Low-grade blueschist facies metamorphism of metagreywackes, Franciscan Complex, northern California

Abstract Metagreywackes in the Eastern Belt of the Franciscan Complex contain the assemblage: Qtz + Ab + Lws + Chl + Ph + Pmp + Fgl + Hem ° Cal/Arg or compatible subassemblages. Blue amphibole first appears in the westernmost part of the belt and pumpellyite is absent in the eastern part. The compositions of the coexisting minerals and the nature of the continuous reactions in these low-grade blueschists suggest that the distribution of blue amphibole and pumpellyite in the Eastern Belt of the Franciscan Complex reflects differences of effective bulk composition rather than differences in physical conditions of metamorphism. In rocks lacking pumpellyite, white mica may be essential to the growth of blue amphibole, but carbonate plays only a limited role. The continuous reaction that limits the appearance of blue amphibole and the disappearance of coexisting pumpellyite has the general form: Pmp + Chl + Ab + Qtz + Hem + H₂O + FeMg_-1= Fgl + Lws. This reaction requires significant hydration as pressure increases in order to produce blue amphibole. Most of the Eastern Belt of the Franciscan Complex formed in limited ranges of temperature and pressure, which are estimated to be 240—280° C, 6.5-7.5 kbar. Pressures in the westernmost part of the area were about 1 kbar lower than in the east. Pressures of about 8.5-10 kbar are estimated for tectonic blocks that contain sodic clinopyroxene.     

New evidence for polyphase metamorphism of glaucophane schist and eclogite exotic blocks in the Franciscan Complex, California and Oregon

ABSTRACT The early metamorphic history of high-grade exotic blocks in the Franciscan Complex may be more complicated than previously supposed. The different assemblages of high-grade glaucophane schist, eclogite, amphibolite and hornblende schist are commonly considered to have formed at the same time from essentially unmetamorphosed oceanic crust. However, new textural and mineralogical data presented here suggest that high-grade glaucophane schist and eclogite have replaced an earlier epidote-amphibolite facies assemblage that is identical to the primary assemblages in many of the hornblende-rich blocks. At least some of the hornblende-rich blocks may therefore be well-preserved remnants of the earlier metamorphism. Comparison of the mineral assemblages and element partitioning in the mixed-assemblage blocks suggests that the glaucophane schist and eclogite metamorphism took place at slightly lower temperatures but at the same or higher pressures than the earlier, hornblende-forming stage.     

Franciscan Complex olistostrome at Crescent City, northern California

An olistostrome and bounding turbidites are exposed within the late Mesozoic Franciscan Complex along the Crescent City (California) coastline. Facies grade in character from Mutti & Ricci Lucchi (1978) mixed facies B, C and D, to F (the olistostrome), to mixed A, B and E, progressing upwards within the Franciscan stratigraphic section. The facies F unit outcrop is up to 600 m thick and extends 12 km along strike. It consists of oblate to tabular blocks, up to 200 m in maximum dimension, of greenstone, tonalite, radiolarian chert, limestone, phyllite and greywacke dispersed in a scaly argillite matrix. The olistostromal origin of the unit is indicated by depositional contacts with bounding turbidites, by the presence of abundant recycled sedimentary clasts within the unit, and by the presence of sedimentary breccias and associated dismembered, slump-folded turbidites both within the olistostrome and among subjacent turbidites. Sandstones are chiefly feldspathic litharenites that were very likely derived from the partially dissected, late Mesozoic Sierran-Klamath magmatic are. Franciscan rocks record an early pervasive, layer-parallel flattening strain in such features as extensional faults, necking and pinch-and-swell structures. Several scales of extensional faulting account for the juxtaposition of turbidites of different facies and/or with varying degrees of stratal disruption, the formation of sandstone lozenges, and the formation of scaly foliation in the olistostrome matrix. The latter resulted from the juxtaposition of lenticles with varying concentrations of silt and clay. These were ultimately derived from the finer divisions of turbidite beds that were incorporated into the olistostrome. The presence of gradational contacts between some sandstone olistoliths and the olistostrome matrix, and of sandstone dykes that intrude fractures and associated drag-folded turbidite beds indicate that Franciscan sediments were not lithified during their early deformation. These sediments were deposited in either a trench or trench slope basin, and were first deformed either by gravity collapse of the trench slope cover or, less likely, by vertical loading beneath the toe of the accretionary wedge. They later were folded during internal shortening of the growing Franciscan accretionary prism.     

Geologic evolution of a Cretaceous tectonometamorphic unit in the Franciscan Complex,western California

ABSTRACT

The Franciscan Yolla Bolly terrane of the NE California Coast Ranges consists mainly of quartzose metagreywackes containing sparse high-pressure/low-temperature (HP/LT) neoblastic minerals, including ubiquitous lawsonite. Some Yolla Bolly rocks also contain one or more of the newly grown phases, pumpellyite, aragonite, glaucophane, and/or jadeitic pyroxene. These blueschist-facies metasandstones recrystallized under physical conditions of ~200–300°C and ~8 kbar at subduction-zone depths approaching 30 km. Petrologically similar Franciscan metaclastic-rich map units – Yolla Bolly terrane-like rocks, here designated the ‘YB’ unit – crop out in the central and southern California Coast Ranges. Recently published detrital zircon U?Pb SIMS and LA-ICPMS data for 19 ‘YB’ metagreywackes indicate maximum ages of formation as follows: ~110–115 Ma (8) in the NE California Coast Ranges; ~95–107 Ma (7) in the San Francisco Bay area + Diablo Range; and ~85–92 Ma (4) in the dextrally offset Nacimiento Block. These fault-bounded ‘YB’ strata do not constitute coeval parts of a single tectonostratigraphic unit. Instead the term tectonometamorphic is proposed for such time-transgressive map units. Based on the current and likely Cretaceous 30° angular divergence between NS-palaeomagnetic stripes of the Farallon oceanic plate and the NNW-trending California convergent margin, I infer that arrival at the arc margin and underflow of a relatively thick segment of oceanic crust and its largely clastic sedimentary blanket may have resulted in progressive southeastward migration of an accreted, subducted, then exhumed HP/LT metagreywacke section. During the ~30 million year interval, ~115–85 Ma, the locus of ‘YB’ accretion, underflow, and tectonic regurgitation evidently moved SE along an ~1000 km stretch of the accretionary margin of western California.     

Metamorphic History of a High-Grade Blueschist Exotic Block from the Franciscan Complex, California

A high-grade blueschist tectonic block from the Franciscan Complexof the northeast Diablo Range shows evidence of three episodesof retrograde blueschist facies metamorphism ± deformationdeveloped under progressively declining P-T conditions. Thefirst retrograde metamorphism involved formation of an outerrind of actinolite + chlorite + rutile ± phengite, andthe growth of coarse-grained chlorite + pumpellyite within theblock. During the second event the rind and outer edge of theblueschist were folded, sheared and fractured, and primary glaucophanewithin the blueschist was replaced by albite, medium-grainedchlorite, and glaucophane-crossite. The third retrograde metamorphismwas marked by the pseudomorphic replacement of rind actinoliteby aragonite and quartz. Aragonite also crystallized extensivelywithin th block, accompanied by lawsonite, chlorite, jadeiticpyroxene, and crossite; this last mineral assemblage is identicalto that of the surrounding Franciscan metasedimentary rocks.Features characteristic of the first and second retrograde metamorphicevents are readily observed in other high-grade tectonic blocksof the Franciscan Complex and the correlative Otter Point Formationof Oregon. In contrast, evidence of a third retrograde metamorphism,matching that of presently associated Franciscan and Otter Pointrocks, has been found in some but not all blocks examined sofar. The high P/T conditions of prograde metamorphism and the availablemetamorphic age determinations suggest that the tectonic blocksoriginally formed in a pre-Franciscan subduction zone setting.Fragments of blueschist and eclogite from this metamorphic terrainwere tectonically incorporated in a serpentinite diapir, andthey developed alteration rinds through interaction with theenclosing ultramafic rock. The available data suggest that theexamined exotic block and at least some others were transferredto the Franciscan as detritus from a body of serpentinite thatreached the earth's surface. Such blocks were then resubductedand metamorphosed along with their presently associated sedimentarysequences.     

Textural evolution and metamorphism of pillow basalts from the Franciscan Complex,western Marin County,California

Petrogenesis of Franciscan pillow basalts from the Franciscan Complex of western Marin County California entails both dynamic crystallization of tholeiitic magma and subsequent low-temperature metamorphism. Brittle deformation during tectonic emplacement of pillow basalts into a chert greywacke terrain is manifested by the shearing of interpillow matrix and polishing of pillow rims, but the igneous textures within pillows are well preserved.The cooling history of pillow basalts can be understood through analysis of morphologic variations of primary olivine and plagioclase from rim to core of the pillow. Crystal sizes and plagioclase dendrite spacings are consisted with a cooling rate which generally decreases inward. Some pillows show a marked asymmetry in plagioclase and olivine morphology suggesting lower cooling rates caused by asymmetric cooling of the pillows. Olivine morphologies, primarily hopper and chain forms, are consistent with cooling rates of 2–10 °C/h for pillow cores and 50–75 °C/h for pillow rims.Low temperature hydrothermal alteration has produced secondary minerals indicative of zeolite facies conditions. Pillow matrix is either chloritic or zeolitic (in part laumontized). Pillow rims display incomplete replacement of calcic palagonite by pumpellyite (Fe₂O₃=9–21 wt%), prehnite (Fe₂O₃=5–7 wt%), sphene and quartz. Metamorphism of pillow interiors, manifested by: (1) veins of quartz, pumpellyite, calcite, or harmotome (BaO=15 wt%); (2) amygdules containing analcime, chlorite or quartz; and (3) replacement of olivine by pumpellyite or smectite/illite, of plagioclase by albite (An3)+sericite, and of glassy groundmass by fine-grained chlorite. Primary augite (Wo3₃₉En₁₃Fs₄₈) was not altered. The described paragenesis may be attributed to oceanfloor and/or Franciscan-type metamorphism.     

Petrogenesis of lawsonite and epidote eclogite and blueschist, Sivrihisar Massif, Turkey

The Sivrihisar Massif, Turkey, is comprised of blueschist and eclogite facies metasedimentary and metabasaltic rocks. Abundant metre‐ to centimetre‐scale eclogite pods occur in blueschist facies metabasalt, marble and quartz‐rich rocks. Sivrihisar eclogite contains omphacite + garnet + phengite + rutile ± glaucophane ± quartz + lawsonite and/or epidote. Blueschists contain sodic amphibole + garnet + phengite + lawsonite and/or epidote ± omphacite ± quartz. Sivrihisar eclogite and blueschist have similar bulk composition, equivalent to NMORB, but record different P–T conditions: ～26 kbar, 500 °C (lawsonite eclogite); 18 kbar, 600 °C (epidote eclogite); 12 kbar, 380 °C (lawsonite blueschist); and 15–16 kbar, 480–500 °C (lawsonite‐epidote blueschist). Pressures for the Sivrihisar lawsonite eclogite are among the highest reported for this rock type, which is rarely exposed at the Earth's surface. The distribution and textures of lawsonite ± epidote define P–T conditions and paths. For example, in some lawsonite‐bearing rocks, epidote inclusions in garnet and partial replacement of matrix epidote by lawsonite suggest an anticlockwise P–T path. Other rocks contain no epidote as inclusions or as a matrix phase, and were metamorphosed entirely within the lawsonite stability field. Results of the P–T study and mapping of the distribution of blueschists and eclogites in the massif suggest that rocks recording different maximum P–T conditions were tectonically juxtaposed as kilometre‐scale slices and associated high‐P pods, although all shared the same exhumation path from ～9–11 kbar, 300–400 °C. Within the tectonic slices, alternating millimetre–centimetre‐scale layers of eclogite and blueschist formed together at the same P–T conditions but represent different extents of prograde reaction controlled by strain partitioning or local variations in fO₂ or other chemical factors.     

Dislocations and voids in pyroxene from a low-temperature eclogite: Mechanism of eclogite formation

New occurrences of the phosphates sarcopside/graftonite (Fe, Mn)₃(PO₄)₂, farringtonite (Mg, Fe)₃(PO₄)₂, and brianite Na₂CaMg(PO₄)₂ in iron meteorites are reported. The sarcopside in Duel Hill (1854) (IVA-Anom) contains less than 0.1 mole % Mn₃(PO₄)₂ and more nearly approaches the Fe-rich end member than does any previously reported natural occurrence. This identification of farringtonite in Barranca Bianca (IIE) is the first report of this mineral in a meteorite group other than the pallasites.     

Genesis and solvus relations of submicroscopically intergrown paragonite and phengite in a blueschist from northern California

Electron microbeam techniques have been used to examine submicroscopically intergrown paragonite, phengite and chlorite from the South Fork Mountain Schist of the Franciscan Terrane of northern California, which was subjected to blueschist facies metamorphism. The sample also contains quartz, albite, lawsonite, and rutile. The subassemblage albite-lawsonite-rutile requires metamorphic conditions on the low-temperature side of the equilibrium albite+lawsonite+rutile=paragonite+sphene+quartz+H₂O (T<200° C and P<7.4 kbars based on thermodynamic data of Holland and Powell 1990). The white micas appear to be optically homogeneous, but back-scattered electron images can distinguish two different micas by their slight difference in contrast. Electron microprobe analyses (EMPA) of micas show Na/(Na+K) ranging from 0.2 to 0.8. The two micas are resolved by transmission electron microscopy (TEM) as packets of phengite and paragonite that range from 20 to several hundred nm in thickness. The compositions, determined by analytical electron microscopy (AEM), constrain the limbs of the phengite-paragonite solvus to values of Na/(Na+K)=<0.02 and 0.97, representing less mutual solid solution than ever reported by EMPA. The textural relations imply that the sheet silicates were derived from reactions between fluids and detrital clays and that they are in an intermediate stage of textural development. We caution that microprobe analyses of apparently homogeneous sheet silicates may yield erroneous data and lead to faulty conclusions using phengite barometry and paragonite-muscovite thermometry, especially in fine-grained rocks that formed at relatively low temperatures. Contribution no. 473 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan, USA     

Anatomy of a subduction complex: architecture of the Franciscan Complex,California, at multiple length and time scales

The Franciscan Complex of California records over 150 million years of continuous E-dipping subduction that terminated with conversion to a dextral transform plate boundary. The Franciscan comprises mélange and coherent units forming a stack of thrust nappes, with significant along-strike variability, and downward-decreasing metamorphic grade and accretion ages. The Franciscan records progressive subduction, accretion, metamorphism, and exhumation, spanning the extended period of subduction, rather than events superimposed on pre-existing stratigraphy. High-pressure (HP) metamorphic rocks lack a thermal overprint, indicating continuity of subduction from subduction initiation at ca. 165 Ma to termination at ca. 25 Ma. Accretionary periods may have alternated with episodes of subduction erosion that removed some previously accreted material, but the complex collectively reflects a net addition of material to the upper plate. Mélanges (serpentinite and siliciclastic matrix) with exotic blocks have sedimentary origins as submarine mass transport deposits, whereas mélanges formed by tectonism comprise disrupted ocean plate stratigraphy and lack exotic blocks. The former are interbedded with and grade into coherent siliciclastic units. Palaeomegathrust horizons, separating nappes accreted at different times, appear restricted to narrow zones of <100 m thickness. Exhumation of Franciscan units, both coherent and mélange, was accommodated by significant extension of the hanging wall and cross-sectional extrusion. The amount of total exhumation, as well as exhumation since subduction termination, needs to be considered when comparing Franciscan architecture to modern and ancient subduction complexes. Equal dextral separation of folded Franciscan nappes and late Cenozoic (post-subduction) units across strands of the (post-subduction) San Andreas fault system shows that the folding of nappes took place prior to subduction termination. Dextral separation of similar clastic sedimentary suites in the Franciscan and the coeval Great Valley Group forearc basin is approximately that of the San Andreas fault system, precluding major syn-subduction strike-slip displacement within the Franciscan.     

Subduction and accumulation of lawsonite eclogite and garnet blueschist in eastern Australia

Lawsonite eclogite and garnet blueschist occur as metre-scale blocks within serpentinite mélange in the southern New England Orogen (SNEO) in eastern Australia. These high-P fragments are the products of early Palaeozoic subduction of the palaeo-Pacific plate beneath East Gondwana. Lu–Hf, Sm–Nd, and U–Pb geochronological data from Port Macquarie show that eclogite mineral assemblages formed between c. 500 and 470 Ma ago and became mixed together within a serpentinite-filled subduction channel. Age data and P–T modelling indicate lawsonite eclogite formed at ~2.7 GPa and 590°C at c. 490 Ma, whereas peak garnet in blueschist formed at ~2.0 GPa and 550°C at c. 470 Ma. The post-peak evolution of lawsonite eclogite was associated with the preservation of pristine lawsonite-bearing assemblages and the formation of glaucophane. By contrast, the garnet blueschist was derived from a precursor garnet–omphacite assemblage. The geochronological data from these different aged high-P assemblages indicate the high-P rocks were formed during subduction on the margin of cratonic Australia during the Cambro-Ordovician. The rocks however now reside in the Devonian–Carboniferous southern SNEO, which forms the youngest and most outboard of the eastern Gondwanan Australian orogenic belts. Geodynamic modelling suggests that over the time-scales that subduction products accumulated, the high-P rocks migrated large distances (~>1,000 km) during slab retreat. Consequently, high-P rocks that are trapped in subduction channels may also migrate large distances prior to exhumation, potentially becoming incorporated into younger orogenic belts whose evolution is not directly related to the formation of the exhumed high-P rocks.     

角闪石族和辉石族矿物的系统矿物学分类命名

角闪石族和辉石族矿物是链状硅酸盐矿物的重要组成部分,它们中的许多矿物种属于造岩矿物和/或工业矿物,具有重要的成因矿物研究意义和工业应用开发价值。国内学者对它们的分类命名和基本系统认识主要源自于王璞等(1984)编著的《系统矿物学》。随着科学技术发展和矿物学研究的不断深入,原有的矿物基础资料和分类命名都在不断更新与完善,迄今已有专业学术机构和学者在不同年代陆续发表了不同版本对该两类矿物的修订或修改意见,但一直没有统一整合,导致在涉及该两类矿物的应用研究中,在分类命名上与国际标准不统一。根据本课题组在国家公益性行业科研专项项目(新编《系统矿物学》)所承担的研究任务和当前国内外研究进展,本文系统归纳、梳理并综述了角闪石族和辉石族矿物的分类方案和命名原则,使分类命名统一标准、原则和认识并与国际接轨,这有利于该两类矿物的理论研究与开发应用,更好地支撑地质学及相关学科的研究与发展。     

Designating tectonostratigraphic terranes versus mapping rock units in subduction complexes: perspectives from the Franciscan Complex of California,USA

Accretionary complex histories are broadly understood. Sedimentation in seafloor and trench environments on drifting subducting plates and in associated trenches, followed by (1) deformation and metamorphism in the subduction zone and (2) subsequent uplift at the overriding plate edge, result in complicated stratigraphic and structural sequences in accretionary complexes. Recognizing, defining, and designating individual terranes in subduction complexes clarify some of these complicated relationships within the resulting continent-scale orogenic belts. Terrane designation does not substitute for detailed stratigraphic and structural mapping. Stratigraphic and structural mapping, combined with radiometric and palaeontologic dating, are necessary for delineation of coherent, broken, and dismembered formations, and various mélange units, and for clarification of the details of subduction complex architecture and history. The Franciscan Complex is a representative subduction complex that has evolved through sedimentation, faulting, folding, and low-temperature metamorphism, followed by uplift, associated deformation, and later overprinted deformation. Many belts of Franciscan rocks are offset by strike-slip faults associated with the dextral San Andreas Fault System. In the Franciscan Complex, among the terrane names applied widely, are the ‘Yolla Bolly Terrane’ and the ‘Central Terrane’. Where detailed mapping and detrital zircon ages exist, data reveal that the two names have been applied to rocks of similar general character and age. In the northeastern Diablo Range, Franciscan Complex rocks include coherent units, broken and dismembered formations, and various types of mélanges, all assigned at various times to the Yolla Bolly and other terranes. The details of stratigraphic and structural history revealed by large-scale mapping and radiometric dating prove to be more useful in clarifying the accretionary complex history than assigning a terrane name to the rocks. That history will assist in resolving terrane assignment issues and allow discrimination of subduction-associated and post-subduction events, essential for understanding the overall history of the orogen.     

Franciscan eclogite revisited: Reevaluation of the P–T evolution of tectonic blocks from Tiburon Peninsula, California, U.S.A.

Summary High-grade blocks in the Franciscan complex at Tiburon, California, record relatively low temperature eclogite-facies metamorphism and blueschist-facies overprinting. The eclogite-facies mineral assemblage contains prograde-zoned garnet + omphacite + epidote ± hornblende (katophoritic and barroisitic Ca–Na amphibole) ± glaucophane + phengite (∼3.5 Si p.f.u.) ± paragonite + rutile + quartz. The blueschist-facies mineral assemblage contains chlorite + titanite + glaucophane + epidote ± albite ± phengite (∼3.3 Si p.f.u.). Albite is not stable in the eclogite stage. New calculations based on garnet-omphacite-phengite thermobarometry and THERMOCALC average-P–T calculations yield peak eclogite-facies P–T conditions of P = 2.2–2.5 GPa and T = 550–620 °C; porphyroclastic omphacite with inclusions of garnet and paragonite yields an average-P–T of 1.8 ± 0.2 GPa at 490 ± 70 °C for the pre-peak stage. The inferred counterclockwise hairpin P–T trajectory suggests prograde eclogitization of a relatively “cold” subducting slab, and subsequent exhumation and blueschist-facies recrystallization by a decreasing geotherm. Although an epidote-garnet amphibolitic assemblage is ubiquitous in some blocks, P–T pseudosection analyses imply that the epidote-garnet amphibolitic assemblage is stable during prograde eclogite-facies metamorphism. Available geochronologic data combined with our new insight for the maximum pressure suggest an average exhumation rate of ∼5 km/Ma, as rapid as those of some ultrahigh pressure metamorphic terranes.     

Reaction spaces and P-T paths: from amphibole eclogite to greenschist facies in the Austroalpine domain (Oetztal Complex)

The transition from feldspar amphibolite to eclogite is a very wide P-T field that extends from some-where close to 5 kbar where the garnet-amphibole pair starts to appear, to 10–20 kbar at albite-out reaction, then up to 25–30 kbar where an hydrated phase such as amphibole can be stable with pyroxene and garnet. Thus the assemblage garnet (py)+ amphibole (tr)+epidote (cz)±plagioclase (ab)±clinopyroxene (di)±quartz (qz)±fluid is commonly reported in a large number of metamorphic terrains. These mineral phases are complex solid-solutions which adapt to variations in environmental conditions mainly by means of continuous reactions. The reaction space, introduced by. Thompson in 1982a, provides a very elegant and powerful tool to approach these high-variance assemblages. The reactions:

Elemental mobility in subduction metamorphism: insight from metamorphic rocks of the Franciscan Complex and the Feather River ultramafic belt,California

The degree of element mobility in subduction metamorphism has generated much debate; some workers advocate considerable mobility during metamorphism, whereas others postulate minimal mobility. We assess this issue by examination of major and trace element concentrations and Pb-, Nd-isotopic data for 39 mafic metavolcanic rocks from the Franciscan subduction complex, related units of coastal California, and the Feather River ultramafic belt of the northern Sierra Nevada, California; these samples span a wide range of metamorphic grade. We conclude that these rocks, despite their metamorphism up to eclogite facies, preserve protolith major and trace elemental compositions and isotopic ratios, with the exception of some mobile large ion lithophile elements such as Ba, Pb, and to a smaller extent La, U, and Sr. Thus subduction metamorphism of these metabasalts occurred in a largely closed system. Lack of light rare earth element enrichment in the rocks demonstrates lack of chemical exchange with subducted metasediments. Relatively low SiO₂ content (<48 wt.%) of many of the metamorphic rocks and the lack of correspondence between silica depletion and metamorphic grade suggests that the silica depletion resulted from seafloor hydrothermal alteration before subduction. In spite of demonstrated mobility of Pb, and possible mobility of Nd, isotopic ratios of Pb and Nd were not modified during subduction metamorphism. In contrast to our results from metabasaltic rocks, our analysis of actinolite-rich rinds from high-grade Franciscan mélange blocks suggests some chemical exchange between metachert and the overlying mantle. The increasing enrichment in Ba and Pb with increasing metamorphic grade suggests that Ba- and Pb-rich fluids interacted more intensely with metabasalt at the higher grades of metamorphism. Comparison of these results with studies of the active Mariana forearc suggests that fluids interacting with the mantle wedge up-dip of the region of magma genesis are derived from subducting sediments overlying the down-going plate.     

Petrogenesis of Franciscan glaucophane schists and associated metamorphic rocks,California

Rocks of the glaucophane-schist facies are widely though irregularly developed in the Franciscan formation of California. Minerals critical of the facies are lawsonite, aragonite, jadeite and omphacitic pyroxenes associated with quartz; amphiboles of the glaucophane-crossite series are almost ubiquitous. The most widely distributed rock, occurring over areas of many square kilometers, is jadeite-lawsonite metagraywacke, commonly veined with aragonite. More spectacular, but occurring mainly in isolated blocks are coarse-grained glaucophane-lawsonite Schists of many kinds. Commonly, but by no means invariably, they are closely associated with bodies of serpentinite. Also common in the vicinity of serpentinite masses are blocks of amphibolite and eclogite.All the metamorphic rocks are considered to be Franciscan sediments and basic volcanics metamorphosed and metasomatized in the deep levels of a folded geosynclinal prism. Experimental data on the stability fields of jadeite-quartz, aragonite, and lawsonite show that the glaucophane-schist facies represents metamorphism at pressures of between 5 and 10 kb and temperatures of 150–300° C. Such conditions could develop at depths greater than 15 km provided a very low geothermal gradient (10°/km) were maintained. The metagray-wackes are considered to represent a regional response to such conditions.The role of serpentinites in glaucophane-schist metamorphism is discussed in terms of a tentatively proposed model: — In very deep levels — perhaps at depths as great as 30 km, bodies of hot ultramafic magma develop restricted aureoles' in which temperatures of 400–600° C are maintained fer perhaps 100–1000 years. The products of metamorphism, which also involves desilication under the influence of the ultramafic magma, are eclogite and amphibolite. Later, and perhaps at higher levels serpentinization of the now solid ultramafic masses (near 400° C), causes renewed metamorphism at lower grades. Marginal development of glaucophane Schists and prehnite and hydrogarnet rocks, and retrogressive alteration of eclogite and amphibolite to glaucophane-schist assemblages is attributed to this period.     

Coexisting clinopyroxene,garnet and amphibole from an “eclogite”, Kakanui,New Zealand

Analyses of major and rare earth elements are presented for co-existing garnet, clinopyroxene, and amphibole from a Kakanui eclogite.New and previously published analyses of garnets suggest a gradual increase of Fe and decrease of Mg from xenocrysts through garnet pyroxene eclogitic rocks to amphibole-rich eclogitic rocks. Clinopyroxenes show a parallel increase in Fe/Mg ratio and an increase in Jadeite component and decrease in Tschermak's component. These data indicate crystallization of garnet and clinopyroxene from an alkali-rich undersaturated magma and are consistent with the concept of eclogite fractionation, but rare earth data allow severe constraints to be placed on this process. The eclogites are considered to be deep-seated crystallization products of nephelinite, but eclogite fractionation is small and cannot account for the association of alkali basalt, basanite and nephelinite.     

Phase relations of calc-silicate assemblagesin the Auerbach marble, OdenwaldCrystalline Complex, Germany

Summary In the Odenwald Crystalline Complex, calc-silicate rocks are concentrated at the margins of the marble layer of Auerbach. They were presumably formed by metasomatic exchange between the calcite marble and the neighbouring granodioritic and quartz-dioritic intrusives. The investigated samples contain the characteristic mineral assemblages: garnet + clinopyroxene + epidote/clinozoisite + calcite + quartz ± titanite (1) and wollastonite + clinopyroxene + garnet + calcite ± quartz ± epidote/clinozoisite ± titanite (2). Microprobe analyses revealed the following compositional ranges: garnet grs_40–98adr_2–55alm_<5.5sps_<5.5pyp_<1; clinopyroxene di_46–88hed_9–47joh_0–5cats_0–6; epidote/clinozoisite ps_20–80. Different phase diagrams were calculated in the system CaO-MgO-Al₂O₃-TiO₂-SiO₂-CO₂-H₂O (CMATSCH) to decipher the P-T-X_CO2 parameters of metamorphism: isobaric T-X_CO2 sections and a P-T projection with mixed volatiles. The phase diagrams illustrate that the observed assemblages can only form in the presence of an H₂O-rich volatile phase. The assemblages are stable over a large range of temperatures, from 580 °C to < 400 °C (at 4 kbar) and at X_CO2 values of less than 0.055 (at 4 kbar). Higher temperatures can be inferred from reaction textures which indicate that garnet + plagioclase (T > 580 °C, at 4 kbar) and wollastonite + plagioclase (T > 660 °C, at 4 kbar) coexisted during an early metamorphic stage. A minimum pressure of 3.5 kbar can be inferred for the early high-temperature stage. Furthermore, on the basis of the calculated phase diagrams, combined with modal abundances in thin sections, it is possible to evaluate fluid behaviour; in the investigated specimens, infiltration of fluids from an external reservoir occurred. A minimum fluid:rock ratio of 3.6:1 can be estimated.

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Zusammenfassung Phasenbeziehungen in Kalksilikat-Paragenesen des Marmorzuges von Auerbach, Odenwald-Kristallin-Komplex, Deutschland Im kristallinen Odenwald konzentrieren sich kalksilikatische Gesteine in den Randbereichen des Marmorzuges von Auerbach. Die kalksilikatischen Partien wurden vermutlich duch metasomatischen Austausch zwischen dem Calcit-Marmor und benachbarten Granodioriten und Quarzdioriten gebildet. Die untersuchten Proben enthalten die charakteristischen Mineralparagenesen: Granat + Klinopyroxen + Epidot/Klinozoisit + Calcit + Quarz + Titanit (1) und Wollastonit + Klinopyroxen + Granat + Calcit ± Quarz ± Epidot/Klinozoisit ± Titanit (2). Mikrosondenanalysen ergaben folgendes Zusammensetzungsspektrum: Granat grs_40–98adr_2–55alm_<5.5sps_<5.5pyp_<1; Klinopyroxen di_46–88hed_9–47joh_0–5cats_0–6s; Epidot/Klinozoisit ps_20–80. Verschiedene Phasendiagramme wurden für das Modellsystem CaO-MgO-Al₂O₃-TiO₂-SiO₂-CO₂-H₂O (CMATSCH) berechnet, um die P-T-X_CO2-Parameter der Metamorphose einzugrenzen: Isobare T-X_CO2-Schnitte und eine P-T-Projektion mit einer Fluid-Mischphase. Die Phasendiagramme verdeutlichen, da? die beobachteten Paragenesen nur in Anwesenheit eines H₂O-reichen Fluids gebildet werden k?nnen. Die Paragenesen sind über einen gro?en Temperaturbereich hinweg stabil, von 580 °C bis < 400 °C (bei 4 kbar) und bei X_CO2-Gehalten von < 0.055 (bei 4 kbar). Ursprünglich h?here Temperaturen k?nnen anhand von Reaktions-Texturen rekonstruiert werden, die zeigen, da? Granat + Plagioklas (T > 580 °C, bei 4 kbar) und Wollastonit + Plagioklas (T > 660 °C, bei 4 kbar) w?hrend eines früheren Metamorphosestadiums koexistierten. Ein Minimaldruck von 3.5 kbar kann für dieses frühe Hochtemperatur-Stadium abgeleitet werden. Mit Hilfe der berechneten Phasendiagramme, in Kombination mit beobachteten Modalgehalten, ist es m?glich, das Verhalten der fluiden Phase abzusch?tzen. Die untersuchten Gesteine implizieren Fluidinfiltration, wobei ein minimales Verh?ltnis Fluid:Gestein von 3.6:1 abgesch?tzt werden kann.

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Received July 29, 1999; accepted March 28, 2000     

Contrasting modes of eclogite and blueschist exhumation in a retreating subduction system: The Tasmanides,Australia

Blueschists and eclogites located in the Tasmanides of eastern Australia preserve evidence of contrasting modes of exhumation. A review of structural, metamorphic, geochronological and geochemical data indicates that these HP metamorphic rocks can be sub-divided into three main groups: (i) eclogite–blueschists with calc-alkaline and tholeiitic affinities contained within thick sedimentary sequences (called continental HP rocks); (ii) moderate-pressure (< 9 kbar) blueschist of arc to MORB-type composition within sedimentary or serpentinite mélange zones (called accretionary HP rocks) and (iii) eclogites of MORB-type composition with or without a pervasive blueschist overprint contained within serpentinite (called exotic HP rocks). Three different modes of exhumation can be ascribed to the different rock types, namely: (i) exhumation influenced by the buoyancy of continental slabs; (ii) exhumation of accretionary HP rocks by corner flow and/or extensional collapse in the accretionary wedge or (iii) discontinuous exhumation of eclogites triggered by slab rollback and trench retreat. We suggest that a dominant west-dipping, eastward migrating subduction zone can explain the distribution and formation of HP metamorphic rocks in the Tasmanides.Thermobarometric and geochronological data from eclogites and blueschists in the Peel–Manning Fault System (New England Orogen) also provide evidence for discontinuous exhumation of subducted oceanic rocks. These data indicate that eclogites were exhumed from depths of ~ 70 km to ~ 30 km during the Ordovician (490–470 Ma), with terminal exhumation and exposure along the Peel–Manning Fault system probably occurring during the Permian. Based on these timing constraints, we suggest a model where HP rocks reside between depth-dependant exhumation circuits for considerable lengths of time.