GPS定位技术在三峡库区崩滑地质灾害监测中的试验分析

采用GPS定位技术对三峡库区崩滑地质灾害监测进行试验性研究，是实现对地质灾害监测、预报和防治的现代化而采取的一项重要举措。其目的是分析、研究和论证利用GPS定位技术进行崩滑监测的可行性并制定技术规程；建立从链子崖至巴东段的地质灾害GPS监测试验（示范）。基于GPS技术在三峡库区崩滑地质灾害监测中的试验研究，分析了GPS监测的最佳时期、最佳时段长度、最佳截止高度的选取及适宜采用的软件和星历等问题，结果表明，利用GPS定位技术进行崩滑地质灾害监测能够满足其精度要求，该项技术是可行的。     

Constraints on a geodetic time transfer network in Iran

Iran is a developing country, and nowadays, a demand to establish a time transfer system can be sensed more than anytime. On the other hand, global positioning system (GPS) is one of the most efficient and accurate systems in precise time estimation and dissemination domain. This study aims to investigate the different accuracy limiting effects of a time transfer system in a geodetic point of view. For this purpose, a simulation study is performed in which pseudo-range and carrier phase observations are simulated for some GPS stations in Iran. The baselines for time transfer have been chosen in a way that the maximum effect of each bias source can be analyzed. Therefore, the results of this study can be used in order to design the absolute and relative locations of the GPS stations equipped with external atomic frequencies in Iran considering a specific application. As a result, the most prominent bias source is the site-specific troposphere parameters which produce a variation of more than 1 ns in the time transfer results. Other bias sources including bias in the coordinate components and orbital information have a considerable impact only for time keeping purposes. Additionally, the influence of noise of the carrier phase and pseudo-range observations is analyzed. Variations of clock estimations between consecutive epochs up to 70 ps and day boundary discontinuities up to 0.6 ns, respectively, are the results of measurement errors. On the other hand, a time transfer between H-masers located at US Naval Observatory and National Resources Canada has been conducted to pursue a standard and efficient algorithm to deal with the problem of day boundary jumps. The method of overlapping batches with 12 h coverage of each of the involved days is applied to overcome this problem. The results of this method show a considerable decrease in the magnitude of the day boundary jumps.     

Optimization of sample preparation method of total sulphur measurement in mine tailings

A sample preparation method of total sulphur measurement of reactive mine tailings was optimized. The total sulphur was measured by inductively coupled plasma optical emission spectroscopy, and ultrasound technique was used for sample digestion. The optimization process was adopted by a combined approach of experimental design and response surface methodology. The digestion time, temperature and acid-oxidant combination (i.e. effect of H₂O₂ with a fixed amount of acid mixture) were investigated. A two-level and three-factor (2³) full factorial design of experiment was applied to identify the most significant factors, and a central composite design was used to optimize the digestion procedure. KZK-1, a sericite schist, was selected as the certified reference material. The optimum methodology at 95 % confidence level (P < 0.05) was identified to be 10 min of digestion at 77 °C, with a solution of 1 ml HNO₃:1 ml HCl:1.35 ml H₂O₂. This combination resulted in 100 % sulphur recovery. The investigated method was verified by X-ray diffraction analysis. The optimum digestion level was applied to a reactive mine tailings, which achieved satisfactory results with a percentage relative standard deviation < 3 %.     

Adsorption capacity of iron oxide-coated gravel for landfill leachate: simultaneous study

Landfill leachate is a high-strength wastewater. If it is not managed properly, it can pollute surrounding environment. The aim of this study is to determine the simultaneous adsorption capacity of iron oxide-coated gravel for metals such as Cd(II), Cu(II), Fe(II), Ni(II) and Zn(II) in high-strength leachate sample. Different operating conditions such as pH, time, and dosages were investigated to determine the kinetics and mechanism of adsorption process. Coating with iron oxide changed the external surface of gravel. The adsorption capacities increased with increased pH, and the optimum pH was found to be 7. High removal rates were observed in a short period of time. The Freundlich model fitted reasonably well to the experimental data, indicating multilayer adsorption process and the heterogeneity of the surface (R ² ranging 0.57–0.94). The Temkin model fitted well to the experimental data as well (R ² ranging 0.67–0.98), indicating that the adsorption is an exothermic process. The adsorption of ions was found to obey second-order kinetics, indicating one-step, surface-only adsorption process. The degree of metal adsorption on iron oxide-coated gravel at pH 7 was in the order Cu(II) > Cd(II) > Fe(II) > Zn(II) > Ni(II).     

Temporal variability of diverse mountain permafrost slope movements derived from multi-year daily GPS data,Mattertal, Switzerland

In this study, high resolution surface measurements of diverse slope movements are compared to environmental factors such as ground surface temperature (GST) and snow cover, in order to reveal and compare velocity fluctuations caused by changing environmental conditions. The data cover 2 years (2011–2013) of Global Positioning System (GPS) and GST measurements at 18 locations on various slope movement types within an alpine study site in permafrost (Mattertal, Switzerland). Velocities have been estimated based on accurate daily GPS solutions. The mean annual velocities (MAV) observed at all GPS stations varied between 0.006 and 6.3 ma^?1. MAV were higher in the period 2013 compared to 2012 at all stations. The acceleration in 2013 was accompanied by a longer duration of the snow cover and zero curtain and slightly lower GST. The amplitude (0–600 %) and the timing of the intra-annual variability were generally similar in both periods. At most stations, an annual cycle in the movement signal was observed, with a phase lag of 1–4 months to GST. Maximum velocity typically occurred in late summer and autumn, and minimum velocity in late winter and beginning of spring. The onset of acceleration always started in spring during the snowmelt period. At two stations located on steep rock glacier tongues, overprinted on the annual cycle, short-term peaks of velocity increase, occurred during the snowmelt period, indicating a strong influence of meltwater.     

Degradation of phenol and trichlorophenol by heterogeneous photo-Fenton process using Granular Ferric Hydroxide<Superscript>®</Superscript>: comparison with homogeneous system

The decomposition of phenol and trichlorophenol (TCP) by using granular ferric hydroxide (GFH) as a photo-Fenton catalyst was investigated and compared with homogeneous photo-Fenton process. Experiments were conducted in a batch mode, duplicate for the degradation of phenol and TCP in the presence of solar light for both the processes. The effect of operating variables for heterogeneous photo-Fenton process like pH, peroxide concentration and GFH concentration on the degradation of the model compounds was optimized by univariate approach. The optimum conditions for the degradation of phenol and TCP were pH 3.0 ± 0.2, peroxide concentration 29.4 mM for phenol and 14.7 mM for TCP at GFH concentration of 0.5 g/500 mL. At optimum conditions, the mineralization efficiency of phenol and TCP by heterogeneous process was compared with homogeneous process. The mineralization efficiency for phenol and TCP was 96 and 86 %, respectively, for heterogeneous photo-Fenton process, while almost complete mineralization (~96 %) was observed for homogeneous process. In heterogeneous photo-Fenton process, longer reaction time was witnessed for complete mineralization of the compounds studied. Low molecular weight aliphatic acids like oxalic acid, acetic acid and inorganic chloride ion (in case of TCP) were observed during both the processes. In these processes, the reaction proceeds by hydroxyl radical (·OH) abstraction of the model compound studied. The mineralization of phenol and TCP obeys pseudo-first-order kinetics irrespective of the processes studied. The results indicate that GFH can be an effective heterogeneous photo-Fenton catalyst for the degradation of phenol and TCP.     

Evaluation of the GPS Precise Point Positioning technique during the 21 July 2017 Kos-Bodrum (East Aegean Sea) Mw 6.6 earthquake

Precise Point Positioning (PPP) algorithms have been widely used in the Global Positioning System (GPS)-based applications. A PPP technique with a single receiver provides effective solutions where accurate absolute positioning is required. This paper provides the performance assessment of GPS PPP for detecting the displacements caused by an earthquake. For this purpose, the earthquake that occurred on 21 July 2017 at Kos-Bodrum with the impact of Mw 6.6 was investigated by analyzing the data of the permanent GPS stations located around the related region with the PPP technique. The location distances of these GPS stations range from 10 to 89 km to the epicenter of this earthquake. GPS data provided from seven permanent stations from the Continuously Operating Reference Stations-Turkey (CORS-TR) and local Bodrum CORS networks were processed to determine the co-seismic displacements during the earthquake. The data of these stations for days of year (DOYs) 200, 201, 202, and 203 were analyzed with post-process static PPP and kinematic PPP methods. GIPSY-OASIS II v6.4 was used for processing the data and all of the solutions were performed in the ITRF2008 reference frame. Two strategies were followed on the post-process static solutions. In the first strategy, 4-day data with 24-h observations were separately analyzed day by day. In the second strategy, the 24-h data were divided into 3-h duration, which is the minimum duration for optimum PPP solutions, and then the analyses were performed. When the displacements between DOYs 200 and 203 are considered in the 24-h data analysis, significant displacements have been observed through northwest direction in the northern stations whereas MUG1 is excluded. Moreover, there is significant displacement through the southeast direction in the station DATC located in the south of the epicenter. When the 3-h solutions are examined, displacements, especially on n and e directions, are observed starting from the solutions, which include Mw 6.6 earthquake. According to the kinematic PPP solutions, the effects of the Mw 6.6 earthquake can be seen clearly in the stations DATC, ORTA, TRKB, and YALI. Considering all outcomes, the PPP technique with both static and kinematic solutions provides effective results for detecting the displacements during the earthquake.     

Redefining the watershed line and stream networks via digital resources and topographic map using GIS and remote sensing (case study: the Neka River’s watershed)

The accurate delineation of area plays a key role in the surveying of land change detection and the classification of land covers. In a hydrologic system, the watershed delineation and the detection of the boundaries among watershed is a basic method for performing spatial analyses. After recent advances in image processing and raster-based spatial analysis in geographic information systems, and being easily accessible data via various sources especially through remote sensing, the reliable determination of topographical boundaries possible is possible. Therefore, an integrated approach of data analysis and modeling can accomplish the task of delineation. The main aim in this research is to evaluate the delineation method of watershed boundary using four different digital elevation models (DEM) including advanced spaceborne thermal emission and reflection radiometer (ASTER), Shuttle Radar Topographic Mission (SRTM), digital topography, and topographic maps. In order to determine a true reference of boundary of watershed, sample data were also obtained by field survey and using global positioning system (GPS). The comparison reference points and the results of these data showed the average distance difference between reference boundary, and the result of ASTER data was 43 m. However, the average distance between GPS reference and the other data was high; the difference between the reference data and SRTM was 307 m, and for digital topographic map, it was 269 m. The average distance between topographic map and the GPS points differed 304 m as well. For the statistical analysis of comparison, the coordinates of 230 points were determined; the paired comparisons were also performed to measure the coefficient of determination, R ², as well as analysis of variance in SPSS software. As a result, the R ² values for the ASTER data with the digital topography and topographic map were 0.0157 and 0.171, respectively. The results showed that there were statistically significant differences in distances among the four means of the selected models. Therefore, considering other three methods, the ASTER DEM is the most suitable applicable data to delineate the borders of watersheds, especially in rugged terrains. In addition, the calculated flow directions of stream based on ASTER are close to natural tributaries as well as real positions of streams.     

The relative importance of soil crust and slope angle in runoff and soil loss: a case study in the hilly areas of the Loess Plateau, North China

Soil crust and slope angle are of important factors affecting runoff production and sediment yield. In the hilly areas of the Loess Plateau, North China, slope lands are distributed extensively and subjected to soil crusting; therefore, the research on the responses of runoff and soil loss to soil crust and slope angle is essential to soil and water conservation. In the study, five pairs of 1 m × 5 m plots with slope angles of 5°, 10°, 15°, 20° and 25° respectively, were established in Wangjiagou watershed, which was located at the Loess Plateau, China. Based on the two simulated rainfall events, uncrusted surface prior to the first simulated rainfall event, and crusted surface prior to the second rainfall event were distinguished. The runoff production and soil loss were measured at intervals of 5 min during the simulated events. It indicated that both soil crust and slope angle played an important role in runoff production and soil loss. With the reference slope angle of 5°, the relative importance of soil crust and slope angle in runoff production was calculated. It showed that soil crust effect on the total runoff volume decreased from 100 to ～40%, while slope angle effect increased from 0 to ～60% with increasing slope angle because soil crust less developed on the steeper slopes. Furthermore, soil crust effect was associated with rainfall duration. At the same slope angle, the relative importance of soil crust decreased with rainfall duration because new crust was formed on the uncrusted surface. The critical slope of erosion was also discussed. Soil loss increased with slope angle when the slope angle was less than 20°. Generally speaking, soil crust effect decreased with slope angle and/or rainfall duration.     

Development of low-cost passive sampler from cow bone char for sampling of volatile organic compounds

A simple and low-cost passive sampler for collection of volatile organic compounds, specifically benzene, toluene, ethylbenzene and xylene (BTEX), from the ambient air has been developed by using cow bone char (CBC) as an adsorbent with desorption by solvent extraction prior to analysis by gas chromatography–mass spectrometry (GC–MS). The laboratory-made CBC was prepared by calcination process in a partially oxidative atmosphere. The developed passive sampler was tested for a suitable amount of CBC used, diffusion tube type and size, and sampling duration, in a closed chamber saturated with each of the BTEX vapors. With the optimum amount of 250 mg CBC packed in a glass bottle (82.6 mm height × 11.1 mm i.d.) and the exposure time of 168 h, detection limits (µg/m³) for BTEX determination using this developed sampler together with GC–MS were 0.28 (benzene), 0.79 (toluene), 0.58 (ethylbenzene), 0.28 (p-xylene) and 0.54 (o-xylene). The proposed method was applied to sampling BTEX from selected petrol stations, traffic congestion areas and a rural area in Chiang Mai Province, Thailand. The BTEX concentrations detected were well correlated with their sources as they were the highest at the petrol station sites, lower at the traffic congestion area sites and the lowest at the rural area site. The laboratory-made passive sampler containing CBC has thus opened up a possibility of having a simple and effective device for sampling of BTEX in the ambient air.     

Sorption of Cd<Superscript>2+</Superscript> ions onto zeolite synthesized from perlite waste

In this work, the studies on the formation of zeolites from expanded perlite waste and their use in the sorption process of Cd²⁺ ions will be reported. Such approach is innovative and has not been investigated elsewhere. The results of the synthesis of zeolites from aluminosilicate waste using hydrothermal method were presented. By-product from the process production of expanded perlite was used as the starting material. Theoretical and practical aspects of Cd²⁺ ions sorption process onto material synthesized in selected conditions (a material with good sorption capacity can be obtained by 24 h reaction of 1 g of perlite waste in 10 mL of 4.0 M NaOH solution with at 70 °C) will be presented. The atomic absorption spectroscopy has been used as the main method, from which the effective cation exchange capacity as well as the proportion of ion exchange to chemisorption in the sorption process have been determined. Structural analyses of the sample before and after sorption process have been also carried out by the mid-infrared spectra measurement, especially pseudolattice range of the spectra was analyzed in detail in which changes caused by ion exchange of non-tetrahedral ions have been observed.     

Removal of phosphates from aqueous solution by sepiolite-nano zero valent iron composite optimization with response surface methodology

In this study, sepiolite-nano zero valent iron composite was synthesized and applied for its potential adsorption to remove phosphates from aqueous solution. This composite was characterized by different techniques. For optimization of independent parameters (pH = 3–9; initial phosphate concentration = 5–100 mg/L; adsorbent dosage = 0.2–1 g/L; and contact time = 5–100 min), response surface methodology based on central composite design was used. Adsorption isotherms and kinetic models were done under optimum conditions. The results indicated that maximum adsorption efficiency of 99.43 and 92% for synthetic solution and real surface water sample, respectively, were achieved at optimum conditions of pH 4.5, initial phosphate concentration of 25 mg/L, adsorbent dosage of 0.8 g/L, and 46.26 min contact time. The interaction between adsorbent and adsorbate is better described with the Freundlich isotherm (R ² = 0.9537), and the kinetic of adsorption process followed pseudo-second-order model. Electrostatic interaction was the major mechanisms of the removal of phosphates from aqueous solution. The findings of this study showed that there is an effective adsorbent for removal of phosphates from aqueous solutions.     

Removal of ibuprofen from aqueous solution by functionalized strong nano-clay composite adsorbent: kinetic and equilibrium isotherm studies

The functionalized nano-clay composite adsorbent was prepared, and its properties were characterized using FT-IR, XRD and SEM techniques. The synthesized nano-clay composite was studied with regard to its capacity to remove ibuprofen under different adsorption conditions such as varying pH levels (5–9), initial ibuprofen concentrations (3, 5 and 10 mg L^?1), contact time, and the amount of adsorbent (0.125, 0.25, 0.5 and 1 g). In order to evaluate the nanocomposite adsorption capacity, the adsorption results were assessed using nine isotherm models. The results showed that the optimum adsorption pH was 6 and that an increase or decrease in the pH reduced the adsorption capacity. The adsorption process was fast and reached equilibrium after 120 min. The maximum efficacy of ibuprofen removal was approximately 95.2%, with 1 g of adsorbent, 10 mg L^?1 initial concentration of ibuprofen, 120 min contact time and pH = 6. The optimal adsorption isotherm models were the Freundlich, Fritz–Schlunder, Redlich–Peterson, Radke–Prausnitz, Sip, Toth and Khan models. In addition, four adsorption kinetic models were employed for adsorption system evaluation under a variety of experimental conditions. The kinetic data illustrated that the process is very fast, and the reaction followed the Elovich kinetic model. Therefore, this nano-clay composite can be used as an effective adsorbent for the removal of ibuprofen from aqueous solutions, such as water and wastewater.     

Determining the optimal pumping duration of transient pumping tests for estimating hydraulic properties of leaky aquifers using global curve-fitting method: a simulation approach

Global curve-fitting method (GCFM) is regarded as an effective approach in hydrogeological parameter estimation, as it integrates and uses pumping data and water recovery data of a transient pumping test for parameter estimation. The impacts of pumping duration on hydrogeological parameter estimation by GCFM were investigated in the present study using 2 in situ pumping tests and 24 simulated transient pumping tests. Empirical formulas for determining the optimal pumping duration were derived. The study results suggest that pumping duration will have impacts on the accuracy of hydrogeological parameter estimation. When pumping duration is longer than a certain period, relative errors of hydrogeological parameter estimation keep relatively stable within an acceptable limit. Therefore, it is unnecessary to continue the pumping for a very long time after the groundwater level has become stable. When the change rate of drawdown over time (γ) in an observation well located within a distance of 100 m to the pumping well reaches 0.134, the pumping can be stopped. If there are more than one observation wells in a pumping test, the smallest γ value should be selected to determine the optimal pumping duration. This research is meaningful in the instruction of pumping tests, and will reduce test costs greatly.     

Biodiesel synthesis from non-edible oils by transesterification using the activated carbon as heterogeneous catalyst

The need for renewable environmentally friendly energy resources is growing every day. Biodiesel is one of the most promising alternatives to the conventional non-renewable energy resources. Heterogeneous catalysts proved a high efficiency in the transesterification of oils to produce biodiesel. In this research, activated carbon was tested as a heterogeneous catalyst in the transesterification of two non-edible oils (waste cooking oil and Jatropha oil) with methanol to produce biodiesel. Activated carbon was characterized using X-ray diffraction, scanning electron microscope and Fourier transformed infrared. The effect of different operating parameters, namely operation time (30, 60, 120 and 180 min), alcohol-to-oil molar ratio (4:1, 6:1, 8:1 and 10:1), catalyst loading [0.5, 1, 2, 3 and 5% (w/w)] and rotational speed (100, 200, 300 and 400 rpm), was investigated. Results showed that increasing the operational time, the alcohol-to-oil molar ratio and the catalyst loading increases the conversion to biodiesel but only to some extent; increasing the stirring rate was found to be beneficial to the process. The optimum conditions were found to be 2 h of heating, 6:1 alcohol-to-oil ratio, 1 wt% catalyst loading and 400 rpm stirring. Under optimum conditions, the conversion to biodiesel reached 93.95 and 93.27% for the waste cooking oil and the Jatropha oil, respectively. The properties of the obtained biodiesel (density, viscosity, flash point, pour point and cloud point) were measured giving promising results.     

Susceptibility analysis of large-scale debris flows based on combination weighting and extension methods

Susceptibility is an important issue in debris flow analysis. In this paper, 26 large-scale debris flow catchments located in the Wudongde Dam site were investigated. Seven major factors, namely, loose material volume per square kilometer, loose material supply length ratio, average gradient of the main channel, average hill slope, drainage density, curvature of the main channel, and poor vegetation area ratio, were selected for debris flow susceptibility analysis. Geographic information system, global positioning system, and remote sensing, collectively known as 3S technologies, were used to determine major factors. Weights of major factors affecting debris flow susceptibility were determined. This paper applied the combination weighting method, which considers both the preference of the engineers for major factors and the objective major factor information by using analytic hierarchy process and entropy method. Combination weights of major factors for the investigated 26 debris flow catchments are 0.20, 0.12, 0.20, 0.10, 0.08, 0.19, and 0.11, respectively. Combination weights follow the order of loose material volume per square kilometer = average gradient of the main channel > curvature of the main channel > loose material supply length ratio > poor vegetation area ratio > average hill slope > drainage density. This paper applied extension theory, which is used to solve incompatibility and contradiction problems, to determine susceptibility. Susceptibility results show that the susceptibility of 4 debris flow catchments are very low, 13 are low, 8 are moderate, and 1 is high. Assessment results exhibit consistency with the activity analysis.     

Municipal solid waste incineration fly ash sintered lightweight aggregates and kinetics model establishment

Municipal solid waste incineration fly ash blended with pine sawdust and shale, using a neotype trefoil rotary kiln to form lightweight aggregates, is an effective and a potential means method of fly ash disposal. The optimum sintering conditions of Trefoil rotary kiln were determined in terms of an orthogonal test by measuring the pellets’ bulk density, granule strength, 1 h water absorption. As far as the kinetics is concerned, an integral method of Coats–Redfern was introduced to analyze the kinetics characteristics of the mixture samples. Also, the kinetic triplets (apparent activation energy, pre-exponential factor and reaction order) were estimated by the reaction of kinetics model functions. It is shown that the optimum sintering conditions are as follows: (a) preheating temperature of 500 °C, (b) sintering temperature of 1130 °C, (c) holding time of 4 min. The optimum reaction models of the four stages are Avrami–Erofeev, Mample, Avrami–Erofeev and There-dimensional diffusion (Jander), respectively.     

Removal of uranium(VI) from aqueous solutions using Eucalyptus citriodora distillation sludge

Adsorption and desorption of uranium(VI) from dilute aqueous solutions by Eucalyptus citriodora distillation sludge was studied in a batch mode. The potential of Eucalyptus citriodora distillation sludge to remove uranium(VI) from aqueous solutions has been investigated at different conditions of solution pH, metal ion concentrations, biosorbent dosage, biosorbent particle size, contact time and temperature. The results indicated that biosorption capacity of Eucalyptus citriodora distillation sludge was strongly affected by the medium pH, the biosorbent dose, metal ion concentrations and medium temperature. Reduction in particle size increased the biosorption capacity. Langmuir and Freundlich isotherm models were applied to biosorption data to determine the biosorption characteristics. An optimum biosorption capacity (57.75 mg/g) was achieved with pH 4.0, particle size 0.255 mm, biosorbent dose 0.5 g/100 mL and initial uranium(VI) concentration of 100 mg/L. Uranium(VI) removal by Eucalyptus citriodora distillation sludge was rapid, the equilibrium was established within 60 min and pseudo-second-order model was found to fit with the experimental data. The biosorption process decreased with an increase in the temperature indicating its exothermic nature. Pretreatments of biomass with different reagents affected its biosorption capacity. A significant increase (34 %) in biosorption capacity (83.25 mg/g) was observed with benzene treatment. Fourier-transform infra-red studies showed the involvement of carbonyl, carboxyl and amide groups in the biosorption process. The results indicated that sulfuric acid had the best effects as an eluent showing 93.24 % desorption capacity.     

Advanced oxidation of catechol in reverse osmosis concentrate generated in leather wastewater by Cu–graphite electrode

Reverse osmosis (RO) concentrate generated from tannery was treated by advanced electrochemical oxidation using graphite electrodes. Catechol was selected as model organic pollutant in the RO concentrate. The influence of applied current density, catechol concentration, pH, temperature and inner electrode space of electrodes was investigated in electrochemical oxidation system. The optimized conditions were found to be current density (j), 100 mA/cm²; electrolysis time (t _eco), 60 min; pH, 7.0; and temperature, 25 °C at an inner electrode space, 2 cm. The average mass transport coefficient for the removal of catechol as COD was found to be 3.0 × 10^?5 m/s at optimum conditions. Faradic efficiency and specific energy consumption were also calculated for the applied current density. Further, the treatment of catechol was confirmed through Fourier transform infrared spectroscopy. Theoretical evaluation of current density suggested that the removal of catechol was controlled when supplied at above limiting applied current densities and mass transport controlled at lower of limiting current densities.     

近水平煤层开采上覆岩层运动与沉陷规律相关研究

将近水平煤层开采的上覆岩层运动与地表沉陷作为一个整体系统进行研究,论述了采场上覆岩层的运动规律和裂隙拱的形成及发展变化过程。并结合地表沉陷的GPS观测,确定了针对具体地质条件的地表移动变形边界角、移动角,找到了井下工作面推进位置与地表下沉速度之间的关系。