滇西勐兴铅锌矿床热液方解石碳氧同位素组成及其意义

勐兴铅锌矿床是保山地块内浅成热液铅锌矿床中极具代表性的矿床,但有关成矿流体来源及演化方面的研究较为薄弱.因方解石与矿化关系密切,故对其C、O同位素组成进行了水岩反应、CO2去气、流体混合作用的理论模拟.结果表明,该矿床方解石的形成主要是由于水岩反应引起的,成矿流体可能来自赋矿地层中富含H2CO3的流体,其中阶段Ⅰ和阶段Ⅱ初始流体的δ13C、δ18O值分别为1.0‰和10.5‰、-0.8‰和7.5‰,方解石的形成温度分别集中于270～315℃和182～230℃之间,δ13C和518O值的降低表明在阶段Ⅱ成矿流体与围岩反应之前己经发生了CO2热液去气作用.     

桂东南志留纪热水沉积成矿的碳氧同位素证据

志留系地层是桂东南博白―岑溪地区铅锌矿床的主要赋矿层位,产出佛子冲和东桃等层状铅锌矿床,其直接赋矿围岩均为下志留统碎屑岩地层中的层状绿色岩和碳酸盐岩夹层。碳、氧同位素测试结果显示,赋矿层位中碳酸盐岩夹层的δ18 O值显著低于正常海相灰岩,在δ18 O-δ13 C图解上碳酸盐岩夹层和矿石中方解石样品投点均集中分布在基性-超基性岩浆岩和花岗岩区及附近。该碳酸盐岩夹层的形成与海底热水沉积作用有关,类似于现代海底烟囱中的低温喷口产物。桂东南志留纪热水沉积成矿作用可以概括为电解成矿机制。     

桂中镇圩碳酸盐岩型滑石矿床热液方解石的锶同位素研究

我国华南石炭系含硅质岩、硅质条带和结核的白云岩地层之中产有一种独特的碳酸盐岩型滑石矿床。该类滑石成矿作用与岩浆活动及变质作用无明显的成因联系;矿体均受向斜构造的控制;矿石质量较好,矿物组成除了滑石以外,仅有少量的方解石。其中,桂中镇圩滑石矿床的经济价值最为重要,其储量达2167万吨。为了查明其成因,笔者对该矿床中与滑石共生的方解石进行了锶同位素地球化学研究。研究结果表明,方解石的Rb含量极低,平均值低于0.10×10–6;Sr含量较高,平均为135.74×10–6,Rb/Sr值小于0.0013,因而,其锶同位素组成可以代表矿化时成矿流体的锶同位素组成。其次,方解石的锶同位素组成较为均一,其87Sr/86Sr值介于0.708220~0.708911之间,平均值为0.708511。对比研究发现,该矿床中方解石的锶同位素组成明显低于盆地卤水和同期岩浆岩,略高于含矿碳酸盐岩、同期海水和海底热液的锶同位素组成,与以碳酸盐岩为主的喀斯特地区的河水、岩溶水和石笋的锶同位素组成较为相似。结合矿床地质特征,笔者认为镇圩滑石矿床的成矿流体很可能为大气降水,属于古岩溶交代成因,这与华南中-晚三叠世逐步隆升为海陆交互相和陆相的地质事实也相吻合。因此,华南早在中-晚三叠世就已经开始喀斯特作用的发育。     

湖北徐家山锑矿床方解石C、O、Sr同位素地球化学

湖北通山的徐家山锑矿床产在上震旦统陡山沱组和灯影组的海相碳酸盐岩中.对该矿床中成矿前和成矿期方解石进行了较系统的C、O、Sr同位素地球化学研究,结果表明,成矿前方解石具相对较高的δ13CPDB(-0.7‰～ 2.0‰)、δ18OSMOW( 18.6‰～ 19.6‰)和Sr含量(2645-8174 μg/g,平均5656μg/g),及较低的87Sr/86Sr比值(0.7096～0.7097);而成矿期方解石具相对较低的δ13CPDB(-3.9‰～-2.1‰)、δ18OSMOW( 11.5‰～ 15.3‰)、Sr含量(785～2563μg/g,平均1571μg/g),和较高的87Sr/86Sr比值(O.7109～0.7154,平均0.7141).分析认为,成矿前方解石的C、O和绝大部分Sr来源于赋矿围岩--震旦系海相碳酸盐岩;而成矿流体为富H2CO3的溶液,它来自或流经富放射成因87Sr的下伏基底碎屑岩--中元古界冷家溪群浅变质岩;该流体与围岩发生水.岩反应导致成矿期方解石和辉锑矿的沉淀.     

Carbon and oxygen isotopes in epigenetic hydrothermal rocks from Hamam-el-Farun,Sinai

Rock samples from an Eocene cliff above the thermal spring of Hamam-el-Farun (west coast of Sinai) show various degrees of dolomitization and calcitization ${}^{18}\text{O}{}^{16}\text{O}$ and ${}^{13}\text{C}{}^{12}\text{C}$ ratios indicate that dolomite and secondary calcite precipitated from hot brines.     

陆生蜗牛壳体碳氧同位素组成与气候

陆生蜗牛响应气候环境变化敏感,其壳体化石碳氧同位素组成（δ¹³C和δ¹⁸O）具有重建古生态和古大气水文条件的巨大潜力。然而目前针对中国黄土古土壤沉积序列中蜗牛化石碳氧同位素组成开展的古环境古气候重建研究却仍然不足,根源在于对蜗牛壳体δ¹³C和δ¹⁸O指标气候意义的认识仍不明确。文章从现代过程研究着手,综述了目前有关蜗牛壳体δ¹³C和δ¹⁸O气候环境意义的研究进展,并指出各自指标存在受控因子的复杂性和多解性等问题。通过总结这些研究认为：陆生蜗牛壳体δ¹³C值主要通过反映植物（尤其C₃）δ¹³C值变化来进一步响应当地降水量变化,进而指示环境的干湿程度,但同时需要考虑环境碳酸盐、大气CO₂等额外因子对壳体δ¹³C的影响;壳体δ¹⁸O值可以在较大程度上反映大气降水δ¹⁸O值变化,但同时需要考虑蒸发作用和温度等因素对壳体δ¹⁸O的影响;壳体δ¹³C和δ¹⁸O在作为气候指标时常受区域和蜗牛种属等因素影响。此外,还介绍了目前中国北方黄土地层中蜗牛壳体化石稳定同位素组成重建季风变化的研究进展和近十年来有关蜗牛壳体团簇同位素新方法的研究进展。最后,论文针对壳体δ¹³C和δ¹⁸O指标存在的问题提出可能的解决办法,并对以后蜗牛碳氧同位素古环境研究方向进行展望。

     

湖南香花岭锡多金属矿床C、O、Sr同位素地球化学

对湖南香花岭锡多金属矿床成矿早、晚两期方解石进行了系统的C、O、Sr同位素研究。结果表明,成矿早期方解石具有相对较低的δ13CPDB（-5.4‰ ~ -1.4‰）、δ18OSMOW（+6.1‰ ~ +13.9‰）和较高的87Sr/86Sr值（0.7101 ~ 0.7230）;而成矿晚期方解石则具有相对较高的δ13CPDB（+0.2‰ ~ +0.6‰）、δ18OSMOW（+19.4‰ ~ +21.5‰）和较低的87Sr/86Sr值（0.7101）。成矿早期方解石为岩浆热液与海相碳酸盐岩相互作用的产物,成矿流体中的碳源于岩浆碳和海相碳酸盐岩;模拟计算结果显示,成矿早期方解石为成矿溶液发生0.05-0.1摩尔分数的 CO2去气作用的产物。而成矿晚期方解石主要为矿区碳酸盐岩围岩低温淋滤的产物,流体中的碳主要源于矿区碳酸盐岩围岩。成矿流体中Sr源于矿区花岗岩和碳酸盐岩,从成矿早期到晚期,岩浆来源的Sr逐渐减少,而碳酸盐岩围岩提供的Sr比例不断增大。     

贵州龙动物群产出层位碳氧同位素研究

贵州龙动物群是二叠-三叠纪大绝灭后海洋生态系统辐射发展阶段最晚期的典型代表,为了解其古环境信息,对贵州省兴义地区顶效及周边产地开展了精细剖面测量,采集碳酸盐岩进行了全岩碳氧同位素测试。测试结果显示：泥麦谷剖面δ¹³C值分布范围-6.3‰~2.6‰,δ¹⁸O分布范围在-5.7‰~-1.2‰;谢米剖面δ¹³C值分布范围在-4.5‰~2.5‰,δ¹⁸O在-5.7‰~-1.2‰;坝尾剖面δ¹³C值分布范围在0.5‰~2‰,δ¹⁸O在-6.4‰~0.1‰;顶效剖面δ¹³C值分布范围在-4.3‰~2.1‰,δ¹⁸O在-7.3‰~-2.5‰。根据碳氧同位素数据相关性分析显示泥麦谷、谢米、坝尾剖面的同位素值受后期成岩作用影响较小。在泥麦谷、谢米及顶效贵州龙动物群产出层位下段均出现明显的δ¹³C负异常,与低水位时期海洋生物快速死亡密切相关,也与火山作用存在一定的联系。由于顶效剖面受后期成岩作用影响,笔者利用泥麦谷、谢米及坝尾剖面δ¹⁸O数据对兴义地区古海水温度进行了恢复,结果显示温度分布在19~27℃,平均为23℃左右,说明当时属于温暖气候环境。     

Carbon and oxygen isotopic composition of Jurassic foraminifers in the Unzha River basin

Study of the carbon and oxygen isotopic composition of the foraminifera shells of different species from the Callovian-Oxfordian undershale rocks in the Unzha River basin near the town of Makar’ev (Central Volga region) has shown that the δ¹⁸O values of the epistomina shells correspond to relatively low temperatures and their δ¹³C values indicate the high productivity of the basin in this period. The Lenticulina tumida shells register low δ¹³C and δ¹⁸O values, which probably reflect the biological effect of fractionation during their formation. The Jurassic lagenids (Lenticulina tumida and Citharina chanika) were characterized by a wider habitat areal or ecological niche. We established the importance of isotopic studies of foraminifers of the same genus, and even better of the same species. Most likely, the foraminifera shells may be applied for study of Mesozoic sedimentation conditions.     

Carbon and hydrogen isotopic compositions of algae and bacteria from hydrothermal environments,Yellowstone National Park

Stromatolites forming today on a small scale in hydrothermal environments are chemical and biological analogues of much larger Precambrian formations. Carbon isotopic composition varied as a function of CO₂ concentration, pH, and species composition. Stratiform, layered stromatolites grew in silica-depositing springs at 55° to 70°C; they consisted mainly of a unicellular alga, Synechococcus, and a filamentous, photosynthetic bacterium, Chloroflexus. These thermophiles become enriched in ¹²C as the concentration of carbon dioxide in the effluent waters increases. At a concentration of 40 ppm total inorganic C, and δ¹³C of organic carbon was ～ ?12%., whereas at 900 ppm total inorganic C, the δ¹³C of similar species was ～ ?25%.. Conical stromatolites or conophytons (principally a filamentous, blue-green alga Phormidium and Chloroflexus) grew at 40°-55°C. In older, broader conophytons, Chloroflexus was the dominant organism. Their δ¹³C values were ～ ?18%. in a variety of hot springs. In carbonate-depositing springs, i.e., carbon dioxide saturated, conophytons and stromatolites consisting of a variety of blue-green algae and photosynthetic bacteria had the most negative δ¹³C values (to ?30%.). These carbon isotope ratios are directly comparable to carbon isotope ratios of kerogen from Precambrian stromatolites. The presence and activity of methanogenic bacteria or heterotrophic, aerobic and anaerobic bacteria did not alter significantly the δ¹³C of the original organic matter.The hydrogen isotopic fractionation between thermophilic organisms and water is 0 to ?74 for temperatures of 85° to 46°C, respectively. Acidophilic algae fractionated hydrogen isotopes to a lesser extent than did the photosynthetic organisms inhabiting neutral pH springs. Because organic matter retains some of its original isotopic signature, relationships of CO₂ levels, pH, temperature, and species composition between modern stromatolites and their environment and those of the Precambrian can be inferred.     

华北克拉通几个地区古元古代碳酸盐岩地层C-O同位素特征

对华北克拉通古元古代辽河群、中条群和湾子群的碳酸盐岩进行了C、O同位素研究。辽河群王家沟组条带状大理岩的δ13CPDB变化于-1.02‰~3.14‰之间,大部分在0.16‰~1.79‰之间,平均值为1.07‰,稍高于海相碳酸盐岩的δ13C平均值0.5‰,δ18OPDB变化于-17.2‰~-10.1‰之间,大部分在-13.4‰~-10.1‰之间,20组数据的均值为-11.9‰。中条群余家山组大理岩的δ13CPDB变化于-0.2‰~0.8‰之间,大部分在0~0.3‰之间,前14个样品的δ13C平均值为0.34‰,稍低于海相碳酸盐岩的δ13C平均值,后16个样品的δ13C平均值为0.54‰,与海相碳酸盐岩的δ13C平均值基本一致,其δ18OPDB变化于-7.9‰~-6.1‰之间,大部分在-7.3‰~-6.1‰之间,前14个样品的δ18O平均值为-6.80‰,后16个样品的δ18O平均值为-6.68‰,两个剖面上的δ18O值没有明显差别。阜平宋家口南湾子群大理岩δ13CPDB变化于1.0‰~3.8‰之间,平均值为2.65‰,明显高于海相碳酸盐岩的δ13C平均值0.5‰,其δ18OPDB变化于-8.8‰~-5.7‰之间,平均值为-6.97‰。研究结果表明所研究的大理岩均形成于一个比较稳定而又相对波动的气候环境,大理岩沉积期间存在海平面和气温旋回变化但没有突变事件。湾子群宋家口剖面大理岩对Jatulian事件有响应,中条群余家山组大理岩对Jatulian事件没有响应,辽河群王家沟组是否存在对Jatulian事件响应还不确切。     

Carbon and oxygen isotopic composition of the Vendian-Cambrian carbonate rocks and paleoecological reconstructions

The carbon isotopic composition of carbonate rocks is widely used for the reconstruction of sedimentation paleoenvironment. Of special interest is the study of the Upper Proterozoic-Cambrian interval—the turning point in the Earth’s geological evolution. Rocks of this age show the widest variations in the carbon isotopic composition of carbonates typically correlated with epochs of global glaciations and change in the CO₂ regime. In this paper, we attempted to show that carbon isotopic variations often indicate postsedimentary alterations of carbonates and reflect the specific geochemical transformations of the rocks. Study of variations of carbon and oxygen isotopic compositions in the Vendian-Cambrian rocks provide insight into lithogenetic processes.     

湖南柿竹园矿田柴山铅锌矿床的C、O同位素组成及其研究意义

研究了柿竹园矿田柴山铅锌矿床早、晚期方解石的C、O同位素组成,并对C、O同位素组成之间明显的正相关关系进行了CO2去气、流体混合与水．岩反应的理论模拟。结果表明,该矿床方解石的形成主要是由成矿流体与围岩发生水-岩反应及温度降低造成的,另外大气降水的加入也起到一定的作用。成矿流体中的可溶性碳以H2CO3为主,早期成矿流体的δ^13C、δ^18O值分别为-2．5‰＋4‰,晚期成矿流体的δ^13C、δ^18O值分别为-1‰和＋6‰,并且在成矿过程中一直有中生代大气降水的加入。     

浙江江山石炭-二叠系碳酸盐岩碳氧同位素特征研究

对浙江江山石头山剖面船山组、栖霞组碳酸盐岩进行了 C、O同位素测定. Mn/Sr比值、δ18O值和δ18O-δ13C散点图检验表明,所得同位素数据反映了碳酸盐岩的原始沉积特征.δ13C和δ18O值变化范围分别为- 5.4‰～ 4.4‰和- 12.2‰～- 5.6‰,平均值分别为 0.5‰和- 8.4‰ .在石炭纪-二叠纪分界线附近没有发生明显的同位素漂移现象.本区碳同位素地层曲线与根据沉积微相推断的海平面变化曲线十分吻合,表现为δ13C高值区海水变深.海水在剖面上的变化规律是浅-中等-较深-中等,相应的δ13C演化曲线表现为波谷段-具次级起伏的相对平缓段-波峰段-平缓段.栖霞组台坪相δ13C值大于船山组台坪相,而且曲线较平直,反映海水较深且环境较稳定.研究区地层记录中的海平面从早到晚逐渐增高,与全球海平面变化曲线不一致,可能与浙皖海盆发生过整体沉降有关.这一区域性差异也在碳同位素记录中得到印证,本区晚石炭世晚期-早二叠世早期δ13C值从老到新慢慢增大,最后再略为下降,演化趋势与 Veizer et al.的碳同位素年代演化曲线相反,说明碳同位素演化在一定程度上能反映区域地壳演变状况.     

Meteoric hydrothermal origin of calcites in “Green Tuff” formations,Miocene age,Japan

Oxygen and carbon isotope compositions were determined for calcites from the Green Tuff formations of Miocene age in Japan. Values of ¹⁸O from 24 calcites in altered rocks from 5 districts range from –2 to +16_SMOW, in most cases from 0 to +8_SMOW. The low ¹⁸O values rule out the possibility of their low-temperature origin or any significant contribution of magmatic fluid in the calcite precipitation. These values, coupled with their mineral assemblages, suggest that the calcites formed from meteoric hydrothermal solutions which caused propylitic alteration after the submarine strata became emergent.Values of ¹³C from the calcites show a wide variation from –17 to 0_PDB. Calcites from different districts have different ranges of ¹³C values, indicating that there was no homogeneous reservoir of carbon at the time the calcite formed, and that the carbon had local sources. Carbon isotopic compositions of calcite within ore deposits in the Green Tuff formations range from –19 to 0_PDB, similar to those of calcite in the altered rocks in the same district, suggesting that the carbon in ore calcites was likely supplied from the surrounding rocks through activity of meteoric hydrothermal solutions.     

The strontium and oxygen isotopic record of hydrothermal alteration of syenites from the Abu Khruq complex,Egypt

Hydrothermal convection initiated by emplacement of the gabbro-syenite complex of Abu Khruq into the Egyptian basement 89 Ma ago systematically altered the trace element and isotopic compositions of the syenites. The scale of Sr transport in migrating solutions was far larger than the scale of Sr isotopic equilibration within rocks. As a result, Sr exchange was heterogeneous in the syenites, an effect which can be observed on three different scales. Within grains of a single mineral species, heterogeneities are related to grain boundaries and microfractures through which fluids migrated. Among minerals within rock samples, heterogeneities are related to differences in susceptibility to Sr alteration. Among samples within a single unit, heterogeneous alteration is apparently related to differences in permeability close to fracture zones.During the early stages of alteration radiogenic Sr derived from the country rocks was added to the syenites, causing small net changes in concentration (5 ppm ave.). Some Rb-Sr mineral isochrons from single rock samples yield the emplacement age because isotopic equilibration of this added Sr sometimes occurred within rock specimens. However, regressions of the whole-rock Rb-Sr data yield apparent ages that are about 10 Ma too old. Later stage alteration involved larger changes in whole-rock Sr concentration (45 ppm ave.) but had little further effect on the isotopic relationships because the Sr was derived from cogenetic gabbros rather than the country rocks.Alterations of Rb, Sr, and Sr isotopic compositions are not well correlated with changes in ¹⁸O/¹⁶O ratio because mineralogy played an important role in decoupling trace element and oxygen isotopic alteration. In general, the absence of such correlations for whole-rock data is not diagnostic of rocks with unaltered trace element and isotopic compositions. Mineral-scale Sr isotopic heterogeneities associated with grain boundaries and microfractures may be the most unambiguous evidence of trace element mobility.Deceased on 9/81     

Carbon and oxygen isotopic composition of carbonates in lavas and ejectites from the Alban Hills,Italy

Carbon and oxygen isotopic analyses have been carried out on carbonates from lavas, ejectites and sedimentary formations in the region of the Alban Hills.The calcite occurring in the lavas, both in veins and cavities and dispersed in the groundmass shows within each flow a fairly uniform isotopic composition not different from that normally observed in sedimentary carbonates, except in the case of one particular flow, where unusually low ¹³C values were recorded. The latter are discussed in terms of a possible contribution of organic carbon or of isotopically light carbonates, the presence of which in the Alban Hills area had been previously recorded.The ejectites examined comprise both limestone and dolostone blocks of various degree of metamorphism and materials of uncertain origin, some of which containing carbon and oxygen of isotopic composition wholly different from that of all carbonates analysed in this work, approaching the range observed in some carbonatites. The isotopic data and the geochemical features of the latter materials are discussed in terms of thermal metamorphism of limestones and of a possible syntexis of evaporite materials.The ¹⁸O and ¹³C values of certain marine limestones from major Mesozoic sedimentary formations in the region are also reported.     

江西省兴源冲铜矿床同位素地球化学特征及成矿机制探讨

兴源冲铜矿床地处九岭南缘铜多金属大型矿集区西段的黄茅地区。文章在成矿地质特征的基础上,通过对矿石进行稳定同位素地球化学研究,重点分析了成矿物质来源,探讨了矿床成矿机制。碳、氧同位素分析结果表明,矿区碳酸盐岩δ13CVPDB为-5·4‰～1·9‰,平均为0·6‰,δ18OSMOW变化范围为9·0‰～13·9‰,平均为10·9‰,主要为海相碳酸盐岩,碳、氧同位素图解表明碳可能主要来源于深部,且受高温变质作用和低温蚀变作用明显;矿石硫化物硫同位素δ34S变化范围主要在1·0‰～6·2‰之间,个别样品同位素比值偏大,对比相似矿床,表明该矿床具有海底喷流沉积和后期岩浆热液叠加作用的特征。上述同位素地球化学特征表明,兴源冲铜矿床是在中元古代海底火山沉积基础上,经新元古代晋宁造山期岩浆热液、动力变质叠加成矿作用所形成。     

Temporal relationship between granite cooling and hydrothermal uranium mineralization at Dalongshan in China: a combined radiometric and oxygen isotopic study

A combined study using multi-radiometric dating and oxygen isotopic geothermometry was carried out for Mesozoic quartz syenite, alkali-feldspar granite and associated hydrothermal uranium mineralization at Dalongshan in the Middle-Lower Yangtze valley of east-central China. Radiometric dating of the quartz syenite yields a whole-rock Rb–Sr isochron age of 135.6±4.3 Ma, a zircon U–Pb isochron age of 132.9±2.2 Ma, and K–Ar ages of 126±2, 118±3 and 94±4 Ma for hornblende, biotite and orthoclase, respectively. The alkali-feldspar granite yields a whole-rock Rb–Sr isochron age of 117.3±3.3 Ma, a zircon U–Pb isochron age of 114.7±2.1 Ma, and K–Ar ages of 112±2, 109±3 and 88±4 Ma for hornblende, biotite and orthoclase, respectively. Oxygen isotope thermometry for both granites gives temperatures of 685 to 720, 555 to 580, 435 to 460 and 320 to 330 °C, for hornblende, magnetite, biotite and orthoclase respectively, when paired with quartz. The systematic differences among the ages by the different techniques on the different minerals are used to reconstruct the cooling history of the granite. The results yield rapid cooling rates of 27.4 to 58.6 °C/Ma from 800 to 300 °C in the early stage, but slow cooling rates of 6.3 to 7.2 °C/Ma from 300 to 150 °C in the late stage. The regular sequence of oxygen isotope temperatures for the different quartz–mineral pairs demonstrates that diffusion is a dominant factor controlling the closure of both radiometric and O isotopic systems during granite cooling. Pitchblende U–Pb isochron dating yields an uranium mineralization age of 106.4±2.9 Ma, which is younger than the age of the granite emplacement and thus considerably postdates the time of magma crystallization, but is close to the closure time of the K–Ar system in the biotite. This points to a close relationship between granite cooling and ore-forming process. It appears that hydrothermal mineralization took place in the stage of slow cooling of the granite, whereas the rapid cooling of the granite was concurrent with the migration of hydrothermal fluids along fault structures. Therefore, the activity of the ore-forming hydrothermal system is temporally dictated by the cooling rates of the granite and may lag about 25 to 30 Ma behind the crystallization timing of associated granite.     

川西甘孜－理塘结合带碳酸盐岩碳氧同位素特征

本文对甘孜-理塘结合带中段出露的碳酸盐岩进行了详细的野外地质调查,按其产状可分为两类:覆于玄武岩之上的碳酸盐岩构造岩片和包裹于玄武岩内的厘米-米级不规则棱角状碳酸盐岩砾岩块。经碳酸盐岩碳、氧同位素测试分析,前者δ¹³C值主体位于0.113‰~1.625‰之间,δ¹⁸O数值为-10.263‰~-5.745‰,总体变化较小,有小幅震荡;而后者δ¹³C值明显较前者大,为4.254‰~3.786‰,δ¹⁸O数值则明显偏小,为-13.471‰~-13.592‰,总体变化量较前者更小,具明显的后期成岩作用改造特征。所有样品Z值均大于123,表明研究区内碳酸盐岩为正常海相碳酸盐岩;结合玄武岩地球化学分析数据认为,碳酸盐岩总体沉积于海山环境,且包裹于其中的碳酸盐岩角砾岩块要早于上覆大套碳酸盐岩形成。