Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.     

Sedimentology and palaeogeomorphology of four large valley systems incising delta plains, western Canada Foreland Basin: implications for mid-Cretaceous sea-level changes

The mid-Cenomanian Dunvegan Formation represents a delta complex deposited on a foreland basin ramp over about 2 my. The Dunvegan is divided into 10 transgressive–regressive allomembers, labelled J–A in ascending order, each defined by regional marine transgressive surfaces. Parasequences within allomembers show an aggradational to offlapping stacking pattern that reflects alternate generation and removal of accommodation. The upper surfaces of allomembers H–E are incised by extensive valley systems traceable for up to 320 km and over about 50 000 km². Valley depths range up to 41 m and can change significantly over short distances. However, the average depth of incision (mean 21 m) shows no systematic variation in longitudinal profiles and no evidence of headward shallowing. Valleys are typically 1–2 km wide, but locally widen to about 8 km. Widening is sometimes associated with confluence zones, but elsewhere it is not. Updip reaches of valleys are dominated by cross-bedded fluvial sandstone forming multistorey point-bar deposits. Sandstones contain widespread but uncommon paired carbonaceous drapes recognizable as tidal bundles. Inclined heterolithic stratification is locally well developed at the top of the valley fill. Downdip reaches of valleys, typically within 50 km of the lowstand shoreline, have a sandstone-dominated lower part and, locally, a mud-rich upper portion consisting of a variety of laminated heterolithic facies with a clear tidal signature. These heterolithic deposits may represent central basin, tidal flat, bayhead delta and point-bar environments. Valley filling took place mainly during the transgressive systems tract (TST) when tidally influenced environments migrated upvalley. Semi-diurnal tidal backwater effects extended at least 30 km landward of the regional maximum transgressive marine shoreline. The aggradational late TST and highstand systems tract (HST) includes deltaic and coastal plain deposits comprising lake and anastomosed river deposits that suggest a very low gradient (≈ 1:3000). Delta parasequences of the falling stage systems tract (FSST) offlap seaward and have no equivalent coastal plain deposits. The FSST has an average width of 60 km and an inferred gradient of 1:2500. The upper surfaces of the HST and FSST are extensively incised by valleys. The lowstand systems tract (LST) is subtly aggradational, lacks valleys and is characterized by large delta lobes fed by major distributaries. The width and inferred slope of the FSST, coupled with the thickness of aggradational TST and HST deposits on the coastal plain, suggest a vertical accommodation of about 35 m per transgressive event. About 11 m of this is attributed to isostatic subsidence resulting from water and sediment loads; the residual 24 m is attributed to eustatic rise. This sea-level change is of the same order of magnitude as the valley depths. The length of valleys, however, does not seem to be explicable solely in terms of downstream forcing by sea-level change, and an additional, upstream-forcing mechanism, possibly related to precipitation cycles in the Milankovitch band, might be inferred.     

The impact of tailings dam spills and clean-up operations on sediment and water quality in river systems: the Rı́os Agrio–Guadiamar,Aznalcóllar,Spain

The Aznalcóllar tailings dam at Boliden Apirsa's Aznalcóllar/Los Frailes Ag–Cu–Pb–Zn mine 45 km west of Seville, Spain, was breached on 25 April 1998, flooding approximately 4600 hectares of land along the Rı́os Agrio and Guadiamar with approximately 5.5 million m³ of acidic water and 1.3×10⁶ m³ of heavy metal-bearing tailings. Most of the deposited tailings and approximately 4.7×10⁶ m³ of contaminated soils were removed to the Aznalcóllar open pit during clean-up work undertaken immediately after the spill until January 1999. Detailed geomorphological and geochemical surveys of the post-clean-up channel, floodplain and valley floor, and sediment and water sampling, were carried out in January and May 1999 at 6 reaches representative of the types of river channel and floodplain environments in the Rı́o Guadiamar catchment affected by the spill. The collected data show that the clean-up operations removed enough spill-deposited sediment to achieve pre-spill metal (Ag, As, Cd, Cu, Pb, Sb, Tl, Zn) concentrations in surface sediment. These concentrations, however, are still elevated above pre-mining concentrations, and emphasise that mining continues to contaminate the Agrio-Guadiamar river system. Dilution by relatively uncontaminated sediment appears to reduce metal concentrations downstream but increases in metal and As concentrations occur downstream, presumably as a result of factors such as sewage and agriculture. River water samples collected in May 1999 have significantly greater dissolved concentrations of metals and As than those from January 1999, probably due to greater sulphide oxidation from residual tailings with concomitant release of metals in the warmer early summer months. These concentrations are reduced downstream, probably by a combination of dilution and removal of metals by mineral precipitation. Single chemical extractions (de-ionised water, CaCl₂ 0.01 mol l⁻¹, CH₃COONH₄ 1 M, CH₃COONa 1 M and ammonium oxalate 0.2 M) on alluvial samples from reaches 1 and 6, the tailings, pre-spill alluvium and marl have shown that the order of sediment-borne contaminant mobility is generally Zn>Cd>Cu>Pb>As. Pb and As are relatively immobile except possibly under reducing conditions. Much of the highly contaminated sediment remaining in the floodplain and channel still contains a large proportion of tailings-related sulphide minerals which are potentially reactive and may continue to release contaminants to the Agrio–Guadiamar river system. Our work emphasises the need for pre-mining geomorphological and geochemical data, and an assessment of potential contributions of contaminants to river systems from other, non-mining sources.     

Geochemical behaviour of major and trace elements in suspended particulate material of the Irtysh river,the main tributary of the Ob river,Siberia

In July 2001, samples of surface suspended particulate material (SPM) of the Irtysh river in its middle and lower reaches (from Omsk City to the confluence with the Ob river) and its main tributaries were collected (18 stations along 1834 km). The SPM samples were analyzed for major and trace element composition. The results show that the geochemistry of Irtysh river SPM is related to landscape and geochemical peculiarities of the river basin on one hand and to industrial activities within the drainage area on the other hand. In the upper basin polymetallic and cinnabar deposits and phosphorite deposits with high As content are widespread. The open-cut mining and developed oil-refining, power plants and other industries lead to the contamination of the environment by heavy metals and other contaminants. The territory of the West Siberian lowland, especially the Ob-Irtysh interfluve, is characterized by the occurrence of swamps and peat-bogs. Tributaries of the Irtysh river originating in this region, have a brown color and the chemical composition of the SPM is specific for stagnant water. In the first 500–700 km downstream from Omsk City the Irtysh river has the typical Al–Si-rich suspended matter composition. After the inflow of the tributaries with brown water the SPM composition is significantly changed: an increase of POC, Fe, P, Ca, Sr, Ba and As concentrations and a strong decrease of the lithogenic elements Al, Mg, K, Na, Ti, Zr can be observed. The data show that Fe-organic components (Fe-humic amorphous compounds, which contribute ca. 75–85% to the total Fe) play a very important role in SPM of the tributaries with brown water and in the Irtysh river in its lower reaches. Among the trace metals significant enrichments relative to the average for global river SPM could only be observed for As and Cd (coefficient of enrichment up to 16 for As and 3–3.5 for Cd). It can be shown that the enrichment of As in the SPM is related to natural processes, i.e. the weathering of phosphate containing deposits with high As concentrations in the upper Irtysh basin and the high As–P affinity in the swamp peaty soil. Dissolved P and As are absorbed by amorphous organic C/Fe oxyhydroxide components which act as carriers during the transport to the main stream of the Irtysh river. The role of anthropogenic factors is probably insignificant for As. In contrast, the enrichment of Cd is mainly related to anthropogenic input. The threefold enrichment of Cd in the SPM just below Omsk City and its continuous decrease down to background level at a distance of 500–700 km downstream points quite definitely to the municipal and industrial sewage of Omsk City as the main source of Cd in the SPM of the Irtysh river.     

Tectonic, sea-level, and climatic controls on Late Paleozoic sedimentation in the western basins of Argentina

Tectonic activity, sea-level changes, and the climate controlled sedimentation in Late Paleozoic basins of western Argentina. The role of each factor is investigated from the geologic record of the Río Blanco and Paganzo basins using three hierarchical orders of stratigraphic bounding surfaces. First-order surfaces correspond to regional unconformities, second-order ones to local unconformities with a lesser regional extent, and third-order surfaces represent locally extended sedimentary truncation. Using this methodology, the Carboniferous–Permian record of the Paganzo and Río Blanco basins may be divided into two megasequences, four sequences, and 12 stratigraphic sections. Megasequences are bounded by regional unconformities that result from tectonic events important enough to cause regional paleogeographic changes. Sequences are limited by minor regional extension surfaces related to local tectonic movements or significant sea-level falls. Finally, stratigraphic sections correspond to extended sedimentary truncations produced by transgressive events or major climatic changes. Sequence I is mainly composed of marine deposits divided into basal infill of the basin (Section 1) and Tournaisian–Visean transgressive deposits (Section 2). Sequence II is bounded by a sharp erosional surface and begins with coarse conglomerates (Section 3), followed by fluvial and shallow marine sedimentary rocks (Section 4) that pass upward into shales and diamictites (Section 5). The base of Sequence III is marked by an extended unconformity covered by Early Pennsylvanian glacial sedimentary rocks (Section 6) that represent the most important glacial event along the western margin of Gondwana. Postglacial deposits (Section 7) occur in the two basins and comprise both glaciolacustrine (eastern region) and transgressive marine (central and western regions) deposits. By the Moscovian–Kasimovian, fluvial sandstones and conglomerates were deposited in most of the Paganzo Basin (Section 8), while localized volcanic activity took place in the Río Blanco Basin. Near the end of the Carboniferous, an important transgression is recorded in the major part of the Río Blanco Basin (Section 9), reaching the westernmost portion area of the Paganzo Basin. Finally, Sequence IV shows important differences between the Paganzo and Río Blanco basins; fluvial red beds (Section 10), eolian sandstones (Section 11), and low-energy fluvial deposits (Section 12) prevailed in the Paganzo Basin whereas volcaniclastic sedimentation and volcanism dominated in the Río Blanco Basin. Thus, tectonic events, sea-level changes and climate exerted a strong and complex control on the evolution of the Río Blanco and Paganzo basins. The interaction of these allocyclic controls produced not only characteristic facies association patterns but also different kinds of stratigraphic bounding surfaces.     

Behavior of heavy metals in sulfide mine tailings and bottom sediment (Salair,Kemerovo region,Russia)

The given work focused on solving the problem of environmental geochemistry related to investigation of element speciation, their mobility, and migration in polluted areas. The purpose was to describe quantitatively migration, distribution, and redistribution of heavy metals by the example of the old tailings (Talmovaya sands) of the Lead Zinc Concentration Plant (Salair, Kemerovo region, Russia) and technogenic bottom sediments of the Malaya Talmovaya river. Contents of elements in the sulfide tailings range in the following limits: Zn: 1,100–27,000 ppm, Cd: 1.3–240 ppm, Pb: 0.01–0.81 ppm, Cu: 220–960 ppm, As: 15–970 ppm, Fe: 19,000–76,000 ppm, and Ba: 80,000–1,00,000 ppm. Element concentrations in the river sediment are proportional to the element contents in the sulfide tailings. Element speciations in the sulfide tailings and technogenic bottom sediments were investigated by the modified sequential extraction procedure. Chemical forms of heavy metals in pore water and surface water were calculated by WATEQ4F software. Principles of heavy metal migration in the sulfide tailings and technogenic bottom deposits were established. The obtained results about element species in the sulfide tailings and sediment explain the main principles of element migration and redeposition. In the mine waste and technogenic bottom deposits, there is vertical substance transformation with formation of geochemical barriers.     

Stratigraphic evidence for anthropogenically induced coastal environmental change from Oaxaca, Mexico

Previous interdisciplinary paleoenvironmental and archaeological research along the Río Verde Valley of Oaxaca, Mexico, showed that Holocene erosion in the highland valleys of the upper drainage basin triggered geomorphic changes in the river's coastal floodplain. This article uses stratigraphic data from sediment cores extracted from Laguna Pastoría, an estuary in the lower Río Verde Valley, to examine changes in coastal geomorphology potentially triggered by highland erosion. Coastal lagoon sediments contain a stratigraphically and chronologically distinct record of major hurricane strikes during late Holocene times. Three distinct storm facies are identified from sediment cores obtained from Laguna Pastoría, which indicate that profound coastal environmental changes occurred within the region and are correlated with increased sediment supplied from highland erosion. The Chione/Laevicardium facies was deposited in an open bay while the Mytella/barnacle facies and sand facies were deposited in an enclosed lagoon following bay barrier formation. We argue that highland erosion triggered major geomorphic changes in the lowlands including bay barrier formation by 2500 cal yr B.P. These environmental changes may have had significant effects on human populations in the region. The lagoon stratigraphy further indicates an increase in mid–late Holocene hurricane activity, possibly caused by increased El Niño frequencies.     

Dispersion of tailings in the Knabena—Kvina drainage basin, Norway, 1: Evaluation of overbank sediments as sampling medium for regional geochemical mapping

Molybdenum mining in the Knabena—Kvina drainage basin (1918–1973) left more than eight million tons of tailings in two small lakes in the headwater area of the Knabena river. The piles, that reach above the water surface, were freely eroded until a dam was built to reduce the dispersion in 1976. Sampling of tailings and fluvial sediments took place almost 20 years later. Sampling media were natural sediment sources, 1-cm-thick slices of overbank sediments of various depths, material from the tailings pond, sandbars, stream sediments, fjord sediments, and integrated samples of floodplain surfaces (0–25 cm). In total 734 samples were collected. Chemical analysis (ICP-AES after aqua regia or HNO₃ extraction) showed that overbank sediments at a certain depth represent the pre-industrial trace metal concentrations within the drainage basin. The tailings and recent fluvial sediments were enriched in approximately the same element suite. The highest enrichment factors were obtained for Cu (8–53) and Mo (22–57). Fluvial processes in the tailings pond have probably selectively eroded fine-grained, low-density particles. Thus, coarse chalcopyrite may have been left behind, while molybdate associated with fine-grained particles may have been selectively entrained causing dilution of Cu and enrichment of Mo in the downstream fluvial sediments. In the sandbars, the highest Cu and Mo concentrations were found in fine-grained sediments downstream of a low-gradient reach that act as a bedload trap. On the floodplains, it is seen that the first areas to be inundated in a flood situation (proximal to the river and in depressions) have the highest metal concentrations. For regional geochemical mapping it is suggested that overbank sediment profiles along river reaches with a laterally stable or slowly migrating channel, should be sampled. In such floodplains, pre-industrial overbank sediments are usually preserved at depth. In case of laterally unstable reaches upstream of the sampling point, polluted and unpolluted sediments may be interlayered or mixed. Therefore, samples should be collected from various depths or sedimentary units in such profiles. A similar sampling strategy should probably be adopted to detect vertical migration of elements especially in areas with acid rain and low bedrock buffer capacity. To obtain high contrasts between polluted and unpolluted drainage basins, the overbank sediment profiles should be within the proximal part of the floodplain.     

River system recovery following the Novaţ-Roşu tailings dam failure, Maramureş County, Romania

The River Vişeu catchment in Maramureş County, northwestern Romania, has a long history of base and precious metal mining. Between 1994 and 2003 waste from mining activity at Baia Borşa was stored in the Novaţ-Roşu tailings pond in the upper Vişeu catchment. However, in March 2000, the tailings dam failed releasing approximately 100,000 m³ of contaminated water and 20,000 t of mineral-rich solid waste, which was routed downstream through the Rivers Novaţ, Vaser and Vişeu into the River Tisa. Following the accident metal (Cd, Cu, Pb, Zn) concentrations in river water and river channel sediment were assessed in samples collected annually (July 2000, 2001, 2002 and 2003) from 29 sites in the Vişeu catchment, downstream of the tailings pond. Additionally, the speciation of sediment-associated metals was established using a 4-stage sequential extraction procedure (SEP) and Pb isotope analysis (^206/204Pb and ^207/204Pb) was carried out to establish the provenance of contaminated sediments. Metal concentrations in river water were found to comply with EU directive ‘target’ values within four months of the failure. However, the impact of the spill upon river channel sediments was found to be much longer-lasting, with evidence of the delayed downstream remobilization of tailings stored within the narrow Novaţ valley following the dam failure, as well as continued inputs of contaminated sediment to the River Vişeu from the River Tisla, another mining-affected tributary. Comparison with data from other recent tailings dam failures, indicates that river system recovery rates depend upon local geomorphological conditions, hydrological regimes, and the nature and scale of post-spill clean-up operations.     

Mobilization of metal-contaminated sediment by ice-jam floods

 A large river ice jam and associated flooding in February 1996 on the Blackfoot and Clark Fork Rivers of western Montana mobilized large amounts of fine-grained sediment. Metal concentrations in sediment downstream from a reservoir containing large amounts of contaminated sediment were enriched in metals after the ice jam, while open reaches above the reservoir were diluted by ice-jam processes. This varied response shows the importance of understanding ice jam events to sediment and metal transport and suggests that ice jams must be considered as important agents affecting sediment metal concentrations in rivers. Received: 4 December 1997 · Accepted: 23 February 1998     

A depositional model for offshore deposits of the lower Blue Gate Member,Mancos Shale,Uinta Basin,Utah, USA

Depositional models that use heterogeneity in mud‐dominated successions to distinguish and diagnose environments within the offshore realm are still in their infancy, despite significant recent advances in understanding the complex and dynamic processes of mud deposition. Six cored intervals of the main body of the Mancos Shale, the lower Blue Gate Member, Uinta Basin, were examined sedimentologically, stratigraphically and geochemically in order to evaluate facies heterogeneity and depositional mechanisms. Unique sedimentological and geochemical features are used to identify three offshore environments of deposition: the prodelta, the mudbelt and the sediment‐starved shelf. Prodelta deposits consist of interlaminated siltstone and sandstone and exhibit variable and stressed trace fossil assemblages, and indicators of high sedimentation rates. The prodelta was dominated by river‐fed hyperpycnal flow. Mudbelt deposits consist of interlaminated siltstone and sandstone and are characterized by higher bioturbation indices and more diverse trace fossil assemblages. Ripples, scours, truncations and normally graded laminations are abundant in prodelta and mudbelt deposits indicating dynamic current conditions. Mudbelt sediment dispersal was achieved by both combined flow above storm wave base and current‐enhanced and wave‐enhanced sediment gravity flows below storm wave base. Sediment‐starved shelf deposits are dominantly siltstone to claystone with the highest calcite and organic content. Bioturbation is limited to absent. Sediment‐starved shelf deposits were the result of a combination of shelfal currents and hypopycnal settling of sediment. Despite representing the smallest volume, sediment‐starved shelf deposits are the most prospective for shale hydrocarbon resource development, due to elevated organic and carbonate content. Sediment‐starved shelf deposits are found in either retrogradational to aggradational parasequence sets or early distal aggradational to progradational parasequence sets, bounding the maximum flooding surface. An improved framework classification of offshore mudstone depositional processes based on diagnostic sedimentary criteria advances our predictive ability in complex and dynamic mud‐dominated environments and informs resource prospectivity.     

Heavy metal anomalies in the Tinto and Odiel River and estuary system,Spain

The Tinto and Odiel rivers drain 100 km from the Rio Tinto sulphide mining district, and join at a 20-km long estuary entering the Atlantic Ocean. A reconnaissance study of heavy metal anomalies in channel sand and overbank mud of the river and estuary by semi-quantitative emission dc-arc spectrographic analysis shows the following upstream to downstream ranges in ppm (μg g^?1): As 3,000 to <200, Cd 30 to <0.1, Cu 1,500 to 10, Pb 2,000 to <10, Sb 3000 to <150, and Zn 3,000 to <200. Organic-rich (1.3–2.6% total organic carbon, TOC), sandysilty overbank clay has been analyzed to represent suspended load materials. The high content of heavy metals in the overbank clay throughout the river and estuary systems indicates the importance of suspended sediment transport for dispersing heavy metals from natural erosion and anthropogenic mining activities of the sulfide deposit. The organic-poor (0.21–0.37% TOC) river bed sand has been analyzed to represent bedload transport of naturally-occurring sulfide minerals. The sand has high concentrations of metals upstream but these decrease an order of magnitude in the lower estuary. Although heavy metal contamination of estuary mouth beach sand has been diluted to background levels estuary mud exhibits increased contamination apparently related to finer grain size, higher organic carbon content, precipitation of river-borne dissolved solids, and input of anthropogenic heavy metals from industrial sources. The contaminated estuary mud disperses to the inner shelf mud belt and offshore suspended sediment, which exhibit metal anomalies from natural erosion and mining of upstream Rio Tinto sulphide lode sources (Pb, Cu, Zn) and industrial activities within the estuary (Fe, Cr, Ti). Because heavy metal contamination of Tinto-Odiel river sediment reaches or exceeds the highest levels encountered in other river sediments of Spain and Europe, a detailed analysis of metals in water and suspended sediment throughout the system, and epidemiological analysis of heavy metal effects in humans is appropriate.     

Effects of colloids on metal transport in a river receiving acid mine drainage,upper Arkansas River,Colorado, U.S.A.

Inflows of metal-rich, acidic water that drain from mine dumps and tailings piles in the Leadville, Colorado, area enter the non-acidic water in the upper Arkansas River. Hydrous iron oxides precipitate as colloids and move downstream in suspension, particularly downstream from California Gulch, which has been the major source of metal loads. The colloids influence the concentrations of metals dissolved in the water and the concentrations in bed sediments. To determine the role of colloids, samples of water, colloids, and fine-grained bed sediment were obtained at stream-gaging sites on the upper Arkansas River and at the mouths of major tributaries over a 250-km reach. Dissolved and colloidal metal concentrations in the water column were operationally defined using tangential-flow filtration through 0.001-pm membranes to separate the water and the colloids. Surface-extractable and total bed sediment metal concentrations were obtained on the <60-μm fraction of the bed sediment. The highest concentrations of metals in water, colloids, and bed sediments occurred just downstream from California Gulch. Iron dominated the colloid composition, but substantial concentrations of As, Cd, Cu, Mn, Pb, and Zn also occurred in the colloidal solids. The colloidal load decreased by one half in the first 50 km downstream from the mining inflows due to sedimentation of aggregated colloids to the streambed. Nevertheless, a substantial load of colloids was transported through the entire study reach to Pueblo Reservoir. Dissolved metals were dominated by Mn and Zn, and their concentrations remained relatively high throughout the 250-km reach. The composition of extractable and total metals in bed sediment for several kilometers downstream from California Gulch is similar to the composition of the colloids that settle to the bed. Substantial concentrations of Mn and Zn were extractable, which is consistent with sediment-water chemical reaction. Concentrations of Cd, Pb, and Zn in bed sediment clearly result from the influence of mining near Leadville. Concentrations of Fe and Cu in bed sediments are nearly equal to concentrations in colloids for about 10 km downstream from California Gulch. Farther downstream, concentrations of Fe and Cu in tributary sediments mask the signal of mining inflows. These results indicate that colloids indeed influence the occurrence and transport of metals in rivers affected by mining.     

The influence of tectonically derived relief and climate on the extent of the last Glaciation east of the Patagonian ice fields (Argentina, Chile)

Two large ice fields between 46°30′ and 51°30′S cover the Patagonian Andes. The North and South Patagonian Ice Fields are separated by the transandine depth line at 47°45′ to 48°15′S. Canal and Río Baker run through this depression. The two ice fields are generally considered relics of a continuous ice cap, which covered the entire Patagonian Andes from 39° to 52°S and extended far into the eastern foreland of the Andes. This assumption is not correct for the 200-km-long section of the Andes between Lago Pueyrredón (Lago Cochrane in Chile) (47°15′S) and Lago San Martín (Lago O'Higgins in Chile) (48°45′S). The lack of a continuous ice cap extending far into the east is caused by the transandine depth line, playing a crucial role in the fluvial erosion and the glacial scouring of this tectonic zone. This depression formed a river system (e.g. Río Baker, Río Bravo and Río Mayer) that drains towards the west. Reconstruction of the maximum glacial advance of the last ice age shows that the eastern outlet glaciers of the two ice fields between Lago San Martín and Lago Pueyrredón did not drain towards the east, but rather followed the general gradient of the transandine depth line. In this area the eastern flank of the Andes between Monte San Lorenzo (3770 m) and Sa. de Sangra (2155 m) supported valley glaciers, which were independent of the expanding ice fields. Only a few valley glaciers advanced towards the Patagonian Meseta. The terminal moraines of these glaciers were erroneously interpreted as the eastern edge of a continuous ice cap. North of 47°30′S the outlet glaciers of the NPI advanced 200 km during the LGM and the late glacial advances nearly reached to 71°W. In contrast, south of 49°S glacier expansion was comparatively less: The LGM is situated only 85–115 km east of the present margins of the large outlet glaciers (O'Higgins, Viedma, and Upsala), and no late glacial advance reached 72°W. These considerable differences of glacier expansion were influenced by the northward migration of the westerly precipitation belt during glacial cycles. There is tentative evidence that the glaciers advanced three times in the period from 14 000 to 9 500 ¹⁴C years BP.     

Sediment-water interactions in the metal-contaminated floodplain of the Clark Fork River,Montana, USA

The distribution and concentration of metals and metalloids in the floodplain of the Clark Fork River of western Montana, USA, are mainly controlled by post-depositional diagenetic mechanisms of metal fractionation. Due to the influx of wastes into the river's headwaters from mining processes around the turn of the century, extensive amounts of contaminated material were deposited onto the floodplain. Tailings were deposited as widespread overbank deposits and point bars adjacent to abandoned channels, and are characterized by orange and gray mottled sediment, which is devoid of vegetation and covered by a blue metal sulfate precipitate during dry periods. Examination of stratigraphic profiles of floodplain sediment indicates three periods of deposition: 1) pre-mining, represented by coarse sand and organic overbank deposits under reducing conditions; 2) syn-mining, characterized by transition sediments and tailings deposits under oxidizing conditions; and, 3) post-mining, distinguished by grass-bound topsoil.Sites were established where sediments and water throughout the stratigraphic section were collected and analyzed. Chemical analyses indicate enriched concentrations of cadmium, copper, manganese, and zinc in sediments and porewater, and arsenic in groundwater, in areas contaminated by tailings deposits. Vertical trends in concentrations of metals show that they are distributed based on apportionment of metal phases between reducing-oxidizing environments and pH fluctuations.     

Major and trace metal mobility during weathering of mine tailings: Implications for floodplain soils

Mine tailings discharged to river systems have the potential to release significant quantities of major and trace metals to waters and soils when weathered. To provide data on the mechanisms and magnitudes of short- and long-term tailings weathering and its influence on floodplain environments, three calendar year-long column leaching experiments that incorporated tailings from Potosí, Bolivia, and soil from unaffected downstream floodplains, were carried out. These experiments were designed to model 20 cycles of wet and dry season conditions. Two duplicate columns modeled sub-aerial tailings weathering alone, a third modeled the effects of long-term floodplain tailings contamination and a fourth modeled that of a tailings dam spill on a previously contaminated floodplain. As far as was practical local climatic conditions were modeled. Chemical analysis of the leachate and column solids, optical mineralogy, XRD, SEM, EPMA, BCR and water-soluble chemical extractions and speciation modeling were carried out to determine the processes responsible for the leaching of Al, Ca, Cu, K, Na, Mg, Mn, Sn, Sr and Ti. Over the 20 cycles, the pH declined to a floor of ca. 2 in all columns. Calcium, Cu, Mg, Mn and Na showed significant cumulative losses of up to 100%, 60%, 30%, 95% and 40%, respectively, compared to those of Al, K, Sr, Sn and Ti, which were up to 3%, 1.5%, 5%, 1% and 0.05%, respectively. The high losses are attributed to the dissolution of relatively soluble minerals such as biotite, and oxidation of chalcopyrite and Cu-sulfosalts, while low losses are attributed to the presence of sparingly soluble minerals such as svanbergite, cassiterite and rutile. These results strongly suggest that the release of tailings to floodplains should be limited or prohibited, and that all tailings should be removed from floodplains following dam spills.     

水沙调节后荆江典型河道横向调整过程的响应——Ⅰ. 二、三维耦合模型的建立

三峡水库蓄水运用后,下游河道来水来沙条件均会发生改变,从而影响河道河势演变过程(包括垂向冲淤变化以及横向调整过程)。为解决长河道因岸滩崩塌引起的河势演变模拟问题,依据水位、流量及输沙量守恒和河床及河岸变形连续等条件,提出虚拟断面连接法构建了考虑岸滩崩塌的二、三维嵌套河势研究数值模型。采用1996年10月~1998年10月沙市至新厂河段实测资料对模型进行了验证,模拟结果与实测结果吻合较好,从而为定量研究水沙条件变化对荆江河道横向调整过程的影响提供了技术支撑。     

Geochemical investigations on fluvial sediments contaminated by tin-mine tailings,Cornwall, England

Tin-mine tailings containing high concentrations of Sn, Cu, Zn, Fe, Mn, As, and W are discharged into the Red River of cornwall, England and are then transported into St. Ives Bay under normal flow conditions. Most of the tin-bearing particles in the fluvial sediments are smaller than 170 μm, but tin-bearing composite grains or mineral grains with tin interspersed in the crystal lattices also occur in coarser size fractions. Tin distribution in the sediments is controlledby: (1) the distance from the source of the tailings, and (2) the concentration processes operating on the river bed. Suspended sediment and sediment transported by saltation filtered from river water samples also showed high concentrations of metals although, in contrast to the bottom sediments, they vary within a narrow range. Distributions of Cu, Zn, Fe, As, and Pb in the filtered sediments probably are related to the physical and chemical behavior of their sulphide minerals during fluvial transportation. A regional stream-sediment geochemical reconnaissance survey for tin did not show the highest concentration in the Red River; this indicated that in other rivers and streams tin reconcentration by selective removal of light minerals had taken place in the bottom sediments after mining operations had ceased. These rivers and streams also can transport large quantitiies of land-derived sediment including tin-mine tailings discharged into them when mines were operating. The minimum distance of tin transported by the Red River is at least 10 km; however, most of the tin was derived from mine tailings and is considered to be unnatural.     

Stratigraphic architecture and infill history of a deglaciated bedrock valley based on georadar, seismic profiling and drilling

The sediment fill of a silled bedrock valley in Western Norway has been investigated with respect to stratigraphy and infill history using a combination of mapping, georadar, seismic profiling and drilling. A small outlet glacier occupies the head of the valley that displays a stepwise down-valley profile and terminates in a lake at 29 m above sea-level. The valley is surrounded by high, steep bedrock slopes and is characterized by a series of filled basins each limited by sills of bedrock or moraine accumulations. Till, glacial outwash and/or rockslide deposits fill in the lower half of the two larger basins. (Fan) delta deposits fringed by the deposits of alluvial fans and colluvial cones dominate the upper fill of most basins. (Fan) delta deposits interfinger downstream with lake sediments in the larger basins and fluvial deposits comprise the top fill. The overall infill pattern was controlled by deglaciation as well as basin size and shape. An overall decreasing sediment supply following deglaciation is shown in the fill of a larger basin down-valley, whereas a recently increasing sediment supply during glacier growth is reflected primarily in an upstream basin. Only the lowermost basin was exposed to a sea-level drop from 75 m above sea-level to the present lake level associated with incision and river migration. This observation is in contrast to the basins above marine influence where incision has been limited due to fixed downstream sills resulting in insignificant erosion except for some fan-head entrenchment. It follows that the fills of these small valley basins display progradational and aggradational trends of deposition and paraglacial reworking has been limited. Additionally, the study demonstrates that georadar profiling, combined with other methods, is very useful for comprehensive investigation of valley basins.     

River processes after rapid valley-filling due to large landslides

A three-stage model is proposed to describe river processes after rapid valley-filling due to large landslides, based on surveys on the Shirayuki river basin in northeast Japan. At Stage I slightly entrenched debris avalanche deposits get covered with fluvial sediments. At Stage II the river along the upper reaches deeply cuts into fill deposits while fan aggradation occurs along the lower reaches. At Stage III river incision occurs along all the courses. This sequence of river processes reflects the changing amounts of post-landslide debris supply from the landslide scar and river banks. The three-stage model is also applicable to other examples of post-landslide river processes, although some lack the Stage I. Morphometric analyses suggest that the presence or absence of the Stage I depends on the ratio of debris supply from the landslide scar to river competence of sediment delivery.