拉拉铜矿含矿岩系地球化学特征及其构造意义

四川会理拉拉铜矿床是我国著名大型富铜矿床,矿床的形成与古元古代河口群海相火山岩密切相关。河口群火山岩除个别样品Nb/Y较低,其他多数样品有一致高的Nb/Y比值(0.7~3.0),属碱性玄武系列;在Nb/Th-Zr/Nb和Zr/Y-Nb/Y图上,HFSE比值成分点主要投在EM1型富集地幔附近,落入洋岛玄武岩(OIB)范围;火山岩较陡的REE分布型式和"驼峰"状微量元素原始地幔标准化分配型式,以及缺乏Nb、Ta负异常,与大陆玄武岩十分吻合;岩石形成于板内裂谷环境。这些地球化学特征表明,河口群火山岩形成于陆间裂谷,来源于地幔深部,指示了矿床的火山喷流沉积成矿作用。同时,岩石大离子元素和轻稀土元素比值不太稳定,变化较大,Eu负异常与蚀变重晶石、萤石和矿化有关,还暗示了岩石遭受了后期变质作用,以及与之有关的矿床变质成矿成因。     

扬子地台西缘河口群钠长岩锆石SHRIMP年龄及岩石地球化学特征

会理拉拉地区是我国著名的铁铜矿区之一,区内前震旦纪河口群是拉拉式铜矿最主要的赋矿岩石。前人利用多种同位素方法对河口群进行过年龄测定,但获得数据差异大,造成河口群在康滇地轴前震旦基底地层划分中存在争议,因而无法约束河口群成岩及变质过程与成矿的关系。通过对河口群钠长岩中的锆石采用高精度SHRIMP U-Pb年代学研究,获得年龄为1 680Ma±13Ma,因而,将河口群归为早元古代晚期。此外,岩石有一致高的Nb/Y比值(0.7～3.0),属碱性玄武系列,在Nb/Th-Zr/Nb和Zr/Y-Nb/Y图上,HFSE比值成分点落入洋岛玄武岩(OIB)范围,具有较陡的REE分布型式和驼峰状微量元素原始地幔标准化分配型式,缺乏Nb,Ta负异常,与大陆玄武岩十分吻合,以及岩石形成于板内裂谷环境,这些地球化学特征表明河口群钠长岩形成于陆间裂谷,来源于地幔深部。     

峨眉山大火成岩省几个典型Ni-Cu-PGE矿床Nd-Os同位素特征——岩石圈参与地幔柱岩浆作用及地壳混染分析

峨眉大火成岩省是我国重要的Cu-Ni-PGE矿床成矿区,典型矿床主要有金宝山铂钯矿、力马河镍矿、朱布(铜镍)铂矿床等 [1～8].这些成矿岩体基本都是小型镁铁-超镁铁质岩体,岩石微量元素地幔标准化曲线均为大陆拉斑玄武岩型式,可与峨眉山玄武岩类比,被认为是峨眉山玄武岩同源岩浆分异的产物 [1～4,9].     

扬子地块北缘西乡群孙家河组火山岩形成时代及元素地球化学研究

西乡群孙家河组为一套低绿片岩相浅变质火山-沉积岩系,主要由基性-中基性-酸性火山岩和凝灰岩、沉凝灰岩、泥岩、硅质岩组成,火山岩岩石类型包括玄武岩、安山岩、英安岩和流纹岩.LA-ICPMS锆石U-Pb定年揭示流纹岩形成时代为832.9±4.9Ma,辉石玄武岩的形成时代为845.0±17Ma,两者在误差范围内一致,属新元古代同期岩浆作用产物.元素地球化学研究表明,孙家河组玄武岩属拉斑玄武岩系列,具有受地壳混染的板内玄武岩的地球化学特点.玄武岩-安山岩-英安岩主量元素成分投点呈规律性变化、REE球粒陨石标准化及微量元素原始地幔标准化分配型式具有一致性并相互重叠,不相容元素Th和相容元素Cr相关模拟图中沿分离结晶线分布,证明玄武岩-安山岩-英安岩为同一基性岩浆分离结晶的产物.REE和微量元素分配型式以及微量元素比值对的显著差异,暗示流纹岩与玄武岩-安山岩-英安岩来源于不同源区.Sr-Nd同位素研究表明,玄武岩-安山岩-英安岩样品的ε_(Nd)(t)值均大于0以及在ε_(Nd)(t)-(~(87)Sr/~(86)Sr)_t图解中位于OIB成分区,表明其源区应为与洋岛玄武岩类似的地幔源区;流纹岩样品具有可与基性熔岩相比拟的ε_(Nd)(t)值,暗示流纹岩最有可能是初生玄武质地壳部分熔融而成.本文所研究的原划孙家河组火山岩系列的形成时代、构造环境的确定以及扬子陆块乃至世界上同一时间内普遍发育大陆裂谷岩浆岩组合的地质事实,说明原划孙家河组以及西乡群中的确存在新元古代的组成部分,它们应是新元古代大陆裂谷的产物,它和扬子地块820M8后造山裂解环境花岗岩均是新元古代晚期Rodinia超大陆裂解作用的岩浆响应.     

柴北缘西端冷湖盐场北山辉长岩地球化学及年代学研究

柴北缘冷湖盐场北山镍铜矿区发育辉长岩和角闪辉长岩;属亚碱性岩石系列。球粒陨石、 原始地幔标准化曲线呈两组特征;但配分型式基本一致;反映其来自同一源区。稀土标准化曲线表现为弱右倾型;Eu基本无异常;说明斜长石分离结晶作用不明显。Rb、 Nb、 Zr、Cr等微量元素丰度及比值具有近似平行部分熔融的演化趋势。结合岩体Mg^#值和岩体固结指数（SI）高等特点;揭示原始岩浆具有幔源原生玄武岩浆特征;认为其成因与俯冲板片流体交代地幔楔源区的部分熔融有关;而且;Nb、 Zr、 Y元素丰度表明辉长岩源区为过渡型地幔。另外;两类岩体强烈亏损Nb、 Ta、 Zr、 Hf、 Ti等高场强元素（HFSE）;富集Ba、 Th、 U、 Pb等大离子亲石元素;反映明显的消减带和岛弧环境岩浆岩典型特征。LA-ICPMS锆石U-Pb测年结果表明辉长岩形成于254±3 Ma;结合该时期区域地质构造背景;认为柴北缘晚二叠世处于俯冲作用之下的岛弧构造环境;具有活动大陆边缘性质。     

羌塘地块南界班公湖-丁青断裂构造带火山岩地球化学及其形成构造环境

利用岩石地球化学的方法，研究了羌塘地块南界班公湖-丁青断裂带中晚中生代火山岩。结果表明，研究区火山岩由拉斑系列大洋玄武岩(MORB)和钙碱性系列岛弧玄武岩(IAB)、玄武安山岩、安山岩、英安岩和流纹岩组成。拉斑系列的洋中脊玄武岩微量元素原始地幔的标准化配分型式，明显不同于N—MORB玄武岩，而具有岛弧型的MORB特征(Ta、Nb的相对亏损)，说明其成因与岛弧环境有一定联系。本区钙碱性系列的岛弧玄武岩(IAB)、安山岩、英安岩和流纹岩在Hacker图解中，微量、稀土元素标准化配分型式上显示出岩浆同源性的特征。通过对研究区内分布的大洋玄武岩、岛弧玄武岩厘定，推断班公湖-丁青缝合带在晚中生代期间可能发育过一个完整的有限洋盆，这将对于进一步研究羌塘地块与其周边各地体的大陆动力学作用过程具有重要意义。     

新疆东准噶尔卡拉麦里蛇绿岩的地球化学特征及大地构造意义

新疆东准噶尔卡拉麦里蛇绿混杂岩的岩石组合为变质橄榄岩、辉长岩、辉绿岩和基性熔岩等.该蛇绿岩中辉长岩的LA-ICP-MS锆石U-Pb年龄(329.9 Ma±1.6 Ma)证明卡拉麦里蛇绿岩的形成时间为早石炭世维宪期.蛇绿岩中辉长岩和基性熔岩REE球粒陨石标准化和微量元素原始地幔标准化分配型式呈平坦型分布,大离子亲石元素丰度低,成分上非常相似于正常的MORB,同时无岛弧及洋岛岩石的地球化学特征,表明该蛇绿岩很可能形成于大洋中脊.结合该区野外地质特征、岩石地球化学和高精度年代学等方面的研究,认为卡拉麦里洋盆形成于泥盆纪初期,最终闭合于旱石炭世谢尔普霍夫期.     

山西新生代汉诺坝玄武岩成因探讨

根据区域地质调查资料,对山西新生代汉诺坝玄武岩的4个火山洼地、7条剖面进行研究。各个火山旋回底部先出现拉斑玄武岩,向上变为碱性玄武岩,岩石均富集大离子亲石元素和轻稀土元素。由东向西,火山喷发时间由早到晚,岩浆活动由弱到强,拉斑玄武岩减少,碱性玄武岩增多,亚碱性玄武岩的稀土元素和微量元素丰度降低,碱性玄武岩的稀土元素和微量元素丰度升高。在原始地幔标准化微量元素蛛网图上,亚碱性玄武岩具Nb、Ta负异常(槽)或呈双峰式,为岛弧玄武岩; 碱性玄武岩呈“隆起”状,类似于洋岛玄武岩(OIB)。山西汉诺坝玄武岩是板块俯冲与地幔柱联合作用的结果,以地幔柱成因为主,板块俯冲成因为辅。亚碱性玄武岩向碱性玄武岩转变,可能代表玄武岩以板块俯冲成因为主转为以地幔柱成因为主; 碱性玄武岩由钾质向钠质变化、亚碱性玄武岩向富铁镁演化,可能分别代表地幔柱向浅、板块俯冲向深的演化过程。     

Petrogenesis and geological implications of the ca.2520Ma gabbroic intrusions in Wutai Mountain of the North China CratoSCIEI北大核心CSCD

本次研究从华北克拉通五台地区基底中识别出一套-25亿年的基性侵入体(主要为岩株)。其中,龙王堂岩株出露面积约5km2,侵入新太古界五台群台怀亚群,岩石类型主要为粗粒辉长岩。一条北东向基性岩墙侵入该岩株,岩墙边部发育明显的冷凝边,岩性为中粒辉长岩。LA-ICP-MS锆石U-Pb同位素年代学分析显示龙王堂粗粒辉长岩岩株形成时代为新太古代晚期(-2520Ma),中粒辉长岩岩墙形成时代为晚三叠世(-230Ma)。锆石原位Lu-Hf同位素分析显示龙王堂岩株具有正的εHf(t)值(4.75-7.95,峰值为6.3),其亏损地幔Hf模式年龄与岩浆年龄接近(tDM=2.64-2.53Ga),指示龙王堂粗粒辉长岩的原始岩浆来自于亏损地幔端元。全岩主微量元素地球化学分析显示龙王堂粗粒辉长岩表现出与洋岛玄武岩(OIB)相似的地球化学特征,并经历了橄榄石和单斜辉石等的结晶分异。结合前人研究成果,本文认为龙王堂新太古代晚期辉长岩岩株与区域上绿岩带(五台群)及同时期花岗侵入体形成时代接近,可能共同指示早期地幔直接分异形成陆壳物质的过程。这可能与俯冲构造体制不同,而与地幔柱作用产生的岩浆特征更为相似。     

布什维尔德杂岩体Platreef矿床与金川铜镍硫化矿床微量元素地球化学特征对比及其意义

采用ICP-MS方法分析了布什维尔德杂岩体Platreef矿床含矿岩石的主量及微量元素含量,并与金川铜镍硫化矿床进行对比研究.Platreef矿床含矿岩石与金川二辉橄榄岩的∑REE接近,球粒陨石标准化后的稀土元素(REE)均表现为轻稀土元素(LREE)富集、重稀土元素(HREE)平坦的右倾型配分曲线,但Platreef含矿岩石总体表现为正Eu异常,金川二辉橄榄岩与矿石样品则大部分表现为较强的负Eu异常,二者的差异实质上反映了成岩矿物斜长石与斜方辉石比率细微的变动.Platreef矿床岩(矿)石富集和高度分异不相容元素,Nb、Ta亏损,显示地幔柱岩浆受到地壳混染后,产生与弧苦橄岩相似的微量元素地球化学特征.金川含矿岩石富集Fe和Ti以及强不相容亲石元素,显示铁质玄武岩微量元素分布特征,虽然也可能受到地壳物质混染,但总体表现出含矿岩体母岩浆则可能来自EMI型富集地幔源区.Platreef矿层原始地幔标准化后Pt、Pd、Ru富集,Ir、Rh相对亏损的PGE配分型式以及Cs、Rb、Th、U、LREE等不相容元素和亲铜元素Cu、Ni的富集.暗示布什维尔德杂岩体岩浆源区残留地幔橄榄岩遭受含高度不相容元素的富矿流体的渗透混染即地幔交代,导致幔源岩浆发生PGE分异.     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

Composition,formation conditions,and genesis of the Talatui gold deposit,the Eastern Transbaikal Region,Russia

The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag₂Te) and matildite (AgBiS₂). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

藏北羌塘丁固—加措地区康托组的时代

自西藏区域地质调查大队创建康托组以来,康托组岩石地层单位广泛应用于羌塘地区,普遍认为其时代为新近纪.笔者于丁固-加措地区的康托组地层中采获古近纪轮藻化石Obtusocharat sp.,O.lanpingenis,Gyrogona qinajiangica和部分孢粉化石,并在康托组底部安山岩中获K-Ar年龄65.1～66.5Ma.上述轮藻组合与同位素年龄指示的地层时代为古新世-始新世,据此将测区康托组的时代确定为古近纪.由于测区康托组之上被唢纳湖组或鱼鳞山组角度不整合覆盖,因此康托组时代的确定不仅进一步完善了测区新生代地层系统,还指示测区在康托组与唢纳湖组或鱼鳞山组之间发生了一次强烈的构造运动.