Experimental investigations on the elastic parameters and uniaxial compressive strength of slate under freeze–thaw cycles

ABSTRACT

In this study, uniaxial compression experiments with seven different bedding angles and six numbers of freeze–thaw cycles were conducted to investigate the influences of freeze–thaw cycles on the elastic parameters and the uniaxial compressive strength of slate. The laws of the elastic parameters, uniaxial compressive strength and failure characteristics were analysed, and a new uniaxial compressive strength prediction model that considers the bedding angle and the number of freeze–thaw cycles as control variables was established and verified using the experimental data. The results showed that the uniaxial compressive strength, elastic modulus and shear modulus decreased exponentially with an increasing number of freeze–thaw cycles. However, the Poisson’s ratio increased linearly with an increasing number of freeze–thaw cycles. The uniaxial compressive strength initially decreased and then increased with increasing bedding angle. There are three forms of failure occurred during the tests: when the bedding angle was 0°≤β ≤ 26.6°, the splitting failure and shear failure occurred at the same time; when the bedding angle was 26.6°≤β ≤ 83.0°, sliding failure occurred along the bedding plane; and when the bedding angle was 83.0°≤β ≤ 90°, splitting failure occurred along the axial direction of sample.     

Microstructural weathering of sedimentary rocks by freeze–thaw cycles: Experimental study of state and transfer parameters

The frost sensitivity of a rock is resulting from the combined action of processes linked to porous network characteristics (state parameters) and to the way water flows into this porous network (transfer parameters), our study was thus about the influence of these parameters on frost weathering of rocks. Sedimentary rocks often found on buildings (limestone and sandstone) and consequently submitted to temperature variations have been selected. State and transfer parameters have been measured for sample characterization and the follow-up of weathering during freeze–thaw cycles. The coupled influence of a state parameter (dynamic modulus of elasticity) and a transfer parameter (water permeability), i.e. between rock skeletal strength and voids connection, has thus been discussed.     

Effect of freeze–thaw cycles on strength and ductility and microstructure of cement-treated silt with polypropylene fiber

Acta Geotechnica - In this paper, the strength, ductility and microstructure behavior of cement-treated silt with polypropylene fiber was studied by a host of experimental studies. The influence of...     

Constitutive model for tailing soils subjected to freeze–thaw cycles based on meso-mechanics and homogenization theory

A constitutive model is proposed for tailing soils subjected to freeze–thaw cycles based on the meso-mechanics and homogenization theory. The evolution of meso-structure upon loading was analyzed within the framework of breakage mechanism. When the new model is formed, tailing soils are idealized as composite materials composed of bonded elements described by an elastic brittle model and frictional elements described by a double hardening model. Based on meso-mechanics and homogenization theory, the nonuniform distributions of stress and strain within the representative volume element are given by introducing a structure parameter of breakage ratio with the derivation of the strain coefficient tensor, which connects the strains of the bonded elements and the representative volume element. The methods for determining model parameters are suggested based on the available tested results. The model proposed here can predict the deformation properties of tailing soils experiencing freeze–thaw cycles with acceptable accuracy. The strain-hardening and post-peak strain-softening behaviors of tailing soils under various confining pressures as well as different numbers of freeze–thaw cycles are well captured, and the dilatancy and contraction features are also adequately represented.

     

Moisture–temperature changes and freeze–thaw hazards on a canal in seasonally frozen regions

Freeze–thaw action is a complex moisture–heat-mechanics interaction process, which has caused prevailing and severe damages to canals in seasonally frozen regions. Up to now, the detailed frost damage mechanism has not been well disclosed. To explore the freeze–thaw damage mechanism of the canal in cold regions, a numerical moisture–heat-mechanics model is established and corresponding computer program is written. Then, a representative canal in the northeast of China is taken as an example to simulate the freeze–thaw damage process. Meanwhile, the robustness of the numerical model and program is tested by some in situ data. Lastly, the numerical results show that there are dramatic water migration and redistribution in the seasonal freeze–thaw variation layer, causing repetitive frost heave and thaw settlement, and tension–compression stresses. Therefore, the strengths of soil are reduced after several freeze–thaw cycles. Further, the heavy denudation damage and downslope movement of the canal slope would be quite likely triggered in seasonally frozen regions. These zones should be monitored closely to ensure safe operation. As a preliminary study, the numerical model and results in this paper may be a reference for design, maintenance, and research on other canals in seasonally frozen regions.     

Analysis of the correlations between freeze–thaw and salt crystallization tests

Two of the most popular weathering tests used for dimension stone are EN 12371 freeze–thaw (FT) and EN 12370 Salt Crystallization (SC). These tests are used to assign a durability value to the rocks. Both tests are based on the cyclical growth of crystals in the porous system of the rock, which causes structural stress on the rock matrix that may affect its integrity. The weathering mechanism is the same in both tests although the rate of volume increase is higher for the salt crystals. Due to this similarity, the two tests provide complementary information. The EN (European Norms) recommend evaluating the results together, but do not establish correlations between the results of these two tests for different types of rocks. Knowing these relationships would improve the understanding of the results and the response to weathering of the rock once placed in a building. In this work, several ornamental rocks (sandstones, limestones, dolostones, and a travertine) from the Iberian Peninsula were submitted to FT and SC tests. Rocks were mineralogically and petrographically characterized, and their porous systems were defined by a combination of techniques (scanning electronic microscopy, digital images analysis, and mercury porosimetry). The results of the tests were quantified numerically to compare them. The velocity of propagation of ultrasonic waves was measured before and after the tests. After the statistical analysis, significant correlations were found between the FT and SC tests, and between the connected porosity and the durability index of the rocks.     

Amphiboles and coexisting ferromagnesian silicates in granitic rocks in Mahé, Seychelles

A variety of granitic rocks from granodiorite to alkaline granite is developed in Mahé island, Seychelles, Microprobe analyses were made on amphiboles and coexisting minerals.Amphibole constitutes the most prominent ferromagnesian minerals in the Seychelles granitic rocks. Its chemical composition ranges widely from calcic through sodic-calcic to alkali amphiboles and amphibole composition evolves systematically from Fe-poor to Fe-rich: magnesiohornblende → ferrohornblende → ferroedenite → silicic ferroedenite → ferrorichterite and ferrowinchite → riebeckite. Riebeckite occurs abundantly in the alkaline rocks as subsolidus minerals. Throughout the evolution two types of isomorphous substitution, Mg ⇌ Fe²⁺ and Al + Ca ⇌ Si + Na principally took place. Compositions of clinopyroxene and biotite also evolve from Fe-poor to Fe-rich varieties. All these compositional evolutions of the constituent minerals suggest a comagmatic origin of the Seychelles granitic rocks studied.In the Seychelles alkaline magma, ferrorichterite crystallized at the late-magmatic stage under conditions of 650–700°C in temperature and of slightly above the QFM buffer in oxygen fugacity. With falling temperature, oxidizing condition prevailed and riebeckite crystallized.Generally, in alkaline granite and quartz syenite magmas, ferrorichterite evolves continuously to arfvedsonitic compositions when oxygen fugacity is defined by QFM buffer even during subsolidus stage. On the other hand, ferrorichterite evolves to riebeckite composition when oxidizing condition prevails. But, in this case, continuous solid solution between ferrorichterite and riebeckite is not found, presumably owing to an existence of a compositional gap between them.     

Fracture mechanism of rock collapse in the freeze–thaw zone of the eastern Sichuan–Tibet Mountains under seasonal fluctuating combinations of water and heat

Natural Hazards - In the freeze–thaw zone of the eastern Sichuan–Tibet Mountains, the phases of water in cracks show strong seasonal variations, which significantly affect the stability...     

Interactions between freeze–thaw actions,wind erosion desertification,and permafrost in the Qinghai–Tibet Plateau

The unique natural environment of the Qinghai–Tibet Plateau has led to the development of widespread permafrost and desertification. However, the relationship between desertification and permafrost is rarely explored. Here we study the interaction between desertification and permafrost using a combination of simulations, experiments, and field observations in the Qinghai–Tibet Plateau. Results show the cohesion values of the test samples that experienced 1, 3, and 6 freeze–thaw cycle times decreased by 65.9, 46.0, and 35.5 %, respectively, and the compressive strength of the test samples decreased by 69.6, 39.6, and 34.7 %, respectively, compared to the test samples that did not experience freeze–thaw cycles. The wind erosion rate of the test block eroded by sand-bearing wind was far larger than that by clean wind under the same conditions; the maximum value was 50 times higher than that by clean wind. The wind erosion rate increased with an increasing number of freeze–thaw cycles, water content, and freeze–thaw temperature difference. The ground temperature below the sand layer was decreased, compared to the natural ground surface that without sand layer covering, the drop amplitude of yearly average temperature was roughly maintained at 0.2 °C below the thick sand layer (1.2 m), and the maximum drop of yearly average temperature was 0.7 °C below the thin sand layer (0.1 m). Therefore, with the presence of water, the destruction of surface soil structure caused by repeated and fierce freeze–thaw actions is the main cause of wind erosion desertification in the permafrost region of Qinghai–Tibet Plateau, and sand-bearing wind is the main dynamic force. The development of eolian sand deposits after the desertification emerges. As a result, the properties of the underlying surface are altered. Due to the high reflectivity and poor heat conductivity of the sand layer, the heat exchange of the land–atmosphere system is impeded, causing a drop in the ground temperature of the underlying permafrost that subsequently preserves the permafrost.     

Geochemical and Sr–Nd isotopic characteristics of granitic rocks from northern Vietnam

Five major felsic igneous suites from northern Vietnam, with ages from mid-Proterozoic to early Cenozoic, were studied. Representative granitic rocks from the Posen Complex (mid-Proterozoic) and the Dienbien Complex (late Permian to early Triassic) show geochemical characteristics similar to those of calc-alkaline to high-K calc-alkaline I-type granites. However, the former, located in the South China block, has significantly higher initial Nd isotopic ratios [ε_Nd(T)=+0.7 to +1.5] and older Nd isotopic model ages (TDM∼1.7 Ga) than the latter [ε_Nd(T)=−4.7 to −9.7; T_DM∼1.3–1.5 Ga] which were emplaced south of the Song Ma Suture and thus in the Indochina block. The generation of both complexes may be attributed to subduction-related processes that occurred in two distinct crustal provenances with different degrees of mantle inputs. On the other hand, Jurassic to Cretaceous granitic rocks from the Phusaphin Complex, contemporaneous rhyolites from the Tule Basin, and late Paleogene granitic rocks from the Yeyensun Complex, all exposed in the South China block between the Ailao Shan–Red River shear zone and the Song Ma Suture, display geochemical features similar to those of A-type granites with intermediate ε_Nd(T) values (+0.6 to −2.8) and younger T_DM ages (0.6–1.1 Ga). These magmas are suggested to have been generated as a consequence of intraplate extension in the western part of the South China block (Yunnan), and to have been transported to their present position by mid-Tertiary continental extrusion along the Ailao Shan–Red River shear zone related to the India–Asia collision. Overall, the isotopic and model age data, reported in this study indicate that in northern Vietnam, the most important crust formation episode took place in the Proterozoic. Likewise, repeated mantle inputs have played a role in the petrogenesis of Phanerozoic granitic rocks.     

Experimental study on mechanical properties of granite after freeze–thaw cycling

It is important to understand the effect of freeze–thaw cycles on the mechanical properties of rocks. In this paper, the variation of the uniaxial compressive strength, peak strain, elastic modulus and stress–strain curves of granite subjected to freeze–thaw cycles with different heating temperatures were studied experimentally and the relationships were derived. As the number of freeze–thaw cycles increases, the compressive strength and elastic modulus decrease, while the peak strain decreases. In addition, an increased temperature increases the peak strain while decreasing the compressive strength and elastic modulus. An expression for the initial damage for the adopted rock material due to freeze–thaw cycling was proposed based on the Loland model. The current research has established a solid foundation for further experimental studies on the fatigue behavior of granite after freeze–thaw cycling.     

Creep behavior of soft clay subjected to artificial freeze–thaw from multiple-scale perspectives

Relying on the application of the artificial freezing method on subway tunnel construction, a series of triaxial creep tests were carried out to study the creep behavior changes of Shanghai soft clay subjected to artificial freeze–thaw action. On this basis, MIP tests were conducted with the soil samples before and after creep for comparison to investigate the microstructure changes. The results indicate that freeze–thawed soil produces smaller creep deformation and instantaneous deformation than the unfrozen soil. On a micro-level, during the creep process, the soil skeleton reaches a new structure balance with smaller pore volume and pore area. But the diameter of the maximum pore increases. The change rate of total intrusion volume is a pivotal micro-parameter to evaluate creep strain as there is a good linear relationship between them.

     

Thermo-hydro-mechanical process and damage mechanism of a cold-region canal under coupled wetting–drying and freezing–thawing cycles

Acta Geotechnica - In cold regions, periodic wetting–drying and freezing–thawing (WDFT) actions lead to frequent and heavy canal damage, weakening the water-conveyance capacities of...     

Late Pleistocene vegetation change in Korea and its possible link to East Asian monsoon and Dansgaard–Oeschger (D–O) cycles

Late Pleistocene carbon isotope (δ¹³C) records from a paleolithic sedimentary sequence collected from Baeki, Hongcheon, central Korea, show long-term changes with superimposed short-term isotopic excursions. The δ¹³C value of the sedimentary organic matter, a proxy for past vegetation change, varied from ? 26‰ to ? 23‰ for the period between 30 and 90 ka, with a long-term variation similar to insolation changes. High-amplitude (? 1‰ to approximately ? 1.5‰) fluctuations superimposed on the long-term changes in the δ¹³C values decreased during stronger summer monsoon intervals but increased during the weakened summer monsoon. This millennial-scale pattern is generally similar to Greenland Dansgaard–Oeschger (D–O) cycles. The possible connection between the Hongcheon area, Korea and high latitudes may be explained by atmospheric circulation changing in response to the D–O oscillations in the Northern Hemisphere.     

Influence of freeze–thaw dynamics on internal geochemical evolution of low sulfide waste rock

Continuous monitoring of a 15 m high heavily instrumented experimental waste rock pile (0.053 wt.% S) since 2006 at the Diavik diamond mine in northern Canada provided a unique opportunity to study the evolution of fresh run-of-mine waste rock as it evolved over annual freeze–thaw cycles. Samples were collected from soil water solution samplers to measure pore water properties, from twelve 4 to 16 m² basal collection lysimeters to measure basal leachate properties in the region underlying the crest of the pile (the core), and from basal drains to measure aggregate total pile leachate properties. By 2012, monitoring of pore water geochemistry within the core structure of the test pile revealed an apparent steady state with respect to weathering geochemistry, represented by (i) a flush of pre-existing blasting residuals and applied tracers, (ii) declining pH, (iii) a stepwise progression and subsequent equilibrium with acid-neutralizing phases (depletion of available carbonates; equilibrium with respect to aluminum hydroxide phases and subsequent iron (III) hydroxide phases), and (iv) concordant release of SO₄, major cations (Ca, Mg, K, Na, Si), and trace metals (Al, Fe, Ni, Co, Cu, Zn). Distinct, high concentration ‘spring flushes’, characteristic of drainage in northern environments and primarily explained by a combination of fluid residence time and the build-up of oxidation products over the winter, were released from core drainage each season. Following the initial flush, the concentration of all dissolved constituents steadily declined, with distinct minimums prior to freeze-up. The opposite trend was observed in the cumulative pile drainage, in which early season leachate dominated by snowmelt and batter flow had low concentrations and late season leachate dominated by contributions from the core of the pile (indicated by season end merging of core and cumulative drainage geochemistry) had higher concentrations. Northern waste rock pile drainage geochemistry is strongly influenced by freeze–thaw cycling and varying core and batter subsystem contributions to total drainage. A comprehensive understanding of thermal cycling in waste rock piles is an important component of temporal predictions of drainage water composition based on up-scaling or reactive transport modeling.     

Annual soil CO2 efflux in a wet meadow during active layer freeze–thaw changes on the Qinghai-Tibet Plateau

Soil CO₂ efflux from an ecosystem responds to the active layer thawing depth (H) significantly. A Li-8100 system was used to monitor the CO₂ exchange from a wet meadow ecosystem during a freeze–thaw cycle of the active layer in a permafrost region on the Qinghai-Tibet Plateau. An exponential regression equation ( $ F_{\text{soil\, flux}} = 1.84e^{0.023H} + 5.06\,R^{2} = 0.96 $ ) has been established on the basis of observed soil CO₂ efflux versus the thawed soil thickness. Using this equation, the total soil CO₂ efflux during an annual freeze–thaw cycle has been calculated to be approximately 8.18 × 10¹⁰ mg C. The results suggest that freeze–thaw cycles in the active layer play an important role in soil CO₂ emissions and that thawed soil thickness is the major factor controlling CO₂ fluxes from the wet meadow ecosystem in permafrost regions on the Qinghai-Tibet Plateau. It can be concluded that with active layer thickening due to permafrost degradation, massive amounts of soil carbon would be emitted as greenhouse gases, and the permafrost region would become a carbon source with a positive feedback effect on climate warming. Hence, more attention should be paid to the influences of the active layer changes on soil carbon emission from these permafrost regions.     

Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study

Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.     

Late Oligocene–Miocene mantle upwelling and interaction inferred from mantle signatures in gabbroic to granitic rocks from the Urumieh–Dokhtar arc,south Ardestan,Iran

The south Ardestan plutonic rocks constitute major outcrops in the central part of Iran’s Cenozoic magmatic belt and encompass a wide compositional spectrum from gabbro to granodiorite. U–Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) dating of zircon three granodiorites yielded ages of 24.6 ± 0.1, 24.6 ± 0.1, and 24.5 ± 0.1 Ma. For tonalitic rocks, internal Rb–Sr isochron ages (biotite, feldspars) indicate cooling ages of 20.4 ± 0.1, 20.5 ± 0.1, and 22.3 ± 0.1 Ma, which are slightly younger than the zircons’ ages. The limited variations in their Sr–Nd isotope ratios indicate derivation from an asthenospheric mantle source. A geodynamic model is presented in which late Oligocene–Miocene rollback of the Neotethyan subducting slab triggered asthenospheric upwelling and partial melting in the south Ardestan. These melts were subsequently modified through fractional crystallization and minor crustal contamination en-route to the surface. Plagioclase + orthopyroxene-dominated fractional crystallization accounts for differentiation of gabbro to gabbroic diorite, whereas fractionation of clinopyroxene, titanomagnetite, and orthopyroxene led to differentiation of gabbroic diorite to diorite. Amphibole fractionation at deeper levels led to the development of tonalites.