四川盆地东部三叠纪含钾岩层古地磁及物性研究

在四川合川地区沥鼻峡部面上进行了古地磁和岩石物性的研究工作,样品采自三叠系须家河组、雷口坡组、嘉陵江组和飞仙关组.共采集手标本500余块,对2200个样品测定了剩余磁化强度及方向、磁化率和密度.对样品进行了热退磁和交变退磁处理,并对部分样品作了镜下签定,确定了该区主要沉积岩石的磁性矿物是磁铁矿和少量磁黄铁矿.根据古地磁测量结果可知,四川盆地三叠纪时远离赤道由南向北漂移,在早三叠世时的古纬度为北纬18.72°附近,随后到达北纬26.68°附近,且后者相对于前者顺时针转动了30°.在此期间还发生了垂直升降作用.这些资料表明,本区在三叠纪时处于有利于成盐的中低纬度地区.我们还依据综合岩石物性资料,划分了本区的岩层.合川剖面的研究结果表明,将古地磁和岩石物性研究用于探讨盐矿生成环境,进行地层对比是非常有用的手段,应该得到广泛的应用.     

黄河下游鲁北平原地下水砷浓度空间变异特征与成因

依据2006—2009年间采集的区内1092件浅层地下水无机分析和现场测试数据,采用地统计学分析方法,分析了黄河下游冲积平原地下水中砷的空间变异特征及在人类活动影响下的污染现状。全区26.65%的样品砷含量超过饮用水标准,超标区域面积占全区总面积的17.3%。浅层地下水中砷的统计特征表明砷的离散程度和变异系数均较高;空间变异特征显示砷在空间上的分布各向异性,砷含量分布差异与地下水流向关系不密切,不同浓度的分布主要受原生条件和污染源的影响;区内约7%的浅层地下水样品砷的浓度由人类活动影响形成,其中12%的砷污染样品源于养殖场砷污染,养殖场内浅层地下水砷检出率、超标率均为全区的2倍;砷污染源包括农村分散养殖场牲畜废弃物排放、含砷农药的施用、工业污水的不达标排放等。     

广西来宾蓬莱滩剖面中上二叠统硅质岩的地球化学特征及沉积背景

广西来宾地区中上二叠统广泛发育硅质岩,蓬莱滩剖面和铁桥剖面是本地区中上二叠统出露最好的剖面.本文对蓬莱滩剖面28件硅质岩(分别为中二叠统茅口组3件与上二叠统合山组25件)的主量和稀土元素进行了分析研究,并结合岩石学特征,认为:蓬莱滩剖面合山组硅质岩沉积于受到陆源物质影响的边缘海盆环境,它们的硅质主要来源于硅质生物,为生物成因;而其茅口组硅质岩则沉积于远离陆源物质影响的边缘海盆环境,它们的硅质主要来源于热液,为热液成因.通过与铁桥剖面的热液成因硅质岩的沉积背景对比研究,结果表明:中晚二叠世时期,来宾地区为富硅的边缘海盆环境,而陆源物质输入程度的差异是造成本地区形成不同成因硅质岩的主要因素.     

因子分析在地球化学数据处理中的应用

因子分析是一种多元统计分析方法,以往地质研究中常用其解决复杂的地质成因及矿化叠加问题。本文利用R型因子分析对岷县寨上-马坞调查区的1:20万水系沉积物样品数据进行处理,计算因子得分,圈定因子得分异常图,并与区内的各种地质作用相联系,取得了一定的效果;利用R-Q型因子分析对寨上及附近的原生晕样品进行分析,通过对矿体及构造带样品的分析,可以划分矿化类型;通过对地层样品的分析,可以划分地层并得出各地层的特征组合元素。因此利用因子分析可以为地球化学数据解释提供重要信息。     

重庆中梁山岩溶槽谷区表土孢粉与现代植被的关系研究

本文选取重庆中梁山岩溶槽谷区的表土和苔藓样品做孢粉分析,探讨其与现代植被的关系,并初步推断中梁山岩溶洼地的花粉来源,为其洼地剖面花粉来源提供参考。结果表明:表土花粉组合与现代植被类型具有较好的对应关系,耕地、撂荒地、灌木丛、马尾松林以及竹林能够较好地反映母体植被的群落组成;混交林与母体植被群落对应关系较差。由于洼地对区域花粉的汇聚作用,其表土花粉谱更能反映整个区域的植被状况。洼地表层样品中松属花粉来源是中梁山地区与西南风区域的花粉;落叶栎属、桤木属、枫杨属、葎草属等的主要来源是周围山地;禾本科花粉来源相对复杂。本研究可为在这一地区利用孢粉学开展第四纪古植被、古气候和古环境等研究提供参考性依据。      

基于模糊神经网的油气综合评判方法研究

针对常规模式识别方法进行油气预测时,存在样本数量大、参数非线性及已知样本数类型分类有明显的模糊性等特点。本文根据神经网络的自适应谐振理论（ＡｄａｐｔｉｖｅＲｅｓｏｎａｎｃｅＴｈｅｏｒｙ）结合模糊Ｋ均值聚类算法、特征参数非线性映射的有效性校验,构成了一个性能完善的地震参数油气预测系统。该系统对样本特征空间用模糊神经网络建立未知样本的预测度量,更加符合客观地质特征和油气分布规律,从而能判别油气富集的有利区域。数值分析和实践应用表明,该方法数值稳定可靠,在储层油气预测方面有较好的效果     

中国花岗岩类和世界花岗岩类平均化学成分的对比研究

中国花岗岩类的出露面积,约占我国陆地总面积的10％。依据12265个样品求出中国花岗岩类的总平均化学成分;并结合Daly,Nockolds和Beyc等花岗岩类样品,近似地求出世界花岗岩类的总平均化学成分。以此为背景,显示出中国花岗岩类富SiO2、Na2O和K2O的区域特征。     

东南极格罗夫山地区铷含量初步调查及手持矿石分析仪的可行性研究

本文对东南极格罗夫山地区出露的基岩样品进行实验室地球化学分析,结果显示出该地区明显的铷元素富集。所测试的123个样品主要为花岗岩、闪长岩、花岗片麻岩、片麻岩等,其中15个样品的铷含量达到0.04%,2个样品的铷含量达到0.1%以上。同时,利用手持快速矿石分析仪(NITON XL3t-500S GOLDD)对该地区213件岩石样品以及92件粉末样品进行测试,并将测试结果与实验室分析结果进行对比分析。分析对比发现,虽然手持快速矿石分析仪相对实验室测试存在一定误差,但是两种测试方法的铷含量随样品表现出一致的变化趋势,且粉末样品相对岩石样品误差明显偏小。     

依据化探成果对东昆仑地质背景的讨论

在东昆仑地区 6 0 0 0 0多km2 的地域内 ,按照 4km2 的采样单元 ,共采集了 15 0 0 0多件水系沉积物样品。按照 16km2 的网格加工成 4 0 0 0多件组合样后 ,定量分析了 4 0种微量元素的含量。在对这些数据进行数学处理的基础上 ,利用斜交因子的分析结果 ,讨论了东昆仑地区的区域地层、断裂构造和中酸性岩浆岩的特征。根据区域地球化学成果 ,进一步明确了昆中、昆南断裂对本区地层和侵入岩分布的控制作用。基于元素区域地球化学背景的对比 ,提出了昆中断裂应向东延伸的证据 ,并指出了东大滩、布青山两个地区经历了相似的地质 地球化学作用     

Geochemistry and origin of rare earth elements (REEs) in the Shengli River oil shale, northern Tibet, China

The Shengli River-Changshe Mountain oil shale zone, located in the North Qiangtang depression, northern Tibet plateau, represents a potentially large marine oil shale resource in China. Twenty-eight samples including oil shale, micritic limestone and marl were collected from the Shengli River area to determine the contents and distribution patterns of rare earth elements (REEs) in marine oil shale. Oil shale samples from the Shengli River area have high ash yield (61.86–67.48%) and TOC content (8.02–13.67%) with low total sulfur (S_t,d) content (0.76–1.39%) and intermediate shale oil content (3.60–16.30%). The total rare earth element (ΣREE) content in oil shale samples is notably depleted (46.79–67.90 μg/g), approximately one third of the mean value of the North American Shale Composite (NASC), and lower than that of world-wide black shales and Chinese coals, but higher than that of world-wide coals and micritic limestone samples (29.21 μg/g) from the Shengli River area. The oil shale samples from the Shengli River area exhibit shale-like Chondrite or NASC-normalized REE patterns similar to those of micritic limestone and marl samples from this area, indicating that REEs of these different lithological samples may have been derived from a similar terrigenous source.REE contents of oil shale samples are highly positive correlated with ash yield and show a positive correlation with Fe and a weakly positive correlation with organic sulfur, and the vertical variations of REEs mainly follow those of Si, Al, K and Ti. All these facts indicate that the REE contents in oil shale seams are mainly controlled by clay minerals and, to a lesser extent, by pyrite, as well as partly associated with oil shale organic constituents. Rare earth elements in the Shengli River oil shale have originated from two sources: a felsic volcanic rock source and a clastic or/and limestone source.     

三峡小江回水区真光层深度及其影响因素分析

为探讨三峡水库运行初期小江回水区水体的光学特性,2007年5月~2008年5月对回水区5个断面水下光合有效辐射(PAR)与常规水质指标进行监测,分析了真光层深度的时空特征及其影响因素.研究区域真光层深度空间差异不明显,但季节变化显著,冬季最高,夏季最低.回归分析表明光合有效辐射(PAR)衰减系数与透明度、总悬浮物浓度有显著的相关性(R2=0.861 9,R2=0.764),与叶绿素a相关性不明显(R2=0.011 3).进一步研究分析表明真光层深度、总悬浮物浓度、叶绿素a主要受小江河口流量、小江回水区水位的影响,复杂的水动力条件与独特的水文条件是影响三峡水库小江回水区真光层深度变化的主要因素.     

一种绢云母样品的综合鉴定分析

运用X射线衍射、差热分析以及扫描电子显微镜等现代分析测试技术，对某地绢云母矿样品进行了综合分析，查明了该样品中矿物组成；证明样品中的粘土矿物成分是绢云母，而不是伊利石，为更好地对该绢云母资源进行开发利用提供了可靠的依据。     

鄂尔多斯白垩系地下水盆地硫酸盐的水文地球化学特征及来源

鄂尔多斯白垩系地下水盆地蕴藏有丰富的地下水资源,地下水赋存于白垩系砂岩中。为了查明地下水微咸水的成因,对40件地下水样品的水化学组成、SO42-的区域分布特征和28件硫同位素组成进行了分析,并对34件岩石样品进行了溶滤试验研究。结果表明:SO42-是地下水中主要阴离子组分,具有东部低西部高,北部低南部高的区域分带特征;硫酸盐是白垩系地层中主要的易溶盐组分,并以石膏和芒硝形式存在;地下水中SO42-主要来源于地层中石膏和芒硝,其次是地层中的硫化物,少量来源于有机硫。     

Environmental Isotopic Characterization of Groundwater and Surface Water in Northeast Missan Province,South Iraq

The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq.Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011–2012.The study shows that most of the groundwater in the aquifer falls above the global meteoric water line,and all the samples fall below the Mediterranean meteoric water line,indicating that these samples are a mixture of two water types.The tritium content of these samples supports this conclusion.The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area:the ephemeral streams(Teeb and Dewerge) and major precipitation sources.According to the tritium levels at or below one tritium unit(TU) obtained from the water,supply wells are highly confined or "not vulnerable".Overall,the 3H results imply that recent recharge has taken place during the last four to five decades.In the recharge area,the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff.Therefore,the groundwater resources in the study area should be protected from contamination,because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.     

Geochemistry and stable isotopic signatures,including chlorine and bromine isotopes,of the deep groundwaters of the Siberian Platform,Russia

The chemical composition and the isotopic characteristics of formation waters from the Siberian Platform are presented. The study involved samples of formation brines from depths ranging from 100 to ∼4000 m at five different sites covering a large area of the Siberian Platform. Four water types were identified. The two main water types that were found are: (1) Ca–Cl brines that are believed to be the residual of an evaporated paleoseawater; and (2) Na–Cl brines that are derived mainly from halite dissolution. The origin of a third group of highly saline samples was not determined. However, the chemical and isotopic characteristics of this group of samples suggest that they were produced by various complex scenarios such as metamorphism, water–rock interaction, permafrost freezing and mixing. The last group of samples represents fresh and brackish waters across the area.     

Quantification of mineral dissolution rates and applicability of rate laws: Laboratory studies of mill tailings

Reliable quantification of mineral weathering rates is a key to assess many environmental problems. In this study, the authors address the applicability of pure mineral laboratory rate laws for dissolution of mill tailings samples. Mass-normalised sulfide and aluminosilicate mineral dissolution rates, determined in oxygenated batch experiments, were found to be different between two samples from the same ∼50-year-old, carbonate-depleted mill tailings deposit. Consideration of difference in particle surface area and mineralogy between the samples resolved most of this discrepancy in rates. While the mineral surface area normalised dissolution rates of pyrite in a freshly crushed pure pyrite specimen and a sulfide concentrate derived from the tailings were within the range of abiotic literature rates of oxidation by dissolved molecular O₂, as were rates of sphalerite and chalcopyrite dissolution in the tailings, dissolution rates of pyrite and aluminosilicates in the tailings generally differed from literature values. This discrepancy, obtained using a consistent experimental method and scale, is suggested to be related to difficulties in quantifying individual mineral reactive surface area in a mixture of minerals of greatly varying particle size, possibly due to factors such as dependence of surface area-normalised mineral dissolution rates on particle size and time, or to non-proportionality between rates and BET surface area.     

13X沸石分子筛的比表面积和孔分布

对利用钾长石粉水热合成的13X沸石分子筛分别进行了比表面积和孔分布测定。结果表明:13X沸石分子筛比表面积约为621.50~747.40 m²/g,总孔体积约为0.344 70~0.393 70 cm³/g;具有高比例且孔径小于2.50 nm的微孔,中-小型实验样品(SXZ-10g和SXZ-1kg)的微孔体积比例相近,为81.33%~84.70%,而扩大实验样品(SXZ-10kg)的微孔体积比例为67.90%~67.98%。13X沸石分子筛微孔的含量是决定13X沸石分子筛具有高比表面积和高效吸附性能的前提。     

竹山和马鞍山绿松石微量元素和稀土元素特征

对竹山和马鞍山两地绿松石的微量元素和稀土元素特征作了对比研究,同时分析了两地绿松石矿物特征和结构特征。采用X射线能谱、电感耦合等离子体质谱、X射线衍射、红外吸收光谱和扫描电镜等测试技术对竹山和马鞍山地区的绿松石样品进行岩石矿物学特征分析。结果表明,竹山与马鞍山地区绿松石在微量元素的含量上存在较大的差别,但主成分含量基本一致;两地区绿松石的稀土元素均富集重稀土,二者的稀土配分模式图出现镨反向,马鞍山地区的绿松石表现出铕负异常;马鞍山绿松石的结晶程度优于竹山县绿松石。该方法对绿松石产地划分的研究具有应用价值。     

Dust fallout characteristics within global dust storm major trajectories

Satellite images from 2000 to 2010 were used to identify major dust trajectories within seven major deserts in the world. The fallen dust from these trajectories were collected and analyzed. The fallen dust rates tend to be lower downwind. The average samples of the world's fallen dust are negatively skewed trimodal with dominancy of silt size fractions (61 %). Most of the fallen dust within major dust trajectories is fining downwind. The fallen dust from the eastern zones (Taklimakan, Gobi, and Australian deserts) are characterized by higher percentages of feldspars and clay minerals, low carbonate content, and grain surface area in comparison to the Western zones (Sahara and Arabian deserts). The Western Sahara Desert dust is differentiated by the highest depositional rates and average quartz percentage (66 %). The dust samples in this zone contain low carbonates and grain surface area compared to dust from the Eastern Sahara Desert. The dust samples within Northern Arabia and Ethiopian-south Arabia zones show the highest average of carbonate amounts and grain surface area.     

Analysis of platinum-group elements in drill core samples from the Meishan Permian-Triassic boundary section,China

There is a long-standing controversy of what triggered the extinction at the Permian-Triassic boundary, the most severe mass extinction in the geologic record, including flood basaltic volcanism and/or bolide impact hypothesis. In order to clarify various pieces of evidence for the mass extinction event at the Permian-Triassic boundary, some researchers from some laboratories throughout the world have made a comprehensive study on a group of samples from the Meishan area of China. Some fresh core samples from the Permian-Triassic boundary in the Meishan area were analyzed in this study. The results showed that there is no Ir anomaly, Moreover, the PGEs patterns of those samples show obvious differentiation characteristics, that is different from the case encountered in meteorites. So no evidence supports the hypothesis of extraterrestrial impact. In contrast, the PGEs patterns are similar to those of Siberian and Emeishan basalts, which indicates that those PGEs are derived mainly from the basalts, lending a support to the correlation between mass extinction at the Permian-Triassic boundary and flood basaltic volcanism. This study has also confirmed the results for samples from section C prior to the analysis of the samples.