Impact of diagenesis on reservoir quality and heterogeneity of the Upper Triassic Chang 8 tight oil sandstones in the Zhenjing area,Ordos Basin,China

Reservoir quality and heterogeneity are critical risk factors in tight oil exploration. The integrated, analysis of the petrographic characteristics and the types and distribution of diagenetic alterations in the Chang 8 sandstones from the Zhenjing area using core, log, thin-section, SEM, petrophysical and stable isotopic data provides insight into the factors responsible for variations in porosity and permeability in tight sandstones. The results indicate that the Chang 8 sandstones mainly from subaqueous distributary channel facies are mostly moderately well to well sorted fine-grained feldspathic litharenites and lithic arkose. The sandstones have ultra-low permeabilities that are commonly less than 1 mD, a wide range of porosities from 0.3 to 18.1%, and two distinct porosity-permeability trends with a boundary of approximately 10% porosity. These petrophysical features are closely related to the types and distribution of the diagenetic alterations. Compaction is a regional porosity-reducing process that was responsible for a loss of more than half of the original porosity in nearly all of the samples. The wide range of porosity is attributed to variations in calcite cementation and chlorite coatings. The relatively high-porosity reservoirs formed due to preservation of the primary intergranular pores by chlorite coatings rather than burial dissolution; however, the chlorites also obstruct pore throats, which lead to the development of reservoirs with high porosity but low permeability. In contrast, calcite cementation is the dominant factor in the formation of low-porosity, ultra-low-permeability reservoirs by filling both the primary pores and the pore throats in the sandstones. The eogenetic calcites are commonly concentrated in tightly cemented concretions or layers adjacent to sandstone-mudstone contacts, while the mesogenetic calcites were deposited in all of the intervals and led to further heterogeneity. This study can be used as an analogue to understand the variations in the pathways of diagenetic evolution and their impacts on the reservoir quality and heterogeneity of sandstones and is useful for predicting the distribution of potential high-quality reservoirs in similar geological settings.     

Diagenetic alterations and reservoir heterogeneity within the depositional facies: A case study from distributary-channel belt sandstone of Upper Triassic Yanchang Formation reservoirs (Ordos Basin,China)

Diagenesis is of decisive significance for the reservoir heterogeneity of most clastic reservoirs. Linking the distribution of diagenetic processes to the depositional facies and sequence stratigraphy has in recent years been discipline for predicting the distribution of diagenetic alterations and reservoir heterogeneity of clastic reservoirs. This study constructs a model of distribution of diagenetic alterations and reservoir heterogeneity within the depositional facies by linking diagenesis to lithofacies, sandstone architecture and porewater chemistry during burial. This would help to promote better understanding of the distribution of reservoir quality evolution and the intense heterogeneity of reservoirs. Based on an analogue of deltaic distributary channel belt sandstone in Upper Triassic Yanchang Formation, 83 sandstone plug samples were taken from 13 wells located along this channel belt. An integration of scanning electron microscopy, thin sections, electron microprobe analyses, rate-controlled porosimetry (RCP), gas-flow measurements of porosity and permeability, and nuclear magnetic resonance (NMR) experiments, together with published data, were analysed for the distribution, mineralogical and geochemical characteristics of detrital and diagenetic components and the distribution of reservoir quality within the distributary channel belt.Distribution of diagenetic alterations and reservoir heterogeneity within the distributary channel belt sandstones include (i) formation of high quality chlorite rims in the middle part of thick sandstones with coarser grain sizes and a lower content of ductile components resulted from the greater compaction resistance of these sandstones (providing larger pore spaces for chlorite growth), leading to formation of the intergranular pore – wide sheet-like throat and intergranular pore - intragranular pore – wide sheet-like throat (Φ>15%, k>1mD) in the middle part of thick sandstones; (ii) formation of thinner chlorite rims in the middle part of thinner sandstones is associated with the intergranular pore - intragranular pore – narrow sheet-like throat (9%<Φ<14%, 0.2mD<k<0.8mD); (iii) strong cementation by kaolinite in the more proximal sandstones of distributary channel owing to the strong feldspar dissolution by meteoric water, resulting in the intragranular pore - group of interstitial cement pores – narrow sheet-like throat/extremely narrow sheet-like throat (8%<Φ<11%, 0.1mD<k<0.3mD) due to the pore-filling kaolinite occluding porosity; (iv) formation of dense ferrocalcite zones (δ¹⁸O_VPDB = −23.4‰ to −16.6‰; δ¹³ C_VPDB = −4.0‰ to −2.3‰) favoured in the top and bottom of the channel sandstone which near the sandstone-mudstone bouding-surface, destroying pore space (Φ<8%, k<0.1mD); (v) strong compaction in sandstone of distributary channel edge laterally as a result of fine grain size and high content of ductile components in those sandstones, forming the group of interstitial cement pores – extremely narrow sheet-like throat with porosity values less than 8%.     

Quantitative impact of diagenesis on reservoir quality of the Triassic Chang 6 tight oil sandstones,Zhenjing area,Ordos Basin,China

The Upper Triassic Chang 6 sandstone, an important exploration target in the Ordos Basin, is a typical tight oil reservoir. Reservoir quality is a critical factor for tight oil exploration. Based on thin sections, scanning electron microscopy (SEM), X-ray diffraction (XRD), stable isotopes, and fluid inclusions, the diagenetic processes and their impact on the reservoir quality of the Chang 6 sandstones in the Zhenjing area were quantitatively analysed. The initial porosity of the Chang 6 sandstones is 39.2%, as calculated from point counting and grain size analysis. Mechanical and chemical compaction are the dominant processes for the destruction of pore spaces, leading to a porosity reduction of 14.2%–20.2% during progressive burial. The porosity continually decreased from 4.3% to 12.4% due to carbonate cementation, quartz overgrowth and clay mineral precipitation. Diagenetic processes were influenced by grain size, sorting and mineral compositions. Evaluation of petrographic observations indicates that different extents of compaction and calcite cementation are responsible for the formation of high-porosity and low-porosity reservoirs. Secondary porosity formed due to the burial dissolution of feldspar, rock fragments and laumontite in the Chang 6 sandstones. However, in a relatively closed geochemical system, products of dissolution cannot be transported away over a long distance. As a result, they precipitated in nearby pores and pore throats. In addition, quantitative calculations showed that the dissolution and associated precipitation of products of dissolution were nearly balanced. Consequently, the total porosity of the Chang 6 sandstones increased slightly due to burial dissolution, but the permeability decreased significantly because of the occlusion of pore throats by the dissolution-associated precipitation of authigenic minerals. Therefore, the limited increase in net-porosity from dissolution, combined with intense compaction and cementation, account for the low permeability and strong heterogeneity in the Chang 6 sandstones in the Zhenjing area.     

Reservoir quality and rock properties modeling – Triassic and Jurassic sandstones,greater Shearwater area,UK Central North Sea

The complex burial and diagenetic histories of the Jurassic Fulmar and Triassic Skagerrak sandstones in the UK Central North Sea present significant challenges with regard to reservoir quality and rock property prediction. Commercial reservoir quality is retained despite deep burial and associated high temperatures and pressures. Shallow marine Fulmar sands are normally compacted (mean IGV = 26 ± 3%) yet have porosities of 21–33%. Porosity was preserved through inhibition of quartz cementation by clay and microquartz coatings, and enhanced by dissolution of framework grains (∼5%). Skagerrak fluvial sands are more compacted (mean IGV = 23 ± 2%), exhibit minor feldspar dissolution (<1%), and have porosities of 16–27%. Quartz cement averages only 2 ± 1.5% due to robust chlorite coats that cover 80% (±13%) of quartz surfaces.We modeled reservoir quality evolution using the forward diagenetic model Touchstone, which simulates porosity loss due to compaction and quartz cementation. Quantitative petrographic analyses and burial history data were used to calibrate Touchstone model parameters. The results were applied to deeper prospects for pre-drill prediction of porosity and permeability. In parallel, petrophysical data were used to characterize the elastic properties of the sandstones to provide a basis for quantitative seismic forward modeling. Experimental data and core-calibrated petrophysical results, reflecting variable in situ fluids and saturations, were used to build an elastic properties model. The model is robust and was used to generate fluid-filled sandstone properties, incorporating Touchstone results, for prospect-specific seismic attribute modeling. Well results from exploration wells are in good agreement with pre-drill Touchstone and elastic properties model predictions.     

Importance of vertical effective stress for reservoir quality in the Skagerrak Formation,Central Graben,North Sea

The complex fluvial sandstones of the Triassic Skagerrak Formation are the host reservoir for a number of high-pressure, high-temperature (HPHT) fields in the Central Graben, North Sea. All the reservoir sandstones in this study comprise of fine-grained to medium-grained sub-arkosic to arkosic sandstones that have experienced broadly similar burial and diagenetic histories to their present-day maximum burial depths. Despite similar diagenetic histories, the fluvial reservoirs show major variations in reservoir quality and preserved porosity. Reservoir quality varies from excellent with anomalously high porosities of up to 35% at burial depth of >3500 m below seafloor to non-economic with porosities <10% at burial depth of 4300 m below seafloor.This study has combined detailed petrographic analyses, core analysis and pressure history modelling to assess the impact of differing vertical effective stresses (VES) and high pore fluid pressures (up to 80 MPa) on reservoir quality. It has been recognised that fluvial channel sandstones of the Skagerrak Formation in the UK sector have experienced significantly less mechanical compaction than their equivalents in the Norwegian sector. This difference in mechanical compaction has had a significant impact upon reservoir quality, even though the presence of chlorite grain coatings inhibited macroquartz cement overgrowths across all Skagerrak Formation reservoirs. The onset of overpressure started once the overlying Chalk seal was buried deeply enough to form a permeability barrier to fluid escape. It is the cumulative effect of varying amounts of overpressure and its effect on the VES history that is key to determining the reservoir quality of these channelised sandstone units. The results are consistent with a model where vertical effective stress affects both the compaction state and subsequent quartz cementation of the reservoirs.     

Mineral types and organic matters of the Ordovician-Silurian Wufeng and Longmaxi Shale in the Sichuan Basin,China: Implications for pore systems,diagenetic pathways,and reservoir quality in fine-grained sedimentary rocks

Mineral types (detrital and authigenic) and organic-matter components of the Ordovician-Silurian Wufeng and Longmaxi Shale (siliceous, silty, argillaceous, and calcareous/dolomitic shales) in the Sichuan Basin, China are used as a case study to understand the control of grain assemblages and organic matter on pores systems, diagenetic pathway, and reservoir quality in fine-grained sedimentary rocks. This study has been achieved using a combination of petrographic, geochemical, and mercury intrusion methods. The results reveal that siliceous shale comprises an abundant amount of diagenetic quartz (40–60% by volume), and authigenic microcrystalline quartz aggregates inhibit compaction and preserve internal primary pores as rigid framework for oil filling during oil window. Although silty shale contains a large number of detrital silt-size grains (30–50% by volume), which is beneficial to preserve interparticle pores, the volumetric contribution of interparticle pores (mainly macropores) is small. Argillaceous shale with abundant extrabasinal clay minerals (>50% by volume) undergoes mechanical and chemical compactions during burial, leading to a near-absence of primary interparticle pores, while pores preserved between clay platelets are dominant with more than 10 nm in pore size. Pore-filling calcite and dolomite precipitated during early diagenesis inhibit later compaction in calcareous/dolomitic shale, but the cementation significantly reduces the primary interparticle pores. Pore-throat size distributions of dolomitic shale show a similar trend with silty shale. Besides argillaceous shale, all of the other lithofacies are dominated by OM pores, which contribute more micropores and mesopores and is positively related to TOC and quartz contents. The relationship between pore-throat size and pore volume shows that most pore volumes are provided by pore throats with diameters <50 nm, with a proportion in the order of siliceous (80.3%) > calcareous/dolomitic (78.4%) > silty (74.9%) > argillaceous (61.3%) shales. In addition, development degree and pore size of OM pores in different diagenetic pathway with the same OM type and maturity show an obvious difference. Therefore, we suggest that the development of OM pores should take OM occurrence into account, which is related to physical interaction between OM and inorganic minerals during burial diagenesis. Migrated OM in siliceous shale with its large connected networks is beneficial for forming more and larger pores during gas window. The result of the present work implies that the study of mineral types (detrital and authigenic) and organic matter-pores are better understanding the reservoir quality in fine-grained sedimentary rocks.     

Exhumed hydrocarbon-seep authigenic carbonates from Zakynthos Island (Greece): Concretions not archaeological remains

In Zakynthos Island (Greece), authigenic cementation of marine sediment has formed pipe-like, disc and doughnut-shaped concretions. The concretions are mostly composed of authigenic ferroan dolomite accompanied by pyrite. Samples with >80% dolomite, have stable isotope compositions in two groups. The more indurated concretions have δ¹⁸O around +4‰ and δ¹³C values between −8 and −29‰ indicating dolomite forming from anaerobic oxidation of thermogenic methane (hydrocarbon seep), in the sulphate-methane transition zone. The outer surfaces of some concretions, and the less-cemented concretions, typically have slightly heavier isotopic compositions and may indicate that concretion growth progressed from the outer margin in the ambient microbially-modified marine pore fluids, inward toward the central conduit where the isotopic compositions were more heavily influenced by the seep fluid. Sr isotope data suggest the concretions are fossil features, possibly of Pliocene age and represent an exhumed hydrocarbon seep plumbing system. Exposure on the modern seabed in the shallow subtidal zone has caused confusion, as concretion morphology resembles archaeological stonework of the Hellenic period.     

Natural sealed fractures in mudrocks: A case study tied to burial history from the Barnett Shale,Fort Worth Basin,Texas, USA

The Mississippian Barnett Shale (Texas, USA), consisting of organic-rich shales and limestones, hosts the largest gas fields of North America. This study examines sealed fractures from core and outcrop samples of the Barnett Shale of the Fort Worth Basin and aims to: 1) characterize the phases occurring in the fractures from samples having experienced different burial histories; 2) establish a paragenetic sequence to relate the timing of fracture origin and sealing with the burial history of the basin; and 3) contribute to the understanding of the mechanisms of fracture formation in shales, including overpressure origin.Four fracture generations were distinguished in the most deeply buried core samples by characterizing the sealing minerals petrographically and geochemically. The generations were inserted into the framework of a reconstructed burial history for the Fort Worth Basin, which allowed a time sequence for fracture development to be established. This in turn allowed inference of conditions of fracture development, and consideration of fracture mechanisms as well as the origin of the parent fluids of sealing minerals.Type 1 fractures formed during early mechanical compaction (at a few 10 s to 100 m of depth) of still not fully cemented sediments. Type 2 fractures formed during moderate burial (∼2 km), from slightly modified seawater. Their timing is consistent with overpressure generated during rapid deposition and differential compaction of Pennsylvanian lithologies during the onset of the Ouachita compressional event. Type 3 fractures formed during deep burial (>3 km) from silica-rich basinal brines possibly derived from clay diagenesis. Type 4 fractures formed at very deep burial (>4 km), from hot and ¹⁸O-rich fluids, carrying light oil (20-30 API) and record the opening of the fluid system after hydrocarbon migration.Differences are highlighted between the timing and thermal regimes under which fractures formed in Barnett lithologies from different areas of the basin, this suggesting that extrapolation of outcrop observations to subsurface must be used with due care.     

Depositional and diagenetic controls on deeply-buried Eocene sublacustrine fan reservoirs in the Dongying Depression,Bohai Bay Basin,China

This paper investigates the reservoir potential of deeply-buried Eocene sublacustrine fan sandstones in the Bohai Bay Basin, China by evaluating the link between depositional lithofacies that controlled primary sediment compositions, and diagenetic processes that involved dissolution, precipitation and transformation of minerals. This petrographic, mineralogical, and geochemical study recognizes a complex diagenetic history which reflects both the depositional and burial history of the sandstones. Eogenetic alterations of the sandstones include: 1) mechanical compaction; and 2) partial to extensive non-ferroan carbonate and gypsum cementation. Typical mesogenetic alterations include: (1) dissolution of feldspar, non-ferroan carbonate cements, gypsum and anhydrite; (2) precipitation of quartz, kaolinite and ferroan carbonate cements; (3) transformation of smectite and kaolinite to illite and conversion of gypsum to anhydrite. This study demonstrates that: 1) depositional lithofacies critically influenced diagenesis, which resulted in good reservoir quality of the better-sorted, middle-fan, but poor reservoir quality in the inner- and outer-fan lithofacies; 2) formation of secondary porosity was spatially associated with other mineral reactions that caused precipitation of cements within sandstone reservoirs and did not greatly enhance reservoir quality; and 3) oil emplacement during early mesodiagenesis (temperatures > 70 °C) protected reservoirs from cementation and compaction.     

Diagenesis and reservoir quality of sandstones with ancient “deep” incursion of meteoric freshwater——An example in the Nanpu Sag,Bohai Bay Basin,East China

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T_h) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T_h (95∼115 °C) of AFI and low δ¹⁸O_(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ¹⁸O_(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.     

Reservoir characterization of Scollard-age fluvial sandstones,Alberta foredeep

A detailed laboratory study of 53 sandstone samples from 23 outcrops and 156 conventional core samples from the Maastrichtian-Paleocene Scollard-age fluvial strata in the Western Canada foredeep was undertaken to investigate the reservoir characteristics and to determine the effect of diagenesis on reservoir quality. The sandstones are predominantly litharenites and sublitharenites, which accumulated in a variety of fluvial environments. The porosity of the sandstones is both syn-depositional and diagenetic in origin. Laboratory analyses indicate that porosity in sandstones from outcrop samples with less than 5% calcite cement averages 14%, with a mean permeability of 16 mD. In contrast, sandstones with greater than 5% calcite cement average 7.9% porosity, with a mean permeability of 6.17 mD. The core porosity averages 17% with 41 mD permeability. Cementation coupled with compaction had an important effect in the destruction of porosity after sedimentation and burial. The reservoir quality of sandstones is also severely reduced where the pore-lining clays are abundant (>15%). The potential of a sandstone to serve as a reservoir for producible hydrocarbons is strongly related to the sandstone’s diagenetic history. Three diagenetic stages are identified: eodiagenesis before effective burial, mesodiagenesis during burial, and telodiagenesis during exposure after burial. Eodiagenesis resulted in mechanical compaction, calcite cementation, kaolinite and smectite formation, and dissolution of chemically unstable grains. Mesodiagenesis resulted in chemical compaction, precipitation of calcite cement, quartz overgrowths, and the formation of authigenic clays such as chlorite, dickite, and illite. Finally, telodiagenesis seems to have had less effect on reservoir properties, even though it resulted in the precipitation of some kaolinite and the partial dissolution of feldspar.     

Diagenesis of the palaeo-oil-water transition zone in a Lower Pennsylvanian carbonate reservoir: Constraints from cathodoluminescence microscopy,microthermometry, and isotope geochemistry

Oil-water transition zones in carbonate reservoirs represent important but rarely studied diagenetic environments that are now increasingly re-evaluated because of their potentially large effects on reservoir economics. Here, data from cathodoluminescence and fluorescence microscopy, isotope geochemistry, microthermometry, and X-ray tomography are combined to decipher the diagenetic history of a 5-m-long core interval comprising the oil-water transition zone in a Lower Pennsylvanian carbonate reservoir. The aim is to document the cementation dynamics prior, during, and after oil emplacement in its context of changing fluid parameters. Intergrain porosity mean values of 7% are present in the upper two sub-zones of the oil-water transitions zone but values sharply increase to a mean of 14% in the lower sub-zone grading into the water-saturated portions of the reservoir and a very similar pattern is observed for permeability values. In the top of the water-filled zone, cavernous porosity with mean values of about 24% is found. Carbonate cements formed from the earliest marine to the late burial stage. Five calcite (Ca-1 through 5) and one dolomite (Dol) phase are recognized with phase Ca-4b recording the onset of hydrocarbon migration. Carbon and oxygen cross-plots clearly delineate different paragenetic phases with Ca-4 representing the most depleted δ¹³C ratios with mean values of about −21‰. During the main phase of oil emplacement, arguably triggered by far-field Alpine tectonics, carbonate cementation was slowed down and eventually ceased in the presence of hydrocarbons and corrosive fluids with temperatures of 110–140 °C and a micro-hiatal surface formed in the paragenetic sequence. These observations support the “oil-inhibits-diagenesis” model. The presence an earlier corrosion surface between phase Ca-3 and 4 is best assigned to initial pulses of ascending corrosive fluids in advance of hydrocarbons. The short-lived nature of the oil migration event found here is rather uncommon when compared to other carbonate reservoirs. The study is relevant as it clearly documents the strengths of a combined petrographic and geochemical study in order to document the timing of oil migration in carbonate reservoirs and its related cementation dynamics.     

Preservation of Mesoproterozoic age deep burial fluid signatures,NW Scotland

Bedding-parallel fibrous calcite is a widely developed feature of mudrock successions, reflecting conditions of fluid overpressure (Stoneley, 1983, Parnell et al., 2000, Cobbold et al., 2013). The calcite preserves signatures of fluids developed during deep burial, including hydrocarbons. Most studied examples are of Phanerozoic (<540 Ma) age. This study reports well-preserved fibrous calcite in the Mesoproterozoic (∼1180 Ma) Stoer Group, NW Scotland. The fibrous calcite occurs immediately above a unit of carbonaceous black shale. If hydrocarbons were generated from the black shales, they could have contributed to the development of fluid overpressure, but there is no direct evidence for this. The calcite reflects the original deep burial fluid, rather than a later overprint, because (i) it has a distribution related to stratigraphy, (ii) the bedding-parallel fibres have not been recrystallized, and (iii) later veining is at high angles to bedding. The calcite contains fluid inclusions, and has yielded stable isotope and entrained volatile data, indicating the potential to record diagenetic processes over one billion years ago.     

Diagenesis and reservoir properties of Middle Jurassic sandstones,Traill Ø, East Greenland: The influence of magmatism and faulting

The c. 500 m thick Middle Jurassic sandstones of the fluvial Bristol Elv and marine Pelion Formations of the East Greenland Basin are evaluated here in order to improve the understanding of the processes that influenced the diagenetic evolution. The study may help to predict the reservoir properties of sandstones affected by magmatism and faulting, both in general and specifically in undrilled areas on- and offshore East Greenland and, in the Vøring Basin on the Mid-Norwegian shelf. The study shows a variety of authigenic mineral phases dominated by quartz cement, carbonate cement, illite and iron-oxide. One of the clear differences between the two formations is the presence of early carbonate-cemented horizons in the marine sandstones; these horizons are inferred to reflect a primary concentration of biogenic clasts and fossil shells. Intense quartz cementation occurs primarily in the fluvial sandstones but the marine sandstones are also highly quartz-cemented. Two episodes of burial and uplift are recorded in the diagenetic sequence and widespread grain-crushing in coarse-grained intervals is believed to result from overpressure and subsequent compaction due to sudden pressure release along major faults. Maximum burial depths may only have been around 2000–2500 m. Cathodoluminescence analyses show that grain crushing was followed by intense quartz cementation. The quartz cement is to a great deal believed to have formed due to increased surface area from crushing of detrital quartz grains, creating fresh nucleation sites for the quartz. Cathodoluminescence investigations also show that only minor pressure dissolution has taken place between detrital quartz grains and that the ubiquitous quartz cementation displays several growth zones, and was thus in part the result of the introduction of silica-rich extra-formational fluids related to the flow of hot fluids along reactivated faults and increased heat flow and temperature due to magmatism. This interpretation is supported by fluid inclusion homogenization temperatures between 117 and 158 °C in quartz cements. In one of the two study areas, the development of macroscopic stylolites has significantly enhanced quartz cementation, probably in connection with thermal convection flow. As a result of the magmatic and fault-related quartz cementation and illitization, the reservoir quality of the sandstone formations deteriorated and changed drastically.     

Petrological and geochemical constraints on diagenesis and deep burial dissolution of the Ordovician carbonate reservoirs in the Tazhong area,Tarim Basin,NW China

Deeply buried (4500–7000 m) Ordovician carbonate reservoirs in the Tazhong area, Tarim Basin, NW China show obvious heterogeneity with porosity from null in limestones and sweet dolostones to 27.8% in sour dolostones, from which economically important oils, sour gas and condensates are currently being produced. Petrographic features, C, O, Sr isotopes were determined, and fluid inclusions were analyzed on diagenetic calcite, dolomite and barite from Ordovician reservoirs to understand controls on the porosity distribution. Ordovician carbonate reservoirs in the Tazhong area are controlled mainly by initial sedimentary environments and eo-genetic and near-surface diagenetic processes. However, vugs and pores generated from eogenetic and telogenetic meteoric dissolution were observed to have partially been destroyed due to subsequent compaction, filling and cementation. In some locations or wells (especially ZG5-ZG7 Oilfield nearby ZG5 Fault), burial diagenesis (e.g. thermochemical sulfate reduction, TSR) probably played an important role in quality improvement towards high-quality reservoirs. C2 calcite and dolomite cements and barite have fluid inclusions homogenization temperatures (Ths) from 86 to 113 °C, from 96 to 128 °C and from 128 to 151 °C, respectively. We observed petrographically corroded edges of these high-temperature minerals with oil inclusions, indicating the dissolution must have occurred under deep-burial conditions. The occurrence of TSR within Ordovician carbonate reservoirs is supported by C3 calcite replacement of barite, and the association of sulfur species including pyrite, anhydrite or barite and elemental sulfur with hydrocarbon and ¹²C-rich (as low as −7.2‰ V-PDB) C3 calcite with elevated Ths (135–153 °C). The TSR may have induced burial dissolution of dolomite and thus probably improved porosity of the sour dolostones reservoirs at least in some locations. In contrast, no significant burial dissolution occurred in limestone reservoirs and non-TSR dolostone reservoirs. The deeply buried sour dolostone reservoirs may therefore be potential exploration targets in Tarim Basin or elsewhere in the world.     

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.     

Systematic sequence-scale controls on carbonate cementation in a siliciclastic sedimentary basin: Examples from Upper Cretaceous shallow marine deposits of Utah and Coloradao,USA

Whilst the relationship between stratigraphic development and carbonate cementation within siliciclastic succession has been documented through a number case studies, these studies have been generally restricted to observations upon individual sequences and/or limited sub-surface data. In this paper, long-term (5 million years), large-scale (>200 km) stratigraphic controls on carbonate cementation patterns are documented from the Upper Cretaceous Panther Tongue Member, Blackhawk Formation and Castlegate Sandstone exposed in the Book Cliffs in Utah and Colorado, USA. Together, these comprise eight progradational wedges of sandstones, which interfinger with the Mancos Shale, deposited within the Western Interior Seaway foreland basin. Petrographic analyses of ferroan dolomite cement bodies within these sandstone wedges show that the ferroan dolomite cements are all early, relative to burial diagenesis within the host sandstones. Stable isotope analyses indicates that a significant meteoric component was present in precipitating fluids and this is consistent with the observation that cements, are always present down-dip of sequence boundaries and/or leached whitecaps beneath coals. In addition, the lateral distribution of cement bodies increases consistently up-succession from less than 5 km in extent in the older sequences, to 30 km in extent in the youngest sequences. These changes in distribution are in response to the increased progradation and increased and more aerially extensive sequence-boundary development in younger sequences. The implications of these data are that whilst localized spatial patterns of diagenesis, and in particular carbonate cementation, are predictable and controlled by the nature and presence of individual stratal surfaces, systematic diagenetic alteration patterns are also present at the sedimentary basin scale and controlled by the nature of larger-scale stratigraphic development and basin evolution. This evolution may be driven by eustatic shifts, or through tectonic or climatic driven base-level shifts. These observations allow an improved insight into the basin-scale processes that control the macroscopic diagenetic properties of sedimentary successions and sub-surface hydrocarbon reservoirs.     

Development and post-depositional deformation of a Middle Eocene deep-water sandy depositional system in the Sørvestsnaget Basin,SW Barents Sea

Three-dimensional seismic data from the Sørvestsnaget Basin, SW Barents Sea supported by well data, are used to investigate a Middle Eocene deep-water depositional system. The system forms a NNW-oriented sediment accumulation, characterized by increased seismic amplitudes, and abrupt western termination. The data indicate that post-depositional sand remobilization and injection led to formation of sub-circular sediment blocks up to several km wide to the east of the main accumulation. The deep-water depositional system was deformed by wing-like sandstone intrusions, extending 200–400 m upwards from the margins of the parent sand bodies. The intrusions have polygonal or broadly circular plan view geometries. Deformation is inferred to have been associated with overpressure of the sand bodies as a result of rapid burial, fluid migration into the sealed sand bodies from deeper sources via synsedimentary faults, and fluid drainage from the surrounding mudrock during early compaction. The final triggering mechanism for sand remobilization and injection is inferred to have been fracture propagation due to differential compaction and/or fault-induced earthquakes. The injectite complexes are often associated with folding of overlying strata, which we relate to differential compaction. Intrusion of sand took place during the Middle Eocene. Post-depositional sand remobilization and injection have important implications for hydrocarbon exploration because they cause changes in the reservoir primary architecture, connectivity and structure.     

Dolomitic concretions in the Eocene Sobrarbe delta (Spanish Pyrenees): Fluid circulation above a submarine slide scar infilling

Numerous dolomite concretions have been discovered in marls of the Eocene Sobrarbe deltaic complex as part of the Ainsa Basin (Spain). This paper presents the first analyses of the shapes, the spatial relationships, the mineralogical, chemical and isotopic compositions of these concretions.The concretions are located above a major fossil submarine slide scar. They are mainly perpendicular to the sedimentary layers. Four distinct shapes of concretions have been distinguished: horizontal flat, sub-vertical cylindrical or cylindrical-complex and stocky. Three main mineral phases are associated with most of the concretions: calcite, celestite and barite. Concretion shapes and mineral occurrences are organized vertically in the marls from bottom to top: (i) at the bottom, flat shapes with septarian cracks filled by calcite and celestite, (ii) in the middle and at the top, cylindrical and cylindrical-complex concretions associated with prismatic barite, calcite and celestite filling conduits related to bioturbations, and (iii) at the top, cylindrical and cylindrical-complex concretions associated with calcite and celestite filling conduits related to bioturbations, and stocky shape concretions.We postulate that concretions have formed by dolomite cementation of the surrounding marls during early diagenesis in the zone of methanogenesis. The high sedimentation rate of the infilling seems to be a factor controlling the mineralogical composition of the concretions. Brown calcite precipitated in voids and fractures of the concretions. Celestite precipitated during burial, completing the filling of voids and fractures. Barite precipitated before celestite, but its time of precipitation relative to brown calcite remains unknown.