Low-Temperature Plasticity of Naturally Deformed Calcite Rocks

Optical, cathodoluminescence and transmission electron microscope (TEM) analyses were conducted on four groups of calcite fault rocks, a cataclastic limestone, cataclastic coarse-grained marbles from two fault zones, and a fractured mylonite. These fault rocks show similar microstructural characteristics and give clues to similar processes of rock deformation. They are characterized by the structural contrast between macroscopic cataclastic (brittle) and microscopic mylonitic (ductile) microstructures. Intragranular deformation microstructures (i.e. deformation twins, kink bands and microfractures) are well preserved in the deformed grains in clasts or in primary rocks. The matrix materials are of extremely fine grains with diffusive features. Dislocation microstructures for co-existing brittle deformation and crystalline plasticity were revealed using TEM. Tangled dislocations are often preserved at the cores of highly deformed clasts, while dislocation walls form in the transitions to the fine-grained     

Dislocation generation, slip systems, and dynamic recrystallization in experimentally deformed plagioclase single crystals

Three samples of gem quality plagioclase crystals of An60 were experimentally deformed at 900 °C, 1 GPa confining pressure and strain rates of 7.5–8.7×10⁻⁷ s⁻¹. The starting material is effectively dislocation-free so that all observed defects were introduced during the experiments. Two samples were shortened normal to one of the principal slip planes (010), corresponding to a “hard” orientation, and one sample was deformed with a Schmid factor of 0.45 for the principal slip system [001](010), corresponding to a “soft” orientation. Several slip systems were activated in the “soft” sample: dislocations of the [001](010) and 110(001) system are about equally abundant, whereas 110{111} and [101] in ( 31) to ( 42) are less common. In the “soft” sample plastic deformation is pervasive and deformation bands are abundant. In the “hard” samples the plastic deformation is concentrated in rims along the sample boundaries. Deformation bands and shear fractures are common. Twinning occurs in close association with fracturing, and the processes are clearly interrelated. Glissile dislocations of all observed slip systems are associated with fractures and deformation bands indicating that deformation bands and fractures are important sites of dislocation generation. Grain boundaries of tiny, defect-free grains in healed fracture zones have migrated subsequent to fracturing. These grains represent former fragments of the fracture process and may act as nuclei for new grains during dynamic recrystallization. Nucleation via small fragments can explain a non-host-controlled orientation of recrystallized grains in plagioclase and possibly in other silicate materials which have been plastically deformed near the semi-brittle to plastic transition.     

Electron microscope study of peridotite xenoliths in kimberlites

Dislocation structures in naturally deformed olivine from garnet peridotite xenoliths from South African kimberlites have been studied by electron microscopy. The substructure consists mainly of straight subboundaries of dislocations with Burgers vectors [001]. Most of the dislocations have both edge and screw components, and the slip planes are mainly (100). The dislocation density between the subboundaries is low.The slip planes in olivine are discussed in relation to the olivine structure. The observed dislocation structures seem to indicate that the large difference in strain rate between natural and experimental deformation will produce a difference in the slip mechanisms.The nature of the deformation lamellae visible in optical microscope is discussed.     

Chemical etching of deformation sub-structures in quartz

Chemical etching of dislocations has been studied in natural and synthetic quartz single crystals, in deformed synthetic quartz and in naturally and experimentally deformed quartzites. The ability of different etchants to produce polished or preferentially etched surfaces on quartz is described. Dislocation etching was achieved on all crystal planes examined by using a saturated solution of ammonium bifluoride as the etchant. Appropriate etching times were determined for etching quartzites for grain size, subgrain boundaries, deformation lamellae, dislocations and twins. Growth and polished surfaces of synthetic single crystal quartz were similarly etched and dislocation etch pits, characteristic of various orientations were found. The use of ammonium bifluoride proved to be expecially advantageous for the basal plane, producing a polished surface with etch pits, suitable for dislocation etch pit counting. “Double” etch pits have been found on Dauphiné twin boundaries on the basal plane and the first order prism, using this etchant. Slip lines and deformation bands were suitably etched on deformed synthetic crystal surfaces for identification of the slip planes. Other acidic etchants have been explored and their application to the study of deformation structures in quartz crystals is discussed.     

Fluid inclusions,deformation and recrystallization in granite tectonites

An investigation has been made of the relationships between tectonic processes and fluid inclusions in quartz from variably deformed and syntectonically recrystallized granitic rocks from the Lachlan Fold Belt, eastern Australia. The quartz contains many fluid inclusions which decorate healed fractures introduced as a result of late-stage brittle deformation. The majority of small inclusions however, are associated with deformation band boundaries and deformation lamellae showing that they have been introduced during or subsequent to ductile deformation. Fluid inclusions disappear from the cores of sub-grains during recovery and before recrystallization, and new inclusions which form along sub-grain boundaries coalesce into stringers. Inclusions are eliminated from both sides of low angle boundaries showing that inclusions leak their contents either through the system of dislocations which accompanies grain interior slip, or by a dissolution-condensation process whereby inclusion contents move by lattice diffusion and condense on the boundaries.     

Defect structures in naturally deformed clinoamphiboles—a TEM study

Naturally deformed clinoamphiboles from the Selbu-Tydal and Forsbäck-Tärnaby areas of the Scandinavian Caledonides exhibit a well defined subgrain microstructure. From a transmission electron microscopy study (TEM), the subgrain boundaries are shown to consist of arrays of positive and negative screw dislocations with Burgers vector . Locally expanded loops are present having long screw segments. The subgrain boundaries are parallel to rational crystallographic planes of the type (hk0). The density of isolated dislocations within the subgrains is low. In addition planar defect structures parallel to (010) and bounded by screw dislocations with are observed. Based on metamorphic criteria the P−T values at the time of the amphibole growth have been estimated at 450°–600°C and 4–6 kbar, and these represent maximum conditions for the deformation. The present results indicate that slip on (hk0) [001] is an operative deformation mechanism in naturally deformed clinoamphiboles.     

Analysis of dislocations in some naturally deformed plagioclase feldspars

Dislocations in intermediate plagioclase feldspars, which were deformed under granulite facies conditions, have been analysed. The study reveals extensive ductile deformation by intracrystalline slip and by twinning. Six out of the seven possible Burgers vectors were identified: \(b = \left[ {001} \right],\tfrac{1}{2}\left[ {110} \right],\tfrac{1}{2}\left[ {1\bar 10} \right],\left[ {101} \right],\tfrac{1}{2}\left[ {112} \right]and\tfrac{1}{2}\left[ {1\bar 12} \right]\) . Most, perhaps all, dislocations are dissociated by up to 200 Å. The microstructure is dominated by [001] screw dislocations, most of which appear to be dissociated in (010). The dominant slip system appears to be (010) [001]. Large grain-to-grain variations in the density of free dislocations indicate that the plastic strain in individual grains depended upon the Schmid factor for (010) [001]. The microstructure suggests that the rate-controlling step for high-temperature creep of plagioclase is cross-slip of extended [001] screw dislocations. The rheological contrast between feldspar and quartz is partly due to a difference in stacking fault energy.     

Microfracturing in relation to atomic structure of plagioclase from a deformed meta-anorthosite

Brittle deformation of Caledonian age affects the Harris (Scotland) meta-anorthosite and occurs as restricted areas with penetrative networks of shear fractures, frequently associated with pseudotachylite. Plagioclase is cut by both transcrystalline and intracrystalline fractures, the latter being of two types: those directly induced by the transcrystalline shear fractures and those which appear to be independent of them. Several orientations of intracrystalline fractures may occur in any one grain.Whereas the orientations of the transcrystalline fractures may be independent of the plagioclase lattice, intracrystalline fractures are clearly crystallographically controlled. The most common intracrystalline fractures follow the main cleavage planes, (001) in all cases, but also frequently (010), (110) and (110). Other fracture directions, often conjugate, are very common. They include (021) and others near (111)–(121) and (111)–(121) close to the [101] and the [112] and [112] zones. These latter planes are those which also occur as cleavages in experimentally shocked microcline and as slip planes and deformation bands in experimentally deformed feldspars.The easy slip and low cohesion in plagioclase can be explained in terms of periodic bond chains in the feldspar structure. The close agreement in orientation between the unusual cleavages developed in the meta-anorthosite and experimentally produced deformation bands in plagioclase suggests that fracture occurs along the deformation bands parallel to dislocation glide planes.     

Experimental deformation of a synthetic dunite at high temperature and pressure. II. Transmission electron microscopy

We have performed detailed transmission electron microscope on most of the deformed synthetic dunite specimens prepared in the study by Zeuch and Green (1984). We have identified three basic types of sub-boundaries, simple tilt walls in (100) and (001). composed by b = [100] and b = [001] edge dislocations, respectively, and twist boundaries in (010) composed of b = [100] and b = [001] screws. We have also observed more complex, asymmetric lilt boundaries in (100) and (001). Like the (010) twist boundaries, these asymmetric tilt walls are common only at the highest temperatures and lowest strain rates. Subgrain development is extensive at the higher temperatures and lower strain rates, and subgrains are composed of the above-mentioned three types of sub-boundaries; edge components in (100) and (001) ire “knitted” to screw components in (010) as described by Kirby and Wegner (1978) for naturally deformed olivine. In many areas of the samples which we studied, subgrain development is not observed, but parallel arrays of tilt boundaries of one type or the other are present. At higher temperatures and lower strain rates. “(100) organization” (Durham et al., 1977) is common; this structure consists of parallel arrays of (100) tilt boundaries with b = [100] screws connecting the sub-boundaries. At lower temperatures we have observed an analogous arrangement of (001) sub-boundaries and b = [001] screws, which we refer to as “(001) organization”. Under all experimental conditions, dislocations with b = [100] and b = [001] are present in approximately equal numbers. However, the two types of dislocations also have distinctly different geometries under all test conditions. We suggest that the transition from slip parallel to [001] to slip parallel to [100] with increasing temperature, which has been reported in earlier studies may also depend upon water content. The substructures which we observe are virtually identical to those seen in many naturally deformed peridolites. and we conclude that the mechanisms involved in both natural and laboratory deformation of olivine polycrystals are similar. On the other hand, the substructures reported here are very different from those observed in experimentally deformed olivine single crystals. It seems likely that these substructural differences reflect fundamental differences in the behavior oh single crystals and polycrystals. which are in turn reflected in different measured creep strengths.     

TEM characterization of dislocations and slip systems in stishovite deformed at 14 GPa, 1,300°C in the multianvil apparatus

Transmission electron microscopy (TEM) has been used to investigate deformation microstructures of synthetic stishovite specimens deformed at 14 GPa, 1,300°C. Geometrical characteristics of numerous dislocations have been characterized by dislocation contrast and stereographic analyses in order to identify the easy slip systems of stishovite. TEM data allowed us to characterize the following slip systems: 〈100〉{001}, 〈100〉{010}, 〈100〉{021}, [001]{100}, [001]{110}, [001]{210} and Observation of sub-grain boundaries and scalloped edge dislocations suggest that climb has been activated in the specimens.     

Tectonic deformation and recrystallisation of oligoclase

Naturally deformed and partially recrystallised oligoclase porphyroclasts were studied in a high voltage electron microscope. The oligoclases had a highly deformed outer mantle zone, which contained high densities of dislocations and albite and pericline deformation twins, and less deformed cores containing fewer dislocations and albite twins but no pericline deformation twins. There was little evidence for recovery; apparently the internal strain energy due to deformation was relieved by recrystallisation. Strain free nuclei developed in areas with the highest defect densities. The resultant new grains had a lower anorthite content than their parents. It is suggested that the recrystallisation processes were aided by strain enhanced diffusion.     

Evidences of Cenozoic strike-slip dislocations of the red river fault system in Paleozoic carbonate strata of Cat Ba Island (Northern Vietnam)

The structural researches of carbonate strata in the northeastern segment of the framework of the Red River Fault System (Cat Ba Island, Northern Vietnam) has been carried out. It was found that weakly deformed carbonate strata are cut by NW-trending (300–310°) strike-slip faults. Development of plicative and disjunctive dislocations occurred along predominantly sinistral strike-slip fault zones formed as a result of ENE regional compression (80°) during the Oligocene-Miocene phase of deformation. Late dislocations confined to the Pliocene-Quaternary phase of deformation (NNW regional compression 330–350°), are relatively less developed. Seismic monitoring data show that both plicative and disjunctive dislocations have continued to the present.     

Cordierite microstructure and texture in a moldanubian gneiss

The microstructure and texture in cordierites of a moldanubian gneiss from the Bohemian Massif has been analysed by transmission electron microscopy (TEM) and universal stage in order to get information on the deformation mechanisms and textural development of this rock-forming mineral. Deformation may have taken place at temperatures between about 500° C and 630° C and pressures smaller than about 3 kb. The elongated cordierite xenoblasts show a typical dislocation creep microstructure consisting of subgrain boundaries and free dislocations. The dislocations have [001], [010] and 1/2<110> Burgers vectors. [001] dislocations often have pure screw and edge character the latter type being climb-dissociated on (001). Among the dislocations reactions are common. The main subgrain boundaries observed are (010)[001], {110}[001] and (001)[010] tilt boundaries. Burgers vectors and dislocation line directions reveal (100)[001], (010)[001], (100)[010], {110} 1/2<110> and (001)1/2<110> as activated slip systems. The crystallographic preferred orientation (here referred to as texture) consists of a [001] maximum in the foliation parallel to the mineral lineation. [100] and [010] maxima are perpendicular to it within and normal to the foliation, respectively, with a girdle tendency normal to the lineation. The texture may be explained by simple shear deformation on the {hkO}[001] slip systems with preference of (010)[001].     

Dislocations associated with optical features in naturally-deformed olivine

Transmission electron microscopy has been used for the direct observation of dislocations in naturally-deformed olivine. The dislocations are arranged in arrays forming low-angle sub-boundaries which have been identified with features observed in the optical microscope. Comparison of this dislocation substructure with that observed in olivine, and in metals, experimentally deformed under various conditions, suggests that the deformation in nature has occurred by creep. Possible mechanisms of creep, involving the cooperative glide and climb of dislocations, are discussed.     

Microstructures and flow mechanisms in regional metamorphic rocks of Japan

A number of microstructural features indicate a difference in the dominant deformation mechanism between the higher temperature Ryoke and the lower temperature Sambagawa and Shimanto metamorphic belts of Japan. The microstructures of metacherts containing deformed radiolaria are divided into two types: in both the Sambagawa and Shimanto belts the quartz grains are tabular while in the Ryoke belt they are equiaxed. TEM studies of these metacherts revealed that the tabular grains contain abundant subboundaries consisting of large numbers of network dislocations and bowe-out dislocations, while the equiaxed grains contain no subboundaries and have low densities of dislocations which are not bowed-out. There is a corresponding difference in the textures (lattice preferred orientation of quartz): the Ryoke metacherts display randomly distributed c-axes of quartz, while the Sambagawa and Shimanto metacherts show conspicuous crossed girdle patterns with some asymmetry. There is a third difference between these regions: in the metacherts of the Ryoke metamorphic belt, the strain magnitudes determined from deformed radiolaria increase with increasing volume fraction of mica in the same metamorphic P and T conditions, while in the Sambagawa and the Shimanto metamorphic cherts the strain magnitudes decrease with increasing the mica fraction.These microstructures, textures, and rheological behaviours of quartz-mica rocks suggest a change of deformation mechanism between the lower temperature Sambagawa and Shimanto, and the higher temperature Ryoke metamorphic belts. Since random fabrics of c-axes of quartz are inconsistent with lattice rotation due to dislocation glide, the Ryoke metacherts may have deformed by pressure-solution.     

含流体相条件下白云岩的低温流动变形--破裂与溶解-结晶的耦合过程

应用光学显微分析、阴极发光显微分析和TEM亚微分析．对于取自阿尔卑斯逆冲断层系底部的变形白云岩开展了详细的显微构造与岩石流动机制分析．光学显微构造和阴极发光分析表明岩石具有典型的类碎裂结构．微角砾常常是白云石颗粒的集合体组成,常常呈浑圆的形态和不规则的边界。基质颗粒中以新生结晶颗粒集合体为主．部分具有溶蚀特点的残余微角砾．而且它们经常具有新生结晶边。对于碎裂岩中变形残斑的透射电镜分析揭示出岩石的脆性特点．主要表现为各种不规则和缠结位错亚微构造特点的出现．而变形基质颗粒却很少具有或仅有微弱发育的位错亚结构。阴极发光显微结构分析进一步证实基质颗粒与微角砾之间在微量元素成分及形成时代上的差异。提出破裂(碎裂)及随后发生的溶解-迁移-结晶过程是断层带岩石细粒化与岩石应变的重要机制．认为破裂与溶解-结晶的耦合以及由此所致的岩石弱化为阿尔卑斯逆冲断层带巨大位移的形成做出了重要的贡献。     

方解石多晶集合体的高速率简单剪切变形实验研究

本文介绍了方解石多晶集合体在高应变率(373S^-1到1507S^-1)下简单剪切变形实验,结果表明,破裂形式和应变率有关,随着应变率的增加,从晶间微破裂为主变为晶内微破裂和粉碎为主。     

Transcrystalline shear fracturing and pseudotachylite generation in a meta-anorthosite (Harris, Scotland)

The meta-anorthosite is locally deformed by brittle shear fracturing, which progressively increases from isolated fractures with little cataclasite to many generations of closely spaced fractures, the intervening rock being highly deformed, in both a plastic and brittle way. In most cases an E-W compression on gently dipping to steep reverse shear planes occurs, which we relate to a Caledonian thrust zone.In places, the highly deformed rock is cut by pseudotachylite veins, which locally form networks. The pseudotachylite is generally intrusive, but does not appear to be related to movement on major slip surfaces. Very locally it may have formed in situ. Pseudotachylite only occurs in highly deformed rock, is only very occasionally deformed itself and, thus, generally represents at each locality the last stage of a complex deformation history, as if its presence welded the rock and prevented further deformation. These striking differences from the country-rock gneisses (in which pseudotachylite occurs on well developed fractures in very slightly deformed rock) are considered to be due to the low anisotropy of the meta-anorthosite, to its lower shear strength and to the easy propagation and branching of the shear fractures in plagioclase. The source of the heat necessary to generate the pseudotachylite melt is not clear—it may come from crack propagation as well as frictional sliding.     

糜棱岩化作用中角闪石变形结构的透射电子显微镜研究

石英的显微结构是判别含石英石变形程度的重要标志，为了认识角闪石在岩石变形过程中的特征，笔者对糜棱岩化闪长岩中普通角闪石的变形显微结构进行了光学和透射电子显微镜研究。研究的角闪石都在石英共生，因而以石英的变形结构作为角闪石变形研究的参照系。笔者发现，当石英呈明显波状消光时，普通角闪石未显示变形结构；当石英变形达到亚颗粒化和重结晶阶段时，普通角闪石的变形显微结构主要表现为单一方向的位错，其伯格斯矢量ｂ