Integrated modelling for water quality management in a eutrophic reservoir in south-eastern Portugal

The Enxoé Reservoir was built in 1998. Since 2000, it has exhibited frequent high chlorophyll-a concentrations, reaching a geometric mean three times higher than the national limit for eutrophication, presenting the reservoir with the highest eutrophic state in Portugal. Toxic algal blooms have also often been observed, which pose serious challenges to water managers, as the reservoir is used for potable water production (25,000 inhabitants). The objective of this study was to implement a reservoir model (CE-QUAL-W2), with inputs from a watershed model (SWAT), in order to represent the actual reservoir state and to test management measures to reduce its trophic level and algal bloom concentration peaks. The integrated model was used to depict the origin of its trophic status. Simulations were also compared to measured data at the reservoir surface (water level, nitrate, orthophosphate, suspended solids, and oxygen) and in water profiles (temperature, oxygen). The model was able to represent stratification and thermocline depths, as well as the actual chlorophyll-a and dissolved oxygen concentrations. The model results showed that internal phosphorus load from deposited sediments was an important factor in fuelling the algal blooms. This process occurs predominantly in summer, when stratification takes place and aeration is reduced, promoting anoxic conditions in the bottom waters. Since the reservoir is relatively shallow (average 5 m), released phosphorus is then easily able to reach the photic zone in most parts of the reservoir, where it is consumed. Different management scenarios were tested, suggesting that a mesotrophic level could barely be reached and maintained simply by reducing the nutrient loads (both external and internal). It is suggested that only an increase in the reservoir dam height could produce a mesotrophic level, averting anoxia by blocking the release of phosphorus from sediments to the photic zone. Future work should focus on a cost–benefit analysis to test the feasibility of each of the proposed scenarios, taking advantage of the integration strategy to assess where in the watershed load reductions would be most effective.     

The water quality of Lake Taihu and its protection

Lake Taihu, the third largest fresh water lake of China, with a surface area of 2338 km², is located in the Changjiang River Delta, the most advanced economic zone in China. It is a typical saucer-like shallow lake in its depth and shape. During the last decade, the rapid economic development of local agriculture and industry both in the urban and rural areas of the Taihu region has made great advances. Great quantities of pollutants have been discharged into the lake, its nutrient content has increased continuously, and phytoplankton blooms have occurred in some areas. Water quality protection in Lake Taihu is very important because of its close relation with economic development and people's daily life. It is urgent to have comprehensive pollution control in Lake Taihu. Based on water quality monitoring data in Lake Taihu from 1986 to 1993, the dynamic variations of water quality and eutrophication trends have been analyzed, showing obvious spatial and temporal variations. The main water quality factors were compared with the standards for drinking water and indicate considerable change with the seasons. Basic strategies to protect water quality and prevent eutrophication are discussed.     

Interpretation and modelling of regional gravity data of the Aveiro Basin (Northwest Portugal)

The gravity map of the Aveiro Basin, North West Portugal was produced in 2000/2001 and some limited two dimensional (2D) interpretation was carried out. It is intended in this article to advance the interpretation and modelling of the original Aveiro basin gravity data. Thus, the data were processed and the horizontal gradient, the second vertical derivative and downward continued field computed. The corresponding maps have been processed and a new interpretation of the basin tectonic features has been proposed. This is compared with the previous geological and tectonic information obtained from former surveys and local boreholes. As the next step a more detailed modelling of the Aveiro Basin took place. Bearing the interpretation of the basin tectonic features in mind, several north–south and east–west gravity profiles were established and modelled. The proposed models were presented and discussed. As a result, a comprehensive mass distribution model for the basin was proposed. Finally, comparison was made between the new gravity model and the previously published tectonic features map. This modelling is particularly useful for groundwater protection, exploration and exploitation and also for the dimensioning of drilling operations. Bearing in mind the geomorphology of the basin the gravity method is a very economical tool for the investigation of basin structures.     

The 1909 Benavente (Portugal) earthquake: search for the source

The Lower Tagus River Valley has been affected by severe earthquakes comprising distant events, as in 1755, and local earthquakes, as in 1344, 1531, and 1909. The 1909 earthquake was located NE of Lisbon, near Benavente, causing serious damage and many losses. Mw 6.0 has been assessed for this earthquake and a reverse faulting focal mechanism solution has been calculated. Poor epicenter location, possible directivity and site effects, low fault slip rates, and the thick Cenozoic sedimentary cover make difficult correlation with regional structures. The focal mechanism indicates an ENE reverse fault as source, though it does not match any outcropping active structure suggesting that the event could have been produced by a blind thrust beneath the Cenozoic sedimentary fill. Hidden sources, inferred from seismic reflection data, are a possible NE structure linking the Vila Franca de Xira and the Azambuja faults, or the southern extension of the later. Evidence of surface rupturing is inhibited by the thick Holocene alluvial cover and the high fluvial sedimentation rate, though a slightly depressed area was identified in the Tagus alluvial plain W of Benavente which was investigated as possible geomorphic evidence of co-seismic surface deformation. A high-resolution seismic reflection profile was acquired across a 0.5 m high scarp at this site, and two trenches were opened across the scarp for paleoseismic research. Some deformation of dubious tectonic origin was found, requiring further studies.     

Monitoring of the groundwater chemical status in the Azores archipelago (Portugal) in the context of the EU water framework directive

A main challenge associated to EU Water Framework Directive corresponds to groundwater monitoring, both quantitative and chemical. The need for monitoring was also stressed by the Azores Water Plan. Monitoring of the chemical status of groundwater in Azores started in 2003 and has been progressively enlarged to all islands, totalizing 72 springs and 32 wells. A large number of parameters are analysed biannually, as major, minor and trace elements, pesticides and total hydrocarbons, as well as microbial indicators. Spring waters are mainly from HCO₃–Na type; instead water from wells is predominantly from the Cl–Na type, been differences attributed to their respective hydrogeologic framework. Springs discharge mainly from perched-water bodies, been influenced mainly from CO₂ in soils, silicate weathering, and seawater spraying and aerosols. Wells are in basal bodies, therefore subject to seawater intrusion influence, and 9% of Cl analyses made in wells exceed the standard value. Heavy metals, metalloids, hydrocarbons and pesticides all comply with standard values. Agriculture pollution also influences groundwater quality, as revealed by both NO₃ and PO₄ content, been the guide value exceeded respectively in 8 and 9% of the analyses. Despite the discontinuous variation of coliforms over time microbial indicators present an impact on water quality.     

A water quality model for the Patuxent estuary: Current conditions and predictions under changing land-use scenarios

A water quality model was developed for the Patuxent estuary using the modeling framework CE-QUAL-W2 (called W2) to address the impact of current and projected land-use changes (stress) on the water quality. The W2 code, supported by the Army Corps of Engineers Waterways Experiment Station, is a two-dimensional (longitudinalvertical) model designed for hydrodynamic and water quality simulations of reservoirs and estuaries. The code was configured for the Patuxent estuary using a finite-difference grid for the water column. Also incorporated into the model calculations are flow and nutrient load results from a watershed model. The integrated model was calibrated with data of 1 yr from 1997 to 1998 by matching results with measured temperature, dissolved oxygen, chlorophylla, and nutrient levels in the water column. The calibrated model was used to predict the water quality effects of different watershed land-use scenarios. Model projection results suggest that reductions of nutrient loads would lead to improvement of anoxic conditions in the bottom waters of the lower Patuxent estuary.     

Modern sediments and sedimentary processes in Lake Rudolf (Lake Turkana) eastern Rift Valley, Kenya

Tertiary sediments around Lake Rudolf (now Lake Turkana) in the East African Rift Valley have yielded abundant palaeontological and palaeoanthropological remains. The present study provides a basis for interpreting the ancient lake environment and furthering our knowledge of rift valley lacustrine deposits. Bottom sediments in Lake Rudolf are fine-grained (average 71% clay) well laminated and have montmorillonite, kaolinite and illite as the principal clay minerals. The sediments are relatively poor in silica (40–45%) but rich in Fe₂O₃ (10%). Both mineral proportions and chemical composition change systematically over the area of the lake and delineate four sedimentological provinces: (1) iron-rich, silty kaolinitic muds (Omo Delta); (2) iron-rich, fine-grained montmorillonite muds (North Basin); (3) silty montmorillonite muds rich in Na₂O and K₂O (Central Delta); and (4) argillaceous calcite silts (South Basin). Omo Delta and North Basin sediments are derived from the volcanics of the Ethiopian plateau; the source of Central Delta sediments is the Precambrian metamorphic terrain of the rift valley margin; the South Basin has a restricted detrital input. The water in the lake is alkaline (pH 9.2) and moderately saline (TDS = 2500 p.p.m.). Comparisons with influent water from the Omo River indicate a 200-fold concentration for the lake water. Models based on equilibrium between sediments and water column account for most of the non-conservative chemical components in the lake water. Sedimentation rates are high (about 1 m per 1000 years) and the dominance of detrital sediments makes Lake Rudolf unusual in comparison with other closed-basin lakes in the African Rift Valley although some similarities with ancient rift valley deposits are suggested.     

Lake water quality assessment: a case study of Shahu Lake in the semiarid loess area of northwest China

A comprehensive assessment on lake water quality was carried out in Shahu Lake, northwest China, to provide valuable information about present lake water quality for decision making. Major ions, general parameters, bacteriological parameters, organics and trace metals monitored monthly in 2014 were considered. Monitored parameters were compared with quality criteria for surface water of China, and overall water quality assessment was carried out using an entropy weighted water quality index (EWQI) based on 20 selected parameters. Lake water quality was also assessed for irrigation purpose. The results show that the lake water is of Cl·SO₄–Na facies with high salinity and COD. The geochemistry of the lake water is regulated by intense evaporation and human activities. TP, TN and F^? are major inorganic contaminants, with over 50% of the water samples polluted by them. Oil, mainly attributed by leaky motor tourist boats, is the major organic pollutants in the lake water, with 10 samples (37.04%) showing higher oil content than the permissible limit. The concentrations of other inorganic and organic contaminants as well as trace metals are well below the permissible limits. The present study indicates that inorganic contamination in the lake water is more severe than organic pollution. The overall lake water quality, assessed by EWQI, is poor and very poor with SO₄ ^2?, TDS, TH and Cl^? being the dominant contributing factors. The lake water is suitable for irrigation in terms of alkalinity, but is unsuitable for irrigation from the salinity point of view. Accelerating the circulation and replenishment of the lake water is an important way of reducing contaminant concentrations. This study is important in providing comprehensive information on lake water quality for decision makers and valuable reference for international lake water researchers.     

Urban groundwater quality in sub-Saharan Africa: current status and implications for water security and public health

Groundwater resources are important sources of drinking water in Africa, and they are hugely important in sustaining urban livelihoods and supporting a diverse range of commercial and agricultural activities. Groundwater has an important role in improving health in sub-Saharan Africa (SSA). An estimated 250 million people (40% of the total) live in urban centres across SSA. SSA has experienced a rapid expansion in urban populations since the 1950s, with increased population densities as well as expanding geographical coverage. Estimates suggest that the urban population in SSA will double between 2000 and 2030. The quality status of shallow urban groundwater resources is often very poor due to inadequate waste management and source protection, and poses a significant health risk to users, while deeper borehole sources often provide an important source of good quality drinking water. Given the growth in future demand from this finite resource, as well as potential changes in future climate in this region, a detailed understanding of both water quantity and quality is required to use this resource sustainably. This paper provides a comprehensive assessment of the water quality status, both microbial and chemical, of urban groundwater in SSA across a range of hydrogeological terrains and different groundwater point types. Lower storage basement terrains, which underlie a significant proportion of urban centres in SSA, are particularly vulnerable to contamination. The relationship between mean nitrate concentration and intrinsic aquifer pollution risk is assessed for urban centres across SSA. Current knowledge gaps are identified and future research needs highlighted.     

Suspended sediment transport,sedimentation, and resuspension in Lake Houston,Texas: Implications for water quality

Lake Houston is a man-made reservoir located northeast of Houston, Texas. The purpose of this investigation was to document suspended sediment transport, sedimentation, and resuspension in the lake with a view towards estimating the influence of sedimentation on water quality. Sediment traps were placed in strategic locations in the lake to collect suspended sediments. Samples were analyzed for bulk density, grain size, organic carbon, and a number of trace elements. These data were analyzed along with meteorological data to examine those factors which regulate suspended sediment input and dispersal, and the role of suspended sediments in controlling water quality within the lake. Sediment input to the lake depends primarily on the intensity of rainfall in the watershed. Sediment movement within the lake is strongly influenced by wave activity, which resuspends sediments from shallow areas, and by wind-driven circulation. The increased residence time of suspended sediments due to resuspension allows greater decomposition of organic matter and the release of several trace elements from sediments to the water column. Virtually all samples from sediment traps suspended between 1 and 5 m above the lake bottom contain medium to coarse silt, and even some very fine sand-sized material. This implies that circulation in Lake Houston is periodically intense enough to transport this size material in suspension. During winter, northerly winds with sustained velocities of greater than 5 m/sec provide the most suitable condition for rapid (<1 d) transport of suspended sediment down the length of the lake. Fluctuations in current velocities and the subsequent suspension/deposition of particles may explain variations in the abundance of coliform bacteria in Lake Houston.     

Correlations between algae and water quality: factors driving eutrophication in Lake Taihu, China

Rapid population increase and economic growth in eastern China has lead to the degradation of many water bodies in the region, such as Lake Taihu, the third largest freshwater lake in China. Using data from recent investigations, the correlations between algae (measured as chlorophyll-a) and water quality indices in Lake Taihu were described by multivariate statistical analyses, and the key driving factors for the lake eutrophication were identified by principal component analysis. Results revealed strong spatiotemporal variation in the correlations between algae and water quality indices, suggesting that the limiting factor for the dominant algae growth depends on seasonality and location and it is necessary to reduce both nitrogen and phosphorus inputs for a long-term eutrophication control in this hyper-eutrophic system. Water temperature was another important controlling factor for algal growth in the lake. Using principal component analysis, nutrient contaminations from anthropogenic and natural inputs were identified as the key driving factor for the water quality problems of the lake. Moreover, five principal components were extracted and characterized with high spatial and seasonal variations in Lake Taihu. The key driving factors were believed to influence spatial variations including heavily polluted areas located in the northern and northwestern parts of the lake, where many manufacturing factories were built and wastewater from domestic and industrial plants was discharged. Based on this analysis, attention should be paid to effective land management, industrial wastewater treatment, and macrophytic vegetation restoration to reduce the pollutant loads and improve water quality. Principal component analysis was found to be a useful and effective method to reduce the number of analytical parameters without notably impairing the quality of information in this study.     

Perched lobe formation in the Gulf of Cadiz: Interactions between gravity processes and contour currents (Algarve Margin, Southern Portugal)

The Gulf of Cadiz is swept by the strong saline Mediterranean Outflow Water (MOW). On the Algarve Margin (South Portugal), this current has constructed fine-grained contourite drifts. This margin is dissected by the Portimao Canyon and three short channels that only incise the upper slope, and are absent on a terrace located at mid-slope depths along the Algarve Margin. High-resolution seismic profiles and sediment cores highlight the original architecture of the sedimentary deposits on this terrace. Coarse-grained lenticular chaotic bodies formed during major relative sea-level lowstands are intercalated within the drift. The lobate shape and sandy nature of the lenticular chaotic bodies and their location at the mouths of the three short channels suggest they are gravity-generated deposits that are perched on the middle continental slope.In the Gulf of Cadiz, the interaction between contour current and gravity processes is strongly controlled by climatic variations and relative sea-level changes during the late Quaternary. During cold periods when sea-level was low, erosion intensified on the continental shelf and the deepest part of MOW was active. Sediment was transported downslope through the channels and deposited on sedimentary lobes perched on the mid-slope terrace. During warm periods when relative sea-level was high, the supply of sediment from the shelf was shut off and the shallowest part of MOW was more active. Contourite drifts fill the channels and bury the sandy lobes.     

High-resolution monitoring of water temperature and oxygen concentration in Lake Murten (Switzerland)

Lake Murten is located in the Lake District in western Switzerland and so far, it has been poorly investigated. The Environmental Service of Fribourg (SEn) has monitored this lake once a month for several years by water profiles (water temperature, pH, dissolved oxygen, conductivity) at its deepest part. The SEn identified the stratification of water masses as one of the main causes for oxygen consumption in the hypolimnion. In the present study, a Lander System was deployed in Lake Murten from April to September 2015 at 20 m depth at the northwestern part of the lake to monitor water temperature and dissolved oxygen at higher resolution (30 s interval). These records were compared with time series of atmospheric parameters like atmospheric temperature, wind speed and precipitation. A clear correlation of lake temperatures with wind speed was observed during the Spring and Autumn. The water mass stratification evolved through the season and reached its peak during Summer, preventing surface turbulences to reach the deeper part (20 m) of the water column and to partially oxygenate the metalimnion.     

Assessment of future trends on groundwater quality in a nitrate vulnerable zone (Esposende–Vila do Conde sector,NW Portugal): towards a combined conceptual and mass transport modelling

Hydrogeology Journal - Nitrate contamination of groundwater is an important public health issue worldwide. For environmental and public health reasons, water should not contain more than...     

Impact of transferred water on the hydrochemistry and water quality of surface water and groundwater in Baiyangdian Lake,North China

The hydrochemical composition of surface water and groundwater is a key parameter for understanding the evolution of water and its quality.In particular, little is known about the impact of transferred water on surface water and groundwater.In this study, Baiyangdian Lake was selected as a typical area for extensive groundwater exploration and surface water transfer in the North China Plain.Surface water and groundwater samples were sampled in dry/wet seasons and then analyzed before/after the water transfer, respectively.Generally, surface water and groundwater are extensively hydrologically connected based on hydrochemical evidence.It was found that the hydrochemical composition of the shallow groundwater is affected by the surface water and that the water quality of the deep groundwater is stable.However, inter-aquifer recharge processes from the shallow groundwater to the deep groundwater existed in the anthropogenic region impacted with high nitrate-ion concentrations.Also, the hydrochemical composition of the surface water and groundwater was dominated by rock-weathering and evaporation-precipitation processes.Due to the existence of the deep vadose zone in the alluvial fan, Na~+was exchanged into soil matrices during the leakage of the surface water.In addition, the transferred water resulted in surface water with good quality, and it also played as an important recharge source to groundwater.As the most important water resource for irrigation and drinking, deep groundwater should be paid more attention in the alluvial fan with frequent water transfer and extensive groundwater exploration.     

Recharge,geochemical processes and water quality in karst aquifers: Central West Bank,Palestine

The Central West Bank aquifer (CWB) is one of the most important resources of fresh groundwater of Palestine. The geology of the area consists mainly of karstic and permeable limestones and dolomites interbedded with argillaceous beds of late Albian–Turonian age. Exploitation of the CWB aquifer, combined with lack of information required to understand the groundwater pattern, represents a challenge for reservoir management. The present work reports hydrogeochemistry, microbiology and environmental isotope data from spring water samples, which were utilized to understand recharge mechanisms, geochemical evolution and renewability of groundwater in CWB aquifer. Besides the major chemical compositions, ionic ratios were used to delineate mineral-solution reactions and weathering processes. Interpretation of chemical data suggests that the chemical evolution of groundwater is primarily controlled by (1) water–rock interactions, involving dissolution of carbonate minerals (calcite and dolomite), and (2) cation exchange processes. The measured equation of the local meteoric water line is δD?=?5.8 δ¹⁸O?+?9.9. Stable isotopes show that precipitation is the source of recharge to the groundwater system. The evaporation line has a linear increasing trend from south to north direction in the study area. All analyzed spring waters are suitable for irrigation, but not for drinking purposes. The results from this study can serve as a basis for decision-makers and stakeholders, with the intention to increase the understanding of sustainable management of the CWBs.     

Treatment of Acid Mine Drainage (AMD) in South Brazil: Comparative active processes and water reuse

This work describes AMD techniques of neutralization, with lime, flocculation of the precipitates and comparative flocs/liquid separation by flotation with microbubbles or by lamellar settling (LS). The AMD treated water was characterized by its quality for recycling in terms of inorganic or organic elements, suspended or dissolved solids, among others. Two types of flocs were formed, “aerated” or not, in a special flocculation reactor, patented by this research group (RGF^®). Aerated flocs formed (within seconds) entered into contact with microbubbles under high shearing and raised-up at rates > 120 mh^− 1 allowing a rapid solid–liquid separation by flotation (HR-high rate), at about 13–15 m³m^− 2 h^− 1 loading capacity. Conversely, the non-aerated flocs settled at about 5–6 m h^− 1 in a lamella settler. Both AMD treatment techniques showed similar efficiencies (removal of ions > 90%) but the separation by lamella settling presented advantages, namely less reagents (no flotation collector required), lower power requirements and easier to operate. The operating costs (approximate values) of the AMD treatment by LS at pH 9 reaches about 0.3 US$ m^− 3 against 0.6 US$ m^− 3 for the HR-flotation process. Results found were proved to be similar to those found in recent ADM treatment installations in South Brazil. The quality of the treated water is fairly good, nearly free of heavy metals ion, low BOD (biological oxygen demand) and TOC (total organic content), low solids content and may be readily reused for irrigation, industrial processes and as wash water (among others, streets, vehicles, dust control). However, there is a need to extend the use of this treated water resource, but this, at least in Brazil, has not been legislated properly. It is concluded that this research will contribute in the discussion of this old and complex problem in acid mining effluents worldwide.