Origin of metaluminous and alkaline volcanic rocks of the Latir volcanic field,northern Rio Grande rift,New Mexico

Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO₂ rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO₂) to quartz latite (67% SiO₂). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO₂ peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km³ high-SiO₂ peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes appear to require development of relatively large magma chambers in the crust that are sustained by large basalt fluxes from the mantle. The lack of extensive crustal contamination and mixing in the Miocene lavas may be related to a decreased basalt flux or initiation of blockfaulting that prevented pooling of basaltic magma in the crust.     

Chemistry and distribution pattern of recent basaltic rocks in Iceland

A survey of Recent basaltic rocks in Iceland is presented. The basalts are classified into three groups: tholeiites, transitional alkali basalts and alkali olivine basalts. The basalts can be divided into petrological regions where the composition of lavas seem to have been fairly constant throughout postglacial and possibly late-Pleistocene time. The tholeiites delineate the crest region of the Mid-Atlantic Ridge as it transects Iceland, and the mildly alkali olivine basalts and the transitional alkali basalts characterize the flank volcanic zones. Tholeiitic and alkalic diffrentiated rocks appear to have a distribution in accordance with the basalt distribution pattern. There is some correlation between the chemistry of the zones and the crustal structure of Iceland. Areal discharge of volcanic rocks varies consistently between the petrological regions being highest in the tholeiite regions. The total output of volcanic rocks along the Mid-Atlantic Ridge in the Iceland area reaches maximum in middle Iceland.     

The petrology and geochemistry of the Azores Islands

Forty lavas from the Azores Islands have been analyzed for ⁸⁷Sr/⁸⁶Sr ratios, major elements, first transition series metals, and LIL elements. The samples belong to the alkali basalt magma series but range from transitional hy-normative basalts from Terceira to basanitoids from Santa Maria. Differentiated lavas include both typical trachytes and comenditic trachytes and comendites. Major and trace element concentrations define smooth trends on variation diagrams, and these trends can be related to phases crystallizing in the rocks. Systematic interisland differences are also apparent in these variation diagrams. LIL element concentrations in island basalts are roughly twice as high as those in tholeiites from the adjacent Mid-Atlantic Ridge which transects the Azores Plateau. ⁸⁷Sr/⁸⁶Sr ratios in lavas from 6 of the 9 islands range from 0.70332 to 0.70354, a range similar to that found in tholeiites from the Mid-Atlantic Ridge transect of the Azores Plateau. This suggests that lavas from these islands and this portion of the Mid-Atlantic Ridge may be derived from a similar source. However, lavas from the islands of Faial and Pico have ⁸⁷Sr/⁸⁶Sr ratios up to 0.70394 and ratios in Sao Miguel lavas range up to 0.70525, suggesting basalts from these islands are derived from a chemically distinct source. Differences in the average LIL element concentrations of the least fractionated ridge tholeiites from the Azores Plateau and alkali basalts from the islands result from differences in extent of partial melting and residual mineralogy. The alkali basalts are derived by roughly half as much melting as are the tholeiites. Trace element concentrations in Azores peralkaline lavas preclude their derivation by partial melting of peridotitic mantle or basaltic crust; rather the data suggest they are produced by fractional crystallization of a basaltic parent.     

Petrology and geochemistry of the Banks Peninsula volcanoes,South Island,New Zealand

Within the volcanic sequence of the twin volcanoes of Lyttelton and Akaroa, Banks Peninsula, New Zealand a number of different magma series have been distinguished.An early series of hawaiites (McQueens Valley Formation) was erupted about 32 m.y. ago and is of transitional or mildly tholeiitic chemistry. Stratigraphically above the McQueens Valley Formation, but unconformably overlain by the main volcanic dome sequence, is a unit of rhyolite (Gebbies Pass Rhyolites) which is not directly related to the earlier or later basaltic volcanism. The rhyolite was probably formed during intracrustal melting which was related to the rise of basaltic magma into the crust.Between 12 and 9.7 m.y. a large volcanic dome, composed mainly of hawaiite, was built at Lyttelton. Dykes, which intrude the Lyttelton volcanic sequence, range in composition from basalt to trachyte. Late, mildly alkalic, basaltic flank flows (7.5–5.8 m.y.) occur in several areas and they, and the differentiated rocks of the dyke swarm can be related by a crystal fractionation model which has been quantitatively tested.Following construction of the Lyttelton dome a second larger dome was built at Akaroa between 9 and 7.5 m.y. The rocks of the Akaroa Volcano are principally hawaiites but rocks ranging in composition through to trachyte also occur. The differentiated rocks of the Akaroa volcano have derived from the basaltic rocks by a crystal fractionation controlled process, operating during ascent through the crust.None of the Banks Peninsula basalts appear to have derived from primitive (pyrolitic) mantle material, but progressive changes in the chemistry of the basalts with time implies that the mantle source regions were evolving geochemically as partial melting proceeded. Later lavas tend to be more alkalic and to have lower MgO/FeO ratios than earlier lavas. The volcanic rocks of the Banks Peninsula volcanoes were derived by fractional removal of olivine, plagioclase, clinopyroxene, magnetite and apatite from ascending basaltic magma batches. Variations between the suites reflect differences between the parental magma batches.     

Aleutian tholeiitic and calc-alkaline magma series I: The mafic phenocrysts

Diagnostic mafic silicate assemblages in a continuous spectrum of Aleutian volcanic rocks provide evidence for contrasts in magmatic processes in the Aleutian arc crust. Tectonic segmentation of the arc exerts a primary control on the variable mixing, fractional crystallization and possible assimilation undergone by the magmas. End members of the continuum are termed calc-alkaline (CA) and tholeiitic (TH). CA volcanic rocks (e.g., Buldir and Moffett volcanoes) have low FeO/MgO ratios and contain compositionally diverse phenocryst populations, indicating magma mixing. Their Ni and Cr-rich magnesian olivine and clinopyroxene come from mantle-derived mafic olivine basalts that have mixed with more fractionated magmas at mid-to lower-crustal levels immediately preceding eruption. High-Al amphibole is associated with the mafic end member. In contrast, TH lavas (e.g., Okmok and Westdahl volcanoes) have high FeO/MgO ratios and contain little evidence for mixing. Evolved lavas represent advanced stages of low pressure crystallization from a basaltic magma. These lavas contain groundmass olivine (FO 40–50) and lack Ca-poor pyroxene. Aleutian volcanic rocks with intermediate FeO/MgO ratios are termed transitional tholeiitic (TTH) and calc-alkaline (TCA). TCA magmas are common (e.g., Moffett, Adagdak, Great Sitkin, and Kasatochi volcanoes) and have resulted from mixing of high-Al basalt with more evolved magmas. They contain amphibole (high and low-Al) or orthopyroxene or both and are similar to the Japanese hypersthene-series. TTH magmas (e.g., Okmok and Westdahl) contain orthopyroxene or pigeonite or both, and show some indication of upper crustal mixing. They are mineralogically similar to the Japanese pigeonite-series. High-Al basalt lacks Mg-rich mafic phases and is a derivative magma produced by high pressure fractionation of an olivine tholeiite. The low pressure mineral assemblage of high-Al basalt results from crystallization at higher crustal levels.     

Petrology of the Cenozoic volcanism in the Upper Benue valley,northern Cameroon (Central Africa)

Thirty-one plugs of alkaline volcanic rocks of Cenozoic age (37 Ma in mean) occur in the Upper Benue valley, northern Cameroon (Central Africa). The complete alkaline series (alkaline basalts, hawaiites, mugearites, phonolites, trachytes and rhyolites) is represented. Basalts contain phenocrysts of olivine, Al-Ti-rich diopside, and Ti-magnetite, and hawaiites-abundant microphenocrysts of plagioclase. Mugearites have a trachytic texture and contain xenocrysts of K-feldspar, apatite, quartz and unstable biotite. Phonolites are peralkaline. Trachytes (peralkaline and non-peralkaline) and rhyolites are characterised by their sodic mineralogy with aegirine-augite, richterite, and arfvedsonite phenocrysts. There is a large compositional gap between basaltic and felsic lavas, except the mugearites. Despite this gap, major- and trace-element distributions are in favour of a co-magmatic origin for the basaltic and felsic lavas. The Upper Benue valley basalts are similar in their chemical and isotopic features to other basalts from both the continental and oceanic sectors of the Cameroon Line. The Upper Benue valley basaltic magmas (⁸⁷Sr/⁸⁶SrƸ.7035; k Nd=+3.9) originate from an infra-lithospheric reservoir. The Sr-Nd isotopic composition and high Sr contents of the mugearites suggest that they are related to mantle-derived magmas and that they result from the mixing, at shallow crustal levels, of a large fraction of trachytic magma with a minor amount of basaltic magma. Major-element modelling of the basalt-trachyte evolution (through hawaiite and mugearite compositions) does not support an evolution through fractional crystallization alone. The fluids have played a significant role in the felsic lavas genesis, as attested by the occurrence of F-rich minerals, calcite and analcite. An origin of the Upper Benue valley rhyolitic magmas by fractional crystallization of mantle-derived primitive magmas of basaltic composition, promoted or accompanied by volatile, halogen-rich fluid phases, may be the best hypothesis for the genesis of these lavas. These fluids also interact with the continental crust, resulting in the high Sr-isotope initial ratios (0.710) in the rhyolites, whereas the Nd isotopic composition has been less affected (k Nd=+0.4).     

Variation in the geochemistry of mantle sources for tholeiitic and calc-alkaline mafic magmas,Western Sunda volcanic arc,Indonesia

Quaternary lavas of the normal island-arc basalt—andesite—dacite association in the islands of Java and Bali range from those belonging to tholeiitic series over Benioff-zone depths of ～ 150 km to high-K calc-alkaline series over Benioff-zone depths of 250 km. More abundant and diverse calc-alkaline lavas are found over intermediate Benioff-zone depths. On average, basaltic lavas become slightly more alkaline (largely due to increased K contents) with increasing depth to the Benioff zone. Levels of incompatible minor and trace elements (K, Rb, Cs, Ba, Nb, U, Th, light REE) show a corresponding increase of almost an order of magnitude.Low average Mg-numbers (～ 0.52) and Ni and Cr abundances (15–25 and 35–60 ppm, respectively) of basaltic lavas suggest that few lavas representing primary mantle-derived magma compositions are present. Calculated primary basaltic magma compositions for most tholeiitic and calc-alkaline volcanic centres are olivine tholeiites with 15–30% ol. The single high-K calc-alkaline centre considered yielded transitional alkali olivine basalt—basanite primary magma compositions. These calculated magma compositions suggest that the percentage of mantle melting decreases with increasing depth to the Benioff zone (from >25 to <10%), while the corresponding depth of magma separation increases from ～ 30 to 60 km.Calculation of REE patterns for basaltic magmas on the basis of peridotitic mantle sources with spinel lherzolite, amphibole lherzolite or garnet lherzolite mineralogy, and model REE levels of twice chondritic abundances, indicates that change in the conditions of magma genesis alone cannot explain the observed change in light-REE abundances of basaltic lavas with increasing depth to the Benioff zone. Complementary calculations of the REE levels of mantle sources required to yield the average tholeiitic, calc-alkaline and high-K calc-alkaline basaltic magma indicate that light-REE abundances must increase from 2–3 to 7–8 times chondrites with increasing depth to the Benioff zone. The percentages of mantle melting favoured on REE evidence are lower than those indicated by major-element considerations.The observed variation in incompatible element geochemistry of mantle magma sources is thought to be related directly or indirectly to dehydration and partial-melting processes affecting subducted oceanic crust. The possible nature of this relationship is discussed.     

Basalts from Madeira: A petrochemical contribution to the genesis of oceanic alkali rock series

Petrological and geochemical investigations have been conducted on the little studied Neogene basaltic rocks of the Madeiran Islands. The Madeiran suite of minor intrusives and lavas consists of parental, unusually soda rich, alkali olivine basalts with hawaiite, mugearite and essexite derivatives. Olivine and clinopyroxene are dominant phenocryst and cumulus nodule phases. Low pressure fractionation of the parental magma by precipitation of these minerals gave rise to the hawaiitic trend. That olivine settling precedes clinopyroxene in the fractionation process can be deduced from Ca and Ni variations in the analysed rocks and phenocryst separates. Late stage feldspar flotation in a hawaiitic derivative liquid led to extrusive mugearites and an intrusive essexite.Low K/Rb ratios in the Madeiran basalts (ave. 325) point to the influence of phlogopite rather than hornblende in the mantle melting zone. The primitive alkali olivine basalt magma is thought to have arisen by partial melting following water release from small amounts of phlogopite (no more than 1%) at mantle depths around 100 km. A deep level of magma generation is consistent with the low values of heat flow recorded in ocean basins. Many other oceanic alkali basalt provinces remote from ridge systems may have arisen in a similar way.     

Petrology of the Western Reykjanes Peninsula, Iceland

The active tholeiitic volcanic zone of the Reykjanes Peninsulaconsists of five volcanic fissure swarms, the two westernmostof which are the subject of this petrological study. The recent(less than 12,000 years) extrusives of the swarms group morphologicallyand petrographically into small picrite basalt lava shields,large olivine tholeiite lava shields and tholeiite fissure lavas;formed in that chronological succession. The picrite basalts exhibit a primitive mineralogy with chromite,olivine (Fo 89) and plagioclase (An 90) as phenocrysts and mayrepresent a primary liquid from the mantle. Simultaneous crystallizationof olivine, plagioclase and augite to form glomerocrysts inthe fissure lavas indicate low pressure cotectic crystallizationconditions. Twenty-eight new major element chemical analyses of the lavasare presented. They are generally characterized by a low contentof alkalies and high CaO. The lavas constitute two main suites,a lava shield suite and a fissure lava suite. There is a positivecorrelation between the volume of individual lavas and the contentof incompatible elements of the lavas within each group. Likewisethere is an overall chemical trend through time demonstrated,for example, by a rise in K₂O from about 0.02 per cent to 0.24per cent during the last, approximately, 12,000 years. There is an apparent chemical zoning within each volcanic swarmsuch that the most evolved and youngest lavas are found in thecentral axial area of the swarm. This central area is also characterizedby graben subsidence, high magnetic anomalies and high temperaturethermal areas, all indicative of shallow magma reservoir(s).In spite of indications of fractional crystallization in theevolution of the olivine tholeiites and tholeiites, some otherprocesses must be sought to explain the volume chemistry relations.Cyclic volcanic activity is tentatively suggested to explainthe observed regular temporal variations within the swarm, eachcycle starting with the formation of picrite basalts.     

Petrology and petrogenesis of a tertiary bimodal dolerite-peralkaline/subalkaline trachyte/rhyolite dyke association from Lundy,Bristol Channel,UK

The island of Lundy forms the southernmost igneous complex of the British Tertiary Volcanic Province (BTVP) and consists of granite (≈ 90%) emplaced into deformed Devonian sedimentary rocks (Pilton Shale) and associated with a swarm of dykes of dolerite/basalt, minor trachyte and rhyolite composition. The dolerites are of varied olivine basalt composition and are associated with peralkaline trachyte and subalkaline/peralkaline rhyolite with alkali feldspar and quartz ± alkali amphibole ± pyroxene mineralogy. The dyke swarm is therefore an anorogenic bimodal dolerite/basalt–trachyte/rhyolite BTVP association. Although the dyke association is bimodal in major element terms between dolerite/basalt and minor trachyte/rhyolite, the mineralogy and trace element geochemistry indicate that the dykes may be regarded as a cogenetic dolerite—peralkaline trachyte/rhyolite association with minor subalkaline rhyolites. Sr and Nd isotope data indicate derivation of these magmas from a similar BTVP mantle source (with or without minor contamination by Pilton Shale, or possibly Lundy granite). The petrogenesis of the Lundy dyke association is therefore interpreted in terms of extensive fractional crystallization of basaltic magma in a magma chamber of complex geometry below the (exposed) Lundy granite. Fractional crystallization of a representative dolerite magma (olivine ± clinopyroxene ± plagioclase) yields trachyte magma from which the crystallization of alkali feldspar (anorthoclase) ± plagioclase (oligoclase) + Fe–Ti oxide + apatite results in peralkaline rhyolite. Rarer subalkaline rhyolites result from fractionation from a similar dolerite source which did not achieve a peralkaline composition so allowing the crystallization and fractionation of zircon. The basalt–(minor trachyte)/rhyolite bimodality reflects rapid crystallization of basalt magma to trachyte (and rhyolite) over a relatively small temperature interval (mass fraction of melt, F = ≈ 0.15). The rapid high level emplacement of basalt, trachyte and rhyolite dyke magmas is likely to have been associated with the development of a substantial composite bimodal basalt–(minor trachytel)/rhyolite volcano above the BTVP Lundy granite in the Bristol Channel.     

金川铜、镍(含PGE)岩浆硫化物矿床母岩浆成分的估计

利用金川侵入体的岩石化学和铂族元素资料,根据Ｒｏｅｄｅｒ和Ｅｍｓｌｉｅ的橄榄石液相平衡原理,估计金川超镁铁质岩的母岩浆为大约含１０８％ＭｇＯ的高镁玄武岩浆;将其与不同构造背景下形成的玄武岩岩石化学成分进行对比,认为金川侵入体的母岩浆的化学成分与巴西北部Ｍａｒａｎｈａｏ低Ｔｉ玄武岩浆的化学成分相似,代表了一种大陆裂谷背景下火山活动的产物。     

西南极菲尔德斯半岛第三纪钙碱性火山岩的生成与演化

西南极菲尔德斯半岛第三纪火山岩的岩石学和岩石化学特征表明,它们基本属于钙碱性火山岩系列,是岛弧火山作用的产物。该岩石组合中,随岩石中SiO_2含量的增加,斜长石斑晶数量减少,微量元素Cr、V丰度降低,Sr、Ba丰度下降,这些揭示了岩浆中斜长石和单斜辉石的分离结晶作用。稀土元素的系统变化也证明了这一点。主元素和微量元素的定量计算所验证了岩浆的分离结晶作用演化过程。     

Petrology and geochemistry of Easter Island

Easter Island has developed around three volcanoes—Poike, an older (3 m.y.) strato-volcano, Rano Kau, a caldera, and the fissure complex of Terevaka and its associated cones. The lavas show a wide compositional spread from tholeiites and olivine tholeiites to hawaiites, mugearites, benmoreites, trachytes and rhyolites (comendites). Hawaiite is by far the most abundant rock type and trachytes and rhyolites are relatively rare. Intermediate and acid rocks are concentrated in the southwestern part of the island on or around Rano Kau.The basaltic rocks, which are plagioclase-phyric or aphyric, are transitional hypersthenenormative types characterized by high contents of Fe, Ti and Zr but low K and Mg. The Poike basalts are marginally lower in Zr, Nb, Y and Zn compared with those of the younger volcanoes, but the trachytes from this centre show anomalously high concentrations of Rb, Zr and Nb.The island's youngest flow, the Roiho basalt, is an olivine tholeiite with distinctly more alkaline affinities: it is olivine-microphyric with relatively high contents of Mg, Ni and K.The study was initiated whilst this author was at Department of Geology and Mineralogy, University of Oxford.     

Trace element geochemistry of high alumina basalt - Andesite - Dacite - Rhyodacite lavas of the Main Volcanic Series of Santorini Volcano,Greece

Trace element systematics throughout the cal-calkaline high alumina basalt — basaltic andesite — andesite — dacite — rhyodacite lavas and dyke rocks of the Main Volcanic Series of Santorini volcano, Greece are consistent with the crystal fractionation of observed phenocryst phases from a parental basaltic magma as the dominant mechanism involved in generating the range of magmatic compositions. Marked inflection points in several variation trends correspond to changes in phenocryst mineralogy and divide the Main Series into two distinct crystallisation intervals — an early basalt to andesite stage characterised by calcic plagioclase+augite+olivine separation and a later andesite to rhyodacite stage generated by plagioclase augite+hypersthene+magnetite+apatite crystallisation. Percent solidification values derived from ratios of highly incompatible trace elements agree with previous values derived from major element data using addition-subtraction diagrams and indicate that basaltic andesites represent 47–69%; andesites 70–76%; dacites ca. 80% and rhyodacite ca. 84% crystallisation of the initial basalt magma. Least squares major element mixing calculations also confirm that crystal fractionation of the least fractionated basalts could generate derivative Main Series lavas, though the details of the least squares solutions differ significantly from those derived from highly incompatible element and addition-subtraction techniques. Main Series basalts may result from partial melting of the mantle asthenosphere wedge followed by limited olivine+pyroxene+Cr-spinel crystallisation on ascent through the sub-Aegean mantle and may fractionate to more evolved compositions at pressures close to the base of the Aegean crust. Residual andesitic to rhyodacite magmas may stagnate within the upper regions of the sialic Aegean crust and form relatively high level magma chambers beneath the southern volcanic centres of Santorini. The eruption of large volumes of basic lavas and silicic pyroclastics from Santorini may have a volcanological rather than petrological explanation.     

Petrology of the Nandewar Volcano,N.S.W., Australia

The Nandewar Mountains, N.S.W., Australia, are the remains of a Miocene continental alkaline volcano whose products range from olivine basalts to comendites and alkali rhyolites. Intermediate hawaiites, mugearites and benmoreites predominate in the shield, in which olivine basalts are rare, and the trachytic rocks form many intrusions into the shield. The Nandewar alkaline series shows extreme fractionation of a relatively differentiated alkali olivine basalt magma, saturated with silica, to yield extremely oversaturated peralkaline comendites and peraluminous alkali rhyolites. The nature of the ferromagnesian phases forming was controlled by low oxygen fugacities. Throughout the series clinopyroxenes range from diopsidic augite, through sodic ferrohedenbergites to hedenbergite-acmite solid solutions. Riebeckite-arfvedsonite solid solutions appear in the trachytes and comendites, and aenigmatite appears in some of the peralkaline rocks. The feldspars in the series fractionate from calcic labradorite through potash oligoclase and calcic anothoclase towards the minimum melting alkali feldspar composition, Ab₆₅Or₃₅. The compositions of the alkali rhyolites approach the minimum in the system SiO₂-KAlSi₃O₈-NaAlSi₃O₈. All the mineralogical and chemical evidence points to the development of the Nandewar series by the processes of extreme crystallization differentiation of an alkali olivine basalt parent magma. No significant contamination occurred, xenoliths and xenocrysts are absent, and volatile transfer and metasomatism played a minor role.     

Nickel content of basaltic magmas: identification of primary magmas and a measure of the degree of olivine fractionation

Available NiO analyses of olivine in peridotites of probable mantle origin are consistent in giving values around 0.40 weight per cent. Assuming that basaltic magma forming from the mantle was in equilibrium with such peridotitic olivine, the NiO content of primary basaltic magmas is estimated to be about 0.030–0.050 weight per cent. The fractionation behaviour of nickel in basaltic magma due to the crystallization of olivine has been calculated using constant NiMg and FeMg exchange partition coefficients between olivine and magma. It is shown that the NiO content of both magma and olivine decreases by 50 per cent after fractional crystallization of 6–12 per cent of olivine. The nickel distribution in some basaltic rocks and olivines is examined in the light of these results, and it is suggested that basaltic magmas, such as some of the ocean-floor basalt and the Hawaiian tholeiite and alkali basalts, represent primary magmas from mantle peridotites.     

Magmatic Evolution of the Ordovician Snowdon Volcanic Centre, North Wales (UK)

The Ordovician Snowdon Volcanic Centre (SVC) of North Walescomprises a bimodal basalt–subalkaline/peralkaline associationemplaced around a caldera within a shallow marine environment.The tectonic setting was associated with closure of the LowerPalaeozoic Iapetus Ocean and cessation of ocean plate subduction.The SVC volcanic products include basaltic lavas and pyroclasticrocks, rhyolitic pyroclastic flow deposits, high-level intrusions,domes, and flows, together with reworked equivalents. A programmeof detailed field mapping, sampling, and chemical analysis hasbeen used to evaluate the structure and magmatic evolution ofthe SVC volcanic system. SVC basalts show a range in chemicalcharacteristics between volcanic arc type and within-plate,ocean island basalt (OIB) type. Subalkaline, silica-oversaturatedintermediate intrusions (icelandites) and five chemically distinctgroups of extrusive and intrusive subalkaline/peralkaline rhyolites(termed A1, A2, B1, B2, and B3) were emplaced during the evolutionof the SVC. This evolution was driven by material and thermalinput from basaltic magma. The SVC basaltic lavas were derivedas partial melts from a heterogeneous volcanic arc to OIB-typespinel lherzolite mantle and experienced up to 60% olivine gabbrofractionation during storage in sill networks in the sub-crustor lower crust. Some magma batches experienced further fractionalcrystallization ({small tilde}70%) and minor crustal contamination({small tilde}10%) to yield the icelandites. Trace element andNd isotope data do not favour an origin for the rhyolites bypartial or total fusion of likely crustal material, and thefive rhyolite groups are regarded as distinct homogeneous batchesof magma derived from varied basaltic magmas. The icelanditesand peralkaline rhyolites (group B3) result, respectively, from{small tilde}50% and {small tilde}80–90% zircon-free fractionalcrystallization of SVC basalts. The subalkaline rhyolites (groupsA1 and B1) result from {small tilde}80–90% fractionalcrystallization of subduction-related basalts similar to thoseof Ordovician basalts which pre-date the Lower Rhyolitic TuffFormation, and groups A2 and B2 were formed by mixing and homogenizationof A1, B1, and B3 magma batches. These data and interpretationsprovide the basis of a model for the complex evolution of asilicic magma system below the SVC caldera around the time ofcessation of Caledonian subduction in North Wales. Rhyolitemagma chambers were short lived and discontinuous; the largestwas probably disc shaped and was almost entirely evacuated duringa >60-km³ ash-flow eruption.     

Geochemistry and tectonic setting of mafic rocks from the Othris Ophiolite,Greece

We present new geochemical analyses of minerals and whole rocks for a suite of mafic rocks from the crustal section of the Othris Ophiolite in central Greece. The mafic rocks form three chemically distinct groups. Group 1 is characterized by N-MORB-type basalt and basaltic andesite with Na- and Ti-rich clinopyroxenes. These rocks show mild LREE depletion and no HFSE anomalies, consistent with moderate degrees (~15%) of anhydrous partial melting of depleted mantle followed by 30–50% crystal fractionation. Group 2 is represented by E-MORB-type basalt with clinopyroxenes with higher Ti contents than Group 1 basalts. Group 2 basalts also have higher concentrations of incompatible trace elements with slightly lower HREE contents than Group 1 basalts. These chemical features can be explained by ~10% partial melting of an enriched mantle source. Group 3 includes high MgO cumulates with Na- and Ti-poor clinopyroxene, forsteritic olivine, and Cr-rich spinel. The cumulates show strong depletion of HFSE, low HREE contents, and LREE enrichments. These rocks may have formed by olivine accumulation from boninitic magmas. The petrogenesis of the N-MORB-type basalts and basaltic andesites is in excellent agreement with the melting conditions inferred from the MOR-type peridotites in Othris. The occurrence of both N- and E-MORB-type lavas suggests that the mantle generating the lavas of the Othris Ophiolite must have been heterogeneous on a comparatively fine scale. Furthermore, the inferred parental magmas of the SSZ-type cumulates are broadly complementary to the SSZ-type peridotites found in Othris. These results suggest that the crustal section may be genetically related to the mantle section. In the Othris Ophiolite mafic rocks recording magmatic processes characteristic both of mid-ocean ridges and subduction zones occur within close spatial association. These observations are consistent with the formation of the Othris Ophiolite in the upper plate of a newly created intra-oceanic subduction zone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Petrogenesis of basalt-comendite and basalt-pantellerite suites,Terceira, Azores,and some implications for the origin of ocean-island rhyolites

Petrogenetic modeling of the Recent lava succession of Santa Barbara and Pico Alto volcanoes and associated basaltic lavas indicates that there are two discrete lava series present, one erupted from the axial rift linking the two central volcanoes and one associated with monogenetic cones scattered around the flanks of Santa Barbara. The felsic lavas of both volcanoes are peralkaline and appear to be derived from associated basalts by fractional crystallization of an assemblage including essential amphibole. Trace element abundances in the felsic lavas, particularly those of Sr and REE, cannot be reconciled with an origin through partial melting of basaltic material at the base of the volcanic pile. The difference between the comenditic and pantelleritic differentiation trends of Santa Barbara and Pico Alto is attributed primarily to FO₂ control of the crystallizing assemblage, probably related to thermal dissociation of magmatic water in the Santa Barbara magma chamber. This effect may be augmented by minor differences in parent basaltic compositions, the Pico Alto pantellerites being derived from the rift basalts whereas the Santa Barbara comendites are derived from the off-rift basalts. A compositional gap between 54 and 64% silica content in the lavas is not present if the suite is extended to include co-magmatic hypabyssal xenoliths, leading to the inference that the gap in this and other bimodal suites results solely from a relative inability of magma of intermediate composition to erupt.     

The petrogenesis of Tertiary cone-sheets in Ardnamurchan, NW Scotland: petrological and geochemical constraints on crustal contamination and partial melting

Abundant cone sheets form one of the last magmatic stages in the Tertiary central complex on the Scottish peninsula of Ardnamurchan and can be grouped into a younger inner and an older outer suite relative to a gabbro intrusion. Most of the cone-sheets consist of tholeiitic to transitional basalt with MgO contents between 7.5% and 4%, although more evolved rocks also occur (to 0.5% MgO). The mafic samples are slightly enriched in the light rare earth elements (Chondrite-normalized La/Sm ∼1.1), the enrichment increases in the more evolved rocks. The compositional variation of the basaltic rocks is mainly due to crystal fractionation of olivine and clinopyroxene at depths of ∼10 km but trace elements show simultaneous assimilation of Archean Lewisian granulite crust. The andesitic to rhyolitic lavas formed by fractional crystallization from the contaminated basaltic magma coupled with assimilation of Proterozoic Moine metasediments at uppermost crustal levels. The occurrence of composite cone-sheets with basaltic and rhyolitic parts and mixtures between these magmas implies that the melts ascended successively but within a short period of time. The parental magmas of the Ardnamurchan cone-sheets must have formed at relatively shallow depths in the mantle and are comparable to the youngest tholeiitic lavas from the neighbouring island of Mull. Received: 5 June 1997 / Accepted: 12 November 1997