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1.
Application of geostatistics and GIS technique to characterize spatial variabilities of bioavailable micronutrients in paddy soils 总被引:6,自引:1,他引:5
To understand the spatial dependency of bioavailable micronutrients in paddy soils, 134 soil samples were taken from Pinghu County, Zhejiang Province, south-east China to characterize the spatial variabilities of bioavailable Cu, Zn, Fe, and Mn. The geostatistics and geographic information system (GIS) techniques were applied. Bioavailable Zn and Mn were fitted to an exponential model with a range of 4.4 km and 2.97 km, respectively. Bioavailable Fe was fitted to the linear model with the longest range of 23.48 km. Bioavailable Cu did not show any spatial correlation with the fitted pure nugget effect model. Bioavailable Zn and Mn had strong spatial dependence due to the effects of intrinsic factors such as parent material, relief and soil types. Bioavailable Fe had moderate spatial dependence over a long distance. The spatial distribution of the four bioavailable micronutrients were significantly correlated to the soil formation factors. Human activity, such as application of fertilizer and pesticide, emission of waste gas and industrial pollution also had significant effects on the spatial distributions of the bioavailable micronutrients. 相似文献
2.
An investigation on spatial distribution, possible pollution sources, and affecting factors of heavy metals in the urban–suburban
soils of Lishui city (China) was conducted using geographic information system (GIS) technique and multivariate statistics.
The results indicated that the topsoils in urban and suburban areas were enriched with metals, such as Cd, Cu, Pb, and Zn.
Spatial distribution maps of heavy metal contents, based on geostatistical analysis and GIS mapping, indicated that Cd, Cr,
Cu, Mn, Ni, Pb, and Zn had similar patterns of spatial distribution. Their hot-spot areas were mainly concentrated in the
densely populated old urban area of the city. Multivariate statistical analysis (correlation analysis, principal component
analysis, and clustering analysis) showed distinctly different associations among the studied metals, suggesting that Cr,
Cu, Ni, Pb, Cd, and Zn had anthropogenic sources, whereas Co and V were associated with parent materials and therefore had
natural sources. The Cd, Cr, Ni, Pb, and Zn contents were positively correlated with soil organic matter, pH, and sand content
(p < 0.01). It is concluded that GIS and multivariate statistical methods can be used to identify hot-spot areas and potential
sources of heavy metals, and assess soil environment quality in urban–suburban areas. 相似文献
3.
Yongcun Zhao Xianghua Xu Jeremy Landon Darilek Biao Huang Weixia Sun Xuezheng Shi 《Environmental Geology》2009,57(5):1089-1102
Topsoil samples (0–20 cm) (n = 237) were collected from Rugao County, China. Geostatistical variogram analysis, sequential Gaussian simulation (SGS),
and principal component (PC) analysis were applied to assess spatial variability of soil nutrients, identify the possible
areas of nutrient deficiency, and explore spatial scale of variability of soil nutrients in the county. High variability of
soil nutrient such as soil organic matter (SOM), total nitrogen (TN), available P, K, Fe, Mn, Cu, Zn, and B concentrations
were observed. Soil nutrient properties displayed significant differences in their spatial structures, with available Cu having
strong spatial dependence, SOM and available P having weak spatial dependence, and other nutrient properties having moderate
spatial dependence. The soil nutrient deficiency, defined here as measured nutrient concentrations which do not meet the advisory
threshold values specific to the county for dominant crops, namely rice, wheat, and rape seeds, was observed in available
K and Zn, and the deficient areas covered 38 and 11%, respectively. The first three PCs of the nine soil nutrient properties
explained 62.40% of the total variance. TN and SOM with higher loadings on PC1 are closely related to soil texture derived
from different parent materials. The PC2 combined intermediate response variables such as available Zn and P that are likely
to be controlled by land use and soil pH. Available B has the highest loading on PC3 and its variability of concentrations
may be primarily ascribed to localized anthropogenic influence. The amelioration of soil physical properties (i.e. soil texture)
and soil pH may improve the availability of soil nutrients and the sustainability of the agricultural system of Rugao County. 相似文献
4.
Spatial variability of heavy metals in soils across a valley plain in Southeastern China 总被引:1,自引:0,他引:1
An investigation was carried out to survey the magnitude and spatial distribution of heavy metals, as well as their relation
with soil series, in a valley plain in Southeastern China. Soil was sampled at 159 sites by combining a squared grid and nested
sampling strategies along the transect perpendicular to the Qujiang River in Zhejiang Province, China. Total concentrations
of six metals, namely Cu, Fe, Mn, Ni, Pb and Zn, were measured. Classical statistics and geostatistics were used to quantify
their spatial characteristics. There was a considerable variation in many of these parameters. The total concentrations ranged
from 6.8 to 29.3 mg kg−1 for Cu, 6,784 to 18,678 mg kg−1 for Fe, 94 to 385 mg kg−1 for Mn, 6.1 to 20.3 mg kg−1 for Ni, 25.0 to 49.5 mg kg−1 for Pb, and 12 to 160 mg kg−1 for Zn. Pearson correlation coefficients among total metal concentrations and selected soil properties showed a number of
strong associations. By virtue of analysis of variance, a predominant influence of soil series on the spatial variability
of metal concentrations was observed. All metals were spatially correlated. The semivariograms of Cu, Fe, Mn, Ni and Zn were
dominated by short range correlation (600 or 700 m), and that of Pb by long range (1200 m). Block kriging maps of total metal
concentrations and soil properties showed strip distributions, perpendicular to the river, in the manner similar to the soil
series. Principal component analysis was run to identify common distribution patterns of heavy metals and soil properties.
These results illustrate that soil series information of valley plain may be useful for developing management zones for site-specific
agriculture. 相似文献
5.
A soil geochemical survey was undertaken in the cultivated region of Agia in Thessaly area, Central Greece. The objectives
of the study were to assess the levels of soil contamination in respect to average concentrations of toxic metals in the region,
to determine the associations between the different toxic elements and their spatial distribution and to identify possible
sources of contamination that can explain the spatial patterns of soil pollution in the area. One hundred seventy three soil
samples were collected and analysed by ICP-AES after digestion with a mixture of HClO4–HNO3–H2O. The study focused on eleven elements (Cu, Pb, Zn, Ni, Co, Mn, As, V, Cr, Fe and Mg) and all of them except Pb have mean
concentrations above the average global soil composition. The elements Ni, Cr, Mn and V show concentrations that according
to G.L.C guidelines the Agia soils are classified as slightly contaminated to contaminated. Factor analysis explained 84.02%
of the total variance of the data through four factors. Combined with spatial interpretation of its output, the method successfully
grouped the elements according to their sources and provided evidence about their natural or anthropogenic origin. 相似文献
6.
The marine coastal sediments from Togo have been analysed for the trace elements Cd, Cr, Cu, Ni, Pb, Sr, V, Zn and Zr to
ascertain the geo-ecological impact of dumping of phosphorite tailings into the sea. Trace element concentrations ranged from
2–44 ppm for Cd, 22–184 ppm for Cu, 19–281 ppm for Ni, 22–176 ppm for Pb, 179–643 ppm for Sr, 38–329 ppm for V, 60–632 ppm
for Zn and 18–8928 ppm for Zr. Regional distribution of trace elements in the marine environment indicates that the concentrations
of Cr, Cu, Ni, Pb, V, Sr and Zn increase seawards and along the coastal line outwards of the tailing outfall, whereas Cd and
Zr showed reversed spatial patterns. Sorting and transport of phosphorite particles by coastal currents are the main factors
controlling the distribution of particle-bound trace metals in the coastal environment. The Cd, Sr and Zn concentrations decrease
with decreasing grain size in marine coastal sediments, whereas Cr, Cu, Ni and Zn concentrations increase with decreasing
grain size. Percolation and shaking experiments were carried out in laboratory using raw phosphate material and artificial
sea water. Enhanced mobilization of Cd from phosphorites by contact with the sea water was observed.
Received: 11 May 1998 · Accepted: 20 October 1998 相似文献
7.
Environment impact of heavy metals on urban soil in the vicinity of industrial area of Baoji city,P.R. China 总被引:3,自引:0,他引:3
Heavy metals in soils are of great environmental concern, in order to evaluate heavy metal contents and their relationships
in the surface soil of industrial area of Baoji city, and also to investigate their influence on the soils. Soil samples were
collected from 50 sites, and the concentration of Pb, Zn, Cu, Cr, Ni heavy metals and the contents of characteristics in soil
from industrial area of Baoji city were determined with X-ray fluorescence method. The concentrations of Pb, Zn, Cu, Cr and
Ni in the investigated soils reached the amount of 2,682.00–76,979.42, 169.30–8,288.58, 62.24–242.36, 91.96–110.54 and 36.14–179.28 mg kg−1, respectively. The major element Pb contents of the topsoils were determined. to highlight the influence of ‘anthropic’ features
on the heavy metal concentrations and their distributions. To compare, all values of elements were much higher than those
of unpolluted soils in the middle of Shaanxi province that average 16.0–26.5, 67.1–120.0, 17.8–57.0, 46.9–65.6 and 24.7–34.6 mg kg−1 for Pb, Zn, Cu, Cr and Ni, respectively. An ensemble of basic and relativity analysis was performed to reduce the precipitate
of Pb in soil was extremely high and greatly relativity with other elements. Meanwhile, Pb, Zn, Cu, Cr, Ni heavy metals were
typical elements of anthropic activities sources, so it was easy to infer to the tracers of anthropic pollutions from the
factorial analysis, which was coming from the storage battery manufactory pollutions. The pollutant distributions were constructed
for the urban area which identified storage battery manufactory soot precipitate as the main source of diffuse pollution and
also showed the contribution of the topsoils of industrial area of Baoji city as the source point of pollution. Consequently,
the impact of heavy metals on soil was proposed and discussed. These results highlight the need for instituting a systematic
and continuous monitoring of heavy metals and other forms of pollutants in Baoji city to ensure that pollution does not become
a serious problem in the future. 相似文献
8.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
9.
Spatial variability of soil organic matter and nutrients in paddy fields at various scales in southeast China 总被引:2,自引:0,他引:2
Xingmei Liu Keli Zhao Jianming Xu Minghua Zhang Bing Si Fan Wang 《Environmental Geology》2008,53(5):1139-1147
The present study examines the spatial dependency of soil organic matter and nutrients in paddy fields at three different
scales using geostatistics and geographic information system techniques (GIS). The spatial variability of soil organic matter
(SOM), total nitrogen (TN) and available phosphorus (AP) has been characterized using a total of 460, 131 and 64 samples that
were, respectively, collected from the Hangzhou–Jiaxing–Huzhou (HJH) Plain (10 km), Pinghu county (1,000 m) and a test plot
area (100 m) within the Pinghu county, Zhejiang province of the southeast China. Semivariograms showed that the SOM and TN
had moderate spatial dependency on the large scale of HJH plain and moderate scale of Pinghu county with long spatial correlation
distances. At the moderate scale of Pinghu county and the small scale of a test plot area, the AP data did not show any spatial
correlation, but had moderate spatial dependency in HJH plain. Spherical and exponential variogram models were best fitted
to all these soil properties. Maps of SOM and TN were generated through interpolation of measured values by ordinary kriging,
and AP by lognormal kriging. This study suggests that precision management of SOM and TN is feasible at all scales, and precision
management of AP is feasible at large scales. 相似文献
10.
María Teresa Rodríguez-Salazar Ofelia Morton-Bermea Elizabeth Hernández-Álvarez Rufino Lozano Victor Tapia-Cruz 《Environmental Earth Sciences》2011,62(5):899-905
This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co,
Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial
soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area.
In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed
as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic
influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried
out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu
and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results
in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area
of Mexico City. 相似文献
11.
Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for
total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability
of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8
(1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg−1, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were
not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%,
respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb
(39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated
soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3,
40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably
decline in the following order: Cd = Pb > Ni > Cu > Zn. 相似文献
12.
以广东省揭阳市揭东区表层土壤B、Cu、Mn、Zn、Mo 5种元素为研究对象,在分析微量元素含量状况和分布特征的基础上,从成土母质、土地利用方式、pH值和有机质含量4个方面来分析其对土壤微量元素含量的影响。利用GIS空间分析法、SPSS数理统计法和相关分析法对揭东区土壤微量元素含量、空间分布特征和影响因素进行分析。结果显示:揭东区表层土壤B、Cu、Mn元素的平均含量分别为18.0 mg/kg、14.5 mg/kg、313 mg/kg,含量均处于缺乏水平;Zn元素的平均含量为77.3 mg/kg,总体处于较丰富水平;Mo元素的平均含量为1.31 mg/kg,含量丰富。相关分析表明B、Cu、Mn、Zn、Mo均受到成土母质和土地利用方式的影响,在粉砂岩成土母质区土壤中B和Mn含量最高,凝灰岩成土母质区土壤中Cu和Mo含量最高,Zn在第四纪沉积物中含量最高;比较各种利用方式的土壤,B、Cu在农用地中含量最高,Mn、Zn和Mo在建设用地中含量最高;土壤pH值与B、Cu、Mn、Zn含量呈极显著的正相关关系(P<0.01);土壤有机质与B、Cu、Zn含量呈极显著的正相关关系(P<0.001... 相似文献
13.
小秦岭金矿区土壤重金属生物有效性与影响因素 总被引:1,自引:0,他引:1
土壤中重金属生物有效性与影响因素分析是土壤重金属风险管控的关键问题。通过实地调查、现场采样、实验测试、综合分析等方法,分析了研究区100km2内Hg、Pb、Cd、Cr、As、Cu、Zn七种重金属元素的有效态含量特征,研究了这些重金属有效态含量之间、有效态含量与全量、有效态与土壤pH、有机质含量、粒度等基本理化参数之间的相关性,分析了重金属污染来源。结果表明,土壤中Hg、Pb、Cd、Cr、As、Cu、Zn七种重金属有效态的平均含量分别为2.29mg/kg、594mg/kg、2.52mg/kg、6.30mg/kg、2.16mg/kg、48.14mg/kg、50.21mg/kg,其变异系数大小为:HgPbCuZnCdAsCr。Hg的变异系数最大,是由于金矿选矿活动采用混汞法提金排放的尾矿堆(库)分布不均。Hg、Pb、Cd、Cu、Zn有效态量与全量之间均存在显著的相关性;土壤有机质与重金属有效态之间存在显著的相关性;土壤pH与有效态重金属之间存在显著的负相关性;土壤粒度对重金属有效态的累积影响不明显。 相似文献
14.
为定量化分析地理因子对土壤中铜(Cu)、钴(Co)、钼(Mo)和锌(Zn)空间分异的影响,作者采集和测定了四川盆地长寿之乡江津区156件表土样品,综合运用数理统计、地统计和地理探测器等方法,分析表土中Cu、Co、Mo和Zn含量的空间分异特征及其驱动因子。表土中Cu、Co、Mo和Zn均值分别为27.0×10-6、18.5×10-6、0.4×10-6和216.8×10-6,分别是中国土壤背景值的1.19倍、1.45倍、0.20倍和2.17倍。研究区表层土壤中Cu(36.6%)、Co(16.9%)、Mo(51.7%)和Zn(89.4%)变异系数都呈中等变异,但Zn和Mo的空间分布不均匀性更加显著。总体上,江津区表土中Cu、Co、Mo和Zn含量在北部相对较高,而南部地区相对较低。土壤中Fe和Mn及成土母岩和土壤类型分别是影响江津区表土中Cu、Co、Mo和Zn空间分异的主控驱动因子,但影响程度不一。总体上,Fe和Mn的独立及交互作用最高,对江津区表土中Cu、Co、Mo和Zn含量的空间分异起到重要作用。 相似文献
15.
X. J. Wang R. M. Liu K. Y. Wang J. D. Hu Y. B. Ye S. C. Zhang F. L. Xu S. Tao 《Environmental Geology》2006,49(8):1208-1216
Polycyclic aromatic hydrocarbons (PAHs) in soil originate from various sources under different spatial scales. Coregionalization
analysis is more revealing than univariate geostatistical analysis. Scale-dependent spatial features of variables reflect
different sources of spatial variability. In this study, 188 topsoil samples in the Tianjin area were collected. The contents
of 16 PAHs and soil background properties were determined for all samples. A multivariate geostatistical approach was used
for multi-scale spatial analysis for PAH compounds. Results show that coal combustion was the major source for the spatial
distribution patterns of PAHs in the topsoil of the studied area. It worked mainly at the short-range scale (5–10 km). Significant
spatial variation patterns were identified. In contrast, no significant spatial distribution trends at the nugget (0–5 km)
or long-range scales (10–50 km) were seen. Long-range transport and site contamination of PAHs might not be key contributors
in forming the distribution pattern of PAHs in the topsoil of Tianjin area. 相似文献
16.
Yongcun Zhao Xianghua Xu Biao Huang Weixia Sun Xuexin Shao Xuezheng Shi Xinling Ruan 《Environmental Geology》2007,52(7):1423-1433
A total of 540 topsoil samples (0–15 cm), 188 subsoil samples (20–40 cm), and four individual soil profiles were collected
in this study for mapping the Cu- and Pb-contaminated areas in soils of Zhangjiagang city, an industrialized city in the Yangtze
River Delta region of China. Robust geostatistical methods were applied for identifying possible spatial outliers of Cu and
Pb data, and then a sequential Gaussian simulation was employed for delineating the potential areas where Cu or Pb concentration
was affected by diffuse pollution. The results showed that the spatial outliers of Cu and Pb were strongly associated with
various types of factories. The anthropogenic input of Cu to soils at local hotspots was closely related to emissions of printing
and dyeing, metallurgical, and chemical factories, whereas a lead oxide factory and a chemical factory resulted in a considerable
increase of Pb in the topsoil of the study area. Approximately 30% of the total land area of the study was at potential risk
from the Cu or Pb diffuse pollution resulting from rapid industrialization of the area over the past 20 years. 相似文献
17.
Hun-Bok Jung Seong-Taek Yun Bernhard Mayer Soon-Oh Kim Seong-Sook Park Pyeong-Koo Lee 《Environmental Geology》2005,48(4-5):437-449
Transport and sediment–water partitioning of trace metals (Cr, Co, Fe, Pb, Cu, Ni, Zn, Cd) in acid mine drainage were studied
in two creeks in the Kwangyang Au–Ag mine area, southern part of Korea. Chemical analysis of stream waters and the weak acid
(0.1 N HCl) extraction, strong acid (HF–HNO3–HClO4) extraction, and sequential extraction of stream sediments were performed. Heavy metal pollution of sediments was higher
in Chonam-ri creek than in Sagok-ri creek, because there is a larger source of base metal sulfides in the ores and waste dump
upstream of Chonam-ri creek. The sediment–water distribution coefficients (K
d) for metals in both creeks were dependent on the water pH and decreased in the order Pb ≈ Al > Cu > Mn > Zn > Co > Ni ≈ Cd.
K
d values for Al, Cu and Zn were very sensitive to changes in pH. The results of sequential extraction indicated that among
non-residual fractions, Fe–Mn oxides are most important for retaining trace metals in the sediments. Therefore, the precipitation
of Fe(–Mn) oxides due to pH increase in downstream sites plays an important role in regulating the concentrations of dissolved
trace metals in both creeks. For Al, Co, Cu, Mn, Pb and Zn, the metal concentrations determined by 0.1 N HCl extraction (Korean
Standard Method for Soil Pollution) were almost identical to the cumulative concentrations determined for the first three
weakly-bound fractions (exchangeable + bound to carbonates + bound to Fe–Mn oxides) in the sequential extraction procedure.
This suggests that 0.1 N HCl extraction can be effectively used to assess the environmentally available and/or bioavailable
forms of trace metals in natural stream sediments. 相似文献
18.
Distribution of Cd,Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China 总被引:2,自引:0,他引:2
An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province,
China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy
metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented
a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China.
The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr
and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction,
and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than
50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration,
and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and
Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing
soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than
acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values.
And the residual fraction of Cu took a predominant part (50%) of the total content. 相似文献
19.
铅锌矿尾砂重金属污染物对不同土地利用类型土壤性质影响的典范对应分析 总被引:4,自引:1,他引:3
广西阳朔思的村铅锌矿尾矿砂坝坍塌造成了大面积农田污染,已往报道多集中在金属矿山开采过程中产生的废液及大量固体废弃物堆砌而造成的环境污染,较少关注因尾矿砂坝坍塌所造成的这种土壤重金属特殊污染模式。本文运用典范对应分析(CCA)研究铅锌矿尾砂坝坍塌对不同土地利用类型(玉米地、柑橘园、水稻田)造成的重金属(铅、锌、铜、镉)污染以及对土壤理化性质(有机碳、碱解氮、速效磷、速效钾、阳离子交换量、碳氮比、pH值)的影响。CCA分析结果表明,研究区污染以铅、锌、镉为主,铜次之,其中锌和镉的空间分布格局受土地利用类型的影响更明显,并且镉对水稻田产生的环境风险最高。此外,在土壤中尾矿砂分布不均的前提下,土地利用类型是造成土壤重金属污染空间分布不同的重要驱动力,受土壤质地和矿砂性质的影响,重金属污染引起的酸化效应在供试土壤中不明显,使得CCA图中pH值所代表的点远离重金属箭头连线;阳离子交换量距重金属连线较近,受重金属影响明显并随重金属污染的加剧而减小;碱解氮、速效磷、速效钾等速效养分受重金属污染的影响并不显著,但与施肥配比和农业管理密切相关;有机碳与重金属箭头连线分布象限相同且包裹于其中,与重金属质量分数呈正相关关系,相较于玉米地和柑橘园,水稻田中有机碳积累量更大,达到18.14 g/kg,可能因稻田中微生物的碳源代谢利用能力明显降低,土壤中有机碳的矿化分解受阻,导致水稻土中有机碳的积累。此外,尾矿砂作为土壤重金属的持续性释放源,尽管对土壤的基本理化性质尤其是速效养分的影响并不明显,但能够通过影响土壤微生物群落间接影响土壤碳循环。 相似文献
20.
The distribution of heavy metal in surface soils and their uptake by plants along roadside slopes in longitudinal range gorge region,China 总被引:1,自引:1,他引:0
Metal distributions (Cd, Cr, Cu, Ni, Pb and Zn) in the soils and plants were investigated in roadside surface soils and grass
herbage collected from two study sites adjacent to Mangshi–Ruili and Dali–Baoshan highways. At each study site, soil and plant
samples were collected along two roadside slopes with distances of 5, 10, 20, 50, 100, and 200 m away from the highway. Results
show that the enrichment of heavy metals in the surface soils and plants along the road is caused by the highway, and it decreases
with the increasing distance from the road. Metal concentrations in the soils and plants along the downslope are higher than
those in the upslope along the road. The six types of metals investigated in this research mainly distributed within 200 m
from the highway. Four types of relationships between metal uptake by plants from soils and the distance were found and their
clear distinctions of Cr, Cu, Pd, Ni and Zn uptake by plants were also investigated. 相似文献