Geochemistry of the pantellerites of Mayor Island,New Zealand

Recent pantelleritic lavas comprise the whole of the isolated and outlying volcano of Mayor Island. Mineralogically, they are characterised by phenocrystic anorthoclase-sodic27 sanidine, quartz, sodic ferrohedenbergite, and cossyrite. Nine new chemical analyses of the lavas are presented (including one residual glass), confirming their strongly sodic and peralkaline nature. One analysis is also given of trachybasalt, which occurs as common inclusions in the mantling pumice deposits. These inclusions are characterised by abundant feldspar phenocrysts. Detailed trace element data is presented for five of the lava samples, representing the mam volcanic phases and the trachybasalt inclusions. The following conclusions are presented:

1. The lavas exhibit a marked enrichment (relative to “average” granitic compositions) of the alkalis; rare earths; highly charged cations (e.g. Nb, Zr, Hf, Mo, U, Th); Ga, Be, and Cl. In contrast, they show a spectacular depletion of Sr, Ba, and Mg, and a less intense depletion of Ca, Sc, V, and Cr.
2. The pantelleritic rare earth patterns show a similar degree of fractionation to the sedimentary pattern, and are dominated by a very strong Eu depletion. This suggests feldspar subtraction. The trachybasalt pattern shows a similar degree of fractionation, but exhibits enrichment of Eu.
3. The trachybasalt inclusions are characterised by a trace element assemblage comparable to alkali basalts, except for higher Ba and exceedingly high K/Rb and K/Cs ratios. The chemical and mineralogical data suggest that they represent partial feldspar accumulate rocks.
4. There is a progressive enrichment of nearly all trace and minor elements in the youngest lavas. This includes those elements that show an overall depletion in the lavas. The younger lavas are also enriched in Na and Fe, but further depleted in Al.

The data is interpreted to indicate that the pantellerites were derived by crystal differentiation from a postulated mildly alkali olivine basalt parent — feldspar fractionation is considered to have been extremely important in this process. It is shown that the element enrichment occurring in the younger lavas may not be wholely explained by crystallisation differentiation alone — it is possible that some additional process is required. It is also shown that the observed enrichment of sodium in the youngest lavas can only occur during crystal fractionation if quartz, as well as anorthoclase, separate from the magma. This is due to the higher alkali abundances of the anorthoclase phenocrysts, relative to the pantellerite compositions. There is limited evidence that post-eruptive devitrification of some of the lavas has resulted in some modification of the lava chemistry, notably sodium loss.     

Petrogenesis of the Elzevir batholith and related trondhjemitic intrusions in the grenville province of eastern Ontario,Canada

The Elzevir batholith belongs to a suite of trondhjemitic intrusions emplaced at ca. 1,240 Ma in the Grenville Province of eastern Ontario. New major and trace element data, including REE, combined with isotopic and petrographic data indicate that:

1. the batholith has calc-alkalic affinities;
2. the Elzevir parental magma is very similar to that of dacites in the nearby, coeval metavolcanic rocks; the magma formed by partial melting of crustal material at granulite grade;
3. chemical differences between the plutonic and volcanic rocks can be best explained by accumulation of plagioclase in the plutonic environment;
4. fractionation was dominated by plagioclase and quartz, with lesser biotite and epidote, and minor zircon and apatite.

It is suggested that melting of sialic crust took place during the ‘docking’ of a partly-evolved, originally ensimatic arc system against the main cratonic mass to the northwest.     

Complex interaction of aluminous metasedimentary xenoliths and siliceous magma; an example from Mt. Amiata (Central Italy)

Aluminous, silica-deficient metasedimentary xenoliths in siliceous lavas of Mt. Amiata have preserved composite zoning-patterns indicative for complex processes of magma-rock interaction. Petrographic observations and small-scale mineralogical and chemical differences between up to five distinct zones (including the core and envelope of lava) provide evidence that:

1. Partial melt formed in and extracted from the xenoliths was more mafic than the host magma and had a Mg/Fe ratio higher than that of the restite, at least during the peak of thermometamorphism.
2. Liquid-state interdiffusion occurred at the interface between partial melt and the enclosing magma.
3. Certain mineral phases in the restite (notably, hercynitic spinel) became unstable in the presence of a siliceous liquid.

Quartz-poor muscovite-biotite schists are considered to be the most likely parent rocks and it is believed that release of volatiles from decomposing micas played a significant role in the high-temperature metamorphic evolution of the xenoliths and their interaction with the magma. The conditions favourable for assimilation were enhanced by injection of mafic magma into the magma chamber. Although this concurrent operation of magma-mixing precludes a quantitative estimate of contamination from the wall-rocks (which was probably of minor importance) the present example indicates that dry acid magma may potentially become more mafic by interaction with partially melted hydrous rocks.     

Geologische und geochemische Untersuchungen im Zentralgneis und in der Greiner Schiefer Serie (Zillertaler Alpen,Tirol)

Geologic, petrological and geochemical investigations have been carried out in the western part of the “Zillertaler Alpen”. Important results are:

1. The premetamorphic material of the Greiner series consists of conglomerates, breccias, arcosic-sandstones or greywackes, bituminous shales, volcanic lavas and tuffs.
2. The southern part of the “Zentralgneis” shows a differentiation trend from alkaline granite to quarzdiorite with predomination of granodiorite.
3. Chemical relationships of granodiorite to its restitic inclusions allow the supposition of a palingenetic origin of the granitic rocks.
4. At least two stages of metamorphism can be differentiated.
5. Parts of the Greiner series, covered by triassic metasediments, are supposed to be of Permian age. A lower age boundary can not yet be given.
6. Some vertical, northeast striking faults with throws of more than 1 or 2 kilometers produced southward verging drag folds.
7. Geodynamic aspects, revealed from regional metamorphism and tectonics, are discussed.

     

Comparative magma/xenolith relationships in some volcanic and plutonic rocks from the French Massif Central

A comparative study of xenoliths from lavas and granitic rocks of central France indicates that:

1. The evolution of the xenoliths is essentially the same in intermediate to acid lavas as in granites. The major factor in this evolution is the assimilation by the host magmas of the quartzofeldspathic components of the xenoliths, which then become Al, Fe, Mg-rich restites.
2. Liquid immiscibility between melted xenoliths and host magmas can only be postulated for acid xenoliths in alkali basalts.
3. The basic microgranular xenoliths in some granites do not show important compositional gaps with their host rocks, though they are regularly more basic. They can be considered as early segregations (cumulates).

     

Field and petrological evidence for the development of an ensialic marginal basin related to the Hercynian orogeny in the Massif Central,France

Six lithologic units in tectonic contact with each other have been defined during mapping of the Devonian in the Beaujolais area of the northeastern Massif Central. Five main igneous suites have been recognized:

1. A transitional basaltic suite restricted to a single unit.
2. An acid volcanic-plutonic suite the members of which are related by fractional crystallization and magma mixing.
3. Low-TiO₂ volcanic rocks with calc-alkaline affinities.
4. A TiO₂-rich tholeiitic suite related to an ophiolitic complex.
5. A plutonic suite with close resemblances to Alaskantype intrusions.

The transitional metabasalts (1) form the oldest igneous suite and could represent either an intraplate magmatic forerunner of rifting or tectonic slices of weakly metamorphosed rocks representing a pre-Acadian event. The next three suites may be related to a short-lived ensialic marginal basin that developed between the Acadian and Bretonian orogenies. The basin is asymmetric, with the ophiolite of the central part flanked by an acid ridge on one side and a passive continental margin on the other. Quartz-keratophyres (2) and calc-alkalic basic volcanic rocks (3) were intercalated in varying proportions to form a bimodal volcanic pile before the rifting event that led to the formation of the ophiolites (4). The acid ridge (2) may be due to the reactivation of a continental basement. Cumulate rocks with Alaskan-type affinities occur as olistoliths, emplaced before the formation of the rift basin, supporting a comparison of the Hercynian belt with accreted magmatic arc terranes.     

Ein Beitrag zur Vulkanologie Süd-Perus

The Nevado Coropuna (6400 m/19 500 ft) is the largest and highest volcano of Peru and is situated 150 km NW of the town of Arequipa at a distance of 110 km from the Pacific coast. Results of a thorough petrographic study are presented including microprobe and radiometric measurements.

1. The constituent rocks building up the Coropuna volcano are lavas and rhyodacitic ash flows intercalated between older and younger lavas at the foot of the cone. The volcanic edifice rests on older ignimbrite sheets (14 m. y.) exposed only in the surrounding valleys.
2. The lavas are typically latite-andesites which contain some normative quartz in the groundmass. Plagioclase has 37–47% An. The depth of the phenocryst crystallization is calculated at 8–12 km based on the equilibrium between plagioclase, clinopyroxene and groundmass.
3. The Coropuna volcano has existed since the Late Miocene (5 m. y.). Approximately 2 m. y. ago a catastrophic explosion produced large rhyodacitic ignimbrite deposits around the foot of the mountain. Thereafter the effusion of lavas was dominant through Holocene times with the latest lavas becoming slightly more acidic (62% SiO₂).
4. 30–40 km to the W and SW of the Coropuna some outliers of the coastal batholites are exposed. Both their radiometric age (Cretaceous, 97 m. y.) and their chemical composition are in disagreement with the notion of these granodioritic to gabbroic rocks as the intrusive equivalents of the young volcanics.

     

Das Relief des Mars' Versuch einer zusammenfassenden Übersicht

The analysis of the martian relief leads to the conclusion that some of the most important relief elements are either concentrically or radially arranged with respect to a central structure and hence form aureoles. In this paper four different types of aureoles are identified and described:

1. impact aureoles (as result of extradynamics),
2. volcanic aureoeles (as result of lava flow through vents),
3. tectonic aureoles (as result of isostatic adjustment and/or settlement),
4. permafrost-related aureoles and mega-aureoles (as result of migration above thawing permafrost in areas with high relief).

The spatial distribution of these different types of aureoles indicates the predominant type of relief-forming dynamics in the area of their distribution (impact-related aureoles occur predominantly in the area of the Southern Uplands; volcanic, tectonic and permafrost-related aureoles in the area of large-scale updomings-TaNoVa, Elysiumand their volcanic provinces).     

Mesozoic volcanics of western sicily

The Mesozoic lavas and minor intrusions in the thrust sheets of western Sicily have the following characteristics:

1. The lavas in the Triassic Mufara Formation in the north were broken into fragments which rotated independently within the incompetent strata that enclose them. This behavior is characteristic of igneous rocks found within the more internal (northerly) thrust units.
2. The Jurassic lavas in the more external (southerly) units have consistent directions which agree with those of the Ammonitico Rosso limestones in the same zone and lie about 30° clockwise from those of coeval autochthonous formations in Tunisia.Schult's presumed Cretaceous directions from Custonaci on the north coast (similar to those found in the Cretaceous Scaglia Rossa at Terrasini to the east byChannel et al., 1980) are rotated still more (140°) with respect to those of the autochthonous Iblean platform of SE Sicily. These differences are believed to reflect rotation of the thrust sheets during tectonic transport in Cenozoic times, the internal units being the most strongly rotated.
3. All the igneous rocks are highly altered: generally the original mineralogy cannot be completely determined. Relative abundances of some of the less mobile elements (Ti, Sr, Y) suggest that they are intraplate basalts.

     

The structural geology of the Dalradian rocks of Slieve Gamph,Cos. Mayo and Sligo,Western Ireland

The paper presents novel information on the Caledonian orogeny in Ireland. A series of Dalradian (Upper Precambrian-Lower Cambrian) metasedimentary rocks occur as an envelope to a granitic igneous complex at Slieve Gamph, Western Ireland. These metasedimentary rocks have been deformed at several distinct times and evidence is shown for the following sequence of events:

1. formation of major nappe structures and a tectonic slide. The axial-plane traces of the folds probably trended N. E.-S. W.
2. formation of upright, gently plunging folds with axial-plane traces of the folds trending N. E.-S. W. Emplacement of the components of the Slieve Gamph igneous complex.
3. formation of a conjugate set of folds:
   1. Open folds with N. N. E.-S. S. W. trending axial-planes which dip to the east,
   2. Open folds with E.W. trending axial-planes which dip to the north.
4. formation of kink-bands, open and conjugate folds with an axialplane trace trending N. W.-S. E.

Late phase of faulting. No isotopic dates are available for these structural events.     

The origin of basaltic rocks in Niutoushan area— high pressure differentiation

The Niutoushan basaltic cone, consisting of subalkali (quartz-tholeiite and olivine-tholeiite) and alkali basalts, is Late Tertiary in age. Its major characteristics are generalized as follows:

1. Both early subalkali and late alkali bali basalts are formed under the same geological environment.
2. The continuity in chemical composition from subalkali to alkali and the low FeO/MgO in alkali basalts show that they are the products of cognate magmatic differentiation.
3. The change from low REE abundance and weak enrichment of LREE in subalkali to high REE abundance and strong enrichment of LREE in alkali basalts indicates obvious REE enrichment and fractionation during magmatic differentiation. Weak positive Eu anomalies in the REE patterns are indicative of their formation under low oxygen fugacity conditions.
4. According to the calculated values, 70–75% of the primary olivine tholeiitic magma had been separated as subalkaline basaltic magma, the rest residual magma became alkaline basaltic magma. This result is consistent to the field observation that the outcrop area of subalkali basalts is four times as much as that of alkali basalts.
5. The basaltic rocks of Niutoushan show an S-type distribution straddling the thermal barrier on Ol′-Ne′-Qu′ diagram and an evolution tendency for Ne to increase with increasing FeO/MgO. This is in agreement with the melting experimental data on olivine basalts at 10–20 kb.
6. Mantle-derived inclusions (spinel lherzolite) in this area occur in both alkali olivine basalts and olivine tholeiites. The latter is of extremely rare occurrence. The formation temperature and pressure of the inclusions in alkalibasalts and olivine tholeiites have been calculated. The results show that the alkaline basaltic magma was separated from the subalkaline basaltic magma at about 20 kb.

Basaltic rocks in Niutoushan were formed through the so-called “high pressure differentiation”, that is, at about 20 kb the crystallization of clinopyroxene and orthpyroxene resulted in the separation of subalkaline basaltic magma from the primary olivine tholeiitic magma, and then the residue gradually became alkaline olivine basaltic magma.     

Melting of acid xenoliths into a basanite: An approach to the possible mechanisms of crustal contamination

Biotite gneiss xenoliths included in a basanitic flow in the Causses region (France) show several kinds of partial melting. Rhyolitic glasses appear at the expense of the quartz + feldspar assemblage; initially undersaturated latitic glasses at the expense of biotite + feldspar (+ quartz); lastly hyperaluminous products derivating from large phenoblasts of alkali feldspar. The microprobe study of these glasses, of their contacts with the host lava, as well as that of the neogenic mineral phases, show that contamination occurs through, at least, four possible processes:

1. Diffusion at the interface between two liquids of contrasted composition (rhyolitic and basanitic).
2. Mechanical mixing of two liquids of less contrasted chemistry (latitic and basanitic).
3. Progressive solution of a solid phase (quartz) into the magma.
4. Vapour phase transfers.

Qualitative magmatic contamination in alkalies (mainly K) and silica results from all these processes; quantitatively, the most important of them seems to be 4.     

Zersetzung von Kalk-Alkali-Gesteinen im rezenten Fumarolengebiet auf Nea Kameni/Santorin/Griechenland

In the present phase of the volcanic activity on Nea Kameni / Santorini / Greece the calc-alkalic volcanic rocks are decomposed by H₂O, CO₂ and SO₂ gases of about 100 °C. Using a method ofGresens (1967) for the determination of gains and losses of compounds five different processes could be distinguished:

1. leaching of compounds
2. enrichment of Ca as gypsum
3. increase of Fe₂O₃ (6%–11%), TiO₂ (0,8%–3%) and Zr
4. enrichment of Al₂O₃ (15%–29%), TiO₂ (0,8%–1,5%) and K
5. increase of Al₂O₃ (15%–26%), Fe₂O₃ (6%–9%), TiO₂ (0,8%–1,3%), Sr, Ba, Pb and Zr

Finally a model for the process of decomposition of calc-alkalic volcanic rocks by sulfuric acid was developed.     

Kyanite eclogites

Prior experimental work has shown that in the laboratory the mineralogy of eclogites is sensitive to the ratio of CaO ∶ MgO ∶ FeO and that the reaction pyroxene + kyanite?garnet + quartz proceeds to the right at high pressures in rocks rich in magnesium and to the left in rocks rich in calcium and iron. Typical basalts crystallized at high pressure never contain kyanite. The chemistry and mineralogy of a large number of naturally occurring eclogites show they belong to three classes.

1. Kyanite-free magmatic eclogites, rich in magnesium, from:
2. kimberlites
3. dunites and serpentinites.
4. Kyanite-bearing eclogites and grosspydites rich in CaO and low in FeO with intermediate MgO from:
5. kimberlites
6. gneisses.
7. Kyanite-free eclogites of metamorphic origin rich in iron with low magnesium and intermediate amounts of calcium from:
8. glaucophane schists
9. gneisses.

     

A K-Ar and Sr-isotopic study of the volcanic rocks of the island of principe,West Africa — Evidence for mantle heterogeneity beneath the Gulf of Guinea

K-Ar dating on a suite of volcanic rocks from the island of Principe gives the following chronology.

1. Basal palagonite breccia (30.6 ± 2.1 Ma).
2. Older Lava Series (OLS) basalt (23.6±0.7 Ma) and hawaiite (19.1±0.5 Ma).
3. Younger Lava Series (YLS) nephelinite (5.60±0.32 Ma) and basanite (3.51 ±0.15).
4. Intrusive phonolite (5.32±0.17 Ma, 5.48±0.19 Ma), tristanite (4.89±0.15 Ma) and trachyphonolite (6.93±0.68 Ma) plugs.

Phonolites and YLS samples plot on a 5.9±0.3 Ma Rb-Sr isochron. The tristanite-trachy-phonolite suite samples also lie on this isochron. This lends support to the suggestion that the YLS basanite magmas were parental to the phonolites but rules out a similar relationship between the OLS magmas and the tristanite-trachyphonolite suite. The mean initial ⁸⁷Sr/⁸⁶Sr ratio for the YLS nephelinites and basanites is 0.70297. The basalts and hawaiites of the OLS show a positive ⁸⁷Sr/⁸⁶Sr vs. Rb/Sr correlation which may be interpreted as a 244±43 Ma pseudoisochron. This could be the result of a large-scale heterogeneity generated in the mantle during the early stages in the break-up of Gondwanaland. The mean initial ⁸⁷Sr/ ⁸⁶Sr ratio (at 21 Ma) for the OLS (0.70326) is significantly higher than that for the YLS and implies an isotopically distinct mantle source.     

The Araguainha astrobleme/Central Brazil

The following facts have supported the origin of the Araguainha circular structure in Central Brazil by a meteoritic impact:

1. the almost circular contour
2. the impact-morphologic sequence including a central uplift, ring walls and a basin rim of escarpments
3. outcrops of suevites and mixed breccias
4. the evidence of shock metamorphism
5. the presence of shatter cones, and
6. negative anomalies of the total intensity of the magnetic field at the center of the ring structure.

     

Low temperature\lg f_{O_2 } - pH diagrams of sulfur isotope evolution in an equilibrium hydrothermal system

According to Sakai-Ohmoto's theory regarding the evolution of sulfur isotopes in hydrothermal systems, in conjunction of new data on chemical resaction equilibrium constants and equilibrium isotopic fractionation factors as well as on individual ion activity coefficients of aqueous sulfur species, the following lgfo₂.-pH diagrams are constructed:

1. mole fractions of aqueous sulfur species (X _i ),
2. stability fields of some minerals in the Fe-S-O system,
3. diagram depicting the oxidation-reduction-state ratio for aqueous sulfur species (R′)
4. isotopic compositions of sulfur compounds ( \(\delta S_1 ^{34} \) ).

     

Some Xenoliths from the alkalic rocks of Teneriffe,Canary Islands

1. Xenoliths of ultrabasic, ultramafic, gabbroic or syenitic type occur in Teneriffe: dunites and clino-pyroxenites in the old alkalic basalt formations of Teno and Anaga peninsulas; gabbroic xenoliths in the Pedro Gil region; nepheline-syenite xenoliths in the Las Canadas and Vilaflor regions where intermediate and phonolitic lavas are abundant; ultramafic, clino-pyroxenite and syenitic xenoliths in the Anaga peninsula where there are many intrusions of nepheline-syenite and phonolitic syenite. Several xenoliths show signs of cataclasis, recrystallisation or reaction of their minerals with the host liquids.
2. The ultrabasic, ultramafic and anorthoclase-rich xenoliths appear to be of cumulus origin, subtracted from basic to intermediate alkalic liquids. Major cumulus phases are: magnesium-rich olivine, sub-silicic, aluminous pyroxene, titanomagnetite, sub-silicic potassic kaersutite, and anorthoclase. It is suggested that the xenoliths formed at depths between 11 km and 30 km, largely under wet conditions that helped suppress formation of cumulus plagioclase.
3. The subtraction of kaersutite from liquids of intermediate composition is thought to be a means of producing the gap in silica content between the Teneriffe trachybasalts and the more siliceous trachyphonolites and phonolites. It is also suggested that the subtraction of kaersutite and anorthoclase would considerably deplete residual liquids in alumina whilst enriching then in soda and this might be the means of producing peralkaline liquids.
4. The presence of the xenoliths supports the geophysical data that indicated that Teneriffe has a sub-crustal structure of plutonic rocks. Correlation of the Teneriffe plutonic xenoliths with exposed plutonic basement rocks from other Canary Islands, which are believed to have similar sub-crustal structures, is considered necessary.

     

Origin of coronas in metagabbros of the Adirondack mts., N. Y.

Metagabbros from two widely separated areas in the Adirondacks show development of coronas. In the Southern Adirondacks, these are cored by olivine which is enclosed in a shell of orthopyroxene that is partially, or completely, rimmed by symplectites consisting of clinopyroxene and spinel. Compositions of the corona phases have been determined by electron probe and are consistent with a mechanism involving three partial reactions, thus:

1. Olivine=Orthopyroxene+(Mg, Fe)⁺⁺.
2. Plagioclase+(Mg, Fe)⁺⁺+Ca⁺⁺=Clinopyroxene+Spinel+Na⁺.
3. Plagioclase+(Mg, Fe)⁺⁺+Na⁺=Spinel+more sodic plagioclase+Ca⁺⁺.

Reaction (a) occurs in the inner shell of the corona adjacent to olivine; reaction (b) in the outer shell; and (c) in the surrounding plagioclase, giving rise to the spinel clouding which is characteristic of the plagioclase in these rocks. Alumina and silica remain relatively immobile. These reactions, when balanced, can be generalized to account for the aluminous nature of the pyroxenes and for changing plagioclase composition. Summed together, the partial reactions are equivalent to:

1. Olivine + Anorthite = Aluminous orthopyroxene + Aluminous Clinopyroxene + Spinel (Kushiro and Yoder, 1966).

In the Adirondack Highlands, coronas between olivine and plagioclase commonly have an outer shell of garnet replacing the clinopyroxene/spinel shell. The origin of the garnet can also be explained in terms of three partial reactions:

1. Orthopyroxene+Ca⁺⁺=Clinopyroxene+(Mg, Fe)⁺⁺.
2. Clinopyroxene+Spinel+Plagioclase+(Mg, Fe)⁺⁺=Garnet+Ca⁺⁺+Na⁺.
3. Plagioclase+(Mg, Fe)⁺⁺+Na⁺=Spinel + more sodic plagioclase+Ca⁺⁺.

These occur in the inner and outer corona shell and the surrounding plagioclase, respectively, and involve the products of reactions (a)-(d). Alumina and silica are again relatively immobile. Balanced, and generalized to account for aluminous pyroxenes and variable An content of plagioclase, they are equivalent to:

1. Orthopyroxene+Anorthite+Spinel=Garnet (Green and Ringwood, 1967).

Amphibole coronas about opaque oxides in rocks of both areas are the result of oxide/plagioclase reactions with addition of magnesium from coexisting olivine. Based on published experimental data, pressure and temperature at the time of corona formation were on the order of 8 kb and 800° C for the garnet bearing coronas, with somewhat lower pressures indicated for the clinopyroxene/spinel coronas.     

Trace and minor element geochemistry of the rhyolitic volcanic rocks,Central North Island,New Zealand

Analytical data are presented for the following elements: Cs, Rb, Ba, K, Sr, Ca, Na, Fe, Mg, Cu, Co, Ni, Li, Sc, V, Cr, Ga, Al, Si, La, Y, and Zr. Eight samples were analysed by the spark source method for rare earths, Tl, Pb, Hf, Sn, Nb, Mo, Bi, and In. In addition to data on rhyolitic volcanics, a small number of intermediate volcanics and eugeosynclinal sediments were analysed for comparative purposes. The following features are shown by the trace element data:

1. The rhyolitic rocks have consistently lower concentrations of most trace and minor elements when compared with recent estimates of average concentrations in granites. None of the criteria for strong fractionation (e.g. low K/Rb, Ba/Rb and K/Cs ratios) are present.
2. The data do not indicate any systematic differences between the rhyolitic lavas and ignimbrites, although the very young rhyolitic pumices are consistently more “basic” in their element concentrations compared to the other rhyolitic analyses.
3. The residual glasses (and devitrified matrices) are depleted, relative to the total rock compositions, in Fe, Mg, Ca, Sr, V, Sc, and Al, and enriched in Cs, Rb, K, Ba, and Si. Zr is depleted in the residual glasses separated from rhyolites, but not in the andesitic residual matrices.
4. The rare earth fractionation patterns of the rhyolitic and andesitic extrusives are very similar, being intermediate between chondritic and sedimentary patterns i.e., there is no evidence of strong fractionation. The rhyolitic patterns also indicate a slight Eu depletion.
5. Comparable trace and minor element behaviour (with the possible exception of Zr) seems to exist through the rhyolite-andesite compositional range. This is supported by the whole rock-residual liquid trends for the various elements studied, which broadly coincide with the observed whole rock trends, both through the rhyolitic-andesitic compositonal range, and within the rhyolitic compositional range.

The data are finally discussed in the light of the possible origin of the rhyolitic magmas. It is believed that the analytical data presented are qualitatively consistent with the recently proposed idea that the magmas are derived by partial fusion of the associated Triassic-Jurassic eugeosynclinal greywacke-argillite sedimentary sequence.