Major Advances in the Study of the Precambrian Geology and Metallogenesis of the North China Craton: A Review

The North China Craton(NCC) is one of the most ancient cratons in the world and records a complex geological evolution since the early Precambrian. In addition to recording major geological events similar to those of other cratons, the NCC also exhibits some unique features such as multistage cratonization(late Archaean and Palaeoproterozoic) and long-term rifting during the Meso–Neoproterozoic. The NCC thus provides one of the best examples to address secular changes in geological history and metallogenic epochs in the evolving Earth. We summarize the major geological events and metallogenic systems of the NCC, so that the evolutionary patterns of the NCC can provide a better understanding of the Precambrian NCC and facilitate comparison of the NCC with other ancient continental blocks globally. The NCC experienced three major tectonic cycles during the Precambrian:(1) Neoarchaean crustal growth and stabilization;(2) Palaeoproterozoic rifting–subduction–accretion–collision with imprints of the Great Oxidation Event and(3) Meso–Neoproterozoic multi-stage rifting. A transition from primitive- to modern-style plate tectonics occurred during the early Precambrian to late Proterozoic and is evidenced by the major geological events. Accompanying these major geological events, three major metallogenic systems are identified:(1) the Archaean banded iron formation system;(2) Palaeoproterozoic Cu–Pb–Zn and Mg–B systems and(3) a Mesoproterozoic rare earth element–Fe–Pb–Zn system. The ore-deposit types in each of these metallogenic systems show distinct characteristics and tectonic affinities.     

Precambrian Geochronology, Chronotectonic Framework and Model of Chronocrustal Structure of the Zhongtiao Mountains

The Zhongtiao Mountains, a typical exposure area of Precambrian rocks, are a concentration area of vari-ous types of copper deposit. The rocks were dated using several dating methods. Based on the age data ob-tained by means of three methods, several aspects are dealt with: (1) the dating results obtained by differentmethods and their geological implications have been compared; (2) a chronotectonic framework has been con-structed by means of these reliable ages, which indicates that the ages of the rocks of the Proterozoic mobilebelt fall in a time span of 2400 to 2000 Ma during which global magmatic records are lacking and reflects theages of important events in the mobile belt; (3) according to the ages of inherited zircons, neodymium modelage of the depleted mantle sources (T_(DM)) and geochemical and geological data, a model of Precambrianchronocrustal structure has been constructed, representing a typical for the North China craton.     

Episodes of Cenozoic Gold Mineralization on the Eastern Margin of the Qinghai-Tibet Plateau:~(40)Ar/~(39)Ar Dating and Implication for Geodynamic Events

A lot of new gold deposits have been found on the eastern margin of the Qinghai-Tibet Plateau during the past two decades. Among them, three main types of gold deposits have been recognized, including quartz-vein-type, shearzone-type and porphyry-type. The former two types of gold deposits are mainly hosted within metamorphic rocks, while the latter is related to Cenozoic magmatism. Although all of these gold deposits are believed to have been formed during the uplift process of the Qinghai-Tibet Plateau in the Cenozoic era (Wang et al., 2002b), precise isotopic age constraints have still been lacking until quite recently. This paper presents new ^40Ar/^39Ar data of some gold deposits on the eastern margin of the Qinghai-Tibet Plateau, which indicate that gold mineralization in the region occurred in response to the episodic stages of the orogenies. Recently obtained ^40Ar/^39Ar data on quartz and feldspars from several gold deposits, such as the Sandiao deposit, the Baijintaizi deposit, the Pusagang deposits, provide new constraints on gold mineralization on the eastern margin of the Qinghai-Tibet Plateau. Geochronological studies of gold deposits along the Daduhe River indicate that there are three stages of gold mineralization. The early two stages occurred as early as 65.1 Ma in the Shuibaiyang deposit and 58.95 Ma in the Ruoji deposit, while the latter stage occurred as late as 25.35 Ma in Baijintaizi and 24.70 Ma in Sandiao. Isotopic dating of three plagioclases from the Beiya deposit, Zhifanggou deposit and Luobodi deposit and a K-feldspar from the Jinchangqing deposit in Yunnan Province indicates that these deposits were formed at two stages. The Zhifanggou and Jinchangqing deposits have early stage records as old as 58.82 Ma in Zhifanggou and 55.49 Ma in Jinchangqing, but all of the above four deposits in Yunnan have late stage records of 23.18 Ma in Jinchangqing, 24.54 Ma in Zhifanggou, 24.60 Ma in Luobodi and 24.56 Ma in Hongnitang. The above results suggest that the gold deposits on the eastern margin of the Qinghai-Tibet Plateau were formed concentratedly at two main episodes, i.e. the end of the Paleocene (about 58 Ma) and the boundary between the Paleogene and the Neogene (about 25 Ma). The later episode appears to be looks like more important and was coupled with the Sichuan movement, which was extensively activated at that period. The beginning of the Cenozoic Era (about 65 Ma) might be another episode of gold mineralization, but only one deposit (Shuibaiyang) in this study has been proved to have been be formed at this stage and might be earlier than the initial collision between the Indian Plate and the Eurasia Plate. In view of geology, the above three episodes of gold mineralization are associated with three events of tectonicmagmatism and/or fluid events. Even though the gold deposits (for example, the Shuibaiyang deposit, Ruoji deposit and Pusagang deposit) were formed at different episodes, all of them are genetically related to tectonic movements in largescale shear zones. It looks like theat tectonic events (including large-scale strike-slip) between Paleogene and Neogene had a wide influence upon gold mineralization, with new deposits formed and old deposits enriched or superimposed to be a higher grade by new stage of mineralization. The above data suggest that gold deposits were not only concentrated in some areas, but also formed mainly at different boundaries of geological times, indicating that there existed some peak stages of gold mineralization (metallogenic episodes), and that the gold deposits were formed mainly by episodic mineralization.     

Geological Characteristics and Manifestations of Geological Processes of Sequence Boundaries and Their Vicinities

This paper discusses the geological characteristics and architectures of sequence boundaries and their vicinities and has proposed a classification scheme for the sequence boundaries, which can thus be grouped into three types and eight categories: type I includes exposed truncated surface, palaeosol surface, palaeokarst surface and exposed surface; type Ⅱ boundaries include structural transitional surface during sea-level fall and transgressive onlap surface; and type Ⅲ includes submarine erosional diagenetic diastem and event surface. A study has been made for the three major boundaries lying between the Permian and pre-Permian, the Permian and Triassic, and the Middle and Lower Triassic respectively in terms of multiple disciplines such as lithostratigraphy, biostratigraphy, magnetostratigraphy and carbon and oxygen isotopic geology. These three boundaries are ascribed to type I , typeⅡ and typeⅢ, respectively.     

Possibility of the Application of the Ultra-long Electromagnetic Wave Remote Sensor to Marine Geological Exploration

The ultra-long electromagnetic wave remote sensing technique developed by Peking University is one of new future techniques, which can detect the submarine geological information from the depth of 20 to 10000 m below the surface by receiving natural ultra-long electromagnetic waves (n Hz to n 100 Hz). The new remote sensor is composed of three parts: a main instrument with a portable computer, an antenna with an amplifier and an external power.The new remote sensing technique is characterized by good stability and reproducibility at the same spot but at different times and high sensitivity and high signal-to-noise ratio, and can reveal geological and lithologic boundaries as well as strata and related mineral sources. Two years of marine geological experiments on this technique have indicated that it can solve many problems in marine geological exploration, e.g. the burial depths of sea-floor mud, Quaternary sediments and submarine structures. This technique can be applied to detecting the sea bed depth     

Formation Mechanism of "Drag Depressions" and Irregular Boundaries in Intraplate Deformation

Almost all intraplate caprocks experienced strong deformation during the convergence of microplates, and then disintegrated into many secondary geologic units with the special characters, such as irregular boundaries and particular structural assemblages. In order to understand the formation mechanism of these special phenomena, a rheological experiment on the structural scenery of the Tongling area is carried out. The result shows that the primary regular and uniform boundaries of the Tongling area becomes irregular because of the enclosing and confinement of surrounding geological units in the process of "compression-shearing-rotation-drag"; simultaneously, two specific "drag depressions" developed at two opposite corners of the block. The former and the later phenomena can be regarded as a typical regional-scale rheological effect and necessary outcome of intraplate deformation respectively.     

Carbon and Strontium Isotopes of Late Palaeozoic Marine Carbonates in the Upper Yangtze Platform,Southwest China

238 marine carbonate samples were collected from seven sedimentary sections ofthe entire late Palaeozoic (Permian, Carboniferous and Devonian) in the Upper Yangtze Plat-form, southwest China. Based on the absence of cathodoluminescence and very low Mn (gener-ally<50 ppm) contents of the samples, it is thought that they contain information on the orig-inal sea water geochemistry. The results of isotopic analyses of these samples are presented interms of δ~(13)C and ~(87)Sr/~(86)Sr ratios versus geological time. The strontium data, consistent withother similar data based on samples from North America, Europe, Africa and other areas inAsia, support the notion of a global consistency in strontium isotope composition of marinecarbonates. The strontium data exhibit three intervals of relatively low ~(87)Sr/~(86)Sr ratios in thelate Middle Devonian to early Late Devonian, Early Carboniferous and Early Permian, corre-sponding to global eustatic high sea level stands. The lowest ~(87)Sr/~(86)Sr ratio recorded in theLate Permian was probably caused by substantial basalt eruptions in the Upper Yangtze Plat-form at the time. Three corresponding periods of relatively high δ~(13)C values at roughly the samethe intervals were caused by a relatively high rate of accumulation of organic carbon duringsea level rises at these times. The deposition of coal was probably responsible for the increaseof sea water δ~(13)C at other times. The δ~(13)C values drop dramatically near theDevonian/Carboniferous, Carboniferous/Permian and Permian/Triassic boundaries, con-sistent with other similar data, which further support the notion that geological time boundariesare associated with mass extinction and subsequent rejuvenation.     

Paleoseismological Analysis Along the Astara Fault System (Talesh Mountain, North Iran)

The Astara Fault System(AFS) is located in the northwest Alborz, east of Talesh Mountain(TM) and west of the South Caspian Basin(SCB). The AFS is one of the basement rock faults in Iran that is heavily involved in seismotectonic activity of the Talesh region, and to which subsidence of the SCB is attributed. There is little information available concerning previous AFS seismic activities and its properties. In order to elucidate the seismic behavior and activities of the AFS, we conducted a research study on paleoseismology of the fault. Based on paleoseismic evidence, two scenarios could be taken into consideration, one of which has three and another has four seismic events with magnitudes Mw in the range of 6.7 to 7.2. Evidence of these seismic events is within sedimentary succession as they have occurred during the past 3 ka(this age is determined based on the deposition rate of the region). Six carbon samples were taken for C~(14) age determination tests, the results of which clearly demonstrated that the EvIV(scenario A) and EvⅢ(scenario B) had occurred before 27,444 cal BP, while other events occurred in the time period between 27,444 cal BP and 3 ka ago. If we consider the occurrence of three or four seismic events(based on the two scenarios) to be between 27,444 cal BP and 3 ka ago, the average recurrence interval is 7,119 ± 1,017, but evidence for these events has been removed. If we assume EvI to be the youngest event(in both scenarios), the minimum elapsed time is therefore 3 ka.     

Abstracts of Acta Geologica Sinica (Chinese Edition) Vol.72, No.1,1998

Establishment and Evolutionary Successions of Entomofaunas in the North of ChinaHONG Youchong (Beijing Museum of Natural History, Beijing, 100050)Terrestrial strata are widely distributed in China, especially in the North of the Chinese palaeocontinent,yielding abundant fossil insects associated with other fossil biotas. Through acumulation of nationwide in-sect specimens and their systematic study for several decades it has been found that the stratigraphic rangeof these fossi1 insects is Upper Carboniferous to Miocene in northern China. In various geological periodsthere appeared various unique insects. According to the history of their appearance, development, flour-ishing and disappearance in geological ages three (Late Palaeozoic, Mesozoic, and Tertiary) evolutionary     

Characterization and recovery of the halophiles in the fluid inclusions in halite

正1 Introduction It is the focus of geology and biology that the creature preserved in the geological history and the organic evolution.The creature preserved in geological history by these things:sedimentary,frozen earth,chrysophoron and evaporation salt.Evaporation salt can preserve the microbe     

白垩纪中期异常地质事件与全球变化

白垩纪中期(125~90 Ma)是地质历史中一个极端温室时期,集中出现一系列异常事件。异常事件是地球系统内各圈层相互耦合的产物,事件相互之间不是孤立的,单个事件引起的全球变化对其他事件起着明显的正/负反馈机制作用。文中基于对白垩纪中期异常事件的深入解剖和分析,包括大规模海底火山事件、大洋缺氧事件、生物异常更替与绝灭、白垩纪超静磁带、大洋红层出现等,在探讨白垩纪中期各个事件特征基础上,重点阐述异常事件所引起的全球变化及其对海洋、气候的影响;提出异常事件之间的相互关联与反馈机制。研究发现,大规模海底火山作用是引起白垩纪中期异常海洋和气候的最根本原因,直接促进大洋缺氧事件、生物绝灭与更替、沉积记录的转变等事件的发生。     

Exploring aberrant bivalve shell ultrastructure and geochemistry as proxies for past sea water acidification

Throughout much of Earth's history, marine carbonates have represented one of the most important geological archives of environmental change. Several pivotal events during the Phanerozoic, such as mass extinctions or hyperthermal events have recently been associated with ocean acidification. Nevertheless, well‐defined geological proxies for past ocean acidification events are, at best, scarce. Here, experimental work explores the response of bivalve shell ultrastructure and isotope geochemistry (δ¹³C, δ¹⁸O and δ²⁶Mg) to stressful environments, in particular to sea water acidification. In this study, the common blue mussel, Mytilus edulis, was cultured (from early juvenile stages to one year of age) at four pH regimes (pH_NBS 7·2 to pH 8·0). Shell growth rate and ultrastructure of mainly the calcitic portion of the shells were compared between experimental treatments. Specimens exposed to low‐pH environments show patches of disordered calcitic fibre orientation in otherwise well‐structured shells. Furthermore, the electron backscattered diffraction analyses reveal that, under acidified conditions, the c‐axis of the calcite prisms exhibits a bimodal or multi‐modal distribution pattern. Similar shell disorder patterns have been reported from mytilids kept under naturally acidified sea water conditions. In contrast, this study found no evidence that different pH regimes affect shell carbon, oxygen or magnesium isotope ratios. Based on these observations, it is proposed that: (i) stressful environments, in this case low sea water pH, predictably affect bivalve biomineralization patterns; and (ii) these findings bear potential as a novel (petrographic) proxy for ancient sea water acidification. An assessment of the applicability of these data to well‐preserved fossil shell material from selected time intervals requires additional work.     

Towards rationalism in Precambrian stratigraphy

There is no generally accepted time or time‐rock Precambrian stratigraphy, as there is for the Phanerozoic. Many authors suggest that a time‐rock nomenclature based on similar principles should be used. But no explicit general principles for the erection of major time or time‐rock stratigraphic divisions exist, or have even been used, while the confusion caused by the evolutionary and unsystematic growth of the Phanerozoic systems is admitted. Consequently, geologists dealing with the Precambrian may feel free to choose whatever methods of time subdivision and nomenclature seem most effective, unprejudiced by Phanerozoic precedent. The familiar ones used by historians seem to be more useful for Precambrian rocks and time, if megacenturies (of 10⁸ years, or 10⁶ centuries) are used instead of centuries, than those used in Phanerozoic stratigraphy. The conclusions that: (1) stratigraphic rock units, plus isotopic age determinations to inter‐relate major sequences and events within a numerical time‐scale of years, are together adequate for handling Precambrian stratigraphic problems, and conversely (2) traditional time and time‐rock stratigraphy is superfluous, represent the main thesis of this paper. Although there is no rock unit of system rank the local restriction of systems would overcome this deficiency; the Adelaide System is an example. Three common fallacies are: (1) rocks are the primary standard of reference for time, (2) geological maps cannot be published without time‐rock stratigraphy, and (3) the same type of nomenclature must be used for both Phanerozoic and Precambrian. International cooperation in the adoption of standard rocks for isotopic dating is advisable to promote accurate correlations in the Precambrian.     

Major crustal boundaries of Australia,and their significance in mineral systems targeting

For over 35 years, deep seismic reflection profiles have been acquired routinely across Australia to better understand the crustal architecture and geodynamic evolution of key geological provinces and basins. Major crustal-scale breaks have been interpreted in some of the profiles, and are often inferred to be relict sutures between different crustal blocks, as well as sometimes being important conduits for mineralising fluids to reach the upper crust. The widespread coverage of the seismic profiles now allows the construction of a new map of major crustal boundaries across Australia, which will better define the architecture of the crustal blocks in three dimensions. It also enables a better understanding of how the Australian continent was constructed from the Mesoarchean through to the Phanerozoic, and how this evolution and these boundaries have controlled metallogenesis. Starting with the locations in 3D of the crustal breaks identified in the seismic profiles, geological (e.g. outcrop mapping, drill hole, geochronology, isotope) and geophysical (e.g. gravity, aeromagnetic, magnetotelluric) data are used to map the crustal boundaries, in plan view, away from the seismic profiles. Some of the boundaries mapped are subsurface boundaries, and, in many cases, occur several kilometres below the surface; hence they will not match directly with structures mapped at the surface. For some of these boundaries, a high level of confidence can be placed on the location, whereas the location of other boundaries can only be considered to have medium or low confidence. In other areas, especially in regions covered by thick sedimentary successions, the locations of some crustal boundaries are essentially unconstrained, unless they have been imaged by a seismic profile. From the Mesoarchean to the Phanerozoic, the continent formed by the amalgamation of many smaller crustal blocks over a period of nearly 3 billion years. The identification of crustal boundaries in Australia, and the construction of an Australia-wide GIS dataset and map, will help to constrain tectonic models and plate reconstructions for the geological evolution of Australia, and will provide constraints on the three dimensional architecture of Australia. Deep crustal-penetrating structures, particularly major crustal boundaries, are important conduits to transport mineralising fluids from the mantle and lower crust into the upper crust. There are several greenfields regions across Australia where deep crustal-penetrating structures have been imaged in seismic sections, and have potential as possible areas for future mineral systems exploration.     

Zircon—Earth's timekeeper

One of the earliest written references to zircon is from Lydgate's edition of Aesop's Fables from c.1400 where a zircon was found ‘hid in the dunghill’. Since the humble surroundings of this early record, zircon has become a popular and important mineral. The name zircon is believed to have derived from the Persian words ‘zar’ and ‘gun’ meaning gold and colour respectively. During the Middle Ages, it was believed that wearing zircon jewellery was a cure against insomnia and protected against disease. In more modern times, zircon has found uses in industrial processes and is a key mineral for geologists investigating the geological history of the Earth. It can incorporate uranium which undergoes radioactive decay to lead at a constant rate. By measuring the ratios of uranium and lead isotopes, geologists can calculate the age at which zircons formed. Physical and chemical durability makes zircon able to survive for long periods of geological time and record information about hallmark geological events in Earth history, including early crustal formation, mountain‐building events and mass extinctions. Indeed, the oldest known material on the planet is a zircon from Jack Hills in Western Australia, dated at 4.4 billion years old, a mere 0.15 billion years after the formation of the Earth. This remarkable durability has also led to zircon finding commercial applications in high‐temperature industrial processes, such as brick foundries, while its chemical inertness makes it a potential material for testing the impact of the radioactive products of nuclear waste on mineral structures.     

Sulfur isotopic evidence for chemocline upward excursions during the end-Permian mass extinction

The latest Permian was a time of major change in ocean chemistry, accompanying the greatest mass extinction of the Phanerozoic. To examine the nature of these changes, samples from two well-studied marine sections that span the Permian-Triassic boundary have been analyzed: the Meishan and Shangsi sections located in Southern China. Isotopic analysis of the carbonate-associated sulfate in these samples provides a detailed record of several isotopic shifts in δ³⁴S_CAS approaching and across the PTB, ranging from +30 to −15‰ (VCDT), with repeated asynchronous fluctuations at the two locations. We interpret the patterns of isotopic shifts, in conjunction with other data, to indicate a shallow unstable chemocline overlying euxinic deep-water which periodically upwelled into the photic zone. These chemocline upward excursion events introduced sulfide to the photic zone stimulating a bloom of phototrophic sulfur oxidizing bacteria. We hypothesize that elemental sulfur globules produced by these organisms and ³⁴S-depleted pyrite produced in the euxinic water column were deposited in the sediment; later oxidation led to incorporation as CAS. This created the large changes to the δ³⁴S_CAS observed in the latest Permian at these locations.     

Possible causes of quasiperiodic variations in geomagnetic reversal frequency and Sr/Sr ratios in marine carbonates through the Phanerozoic

Variations in frequency of geomagnetic reversals through the Phanerozoic have been analyzed jointly with ⁸⁷Sr/ ⁸⁶Sr ratios in marine carbonate sediments. The time series of both parameters contain principal components with periods from 90 to 110 Ma and show a certain correlation. Namely, (i) both time series have five local minimums spaced at similar intervals (period lengths); (ii) the minimums in the Δ⁸⁷Sr/⁸⁶Sr curve follow in time those of the reversal frequency, with a lag from 12 Myr in the Ordovician to 38 Myr in the Cretaceous; (iii) the rate of heat transfer from processes at the core-mantle boundary (in D″ layer) which control the Earth's geological life was from 7 to 25 cm/yr in the Phanerozoic. This rate approaches the observed velocities of horizontal plate motion and the predicted mantle convection rates.     

On the ages of flood basalt events

We review available data constraining the extent, volume, age and duration of all major Phanerozoic continental flood basalts (CFB or traps) and oceanic plateaus (OP), together forming the group of large igneous provinces (LIP), going from the smallest Columbia flood basalts at ～16 Ma to the as yet ill-known remnants of a possible trap at ～360 Ma in eastern Siberia. The 16 traps (CFB and OP) reviewed form a rather unimodal distribution with an initial modal volume of the order of 2.5 Mkm³. Most provinces agree with a rather simple first order model in which volcanism may have lasted of the order of 10 Ma, often resulting in continental break-up, but where most of the volume was erupted in about 1 Ma or sometimes less. This makes CFBs/OPs (LIPs) major geodynamic events, with fluxes exceeding the total output of present day hot spots and even possibly exceeding over short times the entire crustal production of mid-ocean ridges. The proposed correlation between trap ages and the ages of several geological events, including mass extinctions and oceanic anoxia, is found to have improved steadily as more data have become available, to the point that the list of trap ages may coincide with many major divisions in the geological time scale. The four largest mass extinctions in the last 260 Ma coincide to the best resolution available with four traps, making a causal connection between the two through some form of catastrophic climatic perturbations the most likely hypothesis. The time sequence of LIPs appears to have been random and there is no robust evidence for long time trends in the corresponding crustal production rate over the last 260 Ma.