南黄海和东海表层水两种粒级颗粒物和颗粒氮含量的分布特征

测定了南黄海和东海表层水0.7~53.0μm和〉53.0μm这2种悬浮颗粒物（SPM）、颗粒氮（PN）的含量.其结果表明,南黄海和东海表层水0.7~53.0μm粒级的SPM、PN平均含量分别为4.68 mg/dm3、18.50μg/dm3;而〉53.0μm粒级的SPM、PN平均含量分别为0.20 mg/dm3、2.65μg/dm3.0.7~53.0μm和〉53.0μm粒级的PN/SPM含量平均比值分别为0.78%、1.41%（m/m）,后者约是前者的2倍.统计分析结果表明,尽管这2种粒级的SPM、PN含量和PN/SPM含量比值的范围较大,但约80%的数据集中在较小范围内,即0.7~53.0μm和〉53.0μm粒级SPM含量分别集中在0.37~3.68、0.02~0.29 mg/dm3的范围内;0.7~53.0μm和〉53.0μm粒级PN含量分别集中在2.54~18.90、0.40~2.69μg/dm3的范围内;0.7~53.0μm和〉53.0μm粒级的PN/SPM含量比值分别集中在0.14%~1.00%和0.15%~1.95%之间.研究结果表明,研究海域0.7~53.0μm粒级SPM、PN含量有2个高值区,分别位于近岸海区和东海东北部海区.〉53.0μm粒级SPM、PN含量的分布分为2个部分：南黄海表层水SPM、PN含量分布呈从近岸向外海降低的趋势;而东海表层水SPM、PN含量分布呈断面中间高,并分别向近岸和外海降低的趋势.     

The decomposition rate of the organic carbon content of suspended particulate matter in the tropical seagrass meadows

In terms of downward transport, suspended particulate matter(SPM) from marine or terrigenous sources is an essential contributor to the carbon cycle. Within mesoscale environments such as seagrass ecosystems, SPM flux is an essential part of the total carbon budget that is transported within the ecosystem. By assessing the total SPM transport from water column to sediment, potential carbon burial can be estimated. However, SPM may decompose or reforming aggregate during transport, so estimating the vertical flux without knowing the decomposition rate will lead to over-or underestimation of the total carbon budget. Here this paper presents the potential decomposition rate of the SPM in seagrass ecosystems in an attempt to elucidate the carbon dynamics of SPM. SPM was collected from the seagrass ecosystems located at Sikka and Sorong in Indonesia. In situ experiments using SPM traps were conducted to assess the vertical downward flux and decomposition rate of SPM. The isotopic profile of SPM was measured together with organic carbon and total nitrogen content. The results show that SPM was transported to the bottom of the seagrass ecosystem at a rate of up to(129.45±53.79)mg/(m~2·h)(according to carbon). Considering the whole period of inundation of seagrass meadows, SPM downward flux reached a maximum of 3 096 mg/(m~2·d)(according to carbon). The decomposition rate was estimated at from 5.9 μg/(mg·d)(according to carbon) to 26.6 μg/(mg·d)(according to carbon). Considering the total downward flux of SPM in the study site, the maximum decomposed SPM was estimated 39.9 mg/(m~2·d)(according to carbon) and 82.6 mg/(m~2·d)(according to carbon) for study site at Sorong and Sikka, respectively.The decomposed SPM can be 0.6%–2.7% of the total SPM flux, indicating that it is a small proportion of the total flux. The seagrass ecosystems of Sorong and Sikka SPM show an autochthonous tendency with the primary composition of marine-end materials.     

Evidence for aggregate formation in a nepheloid layer and its possible role in the sedimentation of particulate matter

During cruise 73-A-3 of the R/V “Alaminos”, seawater samples from the nepheloid layer and overlying water were collected and filtered through 0.4 μm Millipore^® Ultra Thin filters for microscopic analysis with a Jeol JSM-U3 scanning electron microscope. The results of the studies of the suspended matter with the scanning electron microscope indicate that there is a significant increase in the percentage of the total number of particles that are associated as aggregates for the nepheloid layer relative to the overlying water. This suggests that once nepheloid layers are formed, they might represent regions of high sedimentation due to aggregate formation.     

Examples of spatial and temporal variations of some fine-grained suspended particle characteristics in two Danish coastal water bodies

In June and September of 1999, a LISST-100 in situ laser diffraction particle sizer was used to analyse the temporal and spatial variation of the beam attenuation coefficient, the in situ median particle (aggregate) diameter and the median volume concentration of suspended matter in two Danish coastal water bodies. One of the study sites was generally exposed to wind, while the other was quite sheltered. Measurements of the mass concentration of total suspended matter and chl a were made simultaneously. The in situ median effective density, settling velocity and vertical flux of the suspended matter are computed. Results demonstrate that in September, the in situ median aggregate diameter, settling velocity and vertical flux was smaller (by a factor of up to 16) and the concentration higher (by a factor of up to almost two) than in June. This is attributed to varying degrees of turbulence in the water in the weeks preceding the field work, causing aggregates to break up (lowering in situ aggregate diameter and settling velocity) and sediment to be resuspended (increasing concentration) in September. The fractal dimension of the suspended aggregates is estimated. The fractal dimension is found to increase from June to September at both study sites, supporting the notion of aggregate break-up in September due to turbulence in the upper part of the water column. An algae bloom occurred at the sheltered study site in September. In situ particle size spectra from this site demonstrated increasing aggregate sizes towards the bottom. It is suggested, that the increase in size is due to biologically induced aggregation, causing large aggregates to settle out of the upper part of the water column, leaving finer particles and aggregates behind.     

浙江近岸海域悬浮颗粒物中磷的赋存形态及分布特征研究

磷元素是海洋基础营养盐之一,其赋存形态及分布直接影响海区的初级生产力,是海洋生物地球化学循环的重要驱动力。但大河河口与近海等重要的水生关键带水动力循环过程复杂,导致悬浮颗粒物(SPM )中磷元素的赋存形态和分布特征变化多端,亟须深入研究。根据2016年春季(4−5月)、夏季(7月)和秋季(9−10月)对浙江近岸海域的调查结果,本研究分析了浙江近岸海域SPM中总磷(TPP)、无机磷(PIP)和有机磷(POP)的含量水平、空间分布特征和影响因素。结果表明,浙江近岸海域SPM中TPP含量范围为0.13～66.13 μmol/L,均值为3.35 μmol/L;PIP含量范围为0.03～34.19 μmol/L,均值为1.97 μmol/L;POP含量范围为0.06～31.94 μmol/L,均值为1.39 μmol/L。PIP是浙江近岸海域水体中TPP的主要存在形式,占52.3%。春季浙江近岸海域表层TPP含量占总磷(TP)含量的19.3%～97.7%。春、秋季的SPM中,TPP、PIP和POP含量空间分布相似,均呈现由内湾向外海逐渐降低的变化趋势。PIP、POP与SPM呈显著的正相关性,表现出高SPM含量的海区有着较高的颗粒态磷含量,说明其受陆源输入的影响。春季盐度大于28且SPM含量小于20 mg/L的外侧远海海域,POP与Chl a的相关系数和斜率均明显高于PIP与Chl a的相关系数和斜率,说明该区域浮游植物是POP的主要贡献来源。     

2013年夏季黄、渤海颗粒有机碳分布及来源分析

本文根据2013年夏季黄、渤海海域航次获得的颗粒有机碳(particulate organic carbon, POC)、叶绿素a(chlorophyll a, Chl a)和总悬浮颗粒物(total suspended particles, TSP)数据,结合同步获得的水文环境参数,综合探讨该区夏季POC时空分布特征,以及在不同温盐深水团中POC的主要影响因素。结果表明:在整个研究区POC的浓度范围为102.3～1850.0 μg/L,平均值为(383.7±269.6) μg/L,分布呈现出近岸高、远海低、表层低、底层高的特征。苏北外浅滩海域和北黄海东北区域的10 m层和底层为POC高值区,苏北外海域受到陆源输入、沿岸流混合作用和浮游植物光合作用的影响,POC上下混合均匀且浓度高;南黄海中部因受黄海环流的影响,水体中浮游植物生产力水平低,POC浓度较低。在垂直分布上,近岸海域受陆源输入和再悬浮影响POC浓度高,上下混合均匀;在南黄海和北黄海中部受到黄海环流和黄海冷水团的控制,浮游植物生产力水平低,POC浓度低。对不同温盐水团中POC的影响因素分析发现,在高温低盐水团中,POC受浮游植物初级生产和陆源输入的共同影响;在温盐适中区真光层海水中,浮游植物的初级生产是POC的主要来源;底层的冷水团区,POC主要来源为上层海水中颗粒物的沉降和底层再悬浮作用。     

夏季南黄海悬浮体粒度分布及其影响因素

南黄海是东亚海区陆源物质向西太平洋扩散的重要通道,阐明该海区悬浮体粒度特征及其分布规律对于深入揭示中国东部陆架海区源汇沉积体系形成机制具有重要意义。利用2012年夏季在南黄海调查获取的水文环境资料和悬浮体现场粒度（LISST）观测数据,分析悬浮体粒度分布特征及其影响因素,探讨其在南黄海中部泥质区成因机制中的作用。结果表明：夏季,南黄海悬浮颗粒中≤128 μm的细颗粒主要是由无机矿物颗粒组成,而＞128 μm的粗颗粒则由有机颗粒主导。无机颗粒主要分布在混合作用较强的近岸浅水区以及远岸的近底水层,有机颗粒在水体层化较强海域的密度跃层处占据主导地位。再悬浮的海底表层沉积物是海水中无机颗粒的主要来源,潮混合过程是引起再悬浮作用的主要动力因素。潮混合锋阻挡了近岸高浓度无机悬浮颗粒物沿近底层向远岸扩散,但跨锋面的表层离岸流可以将近岸区的部分无机细颗粒物输运至南黄海中部。密度跃层阻碍了冷水团内营养盐进一步向海表扩散,导致浮游植物在密度跃层处富集;大量浮游生物及其分泌物与细小的无机颗粒相结合形成絮集体是海水中＞128 μm粗颗粒的主要来源。絮集体的形成促进了表层无机细颗粒向海底沉降,促进了泥质区的形成。     

Vertical Patterns of Suspended Matter Characteristics Along a Coastal-basin Transect in the Western Baltic Sea

Suspended particulate matter samples were collected from the water column, the bottom nepheloid layer and the ‘ fluffy layer ’ from four stations along a coastal-basin transect in the Pomeranian Bight, western Baltic Sea. Sampling was performed nine times between October 1996 and December 1998 for various analyses, including electron probe x-ray micro analysis for detailed mineralogical investigations.Specific vertical patterns of clay mineral distributions were found. Suspended particulate matter (SPM) in the bottom nepheloid layer and the ‘ fluffy layer ’ overlying sediments was enriched in organic carbon and hydrated three layer clay minerals, whereas the non-aggregated SPM was dominated by quartz and biogenic opal. It appears that separation effects operate during aggregation of mineral particles and organic matter in repeated cycles of resuspension and settling. No clear seasonal variations in the composition of the SPM were found, in spite of high spatial and temporal variability of biological and physical variables. The results suggest that preferential incorporation, possibly aided by microbiological colonization, of hydrated three layer silicates into the organic flocs is a process that occurs under a wide range of conditions. Because aggregates sink faster than individual particles, aggregate formation led to a relative enrichment of illite and smectite in the near-bottom layers. Considering the affinity of organic contaminants and heavy metals to organic matter, the selective removal of aggregated organic matter and hydrated three-layer clay minerals from the water column and enhanced transport in the near-bottom fluffy layer may be a natural cleansing mechanism operating in the shallow waters of the bight.     

伶仃洋河口泥沙絮凝特征及影响因素研究

泥沙絮凝对河口细颗粒泥沙运动过程起着极其重要的作用。本文通过LISST-100激光粒度仪等仪器实测伶仃洋河口2013年洪季悬浮泥沙絮凝体现场粒径及水动力、泥沙条件,结合实验室悬沙粒径分析,研究大小潮期间伶仃洋河口泥沙絮凝特征,探讨紊动剪切强度、含沙量、盐度分层及波浪等因素对伶仃洋河口泥沙絮凝的影响。结果表明:伶仃洋河口水体中现场粒径平均值为148.53 μm,大于实验室悬沙分散粒径36.74 μm,河口絮凝现象明显;沉速与有效密度、粒径呈正相关,絮团平均有效密度为153.49 kg/m3,平均沉速达1.13 mm/s;小潮时絮团平均粒径大于大潮,垂向上表底层絮团粒径小、中层大,中底层絮团沉速大于表层。伶仃洋河口水动力、泥沙条件是影响其泥沙絮凝的重要因素,低剪切强度（小于5 s-1）、低含沙量（小于50 mg/L）及高体积浓度有利于细颗粒泥沙之间的相互碰撞,促进絮凝作用;当剪切强度与颗粒间碰撞强度高于絮团所能承受的强度时,絮团易破碎分解成小絮团或更细的泥沙颗粒;伶仃洋河口盐度层化引起的泥沙捕获现象增大中层泥沙体积浓度,有利于中层絮凝体的发育;观测期相对较大的波浪增强水体紊动,增大了水体细颗粒泥沙的碰撞几率,表层絮团粒径随波高峰值的出现而增大。     

Observations of Floc Sizes in a Muddy Estuary

Measurements are presented of median floc diameters and associated environmental data over spring-tide tidal cycles at two stations in the muddy Tamar Estuary, UK, for winter, spring and summer conditions. The particulate organic carbon and particulate total carbon contents of mudflats and SPM (suspended particulate matter) at the stations, together with other evidence, indicates that much of the SPM was derived from mud sources that were located between the two stations during winter and spring, and from very mobile sediment sources in the upper estuary during summer. Observed in-situ median floc sizes varied widely, from <50 to >500 μm and rapid settling of particles close to HW and LW (high and low water) left only the smaller flocs in suspension. Time-series of depth-averaged median floc sizes generally were most closely, positively, correlated with depth-averaged SPM concentrations. Floc diameters tended to reach maximum median sizes near the time when SPM concentrations were highest. These high concentrations were in turn largely generated by resuspension of sediment during the fastest current speeds. Although such correlations may have arisen because of SPM-driven floc growth - despite fast tidal currents - there is also the possibility that tough aggregates were eroded from the intertidal mudflats and mudbanks. Although a hypothesis, such large aggregates of fine sediment may have resulted from the binding together of very fine bed particles by sticky extracellular polymeric substances (EPS) coatings, produced by benthic diatoms and by other biologically-mediated activity. A rapid reduction of SPM occurred at the up-estuary station within 2.5 h of HW on the flood, when decelerating currents were still relatively fast. It appears that at least two processes were at work: localised settling of the largest flocs and up-estuary transport in which large flocs were transported further into the estuary before settling into the Tamar's ETM (estuarine turbidity maximum) over the HW-slack period. Up-estuary advection of large flocs and their eventual settling would place the down-estuary edge of the ETM above the upper-estuary station during summer, spring-tide conditions. This position of the ETM was observed close to HW during longitudinal surveys of the estuary.     

长江口及其邻近海域悬浮颗粒物浓度和粒径的时空变化特征

长江口是典型的高浊度河口,长江口及其邻近海域悬浮颗粒物（suspended particulate matter,SPM）浓度跨度大,泥沙过程活跃、复杂。2015年7月9-20日（洪季）和2016年3月7-19日（枯季）,使用OBS和LISST分别测定了该区域99个和89个站位的SPM浊度、光衰减系数、总体积浓度、平均粒径和粒径谱等参数;同时通过现场过滤测定了各站位表、中、底3层的SPM质量浓度以及典型站位SPM中颗粒有机碳（particulate organic carbon,POC）的δ13C、颗粒氮（particulate nitrogen,PN）的δ15N以及POC/PN摩尔比值。结果表明,浊度、光衰减系数、总体积浓度等3个参数均与SPM质量浓度显示出了显著的正相关关系。研究区域SPM平均粒径一般表层大于底层、枯季大于洪季;长江淡水端元输出的SPM粒径枯季也明显大于洪季。具有相似粒径谱特征的SPM可以通过测定δ13C和δ15N值来进一步区分其来源和组成。SPM质量浓度和总体积浓度等参数结合还可以计算SPM有效密度,用以了解研究区域SPM的沉降过程。结果表明两个季节SPM有效密度和粒径之间显示出了显著的负相关关系,说明枯季长江输出的SPM由于粒径大、密度小、沉降速度低,加之强烈的垂直混合和口门拦门沙附近的再悬浮,随着环流可能到达研究区域北部的最东端;而洪季长江输出的SPM由于粒径小、密度大、沉降速度高,在口门附近快速沉降。     

基于水淘选分级的长江口最大浑浊带附近颗粒有机碳的来源、分布和保存

从分粒级的角度研究大河河口颗粒有机碳的输送特征是深刻理解河口淡咸水混合过程中有机碳的生物地球化学过程的关键。于2011年6月采集了长江口最大浑浊带附近盐度梯度下的表层悬浮颗粒物,采用水淘选方法对其按照水动力直径大小进行了分级分离,分析了这些颗粒物的有机碳含量、稳定碳同位素组成及颗粒物比表面积等参数,讨论了不同粒级颗粒物上有机碳的来源、分布和保存随盐度的变化特点及其影响因素。结果表明,随着盐度的增加和粒径的增大,长江口最大浑浊带附近分级颗粒有机碳逐渐降低,颗粒有机碳含量主要集中在小于32μm的粒级。相对于长江干流,长江口颗粒有机碳含量偏低,可能归因于河口最大浑浊带附近特殊的生物地球化学作用,如细颗粒物絮凝——沉降、微生物分解等。基于蒙特卡洛模拟的三端元混合模型的计算表明长江口分级颗粒有机碳主要来源于河流和三角洲输入,海洋来源贡献较小,三者的平均贡献比例分别为40%、35%和25%。在河口盐度梯度的淡水端,不同粒级颗粒物上三角洲来源的有机碳比例均随着盐度升高而增加,而在咸水端,海源有机碳的贡献比例升高,尤其是在16-32μm粒级,最高达39%。32-63μm粒级的颗粒物单位比表面积有机碳含量均大于1.0mg/m~2,小于32μm的颗粒物单位比表面积有机碳含量均在0.4-1.0mg/m~2的范围之内,符合河流颗粒物的一般特点,同时也说明细颗粒物上的有机碳可能已经发生了一定程度的分解,不过相对于长江口表层沉积物,颗粒物单位比表面积有机碳含量普遍较高,表明这些颗粒有机碳在沉降过程中或沉积之后还要经历进一步的再矿化分解,初步的估算表明,长江所输送的陆源有机碳约71%会在沉积过程中损失掉。本研究有助于深入了解大河河口不同粒级颗粒物在有机碳迁移转化过程中的作用,深化对高浊度河口有机碳生物地球化学过程的认识。     

青岛近海秋末冬初悬浮颗粒物中部分金属元素的组成与影响因素研究

2008年11月末在青岛近海和胶州湾11个站点采集表层和底层海水中的悬浮颗粒物(SPM)样品,经消解后用等离子体发射光谱法测定了Al、Ca、Fe、Mg、Mn、Ti和Ba、Co、Cr、Cu、Ni、Pb、Sr、V、Zn共15个金属元素以及P的含量,结合SPM和元素含量聚类分析的结果探讨了秋末冬初青岛近海SPM的来源以及金属元素组成的影响因素.SPM含量范围在1.7～16.1mg/L之间,平均为7.9 mg/L;SPM来源以陆源风化产物为主,生物生产有较小的贡献.SPM中Ti、Fe、Mn、Mg、Al、V、Co、Sr和Ni的含量相对恒定,且主要受陆源输入的控制;Ca和P除受陆源影响外,生物生产亦有附加贡献.离陆地相对较远的区域表层海水SPM中Pb、Zn和Ba、Cr、Cu的含量较高,特别是Pb和Zn的富集因子较大,可能受到了潜在的污染影响.Ti的恒定性以及与SPM的良好相关性代表着在青岛近海可用Ti作为颗粒物陆源指示元素,且优于Al.     

Diel variations of marine snow concentration in surface waters and implications for particle flux in the sea

Successive measurements of the size distribution and abundance of marine snow in the upper 100 m of the Santa Barbara Channel, California, with an in situ still camera system following 11 tagged water masses revealed a consistent pattern of nighttime decreases in the abundance of large particles. A net nocturnal reduction in particulate flux from the upper 100 m as calculated from camera profiles occurred in 75% of the day–night comparisons, and nighttime aggregate carbon losses resulted in a 38% average reduction in camera-derived aggregate flux. Intensive investigation of three stations for 24–48 h each indicated that nighttime decreases in aggregate concentrations and derived aggregate flux could be registered throughout the observed water column. Nocturnal decreases in marine snow concentration are unlikely to result from diel variations in the production of marine snow either as feeding webs of zooplankton or through variations in aggregation rates of smaller particles. Moreover, measured diel variations in the intensity of surface mixing and convective overturn during one of the 24 h deployments were not intense enough to produce aggregate fragmentation and reduced aggregate flux. Nighttime increases in large crustacean zooplankton (i.e., euphausiids and the large copepod Calanus pacificus) could explain some or all of the reduction in aggregate abundance at most stations. Fragmentation and consumption of marine snow by migrating macrozooplankton could produce our observed synchronous diel cycles in marine snow concentration. This is the first empirical evidence of a diel pattern in the concentration and calculated particulate flux of large sinking particles in near-surface waters. The data presented here are consistent with the only other existing diel study, which also reported decreases in marine snow abundance at night at 270 m depths in the oceanic north Atlantic. Diel variations in the sizes and concentrations of marine snow may impact water column processes dependent upon particle availability and size, such as grazing and remineralization, and may generate a diel cycle of food availability to the benthos.     

Biogeochemical evolution of the outflow of the Mediterranean deep-lying particulate organic matter into the northeastern Atlantic

Small- and large-size particles were collected in January and August 1989 throughout the water column (50–3000 m) in a northeastern Atlantic area where deep Mediterranean waters outflowing through the Strait of Gibraltar are incorporated at mid-depth into Atlantic waters. Particles collected by water filtration (0.7 μm pore size) and by vertical hauls of a plankton net (50 μm mesh size) were analysed for their organic carbon and lipid composition, namely fatty acids, hydrocarbons, aliphatic and alicyclic alcohols and ketones, and pigments. Small-size particles exhibited POC concentrations two to three orders of magnitude higher (5–50 μg/l) than large particles (0.01–0.32 μg/l). Strong spatial and temporal variations were also observed. Surface small particles collected in January accounted for 15–50 μg/l of POC, whereas in August, these represented only 5–15 μg/l following the seasonal variability of primary production. Concurrently, the variety of lipid components was larger in January.The lipid components of large-size particles were dominated by zooplankton markers, whereas small particles showed evidence of a mixed algal composition (mainly of haptophytes and moderately of diatoms, prasinophytes, chrysophytes and dinoflagellates) with a bacterial contribution. The vertical profiles of the different lipid classes showed a general decrease with depth, particularly significant in the upper 200 m, consistently with the POC contents. Compositional changes were more evident in small particles and included the loss of unsaturated compounds and the increase of diagenetic and bacterial markers. Unusual increases were observed at mid-depths indicating additional particle inputs, either by in situ formation or by advective transport from the Mediterranean. The latter was recognized because small particles in Mediterranean waters entrained large quantities of continental detritic materials that were also found in the Mediterranean water lenses in the Atlantic. From these observations, it was inferred that the outflow of the Mediterranean deep-lying particulate organic matter might still preserve its signature in the mid-depth northeastern Atlantic waters.     

Distribution of suspended particulate matter in the North Sea as inferred from NOAA/AVHRR reflectance images and in situ observations

Distribution patterns of suspended particulate matter (SPM) in the surface water of the North Sea were calculated on the basis of: (1) the 1973–1993 data base of the EC MAST North West European Shelf Programme (NOWESP); and (2) composite reflectance images constructed from data that were collected by the NOAA/AVHRR satellite in 1990–1991. Three models were used for interpolating the in situ data: (1) a distance-weighted interpolation algorithm in which only the in situ data are taken into account; (2) an algorithm in which the ratios between the measured SPM concentrations and reflectances are interpolated, and the distribution of SPM is calculated from the field of interpolated ratios and the synoptic reflectance image; and (3) a distance-weighted algorithm similar to model-1, but with an additional weight factor that is based on local differences in reflectance. The models were tested for periods of 1 and 3 weeks in September 1990 and January 1991, and for the merged set consisting of all in situ data measured in September and January, respectively, between 1973 and 1993. Model-2 and -3 gave largely similar results and had a performance superior to model-1, particularly because they showed more detailed structures in the spatial distributions. Validations and cross-validations showed that the absolute concentrations of SPM predicted by the models were too low at high in situ concentrations and too high at low in situ concentrations. This shortcoming was due to the relatively high degree of smoothing that we applied in the models to account for the large variance of the in situ data. Semivariograms and correlograms indicated that the in situ data had substantial variability and were poorly correlated even at short distances. Only for the 20-year-merged data set did some correlation ( %) exist for stations km from each other. Monthly distributions of SPM were calculated with model-3 and the 20-year data set. The distributions confirm the main patterns previously found by others, such as the turbidity plume crossing the North Sea from southeast England towards the depository in the Skagerrak and the Norwegian Channel. The distributions indicate that materials from this plume may be deposited in the central North Sea in spring and summer and eroded again in autumn and winter. Areas with maximum SPM concentrations were identified off the Belgian coast and north of the Wadden Sea, particularly in winter, from which particles are entrained into the main current in a narrow strip along the continental coast to the German Bight. The results suggest that the two main fluxes of SPM in the North Sea, off England and along the continental coast, remain largely separated until they both end in the Skagerrak.     

珠江口磨刀门泥沙絮凝特征

本文利用激光粒度仪实测得到珠江口磨刀门河口2013年夏季悬浮泥沙现场絮凝及絮凝体特征,同时对比悬沙分散粒径和含沙量,研究表明:悬沙分散粒径平均值为27.9μm,现场实测絮团粒径平均值为91.6μm,表明磨刀门口外的悬浮泥沙絮凝现象显著;实测絮团平均粒径变化范围为13.0~273.8μm,小潮期间絮团粒径平均值为131.5μm,大于大潮平均值76.9μm;絮凝体粒径在垂向上的变化表现为由表及底先变大再变小。絮团体积浓度、沉速与粒径的关系在不同情况下有差异,体积浓度和絮团粒径在表层和中层有明显正相关关系,絮团沉速在大潮时刻随着粒径的增大而增大。综合分析影响絮凝的因素,得知在珠江口盐度对于絮团大小影响不明显;而流速大小的差异是影响大小潮之间絮团大小不同的主要因素。研究结果有助于了解珠江口细颗粒泥沙输移特性和相关生物化学过程。     

改性黏土除藻的絮凝形态学特征初步研究

在理论上改性黏土絮凝体的形态变化对其除藻过程有指示作用,可作为改性黏土用量和用法调控的依据,本文探讨了现有絮凝颗粒形态学观测与分析方法在改性黏土除藻效率评价上的适用性。借助激光颗粒表征技术和电子显微成像技术,本文观测了改性黏土除藻时的颗粒表面电性、粒径分布、絮凝体结构等絮凝形态学特征,分析了其与除藻效率的相关性。结果表明,现有观测方法可以表征改性导致的黏土颗粒Zeta电位反转、改性前后黏土在不同介质中的颗粒粒级分布差异、以及改性黏土与微藻形成絮凝体的多种显微结构;但由于较大粒径絮体对现有方法观测结果的影响更大,各种黏土的粒径特征与其除藻效率之间没有显著的相关性。现有观测方法获得的改性黏土颗粒形态特征仍不能反映其消除藻细胞的精细过程,特别是由于缺乏有效的絮凝体形态分析方法而导致现有形态参数还不能指示除藻效率的变化,亟需发展适用于改性黏土法除藻过程的颗粒形态分析新方法。     

北极拉普捷夫海夏、秋季颗粒有机碳的分布与来源

随着全球变暖的加剧,北极陆架边缘海碳的源汇过程对全球碳循环的影响及其气候环境效应日益显著。拉普捷夫海作为北冰洋典型的陆架边缘海,在大河、海冰、海洋初级生产力及海岸侵蚀的影响下,该区沉积有机碳的来源、输运和埋藏等过程独具特色。本文基于2018年中俄第二次北极联合科考获得的悬浮颗粒物样品和水文资料,研究了夏末秋初拉普捷夫海颗粒有机碳的分布特征、来源及其影响因素。结果表明,颗粒有机碳（POC）的浓度位于35.27～1 185.58 μg/L之间,平均为172.65 μg/L。受河流输入、海岸侵蚀和海洋初级生产力的影响,表层POC浓度分布呈现近岸高、远岸低趋势;底层POC浓度分布主要受控于沉积再悬浮作用,高浓度POC出现在勒拿河三角洲的东部区域。总悬浮颗粒物浓度与POC浓度总体呈显著正相关,显示出其对POC空间分布的直接影响,且两者在底层中的相关性要高于表层,表明不同层位的POC可能存在来源差异。研究区POC的δ¹³C值处于−31.03‰～−25.79‰之间,表层δ¹³C值较底层明显偏负,且部分站位的δ¹³C值甚至低于周边陆源有机碳的端元,这反映了可能除陆源输入的贡献外,近海浮游植物直接利用大量陆源有机质降解产生的溶解无机碳的过程也对该区域POC的供应和来源解析具有重要的影响。     

1998年11月长江河口悬浮体粒度特征的空间分布

利用Cilas940L型激光粒度仪对1998年11月取自长江河口的46个悬浮体样品进行了粒度测试分析。结果表明，长江河口悬浮体粒度特征在空间上具有明显的变化。悬浮体粒度的平均粒径、分选系数、偏态和峰态等参数，以及粉砂和粘土级含最在河口区平面和垂向上的分布的变化部较为显著。悬浮体的粒度分布为非正态分布，表层悬浮体为双峰分布模式，底层悬浮体为双峰或三峰分布模式。重点探讨了长江河口悬浮体粒度变化的影响因素中的表层沉积物的再悬浮作用和悬浮细颗粒絮凝这两个主要的因素。对长江河口表层沉积物的再悬浮通量进行了估算，表明，不同区域的再悬浮作用存在较大的差异，拦门沙地区为主要的再悬浮发生区。