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1.
《中国地球化学学报》2006,(Z1)
Research on the origin of acid mine drainage(AMD)is helpful to find a way to avoid and remediate AMD and its pollution.AMD is mainly from pyrite(FeS2)-containing minerals(such as coal and ore)during mining process and reproduction,and is common and danger… 相似文献
2.
Modes of Occurrence and Geological Origin of Beryllium in Coals from the Pu''''an Coalfield, Guizhou, Southwest China
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YANG Jianye Department of Materials Xi''''an University of Science Technology Xi''''an Shaanxi 《《地质学报》英文版》2007,81(3):470-476
The concentration, modes of occurrence and geological origin of beryllium in five workable coal beds from the Pu'an Coalfield of Guizhou were studied using the inductively coupled-plasma mass spectrometry (ICP-MS), floating and sinking experiments (FSE) and sequential chemical extraction procedures (SCEP). The results show that the average concentration of beryllium in coals from the Pu'an Coalfield is 1.54μg/g, much lower than that in most Chinese and worldwide coals. Beryllium in the Pu'an coals was not significantly enriched. However, it should be noted that the No. 8 coal bed from the study area has a high concentration of beryllium, 6.89μg/g, three times higher than the background value of beryllium in coal. Beryllium in coal mainly occurs as organic association and has predominantly originated from coal-forming plants when its concentration is relatively low. The concentration of beryllium occurring as organic association is close to that distributed in inorganic matter when beryllium concentration of coal is similar to its background value, and in addition to coal-forming plants, beryllium is mainly derived from detrital materials of terrigenous origin. When beryllium is anomalously enriched in coal, it mainly occurs as organic association and is derived from volcanic tonsteins leached for a long geological time and then adsorbed by organic matter in peat mire. 相似文献
3.
Modes of Occurrence and Geological Origin of Beryllium in Coals from the Pu''an Coalfield, Guizhou, Southwest China
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YANG Jianye Department of Materials Xi''an University of Science Technology Xi''an Shaanxi 《《地质学报》英文版》2007,81(3)
The concentration, modes of occurrence and geological origin of beryllium in five workable coal beds from the Pu'an Coalfield of Guizhou were studied using the inductively coupled-plasma mass spectrometry (ICP-MS), floating and sinking experiments (FSE) and sequential chemical extraction procedures (SCEP). The results show that the average concentration of beryllium in coals from the Pu'an Coalfield is 1.54μg/g, much lower than that in most Chinese and worldwide coals. Beryllium in the Pu'an coals was not significantly enriched. However, it should be noted that the No. 8 coal bed from the study area has a high concentration of beryllium, 6.89μg/g, three times higher than the background value of beryllium in coal. Beryllium in coal mainly occurs as organic association and has predominantly originated from coal-forming plants when its concentration is relatively low. The concentration of beryllium occurring as organic association is close to that distributed in inorganic matter when beryllium concentration of coal is similar to its background value, and in addition to coal-forming plants, beryllium is mainly derived from detrital materials of terrigenous origin. When beryllium is anomalously enriched in coal, it mainly occurs as organic association and is derived from volcanic tonsteins leached for a long geological time and then adsorbed by organic matter in peat mire. 相似文献
4.
Modes of Occurrence and Geological Origin of Beryllium in Coals from the Pu'an Coalfield, Guizhou, Southwest China
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YANG Jianye 《《地质学报》英文版》2007,81(3):470-476
The concentration, modes of occurrence and geological origin of beryllium in five workable coal beds from the Pu'an Coalfield of Guizhou were studied using the inductively coupled-plasma mass spectrometry (ICP-MS), floating and sinking experiments (FSE) and sequential chemical extraction procedures (SCEP). The results show that the average concentration of beryllium in coals from the Pu'an Coalfield is 1.54 μg/g, much lower than that in most Chinese and worldwide coals. Beryllium in the Pu'an coals was not significantly enriched. However, it should be noted that the No. 8 coal bed from the study area has a high concentration of beryllium, 6.89 μg/g, three times higher than the background value of beryllium in coal. Beryllium in coal mainly occurs as organic association and has predominantly originated from coal-forming plants when its concentration is relatively low. The concentration of beryllium occurring as organic association is close to that distributed in inorganic matter when beryllium concentration of coal is similar to its background value, and in addition to coal-forming plants, beryllium is mainly derived from detrital materials of terrigenous origin. When beryllium is anomalously enriched in coal, it mainly occurs as organic association and is derived from volcanic tonsteins leached for a long geological time and then adsorbed by organic matter in peat mire. 相似文献
5.
YANG Jianye Department of Materials Xi'an University of Science Technology Xi'an Shaanxi 《《地质学报》英文版》2007,81(3)
The concentration, modes of occurrence and geological origin of beryllium in five workable coal beds from the Pu'an Coalfield of Guizhou were studied using the inductively coupled-plasma mass spectrometry (ICP-MS), floating and sinking experiments (FSE) and sequential chemical extraction procedures (SCEP). The results show that the average concentration of beryllium in coals from the Pu'an Coalfield is 1.54μg/g, much lower than that in most Chinese and worldwide coals. Beryllium in the Pu'an coals was not significantly enriched. However, it should be noted that the No. 8 coal bed from the study area has a high concentration of beryllium, 6.89μg/g, three times higher than the background value of beryllium in coal. Beryllium in coal mainly occurs as organic association and has predominantly originated from coal-forming plants when its concentration is relatively low. The concentration of beryllium occurring as organic association is close to that distributed in inorganic matter when beryllium concentration of coal is similar to its background value, and in addition to coal-forming plants, beryllium is mainly derived from detrital materials of terrigenous origin. When beryllium is anomalously enriched in coal, it mainly occurs as organic association and is derived from volcanic tonsteins leached for a long geological time and then adsorbed by organic matter in peat mire. 相似文献
6.
Miaoyun ZHANG Shijie WANG Fengchang WU Xianghong YUAN Ying ZHANG 《中国地球化学学报》2006,25(B08):18-18
A comprehensive study on the chemical composition of wet precipitation was carried out from January 2004 to December 2004 at Jinhua, China. All samples were analyzed for pH, electrical conductivity and major ions (F, Cl, NO3,. SO4^2-, K^+, Na^+, Ca^2+, Mg^2+. and NH4^+). The results showed that SO4^2- is one of the dominant anions, accounting for 66.1% of the measured anions in precipitation, while NH4^+ and Ca^2+ account for 56.6% and 33.4% of the measured cations, respectively. Even though the concentrations of SO4^2- and NO3^- were not high relative to those in the northern areas of China, rainwater in the studied area is typically acidic with a volume-weighted mean pH of 4.54 due to the lack of neutralization in precipitation. The fractional acidity value suggested that about 76% of acid was neutralized by alkaline constituents. On the other hand, H^+ showed no significant correlation with other ionic species, which indicates that its acidity might be attributed to the comprehensive effect of all the acidifying and neutralizing ions rather than one major ion in precipitation. A good correlation between Ca^2+ and Mg^2+, as well as between Na^+ and Cl^-, indicated these ions are commonly of crustal and marine origin, respectively. Other relatively good correlations were observed between NH4^+ and SO4^2-, Ca^2+ and SO4^2-, Mg^2+ and SO4^2-, Mg^2+ and NO3^-, and Mg^2+ and Cl^-. These results were attributed to the atmospheric chemical reactions of the acids H2SO4, HNO3 and HCl with alkaline compounds such as NH3 and/or carbonate materials. High enrichment factor of marine source for SO4^2-, Ca^2+ and K^+ indicated that large amounts of these ions came mainly from a non-marine source. Similarly, a high enrichment factor of soil for SO4^2-, NO3^- and CI also suggested that most of these ions did not come from soil source. 相似文献
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The Qulong deposit in Tibet is one of the largest porphyry copper-molybdenum deposits in China. We used short-wave infrared (SWIR) spectroscopy to examine the spectral characteristics of the extensively developed chlorite in this deposit. X-ray diffraction and electron microprobe analyses were used for phase identification and to obtain the chemical composition, ion substitution relationships, and formation environment of the chlorite. SWIR spectral parameters were applied to detect the hydrothermal centers. The results indicate that the wavelength of the absorption feature for Qulong chlorite Fe-OH (Pos2250) range from 2240 to 2268.4 nm; the chlorite substitution relationships are dominated by Mg-Fe substitution at the octahedral sites together with AlⅣ-Si substitution at the tetrahedral sites; the chlorite formation temperatures range within the medium-low temperature hydrothermal alteration range from 164 to 281°C, with an average value of 264°C; the wavelength of the chlorite peak position for Fe-OH (2250 nm) absorption and its chemical composition are positively correlated with AlⅥ, Fe + AlⅥ, Fe/(Fe + Mg), Fe, and Fe + AlⅣ but negatively correlated with Mg and Mg/(Fe + Mg); and the wavelength associated with the chlorite Fe-OH (2250 nm) absorption feature is positively correlated with the temperature at which the chlorite formed. These correlations indicate that more Fe and AlⅥ ions and fewer Mg ions at the octahedral sites of chlorite lead to a longer the wavelength of the chlorite Fe-OH (2250 nm) absorption feature and a higher chlorite formation temperature. The wavelength of the Qulong chlorite Fe-OH (2250 nm) absorption feature (>2252 nm) can thus serve as an exploration indicator to guide the detection of hydrothermal centers in porphyry copper deposits. The results of the study indicate that the mineralogical and SWIR spectral characteristics of chlorite are significant indicators for locating hydrothermal centers within porphyry deposits. 相似文献
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SONG Eping ZHANG Kexin CHEN Jiangjun WANG Chaowen JIANG Gaolei YIN Ke HONG Hanlie CHURCHMAN Jock Gordon 《《地质学报》英文版》2014,88(5):1579-1591
This study collected the early Oligocene to middle Miocene sediments from the Gerze Basin of Tibet, and used X-Ray diffraction (XRD) and Scanning Electron Microscope (SEM) to discuss their clay mineralolgy, clay indices, better understand the clay mineralogy and its paleoclimatic significance. The results show that clay minerals of the Gerze Basin sediments are mainly composed of iilite and chlorite, with minor amounts of smectite and kaolinite, and their relative content varies along the section. Variations of relative contents and clay indices suggest that the Gerze Basin has experienced three-stage evolution of paleoclimate: I ) high ilUte and chlorite contents, with fluctuant smectite and low (I+Ch)/(K+S) ratio, indicative of a dominant seasonal arid climate from the early Oligoeene to late Oligocene; Ⅱ) higher illite and chlorite contents and larger (I+Ch)/(K+S) ratio but absence of kaolinite, indicating a colder and drier climate from the late Oligocene to early Miocene; Ⅲ) high iilite and chlorite contents with fluctuant (I+Ch)/(K+S) ratios and occasional occurrence of kaolinite, suggesting that the climate became warmer and more humid compared with that of stage Ⅱ in the mid-Miocene. These conclusions were also reinforced by the clay morphology, which suggests that physical weathering dominated in stage Ⅱ, while relatively strong chemical weathering was dominant in stages Ⅰ and Ⅲ Clay minerals of the sediments mainly consist of illite and chlorite, indicating that the source rock played a significant role in clay origin. It is inferred that global cooling and the enhancement of denudation and obstruction of northward moisture due to the uplift of the Qinghai-Tibet Plateau were responsible for the provenance of iUite and chlorite under weak chemical weathering. Though the Qinghai-Tibet Plateau reached a certain elevation by the mid-Miocene, yet the mid-Miocene widespread warming might have largely impacted the Gerze climate. 相似文献
9.
Mineral Composition of Loess—Paleosol Samples from the Loess Plateau of China and Its Environmental Significance 总被引:1,自引:0,他引:1
34samples of loess-paleosol from the Luochuan and Xifeng sections in the Loess Plateau,northern China were eparated into sand,silt and clay fractions and analyzed for their mineral compositions.The results indicate that there is almost no difference between loess and paleosol in mineral composition.Major mineral species are quartz,mica,feldspar and chlorite,accounting for about 88-92% of the total;other minerals are kandite,smectite,vermiculite and a few heavy minerals.The calcite,magnetite and hematite were not taken into consideration because of their removal in the process of sample preparation.The main difference with respect to the mineral composition of samples collected from different sections and different statigraphic levels lies in the amount and grain size of minerals hosted.Comparisons between the Luochuan section and the Xifeng section,between paleosol and loess and between the upper part and the lower part of some paleosol layers show that the formers contain less feldspar but more mica and vermiculite and are finer in grain size,indicating the co-occurrence of both biochemical weathering process responsible for mineral change and physical weathering process leading to grain-size change during the soil-forming processes.This result favours such an explanation of the soil-forming mechanism that loess deposition and paleosol development occurred synchronously,though the rate of soil formation was greater than that of loess deposition,thus leading to soil development. 相似文献
10.
The Jinshan gold deposit consists of gold-bearing ultramylonite and gold-bearing quartz vein ores.The Rb-Sr isochron age of fluid inclusions in quartz from quartz veins is the same as that of the gold-bearing ultramylonite,suggesting that both the types of ordbodies were fored simultaneously in the Caledonian Period,in the range 406-409Ma,REE patterns and sulfur,lead,carbon.hydrogen and oxygen isotopy data,as well as the composition of fluid inclusion.have shown that the ore-forming fluids were derived from formation water,and the ore-froming materials came from the gold-hosed rocks.The Jinshan gold deposit occurring in a Caledonian brittle-ductile zone in metamorphosed microclastic rocks owes its orgin to Caledonian reworking processes. 相似文献
11.
土压缩模量预测回归分析方法 总被引:1,自引:0,他引:1
在土压缩模量Es的分析计算中,常用的分析方法是根据土的e-p曲线试验资料建立公式求解,本文引入了数学上的回归分析方法来探讨Es与其它各项物理力学指标参数之间的相关关系,旨在找出对Es影响最显著的指标参数,并建立最优回归方程式,以此来预测Es。研究结果表明:该方法通用性强,应用范围广,亦可推广应用于其它相关领域。 相似文献
12.
Ivan V. BRAGIN Georgy A. CHELNOKOV Oleg V. CHUDAEV Natalia A. KHARITONOVA Sergey V. VYSOTSKIY 《《地质学报》英文版》2016,90(1):276-284
Studied waters belong to warm(T=30-50℃),alkaline(pH=8.9-9.3),low mineralized(TDS235 mg/1)Na-HCO_3 or Na-SO_4-HCO_3 thermal waters with high content of SiO_2(up to 81 mg/l)and F(up to 3.9 mg/1),occur on modern volcano-tectonic rejuvenated areas of Eastern Sikhote-Alin orogenic belt.Low~3He concentration as well as N_2/O_2 and N_2/Ar ratios exclude influence of deep mantle fluid.New rare earth element data constrain our understandmg of water-rock interaction occurring in the water source region.Meteoric origin of waters is proved by stable isotope values varying from-71‰to-136.1‰and from-10.8‰to-18.8‰forδ~2U andδ~(18)O respectively.REE patterns reflect high pH,resultfing from water-rock interaction and oxidative conditions.Calculations of deep aquifer temperature using Na-K and quartz geothermometers show 116.8-131.1°C and 82.2-125.8℃respectively.Presence of deep faults both with abnormal thermal gradient(~45-50 K/km)define unique geochemical shape of thermal waters of Sikhote-Alin,area,where no present volcanic activity is registered. 相似文献
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Using the database of automatic hydrometeorological stations, installed in the Don RIver delta and Taganrog Bay seashore, the sources of the anomalois scale water negative surge and salinization of the Azov Sea under conditions of low river flow in 2015–2016 are studied. The new schemes of stratification and advection of salty sea waters in the Don River mouth under different weather conditions, water discharge and levels are given. 相似文献
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《International Geology Review》2012,54(10):1218-1225
Copper deposits of Cuba belong to the Jurassic lead-zinc-copper, Cretaceous copper and Paleogene copper complexes, which differ substantially in their formation conditions. The island is differentiated into a number of metallogenic zones formed at the initial and early stages of the Cuba folded province. Pinar del Rio, Pinos, Trinidad and Oriente zones, of an intrageanticlinal nature, are prospective with respect to copper vein deposits of the lead-Zinc-copper complex. The Sasa and Cauto zones - intrageosynclinal - are prospective with regard to copper-pyrite and copper vein deposits of the Cretaceous complex. A metallogenic study of the island is indicated in planning the exploration of its copper prospects. -- AGI Staff. 相似文献
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考虑核电厂地基-基础的动力相互作用,应用显式动力有限差分法分析了地震作用下极软岩、较软岩、坚硬岩上核电厂建筑结构基础的地震响应特征,比较了岩石坚硬程度对基础加速度反应谱的影响。研究表明:随着岩石坚硬程度的提高,核电厂建筑物结构基础的地震响应有增加的趋势;在周期轴上,基础处的加速度反应谱曲线会随着岩石坚硬程度的提高逐渐向短周期(高频段)方向移动。在高频段,建造于较坚硬岩石上基础结构的加速度反应谱值偏大;在中等频段,建造于较软岩石上基础结构的加速度反应谱值偏大;在低频段,岩石坚硬程度对加速度反应谱的影响不显著。 相似文献
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Doklady Earth Sciences - Multiannual observations (2009–2017) by means of autonomous seiche recorders have been conducted for marine seiches with one second discreteness in the boot basin for... 相似文献