Magmatic evolution and rare earth element enrichment of Saima alkaline complex,Liaoning, ChinaSCIEI北大核心CSCD

赛马碱性杂岩体位于我国辽东半岛,是一个典型的铀-铌和稀土多金属矿化杂岩体,富含重稀土,其复杂的演化过程和稀土元素富集机制仍没有得到有效约束。本文对该碱性杂岩体中角闪辉石正长岩、正长岩、黑云正长岩、云霓霞石正长岩和异霞正长岩5类岩石及锆石的元素地球化学特征进行了系统研究,并开展了特征矿物包裹体的显微岩相学研究,旨在限定杂岩体母岩浆的演化路径,揭示稀土元素的富集机制。研究结果显示,赛马碱性杂岩体的母岩浆经历了由钾质碱性(角闪辉石正长岩、正长岩和黑云正长岩),到钾质过碱性(云霓霞石正长岩),向钠质过碱性(异霞正长岩)的充分演化。在演化过程中赛马碱性杂岩体母岩浆的体系状态发生了明显变化,碱性岩浆演化受流体不饱和的纯岩浆体系的控制,而过碱性岩浆岩则形成于流体过饱和的岩浆体系,且异霞正长岩母岩浆流体的饱和程度明显高于云霓霞石正长岩的母岩浆。研究还显示,钾质碱性岩浆稀土元素的地球化学行为主要受控于磷灰石等矿物的分离结晶,而成矿的钠质过碱性岩浆稀土、锆和铌等元素的富集成矿则主要受富CO_(2)的高盐度岩浆热液的控制。     

西南三江永平卓潘碱性杂岩体源区与形成机制:全岩元素、锆石U-Pb年代学和Hf同位素联合约束

永平卓潘碱性杂岩体是三江特提斯新生代钾质岩浆带重要组成部分,位于兰坪盆地西缘。岩石类型主要为正长辉石岩、辉石正长岩、正长岩以及少量霞石正长岩。岩石化学性质显示高碱、高K_2O/Na_2O比值、低TiO_2和高Al_2O_3的特征。岩体微量元素显示富集大离子亲石元素(LILE),相对亏损高场强元素(HFSE)元素,特别是"Ta-Nb-Ti"负异常更明显,具有典型俯冲带岩浆的特征。稀土总含量都比较高,LREE富集,HLEE相对亏损,Eu负异常不明显或无Eu负异常,(La/Yb)_N值较大介于38.2～80.3之间。对卓潘岩体的正长岩和正长辉石岩2个样品进行了LA-ICP-MS锆石U-Pb定年,年龄分别为33.40±0.38Ma和34.22±0.33Ma。正长辉石岩εHf(t)值介于-10.6～-4.3之间,二阶段模式年龄在1356～1759Ma之间。卓潘碱性杂岩体不同岩性的稀土元素配分曲线和微量元素原始地幔标准化图解基本一致,表明卓潘碱性杂岩体不同类型的岩石是同源岩浆演化的产物。岩体的Nb/U均值为2.95介于俯冲带流体和全球俯冲沉积物之间以及岩体微量元素明显亏损高场强元素Ti、Nb、Ta,稀土元素表现为轻稀土富集、无或弱的负Ce和负Eu异常,暗示了岩浆源区存在俯冲的洋壳或陆壳沉积物的流体或熔融体与岩石圈地幔的交代富集作用。岩浆源区经历晚石炭世-晚二叠世(305～250Ma)古特提斯昌宁-孟连洋和古特提斯金沙江-哀牢山洋双向俯冲,岩石圈地幔发生富集作用并形成富钾的交代岩石圈地幔。在新生代,新特提斯洋岩石圈从印度大陆岩石圈断离,引发交代富集大陆岩石圈地幔拆沉,热的软流圈上涌,熔融交代的富钾岩石圈地幔,岩浆侵位分异形成卓潘岩体。     

赛马-柏林川碱性杂岩常量组分变异的分离结晶制约

赛马－柏林川碱性杂岩体为侵位于古元古宙与新元古宙之间的缓倾斜岩席状岩体,缓倾的张裂隙制约了分异岩浆的侵位和含矿溶液的流通,交代富集的上地幔产生的富碱岩浆与富集的地壳产生的岩浆以不同比例混合,形成了正长质岩浆和霞石正长质岩浆。含地壳组分较高的正长质岩浆,受富钙辉石、角闪石和镁质较高黑云母的结晶分离制约向硅酸过饱和方向演化;霞石正长质岩浆受富钙辉石—霓辉石、白榴石、含Ｆｅ较高黑云母、黑榴石的分离结晶制约发生分异。稀土元素矿床是霞石正长质岩浆分异残余熔体的产物,侵位于岩体最高层位。     

辽宁赛马碱性岩体层硅铈钛矿化学成分变化及其对碱性岩浆演化的指示意义

辽宁赛马岩体是我国典型的产铀碱性杂岩体,但其稀土矿化机制尚不明确.通过光学显微镜、扫描电镜和电子探针分析,得知该岩体从霞石正长岩经霓霞正长伟晶岩至晚期异霞正长岩,代表性稀土矿物层硅铈钛矿[Na₂Ca₄REETi（Si₂O₇）₂OF_3]不断富集,Nb、Zr和REE（特别是HREE）等高场强元素含量不断升高,部分颗粒具Zr、REE等元素成分环带,以上成分变化与稀土等不相容元素性质、碱性岩浆成分和岩浆结晶分异过程密切相关.此外,层硅铈钛矿经历了一系列的热液蚀变,蚀变部分Ti、Ca、Sr、Na含量增加而Zr、REE含量降低,最终形成由残余层硅铈钛矿+方解石+萤石+铈硅磷灰石组成的假晶,可能与富碱质、F和CO₂的自交代流体作用有关.该研究揭示了碱性岩浆演化过程中,层硅铈钛矿成分变化及热液蚀变组合对指示岩浆结晶分异程度、探究稀土元素分馏及其热液活动性的具有重要意义.      

河北矾山超钾质岩浆氧逸度及含水性特征的磷灰石地球化学记录

产于华北克拉通北缘的晚三叠世矾山超钾质碱性岩杂岩体主要由单斜辉石岩和辉石正长岩等组成,以发育内生磷灰石-磁铁矿矿床而闻名。本文选取矾山杂岩体中的磷灰石为研究对象,通过测试磷灰石的主微量元素及原位Sr-Nd同位素组成以探讨母岩浆的氧逸度及含水性特征。研究表明,矾山磷灰石以轻稀土元素富集、重稀土元素亏损为特征,显示出缺乏显著Ce异常的“右倾”的稀土配分型式,且具有较低的Ga含量及较高的δEu值,暗示杂岩体具有较高的岩浆氧逸度,这也得到了磷灰石Mn氧逸度计的支持。所有磷灰石以高Sr、低Y为特征,具有较高的Sr/Y(>30)和La/Yb(>90)比值,且Sr/Y与La/Yb存在明显的正相关关系,表明矾山超钾质岩浆具有较高的含水量。矾山磷灰石的原位Sr-Nd同位素投点位于地幔序列,明显偏离地壳趋势。母岩浆的“氧化且富水”特征是矾山杂岩体得以发生磷灰石-磁铁矿矿化的重要因素,其主要与板片俯冲过程中蚀变洋壳对岩石圈地幔的交代作用有关。通过对比矾山杂岩体与全球范围内其他地质环境中磷灰石的成分数据,发现具有“高Sr、低F、少Cl”特征的磷灰石可作为识别超钾质碱性岩杂岩体(及其相关金属矿床)的...     

西南三江甭哥金矿床磷灰石地球化学特征及地质意义

甭哥金矿床位于西南三江造山带北段的义敦弧南缘,属于与富碱侵入岩有关的金矿床。目前,对其成矿机理认识仍较为薄弱,制约了资源评价和找矿勘查进展。本文选取甭哥金矿床强矿化的正长斑岩和弱矿化的黑云辉石正长岩中的磷灰石作为研究对象,详细剖析磷灰石的地球化学特征,探讨其记录的成岩成矿信息。结果表明,磷灰石的稀土元素含量特征及配分模式显示富碱岩浆主要来自于壳幔混合的源区,黑云辉石正长岩中磷灰石的(La/Sm)N、(La/Yb)N、(Sm/Yb)N值和Sr含量呈正相关,说明长石结晶对岩浆结晶分异有重要的影响;正长斑岩中磷灰石具有高Sr/Y、Ce/Pb值,而Th/U、(Sm/Yb)N值较低,指示强烈的流体活动参与了岩浆结晶过程;磷灰石挥发分(F、Cl)含量及比值特征指示金矿成矿流体主要来自地幔源区,成矿与富碱、高氯的成矿流体有关。磷灰石Mn氧逸度计估算结果显示,甭哥富碱侵入岩具有高氧逸度特性,但两种不同岩性岩石的氧逸度具有差异性。其中,正长斑岩的logf_(O_2)值为-12～-10. 3,黑云辉石正长岩的logf_(O_2)值为-15. 5～-11. 1,磷灰石中SO_3含量及Ga含量也暗示正长斑岩的氧逸度高于黑云辉石正长岩的特征;结合磷灰石低Mn、Ga含量和高的Cl、SO_3含量,反映甭哥金矿床金的成矿是在高氧逸度条件下金氯络合物迁移、富集而沉淀的结果。因而,磷灰石的地球化学特征对金矿床成矿过程示踪和勘查评价具有重要的指示意义。     

蒙古阿尔泰哈勒赞布勒格泰碱性岩有关的Zr-Nb-Ta-REE矿床地质特征、地球化学与成因初探SCIEI北大核心CSCD

哈勒赞布勒格泰稀有稀土矿床产出于蒙古国阿尔泰地区,是一处与碱性杂岩体有关的超大型Zr-Nb-Ta-REE矿床。该杂岩体具有多期次侵位和多岩相的特征,主要由含钠铁闪石和霓石的碱长正长岩、英碱正长岩、碱长花岗岩、蚀变碱长花岗岩和碱长花岗伟晶岩等组成,并被碱性辉长岩和辉绿岩侵入。其中,蚀变碱长花岗岩发生了全岩Zr、Nb、Ta和REE矿化,并具有广泛的热液交代特征。LA-ICP-MS锆石U-Pb测年显示,该杂岩体中的长英质碱性岩和基性碱性岩具有相似的侵位年龄,均为~400Ma,侵入于~463Ma的黑云母正长花岗岩中。主微量元素地球化学研究显示,该杂岩体具有强过碱性的特征。岩浆演化主要受到碱性长石分异的控制,使硅逐渐聚集于晚期粒间熔体之中,并逐渐演化为英碱正长岩和碱长花岗岩。这个过程使岩浆的过碱性特征不断加强,也使钠铁闪石和霓石逐渐富集。杂岩体的岩浆演化经历了一定程度的锆石、富集稀土的磷灰石、独居石和磷钇矿以及富集Nb的异性石的分异,使Zr、Nb、Ta和REE等成矿元素在岩浆的演化过程中没有得到显著的富集,因此岩浆的演化并非是该杂岩体中稀有稀土元素发生矿化的关键因素。在蚀变碱长花岗岩的石英、碱性长石和钠铁闪石中,普遍发育顺着晶格生长的“雪球状”钠长石,是碱性花岗质共结岩浆演化晚期流体发生周期性饱和并释放,造成Ab周期性过饱和而沉淀的结果。流体的周期性过饱和及释放萃取成矿元素并汇聚于蚀变碱长花岗岩,造成其Zr、Nb、Ta和REE等元素与硅含量相似但未发生蚀变的碱长花岗岩相比富集了近10倍,因此这是发生矿化的根本原因。     

河北承德大庙地区元古代的晚期辉长—苏长岩的岩石特征及其成因

河北承德的大庙斜长岩杂岩体是我国著名的岩体型斜长岩杂岩体,其苏长岩可分为两种类型,即早期苏长岩和晚期辉长—苏长岩。早期苏长岩已发生钠长绿帘角闪岩相变质;晚期辉长—苏长岩变质程度较弱,含有斜长石、斜方辉石和单斜辉石巨晶,主要呈岩墙、岩脉或小岩体侵入于斜长岩杂岩体中,与铁磷矿紧密相关。研究表明:晚期辉长—苏长岩主要由中性斜长石、反条纹长石、单斜辉石、斜方辉石、黑云母、磷灰石、钛磁铁矿和磁铁矿等组成,依矿物含量、成分和结构的差异可分为淡色辉长岩、单斜辉石苏长岩、斜方辉石辉长岩以及含铁磷矿对应岩石。其Ba、Sr和轻稀土富集、Eu弱负异常或无异常特征,表明晚期辉长—苏长岩岩浆不是形成斜长岩的基性岩浆,而是经斜长石分离结晶后的残余岩浆。Sr-Nd-Pb同位素地球化学特征显示晚期辉长—苏长岩可能源自EMI富集的岩石圈地幔,与岩体型斜长岩不存在同源岩浆分离结晶演化的关系。大庙地区晚期辉长—苏长岩的岩浆来源、演化和构造控制的特征对深化研究岩体型斜长岩杂岩体的成因有重要意义。     

赛马—柏林川碱性火山-侵入杂岩体岩浆成因

呈岩席产出的赛马—柏林川碱性火山侵入 杂岩体由正长岩类及响岩霞石正长岩类组成。两类岩浆来源于统一的富集地幔源区。源区中镁铁云母、单斜 辉石等的熔融生成了贫镁铁富碱铝的碱性岩浆。地幔富集作用增强生成正长质岩浆,经一个时期的间隔,从更深位的更加富集的地幔产生了响岩霞石正长质岩浆。 岩浆中有上地壳组分的参予。     

云南永平卓潘碱性杂岩体岩石学和地球化学特征及成因研究

卓潘碱性杂岩体为"三江"地区富碱(高钾)侵入岩的重要组成部分,位于哀牢山-金沙江缝合带的中部,侵位于兰坪盆地南部的白垩系砂岩中,主要由碱性辉长岩、辉石正长岩和霞石正长岩组成。对卓潘碱性杂岩体的岩相学、岩石学、主元素和稀土微量及同位素地球化学特征的系统研究表明,该杂岩体主量元素显示低硅、富钾、高碱(K2O+Na2O为6.92%~13.43%)、低TiO 2(0.31%~1.20%)的特征,属钾质碱性系列岩石;杂岩体的各种岩石均富集Rb、Sr、Ba、Th等大离子亲石元素、亏损Nb、Ta、Ti等高场强元素,并具有轻稀土富集的右倾型稀土元素分布模式、具较高的87Sr/86Sr、206Pb/204Pb、207Pb/204Pb、208Pb/204Pb及较低的143Nd/144Nd等特征,表明源区具有较明显的EMⅡ型富集地幔特征,源区明显受到壳源物质的混染。卓潘岩体形成于印度-欧亚大陆后碰撞的剪切和拉张的构造环境,古扬子板片向西俯冲,诱发了经过陆壳交代混染了的岩石圈地幔的部分熔融。由于兰坪走滑拉分盆地东缘断裂拉伸强度大,岩浆起源的深度大,以及岩浆源区成分(特别是CO2含量)与其它部位不同,因此在卓潘地区形成一套与金沙江-哀牢山-红河断裂带其它新生代富碱斑岩完全不同的过碱性的岩石。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861