Tertiary Volcanic and Tectonic Evolution of the Ayas-Güdül-Celtikci Region,Turkey

Volcanic activity in the Ayas-Güdül-Celtikci region began by Oligocene (?)-early Miocene time and persisted until the end of early Pliocene time. It commenced with andesitic breccias and lavas at the base of the series and evolved through the deposition of ignimbritic and laharic volcanic material toward intermediate levels of the succession. Caldera formation followed this period of volcanic activity. Ephemeral lakes covering the region caused the subaqueous extrusion of the latest lavas during this period of activity. Afterward, limnic and fluvial sedimentation Occurred in the region during a period of volcanic quiescence. This mid-late Miocene deposition was followed by new basaltic activity. The volcanism was controlled by conjugate fault sets, N45W and N15E, representing pure-shear stress in a N20W direction, from the late Oligocene to the end of the early Pliocene. Normal dip-slip faults having a N55E trend were created by local N25W tension, presumably because of the North Anatolian fault, after early Pliocene time.     

Plio-Quaternary evolution of the Küçük Menderes Graben Southwestern Anatolia,Turkey

The Küçük Menderes Graben (KMG) is part of the horst-graben system of southwestern Anatolia (Turkey), bounded by the Bozda? horst in the north and the Ayd?n horst in the south. The Plio-Quaternary evolution of the KMG has been evaluated using the nature of the Miocene-Quaternary fill sediments and palaeostress analysis of slip data measured in different parts of the graben.

The graben is composed of five subbasins—the Kiraz, Ödemi?, Bay?nd?r, Da?k?z?lca-Torbal? and Selçuk—that are connected to each other through narrow Quaternary troughs. The Da?k?z?lca, Kiraz and Selçuk basins bear Miocene and younger sequences whereas the other subbasins are largely filled by Quaternary sediments. The maximum thickness of the Quaternary fill reaches about 270 m in the Ödemi? and Bay?nd?r subbasins.

The calculated slip results indicate multidirectional extension, three successive deformational periods, and possible counterclockwise rotation in the KMG during the post-Miocene period. The first phase was a strike-slip regime under N-S compression, followed by a second phase of deformation which resulted in ENE-WSW extension with strike-slip components. The final phase of deformation was NE-SW extension which constituted the final evolution of the KMG.

The graben gained its present morphological configuration via the onset of E-W-trending, high-angle normal faulting imposed on the regionwide synformal structure during the Plio-Quaternary. The KMG evolved as a result of rifting during the Plio-Quaternary which followed Late Miocene unroofing of the Menderes Massif and the evolution of the Büyük Menderes and Gediz grabens.     

Mineral chemical investigation on sulfide mineralization of the Istala deposit,Gümüşhane,NE-Turkey

The mineralogy of the Istala deposit, Gümüşhane, northeastern Turkey, was studied in detail, and a geochemical investigation was carried out using electron probe micro-analysis (EPMA). Sphalerite, galena, chalcopyrite and pyrite are the major sulfide minerals found in the Istala deposit, with minor amounts of bornite, idaite, tetrahedrite–tennantite, anilite, yarrowite, mckinstryite, covellite and chalcocite. In addition to these, barite and a small quantity of quartz occur as gangue minerals. Based on the textural relations and mineral assemblages, five different stages of crystallization have been recognized. Mineral paragenesis of the first four stages has been found to be similar, whereas clear enrichment has been observed in the modal abundance of the copper sulfide mineral assemblage at the fifth-stage ore formation. Whole-rock geochemical analyses of the Istala ore show an enrichment of Ag content up to 3328 ppm. Optical observations and EPMA study indicated that abundant silver mineralization was found in the Istala ore, especially during the later-stage ore deposition. Repetition to the presence of native silver in the samples, a significant amount of silver was incorporated in bornite, idaite, tetrahedrite–tennantite, anilite, yarrowite, mckinstryite, covellite and chalcocite, whereas a trace amount of silver has been detected in sphalerite, galena, chalcopyrite and pyrite. The homogenization temperatures (T_h) of the primary fluid inclusions were measured between 98 and 284 °C, with frequency peaks around 140 °C, 190 °C and 240 °C. All data obtained support the theory that later stage copper-rich sulfides, formed under the low temperature conditions, are responsible for the large amounts of silver content in the Istala mine.     

Timing of low-temperature metamorphism and cooling of the Paleozoic and Mesozoic formations of the Bükkium,innermost Western Carpathians,Hungary

K-Ar ages of illite-muscovite and fission track ages of zircon and apatite were determined from various lithotypes of the Bükkium, which forms the innermost segment of the Western Carpathians. The stratigraphic ages of these Dinaric type formations cover a wide range from the Late Ordovician up to the Late Jurassic. The grade of the orogenic dynamo-thermal metamorphism varies from the late diagenetic zone through the anchizone up to the epizone (chlorite, maximally biotite isograd of the greenschist facies). The K-Ar system of the illite-muscovite in the < 2 m grain-size fraction approached equilibrium only in epizonal and high-temperature anchizonal conditions. The orogenic metamorphism culminated between the eo-Hellenic (160-120 Ma) phase connected to the beginning of the subduction in the Dinarides, and the Austrian (100-95 Ma) phase characterized by compressional crustal thickening. No isotope geochronological evidence was found for proving any Hercynian recrystallization. The stability field of fission tracks in zircon was approached using the thermal histories of the different tectonic units. A temperature less than 250°C and effective heating time of 20–30 Ma had only negligible effects on the tracks, whereas total annealing was reached between 250 and 300°C. Apatite fission track ages from the Paleozoic and Mesozoic formations show that the uplift of the Bükk Mountains occurred only in the Tertiary (not earlier than ca. 40 Ma ago). Thermal modeling based on apatite fission track length spectra and preserved Paleogene sediment thickness data proved that the Late Neogene burial of the recently exhumed plateau of the Bükk Mountains exceeded 1 km.     

Late Quaternary evolution of the Gediz and Büyük Menderes grabens,Western Anatolia,Turkey

The Gediz and the Büyük Menderes Graben basins, two of the most important structural elements of western Anatolia, markedly differ in their palaeogeographic evolution during the Holocene. On the basis of the study of the facies and the geomorphological characteristics of the youngest sedimentary fills it is suggested that the evolution of the Büyük Menderes basin has a simple progradational history while the Gediz River basin has shown a complex evolution mainly controlled by intense tectonic periods. Comparison between the palaeogeographic evolution of these basins points to the fact that tectonism has been more effective in the Gediz basin during the Holocene.     

Age and Chemistry of Miocene Volcanic. Rocks from the Kiraz Basin of the Küçük Menderes Graben: Its Significance for the Extensional Tectonics of Southwestern Anatolia,Turkey'

Neogene volcanic rocks and granitoid plutons are among the most important geological components of western Turkey. Although they are voluminous north of the Gediz Graben, they are very scarce to the south, where volcanic rocks occur as isolated small exposures in a small number of localities. The Kiraz Basin of the Küçük Menderes Graben is a key locality, in which Tertiary volcanic rocks crop out at three locations. These rocks have been chemically analysed and dated (³⁹Ar-⁴⁰Ar whole rock and biotite analyses) in order to understand their tectonic setting of emplacement and its relation to the wider structure of western Anatolia. Whole rock and biotite ³⁹Ar-⁴⁰Ar ages vary between 13.9 ± 0.2 Ma and 14.6 ± 0.2 Ma.

The Kiraz volcanic rocks are calc-alkaline, with a compositional range from basaltic andesite to dacite. They are strongly enriched in the light ion lithophile elements (LILE) and have chemistries typical of lavas erupted in subduction-related settings. Their close association with rift-bounding faults suggests eruptions via conduits flanking grabens in an extensional environment. The difference in chemical composition and age between the Kiraz volcanic rocks and the slightly older calc-alkaline volcanic rocks north of the Gediz Graben is attributed to their relatively younger ages and greater proximity to the Aegean Arc. Their calc-alkaline chemistry reflects magma generation influenced by the slab descending beneath this arc and eruption/emplacement in an extensional setting.     

Structural damages of the May 19, 2011, Kütahya–Simav earthquake in Turkey

Reconnaissance observations are presented on the building damage caused by the May 19, 2011, Kütahya–Simav earthquake in Western Turkey as well as an overview of strong ground motion data recorded during the earthquake is given. According to Disaster and Emergency Management Presidency of Turkey, the magnitude of the earthquake is 5.7 in local magnitude scale. Although the earthquake can be regarded as a moderate event when considering its magnitude and strong motion recordings, it caused excessive structural damage to buildings in Simav district and several villages in the near vicinity. During the field investigation, different types of structural damage were observed mainly in the reinforced concrete frame buildings with infill walls and masonry buildings with various types of construction materials. Observed damage resulted from several deficiencies in structural and non-structural components of the buildings. Poor construction materials and workmanship, non-conforming earthquake-resistant design and construction techniques and non-ductile detailing are the main reasons for such an extensive damage, as observed in many past earthquakes in Turkey.     

Seismic stratigraphy and depositional history of the Büyükçekmece Bay since Latest Pleistocene,Marmara Sea,Turkey

High-resolution seismic data shed light on latest Pleistocene and Holocene sedimentation beneath the Büyükçekmece Bay, northern shelf area of the Marmara Sea, Turkey. Discontinuous fluvio-marine and marine deposits overlying the erosional truncation surface of Oligocene–Lower Miocene deposits are as thick as 30 m and preserved preferentially within the incised valleys that were controlled by some old faults. A series of prograding shoreline, laterally passing to the latest Pleistocene–Holocene valley-fill deposits, are thought to have accumulated mainly during times of shoreline transgression and sea-level rise. The overall morphology and stratigraphic setting observed in the Büyükçekmece Bay and at the southern outlet of the Bosphorus Strait have nearly same characteristics, implying that similar hydrodynamic conditions, erosional and depositional processes were mainly under the control of strong northerly flows during the Late Quaternary. These flows were less powerful in the Büyükçekmece region with decreased sediment input and smaller accommodation space.     

Dimerelloid rhynchonellide brachiopods in the Lower Jurassic of the Engadine (Canton Graubünden, National Park, Switzerland)

New brachiopods (Dimerelloidea, Rhynchonellida) from Lower Jurassic (?lower Hettangian) hemipelagic sediments of the Swiss National Park in south-eastern Engadine are described: Sulcirostra doesseggeri sp. nov. and Carapezzia engadinensis sp. nov. Sulcirostra doesseggeri is externally similar to S. fuggeri (Frauscher 1883), a dubious species, that could not be included in a comparative study, because relevant samples no longer exist. A single specimen was tentatively assigned to Sulcirostra ?zitteli (Böse 1894) by comparison of its external morphology with S. zitteli from the type locality. The partly silicified brachiopods are associated with sponge spicules, radiolarians and crinoid ossicles. Macrofossils are rare: dictyid sponges, gastropods, bivalves, crustaceans, shark teeth and scales of an actinopterygian fish. The Lower Jurassic sediments (Alpisella beds, a basal member of the Allgäu Formation) preserving the brachiopods belong to the Ortler nappe (Upper Austroalpine nappes). The exact age of the Alpisella beds is not known, as index fossils are lacking. Their stratigraphic position above the Rhaetian Kössen Formation and below the ammonite-dated Trupchun beds suggests a very Early Jurassic, probably early Hettangian age for the new brachiopod fauna. The new species of Sulcirostra and Carapezzia are confined to a very small geographic area, a peculiarity also observed in other Early Jurassic dimerelloid brachiopods. These brachiopods presumably adapted to current-dominated submarine highs, where their shells could not accumulate, except when trapped in submarine cavities or re-deposited in submarine fans. Transport by turbidity currents is suggested for the Early Jurassic dimerelloids from the Engadine. Problems with the generic definition of Sulcirostra and the higher rank classification of Carapezzia are discussed.     

Dynamic Analysis of Deformational Structures of the Xiannüshan Fault Zone in the Three Gorges of the Yangtze River

Field investigation and laboratory work reveal that inhomogeneity of the deformation of the Xiannüshan fault is mainly characterized by lateral zonation, longitudinal segmentation and downward stratification. Based on these results, a 3-D deformational structure model of the fault was established and its geometrical and kinematic characteristics in two main deformational stages i.e. the main Yanshanian and Himalayan were discussed. The directions of principal and the differential stresses in these two stages were determined by using conjugate joints, striations of fault planes and microstructures of the fault zone. The direction of (1 is N-S in direction with differential stresses of 150(250 MPa in the Yanshanian, and N70E with a differential stress ranging from 80-120 MPa in the Himalayan.     

Pyritized mudstone and associated facies in the Permian–Triassic boundary of the Çürük Dağ section,Southern Turkey

This paper is the first study of pyritized mudstones (PM) in the Permian–Triassic (P–T) boundary section of the Çürük Da? (Taurus, Antalya Nappes, Turkey). The mudstones were generally formed as lensoidal-shaped layers or infill materials within nodular platform limestones (hardground). Normal marine fauna is diminished in the pyritized limestones, whereas tube-like microorganisms are apparently increased with the association of pyrite crystals consisting of both framboidal and cubic crystals. The total rock volumes are up to 50–60% clay minerals and are mainly made up of in situ kaolinite and subordinate mixed layer clays (illite–vermiculite). Kaolinite preferentially developed on feldspar crystals, sometimes covering ostracoda bivalves together with gypsum micronodules composed of fan-shaped gypsum crystals. The origin of the kaolinite is, in situ, directly related to feldspar dissolution via heterotrophic bacteria. Thus, kaolinite is found along with bacterial structures. Other mineralogical compositions include established quartz (mostly β-quartz), gypsum crystals (100–200 μm) glauconite and magnetite. Magnetite grains comprise a minor amount (1–2%) and show some bacterial-induced crystal orientations. Glauconite is formed as an accessory mineral that occurs as infill material in biogenic grains. On the other hand, some microspheres represented by a silica-dominated composition are only observed in scanning electron microscopes (SEM) studies under high magnification. Isotope values (d34S) obtained from the pyritized mudstones show an isotopic heterogeneity that suggests that the pyritized mudstone consists of at least two components, with different sulphur-concentrations and d34S values.     

Natural and artificial radioactivity levels and hazards of soils in the Kücük Menderes Basin,Turkey

In this study, natural and artificial radionuclide activity concentrations in surface soils of Kücük Menderes Basin have been measured using gamma spectroscopy. The soil samples were collected from agricultural lands in the Kücük Menderes Basin in Turkey. The activity concentrations of ²²⁶Ra, ²³²Th, ⁴⁰K and ¹³⁷Cs in the soils were found to be range of 12.63 ± 2.28–72.51 ± 11.23, 11.45 ± 2.4–58.12 ± 4.76, 234.8 ± 14.85–1058.52 ± 24 Bq kg^?1 dw and 2.31 ± 0.18–7.75 ± 1.14 Bq kg^?1, respectively. The natural gamma radioactivity of the terrestrial radionuclides in soil samples and the gamma absorbed dose rate, the annual effective dose equivalent, the radium equivalent activity, the external hazard index, were calculated and compared with the international recommended values.     

Dynamic Analysis of Deformational Structures of the Xiannüshan Fault Zone in the Three Gorges of the Yangtze River

Field investigation and laboratory work reveal that inhomogeneity of the deformation of the Xiannüshan fault is mainly characterized by lateral zonation, longitudinal segmentation and downward stratification. Based on these results, a 3-D deformational structure model of the fault was established and its geometrical and kinematic characteristics in two main deformational stages i.e. the main Yanshanian and Himalayan were discussed. The directions of principal and the differential stresses in these two stages were determined by using conjugate joints, striations of fault planes and microstructures of the fault zone. The direction of (1 is N-S in direction with differential stresses of 150(250 MPa in the Yanshanian, and N70E with a differential stress ranging from 80-120 MPa in the Himalayan.     

A combined polarizing microscope,XRD, SEM,and specific gravity study of the petrified woods of volcanic origin from the Çamlıdere-Çeltikçi-Güdül fossil forest,in Ankara,Turkey

The fossil forest in the Çaml?dere-Çeltikçi-Güdül region of the province of Ankara in Turkey has a large number of petrified coniferous and oak tree remains. Petrification occurred in volcanic ashes and tuffs with permineralization, and Fe, Mg, Ca and Ni ions played important roles in the substitution of Si for C. However, the petrified wood samples are heterogeneous in colouration, weight, toughness, and durability, despite being obtained from the same source. Those features are very important for end-users because petrified woods, if cut and polished, are used widely as both decorative indoor tiles and gemstone objects, but heterogeneous materials suffer large wastage while they are being worked and used.Chemical analyses, specific gravity measurements, polarizing microscope studies, X-ray diffraction patterns, and scanning electron image evaluations were performed to classify and identify the homogenous material of the petrified woods relating to its physical and mineralogical characteristics.The different characteristics of the petrified wood samples are due to their varying inner structures, which depend on the replacement silica-building phases and their ratios, and silica particle sizes. Thin sections and XRD patterns revealed that petrified woods in the region were silicified by replacement with both chalcedonic quartz components, including chalcedony (length-fast quartz), moganite and orthorhombic-silica (length-slow quartz), and opalline quartz components including opal-CT and opal-C (length-slow quartz). The scanning electron microscope images were shown that the internal structures of the petrified woods consist of mostly submicron-sized (100–800 nm), and partially nano-sized (60–120 nm) silica-building particles.So, the petrified wood samples can be firstly classified into five main-groups based on their colourations and specific gravity values, then, into three sub-groups based on the principal chalcedonic and opalline quartz silica-building phases and related particle sizes, and also weighing, toughness, and durability. In the first group (samples 1, 2, and 3), the crystallinity gradation of the petrified woods can be classified as quasi-coarse crystalline because they include mainly chalcedony and moganite phases with 800–200 nm ranging in particle size. They are heavy, tough, and resistance as a material, as shown by specific gravity values of 2.60, 2.56, and 2.54, respectively. In the second group (sample 4), the crystallinity gradation of the petrified wood can be classified as quasi-fine crystalline because it includes mainly o-silica and moganite phases with 400–100 nm ranging in particle size. It is medium-heavy, semi-tough and quasi-resistance as a material, as shown by a specific gravity value of 2.42. In the third group (sample 5), the crystallinity gradation of the petrified wood can be classified as quasi-nano-crystalline because it includes mainly opal-CT and opal-C phases with 120–60 nm ranging in particle size. The material is slight, brittle, and weak as a material, as shown by a specific gravity value of 2.18.Ultimately, in the petrified wood found in the Çaml?dere-Çeltikçi-Güdül region of Ankara province in Turkey, it is revealed that samples 1, 2, and 3 represent flint and chalcedony quartz mineral species, samples 4 and 5 represent chalcedony and opal quartz mineral species.     

Effect of Construction Material on Dam Type Selection of the Büyük Karaçay Dam (Hatay, Turkey)

This paper covers the investigation of construction materials and selection of the dam type for the Büyük Karaçay Dam, which was planned to be constructed on Büyük Karaçay River 20 km to the SW of Hatay (Southern Turkey). The purposes of the dam are irrigation, domestic water supply, and producing energy. Auxiliary structures locations have been determined during the study of detailed geological maps of the dam axis and reservoir area. Quality, quantity and hauling distance of natural construction materials were effective to select different dam types. For engineering geological studies exploration boreholes were drilled at the dam site; pressuremeter tests were performed in order to determine bearing capacity and elasticity properties of rocks; pressured water tests were also performed to determine permeability of the dam site. Moreover, physical and mechanical properties of rocks were determined by the laboratory test. In the feasibility stage, the dam type was chosen as the central core rock-fill dam, depending on state of natural construction materials. In design stage dam type was changed as faced symmetrical hardfill dam. Finally, the dam type was revised again during the design stage as concrete face rockfill dam.     

Application of the Sequence Stratigraphy in the Study of Cretaceous-Tertiary of the Tarim Basin, Xinjiang, China

1. IntroductionThe Tarim basin, one of the most developed and important areas of marine Cretaceous-Tertiary in China except for south Tibet, is very rich in oil and gas, such as Kekeya oilfield in southwestern Tarim and Kela2 gas field in northeastern Tarim. Because of the expansion, subduction of the oceanic crust of the Tethys and the collision between the India plate and the Eurasia plate during the Cretaceous-Tertiary, the Tethys transgressed into the Tarim basin from west to east fr…     

Geochemical and Petrological Characteristics of the Kale (Gümüshane) Volcanic Rocks: Implications for the Eocene Evolution of Eastern Pontide Arc Volcanism,Northeast Turkey

The Kale (Gumushane) volcanic rocks crop out in the southern zone of the eastern Pontide arc, and consist mainly of agglomerate, andesite, minor basalt, and tuff associated with sediments (limestone, marl, siltstone, sandstone) deposited in a shallow basin environment. The volcanites show mainly porphyritic, hyalo-porphyritic, and rare fluidal and glomeroporphyritic textures. These volcanic rocks consist predominantly of plagioclase, augite, hornblende, and lesser biotite, magnetite, and quartz, and secondary products of chloritization, carbonation, sericitization, and epidotization. In general, they show disequilibrium textures, possibly reflecting magma-mixing processes.

The volcanic rocks are mainly calc-alkaline in composition, and show moderate potassium enrichment. Most of the major- and trace-element variations reflect the significant role of fractional crystallization during the evolution of the volcanic suite. The fractionating phases are dominantly hornblende and augite, minor plagioclase, and magnetite. The rocks have high LILE and LREE enrichments, but are relatively depleted in HFSE relative to MORB. Moreover, incompatible trace-element distributions show similarities to those of an E-type MORB source. The rocks have moderately fractionated REE patterns with (La/Lu)_N = 2–12. Geochemical data suggest that the volcanites evolved by shallow-level fractional crystallization and magma-mixing contamination of a parental magma derived from metasomatized upper mantle by partial melting after thickening of the Pontide arc during the Paleocene-Eocene. Furthermore, differentiation took place in a magma chamber situated in the thickened arc crust within an extensional tectonic regime.     

Investigation of the quality and physical-geochemical characteristics of the drinking water in Gümüşhane (Turkey) city central

The physical (turbidity, color, smell, taste, pH, and conductivity) and geochemical properties (Ca, Mg, Na, Fe, Mn, Al, K, Cl^?, HCO₃ ^?, SO₄ ^2?, Fe, Cu, Co, Ni, Zn, Cd, Pb, and Cr) of the drinking water in Gümü?hane city center were determined. This city center constitutes the study area. The pH levels of the water samples ranged from 6.3 to 8.2, and their conductivities ranged between 240 and 900 μS. These findings were concordant with the drinking water standards of the Turkey Standard Institute and the World Health Organization. The hardness of the water samples in the study area was between 18.1 and 115.1 °Fr. These samples were classified as extremely hard, hard, and quite hard. In addition, an assessment using the criteria for Inland Surface Water Classification indicated that considering certain parameters (pH levels, amount of Na, SO₄ ^2?, Fe, Mn, Al, Co, Ni, Cu, and Cr), the samples belonged to class I (high quality) water. When Cl^? amount and conductivity were considered, the samples belonged to the first and second classes (less polluted) of water. The water in the study area was generally classified as carbonated and sulfated (Ca + Mg > Na + K) water classes. This water contained more weak acids than strong acids (HCO₃ ^? + CO₃ ^2? > Cl^? + SO₄ ^2?). The pH levels (6.3–8.2) of the water in the study area were unrelated to the varying concentrations of metals in the water. Elements such as Fe, Ni, Cd, Pb, Zn, and Cu increase in the water through the water–rock interaction in the area in which water rises or through the mixture of water with either mine or industrial wastes. In addition, several water samples belonged to an acceptable water class for drinking and usage.     

Hydrogeochemistry and Water Quality Evaluation along the Flow Path in the Unconfined Aquifer of the Düzce Plain,North-western Turkey

The Düzce Plain has a multi-aquifer system, which consists of a near surface unconfined aquifer, along with first and second deeper confined aquifers. Hydrochemical evolution and water quality are related to infiltration of the precipitation, recharge from the formations surrounding the plain, flow path of groundwater and the relationship between surface and groundwater. The groundwater in the unconfined aquifer flows towards the Efteni Lake and the Büyük Melen River. Surface waters are divided into two main hydrochemical facies in the study area: (a) Ca2+–HCO3?; and (b) Ca2+, Mg2+–HCO3-, SO42-. The groundwater has generally three main hydrochemical facies: (a) Ca2+–HCO3-; (b) Ca2+, Mg2+–HCO3-; and (c) Ca2+, Mg2+–HCO3-, Cl-. The hydrochemical facies "a" and "b" dominate within shallow depths in recharge areas under rapid flow conditions, while hydrochemical facies "c" characterizes shallow and mixed groundwater, which dominate intermediate or discharge areas (near Efteni Lake and Büyük Melen River) during low flow conditions and agricultural contamination. Calcium and bicarbonate ions, total hardness and electrical conductivity of total dissolved solids (EC–TDS) values increase along the groundwater flow path; but these parameters remain within the limits specified by the standards set for industrial and agricultural usages.