二叠系-三叠系界线全球层型剖面——回顾和进展

综合评述了5年来对二叠系—三叠系界线(PTB)全球层型剖面——煤山D剖面的研究进展。简要介绍剖面的研究历史、地理和地质背景,叙述了世界上最完整的二叠纪长兴期至三叠纪格里斯巴赫期的牙形石和菊石带,并简短讨论了Otoceras的年代。叙述了煤山与其他剖面长兴期至格里斯巴赫期磁性地层学的对比。介绍了δ13C和δ34S的化学地层学最新研究进展,特别是在PTB附近多个δ13C负漂移的发现。两项重要的分子地层学研究显示了基础生态系统的深刻变化——微生物生态系的灾变和在二叠纪—三叠纪生态系之交严重缺氧事件期间透光带的静海相环境。文章报道了自2001年以来PTB年代测定的进展。PTB之下14cm处火山成因的粘土层25层的年代,现在定为(252·4±0·3)Ma(Mundil等,2004)。文章还讨论了事件地层学,认为尽管在25-26层有一个主事件,煤山PTB附近的事件是多幕式的,并且开始于事件层25-26层之前。因此,PTB大绝灭主因是外星撞击导致的可能性是不大的。     

华南二叠系长兴阶灰岩的碳同位素地层对比

以浙江长兴煤山长兴阶层型剖面、江西上高七宝山剖面、陕西汉中梁山剖面为代表的华南长兴阶碳酸盐岩碳同位素地层,清楚地显示出长兴阶顶、底为碳同位素低值区,其中Ｐ－Ｔ界线附近的碳同位素出现强烈负异常事件。在长兴阶内部两次碳同位素低值异常区,将长兴阶碳同位素演化曲线由下至上明显分为３个旋回,其中长兴阶顶,也即Ｐ－Ｔ界线,碳同位素强烈负异常与生物绝灭事件有关,时间短,变化幅度大,是全球界线对比的重要标志。而其它碳同位素负漂移和由此构成的３个旋回,在华南可以追踪对比。上旋回与长兴阶上段煤山段相当;而中、下旋回则与下段葆青段相当,并将其两分。碳同位素地层对比表明江西上高地区长兴组的中、上部可能属长兴阶,而下部厚约９０ｍ的含Ｇａｌｏｗａｙｉｎｅｌａ灰岩可能属吴家坪晚期。     

滇西昌宁—孟连带西区两个地层问题——兼论昌宁—孟连带的闭合造山过程

对昌宁—孟连带西区的两个地层问题进行了讨论。根据牙形刺和放射虫的发现将原定为拉巴组的塔拉弄—南雅条带的时代厘定为晚泥盆世至早石炭世 ,时代大致与南皮河群的弄巴组或“中区”的“上泥盆统”相当 ,它们之间的确切关系仍有待进一步研究。怕拍组实际上主体属晚二叠世晚期 ,仅顶部可能包含有少量下三叠统印度阶最底部的沉积。对怕拍组的研究证实了澜沧运动的存在 ,昌宁—孟连带自此开始了由海洋盆地向造山带的演变进程 ,这一过程持续达七千万年之久。     

地层单位与全球界线层型:概念、术语、有关规定与研究实例

全球二叠系-三叠系界线(PTB)层型及点("金钉子")定位我国浙江省长兴县煤山D剖面,极大地推动了PTB及二叠系和三叠系研究进展。在简要介绍地层单位与全球界线层型与点建立的相关概念、术语和有关规定、地层划分的主要种类及其地层单位术语的基础上,以全球二叠系—三叠系界线层型及点(中国浙江省长兴县煤山D剖面)为研究实例,综述了该金钉子剖面牙形石生物地层和年代地层研究现状。煤山D剖面构建了目前全球最完整的PTB地层牙形石带序列,为研究二叠纪末大灭绝后生物残存和复苏过程提供了重要的时间坐标系,也为相关的地质事件研究奠定了坚实的基础。     

The Buday’ah Formation, Sultanate of Oman: A Middle Permian to Early Triassic oceanic record of the Neotethys and the late Induan microsphere bloom

The Middle Permian to Lower Triassic Buday’ah section, exposed in the Oman Mountains, is the first deep-sea section to be described in the Neotethys. The oceanic sediments were deposited along the southern Tethys margin in the newly formed Hawasina Basin. It is one of the few places where true Tethyan Permian radiolarites are exposed that allow the documentation of CCD evolution through time. The succession begins as oceanic crust pillow basalt with red ammonoid-rich pelagic limestone occurring both above and within inter-pillow cavities; the new occurrence of Clarkina postbitteri hongshuiensis indicates a late Capitanian age for the carbonate. The sharp change to overlying late Capitanian to Changhsingian radiolarite reflects rapid subsidence about 10 Myrs after initial continental breakup that resulted in the formation of the Neotethys Ocean. New conodonts indicate that the Permian-Triassic boundary succession occurs in the first platy lime mudstone beds above a Changhsingian siliceous to calcareous shale unit. The platy lime mudstone beds include an Upper Griesbachian bloom of calcite filled spheres (radiolarians?) that marks a potential world-wide event. New conodonts indicate an early Olenekian age for overlying grey papery limestone that are devoid of both macrofossils and trace fossils indicating that recovery from the Late Permian extinction has not yet progressed within this deep-water environment.δ¹³C_org, isotope values have not been disturbed and they show a negative shift just below the Permian-Triassic transition and a second one at the parvus zone level above. The Buday’ah succession may represent the most distal and probably deepest Permian and Lower Triassic depositional sequence within the basin.     

Nitrogen isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,Sichuan, South China

Nitrogen isotopic compositions of upper Permian to lowermost Triassic rocks were analyzed at Chaotian in northern Sichuan, South China, in order to clarify changes in the oceanic nitrogen cycle around the Permian–Triassic boundary (P–TB) including the entire Changhsingian (Late Late Permian) prior to the extinction. The analyzed ca. 40 m thick interval across the P–TB at Chaotian consists of three stratigraphic units: the upper Wujiaping Formation, the Dalong Formation, and the lowermost Feixianguan Formation, in ascending order. The upper Wujiaping Formation, ca. 10 m thick, is mainly composed of dark gray limestone with diverse shallow-marine fossils such as calcareous algae and brachiopods, deposited on the shallow shelf. In contrast, the overlying Dalong Formation, ca. 25 m thick, is mainly composed of thinly bedded black mudstone and siliceous mudstone containing abundant radiolarians, deposited on the relatively deep slope/basin. Absence of bioturbation, substantially high total organic carbon contents (up to 15%), and abundant occurrence of pyrite framboids in the main part of the Dalong Formation indicate deposition under anoxic condition. The lowermost Feixianguan Formation, ca. 5 m thick, is composed of thinly bedded gray marl and micritic limestone with minor fossils such as ammonoids and conodonts, deposited on the relatively shallow slope. δ¹⁵N_TN values are in positive values around +1 to +2‰ in the upper Wujiaping Formation implying denitrification and/or anammox in the ocean. δ¹⁵N_TN values gradually decrease to −1‰ in the lower Dalong Formation and are consistently low (around 0‰) in the middle Dalong to lowermost Feixianguan Formation. No clear δ¹⁵N_TN shift is recognized across the extinction horizon. The consistently low δ¹⁵N_TN values suggest the enhanced nitrogen fixation in the ocean during the Changhsingian at Chaotian. Composite profiles based on previous and the present studies demonstrate the substantial δ¹⁵N variation on a global scale in the late Permian to earliest Triassic; a systematic δ¹⁵N difference by low and high latitudes is particularly clarified. Although the enhanced nitrogen fixation throughout the Changhsingian at Chaotian was likely a regional event in northwestern South China, the composite δ¹⁵N profiles imply that the sea area in which fixed nitrogen is depleted has gradually developed worldwide in the Changhsingian, possibly acting as a prolonged stress to shallow-marine biota.     

Ocean Chemistry Revealed by Mineralogical and Geochemical Evidence at the Permian–Triassic Mass Extinction, Offshore the Persian Gulf, Iran

The Upper Permian Dalan Formation and the Lower Triassic Kangan Formation in the Persian Gulf area are mainly composed of shallow marine facies limestone and dolomite. Two subsurface-cored intervals were investigated in order to understand the original mineralogy and paleoceanic conditions. The decreasing trend of Sr concentration in these deposits shows that aragonite was precipitated during the Late Permian and then gradually changed to calcite toward the Permian–Triassic boundary (PTB). The dissolution rate of aragonite decreased from 60 m below the PTB toward the boundary, with the only exception at 10 m below the Permian-Triassic Boundary (PTB) due to the Permian–Triassic unconformity in this region. The increasing trend of Mg/Ca ratio in a global scale at the end-Permian time shows that the interpreted variation of mineralogy does not result from the change of this ratio. The increasing pCO2 and decreasing pH are considered to be the main controlling factors. The increase of Ca2+ at the end-Permian time due to the input of meteoric waters is too little to fully compensate this effect. A local maximum of the Si content just at the PTB confirms the input of runoff waters.     

Ophiceras(蛇菊石)在滇东卡以头组的发现及其意义

Ophiceras(蛇菊石)在滇东海陆交互相卡以头组下部(25层下部)的首次发现,是近期海陆交互相和陆相二叠系-三叠系界线(PTB)研究的重要进展之一。该化石的发现为滇东卡以头组地层时代的确定提供了更加确凿的依据。在煤山D剖面,29-37层为Ophiceras(蛇菊石)的顶峰带,因此,可将滇东密德B剖面的25层与煤山D剖面29层对比,那么滇东地区卡以头组主体(甚至全部)的时代可划归早三叠世。     

煤山D剖面的放射虫动物群与海平面变化

煤山D剖面长兴组的放射虫动物群的研究成果很少.对煤山D剖面的放射虫动物群进行了详细的鉴定、个体数量和种的数量的统计.结果表明: 煤山D剖面长兴组的放射虫动物群的相对丰度、简单分异度与长兴期海平面变化具有耦合性: 放射虫丰度、分异度较大的层位基本对应于长兴早期和长兴晚期2次最大海侵事件发生的层位.长兴早期放射虫的丰度和分异度较大(相对长兴晚期而言), 这与长兴早期水体相对较深有关.煤山剖面放射虫动物群与海平面变化之间的这种耦合性为海平面变化的研究提供了依据.      

Molecular carbon isotope variations in core samples taken at the Permian–Triassic boundary layers in southern China

Stable carbon isotope composition (δ¹³C) of carbonate sediments and the molecular (biomarker) characteristics of a continuous Permian–Triassic (PT) layer in southern China were studied to obtain geochemical signals of global change at the Permian–Triassic boundary (PTB). Carbonate carbon isotope values shifted toward positive before the end of the Permian period and then shifted negative above the PTB into the Triassic period. Molecular carbon isotope values of biomarkers followed the same trend at and below the PTB and remained negative in the Triassic layer. These biomarkers were acyclic isoprenoids, ranging from C₁₅ to C₄₀, steranes (C₂₇ dominates) and terpenoids that were all significantly more abundant in samples from the Permian layer than those from the Triassic layer. The Triassic layer was distinguished by the dominance of higher molecular weight (waxy) n-alkanes. Stable carbon isotope values of individual components, including n-alkanes and acyclic isoprenoids such as phytane, isop-C₂₅, and squalane, are depleted in δ¹³C by up to 8–10‰ in the Triassic samples as compared to the Permian. Measured molecular and isotopic variations of organic matter in the PT layers support the generally accepted view of Permian oceanic stagnation followed by a massive upwelling of toxic deep waters at the PTB. A series of large-scale (global) outgassing events may be associated with the carbon isotope shift we measured. This is also consistent with the lithological evidence we observed of white thin-clay layers in this region. Our findings, in context with a generally accepted stagnant Permian ocean, followed by massive upwelling of toxic deep waters might be the major causes of the largest global mass extinction event that occurred at the Permian–Triassic boundary.     

浙江长兴煤山地区吴家坪阶-长兴阶界线地层的再认识

浙江长兴煤山的 D剖面经多年研究 ,已成为二叠系长兴阶的单位层型和二叠系 -三叠系全球界线层型 ,并被推荐为吴家坪阶 -长兴阶全球界线层型的候选剖面 ,因该剖面上龙潭组地层出露较少 ,以致国内对长兴组与龙潭组的接触关系存有不同意见 ,给层型剖面的建立带来不利影响。在清理和研究了 D剖面西侧 30 0 m处 C剖面的吴家坪阶 -长兴阶界线层段后 ,证实了煤山地区龙潭组与长兴组为整合接触 ,对相关化石的地层分布也获得进一步的认识     

Late Permian–Early Triassic environmental changes recorded by multi-isotope (Re-Os-N-Hg) data and trace metal distribution from the Hovea-3 section,Western Australia

The temporal coincidence between the Late Permian mass extinction (LPME) and the emplacement of Siberian Trap basalts suggests a causal link between the two events. Here, we discuss stratigraphic changes of organic and inorganic (including isotopic) geochemical properties of marine sediments across the Permian–Triassic boundary (PTB) in the Hovea-3 core, Western Australia, a key PTB section in the southern Neo-Tethys ocean. These data are compared with published data from the Meishan section, southern China, and from the Opal Creek section in western Canada, providing a view of Tethys and Panthalassa changes at the PTB. Trace metal and N-isotopic data, together with organic matter properties suggest that anoxic conditions were established prior to the LPME, intensified close to the LPME, and continued with photic-zone euxinia into the Early Triassic. For the Hovea-3 section, Re-Os ages confirm Changhsingian (253.5 ± 1.4 Ma) deposition of the dated interval sampled immediately below the stratigraphic level characterized by major lithological and isotopic changes. Evaluation of Re-Os, N, and Hg elemental and isotopic data for Hovea-3 suggests that anoxic conditions in the latest Permian were generally unrelated to direct magmatic contributions. A major increase in the initial Os isotopic ratio of Lower Triassic shales suggest an ~8× increase in the Early Triassic continental runoff, based on moderately conservative assumptions for end-members contributing Os to the Permian–Triassic ocean. Comparison to other PTB sections confirms a global signal of increasing Re/Os ratios in the Late Permian, and major and long-lived changes in the isotopic composition of the post-extinction ocean. A distinct peak in Hg concentrations carrying a volcanic isotopic signature, also identified in other PTB sections, likely represents a major pulse of Siberian Trap volcanism. This Hg peak in the Hovea-3 section, however, is detected above the stratigraphic level containing multiple other widely recognized and more permanent geochemical changes. Therefore, direct volcanic inputs to the Permian–Triassic Ocean likely post-date the LPME in this Western Australian section.     

Global correlation of basal Triassic layers in the light of the first carbon isotope data on the Permian-Triassic boundary in Northeast Asia

This paper is dedicated to the global correlation of the marine Permian-Triassic boundary layers based on some published and original data on the δ¹³C_org and δ¹³C_carb values obtained for the section along the Suol Creek (Setorym River, southern Verkhoyansk region). The section includes six carbon-isotope intervals readily distinguished in the corresponding curves obtained for several Permian and Triassic reference sections in Eurasia and North America including palleontologically well substantiated sections of central Iran, Kashmir, and South China. This provides grounds for assuming the Permian-Triassic boundary’s position in the Suol Creek section as being close to the carbon-isotope minimum of Interval IV. In the light of new data, the upper part of the Upper Permian Changhsingian Stage in Siberia is proposed to correspond in range to the Otoceras concavum range zone, and the lower substage of the Lower Triassic Induan Stage, to the Tompophiceras pascoei and Wordieoceras decipiens zones. The Otoceras concavum Zone of the Verkhoyansk region in its new understanding is likely correlative with the upper Changhsingian Hypophiceras triviale Zone of Greenland. Carbon-isotope intervals II, III, IV, and V defined in the Permian-Triassic boundary layers of the Verkhoyansk region, which are traceable in several reference sections of Eurasia and North America, evidently coincide with the period of some intensification of the volcanic activity in the initial late Changhsingian and with the first phases of extensive eruption of Siberian trappes in the terminal Changhsingian and initial Induan ages. New data imply the probable survival of some ammonoid species from the superfamily Otoceratoidea after the mass extinction of organisms in the terminal Permian Epoch.     

湖北黄石二门二叠系/三叠系界线剖面长兴阶牙形刺分带及有机碳同位素的变化

湖北黄石二门二叠系/三叠系界线剖面出露完好,原始沉积连续,由乐平统龙潭组保安段灰黑色硅质岩、大隆组黑色硅质岩—硅质泥岩和下三叠统大冶组黑灰色泥岩以及泥岩夹灰岩组成,为介于典型浅水碳酸盐岩型与深海硅质岩型二叠系/三叠系界线剖面之间的半深海剖面。长兴阶可划分为Clarkinasubcarinata—Clarkinawangi及Clarkinachangxingensis两个牙形刺带。后者又可划分为3个亚带,自下而上依次为Clarkinachangxingensischangxingensis—Clarkinadeflecta亚带、Clarkinameishanensis亚带及Waning—Clarkina亚带,完全可以与二叠系/三叠系界线的全球层型剖面与点进行对比。另外,二叠纪末牙形刺的生态演化呈阶段性绝灭模式;有机碳同位素值在二叠纪/三叠系界线处出现明显的负偏移,指示了二叠纪/三叠纪之交生物绝灭后海水表层水原始产率的降低以及大气和海水中CO2含量的增加。     

Sequence Stratigraphy of the Permian--Triassia Boundary Section of Changxing, Zhejiang, Southern China

Three third-order sequences and about one hundred high-frequency cycles or Milankovitchcycles within the Late Permian Changxingian to Early Triassic Griesbachian are identified in theMeishan Section of Changxing, Zhejiang Province, southern China, the candidate stratotype sec-tion of the global Permo-Triassic boundary, based on a detailed study of the biological,ecological and high-resolution allochthonous cyclic events, microfacies and depositional systems.Furthermore, the stacking pattern of the depositional systems across various Changxingian andGriesbachian sedimentary facies of the Lower Yangtze and the sequence stratigraphic frameworkare outlined with the Meishan section as the principal section. In this paper the habitat types offossil biota are applied to semiquantitative palaeobathymetry and the study of relative sea levelchanges.     

The Wuchiapingian–Changhsingian boundary (Upper Permian) at Meishan of Changxing County, South China

Section D at Meishan, Changxing County in the Zhejiang Province, China, has been extensively studied in various aspects of the stratigraphy during the past 20 years. It was ratified by the International Union of Geological Sciences (IUGS) as the Global Standard Stratotype Section and Point (GSSP) for the Permian–Triassic boundary in 2000, and is also a potential stratotype for the Wuchiapingian–Changhsingian boundary. However, the contact relationship between the Longtan (Wuchiapingian) and Changxing (Chainghsingian) formations has been a controversial subject for years. Recent studies on Section C, about 300 m west of Section D, at Meishan confirm a complete depositional succession around the boundary and suggest that the proposed boundary level, the FAD of Clarkina wangi within the lineage from C. longicuspidata to C. wangi, is consistent with the first appearance of the index Changhsingian fusulinid Palaeofusulina sinensis and tapashanitid ammonoids.     

浙江长兴地区二叠系与三叠系界线层型研究

<正> 中国南部二叠系与三叠系分界的层型剖面位于浙江长兴煤山(赵金科、盛金章等,1980)。在这个剖面上,1978年赵金科等把上二叠统的顶界确定在“未定名菊石带”,后经重新研究,又改归于下三叠统底部(赵金科、盛金章等,1980)。1980年5月,我们再度去上述界线层型剖面工作,在“未定名菊石带”同一层位详细采集化石,并到邻区安徽广德独山、江苏宜兴湖汷等地的相当层位调查,进一步证实在界线层型剖面上的“未定名菊石带”     

The prelude of the end-Permian mass extinction predates a postulated bolide impact

The mass extinction at the Permian–Triassic Boundary (PTB) is said to have been abrupt and probably caused by an extraterrestrial impact. However, evidence from the Global Stratotype Section and Point (GSSP) of the base of the Induan at Meishan, China, shows that the biotic crisis began prior to the level, in beds 25 and 26 at which the postulated impact event occurred. Evidence of such an earlier biotic crisis occurs in other sections in South China, and in central and western Tethyan regions. This event is characterized by the extinction of a range of faunas, including corals, deep-water radiolarians, most fusulinids and pseudotirolitid ammonoids, and many Permian brachiopods. In all sections, this extinction level is usually a few decimeters to meters below that of the main mass extinction in the event beds (25 and 26) at Meishan, and their correlatives elsewhere. This earlier extinction event happened before the postulated bolide impact at the level of beds 25 and 26, and constrains interpretation of the mechanisms that brought about this greatest mass extinction. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Timing and magnitude of tetrapod extinctions across the Permo-Triassic boundary

A review of the tetrapod (amphibian and amniote) record across the Permo-Triassic boundary (PTB) indicates a global evolutionary turnover of tetrapods close to the PTB. There is also a within-Guadalupian tetrapod extinction here called the dinocephalian extinction event, probably of global extent. The dinocephalian extinction event is a late Wordian or early Capitanian extinction based on biostratigraphic data and magnetostratigraphy (the extinction precedes the Illawara reversal), so it is not synchronous with the end-Guadalupian marine extinction. The Russian PTB section documents two tetrapod extinction events, one just before the dinocephalian extinction event and the other at the base of the Lystrosaurus assemblage. However, generic diversity across the latter extinction remains essentially the same despite a total evolutionary turnover of tetrapod genera. The Chinese and South African sections document the stratigraphic overlap of Dicynodon and Lystrosaurus. In the Karoo basin, the lowest occurrence of Lystrosaurus is in a stratigraphic interval of reversed magnetic polarity, which indicates it predates the marine-defined PTB, so, as previously suggested by some workers, the lowest occurrence of Lystrosaurus cannot be used to identify the PTB in nonmarine strata. Correlation of the marine PTB section at Meishan, southern China, to the Karoo basin based primarily on magnetostratigraphy indicates that the main marine extinction preceded the PTB tetrapod extinction event. The ecological severity of the PTB tetrapod extinction event has generally been overstated, and the major change in tetrapod assemblages that took place across the PTB was the prolonged and complex “replacement” of therapsids by archosaurs that began before the end of the Permian and was not complete until well into the Triassic. The tetrapod extinctions are not synchronous with the major marine extinctions at the end of the Guadalupian and just before the end of the Permian, so the idea of catastrophic causes of synchronous PTB extinctions on land and sea should be reconsidered.     

贵州紫云四大寨早三叠世地层初步研究

贵州紫云四大寨剖面下三叠统发育较齐全,化石较丰富。在此剖面上发现了大量牙形石、双壳类、菊石等生物化石,其中牙形石在该剖面上为首次发现,并识别出了早三叠世Neospathodusdieneri带、Neospathoduscrista-galli带、Neospathoduswaageni带和Neospathodushomeri-Neospathodustriangularis带的重要牙形石分子或带化石,可与国际同期地层中相应的牙形石化石带进行较好的对比;同时还发现了Claraiagriesbachi-C.concentrica组合和Claraiastachei-Claraiaaurita组合带的双壳类代表性分子。通过对这些化石综合分析,大致拟定了本剖面下三叠统格里斯巴赫亚阶(Griesbachian)、亭纳尔亚阶(Dienerian)、斯密斯亚阶(Smithian)和斯派斯亚阶(Spathian)的年代地层单位界线。