Mineralogical and geochemical spatial analyses of a waste-rock dump at the Libiola Fe–Cu sulphide mine (Eastern Liguria,Italy)

In this work, we investigated a 3 ha sulphide-bearing waste-rock dump (Libiola Mine, Italy) using mineralogical, geochemical, and geostatistical analyses. The dumped materials were highly heterogeneous in grain size and lithology and varied both laterally and vertically. Other than the host rock of the ore, basalts and serpentinites, the dumped materials contained high amounts of low-grade chalcopyrite- and pyrite-rich mineralisations. Due to these characteristics and to the absence of minerals able to neutralise acidity, this waste-rock dump can be classified as an acid mine drainage (AMD) producer. The study confirms that AMD is still active and, in the best scenario, can persist for up to 6.17 × 10³ years. The consequences of this process are of serious environmental concern as it involves strong acidification of the circulating waters, the release of potentially toxic metals into the soil, streams and rivers and the precipitation of huge quantities of secondary Fe-oxides and Fe-oxyhydroxides.     

Mineralogical and chemical evolution of ochreous precipitates from the Libiola Fe–Cu-sulfide mine (Eastern Liguria,Italy)

The mineralogical and chemical evolution of ochreous precipitates forming from acid mine drainage (AMD) from the abandoned Libiola Fe–Cu-sulfide mine (Eastern Liguria, Italy) was followed through a multianalytical approach (XRD, TEM, XRF, ICP) applied to surface precipitates and associated waters collected from several mine adits. The mineralogy of the precipitates changed significantly as a consequence of the variations of the chemical parameters of the circulating solutions (mainly pH, Eh, and sulfate concentrations) which, in turn, were mainly controlled by mixing with unpolluted stream and rill waters of the mining area. A progressive transition from jarosite-, to schwertmannite-, to goethite-, to ferrihydrite-, to amorphous-dominated precipitates was observed, mainly as a consequence of an increase in the pH of the associated solutions. This mineralogical evolution agrees well with the aqueous speciation and Eh–pH stability calculations performed on the waters associated with the different precipitate types. Furthermore, TEM analysis indicated that metastable pristine phases (schwertmannite) tend to transform progressively to well-crystallized more stable species, here represented by goethite. The comparison of the water chemistry and the crystal chemistry of the different precipitates showed a significant decrease in the Zn, Cu, Ni, Co contents in waters where the coexisting precipitates were almost exclusively composed of goethite. The distribution of V, Sr, As concentrations within the different precipitates showed that the most efficient scavenging phase for these elements was jarosite, whereas ferrihydrite efficiently took up Pb ions, and schwermannite acted as a natural sink for Cr.     

Mercury in river sediments, floodplains and plants growing thereon in the drainage area of the Idrija mine, Slovenia

Half a millennium mercury production at Idrija is reflected in increased mercury contents in all environmental segments. The bulk of roasting residues from the middle of the 19th century to 1977 was discharged directly into the Idrijca River, and the material was carried at high waters to the Soca River and farther into the Adriatic Sea. It has been estimated that 45500 tons of mercury were emitted into the environment during the operating period of the mine, which ceased production in 1994. In the lower reaches of the Idrijca the riverine deposits with high mercury contents have been, and will be in the future a source of mercury polluted sediment. Stream sediments were monitored at the same locations along the Idrijca and Soca rivers （70 kin） every 5 years since 1991 （1991-2005）. Grain size distribution was determined by dry sieving and fractions for geochemical analysis were prepared （〈0.04 and 〈0.125 mm）. Soils on river terraces were sampled at 5 localities in the lower course of Idrijca. At two locations of the terrace profiles the samples of averaged meadow forage and plantain （Plantago lanceolata） were collected within a 50-meters radius. We found that there was no decrease in mercury concentration in active river sediments during the last 20 years. Upstream from the Idrija Town the mercury concentrations in active river sediments vary from 1 to 10 mg/kg （average 3.3 mg/kg）. From Idrija to Spodnja Idrija the mercury concentrations increase extremely and vary greatly （32-4,121 mg/kg, the average is 734 mg/kg）. From Spodnja ldrija to the Idrijca-Soca confluence is the average 218 mg/kg, and 57 mg/kg downstream in the Soca River sediments.     

Distribution and behavior of heavy metals in a river polluted by acid mine drainage in the Dabaoshan mine area, China

Acid mine drainage （AMD） has been recognized as a major environmental pollution problem over past decades. This pollutant effluent is complex and is characterized by elevated concentrations of iron and sulfate, low pH, and high concentrations of a wide variety of metals depending on the host rock geology. Massive inadvertent discharges from acid mines have given rise to dramatic cases of ecological damage. These events indicate an improved understanding of the mechanism controlling metal transport to the river is important, since the aquatic ecology will be affected, to some degree, dependent on the phase （dissolved or particulate） in which the metal is transported. In this study, polluted water samples were collected along the Hengshi River near the Dabaoshan mine, Guangdong, China, in April 2005. The concentrations of dissolved Cu, Zn, Cd and Pb have been determined using ICP-MS and the chemical speciation of those metals in suspended particles was examined using BCR methods and SEM/EDX mineralogical analysis. Combining these two sets of data, the intention was to develop geochemical concepts, which explain the behavior of Cu, Zn, Cd and Pb in particle-water interactions of heavy metals in AMD. The results show that the dissolved heavy metals exhibited non-conservative behavior in the Hengshi River. The dissolved and particulate Cu, Zn, Cd and Pb have the similar spatial distribution, which decreased gradually along the river except in the lower reaches because of the absorption-desorption between dissolved and particulate phases. Although the metal concentrations in both phases were elevated, dissolved metals were dominant and had the maximum concentrations in the low pH region.     

Middle-Late Jurassic syndepositional tectonics recorded in the Ligurian Briançonnais succession (Marguareis–Mongioie area,Ligurian Alps,NW Italy)

The Middle–Upper Jurassic succession of the Marguareis–Mongioie area (Ligurian Briançonnais Domain), developed in a protected shelf environment evolving into a pelagic plateau, bears clear evidence of synsedimentary tectonics such as: growth fault-related structures; neptunian dykes; marked lateral variations in stratigraphic thicknesses testifying to the juxtaposition of sectors characterized by different sedimentation and subsidence rates; discordant, anomalous stratigraphic contacts corresponding to paleoescarpments; nodular beds showing evidence of fluidification interpreted as seismites; and the occurrence of sand-sized quartz grains pointing to denudation of Permo-Triassic quartz-rich rocks. Such evidence documents an important Middle-Late Jurassic post-breakup tectonic activity, which was more effective in controlling the basin topography than the Early Jurassic syn-rift tectonic phase. Two main tectono-sedimentary stages, one occurring during the Bathonian, the other falling within the Callovian–Kimmeridgian interval, were reconstructed. The first stage can be referred to a fault-related activity occurring shortly after the initial stages of oceanic spreading of the Ligurian Tethys; the second can be genetically related to the far effects of the first rifting stage of the Bay of Biscay and the Valais basin.     

Geochemical characteristics of acid mine drainage and sediments from coal mines, Shanxi Province, China

In this study, geochemical characteristics of acid mine drainage （AMD） and its sediments from the Malan and Sitai coalmines, Shanxi Province, China, were investigated. Many analytical approaches such as IC, ICP-MS, XRD, XRF, and modeling calculation of hydrogeochemistry using PHREEQCI software were employed. The AMD is characterized by higher concentrations of iron and sulfate, a low pH, and elevated concentrations of a wide variety of heavy metals. The results of modeling calculation by PHREEQCI software demonstrate the metals in AMD are present mainly as Me^n＋ and MeSO4^n-2 species. The sediments of AMD are composed mainly of iron-beating minerals such as goethite and schwertmannite, which are controlled by pH, Fe and SO4^2- concentrations. The schwertmannite mineral has been found for the first time in China.     

Metamorphic consequences of Neogene thermal anomaly in the northern Apennines (Radicondoli-Travale area,Larderello geothermal field – Italy)

Abstract

In the Radicondoli–Travale area of the Larderello geothermal field (Italy) new structural and petrologic data on some metamorphic units, cored from geothermal wells, reveal the existence of a wide complex of hornfels rocks. The development of the complex is related to the emplacement of Neogene magmatic rocks at a shallow depth within a Permo–Triassic terrigenous metasedimentary sequence of a low metamorphic grade. The sequence was subjected to alpine tectonic-metamorphic events. This reconstruction gives new insights in the tectonic setting of metamorphic units below the Tuscan Nappe, in southern Tuscany. Particularly, the medium and high grade metamorphic rocks seem strictly related to the development of Neogene thermal aureoles and do not represent remnants of a Paleozoic basement. Furthermore, in this sector of the Larderello geothermal system, the presence of deep geothermal reservoir at a depth of 3 000 m is mainly linked to the enhanced permeability caused by fracturing in these hornfels rocks. This fracturing is a consequence of the dehydration reaction occurring in the metapelites due to Neogene thermal metamorphism. This mechanism allowed the development of a long-lived hydrothermal system, shown by the secondary mineralogical assemblages. These testify the presence of at least two hydrothermal stages which are well preserved in the less permeable units. © 2000 Editions scientifiques et médicales Elsevier SAS     

Investigation of pyrite oxidation and acid mine drainage characterization associated with Razi active coal mine and coal washing waste dumps in the Azad shahr–Ramian region,northeast Iran

Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.     

Metamorphic consequences of Neogene thermal anomaly in the northern Apennines (Radicondoli-Travale area,Larderello geothermal field – Italy)

In the Radicondoli–Travale area of the Larderello geothermal field (Italy) new structural and petrologic data on some metamorphic units, cored from geothermal wells, reveal the existence of a wide complex of hornfels rocks. The development of the complex is related to the emplacement of Neogene magmatic rocks at a shallow depth within a Permo–Triassic terrigenous metasedimentary sequence of a low metamorphic grade. The sequence was subjected to alpine tectonic-metamorphic events. This reconstruction gives new insights in the tectonic setting of metamorphic units below the Tuscan Nappe, in southern Tuscany. Particularly, the medium and high grade metamorphic rocks seem strictly related to the development of Neogene thermal aureoles and do not represent remnants of a Paleozoic basement. Furthermore, in this sector of the Larderello geothermal system, the presence of deep geothermal reservoir at a depth of 3 000 m is mainly linked to the enhanced permeability caused by fracturing in these hornfels rocks. This fracturing is a consequence of the dehydration reaction occurring in the metapelites due to Neogene thermal metamorphism. This mechanism allowed the development of a long-lived hydrothermal system, shown by the secondary mineralogical assemblages. These testify the presence of at least two hydrothermal stages which are well preserved in the less permeable units.     

Cyclostratigraphic and chronostratigraphic correlations in the Barremian–Aptian shallow-marine carbonates of the central-southern Apennines (Italy)

We present a high-resolution sedimentological analysis of Barremian–Aptian shallow-water carbonates from two cores (S. Maria 6 and 4) that were drilled in the central Apennines (central Italy) and one section (Monte Faito) that crops out in the southern Apennines (southern Italy). The aims of this work are (a) to propose a high-resolution correlation of sections that are located approximately 170 km apart in different tectonic units and paleogeographic domains using a microstratigraphic (cm-scale) approach and (b) to reveal global and regional mechanisms that control the stratigraphic architecture of these carbonate platform strata.A composite S. Maria section was assembled by integrating the sedimentologic and biostratigraphic analyses of the two cores, which overlap each other across the Barremian–Aptian boundary. Both the S. Maria and the Monte Faito sections show repetitive facies patterns that are expressed as elementary cycles, which are hierarchically grouped into bundles and superbundles. The elementary cycles are meter-scale sedimentary units that are bounded by subaerial erosion surfaces, which directly overlie subtidal deposits. This implies that they formed under the influence of relative sea-level fluctuations. In both sections, the superbundles are organized into Transgressive/Regressive Facies Trends (T/RFTs), which are considered to be expressions of lower-frequency relative sea-level changes.These deposits, like their Cretaceous analogues of other areas of the Apennines, show evidence of astronomically controlled eustatic oscillations, which are reflected in the hierarchical organization of their stacking patterns. They also exhibit a sequence-stratigraphic configuration that is best recognizable in the superbundles and T/RFTs. Based on integrated stratigraphic criteria, a high-resolution regional correlation between S. Maria and Monte Faito was developed and compared with the reference section of Monte Raggeto (M. Maggiore, southern Apennines, Italy), where biostratigraphic and cyclostratigraphic studies have been complemented by magneto- and isotope-stratigraphy.We also propose a chronostratigraphic correlation between our T/RFTs and the Tethyan stratigraphic cycles of Hardenbol et al. (1998). Based on the cyclostratigraphic interpretation and orbital chronostratigraphy of the studied interval, we estimate a minimum duration of 5.2 my for the Barremian interval, which is similar to the 4.5 my duration from the Geological Time Scale of Gradstein et al., (2012).     

New data for the kinematic interpretation of the Alps–Apennines junction (Northwestern Italy)

Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution recording changes of subsidence and shift of depocentres in relation to crustal structures.     

Late Oligocene–early Miocene olistostromes (sedimentary mélanges) as tectono-stratigraphic constraints to the geodynamic evolution of the exhumed Ligurian accretionary complex (Northern Apennines,NW Italy)

In the Northern Apennines of Italy, mud-rich olistostromes (sedimentary mélanges) occur at different stratigraphic levels within the late Oligocene–early Miocene sedimentary record of episutural/wedge-top basins. They are widely distributed along the exhumed outer part of the Ligurian accretionary complex, atop the outer Apenninic prowedge, over an area about 300 km long and 10–15 km wide. Olistostromes represent excellent examples of ancient submarine mass-transport complexes (MTCs), consisting of stacked cohesive debris flows that can be directly compared to some of those observed in modern accretionary wedges. We describe the internal arrangement of olistostrome occurrences in the sector between Voghera and the Monferrato area, analysing their relationships with mesoscale liquefaction features, which are commonly difficult to observe in modern MTCs. Slope failures occurred in isolated sectors along the wedge front, where out-of-sequence thrusting, seismicity, and different pulses of overpressured tectonically induced fluid flows acted concomitantly. Referring to the Northern Apennines regional geology, we also point out a gradual lateral rejuvenation (from late Oligocene to early Miocene) toward the SE and an increasing size and thickness of the olistostromes along the strike of the frontal Apenninic prowedge. This suggests that morphological reshaping of the outer prowedge via mass-transport processes balanced, with different pulses over a short time span, the southeastward migration and segmentation of accretionary processes. The latter were probably favoured by the occurrence in the northwestern part of the Northern Apennines of major, inherited palaeogeographic features controlling the northward propagation of the prowedge. Detailed knowledge of olistostromes, as ancient examples of MTCs related to syn-sedimentary tectonics and shale diapirism, and of their lateral variations in term of age and size, provides useful information in regard to better understanding of both the tectono-stratigraphic evolution of the Apenninic prowedge and the submarine slope failures in modern accretionary wedges.     

Stream water geochemistry from mine wastes in Peña de Hierro,Riotinto area,SW Spain: a case of extreme acid mine drainage

In this work we have studied the geochemistry of stream waters arising from waste dumps at the Peña de Hierro mine (Iberian Pyrite Belt, SW Spain), and we have correlated them with the mineralogical and geochemical characteristics of the wastes to asses the source and factors affecting the release of trace elements. The mineralogical composition and geochemistry of 58 borehole samples of waste dumps were studied in the <2 mm fraction. Twenty-eight water samples collected in winter and summer from streams emerging from the waste dumps were analysed for pH, Eh, conductivity, temperature, sulphates and major and trace elements. The leachates from pyrite-rich volcanic tuffs produced very acidic waters, usually with pHs below 2 and reaching values as low as 0.7. The partial dissolution of gossan, which is mainly composed of Fe oxy-hydroxides and is rich in trace elements, released high concentrations of Fe_tot (up to 33 g/L), As (up to 72), Mo (up to 11 mg/L). On the other hand Cd, Zn and Pb reached up to 0.85, 142 and 0.42 mg/L, respectively, in the stream arising from roasted pyrite ashes and other pyritic wastes. Several elements such as Al, Fe, As, Co, Cu and Mo were strongly correlated with the pH, but Cd and Zn were not correlated under such acidic conditions. The precipitation of jarosite seems to be an important factor in the retention of Pb. The mobility sequence of trace elements shows that Co, Zn and Cd were among the most mobile elements; Cu, As and Mo had intermediate mobility, and Pb was the most immobile. This work shows that uncontrolled waste dumping increases the pollution potential, and a selective management could reduce the release of trace elements into stream waters and mitigate the contamination.     

Retrogressive fabric development during exhumation of the Voltri Massif (Ligurian Alps,Italy): arguments for an extensional origin and implications for the Alps–Apennines linkage

Geological mapping coupled with structural investigations carried out in the Voltri Massif (eastern Ligurian Alps, Italy) provide new data for the interpretation of the tectonic context controlling main fabric development during exhumation of its high-pressure core. The Voltri Massif is here interpreted as a c. 30 km-long eclogite-bearing, asymmetric dome formed by the progressive verticalisation of the regional, second-phase mylonitic foliation developed during retrogressive greenschist metamorphic conditions. In this light, the exhumation history is driven by a ductile-to-brittle extensional process, operating through low-angle, top-to-the-W multiple detachment systems. A Late Eocene–Early Oligocene age for this extensional episode is proposed on the basis of structural correlations, stratigraphic and radiometric constraints. In this scenario, the Voltri Massif is interpreted as an extensional domain developed to accommodate the Late Eocene–Early Oligocene arching of the Western Alps–Northern Apennines orogenic system.     

Occurrence of palygorskite and sepiolite in upper Paleocene–middle Eocene marine deep sediments of the Lagonegro Basin (Southern Apennines—Italy): Paleoenvironmental and provenance inferences

A mineralogical and geochemical study of clay lithologies and a biostratigraphic analysis of the carbonates from the deep-sea Lagonegro Basin (Southern Apennines—Italy) have been carried out to deduce in general the provenance of clay sediments and their paleoenvironmental conditions and particular to recognize the signature of the Paleocene–Eocene climatic global warming. The analysed succession comprising a wide stratigraphic interval of the Sannio Unit, spanning between Albian to the upper Oligocene–lower Miocene, is exposed near Accettura and Stigliano villages. Eighteen clay samples were analysed by XRD, XRF, SEM, TG-DTA. Their age was framed by biostratigraphic analyses carried out on carbonate sediments. Mineral assemblage of the clay sediments includes quartz, carbonates (calcite and dolomite), feldspars (plagioclase and k-feldspars), hematite, randomly illite/smectite mixed layers with a low illite percentage, kaolinite, discrete illite–muscovite, chlorite, palygorskite and sepiolite. The low illite percentage in randomly illite/smectite mixed layers indicates low diagenetic conditions for the studied successions. These features are unique for the Cretaceous–Tertiary successions of the Lagonegro domain and are particularly significant for the preservation of the native mineralogical assemblage useful to determine the provenance and paleoenvironmental conditions of the clayey sediments. Palygorskite and sepiolite are concentrated in the upper Paleocene–middle Eocene stratigraphic interval and particularly in the upper part of the early Eocene—lower part of the middle Eocene (biozone of Blow P 9–12). Clay sediments rich in palygorskite and sepiolite show a higher P₂O₅ amount and a lower kaolinite percentage, compatible with warm and arid climatic conditions typical of the global warming event well recorded in the southern tethyan margin. Likely palygorskite and sepiolite formed in lagoonal environment in nearby carbonate platform margins and then they were transported into the Lagonegro Basin as indicated by the well developed habitus of palygorskite. During the Paleogene the Lagonegro Basin and the nearby carbonate platforms represented a key sector the southern paleodomains of the Tethys. The discovery of these minerals gives a contribution to the reconstruction paleoenvironmental conditions of the Tethian paleo-margin during the early–middle Eocene.     

Modified acid–base accounting model validation and pH buffer trend characterisation in mine drainage at the AngloGold Ashanti Obuasi mine in Ghana,West Africa

Acid–base accounting (ABA) is a static test used to evaluate pre-mining drainage quality of ores with interpretations based on a reference 3-data point model. The method is often complemented with a kinetic test to ensure certainty of results. The challenges associated with both methods compel companies to rely on only the ABA test, thereby compromising on the long-term drainage quality. This paper validates a proposed 4-data point model that was used to establish a 20% increase in the alkaline amendment of ores at the AngloGold Ashanti Obuasi Mine in Ghana. The validation was done using model limits, the robustness of coefficient of determination and model factor sequence variation. Acidification trends and mineralogical data evaluation of tailings were used to characterise pH buffer trends in mine drainage. The modified 4-data point model, which incorporates a vital kinetic test factor into the ABA model, provides a criterion for the adjustment of carbonate amendment value to improve acid neutralisation in the drainage; this would reduce (1) cost of experimentation, (2) turnaround time for analyses, (3) complexities associated with both test methods. From the XRD data, alunite and goethite are present in tailings to provide sustained pH buffering in drainage beyond the scope of the modified model, while the characterised pH buffer trend could be used for monitoring drainage quality.     

Mineralogy and geochemistry of fine-grained Dahab stream sediments,Southeastern Sinai,Egypt: emphasis on the intergrowths of Fe–Ti oxides

Acta Geochimica - Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area (southeastern Sinai, Egypt) are presented. The studied...     

Cyanobacterial mineralisation of posnjakite (Cu4(SO4)(OH)6·H2O) in Cu-rich acid mine drainage at Yanqul,northern Oman

This is the first detailed account of the copper sulfate posnjakite (Cu₄(SO₄)(OH)₆·H₂O) coating cm-long filaments of a microbial consortium of four cyanobacteria and Herminiimonas arsenicoxydans. It was first observed on immersed plant leaves and stalks in a quarry sump of the abandoned Yanqul gold mine in the northern region of Oman; rock surfaces in the immediate vicinity show no immediate evidence of posnjakite. However, a thin unstructured layer without filaments but also containing the brightly coloured turquoise posnjakite covers ferruginous muds in the sump. Although copper is a potent bactericide, the microbes seem to survive even at the extreme heavy metal concentrations that commonly develop in the sump during the dry season (Cu²⁺ ≈ 2300 ppm; Zn²⁺ = 750 ppm; Fe²⁺ ≈ 120 ppm; Ni²⁺ = 37 ppm; Cr_total = 2.5 ppm; Cl⁻ = 8250 ppm; and SO₄²⁻ = 12,250 ppm; pH ∼2.6), thus leading to the precipitation of posnjakite over a large range of physicochemical conditions. Upon exposure to the prevailing arid climate, dehydration and carbonation quickly replace posnjakite with brochantite (Cu₄(SO₄)(OH)₆) and malachite (Cu₂(CO₃)(OH)₂). To characterise and understand the geochemical conditions in which posnjakite precipitates from undersaturated fluids (according to our thermodynamic modelling of the dominant elements), waters from rainy and dry periods were analysed together with various precipitates and compared with the observed field occurrences. The findings imply that posnjakite should not form in the examined environment through purely inorganic mechanisms and its origin must, therefore, be linked to the encountered microbial activities.     

Upper crust “boudinage” during post-collisional Miocene extension in Tuscany: Insights from the southern part of the Larderello geothermal area (Northern Apennines,Italy)

A geological study carried out in the southern part of the Larderello geothermal area (Northern Apennines) provides new information on the development mechanism and timing of the earlier extensional structures that formed during the Miocene post-collisional tectonics which affected the orogen. Staircase low-angle normal faults (LANFs) affected a multilayered thickened upper crust after the collisional stage, producing the lateral segmentation of the Tuscan Nappe, the deeper non-metamorphic tectonic unit of the Northern Apennines in the Tuscan area. The tectonic history recorded in two Tuscan Nappe discontinuous bodies revealed that the LANFs took place during the Middle–Late Miocene, displacing collisional structures developed from the Late Oligocene. These Tuscan Nappe bodies are delimited by detachment faults located at the base, within the Tuscan evaporites, and at the top within the Ligurian Units. Their western and eastern margins coincide with east-dipping ramps. These structures and the Tuscan Nappe bodies were later dissected by Pliocene–Quaternary high-angle normal faults. The reconstructed deformation history implies that the Tuscan Nappe bodies are extensional horses developed through an earlier asymmetrical east-dipping extensional duplex system, involved in block faulting during the later, Pliocene-Quaternary, stage of extension.     

Zinc contamination in river water and sediments at Taisyu Zn–Pb mine area,Tsushima Island,Japan

Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml^− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g^− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange.