Submarine and coastal karstic groundwater discharges along the southwestern Mediterranean coast of Turkey

A 120 km-long part of the southwestern coast of Turkey, with well-developed karst terrain in contact with the sea, has been investigated by systematic diving surveys to determine the submarine groundwater discharges (SGDs). The physical, chemical and isotopic data have been used to determine the rate of the fresh groundwater end member (FEM) and its temporal dynamics. About 150 SGDs have been detected by diving surveys employed mostly up to a depth of 30 m below sea level (bsl). Among those, 15 SGDs are in the form of coastal or submarine caves with entrances ranging between sea surface and 40 m bsl. The FEM contribution in SGDs ranges from a few percent to more than 80%. Stable isotope data suggest a range of mean recharge area elevations extending from the coast to more than 1,000 m inland. In many of the SGDs, the FEMs are characterized by tritium-based residence times ranging from recent to several decades. Hypothetical geochemical calculations of mixing between freshwater and seawater end members reveal that more than 45% of freshwater contribution is required for karst development in the SGDs. Models suggest a threshold pH of 7.6 or lower for the carbonate rock dissolution.     

倒虹吸形成深饱水带大型充填溶洞的典型实例圆梁山隧道毛坝向斜深饱水带特大型充填溶洞的形成及充填物成灾机制分析

圆梁山深埋特长隧道是渝怀铁路越岭线路方案的关键性控制工程,隧道总长11.070km。隧道穿越四周被志留系和泥盆系泥岩包围的二叠系及三叠系碳酸盐岩构成且受众多NW～NWW向横张断裂切割的毛坝紧密向斜。穿越毛坝向斜碳酸盐岩长度约2.2km。地表多为岩溶洼地及槽谷,岩溶泉、泉群、暗河多出露于横张断裂端部碳酸盐岩与下伏泥岩接触带。泉出露高程,亦即向斜岩溶水局部排水基准面,多在850～900m以上。隧道高程低于局部排水基准面400～450m。隧道施工开挖揭示,向斜核部和东翼在隧道洞身附近当地地下水位400m以下发育有3个罕见的特大型充填溶洞。其中平切面积达6000m2充填有紫红色粉细砂的2#溶洞多次发生涌砂突水灾害,总涌砂量高达6104m3。3#溶洞则发生过极其特殊的黏性土爆喷型突出灾害。初步综合分析认为:向斜核部的层间滑脱和纵向张裂隙以及东翼茅口碳酸盐岩中部的层间错动带,被NW～NWW向横张断裂所交切,为岩溶水的深循环提供了较通畅的原始通道; 横断层间的水头差,导致岩溶水在此通道中做倒虹吸循环; 长期差异溶蚀使原始导水能力强的裂隙或断裂发展为溶洞,其中的水流转化为管道流。强烈溶蚀冲刷与顶板坍塌导致向斜核部吴家坪组碳酸盐岩中的层间滑脱与纵向张裂隙分别发育为1#、2#溶洞,东翼茅口碳酸盐岩中的层间错动带则发展为3#溶洞; 后因深部径流条件改变而被充填,形成现今这种罕见的深饱水带特大型充填溶洞。     

The use of hydrochemical techniques to estimate the discharge of Ovacık submarine springs on the Mediterranean coast of Turkey

Shallow submarine springs along the Mediterranean coast of Turkey discharge most available groundwater via highly developed karstic (buried channels) systems towards the Mediterranean Sea before interception for domestic and agricultural uses. This phenomenon takes place in OvacLk-Silifke village, one of the most intensive touristic places on the Mediterranean coast of Turkey. This study reports on the hydrochemical tests and dye-tracing techniques that were used to measure the amount of water discharge along the OvacLk coastline. Comparison of the electrical conductivity (EC) of the karst springs, which have a background concentration of 500 µS/cm, with the EC of the coastal and submarine discharges is an important tool for identifying the percentage of available freshwater from the shallow submarine springs.     

Hydrogeological and hydrogeochemical characterization of a karstic mountain region

Karstic limestone formations in the Mediterranean basin are potential water resources that can meet a significant portion of groundwater demand. Therefore, it is necessary to thoroughly study the hydrogeology and hydrogeochemistry of karstic mountain regions. This paper presents a detailed hydrogeological and hydrogeochemical characterization of the Nif Mountain karstic aquifer system in western Turkey, an important recharge source for the densely populated surrounding area. Based on the geological and hydrogeological studies, four major aquifers were identified in the study area including the allochthonous limestone in Bornova flysch, conglomerate-sandstone and clayey-limestone in Neogene series, and the Quaternary alluvium. Physicochemical characteristics of groundwater were measured in situ, and samples were collected at 59 locations comprised of springs and wells. Samples were analyzed for major ions, isotopic composition, arsenic, boron and heavy metals among other trace elements. It was found that the hydrogeological structure is complex with many springs having a wide range of discharge rates. High-discharge springs originate from allochthonous limestone units, whereas low-discharge springs are formed at the contacts with claystone and limestone units. Using stable isotope analysis data, a δ¹⁸O-deuterium relationship was obtained that lies between the Mediterranean meteoric and mean global lines. Tritium analyses showed that low-discharge springs originating from contact zones had longer circulation times compared to the high-discharge karstic springs. Furthermore, hydrogeochemical data revealed that groundwater quality significantly deteriorated as water moved from the mountain to the plains. Heavy metal, arsenic and boron concentrations were generally within drinking-water quality standards with a few exceptions occurring in residential and industrial areas located at the foothills of the mountain. Elevated arsenic concentrations were related to local geologic formations, which are likely to contain oxidized sulfite minerals in claystones. It is concluded that Nif Mountain overall has a significant potential to provide high-quality water with a safe yield of at least 50 million m³/year, which corresponds to about 28% of the mean annual inflow to the Tahtali reservoir, a major water resource for the city of Izmir. An erratum to this article can be found at     

Determining the groundwater potential recharge zone and karst springs catchment area: Saldoran region,western Iran

Assessing the groundwater recharge potential zone and differentiation of the spring catchment area are extremely important to effective management of groundwater systems and protection of water quality. The study area is located in the Saldoran karstic region, western Iran. It is characterized by a high rate of precipitation and recharge via highly permeable fractured karstic formations. Pire-Ghar, Sarabe-Babaheydar and Baghe-rostam are three major karstic springs which drain the Saldoran anticline. The mean discharge rate and electrical conductivity values for these springs were 3, 1.9 and 0.98 m³/s, and 475, 438 and 347 μS/cm, respectively. Geology, hydrogeology and geographical information system (GIS) methods were used to define the catchment areas of the major karstic springs and to map recharge zones in the Saldoran anticline. Seven major influencing factors on groundwater recharge rates (lithology, slope value and aspect, drainage, precipitation, fracture density and karstic domains) were integrated using GIS. Geology maps and field verification were used to determine the weights of factors. The final map was produced to reveal major zones of recharge potential. More than 80 % of the study area is terrain that has a recharge rate of 55–70 % (average 63 %). Evaluating the water budget of Saldoran Mountain showed that the total volume of karst water emerging from the Saldoran karst springs is equal to the total annual recharge on the anticline. Therefore, based on the geological and hydrogeological investigations, the catchment area of the mentioned karst springs includes the whole Saldoran anticline.     

The contribution of marine magnetics in the Gulf of Saint-Malo (Brittany,France) to the understanding of the geology of the North Armorican Cadomian belt

Marine magnetic data extracted from the geophysical database of the SHOM (the French Hydrographic and Oceanographic Service) offer a first overview of the magnetic offshore environment in the Gulf of Saint-Malo (Brittany, France). Their cross-interpretation with available geological and geophysical knowledge provides a new land and sea model of the western part of the Late Proterozoic North Armorican Cadomian belt. In particular, marine data exhibit relatively intense and heterogeneous magnetic signatures, mainly interpreted as the offshore prolongation of plutonic, volcanic, and metamorphic geologic formations recognized onshore. Imprints of major faults well known on land can be inferred at sea from discontinuities and shifting of magnetic anomalies or followed by high-resolution bathymetry. An impressive and dense dolerite dyke swarm propagated on more than 50 km from the coast seaward. Dykes are characterized by both 1-km-deep and less than 50-m-deep superficial magnetic responses, suggesting the existence of deeply rooted super dykes to which individual small-scale structures are connected.     

Hydrogeology of karst aquifer systems in SW Turkey and an assessment of water quality and contamination problems

The aim of this research is to determine the relationship between groundwater flow and water quality of different ground and surface water basins in the southwest Turkey. In addition, groundwater vulnerability is assessed taking into consideration groundwater flow and quality. The autochthonous Beydaglari limestone is the major karstic aquifer in the region. According to the groundwater level map of alluvium aquifers in the basins, groundwater discharge toward the carbonate aquifer is direct and indirect. The hydrogeological connection between ground and surface water basins occurs via the karstic aquifer located at the bottom of the alluvium bottom. In Egirdir lake, water also discharges in the karstic aquifer via karstic sinkholes at the western border of the lake. In the research area, general groundwater discharge is toward the Mediterranean Sea by means of autochthonous carbonate system, according to hydrogeological investigations, research of lineament and hydraulic conductivities. This result is supported by the locations of lineaments and shore springs discharging from the limestone. In addition, spreading of contaminants via karstic aquifer to great distance has been clearly identified.     

Monthly karstic spring flow forecasting using a sequential gaussian simulation technique

Analyzing groundwater hydrologic equations related to karstic aquifers and spring hydrograph simulation have become the focus of many researches. Having double or triple porosity structure, mixed flow nature, and varying conduit permeability have made these formations become complex heterogenic systems with great temporal and spatial hydrodynamic variability. In this paper, a conditional sequential gaussian simulation (SGS) is used to simulate monthly flow data of five karstic springs with different hydrogeological properties, located in Zagros Mountain Chain, in western Iran. To evaluate the performance of the SGS algorithm, the results are compared with those of an autoregressive integrated moving average (ARIMA) model. The results demonstrate the efficiency of the SGS model in simulation of monthly flows compared to the ARIMA model. They also show the suitability of this model for handling uncertainty associated with karstic spring flows through generation of several equally probable stochastic realizations.     

Water balance and water quality in the Çürüksu basin, western Turkey

The purpose of this study is to determine the hydrological properties, groundwater potential, and water quality of the Çürüksu basin, western Turkey, and to contribute to the efforts of providing an adequate water supply for the city of Denizli. To achieve these objectives, the study consisted of mapping the geology and hydrogeology, determining the water balance, and defining the water quality. The basement rock units in the study area include several impervious metamorphic rock types and Mesozoic karstic limestone, which are overlain by Oligocene fluvial and lacustrine strata, Pliocene travertine and limestone, and Quaternary alluvium. The karstic limestone and the travertine and limestone strata constitute potential aquifers in the Çürüksu basin. The discharge regimes of the 22 springs in the two basins show little change through the year. The flow systems of the springs also have a large storage capacity and drainage occurs very slowly. The discharge of the springs does not appear to be affected immediately by monthly variations in precipitation. According to the water balance, the precipitation in the Çürüksu basin cannot provide all of the measured surface runoff. Excess runoff is 2?m3?s–1 in the Çürüksu basin, and in the adjacent Gökp?nar basin the deficit in surface runoff is also 2?m3?s–1. Thus, the underground catchment area of the springs extends beyond the surface drainage area of the Çürüksu basin. Although the P?narba??, Kazanp?nar, and Böceli springs emerge from the karstic limestone aquifer in the Çürüksu basin, these springs are fed from the adjacent Gökp?nar basin. The spring waters emerging from karstic limestone are fresh, of the calcium bicarbonate type, soft, and potable. The spring waters emerging from the travertine and limestone aquifer are low-temperature, brackish, of the calcium sulfate type, very hard, and not potable but useful for the irrigation. The occurrences of coal strata and hydrothermal activity have caused some deterioration of groundwater quality.     

Influence of sea level rise on iron diagenesis in an east Florida subterranean estuary

Subterranean estuary occupies the transition zone between hypoxic fresh groundwater and oxic seawater, and between terrestrial and marine sediment deposits. Consequently, we hypothesize, in a subterranean estuary, biogeochemical reactions of Fe respond to submarine groundwater discharge (SGD) and sea level rise. Porewater and sediment samples were collected across a 30-m wide freshwater discharge zone of the Indian River Lagoon (Florida, USA) subterranean estuary, and at a site 250 m offshore. Porewater Fe concentrations range from 0.5 μM at the shoreline and 250 m offshore to about 286 μM at the freshwater-saltwater boundary. Sediment sulfur and porewater sulfide maxima occur in near-surface OC-rich black sediments of marine origin, and dissolved Fe maxima occur in underlying OC-poor orange sediments of terrestrial origin. Freshwater SGD flow rates decrease offshore from around 1 to 0.1 cm/day, while bioirrigation exchange deepens with distance from about 10 cm at the shoreline to about 40 cm at the freshwater-saltwater boundary. DOC concentrations increase from around 75 μM at the shoreline to as much as 700 μM at the freshwater-saltwater boundary as a result of labile marine carbon inputs from marine SGD. This labile DOC reduces Fe-oxides, which in conjunction with slow discharge of SGD at the boundary, allows dissolved Fe to accumulate. Upward advection of fresh SGD carries dissolved Fe from the Fe-oxide reduction zone to the sulfate reduction zone, where dissolved Fe precipitates as Fe-sulfides. Saturation models of Fe-sulfides indicate some fractions of these Fe-sulfides get dissolved near the sediment-water interface, where bioirrigation exchanges oxic surface water. The estimated dissolved Fe flux is approximately 0.84 μM Fe/day per meter of shoreline to lagoon surface waters. Accelerated sea level rise predictions are thus likely to increase the Fe flux to surface waters and local primary productivity, particularly along coastlines where groundwater discharges through sediments.     

贵州五指山铅锌矿田深部找矿远景分析

贵州五指山铅锌矿田发育北东向、北东东向和北西向断层,分别平行于区域性安顺-贵阳、纳雍-息烽及水城-紫云深大断裂,控制了寒武纪-泥盆纪时期的沉积相和石炭纪前的地层剥蚀程度,以及沉积盆地中成矿流体活动。矿田中的那雍枝矿床的矿体产状、矿石结构构造、围岩蚀变及元素地球化学特征,反映其具有海底喷流沉积矿床成因。矿田深部地球物理场显示,矿田及附近存在北东向、北西向和东西向深大断裂,在几组断裂交汇处及附近的深部存在岩浆岩体及大型岩基,具备深部流体上升的条件。推测那润断层北盘那雍枝矿床深部灯影组内,F9、F10与F1断层相交,灯影组和清虚洞组层位及对应的物化探异常变异区的深部应存在大型层状铅锌矿体,具有超大型铅锌矿床的找矿前景。     

Numerical investigation of groundwater outbursts near faults in underground coal mines

Permeable geologic faults in the coal seam can cause intermittent production problems or unexpected amounts of groundwater outburst from the underlying aquifers. With the acknowledgment of the basic mechanism for groundwater outbursts, the groundwater outburst along the fault zones in coal mines are numerically investigated using RFPA, a numerical code based on FEM. The fracture initiation, propagation, and coalescence in the stressed strata and the seepage field evolution in the stress field are represented visually during the whole process of groundwater outburst. The numerically obtained damage evolution shows that the floor strata could be classified as three zones, i.e. mining induced fracture zone, intact zone and fault reactivation zone, in which the intact zone is the key part for resisting groundwater outburst and directly determines the effective thickness of water-resisting rock layer. With understanding of the evolution of stress field and seepage flow in floor strata, the groundwater outburst pathway is calibrated and the transformation of floor rock mass from water-resisting strata to outburst pathway is clearly illuminated. Moreover, it is shown that geometrical configuration, including inclination angle of faults and seam drop along faults, have an important influence on groundwater outburst. Finally, based on geological, hydrogeology survey and numerical results, the mechanism analysis of groundwater outburst in an engineering case is studied, which can provide significantly meaningful guides for the investigation on mechanism and prevention of groundwater outburst induced by faults in practice.     

Construction of grout curtain in karstic environment case study: Salman Farsi Dam

Salman Farsi is an arch-gravity dam. It is 125 m high and located on the Ghareh-Agaj River in Fars province, south of Iran. From the geological and hydrogeological point of view, this dam is one of the most complicated sites in Iran. Existence of 40 springs at the river level (including hot springs), and many faults and crushed zones are part of these complications. The dam site is famous for its numerous big caverns. Main characteristics of the rock mass are: (1) low permeable limestone of moderate to high strength, (2) high karstification generally localized around intersection of faults or discontinuities. The main purpose of grout curtains is to change the hydrogeological characteristics (reducing the permeability) of the rock mass. Constructing a grout curtain in a karstic environment with a high random distribution of karst features contains some uncertainties and surprises cannot be excluded. During the excavation of grouting galleries, some big caverns at both abutments were discovered. The volume of the biggest one (Golshan’s Cave) exceeds 150,000 m³. A large-scale underground geotechnical treatment is needed to improve the water tightness of the dam site.     

Use of recession-curve analysis for estimation of karstification degree and its application in assessing overflow/underflow conditions in closely spaced karstic springs

In the southern part of the Slovensky Kras Mountains, located on the Hungarian–Slovakian border, a transboundary karstic aquifer Dolny vrch/Alsóhegy underlies the structure and discharges groundwater flow to 15 major karst springs around its margin. Hydrograph recession curves from nine-gauged springs on the Slovak part of the aquifer were analysed, and for each individual spring, depletion hydrograph equations were classified into different categories based on recessional parameters quantitatively describing individual groundwater flow sub–regimes. Discharge depletion was used to create recessional equations, and these were linked to karstification degree, a qualitative scale ranging from 1 to 10. A new application of hydrograph separation was based on examining and combining pairs of springs that likely fit into the category of overflow/underflow springs for a single groundwater reservoir. Recession-curve analysis performed on coupled discharges of two pairs of neighbouring springs was conducted to examine their possible linkage as a single groundwater reservoir, with an overflow outlet and underflow outlet. In the process of discharge coupling, discharges of the springs, hypothesized to be branches of the same source and observed at the same time were simply added together. By analyzing the resulting new time series, a new classification of sub-regimes could be generated. Surprisingly, new facts were revealed about the overflow/underflow springs, which primarily were not recognized previously as being connected components of a single groundwater reservoir. Summations of combined overflow/underflow discharge volumes of a single spring reservoir led to discovery of apparent presence of turbulent flow sub-regimes on the coupled recession curve. Presence of possible overflow/underflow springs of a single groundwater basin should be considered during hydrograph analyses if the springs have attributes that suggest they may be part of a combined flow system. Treating these springs as separate entities as a result can produce significant misinterpretation of drainage parameters. Furthermore, identification of overflow branches facilitates the generation of new research ideas for further speleological investigations nearby, and for assessing the system in a more effective manner.     

Identifying environmental impacts of underground construction

Dewatering of the groundwater resource and associated reduced flow of surface water features are potential negative impacts when constructing underground facilities. Little work has been done to develop methods for the early detection of environmental impacts on water resources where major underground construction is being undertaken. Recognizing this, prior to construction of two rock tunnels in the southwestern USA, a 3-year preconstruction program was implemented to monitor over 100 wells, springs, and streams in the project area that might be affected. This preconstruction monitoring phase has established data for a hydrologic reference which indicates a high degree of spatial and temporal variability. This variability must be accounted for when trying to identify construction-related impacts. The project area was subdivided into areas of similar characteristics based on geologic and hydrologic features. Measurements from features within each unit were then normalized and aggregated to derive a single representative flow parameter. This representative flow was then correlated to precipitation and major stream flow records to allow for a method of estimating unimpacted flow and groundwater levels during and after construction. Application of this method proved useful in determining and enabling a quick response to construction-related impacts.     

Water–gas dynamics and coastal land subsidence over Chioggia Mare field, northern Adriatic Sea

A major development programme comprising 15 gas fields of the northern Adriatic Sea has recently been submitted to the Ministry of the Environment, VIA Committee for the assessment of the environmental impact, by ENI-Agip, the Italian national oil company. One of the largest reservoirs is Chioggia Mare, located about 10 km offshore of the Venetian littoral, with a burial depth of 1000–1400 m. The planned gas production from this field is expected to impact the shoreline stability with a potential threat to the city of Venice, 25 km northwest of the center of Chioggia Mare. To evaluate the risk of anthropogenic land subsidence due to gas withdrawal, a numerical model was developed that predicts the compaction of both the gas-bearing formations and the lateral/bottom aquifer (water drive) during a 13-year producing and a 12-year post-production period, and the transference of the deep compaction to the ground surface. To address the uncertainty of a few important hydromechanical parameters, several scenarios are simulated and the most pessimistic predictions obtained. The modeling results show that at most 1 cm of land subsidence over 25 years may be expected at the city of Chioggia, whereas Venice is not subject to settlement. If aquifer drawdown is mediated by water injection, land subsidence is arrested 5 km offshore, with the Chioggia littoral zone experiencing a rebound of 0.6–0.7 cm. Electronic Publication     

The groundwater discharge in the Mediterranean karst coastal zones and freshwater tapping: set problems and adopted solutions. Case studies

In the karstic regions of the Mediterranean coastal zones the groundwater discharge and its outcrops—the coastal and submarine springs—represent the most typical natural phenomena of littoral karst, the economic potential of which is significant. The case studies discussed in this paper concern the problems of freshwater tapping in karst coastal zones along the Mediterranean littoral. Owing to the geological and hydrogeological approach, the set problems and adopted solutions involve two most important tasks: (1) the regulation of groundwater flow in the tapping facilities and (2) the control system of saltwater encroachment in a larger protection zone, between the coast and the site of tapping facilities.     

河南省主要煤矿区岩溶地下水系统划分

根据地质构造、地形地貌、地层结构与埋藏特征及补径排条件等条件,划分了河南省主要煤矿区的岩溶水系统。对地下水的补径排及水化学特征进行了分类,分析了不同岩溶地下水水系统特征对矿区水害的影响。研究结果可为河南省煤矿开采中存在的水害隐患及其防治提供科学依据。     

Temporal variability of freshwater and pore water recirculation components of submarine groundwater discharges at Baffin Bay,Texas

Submarine groundwater discharges (SGDs) are an important source of freshwater as well as nutrients and other chemicals to bays and estuaries. SGDs are particularly important for coastal bodies in arid and semi-arid regions that are not fed by perennial streams. The Baffin Bay, TX is a shallow coastal water body that is weakly connected to the Gulf of Mexico and has no major rivers or streams draining into it. A year-long submarine groundwater discharge measurement study was carried out at the Loyola Beach of the Baffin Bay during the months of July 2005–June 2006. A total of 23 synoptic SGD sampling events were carried out with most events collecting SGD data continuously over a period of 24 h at a 1-min temporal resolution using an ultrasonic seepage meter. The median SGD was noted to be 3.83 cm/d with an inter-quartile range (IQR) of 11.36 cm/d. Four sampling events had anomalously high SGD values (~27–48 cm/d) which are hypothesized to be due to the geologic heterogeneity of the sea bed and meteorological effects. Eight of the 23 sampling events had a negative average SGD flux indicating landward flow. The short-term diurnal variability of SGD was comparable or sometimes higher than the longer-term and between-events variability. No long-term trend could be inferred. In the short-term, SGD measurements showed considerable persistence and the effective sample size analysis indicated each sampling event (consisting of over 1,000 samples) yielded only a handful of statistically independent measurements of SGD. The measured SGD values exhibited both negative (hydraulically controlled) and positive (wave set-up controlled) correlations with the bay water levels. Marine controls appeared to be the most significant SGD drivers and are in turn controlled by prevailing aeolian forcings. The salinity of the SGDs were estimated from measured sonic velocities and used in conjunction with the end-member mixing models to estimate fresh (meteoric) and re-circulated pore-water fractions. The freshwater fraction of the SGD was estimated to vary between nearly 4 and 89 % with a median value of 9.96 % and an IQR of 7.16 %. Three events were noted to have abnormally high freshwater fractions (~28, 50 and 84 %) which are likely artifacts caused by bay water freshening from rainfall and plausible thermal expansion. The meteoric and pore-water partitioning was sensitive to the assumed end-member concentrations. This study provides preliminary estimates for SGDs along the South Texas coast line and is useful for calibrating groundwater flow models and understanding the relative importance of terrestrial and marine controls on SGD. However, the heterogeneous nature of the sedimentary geology of the Texas Gulf Coast implies the SGD fluxes are likely to exhibit considerable spatial variation that has not been characterized yet. Therefore, the study provides useful insights for such future data collection and monitoring activities. The measured SGD values at Baffin Bay, TX are comparable to those reported at other parts of the Gulf of Mexico.     

The mineral springs of the Scrajo spa (Sorrento peninsula,Italy): a case of “natural” seawater intrusion

This paper deals with the mineral springs feeding the Scrajo spa in the Sorrento peninsula southeast of Naples, approximately 6 km from Castellammare di Stabia, another spa location. The Scrajo mineral water is sulphureous, salt-bromine-iodic and CO₂-rich. The two hydromineral areas fall within the groundwater basin of Mt. Faito formed chiefly by limestones. Due to the high permeability of the limestones, there is considerable rainwater infiltration which recharges a basal fresh groundwater resting on denser seawater. This groundwater body feeds the mineral springs of the Scrajo spa, the springs of Castellammare di Stabia and some submarine springs. All the data gathered for the Scrajo springs led to propose the following mineralisation scheme: (1) The basal fresh groundwater of Mt. Faito (on underlying seawater) receives endogenous contributions of CO₂ and H₂S which cause a “natural” seawater intrusion within the fresh groundwater; (2) The upwelling of gases would appear to occur via the major faults which bound Sorrento peninsula to the NW; (3) During the year, the chemistry of the springs changes according to different degrees of seawater intrusion: the minimum occurs in June and the maximum in November. The close interaction between the sea and the Scrajo’s mineral waters (but also those of Castellammare di Stabia) highlights their particular vulnerability not only to over-extraction of groundwater but also to climate change. Finally, a hypothesis is presented to explain the connection between the mineral waters rich in CO₂ and H₂S and the concentration of karst phenomena observed in the Scrajo area.