A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies

In this review we provide the data needed to interpret remote spectroscopic studies of O₂ molecules embedded in the icy surfaces of outer solar system bodies. O₂ produced by radiolysis has been seen in the gas phase and as the so-called ‘solid O₂’ trapped in the icy surfaces of Ganymede, Europa and Callisto. It may also have been indirectly observed on a number of objects by its radiolysis product, O₃. These observations indicate the importance of O₂ for understanding the chemical processes occurring on icy outer solar system surfaces. Therefore, the published absorption spectra of gaseous, liquid and solid O₂ and of O₂ embedded in H₂O ice are reviewed in some detail. Particular emphasis has been placed on the presentation of transition probabilities for the various O₂ spectral series so that their relative importances can be assessed when they are used for modelling the radiation chemistry occurring in such environments.     

The angular width of the coherent back-scatter opposition effect: An application to icy outer planet satellites

It has been suggested recently that coherent back-scattering of light from powder-like regolithic surfaces can explain remarkable opposition brightening of some atmosphereless solar system bodies. In this paper, a dense-medium light-scattering theory is used to calculate the half-width at half-maximum (HWHM) of the coherent back-scattering peak for a number of scattering models. We demonstrate that HWHM strongly depends on the optical properties of the scattering medium and can serve as a critical test in comparing alternative models. It is shown that coherent back-scaterring may be a likely explanation of the opposition effect exhibited by icy outer planet satellites.     

Micrometeorite impact annealing of ice in the outer Solar System

The spectra of water ice on the surfaces of icy satellites and Kuiper Belt Objects (KBOs) indicate that the surface ice on these bodies is in a crystalline state. This conflicts with theoretical models, which predict that radiation (galactic cosmic rays and solar ultraviolet) should damage the crystalline structure of ice on geologically short timescales. Temperatures are too low in the outer Solar System for the ice to anneal, and reflectance spectra of these bodies should match those of amorphous solid water (ASW). We assess whether the kinetic energy deposited as heat by micrometeorite impacts on outer Solar System bodies is sufficient to anneal their surface ice down to a near-infrared optical depth . We calculate the kinetic energy flux from interplanetary micrometeorite impacts, including gravitational focusing. We also calculate the thermal diffusion of impact heat in various surfaces and the rate of annealing of ice. We conclude that the rate of annealing from micrometeorite impacts is sufficient to explain the crystallinity of ice on nearly all the surfaces of the saturnian, uranian and neptunian satellites. We discuss how the model can be used in conjunction with spectra of KBOs to probe dust fluxes in the Kuiper Belt.     

Water ice polymorphs and their significance on planetary surfaces

Impacts into an icy surface could produce significant amounts of high pressure forms of water ice. Due to the relatively low ambient surface temperatures on satellites in the outer solar system and the modest temperature rises accompanying the impact pressures required for water ice metamorphism, high-pressure polymorphs will be created by and may remain after large cratering events. If so, those high-pressure ices should be ubiquitous. Low-pressure cubic ice may be abundant as well. Impacts into an icy regolith may both produce high-pressure polymorphs from ice I and destroy high-pressure polymorphs already present. The result will be an (unknown) equilibrium concentration of high pressure polymorphs in the regolith. Polymorphs may be detectable and mappable by reflection spectroscopy at vacuum ultraviolet and mid-infrared wavelengths.     

Laboratory Studies of Icy Regoliths in Relation to Observations of Minor Bodies in the Outer Solar System

Observing the properties of solar lightscattered by TNOs is (up to now) the only way to obtain information on the physical properties of their surfaces. As such observations, performed near backscattering, become available, it is important to stress the significance of the phase angle and wavelength dependences of the linear polarization of the scattered light. At small phase angles, a narrow spike in brightness and a significantly negative polarization could be typical of icy regoliths, actually expected to be formed by alteration of icy bodies surfaces. Accurate experimental simulations of icyaggregates and regoliths formation that should take place with the ICAPS facility on board the ISS are presented, with emphasis on light scattering measurements providing a link between remote observations of TNOs and physical properties of their surfaces.     

Synthesis and characterization of peptides after high-energy impact on the icy matrix: Preliminary step for further UV-induced formation

In the interstellar medium, the most probable source of organic molecules could be non-equilibrium processes driven by photons, cosmic rays, shock waves and solid bodies’ collisions. The dense cold phase of ISM host icy dust grains—important chemical catalyst during its life cycle. Such particles consist of mineral core composed by silicate or olivine admixed with metal sulfides and oxides, with the water-icy envelope containing organic molecules. Organic molecules in the ISM evolve and become later incorporated in solar system material (comets and meteorites).The formation of polypeptides from single amino acids was traced in simulation experiments representing the inner structure of icy dust grains. Experimental chamber was irradiated at subzero temperatures at the dosage of 2.54 kRad/min. Solid frozen solutions of Gly and Phe were taken as the experimental samples inserted into the metal tube kept at subzero temperatures in the presence of liquid nitrogen. Formation of di- and tri-peptides was demonstrated after applying mass-spectrometry and high performance liquid chromatography (HPLC) techniques.Having polypeptides within the icy matrix, dust grains with ice mantles are transported to warm, dense and active protostellar regions, where ultraviolet irradiation may become important and alter the grain composition. Furthermore UVC radiation may contribute to the formation of additional amounts of polypeptides, since short-wave photons are totally adsorbed by a thin outer layer. This presumption coincides with our previous investigations concerning UV impact on prebiotic formation of the main biological molecules. Combination of two irradiation types in different stages of interstellar flight could compensate the effects of low reagents concentration and temperature. Since the primordial Earth had no atmosphere, the natural carriers could get freely onto its surface and thus raise the concentration of organic molecules.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.     

Dust ring formation due to ice sublimation of radially drifting dust particles under the Poynting-Robertson effect in debris disks

In a disk with a low optical depth, dust particles drift radially inward by the Poynting-Robertson (P-R) drag rather than are blown out by stellar radiation pressure following destructive collisions. We investigate the radial distribution of icy dust composed of pure ice and refractory materials in dust-debris disks taking into account the P-R drag and ice sublimation. We find that icy dust particles form a dust ring by their pile-ups at the edge of their sublimation zone, where they sublime substantially at the temperature 100-110 K. The distance of the dust ring is 20-35 AU from the central star with its luminosity L_??30L_⊙ and 65(L_?/100L_⊙)^1/2 AU for L_??30L_⊙, where L_⊙ is the solar luminosity. The effective optical depth is enhanced by a factor of 2 for L_??100L_⊙ and more than 10 for L_??100L_⊙. The optical depth of the outer icy dust disk exceeds that of the inner disk filled with refractory particles, namely, the residue of ice sublimation, which are further subjected to the P-R effect. As a result, an inner hole is formed inside the sublimation zone together with a dust ring along the outer edge of the hole.     

Implications of using broadband photometry for compositional remote sensing of icy objects

Water ice has such a low absorption coefficient at visual wavelengths (～0.01 cm^?1) that a very small amount of particulate material can significantly darken an icy surface. A variety of ice plus particle mixtures were studied to show that particulate contaminations of ～1% by weight (even 0.1% or less in some cases) in ice or frosts result in reflectance levels close to that of the contaminants. In a very clear ice (no bubbles) it is plausible to have a reflectance < 0.05 for particulate contaminations ～10^?7 by weight for submicron dark particles, such as carbon lampblack. Scattering conditions compete for domination with contaminants for control of visual reflectance, implying that the apparent reflectivity level and color of a surface is a poor indicator of ice content. A dark surface (e.g., albedo 0.05) does not necessarily imply that there us very little water ice present. Infrared JHK colors of water ice and other minerals, including ice-mineral mixtures, show that some orthopyroxenes can have JHK colors very similar to fine-grained water frosts. In general, it is possible that the JHK colors of an ice plus particulate mixture can fall anywhere in the classical J-H versus H-K diagram, thus the diagram cannot be used to distinguish a predominately “rock” surface from one which is predominantely ice for one specific case. An important exception is the case where both the J-H and H-K colors are ??0.2. It appears that such colors indicate a relatively pure icy surface. In some cases, the diagram might be used as a statistical tool to distinguish between the compositions of surfaces within a class of objects, but the validity of such comparisons decreases for different classes, such as the main-belt asteroids when compared to outer solar system satellites, where water ice is more stable.     

The icy Galilean satellites: ultraviolet phase curve analysis

Ultraviolet disk-integrated solar phase curves of the icy galilean satellites Europa, Ganymede, and Callisto are presented, using combined data sets from the International Ultraviolet Explorer (IUE), Hubble Space Telescope (HST), and the Galileo Ultraviolet Spectrometer. Global, disk-integrated solar phase curves for all three satellites, in addition to disk-integrated solar phase curves for Europa's leading, trailing, jovian, and anti-jovian hemispheres, are modeled using Hapke's equations for 7 broadband UV wavelengths between 260 and 320 nm. The sparse coverage in solar phase angle, particularly for Ganymede and Callisto, and the noise in the data sets poorly constrain some of the photometric parameter values in the model. However, the results are sufficient for forming a preliminary relationship between the effects of particle bombardment on icy surfaces and photometric scattering properties at ultraviolet wavelengths. Callisto exhibits a large UV opposition surge and a surface comprised of relatively low-backward scattering particles. Europa's surface displays a dichotomy between the jovian and anti-jovian hemispheres (the anti-jovian hemisphere is more backward scattering), while a less pronounced hemispherical variation was detected between the leading and trailing hemispheres. Europa's surface, with the exception of the trailing hemisphere region, appears to have become less backscattering between the late-1970s-early-1980s and the mid-1990s. These results are commensurate with the bombardment history of these surfaces by magnetospheric charged particles.     

The opposition effect in the outer Solar system: A comparative study of the phase function morphology

In this paper, we characterize the morphology of the disk-integrated phase functions of satellites and rings around the giant planets of our solar system. We find that the shape of the phase function is accurately represented by a logarithmic model [Bobrov, M.S., 1970. Physical properties of Saturn's rings. In: Dollfus, A. (Ed.), Surfaces and Interiors of Planets and Satellites. Academic, New York, pp. 376-461]. For practical purposes, we also parametrize the phase curves by a linear-exponential model [Kaasalainen, S., Muinonen, K., Piironen, J., 2001. Comparative study on opposition effect of icy solar system objects. Journal of Quantitative Spectroscopy and Radiative Transfer 70, 529-543] and a simple linear-by-parts model [Lumme, K., Irvine, W.M., 1976. Photometry of Saturn's rings. Astronomical Journal 81, 865-893], which provides three morphological parameters: the amplitude A and the half-width at half-maximum (HWHM) of the opposition surge, and the slope S of the linear part of the phase function at larger phase angles.Our analysis demonstrates that all of these morphological parameters are correlated with the single-scattering albedos of the surfaces.By taking more accurately into consideration the finite angular size of the Sun, we find that the Galilean, Saturnian, Uranian and Neptunian satellites have similar HWHMs (?0.5^°), whereas they have a wide range of amplitudes A. The Moon has the largest HWHM (∼2^°). We interpret that as a consequence of the “solar size bias”, via the finite angular size of the Sun which varies dramatically from the Earth to Neptune. By applying a new method that attempts to morphologically deconvolve the phase function to the solar angular size, we find that icy and young surfaces, with active resurfacing, have the smallest values of A and HWHM, whereas dark objects (and perhaps older surfaces) such as the Moon, Nereid and Saturn's C ring have the largest A and HWHM.Comparison between multiple objects also shows that solar system objects belonging to the same planet have comparable opposition surges. This can be interpreted as a “planetary environmental effect” that acts to locally modify the regolith and the surface properties of objects which are in the same environment.     

Optical alteration of complex organics induced by ion irradiation:: 1. Laboratory experiments suggest unusual space weathering trend

Most ion irradiation experiments relevant to primitive outer Solar System objects have been performed on ice and silicate targets. Here we present the first ion irradiation experiments performed on natural complex hydrocarbons (asphaltite and kerite). These materials are very dark in the visible and have red-sloped spectra in the visible and near-infrared. They may be comparable in composition and structure to refractory organic solids on the surfaces of primitive outer Solar System objects. We irradiated the samples with 15-400 keV H⁺, N⁺, Ar⁺⁺, and He⁺ ions and measured their reflectance spectra in the range of 0.3-2.5 μm before ion implantation and after each irradiation step. The results show that irradiation-induced carbonization gradually neutralizes the spectral slopes of these red organic solids. This implies a similar space weathering trend for the surfaces of airless bodies optically dominated by spectrally red organic components. The reduction of spectral slope was observed in all experiments. Irradiation with 30 keV protons, which transfers energy to the target mostly via electronic (inelastic) collisions, showed lower efficiency than the heavier ions. We found that spectral alteration in our experiments increased with increasing contribution of nuclear versus electronic energy loss. This implies that nuclear (elastic) energy deposition plays an important role in changing the optical properties of irradiated refractory complex hydrocarbon materials. Finally, our results indicated that temperature variations from 40 K to room temperature did not influence the spectral properties of these complex hydrocarbon solids.     

Radiation-induced amorphization of crystalline ice

We study radiation-induced amorphization of crystalline ice, analyzing the results of three decades of experiments with a variety of projectiles, irradiation energy, and ice temperature, finding a similar trend of increasing resistance of amorphization with temperature and inconsistencies in results from different laboratories. We discuss the temperature dependence of amorphization in terms of the ‘thermal spike’ model. We then discuss the common use of the 1.65 μm infrared absorption band of water as a measure of degree of crystallinity, an increasingly common procedure to analyze remote sensing data of astronomical icy bodies. The discussion is based on new, high quality near-infrared reflectance absorption spectra measured between 1.4 and 2.2 μm for amorphous and crystalline ices irradiated with 225 keV protons at 80 K. We found that, after irradiation with 10¹⁵ protons cm⁻², crystalline ice films thinner than the ion range become fully amorphous, and that the infrared absorption spectra show no significant changes upon further irradiation. The complete amorphization suggests that crystalline ice observed in the outer Solar System, including trans-neptunian objects, may results from heat from internal sources or from the impact of icy meteorites or comets.     

Possible nature of cometary atmosphere particles

The polarimetric and spectrophotometric data of observations, the results of laboratory simulations, and theoretical calculations are considered as evidence in favor of the presence of large irregular particles in cometary atmospheres. The attempt is made to define more precisely the particle parameters. In particular, observations of some comets at small phase angles can be interpreted by light scattering on large icy grains. The results of laboratory experiments with ice at low temperatures and pressures are adduced; this can be explain the formation of a large icy grain cloud near the cometary nucleus. Changes of these particles under the effects of solar radiation are considered.     

Preliminary studies concerning subsurface probes for the exploration of icy planetary bodies

It is well-known that the permanent terrestrial ice sheets (glaciers and polar caps) contain a lot of information about the recent geological history and in particular about climatic changes. Extrapolating this fact to other ice sheets in the solar system (e.g. the Mars polar regions, the icy moons of the outer planets, etc.), we may expect a similar wealth of information. To obtain this information it is possible to drill holes or melt the ice by a heated probe, which in this way is able to penetrate the surface and investigate the deeper layers in situ. In the latter case the driving agent is the heating power and the weight of the probe. In this paper we consider the application of such “melting probes” for exploring the structure of ice sheets in extraterrestrial environments. We describe several laboratory experiments with simple melting probes performed under cryo-vacuum conditions and compare the results with tests in a terrestrial environment. The experiments revealed that under space conditions the downward motion of a heated probe in an ice sheet is characterized by intermittent periods of sublimation and melting of the surrounding ice, sometimes interrupted by periods where a part of the probe's outer surface is frozen to the surrounding ice. This leads to a temporary blocking of the probe's downward motion. A similar situation can occur when the trailing tether is frozen in behind the probe. During the periods of ice sublimation the penetration process is significantly more power consuming, due to the large difference between the latent heat of sublimation and the latent heat of melting for water ice.     

Ion irradiation of H2O ice on top of sulfurous solid residues and its relevance to the Galilean satellites

In this paper we present the results of new experiments of ion irradiation of water ice deposited on top of a solid sulfurous residue to study the potential formation of SO₂ at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the sulfur dioxide ice detected on the surfaces of the Galilean satellites. In situ infrared spectroscopy was the used experimental technique. We have irradiated a thin film of H₂O frost on a sulfurous layer with 200 keV of He⁺ at 80 K. The used sulfurous residue was obtained by irradiation of frozen SO₂ at 16 K and it is used as a template of sulfur bearing solid materials. We have not found evidences of the efficient formation of SO₂ after irradiation of H₂O ice on top of the sulfurous residue. An upper limit to the production yield of SO₂, of interface area for each 100 eV of energy absorbed in 1 cm³ of ice-covered residue, has been estimated. These results have relevance in the context of the surfaces of the icy Galilean satellites in which SO₂ was detected. Our results show that radiolysis of mixtures of water ice and refractory sulfurous materials is not the primary formation mechanism responsible for the SO₂ present on the surfaces of the Galilean satellites.     

Laboratory simulation experiments on the solid-state greenhouse effect in planetary ices

Icy surfaces like the polar caps of Mars, comets, Edgeworth-Kuiper belt objects or the surface areas of many moons in the outer Solar System behave different than rock and soil surfaces when irradiated by solar light. The latter ones absorb and reflect incoming solar radiation immediately at the surface. In contrast, ices are partially transparent in the visible spectral range and opaque in the infrared. Due to this fact it is possible for the solar radiation to reach a certain depth and increase the temperature of the sub-surface layers directly. This internal temperature rise is called “solid-state greenhouse effect,” in analogy to the classical greenhouse effect in an atmosphere. It may play an important role in the energy balance of various icy bodies in the Solar System. Within the scope of a project conducted at the Space Research Institute of the Austrian Academy of Sciences in Graz the solid-state greenhouse effect was investigated experimentally and theoretically. A number of experiments with diverse materials, focussing mainly on layered samples with a surface cover consisting of transparent H₂O-ice, were performed. The samples were irradiated under cryo-vacuum conditions by a solar simulator. The temperature distributions inside the samples were measured and compared with the results of numerical model calculations. We found that the predicted sub-surface temperature maximum is very clearly measurable in glass beads samples with various particle size distributions, but can also be detected in transparent compact surface ice layers. However, in the latter case it is less distinct than originally expected. Measuring the effect by laboratory methods turned out to be a difficult task due to the shallow depth where the temperature maximum occurs.     

Surface evolution of two-component stone/ice bodies in the Jupiter region

Observational and theoretical data converge on the conclusion that planetesimals in Jupiter's region of the solar nebula were initially composed predominantly of a mixture of roughly 39–70% H₂O ice by volume, and 30–61% dark stony material resembling carbonaceous chondrites. Recent observations emphasize a division of most asteroid and satellite surfaces in this region into two distinct groups: bright icy material and dark stony material. The present model accounts for these by two main processes: an impact-induced buildup of a dark stony regolith in the absence of surface thermal disturbance, and thermal-disturbance-induced eruption of “water magmas” that create icy surfaces. “Thermal disturbances” include tidal and radiative effects caused by nearness of a planet. A correlation of crater density and albedo, Ganymede's dark-ray craters, and other observed phenomena (listed in the summary) appear consistent with the model discussed here.     

Refractive index measurements of ammonia and hydrocarbon ices at 632.8 nm

Optical constants in a broad temperature and wavelength range are important input parameters in radiative transfer models used in studies of planetary atmospheres. In the laboratory, the refractive index values of ices at the HeNe laser wavelength (632.8 nm) are often used to monitor the growth rate and thickness of ice films. In this report we present laboratory measurements determining the refractive index at 632.8 nm of ammonia and hydrocarbon ices in the temperature range 80-100 K. Thin ice films are vapor-deposited on a cryogenically cooled mirror located inside a high-vacuum apparatus. The real component of the refractive index of these ice films is determined by a two-angle interferometric technique. Optical modeling calculations of the transmittance and reflectance through the thin ice films assist in the interpretation of the experimental results. We discuss our results and compare them with other measurements available in the literature. The results reported here are relevant to the spectroscopy of icy objects in the solar system; they are needed to perform laboratory characterization of ices, derive optical constants, and model spectra.     

Seas under ice: Stability of liquid-water oceans within icy worlds

The present-day existence of internal oceans under the outer ice shell of several icy satellites of the Solar System has been recently proposed. The presence of antifreeze substances decreasing ice’s melting point (and tidal heating in Europa’s case) has been generally believed to allow the stability of such oceans; limited cooling of the water (ice plus liquid) layer, due to stability against convection or to stagnant lid convection in the icy shell, have been also considered. Here we propose that even pure liquid-water oceans could survive today within several icy worlds, and we consider some factors affecting thermal modeling in these bodies. So, the existence of such oceans would be a natural consequence of the physical properties of water ice, independently from the addition of antifreeze substances or any other special conditions. The inclusion of these substances would contribute to expand the conditions for water to stay liquid and to increase ocean’s volume.