Groundwater Discharge as a Source of Dissolved Carbon and Greenhouse Gases in a Subtropical Estuary

Groundwater may be highly enriched in dissolved carbon species, but its role as a source of carbon to coastal waters is still poorly constrained. Exports of deep and shallow groundwater-derived dissolved carbon species from a small subtropical estuary (Korogoro Creek, Australia, latitude ?31.0478°, longitude 153.0649°) were quantified using a radium isotope mass balance model (²³³Ra and ²²⁴Ra, natural groundwater tracers) under two hydrological conditions. In addition, air-water exchange of carbon dioxide and methane in the estuary was estimated. The highest carbon inputs to the estuary were from deep fresh groundwater in the wet season. Most of the dissolved carbon delivered by groundwater and exported from the estuary to the coastal ocean was in the form of dissolved inorganic carbon (DIC; 687 mmol m^?2 estuary day^?1; 20 mmol m^?2 catchment day^?1, respectively), with a large export of alkalinity (23 mmol m^?2 catchment day^?1). Average water to air flux of CO₂ (869 mmol m^?2 day^?1) and CH₄ (26 mmol m^?2 day^?1) were 5- and 43-fold higher, respectively, than the average global evasion in estuaries due to the large input of CO₂- and CH₄-enriched groundwater. The groundwater discharge contribution to carbon exports from the estuary for DIC, dissolved organic carbon (DOC), alkalinity, CO₂, and CH₄ was 22, 41, 3, 75, and 100 %, respectively. The results show that CO₂ and CH₄ evasion rates from small subtropical estuaries surrounded by wetlands can be extremely high and that groundwater discharge had a major role in carbon export and evasion from the estuary and therefore should be accounted for in coastal carbon budgets.     

Geochemical,isotopic and hydrological mass balance approaches to constrain the lake water–groundwater interaction in Dal Lake,Kashmir Valley

It is important to have qualitative as well as quantitative understanding of the hydraulic exchange between lake and groundwater for effective water resource management. Dal, a famous urban fresh water lake, plays a fundamental role in social, cultural and economic dynamics of the Kashmir Valley. In this paper geochemical, isotopic and hydrological mass balance approaches are used to constrain the lake water–groundwater interaction of Dal Lake and to identify the sources of lake water. Water samples of precipitation (n = 27), lake water (n = 18) and groundwater (n = 32) were collected across the lake and its catchment for the analysis of δ¹⁸O and δ²H. A total of 444 lake water samples and 440 groundwater samples (springs, tube wells and dug wells) were collected for the analysis of Ca²⁺, Mg²⁺, HCO₃ ^?, SO₄ ^2?, Cl^?, NO₃ ^?, Na⁺ and K⁺. Water table and lake water level were monitored at 40 observation locations in the catchment. Water table map including pH and EC values corroborate and verify the gaining nature of the Dal Lake. Stable isotopes of lake water in Boddal and Gagribal basins showed more deviation from the global meteoric water line than Hazratbal and Nigeen basins, indicating the evaporation of lake water. The isotopic and geochemical mass balance suggested that groundwater contributes a significant proportion (23–40%) to Dal Lake. The estimated average groundwater contribution to Dal Lake ranged from 31.2 × 10³ to 674 × 10³ m³ day^?1 with an average of 276 × 10³ m³ day^?1. The study will be useful to delineate the possible sources of nutrients and pollutants entering the lake and for the management of lake water resources for sustainable development.     

Carbon Dioxide and Methane Emissions from Mangrove-Associated Waters of the Andaman Islands,Bay of Bengal

We estimated CO₂ and CH₄ emissions from mangrove-associated waters of the Andaman Islands by sampling hourly over 24 h in two tidal mangrove creeks (Wright Myo; Kalighat) and during transects in contiguous shallow inshore waters, immediately following the northeast monsoons (dry season) and during the peak of the southwest monsoons (wet season) of 2005 and 2006. Tidal height correlated positively with dissolved O₂ and negatively with pCO₂, CH₄, total alkalinity (TAlk) and dissolved inorganic carbon (DIC), and pCO₂ and CH₄ were always highly supersaturated (330–1,627 % CO₂; 339–26,930 % CH₄). These data are consistent with a tidal pumping response to hydrostatic pressure change. There were no seasonal trends in dissolved CH₄ but pCO₂ was around twice as high during the 2005 wet season than at other times, in both the tidal surveys and the inshore transects. Fourfold higher turbidity during the wet season is consistent with elevated net benthic and/or water column heterotrophy via enhanced organic matter inputs from adjacent mangrove forest and/or the flushing of CO₂-enriched soil waters, which may explain these CO₂ data. TAlk/DIC relationships in the tidally pumped waters were most consistent with a diagenetic origin of CO₂ primarily via sulphate reduction, with additional inputs via aerobic respiration. A decrease with salinity for pCO₂, CH₄, TAlk and DIC during the inshore transects reflected offshore transport of tidally pumped waters. Estimated mean tidal creek emissions were ～23–173 mmol m^?2 day^?1 CO₂ and ～0.11–0.47 mmol m^?2 day^?1 CH₄. The CO₂ emissions are typical of mangrove-associated waters globally, while the CH₄ emissions fall at the low end of the published range. Scaling to the creek open water area (2,700 km²) gave total annual creek water emissions ～3.6–9.2?×?10¹⁰ mol CO₂ and 3.7–34?×?10⁷ mol CH₄. We estimated emissions from contiguous inshore waters at ～1.5?×?10¹¹ mol CO₂?year^?1 and 2.6?×?10⁸ mol CH₄?year^?1, giving total emissions of ～1.9?×?10¹¹ mol CO₂?year^?1 and ～3.0?×?10⁸ mol CH₄?year^?1 from a total area of mangrove-influenced water of ～3?×?10⁴ km². Evaluating such emissions in a range of mangrove environments is important to resolving the greenhouse gas balance of mangrove ecosystems globally. Future such studies should be integral to wider quantitative process studies of the mangrove carbon balance.     

Interactions of artificial lakes with groundwater applying an integrated MODFLOW solution

Artificial lakes (reservoirs) are regulated water bodies with large stage fluctuations and different interactions with groundwater compared with natural lakes. A novel modelling study characterizing the dynamics of these interactions is presented for artificial Lake Turawa, Poland. The integrated surface-water/groundwater MODFLOW-NWT transient model, applying SFR7, UZF1 and LAK7 packages to account for variably-saturated flow and temporally variable lake area extent and volume, was calibrated throughout 5 years (1-year warm-up, 4-year simulation), applying daily lake stages, heads and discharges as control variables. The water budget results showed that, in contrast to natural lakes, the reservoir interactions with groundwater were primarily dependent on the balance between lake inflow and regulated outflow, while influences of precipitation and evapotranspiration played secondary roles. Also, the spatio-temporal lakebed-seepage pattern was different compared with natural lakes. The large and fast-changing stages had large influence on lakebed-seepage and water table depth and also influenced groundwater evapotranspiration and groundwater exfiltration, as their maxima coincided not with rainfall peaks but with highest stages. The mean lakebed-seepage ranged from ~0.6 mm day^?1 during lowest stages (lake-water gain) to ~1.0 mm day^?1 during highest stages (lake-water loss) with largest losses up to 4.6 mm day^?1 in the peripheral zone. The lakebed-seepage of this study was generally low because of low lakebed leakance (0.0007–0.0015 day^?1) and prevailing upward regional groundwater flow moderating it. This study discloses the complexity of artificial lake interactions with groundwater, while the proposed front-line modelling methodology can be applied to any reservoir, and also to natural lake interactions with groundwater.     

Spatial and Temporal Variability of the CO2 Fluxes in a Tropical, Highly Urbanized Estuary

The spatial and temporal variations of the flux of CO₂ were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO₂ fluxes indicate that the upstream inputs of CO₂ from the rivers are largely responsible for the net annual CO₂ emission to the atmosphere of +30 to +48 mmol m^?2 day^?1, depending on the CO₂ exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO₂ flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m^?2 day^?1 in summer and ?246 mmol m^?2 day^?1 in winter. The pCO₂ values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg^?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO₂ in estuarine waters.     

Quantification of the water balance and hydrogeological processes of groundwater–lake interactions in the Pampa Plain, Argentina

This paper gives an account of the assessment and quantification of the water balance and the hydrogeological processes related to lake–groundwater interaction in the Pampa Plain by using hydrogeochemical, isotopic and flow numerical modeling techniques. La Salada is a permanent shallow lake, with an area of 5.8 km², located on the SE of Buenos Aires Province. A total of 29 lake water samples and 15 groundwater samples were collected for both hydrochemical analysis and environmental stable isotope determination. Water table depths were measured in wells closed to the lake. Groundwater samples appear grouped on the Local Meteoric Water Line, suggesting a well-mixed system and that rainfall is the main recharge source to the aquifer. Water evaporation process within La Salada is also corroborated by its isotopic composition. The model that best adjusts to La Salada Lake hydrochemical processes includes evaporation from groundwater, calcite precipitation with CO₂ release and cationic exchange. The annual water balance terms for the lake basin indicates for each hydrological component the following values: 1.16 E⁰⁸ m³ rainfall, 8.15 E⁰⁷ m³ evapotranspiration, 1.90 E⁰⁶ m³ runoff, 1.55 E⁰⁷ m³ groundwater recharge, 6.01 E⁰⁶ m³ groundwater discharge to the lake, 9.54 E⁰⁶ m³ groundwater discharge to the river, 5.00 E⁰⁵ m³ urban extraction and 4.90 E⁰⁶ m³ lake evaporation. Integrated analysis of hydrochemical and isotopic information helped to calibrate the groundwater flow model, to validate the conceptual model and to quantitatively assess the basin water balance.     

Geochemistry and quality of groundwater of Gummanampadu sub-basin, Guntur District, Andhra Pradesh, India

Groundwater survey has been carried out in the area of Gummanampadu sub-basin located in Guntur District, Andhra Pradesh, India for assessing the factors that are responsible for changing of groundwater chemistry and consequent deterioration of groundwater quality, where the groundwater is a prime source for drinking and irrigation due to non-availability of surface water in time. The area is underlain by the Archaean Gneissic Complex, over which the Proterozoic Cumbhum rocks occur. The results of the plotting of Ca²⁺ + Mg²⁺ versus HCO₃ ^? + CO₃ ^2?, Ca²⁺ + Mg²⁺ versus total cations, Na⁺ + K⁺ versus total cations, Cl^? + SO₄ ^2? versus Na⁺ + K⁺, Na⁺ versus Cl^?, Na⁺ versus HCO₃ ^? + CO₃ ^2?, Na⁺ versus Ca²⁺ and Na⁺: Cl^? versus EC indicate that the rock–water interaction under alkaline condition is the main mechanism in activating mineral dissociation and dissolution, causing the release of Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, CO₃ ^2?, SO₄ ^2? and F^? ions into the groundwater. The ionic relations also suggest that the higher concentrations of Na⁺ and Cl^? ions are the results of ion exchange and evaporation. The influences of anthropogenic sources are the other cause for increasing of Mg²⁺, Na⁺, Cl^?, SO₄ ^2? and NO₃ ^? ions. Further, the excess alkaline condition in water accelerates more effective dissolution of F^?-bearing minerals. Moreover, the chemical data plotted in the Piper’s, Gibbs’s and Langelier–Ludwig’s diagrams, computed for the chloro-alkaline and saturation indices, and analyzed in the principal component analysis, support the above hypothesis. The groundwater quality is, thus, characterized by Na⁺ > Ca²⁺ > Mg²⁺ > K⁺: HCO₃ ^? + CO₃ ^2? > Cl^? > SO₄ ^2? > NO₃ ^? > F^? facies. On the other hand, majority of groundwater samples are not suitable for drinking with reference to the concentrations of TDS, TH, Mg²⁺ and F^?, while those are not good for irrigation with respect to USSL’s and Wilcox’s diagrams, residual sodium carbonate, and magnesium hazard, but they are safe for irrigation with respect to permeability index. Thus, the study recommends suitable management measures to improve health conditions as well as to increase agricultural output.     

High lipid content and productivity of microalgae cultivating under elevated carbon dioxide

This study examined the cell growth rate, lipid contents, lipid productivity, chlorophyll a concentration, and carbon dioxide tolerance of Chlorella vulgaris under various cultivation conditions. The pH, concentration of carbon dioxide in media, and light intensity variables were manipulated to obtain high lipid productivity. The optimum conditions were at pH 7.0, 2,930 lux, and 30 % carbon dioxide. Biomass concentration reached 1,288, 1,130, and 1,083 mg L^?1 at 15, 30, and 50 % CO₂ after 6 days, respectively, implying that this strain has appreciable tolerance to carbon dioxide. The highest concentration of chlorophyll a occurred at 2,930 lux and decreased with increasing light intensity gradually. The maximum specific growth rate was 3.25 day^?1 based on the dry weight and 4.63 day^?1 based on the cell number. The lipid content (45.68 %) and lipid productivity (86.03 mg day^?1 L^?1) obtained in this study are higher than reported values in literatures. Hence, C. vulgaris is a good candidate for subsequent research in biodiesel production under elevated carbon dioxide concentration by microalgae.     

Assessment of groundwater quality in and around Vedaraniyam,South India

Groundwater from 47 wells were analyzed on the basis of hydrochemical parameters like pH, electric conductivity, total dissolved solids, Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl^?, CO₃ ^2?, HCO₃ ^?, NO₃ ^?, PO₄ ^3? and F^? in the Cauvery delta of Vedaraniyam coast. Further, water quality index (WQI), sodium percentage (Na %), sodium absorption ratio, residual sodium carbonate, permeability index and Kelley’s ratio were evaluated to understand the suitability of water for drinking and irrigation purposes. The result shows significant difference in the quality of water along the coastal stretch. The order of dominance of major ions is as follows: Na⁺ ≥ Mg²⁺ ≥ Ca²⁺ ≥ K⁺ and Cl^? ≥ HCO₃ ^? ≥ CO₃ ^2? ≥ PO₄ ^3? ≥ F^?. Na/Cl, Cl/HCO₃ ratio and Revelle index confirmed that 60–70 % of the samples were affected by saline water intrusion. WQI showed that 36 % of the samples were good for drinking and the remaining were poor and unsuitable for drinking purpose. The degradation of groundwater quality was found to be mainly due to over-exploitation, brackish aquaculture practice, fertilizer input from agriculture and also due to domestic sewage.     

Fluoride-bearing groundwater in Gummanampadu Sub-basin, Guntur District, Andhra Pradesh, India

The functional factors responsible for fluoride (F^?)-bearing groundwater used for drinking as well as for cooking in the area of Gummanampadu Sub-basin, Guntur District, Andhra Pradesh, India are discussed. The study area is a part of an Archean Gneissic Complex, consisting of banded-biotite-hornblende-gneisses, over which the Proterozoic Cumbhum quartzites, shales, phyllites, and dolomitic limestones occur. The chemistry of groundwater is dominated by carbonates (HCO₃ ^? and CO₃ ^2?) at a higher pH. This results in a higher total alkalinity over total hardness, causing an excess alkalinity. Sodium ion is dominated among the cations (Ca²⁺, Mg²⁺, and K⁺). The concentration of F^? (2.1–3.7 mg/L) is higher than that of desirable national limit (1.2 mg/L) prescribed for drinking purpose. A significant positive correlation exists between F^? and pH as well as that between F^? and HCO₃ ^? + CO₃ ^2?. This indicates that the alkaline condition is the prime conducive factor for dissolving F^?-bearing minerals more effectively leading to a higher concentration of F^? in the groundwater. Furthermore, a positive chloro-alkaline index reflects the ion exchange, and an oversaturation with respect to CaCO₃ indicates the evaporation. In addition, a negative relation between the well depth and F^? shows the effect of solubility and/or leaching of salts in different depth levels. These factors regulate the concentration of F^? in the groundwater. On the other hand, a positive correlation of F^? with SO₄ ^2? as well as with K⁺ shows the human land use activities (namely, use of chemical fertilizers, disposal of domestic wastes, etc.), which add F^? to the groundwater. A significant number of the residents of the study area suffer from the health disorders related to fluorosis, which is a consequence of higher concentration of F^? in the drinking water. Thus, this study emphasizes the need for supply of safe drinking water, nutritional diet, rainwater-harvesting structures, and public education to realize “health for all” motto of World Health Organization.     

Groundwater balance in the Khor Arbaat basin, Red Sea State, eastern Sudan

The Khor Arbaat basin is the main source of potable water supply for the more than 750,000 inhabitants of Port Sudan, eastern Sudan. The variation in hydraulic conductivity and storage capacity is due to the heterogeneity of the sediments, which range from clay and silt to gravely sand and boulders. The water table rises during the summer and winter rainy seasons; it reaches its lowest level in the dry season. The storage capacity of the Khor Arbaat aquifer is estimated to be 21.75?×?10⁶ m³. The annual recharge through the infiltration of flood water is about 1.93?×?10⁶ m³. The groundwater recharge, calculated as underground inflow at the ‘upper gate’, is 1.33?×?10⁵ m³/year. The total annual groundwater recharge is 2.06?×?10⁶ m³. The annual discharge through underground outflow at the ‘lower gate’ (through which groundwater flows onto the coastal plain) is 3.29?×?10⁵ m³/year. Groundwater discharge due to pumping from Khor Arbaat basin is 4.38?×?10⁶ m³/year on average. The total annual groundwater discharge is about 4.7?×?10⁶ m³. A deficit of 2.6?×?10⁶ m³/year is calculated. Although the total annual discharge is twice the estimated annual recharge, additional groundwater flow from the fractured basement probably balances the annual groundwater budget since no decline is observed in the piezometric levels.     

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin,northwest China

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114?×?10⁴ m³/year in 2017 to 11,875?×?10⁴ m³/year in 2021, and to 17,039?×?10⁴ m³/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277?×?10⁴ m³/year in 2017 to 1857?×?10⁴ m³/year in 2021, and to 510?×?10⁴ m³/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.     

Calculating groundwater mixing ratios in groundwater-inrushing aquifers based on environmental stable isotopes (D, 18O) and hydrogeochemistry

Conventional hydrogeochemical data and environmental stable isotopes are used to identify the recharge sources and the water–rock interactions in the groundwater-flowing direction within the multilayer groundwater system of the Sulin coal-mining district in the north Anhui province in China. δD and δ ¹⁸O of groundwater in the mining district decrease along the groundwater-flowing direction in the recharge areas, yet in the runoff or discharge areas, they rise and fall along average δ values (δ ¹⁸O = ?8.68 ‰, δD = ?67.4 ‰), which are lower than average δ values of local atmospheric precipitation (δ ¹⁸O = ?7.80 ‰, δD = ?52.4 ‰). Principal component analysis is used to analyze the conventional hydrogeochemical data (K⁺ + Na⁺, Mg²⁺, Ca²⁺, Cl^?, SO₄ ^2?, HCO₃ ^?, CO₃ ^2?) in the groundwater. The first and second principal components have large variance contributions, and represent “pyrite oxidation or groundwater hardening” and “desulfurization or cation exchange and adsorption,” respectively. From conventional hydrogeochemical data and environmental stable isotopes, it is demonstrated that groundwater of the Sulin coal-mining district is characterized by a mixing type, which is confirmed by three recharge end-members: fresh groundwater, leaching groundwater, and retained groundwater. By means of a sample dot-encompassed triangle in the scatter diagram of load scores for Component 1–Component 2, whose vertexes stand for the three end-members, a model for calculating groundwater mixing ratio is established and applied successfully to the evaluation and management of groundwater hazards in the coal-mining districts.     

Estimating groundwater inflow and leakage outflow for an intermontane lake with a structurally complex geology: Georgetown Lake in Montana,USA

Stable isotopes of the water molecule (δ¹⁸O and δD) for groundwater, lake water, streams, and precipitation were coupled with physical flux measurements to investigate groundwater–lake interactions and to establish a water balance for a structurally complex lake. Georgetown Lake, a shallow high-latitude high-elevation lake, is located in southwestern Montana, USA. The lake is situated between two mountain ranges with highlands primarily to the east and south of the lake and a lower valley to the west. An annual water balance and (δ¹⁸O and δD) isotope balance were used to quantify annual groundwater inflows of 2.5?×?10⁷ m³/year and lake leakage outflows of 1.6?×?10⁷ m³/year. Roughly, 57% of total inflow to the lake is from groundwater, and 37% of total outflow at Georgetown Lake is groundwater. Stable isotopes of groundwater and springs around the lake and surrounding region show that the east side of the lake contains meteoric water recharged annually from higher mountain sources, and groundwater discharge to the lake occurs through this region. However, springs located in the lower western valley and some of the surrounding domestic wells west of the lake show isotopic enrichment indicative of strong to moderate evaporation similar to Georgetown Lake water. This indicates that some outflowing lake water recharges groundwater through the underlying west-dipping bedrock in the region.     

Air–Water CO<Subscript>2</Subscript> Fluxes and Net Ecosystem Production Changes in a Baja California Coastal Lagoon During the Anomalous North Pacific Warm Condition

The present study examines the temporal variability of air–water CO₂ fluxes (FCO₂) and seawater carbonate chemistry in a Baja California coastal lagoon during an exceptionally warm anomaly that was developed in Northeast Pacific coasts during 2014. This oceanographic condition led to a summer-like season (weak upwelling condition) during the study period, which reached a maximum surface temperature anomaly of 2 °C in September 2014. San Quintín Bay acts as a source of CO₂ to the atmosphere in 2014 (3.3 ± 4.8 mmol C m^?2 day^?1) with the higher positive fluxes mainly observed in summer months (9.0 ± 5.3 mmol C m^?2 day^?1). Net ecosystem production (NEP) switched seasonally between net heterotrophy and net autotrophy during the study period, with an annual average of 2.2 ± 7.1 mmol C m^?2 day^?1, which indicates that San Quintín Bay was a net autotrophic system during the atypical warm oceanographic condition in 2014. This pattern of seasonal variations in the carbon balance at San Quintín Bay appears to be linked to the life cycle of benthic communities, which play an important role in the whole-ecosystem metabolism. Under the limited input from external sources coupled with an increase in seawater temperatures, the recycled benthic carbon and nutrient fluxes play a major role to sustain water-column processes within the bay. Since the upwelling condition may influence the magnitude of the air–water CO₂ fluxes, our results clearly indicated that San Quintín Bay is a net source of carbon to the atmosphere regardless of the adjacent oceanic conditions. Our study sheds light on the carbon dynamics and its metabolic implications in a shallow coastal ecosystem under a regional warm anomaly and contributes potentially relevant information in view of the likely future scenario of global climate change.     

Groundwater mixing in the discharge area of San Vittorino Plain (Central Italy): geochemical characterization and implication for drinking uses

Discharge areas of carbonate fractured and karstified aquifers are a sensitive system of great interest, where frequently groundwater resources are tapped for drinking water supply. In geological settings affected by recent and/or active tectonics, mixing between fresh water coming from recharge areas and groundwater from deeper circuits, influenced by raising fluids, influences hydrogeochemistry. Surveys on major ions, trace elements and stable isotopes have been performed in the San Vittorino Plain (Central Italy), where the major source of drinking water for Rome is located (Peschiera Springs, mean discharge 18 m³ s^?1, half of them tapped). Results of 21 springs revealed different contribution from recharge areas and deep flow paths, by increasing salinity and ion content, with particular references to Ca²⁺, HCO₃ ^? and SO₄ ^2?. Three main groups, respectively, related to fresh waters from recharge areas, groundwater from deep contribution and a mixing group between them, have been identified. Water stable isotopes allow to identify the common origin from rainfall and a very steady contribution with seasons and year, due to the huge extent of recharge area (>1000 km²). Saturation Indexes gave insight on the contribution of deep fluids, mainly CO₂ and H₂S, which turned groundwater to undersaturated conditions, facilitating rock dissolution. By PHREEQC software, the mixing between two considered end-members has been simulated, evaluating about 25% of deep contribution in the basal springs of San Vittorino Plain. Chemistry of Peschiera spring reveals a very limited percentage of deep flow paths (10%), which can lead to slight hydrochemistry changes even in possible drought conditions, when discharge can decrease until 15 m³ s^?1.     

Spatial variability of groundwater quality and its suitability for drinking and irrigation in the Amik Plain (South Turkey)

In this study, it is determined physicochemical properties of the groundwater and the spatial variability of physicochemical properties of the groundwater in the Amik plain and as well as assess its suitability for drinking and irrigation. A total 92 groundwater samples were collected from drilled well in June 2012. In addition, the 42 of 92 drilled wells were also sampled in September 2012 to evaluate the changes of groundwater properties. According to t test values, the mean Ca²⁺, SO₄ ^2?, Mg²⁺ and TH values in the June period were significantly lower than those of the September period. On the other hand, the mean (CO ₃ ^2?  + HCO₃ ^?) and RSC and MR values in the June period were significantly higher than those of the September period. The order of relative abundance of major cations in the groundwater (in mg L^?1) is in order Na⁺ > Mg²⁺ > Ca²⁺ > K⁺. The order of the anions abundance (mg L^?1) is SO₄ ^2? > Cl^? > HCO₃ ^? > CO₃ ^2? in this research. Log and square-root transformation were carried out for the most of the water properties before the calculation of semivariance. The nugget ratio showed all the variables were strongly spatial dependent except for K⁺ and Mg²⁺ and (CO₃ ^2? + HCO₃ ^?) which showed moderate spatial dependence (ratio ranging from 28 to 49.9 %). Spatial distribution analysis of groundwater quality indicated that The EC, TDS values and Na and Cl^? contents which is important water quality parameters increase from northern towards southern. The total hardness values increase also from northwestern towards southwestern.     

CO<Subscript>2</Subscript> flux variation and its contribution area in the debris-covered area of Koxkar Glacier,Mt. Tianshan in China

During the formation and development of glacial meltwater runoff, hydrochemical erosion is abundant, especially the hydrolysis of K/Na feldspar and carbonates, which can consume H⁺ in the water, promote the formation of bicarbonate by dissolving atmospheric CO₂, and affect the regional carbon cycle. From July 21, 2015, to July 18, 2017, the CO₂ concentration and flux were observed by the eddy covariance (EC) method in the relatively flat and open moraine cover area of Koxkar Glacier in western Mt. Tianshan, China. We found that: (1) atmospheric CO₂ fluxes ranged from ??408.95 to 81.58 mmol m^?2 day^?1 (average ? 58.68 mmol m^?2 day^?1), suggesting that the study area is a significant carbon sink, (2) the CO₂ flux footprint contribution areas were primarily within 150 m of the EC station, averaging total contribution rates of 93.30%, 91.39%, and 90.17% of the CO₂ flux in the snow accumulation, snow melting, and glacial melting periods, respectively. Therefore, the contribution areas with significant influences on CO₂ flux observed at EC stations were concentrated, demonstrating that grassland CO₂ flux around the glaciers had little effect at the EC stations, (3) in the predominant wind direction, under stable daytime atmospheric stratification, the measurement of CO₂ flux, as interpreted by the Agroscope Reckenholz Tanikon footprint tool, was 79.09% ± 1.84% in the contribution area. This was slightly more than seen at night, but significantly lower than the average under unstable atmospheric stratification across the three periods of interest (89%). The average distance of the farthest point of the flux footprint under steady state atmospheric conditions was 202.61?±?69.33 m, markedly greater than that under non-steady state conditions (68.55?±?10.34 m). This also indicates that the CO₂ flux observed using EC was affected primarily by hydrochemical erosion reactions in the glacier area, (4) a good negative correlation was found between net glacier exchange (NGE) of CO₂ and air temperature on precipitation-free days. Strong ice and snow ablation could promote hydrochemical reactions of soluble substances in the debris area and accelerated sinking of atmospheric CO₂. Precipitation events might reduce snow and ice melting, driven by reduced regional temperatures. However, a connection between NGE and precipitation, when less than 8.8 mm per day, was not obvious. When precipitation was greater than 8.8 mm per day, NGE decreased with increasing precipitation, (5) graphically, the slope of NGE, related to daily runoff, followed a trend: snow melting period?>?snow accumulation period?>?early glacial ablation period?>?late glacier ablation period?>?dramatic glacier ablation period. The slope was relatively large during snow melting, likely because of CO₂ sinking caused by water–rock interactions. The chemical reaction during elution in the snow layer might also promote atmospheric CO₂ drawdown. At the same time, the damping effect of snow cover and the almost-closed glacier hydrographic channel inhibited the formation of regional runoff, possibly providing sufficient time for the chemical reaction, thus promoting further CO₂ drawdown.     

Seasonal Oxygen Dynamics in a Warm Temperate Estuary: Effects of Hydrologic Variability on Measurements of Primary Production,Respiration, and Net Metabolism

Seasonal responses in estuarine metabolism (primary production, respiration, and net metabolism) were examined using two complementary approaches. Total ecosystem metabolism rates were calculated from dissolved oxygen time series using Odum’s open water method. Water column rates were calculated from oxygen-based bottle experiments. The study was conducted over a spring-summer season in the Pensacola Bay estuary at a shallow seagrass-dominated site and a deeper bare-bottomed site. Water column integrated gross production rates more than doubled (58.7 to 130.9 mmol O₂ m^?2 day^?1) from spring to summer, coinciding with a sharp increase in water column chlorophyll-a, and a decrease in surface salinity. As expected, ecosystem gross production rates were consistently higher than water column rates but showed a different spring-summer pattern, decreasing at the shoal site from 197 to 168 mmol O₂ m^?2 day^?1 and sharply increasing at the channel site from 93.4 to 197.4 mmol O₂ m^?2 day^?1. The consistency among approaches was evaluated by calculating residual metabolism rates (ecosystem ? water column). At the shoal site, residual gross production rates decreased from spring to summer from 176.8 to 99.1 mmol O₂ m^?2 day^?1 but were generally consistent with expectations for seagrass environments, indicating that the open water method captured both water column and benthic processes. However, at the channel site, where benthic production was strongly light-limited, residual gross production varied from 15.7 mmol O₂ m^?2 day^?1 in spring to 86.7 mmol O₂ m^?2 day^?1 in summer. The summer rates were much higher than could be realistically attributed to benthic processes and likely reflected a violation of the open water method due to water column stratification. While the use of sensors for estimating complex ecosystem processes holds promise for coastal monitoring programs, careful attention to the sampling design, and to the underlying assumptions of the methods, is critical for correctly interpreting the results. This study demonstrated how using a combination of approaches yielded a fuller understanding of the ecosystem response to hydrologic and seasonal variability.     

Carbon dioxide in Postojna Cave (Slovenia): spatial distribution,seasonal dynamics and evaluation of plausible sources and sinks

The CO₂ concentration of the air in Postojna Cave (400–7900 ppm) is found to be induced by CO₂ sources (human respiration contributing?~?20,000–58,000 ppm per breath, outgassing of dripwater and water seeping from the vadose zone/epikarst with a pCO₂ values of 5000–29,000 ppm, and underground Pivka River having pCO₂ at 2344–4266 ppm) and CO₂ dilution (inflow of outside air with a CO₂ concentration of?~?400 ppm). Measurements show that sinking Pivka River has the lowest CO₂ concentration among plausible CO₂ sources but still continuously exceeds the surrounding cave air CO₂ concentration. During the winter months, intensive ventilation reduces the cave air CO₂ concentration to outside levels (~?400 ppm), even in the centre of the cave system. CO₂ dilution is less pronounced in summer (CO_2(min)?≈?800 ppm), since the ventilation rate is not as strong as in winter and the outside air that enters the cave through breathing holes and fractures is enriched with soil CO₂. During spring and autumn, the daily alternation of the ventilation regime with a smaller rate of air exchange results in yearly cave air CO₂ peaks of up to?~?2400 ppm. Some dead-end passages can be much less affected by ventilation, resulting in a cave air CO₂ concentration of up to 7900 ppm. The strongest diurnal CO₂ peaks due to human respiration were recorded during the spring holidays (increase of up to 1300 ppm day^?1), compared to considerably smaller summer peaks despite peak visits (increase of?~?600 ppm day^?1).