Interpretation of SOFIE PMC measurements: Cloud identification and derivation of mass density,particle shape,and particle size

The Solar Occultation For Ice Experiment (SOFIE) was launched onboard the Aeronomy of Ice in the Mesosphere (AIM) spacecraft to measure polar mesospheric clouds (PMCs) and their environment. This work describes methods for identifying PMCs in SOFIE observations and determining mass density, particle shape, particle effective radius, and the parameters of a Gaussian size distribution. Results using SOFIE measurements from the northern summer of 2007 are compared with concurrent observations by the ALOMAR lidar in northern Norway. Ice particle properties determined from SOFIE are in good agreement with the lidar results, considering the differences in instrument characteristics.     

Phase functions of polar mesospheric cloud ice as observed by the CIPS instrument on the AIM satellite

The Cloud Imaging and Particle Size (CIPS) instrument on the Aeronomy of the Ice in the Mesosphere (AIM) spacecraft is a 4-camera nadir pointed imager with a bandpass centered at 265 nm and a field of view of 120°×80°. CIPS observes polar mesospheric clouds (PMCs) against the sunlit Rayleigh-scattered background. At individual polar locations approximately 5 km×5 km in area, CIPS observes the same volume of air seven times over a range of scattering angles from about 35° to 150°. These multi-angle observations allow the identification and extraction of the PMC scattered radiance from the Rayleigh-scattered background. We utilize the fact that the former has a highly asymmetric phase function about 90° scattering angle, while the latter has a phase function that is symmetric. The retrieved PMC phase function can then be interpreted to obtain PMC particle size distributions. We describe a technique for identification of PMCs in the CIPS observations through the separation of the Rayleigh and PMC radiances. PMC phase function results are shown for the first season of CIPS observations. Assuming the particles are oblate spheroids with an axial ratio of 2, and a Gaussian distribution of width 14 nm, we find the phase functions are consistent with mean radii between 50 and 60 nm. These results are similar to those discussed by Hervig et al. [2009. Interpretation of SOFIE PMC measurements: cloud identification and derivation of mass density, particle shape, and particle size. J. Atmos. Sol. Terr. Phys., in review.] in this issue from the Solar Occultation for Ice Experiment (SOFIE) which also flies on the AIM satellite.     

SOFIE PMC observations during the northern summer of 2007

This work examines the first season of polar mesospheric cloud (PMC) observations from the Solar Occultation for Ice Experiment (SOFIE). SOFIE observations of temperature, water vapor, and PMC frequency, mass density, particle shape, and size distribution are used to characterize the seasonal evolution and altitude dependence of mesospheric ice and the surrounding environment. SOFIE indicates that ice is nearly always present during summer, and that the ice layer is continuous from about 81 km altitude to the mesopause and above. Ice particles are observed to be more aspherical above and below the extinction peak altitude, suggesting a relationship between particle shape and mass density. The smallest particles are observed near the top of the ice layer while the largest particles exist at low concentrations near cloud base. A strong correlation was found between water vapor and particle size with small particles existing when H₂O is low. This relationship holds when examining variability in altitude, and variability over time at one altitude.     

Field experiments constraining the probability distribution of particle travel distances during natural rainstorms on different slope gradients

Rain splash erosion is an important soil transport mechanism on steep hillslopes. The rain splash process is highly stochastic; here we seek to constrain the probability distribution of splash transport distances on natural hillslopes as a function of hillslope gradient and total precipitation depth. Field experiments were conducted under natural precipitation events to observe splash travel on varying slope gradients. The downslope fraction of splash transport on 15°, 25° and 33° gradients were 85%, 96% and 96%, respectively. Maximum splash transport (L_max) was related to the rain splash detachment of soil particles and slope gradient. An empirical relationship of L_max to the precipitation depth and gradient was obtained; it is linearly proportional to hillslope gradient and logarithmically related to precipitation depth. Measured splash distances were calibrated to the fully two‐dimensional (2D) model of splash transport of Furbish et al. (Journal of Geophysical Research 112 : F01001, 2007) that is based on the assumption that radial splash distances are exponentially distributed; calibrated values of mean splash transport distances are an order of magnitude greater than those previously determined in a controlled laboratory setting. We also compared measured data with several one‐dimensional (1D) probability distributions to asses if splash transport distances could be better explained by a heavy‐tailed probability distribution rather than an exponential probability distribution. We find that for hillslopes of 15° and 25°, although a log‐normal probability distribution best describes the data, we find its likelihood is nearly indistinguishable from an exponential distribution based on computing maximum likelihood estimators for all 1D distributions (exponential, log‐normal and Weibull). At 33°, however, we find stronger evidence that measured travel distances are heavy‐tailed. Copyright © 2011 John Wiley & Sons, Ltd.     

Palaeomagnetism of Upper Cretaceous volcanic rocks from Cabo de Sto. Agostinho,Brazil

One hundred samples from nine sites in Upper Cretaceous volcanics (K/Ar age 85–99 m.y.) of the magmatic province of Cabo de Santo Agostinho, Pernambuco (8.4°S, 35.0°W) yield a mean direction of magnetizationD = 0.4°, I = ?20.6°withα₉₅ = 4.8°, k = 114 after AF cleaning. All sites have normal polarity with a mean pole, named SAK₁₀, at 87.6°N, 135°E withA₉₅ = 4.5° which is close to other Upper Cretaceous poles for South America. These poles are compared with Upper Cretaceous poles of Africa for various reconstructions of the two continents.     

Palaeomagnetism of Mesozoic igneous rocks from the Maranha˜o Basin,Brazil, and the time of opening of the South Atlantic

From Middle-Upper Jurassic volcanics at the western margin of the Maranha?o Basin (6.4°S, 47.4°W) 15 sites (121 samples) have a mean magnetization directionD = 3.9°,I = ?17.9° withα₉₅ = 9.3°,k = 17.9 after AF cleaning (all sites have normal polarity). This yields a pole (named SAJ₂) at 85.3°N, 82.5°E (A₉₅ = 6.9°) which is near to the other known Middle Jurassic South American pole. For 21 sites (190 samples) from Lower Cretaceous basalt intrusions from the eastern part of the Maranha?o Basin (6.5°S, 42°W) the mean direction isD = 174.7°,I = +6.0° withα₉₅ = 2.8°,k = 122 (all sites have reversed polarity) yielding a pole (SAK₉) at 83.6°N, 261°E (A₉₅ = 1.9°) in agreement with other Lower Cretaceous pole positions for South America. Comparing Mesozoic pole positions for South America and Africa in the pre-drift configuration after Bullard et al. [13] one finds a significant difference (with more than 95% probability) for the Lower Cretaceous and Middle Jurassic poles and also a probable difference for the mean Triassic poles indicating a small but probably stationary separation of the two continents from the predrift position in the Mesozoic until Lower Cretaceous time which may be due to an early rifting event.     

Electrical conductivity of igneous rocks: Composition and temperature relations

The conductivity of four igneous rocks with, 49, 65, 77, and 84% SiO₂ was measured as a function of temperature in the interval from 20° to 1280°C; measurements were made in a vacuum of 10^?3 torr. No simple relationships were found between conductivity and SiO₂ content or versus major element groupings such as Na₂O=K₂O=CaO and TiO₂=Cr₂O₃=Al₂O₃=Fe₂O₃=FeO. An analytical expression was obtained between conductivity and the albite-quartz ratio, valid for temperatures between 300° and 1200°C. It was necessary to compute the CIPW norm in order to obtain the albite and quartz percentages. The onset of melting apparently occurred between 600° and 700°C. Petrography performed on two samples after cooling showed 70 and 85% partial melting. Three conduction regions were identified: 1) below 300°C, 2) between 300°C and 600°C, and 3) above 600°C. Different activation energies obtained for the heating and cooling intervals confirm that the sample undergoes textural changes in the heating-cooling cycle. Activation energy increments of 0.1 and 0.2 eV per decade of albite-quartz ratio were obtained.     

Paleomagnetic constraints on Miocene rotation in the central Japan Arc

We present new Middle Miocene paleomagnetic data for the central Japan Arc, and discuss their implications for Miocene rotation. To obtain a refined paleodirection, we made magnetic measurements on basaltic to andesitic lavas and intrusive rocks from 12 sites in the Tsugu volcanic rocks (ca 15 Ma) in the northern part of the Shitara area, Japan. Significant secondary magnetizations in samples with strong magnetic intensities are interpreted as lightning‐induced components. Mean directions carried by magnetite and/or titanomagnetite were determined for all sites. An overall mean direction with a northerly declination was obtained from dual‐polarity site means for nine sites. This direction is indistinguishable from the mean direction for coeval parallel dikes in the northern part of the Shitara area, and also indistinguishable from the Miocene reference direction derived from the paleopole for the North China Block in the Asian continent. These comparisons suggest little or no rotation or latitudinal motion in the study area with respect to the North China Block since 15 Ma. We obtained a refined early Middle Miocene paleodirection (D = 9.7°, I = 52.5°, α₉₅ = 4.8°; 30 sites) and paleopole (82.0°N, 230.8°E, A₉₅ = 5.6°) for Shitara by combining data from the Tsugu volcanic rocks and a coeval dike swarm. An anomalous direction found at three sites could be a record of an extraordinary field during a geomagnetic polarity transition or excursion. Paleomagnetic data from Shitara suggest that: (i) the western wing of the Kanto Syntaxis, a prominent cuspate geologic structure in central Honshu, underwent a counterclockwise rotation with respect to the main part of the southwestern Japan Arc between ca 17.5 Ma and 15 Ma; (ii) collision between the Japan and Izu–Bonin (Ogasawara) Arcs began prior to 15 Ma; and (iii) clockwise rotation of the entire southwestern part of the Japan Arc had ceased by 15 Ma.     

Crystallization of tholeiitic basalt in Alae Lava Lake,Hawaii

The eruption of Kilauea Volcano August 21–23, 1963, left 600,000 cubic meters of basaltic lava in a lava lake as much as 15 meters deep in Alae pit crater. Field studies of the lake began August 27 and include repeated core drilling, measurements of temperature in the crust and melt, and precise level surveys of the lake surface. The last interstitial melt in the lake solidified late in September 1964; by mid August 1965 the maximum temperature was 690°C at a depth of 11.5 meters. Pumice air-quenched from about 1140°C contains only 5 percent crystals — clinopyroxene, cuhedral olivine (Fo ₈₀), and a trace of plagioclase, (An ₇₀). Drill cores taken from the zone of crystallization in the lake show that olivine continued crystallizing to about 1070°C; below that it reacts with the melt, becoming corroded and mantled by pyroxene and plagioclase. Below 1070°C, pyroxene and plagioclase crystallized at a constant ratio. Ilmenite first appeared at about 1070°C and was joined by magnetite at about 1050°C; both increased rapidly in abundance to 1000°C. Apatite first appeared as minute needles in interstitial glass at 1000°C. Both the abundance and index of refraction of glass quenched from melt decreased nearly linearly with falling temperature. At 1070°C the quenched lava contains about 65 percent dark-brown glass with an index of 1.61; at 980°C it contains about 8 percent colorless glass with an index of 1.49. Below 980°C, the percentage of glass remained constant. Progressive crystallization forced exsolution of gases from the melt fraction; these formed vesicles and angular pores, causing expansion of the crystallizing lava and lifting the surface of the central part of the lake an average of 19.5 cm. The solidified basalt underwent pneumatolitic alteration, including deposition of cristobalite at 800°C, reddish alteration of olivine at 700°C, tarnishing of ilmenite at 550°C, deposition of anhydrite at 250°C, and deposition of native sulfur at 100°C. Ferric-ferrous ratios suggest that oxidation with maximum intensity between 550°C and 610°C moved downward in the crust as it cooled; this was followed by reduction at a temperature of about 100°C. The crystallized basalt is a homogeneous fine-grained rock containing on the average 48.3 percent by volume intergranular pyroxene (augite > pigeonite), 34.2 percent plagioclase laths (An_{60 70}), 7.9 percent interstitial glass, 6.9 percent opaques (ilmenite > magnetite), 2.7 percent olivine (Fo_{70 80}), and a trace of apatite. Chemical analyses of 18 samples, ranging from initially quenched pumice to lava cored more than a year after the eruption from the center and from near the base of the lake, show little variation from silica-saturated tholeiitic basalt containing 50.4 percent SiO₂, 2.4 percent Na₂O, and 0.54 percent K₂O. Apparently there was no significant crystal settling and no appreciable vapor-phase transport of these components during the year of crystallization. However, seven samples of interstitial liquid that had been filter-pressed into gash fractures and drill holes from partly crystalline mush near the base of the crust show large differences from the bulk composition of the solidified crust—lower MgO, CaO, and Al₂O₃; and higher total iron, TiO₂, Na₂O, K₂O, P₂O₅, and F, and, in most samples, SiO₂. The minor elements Ba, Ga, Li, Y, and Yb and possibly Cu tend to be enriched in the filter-pressed liquids, and Cr and possibly Ni tend to be depleted.     

Paleomagnetism of certain constituents of the Bay St. George sub-basin,western Newfoundland

Paleomagnetic studies have been made of certain constituents of the Bay St. George sub-basin. Specifically, results are reported from the Spout Falls Formation (Tournaisian), the Jeffreys Village Member of the Robinsons River Formation (Visean), and the Searston Formation (Namurian-Westphalian). The following magnetizations have been isolated: Spout Falls A (Tournaisian) with D = 343.5°, I = ?22.7°, k = 61.2, α₉₅ = 7.1° and the corresponding pole at 28.6°N, 139.5°E (4.5°, 8.5°); Spout Falls B (Kiaman) with D = 166.7°, I = 12.2°, k = 51.7, α₉₅ = 10.7° and the corresponding pole at 34.5°S, 42.7°W (5.5°, 10.9°); Jeffreys Village A (Visean) with D = 351.2°, I = ?27.3°, k = 54.0, α₉₅ = 7.6° and the corresponding pole at 26.5°N, 130.7°E (4.5°, 8.3°); Searston A (Namurian) with D = 161.7°, I = 11.7°, k = 107, α₉₅ = 7.4° and the corresponding pole at 33.9°S, 37.2°W (3.8°, 7.5°); and Searston C with D = 111.6°, I = ?13.8°, k = 28.8, α₉₅ = 14.5° and the corresponding pole at 19.6°S, 19.0°E (7.6°, 14.8°). After comparison with paleopoles of similar ages derived from eastern and western Newfoundland rocks, from constituents of the east coast basin and for interior North America, it is concluded that: (1) it is unlikely that any large scale relative motion took place since the Early Carboniferous between eastern and western Newfoundland; (2) it is unlikely that any north-south relative motion took place between the east coast basin and the Bay St. George sub-basin; and (3) the Bay St. George sub-basin results do not support the earlier proposed displaced terrane hypothesis of the northern Appalachians in as much as the motions during the Carboniferous are not supported. There is evidence of the northward motion of the Appalachians and North America as a whole during the Carboniferous. The magnetostratigraphic horizon marker in the Carboniferous separating a dominant normal and reversed magnetization on the older side and an entirely reversed (Kiaman) magnetization on the younger side may be placed in the Bay St. George sub-basin at the base of the Searston Formation.     

Studies in diffusion,IV. Pressure dependence of Ar diffusion in phlogopite mica

Radiogenic Ar diffusion from phlogopite mica has been measured at 900° and 1080°C at 15 kbars pressure, using a Griggs-type hot creep tester operated at hydrostatic pressure, and followed by standard mass spectrometric analysis. The diffusion coefficients fall within the uncertainty of the diffusion results reported by Giletti (1974) at 1 kbar at 900° and on extrapolation of that Arrhenius plot to 1080°C. That linear plot is given by D₀ = 0.75 and Q = 57.9kcal/g-atom Ar. In the observed temperature range, the effect of pressure up to 15 kbars is not significant. A second Ar diffusion, which employed Ca(OH)₂-CaO as a water buffer, was run at 1 atm H₂O pressure and 550°C for 781 days. The resulting diffusion coefficient agrees, within the uncertainty, with the extrapolation of the earlier curve. This result, and both earlier ones at 600°, are similar in that they fall below the curve. Consequently, despite the agreement within the uncertainty, it is possible that diffusion of Ar from phlogopite below 650°C is somewhat slower than given by the above equation parameters.     

Paleomagnetic study of Cambrian Potsdam Group sandstones,St. Lawrence Lowlands,Quebec

We report paleomagnetic results from oriented drill core samples collected at 10 sites (80 samples) from the Covey Hill and 19 sites (96 samples) from the overlying, fossiliferous Cha?teauguay Formations of the gently dipping Late Cambrian Potsdam Group sandstones exposed in the St. Lawrence Lowlands of Quebec. Stepwise thermal demagnetization analyses ave revealed the presence of two predominant groups of coherent magnetizations C-1 and C-2, after simple correction for bedding tilt. The C-1 group magnetization is a stable direction (D=332°, I=+18°) with unblocking temperatures (T_UB) between 550 and 650°C, present in the older Covey Hill Formation; this direction is probably a chemical remanence acquired during the Covey Hill diagenesis and carried predominantly by hematite. The C-2 group magnetization (D=322°, I=+9°) is present at 13 sites of the younger Cha?teauguay Formation; this is probably carried by magnetite and represents a penecontemporaneous, depositional DRM, characterized by T_UB spectra 400–550°C. We believe that C-2 is relatively younger than C-1 based on a combination of arguments such as the presence of opposite polarities, internal consistency, similarity and common occurrence of C-1 and C-2 respectively in the Covey Hill and Cha?teauguay members. The corresponding paleomagnetic poles C-1 (46°N, 149°E; dp, dm=3°, 5°) and C-2 (37°N, 156°E; dp, dm=2°, 5°) are not significantly different from most of the other Late Cambrian (Dresbachian-Franconian) poles derived from sediments exposed in the southern region (Texas) of the North American craton which are also believed to have been deposited during Croixian Sauk sea transgression similar to the Potsdam sandstones. Although adequate faunal control is lacking (in particular for the Covey Hill Formation), this comparison with the Cratonic poles suggests a Late Cambrian age to the Potsdam poles. The agreement between the results also gives the evidence for internal consistency of cratonic poles at least for Late Cambrian.The incoherent C-3 group remanence (D=250°, I=?15°) is commonly present at 7 sites in both the formations; this may not correspond to a reliable paleomagnetic signal. The other remanence C-4 (D=180°, I=+10°) is found only at 3 sites located in the uppermost stratigraphic levels of the Cha?teauguay Formation; the corresponding paleomagnetic pole (40°N, 107°E) does not differ significantly from the Ordovician and some Late Cambrian poles. The present data are insufficient to resolve a problem in apparent polar wander for Middle and Late Cambrian time posed by the existence of high-latitude poles for some strata of Middle Cambrian age and low-latitude poles for some strata of Late Cambrian age.     

Gas composition of Popocatépetl Volcano between 2007 and 2008: FTIR spectroscopic measurements of an explosive event and during quiescent degassing

On December 1, 2007, the solar absorption infrared spectra of the Popocatépetl volcanic plume was recorded during an eruptive event and complementarily on November 17, 2008, the passive quiescent degassing was measured from the same site. A portable FTIR spectrometer with a scanning mirror for fast tracking of the sun provided the flexibility, quality, and simplicity needed for field deployment. Slant columns of the gases SO₂, HCl, HF, and SiF₄ were retrieved and strong differences could be observed when comparing gas ratios in both time periods. During the explosive eruption, the SO₂/HCl ratio was three times greater and the HF/HCl ratio was slightly smaller than during passive degassing.While the ratios among SO₂, HCl, HF, and SiF₄ describe the chemical composition of the volcanic gas mixture, the SiF₄/HF ratio provides information about the equilibrium temperatures of the stored gases which in this study were calculated at 150° and 185 °C for the explosive and quiescent degassing episodes, respectively. We conclude that cooling of lava domes in the crater precedes Vulcanian explosions as suggested by Schaaf et al (2005). Based on SO₂ flux (Grutter et al., 2008) and measurements and data from the November 2008 event, the average fluxes for HCl, HF, SiF₄, and F through quiescent degassing are estimated to be 204, 22.7, 9.8, and 31.7 tons/day, respectively. These values are similar to those reported by Love et al. (1998) more than 10 yrs ago.     

Palaeomagnetism of porphyritic stocks and rhyolite sills,Avalon Zone of eastern Newfoundland

The eastern segment of the Appalachian orogen is largely underlain by late Precambrian (Hadrynian) rocks affected by the Avalonian, Acadian and possibly Alleghenian orogenies. The provenance of the Avalon Zone of Newfoundland is uncertain. The region investigated in this segment consists of porphyrite stocks and sills (laccoliths) intrusive into the sedimentary, tuffaceous and volcanic rocks of the Harbour Main Group and rhyolite sills intrusive into the porphyrites. Some 55 oriented samples (148 specimens) collected at 11 sites were thermally (20–650°C) and AF (0.05–100 mT) demagnetized. Three components of magnetization were isolated: C (311°, +48°, α₉₅ = 11°, k = 21, 10 sites), A (13°, +37°, α₉₅ = 14°, k = 22, 6 sites), and B (67°, +45°, α₉₅ = 15°, k = 27,5 sites). Based on coercivity spectra, unblocking temperatures, frequency distribution and precision parameters of the respective components, it is suggested that component C is older than component A which is turn is older than component B. The palaeopoles of components C, A and B are: 211°E, 48°N (d_p = 9.8°, d_m = 14.7°); 101°E, 61°N (d_p = 9.6°, d_m = 16.4°); 33°E, 34°N (d_p = 12°, d_m = 19°), respectively. Component C is most probably primary. Component A is secondary and its pole is near that of Carboniferous and Early Permian North America poles, indicating that the porphyrites and the rhyolites were remagnetized in the late Palaeozoic. Component B remains unexplained; it is possible that it is an unresolved pseudo-component but it is more likely an overprint. There are few palaeomagnetic results for the late Precambrian period in Avalon terrane(s). The preliminary results of this study suggest the presence of a separate plate from North American at that time. These results will prove useful for the palaeoreconstruction of the continents (North Africa, northeast Europe) in the late Precambrian period.     

Etude de la phase gazeuse occluse dans les laves de «l’Ardoukôba», volcan éphémère d’une dorsale émergée (Afar)

Gases trapped in lavas of three main flows of the Ardoukôba eruption (8 to 15 November, 1978) have been analysed by mass spectrometry. These analyses concern both plagioclase phenocrysts and microcrystalline mesostasis. Fluids are released between 500°C and 1200°C, and consist of H₂O, CO₂, CO, N₂, SO₂, HCl, H₂, CH₄ with traces of hydrocarbons and H₂S. The total content is less than 0.3–0.4 wt. % of samples with about 0.1–0.15 wt % of H₂O. No significant variation among the three flows is observed. Plagioclase phenocrysts are less abundant in fluids than the mesostasis (～2/3). The gases trapped in these phenocrysts are richer in CO and organic compounds, whereas mesostasis contain more H₂O, CO₂ and SO₂. CO is likely produced by reduction of CO₂ and H₂O with carbon during either analyses or eruption itself, or is of primary origin. In the latter case, gas composition suggests an entrapment temperature of about 1200°C ± 75°C. Kinetic study of the water and carbon dioxide release allows to calculate the diffusion characteristics of these fluids. Water and carbon dioxide behave rather similarly. Plagioclase gives a single activation energy value (8 Kcal/mole), while mesostasis gives two values (8 Kcal/mole, 15 Kcal/mole). Diffusion coefficients at 20°C are estimated to fall in the range 10^?13 · 10^?12 cm² · sec^?1.     

Evolution of fluid geochemistry at the Turrialba volcano (Costa Rica) from 1998 to 2008

Turrialba (10°02′N, 83°45′W) is a 3,349-m high stratovolcano belonging to the Holocene “Cordillera Central” volcanic belt of Costa Rica. The summit consists of three EW-oriented craters (East, Central, and West). Since its last eruptive phase (1864–1866), the Central and West craters have displayed modest fumarolic activity, with outlet temperatures clustering around 90°C. In 2001, seismic swarms, ground deformation, and increasing fumarolic activity occurred. From 2005 to 2008, new fumarolic vents opened between and within the Central and West craters, and along the western and southwestern outer flanks of the volcanic edifice. These physical changes were accompanied by a drastic modification in the gas chemistry that can be divided in three stages: (1) hydrothermal (from 1998 to autumn 2001), characterized by the presence of H₂O, CO₂, H₂S, and, to a very minor extent, HCl and HF; (2) hydrothermal/magmatic (autumn 2001–2007), with the appearance of SO₂ and a significant increase of HCl and HF; and (3) magmatic-dominated (2007–2008), characterized by increased SO₂ content, SO₂/H₂S > 100, and temperatures up to 282°C. Accordingly, gas equilibrium in the CO₂-CH₄-H₂ system suggests a progressive evolution of the deep fluid reservoir toward higher temperatures and more oxidizing conditions. The chemical–physical modifications of Turrialba in the last decade can be interpreted as part of a cyclic mechanism controlling the balance between the hydrothermal and the magmatic systems. Nevertheless, the risk of rejuvenation of the volcanic activity cannot be excluded, and an appropriate seismic, ground deformation, and geochemical monitoring program is highly recommended. Turrialba lies at a distance of 35 and 15 km from San José and Cartago, respectively, the two largest cities in Costa Rica.     

Plio-pleistocene paleomagnetic record from the Michoacán-Guanajuato Monogenetic Volcanic Field (Western Mexico)

The paleosecular variation (PSV) and polarity transitions are two major features of the Earth’s magnetic field. Both PSV and reversal studies are limited when age of studied units is poorly constrained. This is a case of Central and western Mexico volcanics. Although many studies have been devoted to these crucial problems and more than 200 paleomagnetic directions are available for the last 5 Ma, only few sites were dated directly. This paper presents new paleomagnetic results from seventeen independent cooling units in the Michoacán-Guanajuato Volcanic Field (MGVF) in western Mexico. Twelve sites are directly dated by ⁴⁰Ar/³⁹Ar or K-Ar methods and span from 2.78 to 0.56 Ma. The characteristic paleodirections are successfully isolated for 15 lava flows. The mean paleodirection (inclination I and declination D) obtained in this study is I = 28.8°, D = 354.9°, and Fisherian statistical parameters are k = 28, α₉₅ = 7.3°, N=15, which corresponds to the mean paleomagnetic pole position P_lat = 83.9°, P_long = 321.6°, K = 34, A₉₅ = 6.6°. The paleodirections obtained in present study compiled with those, previously reported from the MGVF, are practically undistinguishable from the expected Plio-Quaternary paleodirections. The paleosecular variation is estimated through the study of the scatter of the virtual geomagnetic poles giving S_F = 15.9 with S_U =21.0 and S_L = 12.7 (upper and lower limits respectively). These values agree reasonably well with the recent statistical Models. The oldest sites analyzed (the Santa Teresa and Cerro Alto) yield normal polarity magnetizations as expected for the cooling units belonging to the Gauss geomagnetic Chron. The interesting feature of the record comes from lava flows dated at about 2.35 Ma with clearly defined normal directions. This may point out the possible existence of a normal polarity magnetization in the Matuyama reversed Chron older than the Reunion and may be correlated to Halawa event interpreted as the Cryptochron C2r.2r-1. Another important feature of the geomagnetic record obtained from the MGVF is the evidence of fully reversed geomagnetic field within Bruhnes Chron, at about 0.56 Ma corresponding to the relative paleointensity minimum of global extent found in marine sediments at about 590 ka.     

Palaeomagnetism and K-Ar ages of triassic igneous rocks from the Ischigualasto-Ischichuca Basin and Puesto Viejo Formation,Argentina

The palaeomagnetism of Middle Triassic (224 ± 5 m.y.) igneous rocks from the Ischigualasto-Ischichuca Basin (67°40′W, 30°20′S) was investigated through 86 oriented hand samples from 11 sites. At least one reversal of the geomagnetic field has been found in these rocks. Nine sites yield a palaeomagnetic pole at 239°E, 79°S (α₉₅ = 15°, k = 13).The K-Ar age determinations of five igneous units of the Puesto Viejo Formation give a mean age of 232 ± 4 m.y. (Early Triassic). The palaeomagnetism of six igneous units of the Puesto Viejo Formation (68°W, 35°S) was investigated through 60 oriented samples. These units, two reversed relative to the present magnetic field of the Earth and four normal, yield a pole at 236°E, 76°S (α₉₅ = 18°, k = 14).Data from the Puesto Viejo Formation indicate, for the first time on the basis of palaeomagnetic and radiometric data, that the Illawarra Zone, which defines the end of the Kiaman Magnetic Interval, extends at least down to 232 ± 4 m.y. within the Early Triassic. The palaeomagnetic poles for the igneous rocks of the Ischigualasto-Ischichuca Basin and Puesto Viejo Formation form an “age group” with the South American Triassic palaeomagnetic poles (mean pole position: 239°E, 77°S; α₉₅ = 6.6°, k = 190). The Middle and Upper Permian, Triassic and Middle Jurassic palaeomagnetic poles for South America would define a “time group” reflecting a quasi-static interval (mean pole position: 232°E, 81°S; α₉₅ = 4°, k = 131).     

Adsorptive Removal of Acid Blue 15: Equilibrium and Kinetic Study

Activated carbons prepared from sunflower seed hull have been used as adsorbents for the removal of acid blue 15 (AB‐15) from aqueous solution. Batch adsorption techniques were performed to evaluate the influences of various experimental parameters, e. g., temperature, adsorbent dosage, pH, initial dye concentration and contact time on the adsorption process. The optimum conditions for AB‐15 removal were found to be pH = 3, adsorbent dosage = 3 g/L and equilibrium time = 4 h at 30°C. The adsorption of AB‐15 onto the adsorbent was found to increase with increasing dosage. It was found from experimental results that the Langmuir isotherm fits the data better than the Freundlich and Temkin isotherms. The maximum adsorption capacity, Q_m (at 30°C) was calculated for SF1, SF2, and SF3 as 75, 125 and 110 mg g^–1 of adsorbent, respectively. It was found that the adsorption follows pseudo‐second order kinetics. The thermodynamic parameters such as ΔG°, ΔH°, and ΔS° were also evaluated. The activated carbons prepared were characterized by FT‐IR, SEM and BET analysis.     

Latitudinal dependence of the seasonal variation of particulate extinction in the UTLS over the Indian longitude sector during volcanically quiescent period based on lidar and SAGE-II observations

The altitude profiles of particulate extinction in the upper troposphere and lower stratosphere (UTLS) obtained from SAGE-II in the latitude region 0–30°N over the Indian longitude sector (70–90°E) are used to study the latitudinal variation of its annual pattern in this region during the volcanically quiescent period of 1998–2003. The SAGE-II data is compared with the lidar measurements from Gadanki (13.5°N, 79.2°E) when the satellite had an overhead occultation pass over a small geographical grid centered at this location. The particulate optical depth (τ_p) in the UT region shows a general decrease with increase in latitude and a pronounced summer–winter contrast with relatively low values during winter and high values during summer. In general, these variations are in accordance with the latitudinal variation of convective available potential energy (CAPE) and thunderstorm activity, which are good representative indices of tropospheric convection. While the particulate extinction (and τ_p) in the 18–21 km (LS₁) region is relatively low in the equatorial region up to 15°N, it shows an increase in the off-equatorial region, beyond 15°N. While the annual variation of τ_p in the LS₁ region is almost insignificant near the equator, it is rather well pronounced in latitude region between 10 and 15°N with relatively high values during winter and low values during summer. Beyond 20°N, this shows a prominent peak during summer. At a higher altitude, the 21–30 km (LS₂) region, the latitude variation of τ_p shows a different pattern with high values near the equator and low values in the off-equatorial region confirming the existence of a stratospheric aerosol reservoir. Low values of τ_p at lower regime (LS₁) near the equator could be due to rapid transport of particulates from the near equatorial region to higher latitudes, while the equatorial high at upper regime (LS₂) could be due to lofting and subsequent accumulation.