用在海底沉积而成的特殊矿床，故在找矿勘探讨既要研究沉积矿时形成的原生晕，又要研究热液经过围岩时蚀变而产生的次生晕?Ｍｎ晕，Ｔｌ，Ｈｇ，Ｂａ，Ａｓ和Ｚｎ等元素的异常，络合剂元素的富集，微量元素的分布，铅同位素，岩石化学异指数尤其是块状硫化物Ｃｕ矿中     

Subseafloor hydrothermal alteration during the Early Proterozoic at Garpenberg,Central Sweden

The Early Proterozoic sulfide deposit at Garpenberg is located in the metallogenetic province of central Sweden. It is a strata-bound massive sulfide deposit contained in a supracrustal sequence of mainly acid metavolcanic rocks. Stratiform Zn-Pb-Cu mineralization is underlain by Cu-bearing stockwork ore and an extensive alteration zone. The sulfide ores and their altered wall rocks were formed by subseafloor hydrothermal activity. The alteration pattern observed in the wall rocks of this deposit is consistent with a hydrothermal system where the fluid consists mainly of seawater and a high water/rock mass ratio predominates. The hydrothermal activity caused the destruction of the primary mineralogy, mainly feldspars, and a general redistribution of the chemical elements in the altered wall rocks which were principally depleted in Ca, Na and Eu and enriched in Mg. Eu was redeposited with the ore metals near or at the seafloor and Ca was deposited as limestone. Most of the major and trace elements show large mobility during the alteration; only Ti, Zr, Y and REE (excluding Eu) behaved as relatively immobile elements.     

东昆仑成矿带典型矿床分析

在综述东昆仑地区成矿地质背景及成矿条件的基础上,通过对肯德可克、驼路沟、督冷沟和大场等典型矿床的剖析,详细论述了矽卡岩型铁多金属矿、海相火山喷气沉积叠加后期改造型钴(金)矿、块状硫化物型铜钴矿和造山型金矿的成矿特征、成矿规律及找矿前景,并结合区域成矿模式、找矿模型和各类矿产、异常的空间分布特征确定出8个成矿远景区,13个找矿靶区。同时指出东昆仑各成矿带的成(找)矿潜力由大到小的依次排序为:昆南成矿带≈阿尼玛卿-北巴颜喀拉成矿带>昆北成矿带>>昆中成矿带。     

四川呷村V HMS矿床：从野外观察到成矿模型

呷村矿床是一个与晚三叠世海相钙碱性酸性火山岩系有关的典型块状硫化物（VHMS）矿床。热水流体系统和贱金属成矿作用发育于义敦岛弧碰撞造山带上的弧间裂谷盆地内,并受其内部的一系列局限盆地及SN向基底断裂－裂缝系统控制。含矿岩系为双峰岩石组合,具火山碎屑岩－矿体－喷气岩“三位一体”特征。硫化物矿床具有“块状矿席＋层控网脉状矿带”式三维结构特征。块状矿席发育多旋回的硫化物－硫酸盐韵律型式,揭示热水流体在海底的幕式排泄以及硫化物－硫酸盐在卤水池内的韵律式化学淀积和滑塌堆积过程。层控网脉状矿带产出于流纹质火山岩系,与上覆的块状矿席平行展布,揭示高渗透性碎屑岩层和多条同级别断层或断裂共同约束海底下部热水流体,并诱导其“弥散式”排泄和侧向流动交代。热水流体的传导冷凝过程导致硫化物沉积、热水流体与冷海水的简单混合导致硅质岩或／重晶石淀积,传导冷凝与海水混合的联合作用导致含硫化物重晶石、硅质岩和红碧玉形成。     

庐枞盆地大倪庄铜矿床地质特征、成岩时代及成因探讨

大倪庄铜矿是庐枞盆地内部近年来发现的一处小型斑岩型矿床。本次工作以大倪庄铜矿为研究对象,基于详细的野外观察和系统的岩相学、矿相学工作,总结了矿床的蚀变特征,即主要发育:钾硅酸盐化、黄铁绢英岩化、青磐岩化、碳酸盐化蚀变;确定了矿化特征、矿物生成顺序并划分了成矿阶段,即:钾硅酸盐化阶段、硫化物阶段、碳酸盐化阶段,其中硫化物阶段可进一步划分为石英硫化物亚阶段、绿帘石-绿泥石亚阶段。通过对与成矿有关的侵入岩体(正长斑岩)采用LA-ICP-MS锆石U-Pb定年,获得正长斑岩LA-ICP-MS锆石U-Pb年龄为(126.6±1.8)Ma,形成时代为早白垩世,对应于盆地内双庙旋回岩浆侵入活动。通过与其他区域相似矿床对比分析,探究了此类矿床控矿因素,为该地区斑岩型铜矿找矿勘查提供参考。     

金沙江造山带碰撞后地壳伸展背景——火山成因块状硫化物矿床的重要成矿环境

近年来对金沙江造山带区域地质、矿床地质和岩石地球化学新资料的研究和典型火山成因块状硫化物(VHMS)矿床的解剖,金沙江造山带的VHMS成矿作用主要发生于早二叠世晚期—晚二叠世海相弧火山岩和晚三叠世裂谷盆地海相火山岩中,构成西南三江地区一条重要的多金属块状硫化物成矿带。成矿带内晚三叠世碰撞后地壳伸展背景下形成的上叠裂谷盆地是其VHMS成矿作用的主体,盆地中火山活动从早期的双峰式火山岩演变为晚期的中酸性火山岩,岩石地球化学特征与孤火山岩有明显的区别,反映其形成于伸展背景。伸展盆地的早期阶段,在双峰火山岩组合的高钾流纹质火山岩系中产出鲁春式VHMS矿床,具有Zn-Cu-Pb-Ag金属组合特征,形成于深水环境;伸展盆地的晚期阶段,在中酸性火山岩系与上覆碳酸盐岩接触带中产出赵卡隆式VHMS矿床,具有Ag-Fe-Pb-Zn金属组合特征,形成于浅水环境;盆地的末期阶段,在滨浅海相磨拉石碎屑岩中产出里仁卡式石膏矿床。金沙江造山带碰撞后地壳伸展背景下VHMS成矿作用的研究,对于造山带中的找矿工作具有重要的指导意义。     

闽西南地区块状硫化物矿床的喷流-沉积成矿作用

通过对闽西南地区石炭纪—早二叠世主要块状硫化物矿床的区域成矿背景、贮矿层位特征以及矿石矿物成分、结构构造,硫同位素地球化学特征、成矿温度等分析研究,指出该地区石炭纪—早二叠世块状硫化物矿床的形成多与海底火山活动有关,贮矿层中伴有典型的喷流沉积岩—硅质岩,并提出闽西南地区块状硫化物矿床存在海底喷流-沉积成矿作用的新认识。     

内蒙古喀喇沁旗安家营子金矿蚀变及其分布研究

位于华北克拉通北缘的安家营子金矿是一赋存在花岗岩中的复合型金矿,既有石英脉型矿化,也有蚀变岩型矿化,矿区发育广泛的热液蚀变。本文在详细的矿床地质特征研究基础上,通过系统采样、镜下鉴定,详细研究了安家营子金矿蚀变岩的类型、矿物组合、空间分布以及地球化学特征,探讨了蚀变岩的分带性、成矿流体的演化等。结果表明,安家营子金矿主要受NNE向脆性断裂的控制,蚀变岩即分布在断裂的影响范围内。主要的蚀变类型有钠长石化、绢云母化、绿泥石化、硅化和黄铁绢英岩化等,其中钠长石化在整个矿区均有分布,其余蚀变则分散在不同的独立区域。热动力学数据表明,安家营子金矿早期成矿流体K^+含量不高,可能相对富Na^+,因此钠长石化大量出现;随着钠长石的大量形成,流体成分演化至绢云母和钾长石的稳定范围,并出现绢云母化,但钾长石保持稳定。随着流体进一步演化至绢云母的稳定范围,绢英岩化开始大量出现,并且斜长石和钾长石基本消失,形成矿区主要的蚀变岩型矿体。安家营子金矿形成于喀喇沁变质核杂岩快速隆升期,因此控矿的次级脆性断裂构造的性质在拉张和剪切之间波动,导致蚀变分带不明显,也使得脉状矿化和蚀变岩型矿化叠加在一起。     

印度尼西亚巴都希贾乌斑岩型铜——金矿床成矿特征

巴都希贾乌铜金矿是坐落在印度尼西亚松巴岛西南部的世界级的斑岩型铜金矿床,产于岛弧环境。从容矿岩石、矿化、蚀变、成矿流体等方面分析总结了该矿床的基本特征。矿床在岩浆组合、空间形态和矿化及围岩蚀变特征上均体现出了明确的斑岩型矿床的特征;矿区围岩蚀变可划分为四个阶段,与成矿关系最为密切的是第一阶段的黑云母化;成矿流体为相对低温高盐度的流体,且具有由深到浅石盐溶解温度升高的趋势。