280–310 Ma rift-related basaltic magmatism in northern Baoshan,SW China: Implications for Gondwana reconstruction and mineral exploration

The temporal and spatial variations of Late Paleozoic basaltic lavas in Baoshan, the northern part of a Gondwana-derived micro-continental block called Sibumasu, are important for Gondwana reconstruction. Magmatic zircon crystals from three selected dolerite dykes in the Baoshan region yield U-Pb ages from ~295 to ~310 Ma. These new ages, together with previous zircon U-Pb ages for this type of rock, define a protracted (~30 myr) episode of basaltic magmatism from ~310 to 280 Ma in a small area of this region, which is inconsistent with the typical temporal-spatial distribution of mantle plume magmatism. The trace element compositions of the Baoshan dolerite dykes and associated lavas are similar to arc basalts as well as continental flood basalts worldwide, showing light REE enrichments and negative Nb-Ta anomalies. Mixing calculations using the Sr-Nd-Hf isotope data of the Baoshan mafic rocks indicate that their intriguing trace element characteristics can be explained by contamination of mantle-derived magmas with crustal materials. Our new data, together with the lack of Late Paleozoic are-related calcalkaline rocks and granitoids in the Sibumasu block and other contemporaneous Gondwana-derived micro-continental blocks, strongly support the premise that the 310–280 Ma basalts and dolerites in the Baoshan region are the products of continental rift-related magmatism rather than arc magmatism. Based on the temporal correlation of the 310–280 Ma rift-related magmatism in several related Gondwana-derived micro-continents (Sibumasu, South Qiangtang, Lhasa and Himalaya), plus other independent constraints such as paleoclimate biotas and paleolatitudes from the literature, we provide an improved model for the configuration of the Gondwana supercontinent in the Early Permian. Based on the results from this study, we conclude that further investment in the exploration of magmatic Ni-Cu sulfide deposits associated with the 310–280 Ma mafic-ultramafic intrusions in northern Baoshan and the other related Gondwana-derived micro-continental blocks is warranted.     

Climatic control on the composition of Carboniferous–Permian Gondwana sediments,Khalaspir basin,Bangladesh

Late Paleozoic or Permo-Carboniferous Gondwana successions world-wide are marked by widespread and lengthy glaciation (~ 67 Ma), and multiple transitions from Icehouse to Greenhouse state. Mineralogical and compositional changes in sandstones and mudstones of the Gondwana succession in drill hole GDH-45 from the Khalaspir basin of Bangladesh are interpreted in a climatic framework, using the proxies of the Mineralogical Index of Alteration (MIA) and the Chemical Index of Alteration (CIA). Low MIA (< 75) and CIA (< 70) values in the lowermost unit (Unit 1) of the Khalaspir Gondwana sequence indicates minimal chemical weathering of the source and imply cold and dry glacial climatic conditions. Values increase progressively in the overlying Unit 2, suggesting warming and deglaciation. Very high MIA (80–100) and CIA (90–100) values in Unit 3 indicate intense chemical weathering associated with warm and humid climatic conditions in a post-glacial setting. These changes are recorded in both sandstones and mudstones, illustrating the value of acquiring data for a variety of size grades. The stratigraphic changes are also well recorded by progressively decreasing K₂O/Al₂O₃ and increasing Ga/Rb ratios, the combination of which may comprise a new geochemical proxy of climate and weathering. Upward increase in the modal Q / (F + L) and Qp / (F + L) ratios are also consistent with change from cool to warm and humid climate in the source region. The change in climatic conditions within the Khalaspir sequence is also well correlated with the Gondwana successions of other continental blocks, and records the climatic fluctuations and extent of climatic impact in Gondwanaland during the Permo-Carboniferous.     

Tracing the position of the South China block in Gondwana: U–Pb ages and Hf isotopes of Devonian detrital zircons

U–Pb detrital zircon geochronology from Lower Devonian quartz arenites of the northwestern margin of the Yangtze block yields dominant early Neoproterozoic (0.85–1.0 Ga), Pan-African (0.5–0.65 Ga) and middle Neoproterozoic (0.68–0.8 Ga) age populations and minor Mesoproterozoic to middle Mesoarchean (1.0–3.0 Ga) ages. Middle Mesoarchean to Mesoproterozoic rocks, however, are widespread in the South China block. Although Hf isotopic compositions show both juvenile crustal growth and crustal reworking for all the age groupings, the crust growth, essentially mantle-derived, occurred mainly around 3.1 Ga, 1.9 Ga and 1.0 Ga, respectively. Zircon typology and youngest grain ages indicate that this suite of quartz arenites was the product of multiphase reworking. Abundant magmatic zircon detritus with concordant U–Pb Grenvillian and Pan-African ages, together with accompanying various ε_Hf(t) values, indicate an exotic provenance for the quartz arenite external to the South China block. Qualitative comparisons of age spectra for the late Neoproterozoic sediments of the Cathaysian Block, early Paleozoic sediments of pre-rift Tethyan Himalaya sequence in North India and lower Paleozoic sandstone from the Perth Basin in West Australia, show that they all have two the largest age clusters representing Grenvillian and Pan-African orogenic episodes. The resemblance of these age spectra and zircon typology suggests that the most likely source for the Lower Devonian quartz arenites of the South China block was the East African Orogen and Kuunga Orogen for their early Grenvillian and Pan-African populations, whereas the Hannan–Panxi arc, Jiangnan orogen, and the Yangtze block basements might have contributed to the detrital zircon grains of the Neoproterozoic and Pre-Grenvillian ages. Hf isotopic data indicate that the crustal evolution of the drainage area matches well with the episodic crust generation of Gondwana. These results imply that the previously suggested position of the SCB in Gondwana should be re-evaluated, and the South China block should be linked with North India and West Australia as a part of East Gondwana during the assembly of Gondwana, rather than a discrete continent block in the paleo-Pacific.     

The 7^th International Symposium on Environmental Geochemistry, September 24-27, 2006, Beijing, China

Preface The International Symposium on Environmental Geochemistry, first held in London, Great Britain in 1985, has become a premier international forum for the presentation and discussion of advances in scientific understanding of environmental geochemistry. The 7^th International Symposium on Environmental Geochemistry is being held in Beijing, China. The symposium is sponsored by the State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences and the Chinese Society for Mineralogy, Petrology and Geochemistry.     

Origin of the Maoduan Pb–Zn–Mo deposit, eastern Cathaysia Block, China: geological, geochronological, geochemical, and Sr–Nd–Pb–S isotopic constraints

The Maoduan Pb–Zn–Mo deposit is in hydrothermal veins with a pyrrhotite stage followed by a molybdenite and base metal stage. The Re–Os model ages of five molybdenite samples range from 138.6 ± 2.0 to 140.0 ± 1.9 Ma. Their isochron age is 137.7 ± 2.7 Ma. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the nearby exposed Linggen granite porphyry gave a ²⁰⁶Pb/²³⁸U age of 152.2 ± 2.2 Ma and the hidden Maoduan monzogranite yielded a mean of 140.0 ± 1.6 Ma. These results suggest that the intrusion of the Maoduan monzogranite and Pb–Zn–Mo mineralization are contemporaneous. δ ³⁴S values of sulfide minerals range from 3.4‰ to 4.8‰, similar to magmatic sulfur. Four sulfide samples have ²⁰⁶Pb/²⁰⁴Pb = 18.252–18.432, ²⁰⁷Pb/²⁰⁴Pb = 15.609–15.779, and ²⁰⁸Pb/²⁰⁴Pb = 38.640–39.431, similar to the age-corrected data of the Maoduan monzogranite. These isotope data support a genetic relationship between the Pb–Zn–Mo mineralization and the Maoduan monzogranite and probably indicate a common deep source. The Maoduan monzogranite has geochemical features similar to highly fractionated I-type granites, such as high SiO₂ (73.7–75.2 wt.%) and alkalis (K₂O + Na₂O = 7.8–8.9 wt.%) and low FeO_t (0.8–1.3 wt.%), MgO (~0.3 wt.%), P₂O₅ (~0.03 wt.%), and TiO₂ (~0.2 wt.%). The granitic rocks are enriched in Rb, Th, and U but depleted in Ba, Sr, Nb, Ta, P, and Ti. REE patterns are characterized by marked negative Eu anomalies (Eu/Eu^* = 0.2–0.4). The Maoduan monzogranite, having (⁸⁷Sr/⁸⁶Sr) _t  = 0.7169 to 0.7170 and ε_Nd(t) = −13.8 to −13.7, was probably derived from mixing of partial melts from enriched mantle and the Paleoproterozoic Badu group in an extensional tectonic setting.     

Natural disasters in China: 1900–2011

China is a country prone to high frequency of natural catastrophic events. According to the natural disaster data from 1900 to 2011, the major disaster types include drought, earthquake, epidemic, extreme temperature, flood, mass movement wet and storm. The occurrence of natural disaster and economic loss is increased during the studied period. However, the death toll induced by natural disaster is decreased significantly. A new frame of social development and natural disaster is proposed to discuss the impact of population and GDP on the influence of disaster through the recording and reduction efforts. The results indicated that economic development contributes to the reduction in the impact of natural disaster on the people lives and society. New comprehensive integrated management, including international cooperation, should be established.

     

Elemental and organic geochemistry of Gondwana sediments from the Krishna–Godavari Basin,India

Elemental and organic geochemical studies have been carried out on the Gondwana sediments, collected from the outcrops of Permian and Jurassic–Cretaceous rocks in the Krishna–Godavari basin on the eastern coast of India, to understand their paleo and depositional environment and its implications for hydrocarbon generation in the basin. Amongst the studied formations, the Raghavapuram, Gollapalli and Tirupati form a dominant Cretaceous Petroleum System in the west of the basin. Raghavapuram shales and its stratigraphic equivalents are the source rock and Gollapalli and Tirupati sandstones form the reservoirs, along with basaltic Razole formation as the caprock. Major element systematics and X-ray diffraction study of the sandstones indicate them to be variably enriched with SiO₂ relative to Al₂O₃ and CaO, which is associated, inherently with the deposition and diagenesis of the Gondwana sediments. Post-Archean Average Shale normalized rare earth elements in shales show enrichment in most of the samples due to the increasing clay mineral and organic matter assemblage. A negative europium and cerium anomaly is exhibited by the REE's in majority of rocks. Composed primarily of quartz grains and silica cement, the Gollapalli and Tirupati sandstones have characteristics of high quality reservoirs. The shales show a significant increase in the concentration of redox sensitive trace elements, Ni, V, Cr, Ba and Zn. The total organic carbon content of the shales ranges between 0.1 and 0.5 wt%. Programmed pyrolysis of selected samples show the Tmax values to range between 352–497 °C and that of hydrogen index to be between 57–460 mgHC/gTOC. The organic matter is characterized by, mainly, gas prone Type III kerogen. The n-alkane composition is dominated by n-C₁₁–C₁₈ and acyclic isoprenoid, phytane. The aromatic fraction shows the presence of naphthalene, anthracene, phenanthrene, chrysene and their derivatives, resulting largely from the diagenetic alteration of precursor terpenoids. The organic geochemical proxies indicate the input of organic matter from near-shore terrestrial sources and its deposition in strongly reducing, low oxygen conditions. The organic matter richness and maturity derived from a favorable depositional setting has its bearing upon the Gondwana sediments globally, and also provides promising exploration opportunities, particularly in the Raghavapuram sequence of the KG basin.     

China’s container-related dynamics, 1990–2005

This study seeks to gauge how far China’s container-related dynamics between 1990 and 2005 fit into the wider perspective about transport and development within developing countries. In particular, attention is focussed on the role of specific modes to determine the extent of the penetration of containers within China. Before addressing these key issues extant models relating to an understanding of port and transport evolution in less-developed countries are recalled, synthesized and used as a base upon which an appropriate review of China’s case can be conducted. Applying them to China’s northern, central and southern port ranges not only helps assess the efficacy of these models but also highlights the contribution of individual modes.