A methodological approach for estimating turbidity in a river

During the operations of purging and disposal of sediments of a reservoir it is necessary to know the values of turbidity in the river downstream in natural condition,in the absence of dams or river training works.The paper shows that under these conditions the ratio of the average values of sediment discharge to the annual maximum value of water discharge is a function of the average annual turbidity.Turbidity can be considered as representative synthetic index of the climatic conditions,the lithological features and the land cover of the basin,and the geometric characteristics of the river network.The proposed relationship of sediment discharge as a function of water discharge were validated on the basis of data collected from different Italian regions that have very different morphological,geo-lithological and rainfall features and that are characterised by a basin area changing between a few dozen and thousands of square kilometres.The results can be considered satisfying.     

Magnetic Field Feedback Circuit for Geomagnetic Field Compensation Control

In the current state of geomagnetic instrument testing, some aspects of geomagnetic instrument performance are difficult to test in the laboratory. If laboratory test results are inadequate, the instrument will have multiple problems while operating in the field, where a geomagnetic instrumentation test platform with a stable natural magnetic field is critical. Here, the magnetic field feedback circuit for geomagnetic field compensation control is studied in detail. That is, the magnetic field measured by the feedback magnetic sensor and the required working magnetic field are compared as input to the system, and the electric signal is transmitted to the feedback coil through an analog circuit to form a closed loop control, which provides compensation to control the magnetic field. Compared with the existing magnetic shielding method, the analog control circuit can achieve the realization of any working magnetic field, and it is not limited to a null magnetic field. The experimental result shows that the system compensates the earth''s magnetic field of 10,000nT with an average error of 10.6nT and average compensation error of 0.106%, providing a high compensation accuracy. The system also shows high sensitivity and excellent stability. The feedback circuit has achieved effective compensation control for the earth''s magnetic field.     

Artificially triggered lightning and its characteristic discharge parameters in two severe thunderstorms

The lightning-induced-damages in the mid-latitude regions are usually caused during severe thunder-storms. But the discharge parameters of natural lightning are difficult to be measured. Five lightning flashes have been artificially triggered with the rocket-wire technique during the passage of two severe thunderstorms. The discharge current and close electric field of return stroke in artificially triggered lightning have been obtained in microsecond time resolution by using current measuring systems and electric field change sensors. The results show that the five triggered lightning flashes include 1 to 10 return strokes, and the average return stroke current is 11.9 kA with a maximum of 21.0 kA and a mini-mum of 6.6 kA, similar to the subsequent return strokes in natural lightning. The half peak width of the current waveform is 39 μs, which is much larger than the usual result. The peak current of stroke Ip (kA) and the neutralized charge Q(C) has a relationship of Ip = 18.5Q0.65. The radiation field of return stroke is 5.9 kV·m-1 and 0.39 kV·m-1 at 60 m and 550 m, respectively. The radiation field decreases as r -1.119 with increase of horizontal distance r from the discharge channel. Based on the well-accepted transmission line model, the speed of return stroke is estimated to be about 1.4×108 m·s-1, with a variation range of (1.1―1.6)×108 m·s-1. Because of the similarities of the triggered lightning and natural lightning, the results in this article can be used in the protection design of natural lightning.     

用氚讨论中国西部新疆干旱区的水循环率

Tritium concentrations are used to trace water circulation in the Urumqi and Turfan basins in the Xinjiang, western China. Tritium analyses were made for 77 water samples of river waters, groundwaters, spring waters, lake waters and glacier ice collected in summers in 1992 and 1994. The tritium concentrations in the waters are in a wide range from 0 to 125 TU, most of which are considerably high compared with those of most waters in Japan, because tritium levels in precipitation in the area are over ten times as high as those in Japan. River waters originating in glacier regions contain melt glacier, the proportion of which is over 0.5 to river water. The mean resi-dence time of circulating meteoric water in the mountain regions is estimated to be about 15 years. Most groundwaters and spring waters in the flat regions are mainly derived from river waters originating in glacier regions. The groundwater of greatest tritium concentrations in wells in Urumqi City is derived from Urumqi River about 25 years ago. It takes several ten years for river water to pass the underground to many springs. Some groundwaters and spring waters have taken a long time more than 40 years to travel under the ground. Enrichment of tritium in lake water by evaporation is considered to estimate the contribution of groundwater flow to the recharge of lake. Various contributions of groundwater to lakes are inferred for the various type of salinity in closed or semi-closed lakes. The inflow rates of groundwater to salt lakes are small as against fresh water lakes.     

Hydrologic separation and their contributions to N loss in an agricultural catchment in hilly red soil region

The impacts of hydrological processes on N loss is of great value to understand the N transport at catchment scale,which is far from clear. Rainfall, soil water, groundwater and stream water and their N concentrations were monitored from March 2017 to February 2018 in Sunjia agricultural catchment of the red soil critical zone. Objectives of this study were:(1) to determine the dynamics of N concentration of different waters and their N loads;(2) to assess their contributions to N load of streamflow in the paddy and upland mixed agricultural catchment. Our results showed that the N concentrations of soil water(4.8 mg L~(-1)) and groundwater(6.0 mg L~(-1)) were the highest, approximately 2 to 5 times higher than those of stream water(2.7 mg L~(-1)), rain water(1.7 mg L~(-1)) and irrigation water(1.2 mg L~(-1)). The N net loss of the catchment(38.2 kg ha~(-1) yr~(-1))accounted for 15% of the total fertilizer N input. Rainy season(April–June) was a high-risk period of N loss, contributing to more than one third of the total annual loss amount. Using end-member mixing analysis model(EMMA), we found groundwater(whose discharge accounted for 25% of the catchment streamflow) was an important source for the N loss in the agricultural catchment. Even in this catchment with coexisting upland and paddy field ecosystems, identified end-members could be used to predict the N load well(R~20.87, p0.001). These results can deepen our understanding of the relationship between hydrological process and N transport in the red soil critical zone and are also helpful to improve the water and fertilizer management in subtropical agricultural catchment.     

Highlights of Recent Scientific Earthquake Hazard Mitigation

Earthquakes are a serious natural disaster faced by countries all over the world. Research on earthquake hazard mitigation are important parts of earthquake science and is a feature of China''s development of earthquake science. In recent years, the Ministry of Science and Technology (MOST) of the People''s Republic of China, the National Natural Science Foundation of China (NSFC) and the China Earthquake Administration (CEA) have attached great importance to basic research on earthquake hazard mitigation, and new opportunities and challenges have emerged. This paper collects the applications and approvals of the National Key R&D Program and the NSFC projects undertaken by the research institutes of the CEA system in recent years. The CEA system has received funding in the 13th “Five-year Plan” for “Monitoring, Early Warning and Prevention of Major Natural Disaster”. The implementation of these projects is expected to provide support for the basic science and applied research of the CEA system. In the NSFC, the number of applications from the CEA system is relatively stable, and the funding rate is slightly higher than the average for the department of earth science. Although no detailed statistical analysis has been performed, the CEA system still has room for improvement in the application of talent and major programs. I hope that the brief review of new opportunities that have arose in recent years described in this article can provide some background and new thinking for future challenges.     

A hydrochemical study of the Hammam Righa geothermal waters in north-central Algeria

This study focuses on the hydrochemical characteristics of 47 water samples collected from thermal and cold springs that emerge from the Hammam Righa geothermal ?eld, located in north-central Algeria. The aquifer that feeds these springs is mainly situated in the deeply fractured Jurassic limestone and dolomite of the Zaccar Mount. Measured discharge temperatures of the cold waters range from 16.0 to 26.5 °C and the hot waters from 32.1 to 68.2 °C. All waters exhibited a near-neutral p H of 6.0–7.6. The thermal waters had a high total dissolved solids(TDS) content of up to 2527 mg/l, while the TDS for cold waters was 659.0–852.0 mg/l. Chemical analyses suggest that two main types of water exist: hot waters in the up?ow area of the Ca–Na–SO_4type(Hammam Righa) and cold waters in the recharge zone of the Ca–Na–HCO_3type(Zaccar Mount). Reservoir temperatures were estimated using silica geothermometers and?uid/mineral equilibria at 78, 92, and 95 °C for HR4, HR2,and HR1, respectively. Stable isotopic analyses of the δ~(18)O and δD composition of the waters suggest that the thermal waters of Hammam Righa are of meteoric origin. We conclude that meteoric recharge in?ltrates through the fractured dolomitic limestones of the Zaccar Mount and is conductively heated at a depth of 2.1–2.2 km. The hot waters then interact at depth with Triassic evaporites located in the hydrothermal conduit(fault), giving rise to the Ca–Na–SO_4water type. As they ascend to the surface,the thermal waters mix with shallower Mg-rich groundwater, resulting in waters that plot in the immature water?eld in the Na–K–Mg diagram. The mixing trend between cold groundwaters from the recharge zone area(Zaccar Mount) and hot waters in the up?ow area(Hammam Righa) is apparent via a chloride-enthalpy diagram that shows a mixing ratio of 22.6 \ R \ 29.2 %. We summarize these results with a geothermal conceptual model of the Hammam Righa geothermal ?eld.     

Theory and Method for Identifying Well Water Level Anomalies in a Groundwater Overdraft Area

The overexploitation of underground water leads to the continuous drawdown of groundwater levels, change of water quality and dry-up in dynamic water level observation wells. Due to land subsidence, the well pipes uplift and the observation piping systems are damaged. These environmental geology problems can present serious difficulties for the identification of earthquake anomalies by groundwater level observation. Basied on hydrogeological theories and methods, the paper analyzes the relations of the water balance state of aquifers with stress-strain conditions and the water level regime, and then discusses preliminarily the theory and method for identifying well water level anomalies in a groundwater overdraft area. The result shows that we can accurately judge the nature of the anomaly according to the diffusion character of the drawdown funnel in the well area in combination with the aforementioned theory and method and multi-year variation patterns obtained from existing data. The results of the research are helpful for distinguishing the influence of single centralized water pumping from the long-term overdraft of water on the water level, correctly recognizing water level anomalies in the groundwater overdraft area and increasing the level of earthquake analysis and prediction.     

Experiments on Exploration of Shallow Fine Structures and the Construction of the 1-D Velocity Model in the Pingtan Island, Fujian

112 short-period seismographs were set up in the 400km² area of Pingtan Island and its surrounding areas in Fujian. The combined observations of the airgun source and ambient noise source were carried out using a dense array to receive the 387 airgun signals excited around the island and one month of continuous ambient noise recording. The 1-D P-wave and S-wave shallow velocity model of Pingtan Island is obtained by the inversion of the airgun body wave''s first arrival time data, and the reliability of the velocity model is verified by using the surface wave phase velocity dispersion curve, which can provide initial model for subsequent 3-D imaging. The experimental results show that this experiment is a successful demonstration of local scale green non-destructive detection, which can provide basic data for shallow surface structure research and strong vibration simulation of the Pingtan Island.     

Delayed response model for bankfull discharge predictions in the Yellow River

Delayed response means that channels cannot achieve a new equilibrium state immediately following disruption;the channel requires a response time or relaxation time to reach equilibrium.It follows that the morphological state of fluvial system represents the cumulative effects of all previous disturbances and environmental conditions.A unique feature of the delayed response model for bankfull discharge is that the model is capable of representing the cumulative effects of all previous flow conditions when applied to predict the path/trajectories of bankfull discharge in response to altered flow regimes.In this paper,the delayed response model was modified by readjusting the weight for the initial boundary conditions and introducing a variableβwith respect to time.The modified model was then applied to the bankfull discharge calculations for three selected river reaches of the Yellow River,with each reach having different geomorphic settings and constraints. Results indicated that the modified model can predict accurately the bankfull discharge variation in response to changes in flow discharge and sediment load conditions that have been dramatically altered in the past.Results also demonstrated the strong dependence of current bankfull discharge on the previous years’ flow conditions,with the relaxation time varied from 2 to 14 years,meaning that the bankfull discharge was not only affected by the flow discharge and sediment load in the current year,but also by those in previous 1 to 13 years.Furthermore,the relaxation time of bankfull discharge adjustment was inversely proportional to the long-term average suspended sediment concentrations,and this may be explained by fact that high sediment concentrations may have a high potential to perform geomorphic work and there is more sediment readily available to shape the channel boundary and geometry.     

Potential Occurrence of MTBE and BTEX in Groundwater Resources of Amman–Zarqa Basin,Jordan

This study investigates potential occurrence, distribution, and sources of the newly added gasoline oxygenate, methyl‐tert‐butyl ether (MTBE) and the petroleum derivatives benzene, toluene, ethylbenzene, and xylenes called collectively, BTEX, in Jordan's heavily populated Amman–Zarqa Basin (AZB). It presents the first data on the levels of MTBE and BTEX in the aquifers of this basin. One hundred and seventy‐nine (179) groundwater wells were sampled near petrol service stations, oil refinery storage tanks, car wrecks, bus stations, and chemical industries at different locations in the basin. Headspace GC and purge and trap GC–MS were utilized to determine the target substances in the samples. Concentrations of BTEX varied between no‐detection (minimum) for all of them to 6.6 µg/L (maximum) for ethylbenzene. MTBE was found in few samples but none has exceeded the regulated levels; its concentrations ranged between no‐detection to 4.1 µg/L. However, though the contamination levels are very low they should be considered alarming.     

Land Application of Sulfate Salts for Enhanced Natural Attenuation of Benzene in Groundwater: A Case Study

Sulfate reducing conditions are widely observed in groundwater plumes associated with petroleum hydrocarbon releases. This leads to sulfate depletion in groundwater which can limit biodegradation of hydrocarbons (usually benzene, toluene, ethylbenzene, xylenes [BTEX] compounds) and can therefore result in extended timeframes to achieve groundwater cleanup objectives by monitored natural attenuation. Under these conditions, sulfate addition to the subsurface can potentially enhance BTEX biodegradation and facilitate enhanced natural attenuation. However, a delivery approach that enables effective contact with the hydrocarbons and is able to sustain elevated and uniform sulfate concentrations in groundwater remains a key challenge. In this case study, sulfate addition to a groundwater plume containing predominantly benzene by land application of agricultural gypsum and Epsom salt is described. Over 4 years of groundwater monitoring data from key wells subjected to pilot‐scale and site‐wide land application events are presented. These are compared to data from pilot testing employing liquid Epsom salt injections as an alternate sulfate delivery approach. Sulfate land application, sulfate retention within the vadose zone, and periodic infiltration following ongoing precipitation events resulted in elevated sulfate concentrations (>150 mg/L) in groundwater that were sustained over 12 months between application events and stimulated benzene biodegradation as indicated by declines in dissolved benzene concentration, and compound‐specific isotope analysis data for carbon in benzene. Long‐term groundwater benzene concentration reductions were achieved in spite of periodic rebounds resulting from water table fluctuations across the smear zone. Land application of gypsum is a potentially cost‐effective sulfate delivery approach at sites with open, unpaved surfaces, relatively permeable geology, and shallow hydrocarbon impacts. However, more research is needed to understand the fate and persistence of sulfate and to improve the likelihood of success and effectiveness of this delivery approach.     

Glutamic Acid Modified Fenton System for Degradation of BTEX Contamination

The present study employed a modified Fenton system that aims to extend the optimum pH range towards neutral conditions for studying the oxidation of benzene, toluene, ethyl benzene, xylenes (BTEX) using glutamic acid (Glu) as an iron chelator. Addition of 20 mM Glu greatly enhanced the oxidation rate of BTEX in modified Fenton system at pH 5–7. A rapid mass destruction (>97% after 1 h) of BTEX as a water contaminant carried out in the presence of 500 mM H₂O₂, 10 mM Fe²⁺, and 20 mM Glu at pH 5 could be shown. The efficiency of this modified Fenton's system for mass destruction of BTEX in contaminated water was measured to estimate the impact of the major process variables that include initial concentrations of soluble Fe, H₂O₂, Glu (as metal chelating agent), and reaction time.     

Used Motor Oil as a Source of MTBE, TAME, and BTEX to Ground Water

Methyl tert-butyl ether (MTBE), the widely used gasoline oxygenate, has been identified as a common ground water contaminant, and BTEX compounds (benzene, toluene, ethylbenzene, and xylenes) have long been associated with gasoline spills. Because not all instances of ground water contamination by MTBE and BTEX can be attributed to spills or leaking storage tanks, other potential sources need to be considered. In this study, used motor oil was investigated as a potential source of these contaminants. MTBE in oil was measured directly by methanol extraction and gas chromatography using a flame ionization detector (GC/FID). Water was equilibrated with oil samples and analyzed for MTBE, BTEX, and the oxygenate tert-amyl methyl ether (TAME) by purge- and-trap concentration followed by GC/FID analysis. Raoult's law was used to calculate oil-phase concentrations of MTBE, BTEX, and TAME from aqueous-phase concentrations. MTBE, TAME, and BTEX were not detected in any of five new motor oil samples, whereas these compounds were found at significant concentrations in all six samples of the used motor oil tested for MTBE and all four samples tested for TAME and BTEX. MTBE concentrations in used motor oil were on the order of 100 mg/L. TAME concentrations ranged from 2.2 to 87 mg/L. Concentrations of benzene were 29 to 66 mg/L, but those of other BTEX compounds were higher, typically 500 to 2000 mg/L.     

Tidal influence on BTEX biodegradation in sandy coastal aquifers

A numerical study was conducted to investigate the influence of tides on the fate of terrestrially derived BTEX discharging through an unconfined aquifer to coastal waters. Previous studies have revealed that tide-induced seawater circulations create an active salt–freshwater mixing zone in the near-shore aquifer and alter the specific subsurface pathway for contaminants discharging to the coastal environment. Here the coupled density-dependent flow and multi-species reactive transport code PHWAT was used to examine the impact of these tidal effects on the aerobic biodegradation of BTEX released in a coastal aquifer and its subsequent loading to coastal waters. Simulations indicated that tides significantly enhance BTEX attenuation in the near-shore aquifer. They also reduce the rate of chemical transfer from the aquifer to the ocean and exit concentrations at the beach face. For the base case consisting of toluene transport and biodegradation, 79% of toluene initially released in the aquifer was attenuated prior to discharge with tides present, compared to only 1.8% for the non-tidal case. The magnitude of tidal forcing relative to the fresh groundwater flow rate was shown to influence significantly the extent of biodegradation as it controls the intensity of salt–freshwater mixing, period of exposure of the contaminant to the mixing zone and rate of oxygen delivery to the aquifer. The oxygen available for biodegradation also depends on the rate at which oxygen is consumed by natural processes such as organic matter decomposition. While simulations conducted with heterogeneous conductivity fields highlighted the uncertainties associated with predicting contaminant loadings, the study revealed overall that BTEX may undergo significant attenuation in tidally influenced aquifers prior to discharge.     

A Modified Radial Diagram Approach for Evaluating Natural Attenuation Trends for Chlorinated Solvents and Inorganic Redox Indicators

Selection of monitored natural attenuation as a ground water remedy requires that sound scientific documentation clearly illustrating the effectiveness of this remedial alternative be presented to regulatory agencies and concerned citizens. An innovative radial diagram approach is applied to illustrate natural attenuation trends for total benzene, toluene, ethylbenzene, and xylenes (BTEX) and chlorinated ethenes at a former fire training area at Pittsburgh Air Force Base, New York. A BTEX-CAH (chlorinated aliphatic hydrocarbons) radial diagram map shows that concentrations of site contaminants are generally decreasing along the primary flowpath downgradient from the source area. This radial diagram map also suggests that there is a spatial correlation between decreasing CAH parent compound concentrations and increasing or stable daughter product concentrations. This provides secondary evidence of intrinsic biodegradation of TCE downgradient from the source area. A SEQUENCE-Redox™ map suggests that there is a spatial correlation between trends in electron acceptor and metabolic byproduct concentrations, and the decline in total BTEX concentrations downgradient from the source area. This correlation provides secondary evidence for the intrinsic biodegradation of total BTEX in the aquifer. This study demonstrates that radial diagram visual aids can provide a clear and efficient approach for documenting natural attenuation lines of evidence, as an alternative or a complement to using multiple contour maps, tabulated data, or log-linear plots.     

Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

A Practical Approach to the Design, Monitoring, and Optimization of In Situ MTBE Aerobic Biobarriers

A paradigm for the design, monitoring, and optimization of in situ methyl tert -butyl ether (MTBE) aerobic biobarriers is presented. In this technology, an oxygen-rich biologically reactive treatment zone (the "biobarrier") is established in situ and downgradient of the source of dissolved MTBE contamination in groundwater, typically gasoline-impacted soils resulting from leaks and spills at service station sites or other fuel storage and distribution facilities. The system is designed so that groundwater containing dissolved MTBE flows to, and through, the biobarrier treatment zone, ideally under natural gradient conditions so that no pumping is necessary. As the groundwater passes through the biobarrier, the MTBE is converted by microorganisms to innocuous by-products. The system also reduces concentrations of other aerobically degradable chemicals dissolved in the groundwater, such as benzene, toluene, xylenes, and tert -butyl alcohol. This design paradigm is based on experience gained while designing, monitoring, and optimizing pilot-scale and full-scale MTBE biobarrier systems. It is largely empirically based, although the design approach does rely on simple engineering calculations. The paradigm emphasizes gas injection–based oxygen delivery schemes, although many of the steps would be common to other methods of delivering oxygen to aquifers.     

Factors contributing to nitrate contamination in a groundwater recharge area of the North China Plain

Nitrate contamination is a common problem in groundwater of the North China Plain (NCP) owing to overuse of fertilizers and discharge of wastewater. Accordingly, it is important to investigate nitrate contamination in recharge areas to understand the fate of nitrate in the plains area. In this study, the spatial and temporal distribution characteristics of nitrate and factors contributing to its sources and transformation in shallow groundwater of the Beiyishui River watershed, NCP, were analysed by a combination of multiple regression and multi‐tracer methods. The nitrate concentration of 79% of the samples exceeded the natural environmental standard of 13.3 mg l^?1, while that of 23% of the samples exceeded the World Health Organization (WHO) drinking water standard of 50 mg l^?1. Groundwater age estimation of the hill regions based on chlorofluorocarbons (CFCs) revealed a mix of young water from 1982 to 1990 and old, low CFC water. The analysis based on the variations in land use in past years revealed that part of the grassland was converted into woodland between 1980 and 1995; therefore, the land use at the recharge time was used to determine which surface conditions influence groundwater nitrate concentrations. Multiple regression analysis showed that point source pollution contributed to the high concentration of nitrate in the hill region. Fertilizer application associated with land use change from grassland to woodland was also related to the present nitrate concentration. In the plains area, the contribution of fresh water from fault fractures and denitrification led to 31 to 72% and 6 to 51% reductions in nitrate concentrations, respectively. Our results suggested that controlling point source contamination and fertilizer input to hilly regions of the study will prevent groundwater of the plains area from deterioration in future years by mixing fresh water into the aquifers and decreasing denitrification, and therefore nitrate concentrations. Copyright © 2015 John Wiley & Sons, Ltd.     

Enhancement of In Situ Bioremediation of BTEX-Contaminated Ground Water by Oxygen Diffusion from Silicone Tubing

A field study of oxygen-enhanced biodegradation was carried out in a sandy iron-rich ground water system contaminated with gasoline hydrocarbons. Prior to the oxygen study, intrinsic microbial biodegradation in the contaminant plume had depleted dissolved oxygen and created anaerobic conditions. An oxygen diffusion system made of silicone polymer tubing was installed in an injection well within an oxygen delivery zone containing coarse highly permeable sand. During the study, this system delivered high dissolved oxygen (DO) levels (39 mg/L) to the ground water within a part of the plume. The ground water was sampled at a series of monitors in the test zone downgradient of the delivery well to determine the effect of oxygen on dissolved BTEX, ground water geochemistry, and microbially mediated biodegradation processes. The DO levels and Eh increased markedly at distances up to 2.3 m (7.5 feet) downgradient. Potential biofouling and iron precipitation effects did not clog the well screens or porous medium. The increased dissolved oxygen enhanced the population of aerobes while the activity of anaerobic sulfate-reducing bacteria and methanogens decreased. Based on concentration changes, the estimated total rate of BTEX biodegradation rose from 872 mg/day before enhancement to 2530 mg/day after 60 days of oxygen delivery. Increased oxygen flux to the test area could account for aerobic biodegradation of 1835 mg/day of the BTEX. The estimated rates of anaerobic biodegradation processes decreased based on the flux of sulfate, iron (II), and methane. Two contaminants in the plume, benzene and ethylbenzene, are not biodegraded as readily as toluene or xylenes under anaerobic conditions. Following oxygen enhancement, however, the benzene and ethylbenzene concentrations decreased about 98%, as did toluene and total xylenes.