方解石表面Cd2+与Pb2+类质同象的AFM研究

 借助原位液槽原子力显微镜（in situ AFM）的观察,通过Cd2+,Pb2+替代方解石最外层晶格Ca2+生长模式的实验研究, 探讨了Cd2+与Pb2+作用下方解石表面溶解与结晶行为。在液体反应槽中,分别将含不饱和Cd2+与Pb2+溶液流经方解石{101 _ 4}解理面,结果发现:（1）Cd2+的存在不影响方解石沿<4_41> 晶向台阶的溶解,而Pb2+的存在则强烈阻碍了方解石沿<441>+晶向台阶的溶解;（2）停止输入溶液含Cd2+,Pb2+溶液后,随着方解石表面与溶液达到平衡,溶解过程逐渐转变为结晶过程。结果显示在Cd2+存在时,单分子生长层具有方解石原有的定向性,而在Pb2+存在时的生长则不具任何定向性。尽管有此差异, 但（Ca,Cd）CO3 和（Ca,Pb）CO3 固溶体都受控于单分子层外延生长这一结晶机理。 　　含Cd2+和Pb2+溶液对方解石溶解动力学的作用与选择性吸附的阳离子半径大小、吸附复合体的几何形状及其结晶学取 向有关。Cd2+离子倾向于优先进入更狭小的<4_41>- 晶向的微台阶上,而Pb2+则倾向于形成扭曲的八面体络合物吸附在更开 阔的<4_41>+ 晶向台阶上。因此,Pb2+存在下方解石表面生长方向无序可认为是白铅矿和方解石结构差异的原因。     

Self-limiting growth on dolomite: Experimental observations with in situ atomic force microscopy

In situ Atomic Force Microscopy (AFM) and Lateral Force Microscopy (LFM) studies on dolomite (101?4) were performed during exposure to supersaturated aqueous solutions (supersaturated in dolomite, calcite, aragonite, vaterite, huntite and magnesite) at pH = 9 at various Ca²⁺/Mg²⁺ aqueous ion activity ratios. At high saturation ratios, rapid growth of a single layer (∼3 Å thick) of a carbonate followed by much slower growth of a second layer was observed. Growth of the second layer was highly inhibited, suggesting that the first layer was essentially self-limited, and inhibited further layer-by-layer growth. The growth of the first layer was observed over a wide range of Ca²⁺/Mg²⁺ ratios, suggesting that the dolomite surface is favorable to formation of a range of Ca-Mg carbonates. LFM data revealed contrast in the tip-surface frictional forces on the first grown layer, but this contrast was only observed in layers grown from middle to high Ca²⁺/Mg²⁺ solutions. Thus, LFM may have detected or responded to differences in the structure and/or composition between the first layer relative and the dolomite substrate. Dissolution of the first layer occurred from significantly supersaturated solutions relative to ordered stoichiometric dolomite permitting an estimate of the excess interfacial strain energy of up to 10 mJ/m².     

How do mineral coatings affect dissolution rates? An experimental study of coupled CaCO3 dissolution—CdCO3 precipitation

Coupled CaCO₃ dissolution-otavite (CdCO₃) precipitation experiments have been performed to 1) quantify the effect of mineral coatings on dissolution rates, and 2) to explore the possible application of this coupled process to the remediation of polluted waters. All experiments were performed at 25°C in mixed-flow reactors. Various CaCO₃ solids were used in the experiments including calcite, aragonite, and ground clam, mussel, and cockle shells. Precipitation was induced by the presence of Cd(NO₃)₂ in the inlet solution, which combined with aqueous carbonate liberated by CaCO₃ dissolution to supersaturate otavite. The precipitation of an otavite layer of less than 0.01 μm in thickness on calcite surfaces decreases its dissolution rate by close to two orders of magnitude. This decrease in calcite dissolution rates lowers aqueous carbonate concentrations in the reactor such that the mixed-flow reactor experiments attain a steady-state where the reactive fluid is approximately in equilibrium with otavite, arresting its precipitation. In contrast, otavite coatings are far less efficient in lowering aragonite, and ground clam, mussel, and cockle shell dissolution rates, which are comprised primarily of aragonite. A steady-state is only attained after the precipitation of an otavite layer of 3-10 μm thick; the steady state CaCO₃ dissolution rate is 1-2 orders of magnitude lower than that in the absence of otavite coatings. The difference in behavior is interpreted to stem from the relative crystallographic structures of the dissolving and precipitating minerals. As otavite is isostructural with respect to calcite, it precipitates by epitaxial growth directly on the calcite, efficiently slowing dissolution. In contrast, otavite’s structure is appreciably different from that of aragonite. Thus, it will precipitate by random three dimensional heterogeneous nucleation, leaving some pore space at the otavite-aragonite interface. This pore space allows aragonite dissolution to continue relatively unaffected by thin layers of precipitated otavite. Due to the inefficiency of otavite coatings to slow aragonite and ground aragonite shell dissolution, aragonite appears to be a far better Cd scavenging material for cleaning polluted waste waters.     

Nanoscale phenomena during the growth of solid solutions on calcite {101¯4} surfaces

This work deals with the growth behaviour of calcite {101¯4} surfaces in contact with multicomponent aqueous solutions containing divalent cations (Ba²⁺, Sr²⁺, Mn²⁺, Cd²⁺, or Mg²⁺). The result is the formation of solid solutions, with calcite or aragonite as one of the end-members. In situ atomic force microscopy has revealed a wide variety of surface phenomena occurring during the formation of these solid solutions. Among them are: (1) the thickening of growth steps and the subsequent dissolution of surfaces followed by the nucleation of secondary three-dimensional nuclei on calcite surfaces, (2) the transition between growth mechanisms, (3) the formation of an epitaxial layer that armours the substrate from further dissolution and (4) the inhibitory effect of the newly formed surface on the subsequent growth (template effect). The two last phenomena can considerably limit coprecipitation as an effective mechanism for divalent metal uptake. All the phenomena described are a consequence of the interplay between thermodynamics, supersaturation of the aqueous solution with respect to the possible solid solutions and the crystallographic control of the surfaces on the cation incorporation, and indicates that there are many differences between the crystal growth of solid solutions and phases with fixed composition.     

堆载下单桩负摩阻力工作性状非线性数值分析

利用三维非线性数值方法对一算例在堆载作用下桩侧负摩阻力进行了计算分析。计算结果揭示了摩擦型、端承型桩负摩阻力工作性状的异同;分析了堆载速度、桩顶荷载对负摩阻力的影响:堆载越快,负摩阻力越小;在无桩顶荷载作用下,由负摩阻力引起的下拉荷载最大,可视为常规方法设计的上限值;桩顶荷载与堆载施工顺序对负摩阻力的影响也很大,先施加桩顶荷载,后进行堆载所产生的负摩阻力最大,反之最小。     

Stresses due to vertical subsurface loading for an inhomogeneous cross‐anisotropic half‐space

In this article, we present the solutions for the stresses induced by four different loads associated with an axially loaded pile in a continuously inhomogeneous cross‐anisotropic half‐space. The planes of cross‐anisotropy are parallel to the horizontal surface of the half‐space, and the Young's and shear moduli are assumed to vary exponentially with depth. The four loading types are: an embedded point load for an end‐bearing pile, uniform skin friction, linear variation of skin friction, and non‐linear parabolic variation of skin friction for a friction pile. The solutions for the stresses due to the pile load are expressed in terms of the Hankel integral and are obtained from the point load solutions of the same inhomogeneous cross‐anisotropic half‐space which were derived recently by the authors (Int. J. Rock Mech. Min. Sci. 2003; 40 (5):667–685). A numerical procedure is proposed to carry out the integral. For the special case of homogeneous isotropic and cross‐anisotropic half‐space, the stresses predicted by the numerical procedure agree well with the solutions of Geddes and Wang (Geotechnique 1966; 16 (3):231–255; Soils Found. 2003; 43 (5):41–52). An illustrative example is also given to investigate the effect of soil inhomogeneity, the type and degree of soil anisotropy, and the four different loading types on the vertical normal stress. The presented solutions are more realistic in simulating the actual stratum of loading problem in many areas of engineering practice. Copyright © 2004 John Wiley & Sons, Ltd.     

不同粗糙度的节理直剪颗粒流分析

利用二维颗粒流程序生成5种不同粗糙程度的节理模型,并对5种节理模型进行了5种不同法向恒定荷载作用下的直剪试验,从细观角度分析了不同粗糙程度的节理模型在法向荷载下的形貌损伤情况和裂纹演化机制。与此同时,分析了节理JRC值和节理面颗粒摩擦系数对节理抗剪强度影响,并反推出了节理面抗剪强度参数Cj与?j与JRC值的关系。结果为：法向恒定荷载越大时,节理峰值抗剪应力越大,剪胀现象越小,节理形貌损伤范围越大。随着剪切的进行,上下节理面接触范围减小,微裂纹开始主要沿节理面产生,随着剪切位移的继续增加微裂纹数量显著增加,并且不局限于节理面附近而深入到模型内部。随着节理粗糙程度（JRC值）和节理面颗粒摩擦系数的增加节理峰值抗剪应力也增大。节理抗剪强度参数Cj与?j随着JRC值的增大而增大。所得结果可以为室内试验和工程应用提供参考和依据。     

Metastable phenomena on calcite {101̄4} surfaces growing from Sr2+–Ca2+–CO32− aqueous solutions

In situ atomic force microscopy (AFM) experiments, scanning electron microscopy (SEM) imaging and composition analysis, and X-ray diffraction have provided information about the growth, dissolution and transformation processes promoted by Sr²⁺–Ca²⁺–CO₃²⁻ aqueous solutions in contact with calcite {101̄4} surfaces. Experiments have shown a wide variety of surface phenomena, such as the influence of the Sr-bearing newly-formed surface on the subsequent growth (template effect), the growth and subsequent dissolution of surfaces and the nucleation of secondary three-dimensional nuclei on calcite surfaces. These phenomena reveal the metastability of the crystallisation system and are a consequence of the interplay between thermodynamics (the relative stability of the two calcite and aragonite structure solid solutions that can be formed), supersaturation of the aqueous solution with respect to the two possible solid solutions, and the crystallographic control of the surfaces on cation incorporation.     

考虑土体屈服的纵横荷载单桩变形内力分析

为提高桩身变形较大时纵横荷载单桩的设计计算水平,假定地基反力系数沿深度线性增加,考虑土体屈服及纵向荷载的P-?效应并计入桩身自重和桩侧摩阻力的影响,得到了地面以下桩身变形和内力的幂级数解。结合已有的地面以上桩身响应的幂级数解,采用Fortran语言编制了计算程序。计算结果表明：桩顶位移、地面处桩身位移及桩身最大弯矩均随纵横向荷载和自由段桩长的增加而增大,并随土体屈服位移的增加而减小;纵向荷载足够大时桩基失稳;桩顶约束条件对桩的响应影响很大。计算值与模型试验的实测值吻合较好,所得解和程序是可靠的。     

移动荷载作用下非均匀地基的动力响应分析

基于线弹性动力学理论,结合坐标变换,建立了移动荷载作用下非均匀弹性半平面地基的动力控制方程,利用半解析法研究了移动荷载作用下二维非均匀地基的动力响应问题。采用傅里叶（Fourier）级数展开,假设了响应函数的级数形式,通过理论推导获得了剪切模量随深度任意变化的非均匀地基在移动荷载作用下各物理量的解析表达式。考虑土体的剪切模量沿厚度方向按幂函数梯度变化,通过数值算例分析并讨论了地基非均匀参数、荷载移动速度以及地基表面的剪切模量等对地基力学响应的影响规律,并与均质地基的计算结果进行了比较。数值结果表明：地基中各点的竖向位移随着土体表面剪切模量和表征土体非均匀性的梯度因子的增大而减小,随着荷载移动速度的增大而增大。在移动荷载作用下,非均匀地基与均匀地基的动力响应有着显著的区别。     

基于纳米划痕试验的砂岩结构面宏-微观摩擦系数关系研究

基本摩擦系数是影响岩体结构面抗剪强度的重要参数。常规室内试验方法所确定的基本摩擦系数往往受矿物成分、温度等因素影响,为系统揭示结构面的基本摩擦性质,分别研究了砂岩宏观摩擦系数与微观摩擦系数,并建立了两者的关系。首先,通过X射线衍射、纳米压痕试验确定砂岩矿物组分与力学参数。其次,采用倾斜试验、直剪试验开展摩擦系数的宏观尺度研究,对规格为10 cm×10 cm×5 cm的平直结构面试样开展直剪试验,分别施加1、2、3、8、12 MPa的恒定法向应力,研究表明,摩擦系数随法向应力增加呈对数降低趋势,随剪切速率增加呈对数增长趋势。再次,采用纳米划痕试验开展摩擦系数的微观尺度研究,研究表明,低荷载条件下,长石矿物摩擦系数随荷载增加表现出先降低后保持不变的趋势,石英矿物摩擦系数随荷载增加表现出先降低后增加的趋势;此外,随着剪切速率的增加,两种矿物的摩擦系数在低荷载条件下呈增长的趋势,在高荷载条件下基本保持稳定。最后,基于摩擦系数的宏-微观摩擦系数试验结果,采用速度-状态摩擦（RSF）定律建立红砂岩基本摩擦系数与矿物摩擦系数的线性回归方程,并通过直剪试验验证了该经验关系的可靠性,其误差范围为0.17...     

Thickness and structure of the water film deposited from vapour on calcite surfaces

Synchrotron X-ray reflectivity (SXR) was used to measure the thickness of the water film that adsorbs on a {} cleavage surface of calcite (CaCO₃) in a sample chamber where relative humidity could be controlled within the range from <4% to 90%. Gases used to carry water vapour were initially either 100% N₂ or 100% CO₂. The product water film was remarkably constant in thickness at 15.5 Å (±1 Å) and independent of humidity. When N₂ was used as the carrier gas, this film displayed a gap in its electron density at between 0.6 and 2 Å distance from the calcite surface, depending on humidity. This implies that a change in the arrangement of water molecules occurs in direct proximity to the surface. This electron density discontinuity was measurably further from the calcite surface, at 3.4 Å, when CO₂ was used as the carrier gas. Except for this thin low density region proximate to the calcite surface, the density of the adsorbed water layer was 0.9 g cm⁻³, therefore suggesting a significant degree of ordering. Atomic force microscopy (AFM) images were completed in conjunction with the SXR measurements on similarly prepared calcite cleavage surfaces. AFM showed that terraces may be atomically flat over 1 μm or more. SXR corroborated this observation, with results showing that carefully cleaved surfaces had a starting root mean square (r.m.s.) roughness of ∼1.2 Å. Diffuse scatter measurements constrained the correlation lengths of these surfaces to be at least 18,000 Å. For comparison with the cleaved samples, a surface was also prepared by chemo-mechanical Syton polishing. This surface gave an r.m.s roughness by SXR that was an order of magnitude higher, equal to 12.1 Å. In this case, diffuse scatter resolved a correlation length of 950 Å, and revealed a fractal dimension that was higher than for the cleaved surface. On Syton polished samples, the water film determined by SXR was about twice as thick as for freshly cleaved surfaces, with a density of 1.0 g cm⁻³, equal to that of bulk water. However, surface roughness was too large to allow resolution of any gap in the electron density within the water layer proximate to the solid surface. Our AFM observations also confirm previous reports of calcite surface recrystallization. The electron density of the solid surface determined by SXR is indistinguishable from that of calcite, indicating that any material recrystallized within the adsorbed water film is compositionally indistinguishable from the calcite substrate.     

不同垂直荷重对风化砂改良膨胀土抗剪强度影响研究

本文以风化砂改良膨胀土的抗剪强度指标为研究对象,通过室内直接剪切试验,研究了在不同垂直荷重作用下,不同掺砂比例及不同含水率对改良膨胀土抗剪强度指标c、值的影响规律及各种不同垂直荷重下的-关系。影响直接剪切试验结果的两个关键因素是试验时的垂直荷重和剪切速率,而现行规范对剪切速率是有明确规定的,但对垂直荷重只有一个推荐性的取值。本文对膨胀土掺入了10%、20%、30%、40%、50%的风化砂,分别配以6%、8%、10%、12%、14%的水,然后在I级垂直荷重(12.5～50kPa)、Ⅱ级垂直荷重(62.5～100kPa)、Ⅲ级垂直荷重(100～400kPa)作用下,进行剪切试验。通过试验研究得知:垂直荷重对改良后膨胀土抗剪强度指标影响较大,随着垂直荷重的减小,掺砂后的膨胀土内摩擦角逐渐增大,黏聚力逐渐减小; 在各级垂直荷重下,在同一含水率状态下,黏聚力均随着掺砂比例的增大而逐渐减小,而内摩擦角均是先增大后减小; 在同一掺砂比例下,黏聚力及内摩擦角均随着含水率的增大而先增大后减小。本试验的研究成果为风化砂改良膨胀土用作公路路基填料提供了试验依据。     

RESPONSE OF A LAYERED ELASTIC MEDIUM TO A MOVING STRIP LOAD

Analytical determination of stresses and deformations caused by moving loads is vital to foundation and pavement designs. In current applications, moving loads are often approximated to be vertical impact loads. In this work, however, a live load is modelled as a uniform distribution of normal or shear stresses in actual motion. Then, a layer stiffness approach utilizing linear elasticity is followed in determining the surface and interior deformations due to the live load. By superimposing the two solutions for normal and shear surface stresses, the new approach can be made to provide an approximate solution to the problem of evaluating stresses and deformations caused by a wide wheel load rolling on a layered elastic system. Although elastic solutions in general are inadequate to explain the more significant consequences of pore pressure generation and dissipation in the soil subgrade, these results can certainly be useful to examine the shearing effects of wide rolling wheels on the asphalt layer and immediate settlement of the subgrade. It is found that the dynamic effects of a smoothly rolling wide load are significant at relatively low wheel velocities compared to those of shear waves in the subgrade and base.     

Specific effects of background electrolytes on the kinetics of step propagation during calcite growth

The mechanisms by which background electrolytes modify the kinetics of non-equivalent step propagation during calcite growth were investigated using Atomic Force Microscopy (AFM), at constant driving force and solution stoichiometry. Our results suggest that the acute step spreading rate is controlled by kink-site nucleation and, ultimately, by the dehydration of surface sites, while the velocity of obtuse step advancement is mainly determined by hydration of calcium ions in solution. According to our results, kink nucleation at acute steps could be promoted by carbonate-assisted calcium attachment. The different sensitivity of obtuse and acute step propagation kinetics to cation and surface hydration could be the origin of the reversed geometries of calcite growth hillocks (i.e., rate of obtuse step spreading < rate of acute step spreading) observed in concentrated (ionic strength, IS = 0.1) KCl and CsCl solutions. At low IS (0.02), ion-specific effects seem to be mainly associated with changes in the solvation environment of calcium ions in solution. With increasing electrolyte concentration, the stabilization of surface water by weakly paired salts appears to become increasingly important in determining step spreading rate. At high ionic strength (IS = 0.1), overall calcite growth rates increased with increasing hydration of calcium in solution (i.e., decreasing ion pairing of background electrolytes for sodium-bearing salts) and with decreasing hydration of the carbonate surface site (i.e., increasing ion pairing for chloride-bearing salts). Changes in growth hillock morphology were observed in the presence of Li⁺, F⁻ and , and can be interpreted as the result of the stabilization of polar surfaces due to increased ion hydration. These results increase our ability to predict crystal reactivity in natural fluids which contain significant amounts of solutes.     

Friction on a granite to granite interface

Summary Direct shear tests were conducted on a granite to granite interface for the purpose of tracing the evolution of frictional resistance as the initially smooth and polished surface wears during continuing shearing displacement. At the moment when sliding on the freshly manufactured interface starts (first slip), the friction angle is very low, between 15° and 20°, but then it increases with displacement rapidly without reaching a peak in the first test (maximum displacement less than 25 mm). Upon repeated shearing of the same surface (without re-finishing), this process of displacement-strengthening continues until a total accumulated displacement of about one half of one meter is reached. At this point, the angle of friction would typically be between 42° and 44°.Once the residual surface was established, the effect of time-related parameters, the duration of stationary contact under constant normal and shear load and variable displacement rate, were investigated. The frictional resistance is shown to increase with decreasing displacement rate and to increase with the duration of stationary contact.At a normal load greater than about one half of one MPa, shear displacement on a residual surface proceeds in an unstable, stick-slip manner. The change from stable to unstable sliding, that can be effected by either decreasing the sliding velocity or increasing the normal load, is not instantaneous, but occurs over a finite amount of displacement.     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.     

地下工程衬砌与减震层接触面力学特性直剪试验及数值仿真

泡沫混凝土作为隧道减震材料在抵抗地震压剪荷载方面具有重要作用,为了研究减震层-衬砌接触面在地震压剪荷载作用下的破坏特征与剪应力演化规律,利用RMT-150C电液伺服试验机开展了二者接触面在不同法向应力下的直剪试验,获得了剪应力-剪切位移、峰值强度、残余强度、剪切刚度的变化规律及接触面的破坏特征和物态变化。根据有限元模拟结果,探究接触面上剪应力的分布及演化规律。研究表明：泡沫混凝土-衬砌接触面的破坏特征受法向应力与泡沫混凝土密度共同影响,其剪应力-剪切位移曲线形态可归结为3种类型,且随泡沫混凝土密度和法向应力的变化可以相互转化;泡沫混凝土密度及法向应力对接触面峰值强度、残余强度及剪切刚度的影响是相互的,且法向应力的影响权重较大。根据剪应力-剪切位移曲线的变化规律,提出了复合指数模型来反映泡沫混凝土-衬砌接触面在压剪作用下损伤演化及摩擦滑移过程,研究结果可以为更加有效的抗减震设计提供一定参考。     

混凝土桩-泥皮-砂土接触面力学特性试验研究

为研究泥皮、粗糙度对桩-土接触面力学特性的影响规律,根据灌注桩成孔后的孔径-深度曲线,应用统计分析法获得了桩侧凸出尺寸和粗糙度的分布频率规律,以此构建了表面光滑和梯形凹槽混凝土板来模拟实际桩侧表面粗糙度。在此基础上,开展了不同泥皮厚度、粗糙度条件下的混凝土-砂土接触面大型直剪试验。其研究结果表明：无泥皮条件下粗糙接触面,其剪切应力-切向位移关系曲线呈软化型;泥皮厚度为5、10 mm条件下,呈硬化型。剪切模量G0.02随泥皮厚度增加而衰减。对光滑混凝土板,其接触面峰值剪切强度和峰值摩擦角随泥皮厚度的增加呈指数关系衰减;对粗糙混凝土板,峰值剪切强度和峰值摩擦角随泥皮厚度的增加近似呈线性衰减。初始泥皮越厚,试验后的泥皮土和泥皮越厚,接触面剪切强度越低。无泥皮条件下粗糙度对接触面峰值剪切强度的影响规律：存在一个临界粗糙度Icr =10 mm,当混凝土板的粗糙度I< Icr时,接触面峰值剪切强度和峰值摩擦角随粗糙度的增大而增大;当I≥Icr时,二者随着接触面粗糙度的增大而减小,泥皮存在会影响改变这一规律。