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1.
Chemical kinetic model for the lower atmosphere of Venus   总被引:1,自引:0,他引:1  
A self-consistent chemical kinetic model of the Venus atmosphere at 0-47 km has been calculated for the first time. The model involves 82 reactions of 26 species. Chemical processes in the atmosphere below the clouds are initiated by photochemical products from the middle atmosphere (H2SO4, CO, Sx), thermochemistry in the lowest 10 km, and photolysis of S3. The sulfur bonds in OCS and Sx are weaker than the bonds of other elements in the basic atmospheric species on Venus; therefore the chemistry is mostly sulfur-driven. Sulfur chemistry activates some H and Cl atoms and radicals, though their effect on the chemical composition is weak. The lack of kinetic data for many reactions presents a problem that has been solved using some similar reactions and thermodynamic calculations of inverse processes. Column rates of some reactions in the lower atmosphere exceed the highest rates in the middle atmosphere by two orders of magnitude. However, many reactions are balanced by the inverse processes, and their net rates are comparable to those in the middle atmosphere. The calculated profile of CO is in excellent agreement with the Pioneer Venus and Venera 12 gas chromatographic measurements and slightly above the values from the nightside spectroscopy at 2.3 μm. The OCS profile also agrees with the nightside spectroscopy which is the only source of data for this species. The abundance and vertical profile of gaseous H2SO4 are similar to those observed by the Mariner 10 and Magellan radio occultations and ground-based microwave telescopes. While the calculated mean S3 abundance agrees with the Venera 11-14 observations, a steep decrease in S3 from the surface to 20 km is not expected from the observations. The ClSO2 and SO2Cl2 mixing ratios are ∼10−11 in the lowest scale height. The existing concept of the atmospheric sulfur cycles is incompatible with the observations of the OCS profile. A scheme suggested in the current work involves the basic photochemical cycle, that transforms CO2 and SO2 into SO3, CO, and Sx, and a minor photochemical cycle which forms CO and Sx from OCS. The net effect of thermochemistry in the lowest 10 km is formation of OCS from CO and Sx. Chemistry at 30-40 km removes the downward flux of SO3 and the upward flux of OCS and increases the downward fluxes of CO and Sx. The geological cycle of sulfur remains unchanged.  相似文献   

2.
3.
In situ measurements of the Venus atmosphere, made by the entry probes Venera 4, 5, 6, and 7, and data from the Mariner 5 flyby, have provided essentially new and reliable information and have powerfully contributed to our understanding of the nearest planet. The abundances of the principal atmospheric constituents and the temperature and pressure profiles down to the Venus surface were obtained for the first time. It was shown that the atmosphere is composed primarily of CO2 and that N2 (if any) and H2O are relatively minor admixtures. In the region of the Venera 7 landing, the temperature and pressure at the Venus surface were established as equal to 747 ± 20°K and 90 ± 15 kgcm−2. Space vehicles have also provided limited but quite important information on the physical properties of the Venus upper atmosphere and ionosphere, and on the interaction of the planet with the interplanetary environment. The main characteristics of the Venus atmosphere are discussed here with emphasis on the Venera results, including instrumentation, data processing, and altitude profiles.  相似文献   

4.
A.T. Young 《Icarus》1973,18(4):564-582
Water solutions of sulfuric acid, containing about 75% H2SO4 by weight, have a refractive index within 0.01 of the values deduced from polarimetric observations of the Venus clouds. These solutions remain liquid at the cloud temperature, thus explaining the spherical shape of the cloud particles (droplets). The equilibrium vapor pressure of water above such solutions is 0.01 that of liquid water or ice, which accounts for the observed dryness of the cloud region. Furthermore, H2SO4 solutions of such concentration have spectra very similar to Venus in the 8–13 μm region; in particular, they explain the 11.2 μm band. Cold sulfuric acid solutions also seem consistent with Venus spectra in the 3–4 μm region. The amount of acid required to make the visible clouds is quite small, and is consistent with both the cosmic abundance of sulfur and the degree of out-gassing of the planet indicated by known atmospheric constituents. Sulfuric acid occurs naturally in volcanic gases, along with known constituents of the Venus atmosphere such as CO2, HCl, and HF ; it is produced at high temperature by reactions between these gases and common sulfate rocks. The great stability and low vapor pressure of H2SO4 and its water solutions explain the lack of other sulfur compounds in the atmosphere of Venus—a lack that is otherwise puzzling.Sulfuric acid precipitation may explain some peculiarities in Venera and Mariner data. Because sulfuric acid solutions are in good agreement with the Venus data, and because no other material that has been proposed is even consistent with the polarimetric and spectroscopic data, H2SO4 must be considered the most probable constituent of the Venus clouds.  相似文献   

5.
The model is intended to respond to the recent findings in the Venus atmosphere from the Venus Express and ground-based submillimeter and infrared observations. It extends down to 47 km for comparison with the kinetic model for the lower atmosphere (Krasnopolsky, V.A. [2007]. Icarus 191, 25–37) and to use its results as the boundary conditions. The model numerical accuracy is significantly improved by reduction of the altitude step from 2 km in the previous models to 0.5 km. Effects of the NUV absorber are approximated using the detailed photometric observations at 365 nm from Venera 14. The H2O profile is not fixed but calculated in the model. The model involves odd nitrogen and OCS chemistries based on the detected NO and OCS abundances. The number of the reactions is significantly reduced by removing of unimportant processes. Column rates for all reactions are given, and balances of production and loss may be analyzed in detail for each species.The calculated vertical profiles of CO, H2O, HCl, SO2, SO, OCS and of the O2 dayglow at 1.27 μm generally agree with the existing observational data; some differences are briefly discussed. The OH dayglow is ~30 kR, brighter than the OH nightglow by a factor of 4. The H + O3 process dominates in the nightglow excitation and O + HO2 in the dayglow, because of the reduction of ozone by photolysis. A key feature of Venus’ photochemistry is the formation of sulfuric acid in a narrow layer near the cloud tops that greatly reduces abundances of SO2 and H2O above the clouds. Delivery of SO2 and H2O through this bottleneck determines the chemistry and its variations above the clouds. Small variations of eddy diffusion near 60 km result in variations of SO2, SO, and OCS at and above 70 km within a factor of ~30. Variations of the SO2/H2O ratio at the lower boundary have similar but weaker effect: the variations within a factor of ~4 are induced by changes of SO2/H2O by ±5%. Therefore the observed variations of the mesospheric composition originate from minor variations of the atmospheric dynamics near the cloud layer and do not require volcanism. NO cycles are responsible for production of a quarter of O2, SO2, and Cl2 in the atmosphere. A net effect of photochemistry in the middle atmosphere is the consumption of CO2, SO2, and HCl from and return of CO, H2SO4, and SO2Cl2 to the lower atmosphere. These processes may be balanced by thermochemistry in the lower atmosphere even without outgassing from the interior, though the latter is not ruled out by our models. Some differences between the model and observations and the previous models are briefly discussed.  相似文献   

6.
While CO, HCl, and HF, that were considered in the first part of this work, have distinct absorption lines in high-resolution spectra and were detected four decades ago, the lines of HDO, OCS, and SO2 are either very weak or blended by the telluric lines and have not been observed previously by ground-based infrared spectroscopy at the Venus cloud tops. The H2O abundance above the Venus clouds is typically below the detection limit of ground-based IR spectroscopy. However, the large D/H ratio on Venus facilitates observations of HDO. Converted to H2O with D/H ≈ 200, our observations at 2722 cm−1 in the Venus afternoon show a H2O mixing ratio of ∼1.2 ppm at latitudes between ±40° increasing to ±60° by a factor of 2. The observations in the early morning reveal the H2O mixing ratio that is almost constant at 2.9 ppm within latitudes of ±75°. The measured H2O mixing ratios refer to 74 km. The observed increase in H2O is explained by the lack of photochemical production of sulfuric acid in the night time. The recent observations at the P-branch of OCS at 4094 cm−1 confirm our detection of OCS. Four distributions of OCS along the disk of Venus at various latitudes and local times have been retrieved. Both regular and irregular components are present in the variations of OCS. The observed OCS mixing ratio at 65 km varies from ∼0.3 to 9 ppb with the mean value of ∼3 ppb. The OCS scale height is retrieved from the observed limb darkening and varies from 1 to 4 km with a mean value of half the atmospheric scale height. SO2 at the cloud tops has been detected for the first time by means of ground-based infrared spectroscopy. The SO2 lines look irregular in the observed spectra at 2476 cm−1. The SO2 abundances are retrieved by fitting by synthetic spectra, and two methods have been applied to determine uncertainties and detection limits in this fitting. The retrieved mean SO2 mixing ratio of 350 ± 50 ppb at 72 km favors a significant increase in SO2 above the clouds since the period of 1980-1995 that was observed by the SOIR occultations at Venus Express. Scale heights of OCS and SO2 may be similar, and the SO2/OCS ratio is ∼500 and may be rather stable at 65-70 km under varying conditions on Venus.  相似文献   

7.
The role of SO2 in the chemistry of the clouds of Venus has been investigated by deducing its mixing ratio profile in the atmosphere through millimeter wavelength interferometric measurements of the planet's limb darkening. The first zero crossing of the Venus visibility function was measured to be β0 = 0.6221 ± 0.0007 at a wavelength of 3.4 mm using a reference radius for Venus of 6100 km. This measurement constrains the amount of limb darkening and shows that the high concentrations of SO2 found in the lower atmosphere do not persist above an altitude of 42 km. Thus, a sink for SO2 exists below the level of the lowest cloud deck.  相似文献   

8.
Sulfur dioxide has a strong and complex rotational spectrum in the microwave and far infrared regions. The microwave absorption due to SO2 in a CO2 mixture is calculated for conditions applicable to the Venus atmosphere. It is shown that at the concentrations detected by Pioneer-Venus in situ measurements, SO2 may be expected to contribute significantly to the microwave opacity of the Venus atmosphere. In particular, SO2 might provide the major source of opacity in the atmospheric region immediately below the main sulfuric acid cloud deck. The spectrum is largely nonresonant at the pressures where SO2 is expected to occur, however.  相似文献   

9.
Yong Hong  Bruce Fegley Jr. 《Icarus》1997,130(2):495-504
We use gas chromatography to identify and measure the amounts of carbonyl sulfide (OCS) formed in a gas-flow system via the net thermochemical reactionsat temperatures of 470–612°C and ambient atmospheric pressure. The goal of our work is to evaluate the importance of reactions (1) to (3), which have been proposed as potential sources of OCS in Venus' lower atmosphere. Our results show OCS formation by reaction (3), but not by reactions (1) or (2) under our experimental conditions. Based on our results, experimental data from the literature, and theoretical models in the literature, we conclude that (1) the reaction of S2and CO is an important source of OCS in Venus' lower atmosphere, and (2) probably neither reaction (1) nor reaction (2) is an important source of OCS on Venus. Finally, we use thermodynamic data for reaction (3) and Venera spacecraft observations of CO and sulfur vapor at 0–12-km altitude to calculate an OCS equilibrium abundance of 1–14 ppmv, with a nominal value of 5 ppmv, for reaction (3) near Venus' surface.  相似文献   

10.
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO2. O stimulates cooling by the emission at 15 μm in the collisions with CO2. (3) There is a great progress in the observations of photochemical tracers and minor constituents on Mars in the current decade. This progress is supported by progress in photochemical modeling, especially by photochemical GCMs. Main results in these areas are briefly discussed. The problem of methane presents the controversial aspects of its variations and origin. The reported variations of methane cannot be explained by the existing data on gas-phase and heterogeneous chemistry. The lack of current volcanism, SO2, and warm spots on Mars favor the biological origin of methane. (4) Venus’ chemistry is rich and covers a wide range of temperatures and pressures and many species. Photochemical models for the middle atmosphere (58-112 km), for the nighttime atmosphere and night airglow at 80-130 km, and the kinetic model for the lower atmosphere are briefly discussed.  相似文献   

11.
Venus was observed at 2.4 and 3.7 μm with a resolving power of 4×104 using the long-slit high-resolution spectrograph CSHELL at NASA IRTF. The observations were made along a chord that covered a latitude range of ± 60° at a local time near 8:00. The continuous reflectivity and limb brightening at 2.4 μm are fitted by the clouds with a single scattering albedo 1−a=0.01 and a pure absorbing layer with τ=0.09 above the clouds. The value of 1−a agrees with the refractive index of H2SO4 (85%) and the particle radius of 1 μm. The absorbing layer is similar to that observed by the UV spectrometer at the Pioneer Venus orbiter. However, its nature is puzzling. CO2 was measured using its R32 and R34 lines. The retrieved product of the CO2 abundance and airmass is constant at 1.9 km-atm along the instrument slit in the latitude range of ± 60°. The CO mixing ratio (measured using the P21 line) is rather constant at 70 ppm, and its variations of ∼10% may be caused by atmospheric dynamics. The observed value is higher than the 50 ppm retrieved previously from a spectrum of the full disk, possibly, because of some downward extension of the mesospheric morningside bulge of CO. The observations of the HF R3 line reveal a constant HF mixing ratio of 3.5±0.5 ppb within ± 60° of latitude, which is within the scatter in the previous measurements of HF. OCS has been detected for the first time at the cloud tops by summing 17 lines of the P-branch. The previous detections of OCS refer to the lower atmosphere at 30-35 km. The retrieved OCS mixing ratio varies with a scale height of 1 to 3 km. The mean OCS mixing ratio is ∼2 ppb at 70 km and ∼14 ppb at 64 km. Vertical motions in the atmosphere may change the OCS abundance. The detected OCS should significantly affect Venus' photochemistry. A sensitive search for H2S using its line at 2688.93 cm−1 results in a 3 sigma upper limit of 23 ppb, which is more restrictive than the previous limit of 100 ppb.  相似文献   

12.
Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO2 using its spectral absorption bands near 280 and 220 nm. SO2 column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO2 column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO2 content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO2 column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO2 into the upper atmosphere.  相似文献   

13.
Some features of the wind-velocity determination based on the results of Doppler shift measurements from the Venera probes during their descent in the Venus atmosphere are discussed. The validity of assumptions used in the reduction and analysis of these data are treated in connection with the preceding paper by Ainsworth and Herman. We conclude that the Venera velocity profiles are a valid representation of Venus atmospheric conditions.  相似文献   

14.
A multi-wavelength radio frequency observation of Venus was performed on April 5, 1996, with the Very Large Array to investigate potential variations in the vertical and horizontal distribution of temperature and the sulfur compounds sulfur dioxide (SO2) and sulfuric acid vapor (H2SO4(g)) in the atmosphere of the planet. Brightness temperature maps were produced which feature significantly darkened polar regions compared to the brighter low-latitude regions at both observed frequencies. This is the first time such polar features have been seen unambiguously in radio wavelength observations of Venus. The limb-darkening displayed in the maps helps to constrain the vertical profile of H2SO4(g), temperature, and to some degree SO2. The maps were interpreted by applying a retrieval algorithm to produce vertical profiles of temperature and abundance of H2SO4(g) given an assumed sub-cloud abundance of SO2. The results indicate a substantially higher abundance of H2SO4(g) at high latitudes (above 45°) than in the low-latitude regions. The retrieved temperature profiles are up to 25 K warmer than the profile obtained by the Pioneer Venus sounder probe at altitudes below 40 km (depending on location and assumed SO2 abundance). For 150 ppm of SO2, it is more consistent with the temperature profile obtained by Mariner 5, extrapolated to the surface via a dry adiabat. The profiles obtained for H2SO4(g) at high latitudes are consistent with those derived from the Magellan radio occultation experiments, peaking at around 8 ppm at an altitude of 46 km and decaying rapidly away from that altitude. At low latitudes, no significant H2SO4(g) is observed, regardless of the assumed SO2 content. This is well below that measured by Mariner 10 (Lipa and Tyler 1979, Icarus39, 192-208), which peaked at ∼14 ppm near 47 km. Our results favor ≤100 ppm of SO2 at low latitudes and ≤50 ppm in polar regions. The low-latitude value is statistically consistent with the results of Bézard et al. (1983, Geophs. Res. Lett.20, 1587-1590), who found that a sub-cloud SO2 abundance of 130±40 ppm best matched their observations in the near-IR. The retrieved temperature profile and higher abundance of H2SO4(g) in polar regions are consistent with a strong equatorial-to-polar, cloud-level flow due to a Hadley cell in the atmosphere of Venus.  相似文献   

15.
New data about the top clouds of Venus were obtained during the radiometric experiment on-board the Venera 9 and Venera 10 orbiters. A diurnal component of the ir thermal radiation was determined for the latitude range ?40, +50°. The brightness temperature of radiation referred to the normal was measured; it was 244°K at night and 239°K at the subsolar point for the 7- to 13-, 17- to 30-μm bands. Minimum temperatures correspond to the meridian of local time 16.00h and are 232°K. There is also a zone of lower temperatures in the region of local time 7.5h. Absolute temperatures were measured with an accuracy of ?1.9°+1.2°. Thermal radiation has no distinct latitudinal dependence but has a day-night asymmetry, with the night radiation flux exceeding that on the day side by 17%. The limb-darkening law for thermal radiation is rather complicated, depending on the time of day. There are at least two states of the radiating cloud cover: day and night. The extinction coefficient is close to 0.24 km?1. The analysis shows that the source function of the medium is close to Planck's function. During the day the flux of thermal radiation is assumed to be weakened by an aerosol medium forming by photochemical processes. Comparison of experimental and calculated data yields a particle concentration in the radiating cloud cover of about 95 cm?3. Experimental data and the results of ground-based measurements were used to determine the radiometric albedo of Venus, 0.79?0.01+0.02.  相似文献   

16.
《Planetary and Space Science》2007,55(12):1712-1728
The structure of the Venus atmosphere is discussed. The data obtained in the 1980s by the last Soviet missions to Venus: orbiters Venera 15, 16 and the entry probes and balloons of Vega 1 and 2 are compared with the Venus International Reference Atmosphere (VIRA) model. VIRA is based on the data of the extensive space investigations of Venus in the 1960s and 1970s. The results of the IR Fourier Spectrometry experiment on Venera 15 are reviewed in detail. This instrument is considered as a precursor of the long wavelength channel of the Planetary Fourier Spectrometer on Venus Express.  相似文献   

17.
Recent papers attributing the observed microwave opacity of the middle atmosphere of Venus to gaseous sulfur dioxide (SO2) and other cloud-related gases have motivated laboratory measurements of their microwave absorbing properties under simulated conditions for this region. In the pressure range from 1 to 5 atmospheres and in the temperature range from 297 to 355°K, the absorption of SO2 in a carbon dioxide (CO2) atmosphere, at 2.257 and 8.342 GHz, has been found to be approximately 50% larger than that calculated from Van Vleck-Weisskopf theory. The measured absorption is about 25 × 106 q?2p1.20 T?3.1 (dB km?1), where q is the sulfur dioxide number mixing ratio, ? is frequency in gigahertz, p is pressure in atmospheres, and T is temperature in degrees Kelvin. This represents the best-fit expression to the observed pressure dependence, while theoretical values of frequency and temperature dependence are accepted as being consistent with the measurements. Another cloud-related gas, sulfur trioxide (SO3), was also tested in a CO2 atmosphere and found to be relatively transparent. These results reduce the amount of SO2 in the Venus middle atmosphere required to explain the opacity measured by radio occulatation, but this amount still exceeds the abundance measured in situ by atmospheric probes, suggesting that there must be another important source of opacity. Preliminary measurements of the 13-cm absorptivity of gaseous sulfuric acid (H2SO4) show it to be a strong microwave absorber, and thus likely to be responsible for a significant and possibly major part of the observed opacity.  相似文献   

18.
A. Seiff  Donn B. Kirk 《Icarus》1982,49(1):49-70
Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27°S latitude. Comparison of the midnight sounding with the morning sounding at 31°S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of G. M. Keating, J. Y. Nicholson, and L. R. Lake (1980, J. Geophys. Res., 85, 7941–7956) above 140 km with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are ~ 130°K, somewhat warmer than those reported by Keating et al.  相似文献   

19.
Two extreme ultraviolet (EUV) spectrophotometers flown in December 1978 on Venera 11 and Venera 12 measured the hydrogen Lyman α emission resonantly scattered in the atmosphere of Venus. Measurements were obtained across the dayside of the disk, and in the exosphere up to 50,000 km. They were analyzed with spherically symmetric models for which the radiative transfer equation was solved. The H content of the Venus atmosphere varies from optically thin to moderately thick regions. A shape fit at the bright limb allows one to determine the exospheric temperature Tc and the number density nc independently of the calibration of the instrument or the exact value of the solar flux. The dayside exospheric temperature was measured for the first time in the polar regions, with Tc = 300 ± 25°K for Venera 11 (79°S) and Tc = 275 ± 25°K (59°S) for Venera 12. At the same place, the density is nc = 4?2+3 × 104 atom.cm?3, and the integrated number density Nt from 250 to 110 km (the level of CO2 absorption) is 2.1 × 1012 atom.cm?2, a factor of 3 to 6 lower than that predicted in aeronomical models. This probably indicates that the models should be revised in the content of H-bearing molecules and should include the effect of dynamics. Across the disk the value of Nt decreases smoothly with a total variation of two from the morning side to the afternoon side. Alternately it could be a latitude effect, with less hydrogen in the polar regions. The nonthermal component if clearly seen up to 40,000 km of altitude. It is twice as abundant as at the time of Mariner 10 (solar minimum). Its radial distribution above 4000 km can be simulated by an exospheric distribution with T = 1030K and n = 103 atom.cm?3 at the exobase level. However, there are less hot atoms between 2000 and 4000 km than predicted by an ionospheric source. A by-product of the analysis is a determination of a very high solar Lyman α flux of 7.6 × 1011 photons (cm2 sec Å)?1 at line center (1 AU) in December 1978.  相似文献   

20.
This paper presents the principal results of wind velocity and turbulence measurements in the Venus atmosphere during the Venera flights.  相似文献   

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