The ultrafine mineralogy of a molten interplanetary dust particle as an example of the quench regime of atmospheric entry heating

Abstract— Melting and degassing of interplanetary dust particle L2005B22 at ～1200 °C was due to flash heating during atmospheric entry. Preservation of the porous particle texture supports rapid quenching from the peak heating temperature whereby olivine and pyroxene nanocrystals (3 nm-26 nm) show partial devitrification of the quenched melt at T ? 450 °C–740 °C. The implied ultrahigh cooling rates are calculated at ～105 °C/h–106 °C/h, which is consistent with quench rates inferred from the temperature-time profiles based on atmospheric entry heating models. A vesicular rim on a nonstoichiometric relic forsterite grain in this particle represents either evaporative magnesium loss during flash heating or thermally annealed ion implantation texture.     

Thermally metamorphosed carbonaceous chondrites from data for thermally mobile trace elements

Abstract— We report radiochemical neutron activation analysis (RNAA) data for U, Co, Au, Sb, Ga, Rb, Cs, Se, Ag, Te, Zn, In, Bi, Tl, and Cd (ordered by increasing ease of vaporization and loss from the Murchison CM2 chondrite during open-system heating) in nine Antarctic C2 and C3 chondrites. These meteorites exhibit properties (obtained by reflectance spectroscopy, O isotopic mass spectrometry and/or mineralogy-petrology) suggesting thermal metamorphism in their parent bodies. Five of these meteorites (Asuka (A) 881655, Yamato (Y) 793495, Y-790992, Pecora Escarpment (PCA) 91008, and Y-86789—paired with Y-86720) exhibit significant depletion of the most thermally mobile 1–5 trace elements, which is consistent with open-system loss during extended parent-body heating (under conditions duplicated by week-long heating of the Murchison C2 chondrite, heated at 500–700 °C in a low-pressure (initially 10^?5atm) H₂ atmosphere). From earlier data, three other C3 chondrites—Allan Hills (ALH) 81003, ALH 85003, and Lewis Cliffs (LEW) 85332—show significant Cd depletion. Nine additional C2 and C3 chondrites show no evidence of mobile trace element depletion—including Y-793321, which by all other criteria was mildly metamorphosed thermally. Either metamorphism of these nine meteorites occurred under closed conditions and/or alteration took place under such mild conditions that even Cd could not be lost. The RNAA data suggest that 10 of the 46 Antarctic carbonaceous chondrites (including 4 of 37 from Victoria Land and 6 of 9 from Queen Maud Land) exhibit open-system loss of at least some thermally mobile trace elements by heating in their parent bodies, whereas none of the 25 non-Antarctic falls experienced this. These results are consistent with the idea that the Antarctic sampling of near-Earth material differs from that being sampled today.     

Crystallization of calcium‐aluminum‐rich inclusions: Experimental studies on the effects of repeated heating events

Abstract— The observed textures and chemistry of calcium‐aluminum‐rich inclusions (CAIs) are presumed to be the culmination of a series of repeated heating and cooling events in the early history of the solar nebula. we have examined the effects of these heating/cooling cycles experimentally on a bulk composition representing an average type b cai composition by varying the nature of the starting material. Although the most recent and/or highest temperature event prior to incorporation into the parent body dominates the texture and chemistry of the CAI, prior events affect the phase compositions and texture. We have determined that a prior low‐temperature event (simulated by heating the sample to 1275 °C and cooling slowly) increases the likelihood of anorthite crystallization in subsequent higher temperature events. A prior high‐temperature event that produced dendritic melilite (simulated by heating the sample to 1550 °C and cooling rapidly) results in melilite that shows evidence of rapid crystallization in subsequent lower temperature events. The addition of Pt powder to the starting material appears to enhance the ability of anorthite to nucleate from this composition and increases the number of melilite crystals present in samples that crystallize euhedral melilite.     

Simulating flash heating in a muffle tube furnace

Abstract— Very rapid heating is an important chondrule-formation process, and it has not been clear whether conventional equipment, such as a muffle tube furnace, is adequate for the simulation of heating on a timescale of seconds. We present a method for measuring the internal temperature reached by a charge during rapid heating when the thermocouple response lags. We have constrained charge temperatures by monitoring the time required to melt metal wires of various compositions and melting points placed inside charges with furnace temperature at 1400, 1500, and 1600 °C. The times required for melting of the metal wires define the temperature paths inside the charges. At 1400 °C, a charge takes 31 s to reach 1399 °C; at 1500 °C, a charge takes 10 s to reach 1495 °C; and at 1600 °C, a charge takes 6 s to reach 1538 °C. Heating rates in vertical muffle tube furnaces are adequate for studying flash melting processes (i.e., of «1 min duration) invoked, for example, in the formation of chondrules.     

Coronal heating

The prospects for observational tests of coronal heating theories are examined. Three heating mechanisms (Alfvén waves, D.C. electric currents, and MHD turbulence) are reviewed from this point of view. Some suggestions are offered for future tests but none, so far, would give unambiguous critical results.Operated by the Association of Universities for Research in Astronomy, Inc. (AURA) under cooperative agreement with the National Science Foundation.     

Organics preserved in anhydrous interplanetary dust particles: Pristine or not?

The chondritic‐porous subset of interplanetary dust particles (CP‐IDPs) are thought to have a cometary origin. Since the CP‐IDPs are anhydrous and unaltered by aqueous processes that are common to chondritic organic matter (OM), they represent the most pristine material of the solar system. However, the study of IDP OM might be hindered by their further alteration by flash heating during atmospheric entry, and we have limited understanding on how short‐term heating influences their organic content. In order to investigate this problem, five CP‐IDPs were studied for their OM contents, distributions, and isotopic compositions at the submicro‐ to nanoscale levels. The OM contained in the IDPs in this study spans the spectrum from primitive OM to that which has been significantly processed by heat. Similarities in the Raman D bands of the meteoritic and IDP OMs indicate that the overall gain in the sizes of crystalline domains in response to heating is similar. However, the Raman Γ_G values of the OM in all of the five IDPs clearly deviate from those of chondritic OM that had been processed during a prolonged episode of parent body heating. Such disparity suggests that the nonaromatic contents of the OM are different. Short duration heating further increases the H/C ratio and reduces the δ¹³C and δD values of the IDP OM. Our findings suggest that IDP OM contains a significant proportion of disordered C with low H content, such as sp² olefinic C=C, sp³ C–C, and/or carbonyl contents as bridging material.     

Constraining Coronal Heating: Employing Bayesian Analysis Techniques to Improve the Determination of Solar Atmospheric Plasma Parameters

One way of revealing the nature of the coronal heating mechanism is by comparing simple theoretical one-dimensional hydrostatic loop models with observations at the temperature and/or density structure along these features. The most well-known method for dealing with comparisons like that is the χ ² approach. In this paper we consider the restrictions imposed by this approach and present an alternative way for making model comparisons using Bayesian statistics. In order to quantify our beliefs we use Bayes factors and information criteria such as AIC and BIC. Two datasets (Ugarte-Urra et al. 2005; Priest et al. 2000) are reanalyzed using the method described above. For the dataset of Ugarte-Urra et al. (2005), we conclude to apex dominant heating as the likely heating candidate, whereas the dataset of Priest et al. (2000) implies basal heating. Note that these new results are different from those obtained using the chi-squared statistic. For this we suggest that proper usage of Classical and Bayesian statistics should be applied in order to make safe assumptions about the nature of the coronal heating mechanisms.     

Cover

Cover: Images of lunar soil grains (measuring 1.5 μm in size) before and after experiencing thermal shock to 1000 ºC, simulating a micrometeorite impact inside the transmission electron microscope using the Hitachi Blaze heating holder. The grain is shown in high‐angle annular dark‐field before (upper left) and after heating (upper right) as well as in secondary electron imaging before (lower left) and after (lower right). For details, see the article by Michelle Thompson et al. on p. 413 . Images courtesy of M. Thompson.     

Survival of organic phases in porous IDPs during atmospheric entry: A pulse‐heating study

Abstract— In this study, we have performed pulse‐heating experiments at different temperatures for three organic molecules (a polycyclic aromatic hydrocarbon [PAH], a ketone, and an amino acid) absorbed into microporous aluminum oxide (Al₂O₃) in order to imitate the heating of the organic molecules in interplanetary dust particles (IDPs) and micrometeorites (MMs) during atmospheric entry and to investigate their survival. We have shown that modest amounts (a few percent) of these organic molecules survive pulse‐heating at temperatures in the 700 to 900 °C range. This suggests that the porosity in IDPs and MMs, combined with a sublimable phase (organic material, water), produces an ablative cooling effect, which permits the survival of organic molecules that would otherwise be lost either by thermal degradation or evaporation during atmospheric entry.     

Heating experiments simulating atmospheric entry heating of micrometeorites: Clues to their parent body sources

Abstract— Depending on their velocity, entry angle and mass, extraterrestrial dust particles suffer certain degrees of heating during entry into Earth's atmosphere, and the mineralogy and chemical composition of these dust particles are significantly changed. In the present study, pulse-heating experiments simulating the atmospheric entry heating of micrometeoroids were carried out in order to understand the mineralogical and chemical changes quantitatively as well as to estimate the peak temperature experienced by the particles during entry heating. Fragments of the CI chondrites Orgueil and Alais as well as pyrrhotites from Orgueil were used as analogue material. The experiments show that the volatile elements S, Zn, Ga, Ge, and Se can be lost from 50 to 100 μm sized CI meteorite fragments at temperatures and heating times applicable to the entry heating of similar sized cosmic dust particles. It is concluded that depletions of these elements relative to CI as observed in micrometeorites are mainly caused by atmospheric entry heating. Besides explaining the element abundances in micrometeorites, the experimentally obtained release patterns can also be used as indicators to estimate the peak heating of dust particles during entry. Using the abundances of Zn and Ge and assuming their original concentrations close to CI, a maximum heating of 1100–1200 °C is obtained for previously analyzed Antarctic micrometeroites. Thermal alteration also strongly influenced the mineralogy of the meteorite fragments. While the unheated samples mainly consisted of phyllosilicates, these phases almost completely transformed into olivine and pyroxene in the fragments heated to ≥800 °C. Therefore, dust particles that still contain hydrous minerals were probably never heated to temperatures ≥800 °C in the atmosphere. During continued heating, the grain size of the newly formed silicates increased and the composition of the olivines equilibrated. Applying these results quantitatively to Antarctic micrometeorites, typical peak temperatures in the range of 1100–1200 °C during atmospheric entry heating are deduced. This temperature range corresponds to the one obtained from the volatile element concentrations measured in these micrometeorites and points to an asteroidal origin of the particles.     

The roles of particle precipitation and Joule heating in the energy balance of the Jovian thermosphere

Order of magnitude calculations have been carried out to compare particle precipitation and Joule heating with solar radiation as sources of energy in the Jovian thermosphere. Calculations based on a detailed atomic cross section approach to energy deposition show that the efficiency of conversion of energetic particle precipitation energy into thermal energy is 0.33, larger than on Earth. This emphasizes the role of particle precipitation heating, which may serve as a source for gravity waves. In contrast to the terrestrial case, Joule heating is found to be of only minor significance in the Jovian atmosphere.     

Nonthermal Electron Energy Deposition in the Chromosphere and the Accompanying Soft x-ray Flare Emission

We analyse four solar flares which have energetic hard X-ray emissions, but unusually low soft X-ray flux and GOES class (C1.0–C5.5). These are compared with two other flares that have soft and hard X-ray emission consistent with a generally observed correlation that shows increasing hard X-ray accompanied by increasing soft X-ray flux. We find that in the four small flares only a small percentage of the nonthermal electron beam energy is deposited in a location where the heating rate of the electron beam exceeds the radiative cooling rate of the ambient plasma. Most of the beam energy is subsequently radiated away into the cool chromosphere and so cannot power chromospheric evaporation thus reducing the soft X-ray emission. We also demonstrate that in the four small flares the nonthermal electron beam energy is insufficient to power the soft X-ray emitting plasma. We deduce that an additional energy source is required, and this could be provided by a DC-electric field (where quasi-static electric field channels in the coronal loops accelerate electrons, and those electrons with velocity below a critical velocity will heat the ambient plasma via Joule heating) in preference to a loop-top thermal source (where heat flux deposited in the corona is conducted along magnetic field lines to the chromosphere, heating the coronal plasma and giving rise to further chromospheric evaporation).     

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.     

Primordial and cosmogenic noble gases in the Sutter's Mill CM chondrite

The Sutter's Mill (SM) CM chondrite fell in California in 2012. The CM chondrite group is one of the most primitive, consisting of unequilibrated minerals, but some of them have experienced complex processes occurring on their parent body, such as aqueous alteration, thermal metamorphism, brecciation, and solar wind implantation. We have determined noble gas concentrations and isotopic compositions for SM samples using a stepped heating gas extraction method, in addition to mineralogical observation of the specimens. The primordial noble gas abundances, especially the P3 component trapped in presolar diamonds, confirm the classification of SM as a CM chondrite. The mineralogical features of SM indicate that it experienced mild thermal alteration after aqueous alteration. The heating temperature is estimated to be <350 °C based on the release profile of primordial ³⁶Ar. The presence of a Ni‐rich Fe‐Ni metal suggests that a minor part of SM has experienced heating at >500 °C. The variation in the heating temperature of thermal alteration is consistent with the texture as a breccia. The heterogeneous distribution of solar wind noble gases is also consistent with it. The cosmic‐ray exposure (CRE) age for SM is calculated to be 0.059 ± 0.023 Myr based on cosmogenic ²¹Ne by considering trapped noble gases as solar wind, the terrestrial atmosphere, P1 (or Q), P3, A2, and G components. The CRE age lies at the shorter end of the CRE age distribution of the CM chondrite group.     

Sublimation extraction coupled with gas chromatography-mass spectrometry: A new technique for future in situ analyses of purines and pyrimidines on Mars

We have developed a sublimation technique coupled with chemical derivatization and gas chromatography mass spectrometry (GC-MS) to detect nucleobases and other volatile organic compounds derived from bacteria in Mars analog materials. To demonstrate this technique, a sample of serpentine inoculated with Escherichia coli (E. coli) cells was heated to 500 °C for several seconds under Martian ambient pressure. The sublimate was collected on a cold finger, then derivatized and analyzed by GC-MS. We found that adenine, cytosine, thymine and uracil were the most abundant molecules detected in the sublimed E. coli extract by GC-MS. In addition, nucleobases were also detected in sublimed extracts of a deep-sea sediment sample, seawater, and soil collected from the Atacama Desert in Chile after heating the samples under the same conditions. Our results indicate that nucleobases can be easily isolated directly from natural samples using sublimation and then detected by GC-MS after chemical derivatization. The sublimation-based extraction technique is one approach that should be considered for use by future in situ instruments designed to detect organic compounds relevant to life in the Martian regolith.     

A model for the temperature-dependence of tidal dissipation in convective plumes on icy satellites: Implications for Europa and Enceladus

To explain the formation of surface features on Europa, Enceladus, and other satellites, many authors have postulated the spatial localization of tidal heating within convective plumes. However, the concept that enhanced tidal heating can occur within a convective plume has not been rigorously tested. Most models of this phenomenon adopt a tidal heating with a temperature-dependence derived for an incompressible, homogeneous (zero-dimensional) Maxwell material, but it is unclear whether this formulation is relevant to the heterogeneous situation of a warm plume surrounded by cold ice. To determine whether concentrated dissipation can occur in convective plumes, we develop a two-dimensional model to compute the volumetric dissipation rate for an idealized, vertically oriented, isolated convective plume obeying a Maxwellian viscoelastic compressible rheology. We apply the model to the Europa and Enceladus ice shells, and we investigate the consequences for partial melting and resurfacing processes on these bodies. We find that the tidal heating is strongly temperature dependent in a convective ice plume and could produce elevated temperatures and local partial melting in the ice shells of Europa and Enceladus. Our calculation provides the first quantitative verification of the hypothesis by Sotin et al. [Sotin, C., Head, J.W., Tobie, G., 2002. Geophys. Res. Lett. 29. 74-1] and others that the tidal dissipation rate is a strong function of temperature inside a convective plume. On Europa, such localized heating could help allow the formation of domes and chaos terrains by convection. On Enceladus, localized tidal heating in a thermal plume could explain the concentrated activity at the south pole and its associated heat transport of 2-7 GW.     

Hydrodynamical simulations of cluster formation with central AGN heating

We analyse a hydrodynamical simulation model for the recurrent heating of the central intra-cluster medium (ICM) by active galactic nuclei (AGN). Besides the self-gravity of the dark matter and gas components, our approach includes the radiative cooling and photoheating of the gas, as well as a subresolution multiphase model for star formation and supernova feedback. Additionally, we incorporate a periodic heating mechanism in the form of hot, buoyant bubbles, injected into the intragalactic medium (IGM) during the active phases of the accreting central AGN. We use simulations of isolated cluster haloes of different masses to study the bubble dynamics and heat transport into the IGM. We also apply our model to self-consistent cosmological simulations of the formation of galaxy clusters with a range of masses. Our numerical schemes explore a variety of different assumptions for the spatial configuration of AGN-driven bubbles, for their duty cycles and for the energy injection mechanism, in order to obtain better constraints on the underlying physical picture. We argue that AGN heating can substantially affect the properties of both the stellar and gaseous components of clusters of galaxies. Most importantly, it alters the properties of the central dominant (cD) galaxy by reducing the mass deposition rate of freshly cooled gas out of the ICM, thereby offering an energetically plausible solution to the cooling-flow problem. At the same time, this leads to reduced or eliminated star formation in the central cD galaxy, giving it red stellar colours as observed.     

Micrometeorites and Their Implications for Meteors

Micrometeorites (MMs) are extraterrestrial dust particles, in the size range 25–400 μm, recovered from the Earth’s surface. They have experienced a wide range of heating during atmospheric entry from completely molten spherules to particles heated to temperatures <300°C that have retained low temperature minerals. The majority of MMs have mineralogies, textures and compositions that strongly resemble components from chondritic meteorites suggesting these correspond to sporadic, low geocentric velocity meteors. Changes in MMs due to entry heating, however, have implications for meteoric processes in general that may allow the observed behaviour of meteors to be directly related to the material properties of their meteoroids.     

A molecular and isotopic study of the macromolecular organic matter of the ungrouped C2 WIS 91600 and its relationship to Tagish Lake and PCA 91008

Abstract– Insight into the chemical history of an ungrouped type 2 carbonaceous chondrite meteorite, Wisconsin Range (WIS) 91600, is gained through molecular analyses of insoluble organic matter (IOM) using solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy, X‐ray absorption near edge structure spectroscopy (XANES), and pyrolysis‐gas chromatography coupled with mass spectrometry (pyr‐GC/MS), and our previous bulk elemental and isotopic data. The IOM from WIS 91600 exhibits similarities in its abundance and bulk δ¹⁵N value with IOM from another ungrouped carbonaceous chondrite Tagish Lake, while it exhibits H/C, δ¹³C, and δD values that are more similar to IOM from the heated CM, Pecora Escarpment (PCA) 91008. The ¹³C NMR spectra of IOM of WIS 91600 and Tagish Lake are similar, except for a greater abundance of CH_xO species in the latter and sharper carbonyl absorption in the former. Unusual cross‐polarization (CP) dynamics is observed for WIS 91600 that indicate the presence of two physically distinct organic domains, in which the degrees of aromatic condensation are distinctly different. The presence of two different organic domains in WIS 91600 is consistent with its brecciated nature. The formation of more condensed aromatics is the likely result of short duration thermal excursions during impacts. The fact that both WIS 91600 and PCA 91008 were subjected to short duration heating that is distinct from the thermal history of type 3 chondrites is confirmed by Carbon‐XANES. Finally, after being briefly heated (400 °C for 10 s), the pyrolysis behavior of Tagish Lake IOM is similar to that of WIS 91600 and PCA 91008. We conclude that WIS 91600 experienced very moderate, short duration heating at low temperatures (<500 °C) after an episode of aqueous alteration under conditions that were similar to those experienced by Tagish Lake.     

An experimental study on impact-induced alterations of planetary organic simulants

The present study systematically investigates shock-induced alteration of organic simulants of planetary bodies (OSPBs) as a function of peak shock pressure and temperature by impact experiments. Our results show that the composition and structure of OSPBs are unchanged upon impacts at peak pressures ≤~5 GPa and temperatures ≤~350 °C. On the other hand, these are dramatically changed upon impacts at >7–8 GPa and > ~400 °C, through loss of hydrogen-related bonds and concurrent carbonization, regardless of the initial compositions of OSPBs. Compared with previous results on static heating of organic matter, we suggest that shock-induced alteration cannot be distinguished from static heating only by Raman and infrared spectroscopy. Our experimental results would provide a proxy indicator for assessing degree of shock-induced alteration of organic matter contained in carbonaceous chondrites. We suggest that a remote-sensing signature of the 3.3–3.6 μm absorption due to hydrogen-related bonds on the surface of small bodies would be a promising indicator for the presence of less-thermally-altered (i.e., <350 °C) organic matter there, which will be a target for landing to collect primordial samples in sample-return spacecraft missions, such as Hayabusa2 and OSIRIS-REx.