Negotiating Indigenous benefits from payment for ecosystem service (PES) schemes

This paper draws on research conducted with Aboriginal land managers across Northern Australia to show how and why payments for ecosystem service (PES) schemes should be framed around Indigenous rights to and relationships with their traditional estates. PES schemes offer opportunities to recognize and support Aboriginal communities' land and sea management knowledge and practices, and there is strong evidence that Indigenous communities are seeking to engage with such schemes. We focus on Aboriginal savanna landscape management, particularly traditional burning practices, to extend the ecosystem services framework to recognize Indigenous values and interactions with their lands as a critical service for Indigenous well-being. Drawing on case-study analysis of PES projects negotiated to support Aboriginal fire management programs across Northern Australia, we show how cultural ecosystem services can be applied to represent the active, dynamic and often interdependent relationships inherent in Indigenous human-environment relationships.     

Potential effect of climate change on observed fire regimes in the Cordilleran forests of South-Central Interior, British Columbia

Climate change is predicted to result in a warmer and drier climate in many parts of the world, including south-central British Columbia. With a shift in climate, a change in fire regimes is likely to occur. In this study, a statistically significant increase in mean fire size was predicted to occur along with an increase maximum fire size and decrease in the mean fire interval. A change in these fire regime characteristics suggests a climate-change driven shift in fire regimes may occur by the 2020s. The shift in fire regime suggests the proportion of the landscape burning every 50 years or less will increase from 34 % to 93 % by the 2080s. Change in fire regimes will have direct implications for ecosystem management as the combination of large, flammable fuel types and fire-prone climatic conditions will increase the risk of larger more frequent fires and increase the costs and dangers involved in managing fire-prone forests in the Cordilleran region of south-central British Columbia. The climate change-driven shift in fire regime questions the use of historic fire regime characteristics for determining landscape-level conservation targets within the study area.     

Methods for exploring management options to reduce greenhouse gas emissions from tropical grazing systems

Increasing atmospheric concentrations of greenhouse gases are expected to result in global climatic changes over the next decades. Means of evaluating and reducing greenhouse gas emissions are being sought. In this study an existing simulation model of a tropical savanna woodland grazing system was adapted to account for greenhouse gas emissions. This approach may be able to be used in identifying ways to assess and limit emissions from other rangeland, agricultural and natural ecosystems.GRASSMAN, an agricultural decision-support model, was modified to include sources, sinks and storages of greenhouse gases in the tropical and sub-tropical savanna woodlands of northern Australia. The modified model was then used to predict the changes in emissions and productivity resulting from changes in stock and burning management in a hypothetical grazing system in tropical northeastern Queensland. The sensitivity of these results to different Global Warming Potentials (GWPs) and emission definitions was then tested.Management options to reduce greenhouse gas emissions from the tropical grazing system investigated were highly sensitive to the GWPs used, and to the emission definition adopted. A recommendation to reduce emissions by changing burning management would be toreduce fire frequency if both direct and indirect GWPs of CO₂, CH₄, N₂O, CO and NO are used in evaluating emissions, but toincrease fire frequency if only direct GWPs of CO₂, CH₄ and N₂O are used. The ability to reduce greenhouse gas emissions from these systems by reducing stocking rates was also sensitive to the GWPs used. In heavily grazed systems, the relatively small reductions in stocking rate needed to reduce emissions significantly should also reduce the degradation of soils and vegetation, thereby improving the sustainability of these enterprises.The simulation studies indicate that it is possible to alter management to maximise beef cattle production per unit greenhouse gases or per unit methane emitted, but that this is also dependent upon the emission definition used. High ratios of liveweight gain per unit net greenhouse gas emission were found in a broadly defined band covering the entire range of stocking rates likely to be used. In contrast, high values of liveweight gain per unit anthropogenic greenhouse gas emission were found only at very low stocking rates that are unlikely to be economically viable.These results suggest that policy initiatives to reduce greenhouse gas emissions from tropical grazing systems should be evaluated cautiously until the GWPs have been further developed and the implications of emission definitions more rigorously determined.     

Aging of savanna biomass burning aerosols: Consequences on their optical properties

During the FOS-DECAFE experiment at Lamto, Ivory Coast, in January 1991, various ground studies were undertaken simultaneously in order to investigate the physical and chemical characteristics of smoke emitted by savanna biomass burning. Here we present sunphotometer ground-based results which allow the measurements of the spectral optical depth between 450 and 850 nm, the atmospheric water vapour content and the particle size distribution spectrum. The carbonaceous content of the savanna biomass burning aerosols is also investigated. This is the first time that the physical characteristics of particles emitted by savanna plumes are obtained from ground-field studies. All the results suggest that a rapid aging of the smoke occurs first hundred metres from the savanna fire èmission source. They show a relationship between the optical properties of smoke and the chemical aging of the aerosols primarily due to particle growth and a loss of organic material relative to the black carbon content.     

Emissions of Polycyclic aromatic hydrocarbons by savanna fires

Although Polycyclic aromatic hydrocarbons (PAH) are known as anthropogenic compounds arising from the combustion or the pyrolysis of fossil fuels, they may be also emitted by the combustion of vegetation. A field study was carried out in January 1991 at Lamto (Ivory Coast) as part of the FOS DECAFE experiment (Fire Of Savanna). Some ground samplings were devoted to the qualitative and quantitative characterization of atmospheric emissions by savanna fires during prescribed burns and under background conditions. Specific collections for gaseous and particulate PAHs have shown that the African practice of burning the savanna biomass during the winter months is an important source of PAHs. These compounds are emitted mainly in gaseous form but a significant fraction, essentially heavy PAHs, is associated with fine carbonaceous particles and can therefore represent a hazard for human health, since some of these compounds are mutagenic and carcinogenic. Twelve compounds were identified during the fire episodes and in the atmospheric background. The total concentration in the fires is of the order of 10 ng m^–3 for the gas phase and from 0.1 to 1 ng m^–3 in the aerosols. In the atmospheric background the mean concentrations are regular, 0.15 ng m^–3 and 2 pg m^–3, respectively. These concentrations are comparable with what is observed in European rural zones. The particulate emissions of PAHs by the savanna fires are distinguished by the abundance of some compounds which can be considered as tracers, although they are also slightly emitted by fossil fuel sources. These compounds are essentially pyrene, chrysene and coronene. In the gas phase, although no individual PAH may be considered as specific of the biomass combustion emissions, the relative abundances of the main PAHs are characteristic of the biomass burning. The concentrations of pyrene and fluorene are always predominant; these compounds could be considered as characteristic emission products of smoldering and flaming episodes, respectively. In the background the PAH composition shows that in a tropical region the air consists of a mixture coming from the various sources, but the biomass combustion is by far the most important source.The fluxes of total PAH emitted by savanna biomass burning in Africa were estimated to be of the order of 17 and 600 ton yr^–1, respectively, for the particulate PAHs and the gaseous PAHs, respectively.     

Interannual climate variation,land type and village livelihood effects on fires in Kalimantan,Indonesia

The increasing extent and frequency of fires globally requires nuanced understanding of the drivers of large-scale events for improved prevention and mitigation. Yet, the drivers of fires are often poorly understood by various stakeholders in spatially expansive and temporally dynamic landscapes. Further, perceptions about the main cause of fires vary amongst stakeholders, which amplify ongoing challenges from policies being implemented inconsistently across different governance levels. Here, we develop a spatially and temporally-explicit typology of fire prevalence across Kalimantan, Indonesia, a region with significant contribution to global greenhouse gas emissions. Based on livelihood information and data on climate, soil type and forest degradation status, we find that in intact forest the density of fires in villages that largely coincide with oil palm concessions was twice as high as in villages outside the concessions across all years. Fires occurring in degraded land on mineral soil across all years were also most prevalent in villages with industrial plantations (oil palm or timber). On the other hand, in degraded peatland, where fires are most intense during dry years induced by the El Niño episodes, occurrence rates were high regardless of village primary livelihoods. Based on these findings we recommend two key priorities for fire mitigation going forward for policy across different governance levels in Kalimantan: degraded peatland as the priority area and industrial plantations as the priority sector. Our study suggests a fire prevention and mitigation approach, which accounts for climate, land type and village livelihood, has the potential to deliver more effective means of management.     

Atmospheric methane budget in Africa

This assessment of the atmospheric methane budget for the African Continent is based on a set of experimental data obtained in tropical Africa including methane emission from various biogenic sources, and biomass burning, and methane consumption in savanna and forest soils. Emission rates from the various sources, uptake rates of soils, and complementary data from the litterature allow calculation of regional methane fluxes by means of different data bases. Biomass burning, animals and natural wetlands are the three dominant sources of methane in Africa while rice paddy fields and termites appear as minor sources. The total methane emission is estimated to be in the range 20–40 MT of CH₄ per year, methane uptake by soils being less than 2 MT per year. Net methane emission from the African continent accounts for less than 10% of global emissions from terrestrial ecosystems.     

Particulate content of savanna fire emissions

As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO₂ real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO₂) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg C_{dry plant} and EF(Ct)=7.4±3.4 and 56±16 g C/kg C_{dry plant} for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions.     

Domestic Combustion of Biomass Fuels in Developing Countries: A Major Source of Atmospheric Pollutants

Biomass burning has important impacts on atmospheric chemistry and climate. Fires in tropical forests and savannas release large quantities of trace gases and particulate matter. Combustion of biofuels for cooking and heating constitutes a less spectacular but similarly widespread biomass burning activity. To provide the groundwork for a quantification of this source, we determined in rural Zimbabwe the emissions of CO₂, CO, and NO from more than 100 domestic fires fueled by wood, agricultural residues, and dung. The results indicate that, compared to open savanna fires, emissions from domestic fires are shifted towards products of incomplete combustion. A tentative global analysis shows that the source strength of domestic biomass burning is on the order of 1500 Tg CO₂–C yr^–1, 140 Tg CO–C yr^–1, and 2.5 Tg NO–N yr^–1. This represents contributions of about 7 to 20% to the global budget of these gases.     

Trace elements in tropical African savanna biomass burning aerosols

As a part of the FOS/DECAFE experiment, aerosol particles emitted during prescribed savanna fires were collected in January 1991 at Lamto (Ivory Coast), either close to the emission or in ambient air. Analytical transmission electron microscopy pointed out the presence of sub-micrometer soots, salt condensates, vegetation relicts and soil derived particles. The samples were also analyzed for their total particulate matter (TPM) content and elemental composition by PIXE or XRF. At the emission, high concentrations of soil derived elements (Fe and Al) pointed out an intense remobilization process during the fires. Biomass burning emissions contributed to more than 90% of the measured concentrations, of P, Cl, S, K, Cu and Zn, which were found primarily in the fine fraction with the exception of P. Near the emission, K was mainly present as KCl, evolving to K₂SO₄ in the ambient samples. Trace elements emission factors were obtained for the first time for the African savanna burning and their annual emissions were estimated: our median K emission factor (0.78 g/kg of C) is higher than estimates for other ecosystems (0.2–0.58 g/kg of C); Zn emissions (0.008 Tg/year) account for 4 to 11% of the global anthropogenic emissions.     

Bottom up approach to estimate air pollution of rice residue open burning in Thailand

Rice residue open burning is a farmer activity potentially contributes to global warming. This study was conducted with the objective of examining the spatial and temporal distribution of emissions from rice residue open burning in Thailand by using questionnaire survey and field experimentation. A sample of 1000 Thai farmers was interviewed in order to study the fire behaviours of farmers. One hundred and twenty rice sampling plots were selected for measuring rice residue characteristics. Of the farmer’s fire behaviour, 45% of farmer regularly uses prescribed burning technique for land preparation activities. The amount of rice residue was approximately 117.7 Mt. Although nearly 60% of total residue was subjected to burning in the fields, only 15% of rice residue is actually burned in the fields because the residue and soil have high moisture content. The burning emissions are computed at 1.67 Mt of CO, 0.04 Mt of NO_x, 0.35 Mt of PM_2.5, 0.12 Mt of PM₁₀, and 0.01 Mt of BC. Approximately 30%, 26%, and 17% of all emissions are contributed by the lower-northern, central, and western regions of Thailand, respectively. Moreover, 31% and 30% of all emissions are annually emitted from December to January and April to May over one month periods following each harvesting season. The comparisons of rice residue burning emissions provided by this study and previous studies have found the emissions discovered in this study to range from one to five times higher than the finding of previous studies. This finding demonstrates the importance of the assessment of activity data specific to farming fire characteristics.     

Local boundary-layer development over burnt and unburnt tropical savanna: an observational study

Fire scars have the ability to radically alter the surface energy budget within a tropical savanna by reducing surface albedo, increasing available energy for partitioning into sensible and latent heat fluxes and increasing substrate heat flux. These changes have the potential to alter boundary-layer conditions and ultimately feedback to local and regional climate. We measured radiative and energy fluxes over burnt and unburnt tropical savanna near Howard Springs, Darwin, Australia. At the burnt site a low to moderate intensity fire, ranging between 1,000 and 3,500 kW m⁻¹, initially affected the land surface by removing all understorey vegetation, charring and blackening the ground surface, scorching the overstorey canopy and reducing the albedo. A reduction in latent heat fluxes to almost zero was seen immediately after the fire when the canopy was scorched. This was then followed by an increase in the sensible heat flux and a large increase in the ground heat flux over the burnt surface. Tethered balloon measurements showed that, despite the presence of pre-monsoonal rain events occurring during the measurement period, the lower boundary layer over the burnt site was up to 2^°C warmer than that over the unburnt site. This increase in boundary-layer heating when applied to fire scars at the landscape scale can have the ability to form or alter local mesoscale circulations and ultimately create a feedback to regional heating and precipitation patterns that may affect larger-scale processes such as the Australian monsoon.     

Indigenous Australians’ knowledge of weather and climate

Although the last 200 years of colonisation has brought radical changes in economic and governance structures for thousands of Aboriginal and Torres Strait Islanders living in remote areas of northern Australia, many of these Indigenous people still rely upon, and live closely connected to, their natural environment. Over millennia, living ‘on country’, many of these communities have developed a sophisticated appreciation of their local ecosystems and the climatic patterns associated with the changes in them. Some of this knowledge is recorded in their oral history passed down through generations, documented in seasonal weather calendars in local languages and, to a limited degree, transcribed and translated into English. This knowledge is still highly valued by these communities today, as it is used to direct hunting, fishing and planting as well as to inform many seasonally dependant cultural events. In recent years, local observations have been recognised by non-Indigenous scientists as a vital source of environmental data where few historic records exist. Similar to the way that phenological observations in the UK and US provide baseline information on past climates, this paper suggests that Indigenous observations of seasonal change have the potential to fill gaps in climate data for tropical northern Australia, and could also serve to inform culturally appropriate adaptation strategies. One method of recording recent direct and indirect climate and weather observations for the Torres Strait Islands is documented in this paper to demonstrate the currency of local observations of climate and its variability. The paper concludes that a comprehensive, participatory programme to record Aboriginal and Torres Strait Islander knowledge of past climate patterns, and recent observations of change, would be timely and valuable for the communities themselves, as well as contributing to a greater understanding of regional climate change that would be useful for the wider Australian population.     

Relative effects of climate change and wildfires on stream temperatures: a simulation modeling approach in a Rocky Mountain watershed

Freshwater ecosystems are warming globally from the direct effects of climate change on air temperature and hydrology and the indirect effects on near-stream vegetation. In fire-prone landscapes, vegetative change may be especially rapid and cause significant local stream temperature increases but the importance of these increases relative to broader changes associated with air temperature and hydrology are not well understood. We linked a spatially explicit landscape fire and vegetation model (FireBGCv2) to an empirical regression equation that predicted daily stream temperatures to explore how climate change and its impacts on fire might affect stream thermal conditions across a partially forested, mountainous landscape in the western U.S. We used the model to understand the roles that wildfire and management actions such as fuel reduction and fire suppression could play in mitigating stream thermal responses to climate change. Results indicate that air temperature increases associated with future climates could account for a much larger proportion of stream temperature increases (as much as 90 % at a basin scale) than wildfire. Similarly, land management scenarios that limited wildfire prevalence had negligible effects on future stream temperature increases. These patterns emerged at broader spatial scales because wildfires typically affected only a subset of a stream’s network. However, at finer spatial and temporal scales stream temperatures were sensitive to wildfire. Although wildfires will continue to cause local, short-term effects on stream temperatures, managers of aquatic systems may need to find other solutions to cope with the larger impact from climate change on future stream warming that involves adapting to the increases while developing broad strategies for riparian vegetation restoration.     

The impact of climate change on the risk of forest and grassland fires in Australia

We explore the impact of future climate change on the risk of forest and grassland fires over Australia in January using a high resolution regional climate model, driven at the boundaries by data from a transitory coupled climate model. Two future emission scenarios (relatively high and relatively low) are used for 2050 and 2100 and four realizations for each time period and each emission scenario are run. Results show a consistent increase in regional-scale fire risk over Australia driven principally by warming and reductions in relative humidity in all simulations, under all emission scenarios and at all time periods. We calculate the probability density function for the fire risk for a single point in New South Wales and show that the probability of extreme fire risk increases by around 25% compared to the present day in 2050 under both relatively low and relatively high emissions, and that this increases by a further 20% under the relatively low emission scenario by 2100. The increase in the probability of extreme fire risk increases dramatically under the high emission scenario by 2100. Our results are broadly in-line with earlier analyses despite our use of a significantly different methodology and we therefore conclude that the likelihood of a significant increase in fire risk over Australia resulting from climate change is very high. While there is already substantial investment in fire-related management in Australia, our results indicate that this investment is likely to have to increase to maintain the present fire-related losses in Australia.     

Exploring CO pollution episodes observed at Rishiri Island by chemical weather simulations and AIRS satellite measurements: long-range transport of burning plumes and implications for emissions inventories

The summer of 2003 was an active forest fire season in Siberia. Several events of elevated carbon monoxide (CO) were observed at Rishiri Island in northern Japan during an intensive field campaign in September 2003. A simulation with a global chemistry-transport model is able to reproduce the general features of the baseline levels and variability in the observed CO, and a source attribution for CO in the model suggests that the contribution from North Asia dominated, accounting for approximately 50% on average, with contributions of 7% from North America and 8% from Europe and 30% from oxidation of hydrocarbons. With consideration of recent emission estimates for East Asian fossil fuel and Siberian biomass burning sources, the model captures the timing and magnitude of the CO enhancements in two pollution episodes well (17 and 24 September). However, it significantly underestimates the amplitude during another episode (11–13 September), requiring additional CO emissions for this event. Daily satellite images from AIRS reveal CO plumes transported from western Siberia toward northern Japan. These results suggest that CO emissions from biomass burning in western Siberia in 2003 are likely underestimated in the inventory and further highlight large uncertainties in estimating trace gas emissions from boreal fires.     

Divergent trends in ecosystem services under different climate-management futures in a fire-prone forest landscape

While ecosystem services and climate change are often examined independently, quantitative assessments integrating these fields are needed to inform future land management decisions. Using climate-informed state-and-transition simulations, we examined projected trends and tradeoffs for a suite of ecosystem services under four climate change scenarios and two management scenarios (active management emphasizing fuel treatments and no management other than fire suppression) in a fire-prone landscape of dry and moist mixed-conifer forests in central Oregon, USA. Focal ecosystem services included fire potential (regulating service), timber volume (provisioning service), and potential wildlife habitat (supporting service). Projections without climate change suggested active management in dry mixed-conifer forests would create more open forest structures, reduce crown fire potential, and maintain timber stocks, while in moist mixed-conifer forests, active management would reduce crown fire potential but at the expense of timber stocks. When climate change was considered, however, trends in most ecosystem services changed substantially, with large increases in wildfire area predominating broad-scale trends in outputs, regardless of management approach (e.g., strong declines in timber stocks and habitat for closed-forest wildlife species). Active management still had an influence under a changing climate, but as a moderator of the strong climate-driven trends rather than being a principal driver of ecosystem service outputs. These results suggest projections of future ecosystem services that do not consider climate change may result in unrealistic expectations of benefits.     

Natural gas and climate finance

Should energy projects to extend the use of natural gas be considered for funding under public climate finance commitments? This article provides an overview of evidence for and against climate finance for natural gas projects. The argument focuses on a case study, the UK’s International Climate Fund (ICF). This synthesis concludes that gas-related projects will rarely be eligible for funding under public climate finance, save a few exceptions in which they provide energy access to households directly. Although gas power plants have generally lower emissions than those which use other fossil fuels such as coal, their impact will depend on the material constraints to calculate emissions reductions, the context of implementation, and the political economy of the target country. Three case studies demonstrate that energy access projects need to be understood as providing a whole range of sustainable benefits, from improving local health to reducing emissions. Overall, gas-related projects are complex interventions that require context-specific knowledge of both the effects of technology and the possible business models that can work in context.

POLICY RELEVANCE

This article investigates whether projects related to natural gas constitute an appropriate use of public climate finance, with a particular focus on the UK’s International Climate Fund. Policy makers in developed countries will decide in the coming years how to use public climate finance; that is, the fraction of overseas development assistance (ODA) for climate change mitigation and adaptation. In the UK, for example, the ICF is the most important instrument to provide climate finance for developing countries. In 2013, the UK set out a clear position ‘to end support for public financing of new coal-fired power plants overseas, except in rare circumstances.’ This ban has fostered debate about whether similar positions should follow for other fossil fuels such as natural gas, specifically in the context of ICF funding. Similar debates are taking place in other countries such as Germany and Norway, and are informing the implementation of international facilities such as the Green Climate Fund.     

秸秆焚烧对区域城市空气质量影响的模拟分析

利用融合火点排放源、人为源和生物源的WRF-Chem(Weather Research and Forecasting Model coupled with Chemistry)模式,模拟2015年9月30日08:00(北京时间)起的72 h发生在淮河流域的一次农作物秸秆大面积露天焚烧过程,研究了农作物秸秆焚烧释放的气态污染物和颗粒物对区域城市空气质量的影响。通过有无火点两组试验分析了此次秸秆焚烧对流域内河南、山东、江苏和安徽四省83座城市CO、PM10(空气动力学当量直径小于等于10μm的颗粒物,即可吸入颗粒物)、PM2.5(空气动力学当量直径小于等于2.5μm的颗粒物,即细颗粒物)和O3浓度的定量影响,结果表明:(1)融合NCAR-FINN(Fire Inventory from NCAR)火点排放资料的WRF-Chem模式较好地再现了此次秸秆焚烧及火点烟羽扩散过程。同时结合EDGAR-HTAP(Emission Database for Global Atmospheric Research on Hemispheric Transport of Air Pollution)人为源和MEGAN(Model of Emission of Gases and Aerosols from Nature)生物源的WRF-FIRE(考虑火点排放试验)对流域内城市大气污染物的模拟效果较为理想,尤其对秸秆焚烧释放的污染物CO、PM10和PM2.5和产生的二次污染物O3浓度的模拟。(2)秸秆焚烧所释放的污染物造成流域内城市一次污染物CO、PM10和PM2.5浓度的增加,火点中心和下风向城市增幅最为明显,最大小时浓度增幅达到3倍标准差。气态污染物CO和相比PM10粒径更小的PM2.5可随风扩散至更远的地区,对城市浓度影响更大。(3)此外,秸秆焚烧也使得火点中心城市和下风向城市二次污染物O3浓度增加,但小时浓度增幅极值区分布在火点下风向烟羽末端太阳光照充足的地区,最大小时浓度增幅接近3倍标准差。秸秆焚烧对区域城市空气质量的影响存在明显的空间分布差异且对城市各大气污染成分的影响也不相同。     

Rainwater Chemistry and Wet Deposition over the Wet Savanna Ecosystem of Lamto (Côte d'Ivoire)

From the IGAC-DEBITS Africa network (IDAF), data sets on precipitation chemistry collected from the ‘wet savanna ecosystem’ site of Lamto (Côte d'Ivoire), are analyzed (1995–2002). Inorganic (Ca^{2 +}, Mg^{2 +}, Na⁺, K⁺, NH₄ ⁺, Cl^?, SO₄ ^{2 ?}, NO₃ ^?) and organic (HCOO^?, CH₃COO^?) ions content were determined using Ion Chromatography. The analyzed 631 rainfall events represent 8420.9 mm of rainfall from a 9631.1 mm total. The precipitation chemistry at Lamto is influenced by four main sources: natural biogenic emissions from savanna soils (NO _x and NH₃), biomass burning (savanna and domestic fires), terrigeneous particles emissions from dry savanna soils, and marine compounds embedded in the summer monsoon. The inter-annual variability of the weighted volume mean concentration of chemical species linked with wet deposition fluctuates by ～ 20% over the period. Ammonium concentration is found to be the highest (17.6 μ eq.l^{? 1}) from all IDAF sites belonging to the West Africa ecosystems. Ammonia sources are from domestic animals, fertilizers and biomass burning. In spite of the high potential acidity of 30.5 μ eq.l^{? 1} from NO₃ ^?, SO₄ ^{2 ?}, HCOO^? and CH₃COO^?, a relatively weak acidity is measured: 6.9 μ eq.l^{? 1}. The 40% acid neutralization is explained by the acid gas – alkaline soil particles interaction. The remaining neutralization is from inclusion of gaseous ammonia. When results from Lamto, are compared with those from Banizoumbou (dry savanna) and Zoetele (equatorial forest), a regional view for wet tropospheric chemistry processes is obtained. The high concentration of the particulate phase in precipitation emphasizes the importance of multiphases processes between gases and particles in the atmospheric chemistry of the West Africa ecosystems. For example, the nss Ca^{2 +} precipitation content, main indicator of terrigeneous particles, goes from 30.8 μ eq.l^{? 1} in dry savanna to 9.2 μ eq.l^{? 1} at Lamto and 8.9 μ eq.l^{? 1} in the Cameroon forest. A similar gradient is obtained for rainfall mineral particles precipitation content with contribution of 80% in dry savanna, 40% in wet savanna, and 20% in the equatorial forest.