西南太平洋新喀里多尼亚洛亚蒂盆地的现代沉积作用

洛亚蒂盆地沉积物是棕黄色软泥和生物碎屑砂。它们有5个来源:新喀里多尼亚堤礁、深海生物群落、浮游生物群体和火山碎屑。沉积物由浊流和半深海沉积物的互层组成,可以通过粒度分析,矿物成分和生物碎屑的分析将两者加以区分。通过对蒂奥和利富之间的岩心的研究,认识到在蒂奥水道对面,分布着一个展布广阔,但幅度很小、延伸50km的海底扇。     

Quaternary sediments in the axial zone of the Brazil Basin

Lithological and micropaleontological studies of sediments were carried out along the meridional profile across the Brazil Basin. Based on nannoplankton and diatom assemblages, the sediments represented by oxidized miopelagic clays, differently reduced hemipelagic clays, and clayey-siliceous (Ethmodiscus) and calcareous (coccolith-foraminiferal) oozes are attributed to the Pleistocene-Holocene. Specific features of sedimentary material indicate its redeposition by Antarctic bottom waters, mudflows, slumps, and rockslides. It is shown that sedimentation in the Brazil Basin corresponds to the incomplete pelagic (miopelagic) type of oceanic lithogenesis transitional to the near-continental one.     

Deep-water resedimentation of anhydrite and gypsum deposits in the Middle Miocene (Belayim Formation) of the Red Sea, Egypt

The Middle Miocene evaporites in the Red Sea rift were deposited within a complex system of fault-bounded basins that were episodically active during sedimentation. Such a tectonic framework is known to be highly favourable to resedimentation processes. An offshore petroleum well in the north-western Red Sea has cored, below a massive salt unit, an anhydrite-bearing succession which provides an excellent opportunity to study the processes of gravity induced redeposition of Ca-sulphates in a deep basin. Anhydrite deposits, interbedded with siliciclastic layers and thin halite layers, are composed of resedimented facies ranging from fine-grained laminated sediments to coarse-grained breccias. The components derive from the reworking of shelf sediments deposited initially in shallow water to supratidal settings on the surface and edges of structural highs bordering depressions: proximal siliciclastic deposits with interstitial anhydrite (cement patches, nodules) or gypsum and dolostones with early diagenetic anhydrite facies (nodular, chicken-wire) formed in sabkha conditions, interstitially grown gypsum crystals and subaqueous gypsum crusts precipitated in hypersaline ponds, and diatom-rich oozes formed in marine, shallow-water conditions. The homogeneity of the stable isotope composition and petrography of sulphates argue for the initial crystallization of Ca-sulphates within brines of the same origin and in closely interconnected sedimentary settings. The unconsolidated sediments redeposited as slope-foot accumulations were carried both as anhydrite (nodules, soft masses, various fragments, individual grains or crystals released by disintegration of large masses) and gypsum (crystalline aggregates or single crystals) later converted to anhydrite during burial. Layers of chaotic breccia are interpreted as the result of seismic events, whereas the fine-grained deposits could be related to redistribution by nepheloid layers of suspensions of finer grains released by disintegration of the soft anhydrite masses during downslope transport, or of in situ deposits removed by the turbiditic flows.     

Grain size and geochemistry of surface sediments in northwestern continental shelf of the South China Sea

Eighty-six surface sediments collected from the northwestern continental shelf of the South China Sea (SCS) were analyzed for grain size distribution, calcium carbonate, organic carbon, and major and trace element compositions to investigate sediment provenance and factors controlling their geochemical composition. Sediments from the eastern continental shelf of Hainan Island have higher sand and lower clay content, while the samples from the nearshore Hainan Island have higher contents of gravel and clay. Calcium carbonate contents in samples show a positive correlation with water depth in northwestern shelf of SCS, suggesting that it is related to biological factors. However, the nearshore sediments have higher contents of organic carbon compared to those of the outer shelf, possibly suggesting that the terrigenous organic matter usually deposited in nearshore environments such as bays and estuaries. Compared with the upper continental crust, the samples have relatively lower contents of SiO₂ and Al₂O₃, higher than those of the Pearl and Red river sediments. The low contents of K₂O and Na₂O in sediments from the northwestern continental shelf are consistent with intense chemical weathering in the river basin due to the seasonally hot and humid climate regime. The sediments mainly consist of three components, including the gravel fraction composed of calcareous debris, the sand fraction composed of quartz, and the silt and clay fractions mainly composed of clay minerals. The content of each component depends on grain size, sediment source, biogenesis, and hydrodynamic conditions, which finally controls the chemical composition of the sediments. The distributions of Co/Al₂O₃, Cr/Al₂O₃, and Zr/Sc ratios for sediments in the northwestern continental shelf suggest that source rocks are mainly composed of felsic rocks rather than mafic rocks. There is a distinct difference in sediment source between eastern and western shelf sediments; the eastern shelf sediments are characterized by high Zr/Sc ratios mainly derived from the Pearl River, while the western shelf sediments have relatively low values of Zr/Sc indicating a main contribution possibly sourced from the Red River Basin. Terrigenous materials from Hainan Island usually influence the geochemistry of sediments deposited in the nearshore area.     

Radiolarites et sédiments hypersiliceux océaniques: une comparaison

The mineralogical and chemical composition of Jurassic radiolarian cherts has been studied in Morocco (Rif), Italy (Lombardy basin and Apennines), Greece (Pindus zone and Vourinos Massif), some in close association with ophiolites. We have compared these samples with Cretaceous cherts from the NW Pacific (Leg 32) and with Cenozoic diatomaceous oozes from the Sea of Japan (Leg 31). The silica in the radiolarian cherts is quartz or chalcedony. Most of these rocks also contain feldspars and hematite while the clay fraction is composed of illite and/or chlorite generally associated with swelling clays and, locally, with kaolinite. In oceanic sediments all mineralogical species of silica have been detected (from opal to quartz), the clays generally being the same as those of the radiolarian cherts, the feldspars also being present. Based on the chemical composition of the radiolarian cherts, three facies can be distinguished: massive cherts, pelitic radiolarites and ferruginous radiolarites, the latter occurring only near the contact with volcanic basement. The chemical composition of cherts and diatom oozes from the Pacific is very close to the composition of radiolarian cherts. Although the mineralogy of radiolarian cherts can be related to several models (detrital, diagenesis of pelagic clays etc.) the detrital origin of part of the clay fraction seems certain. The origin of silica and its relation to the palaeolatitudes and the relatively confined nature of the Tethys oceans as well as the influence of volcanic inputs are evaluated, Chemical and mineralogical composition of radiolarian cherts shows that the diagenesis of the clay fraction is not a significant source of silica. Accumulation of diatom oozes in the Sea of Japan and in other areas, shows that the distance from continents and very deep seas are not essential to the development of siliceous sedimentation.     

Sedimentation in the Angola and Cape basins during the quaternary

Reference cores of sediments from the Angola and Cape basins were subjected to lithological, geochemical, and micropaleontological investigations. Based on nannofossil and diatom assemblages, the examined sediments represented by oxidized miopelagic clays, calcareous (nannofossil-foraminiferal, foraminiferal-nannofossil), calcareous-clayey, and clayey-calcareous mud are estimated to be the Pleistocene-Holocene in age. The Cape Basin section includes surface and buried ferromanganese nodules. There are indications of sedimentary material redeposition by the Antarctic Bottom Water and turbidity currents. The South Polar Front zone changed repeatedly its geographic position and migrated northward from the presentday one. As a whole, the Pleistocene-Holocene sedimentation in the Angola and Cape basins corresponds to the incomplete pelagic (miopelagic) type of oceanic lithogenesis.     

Rare Earth Elements in the Bottom Sediments of the East Arctic Seas of Russia as Indicators of Terrigenous Input

The REE distribution was studied in the bottom sediments of the East Arctic shelf of Russia. It is established that sediments of the Laptev and western East Siberian seas are significantly enriched in REEs, the contents of which are much higher than those of other near-continental basins. The main REE sources are runoff of the Lena River, the basin of which comprises ancient crystalline shields and magmatic rocks enriched in LREEs with significant contribution from the coastal erosion of the ice complex from the Laptev Sea and western East Siberian Sea. The terrigenous flux with a specific REE composition is supplied to the Chukchi Sea through the Bering Strait.     

Dinantian sedimentation and the basement structure of the Derbyshire Dome

The depositional history of the Dinantian on the Derbyshire Dome can be divided into three phases: (1) pre-Holkerian: onlap of an irregular basement surface by evaporite and carbonate sediments, (2) Holkerian to Asbian: sedimentation on a carbonate shelf formed by the merging of early Dinantian depocentres following burial of the basement topography, and (3) Brigantian: formation of intrashelf basins and the development of a carbonate ramp on part of the pre-existing shelf. A model of the basement structure underlying the Derbyshire Dome is presented to explain the location of the Brigantian intrashelf basins and carbonate ramp. The basement consists of two main tilted fault blocks separated by a smaller tilt block. Movement on faults bounding the tilt blocks caused the development of intrashelf basins. The basin margins were controlled by structures which developed in the cover sediments. The carbonate ramp present during the late Brigantian developed in response to an eastward tilting of the basement.     

广西那坡盆地火山岩-碳酸盐岩混杂型滑塌堆积:特殊的弧前域构造指相标志及其大地构造意义

本文详细调查揭示,位于中越边境地区的那坡弧前盆地北部边缘发育17处滑塌堆积,有些表现为火山岩-碳酸盐岩块混杂型滑塌堆积,即由火山岩滑塌块体和碳酸盐岩滑塌块体无序堆积而成;有些只是具软沉积变形特征的薄层碳酸盐岩滑塌块体;还有些是砂屑灰岩滑塌块体与碳酸盐岩(或钙质)浊积岩组合以及单一的碳酸盐岩浊积岩或碳酸盐岩碎屑流。碳酸盐岩质块体流和碎屑流一般夹于大型或巨型滑塌块体间,而碳酸盐岩(或钙质)浊积岩和块状砂岩等一般发育于滑塌堆积的远端,有的覆盖于滑塌块体之上。无论是时代还是地球化学组成,滑塌堆积中的具枕状构造的火山岩块与盆地北侧富宁县架街一带的早-中三叠世弧火山岩完全一致。具软沉积变形特征的薄层碳酸盐滑塌岩块中发育有厚30cm左右的风暴沉积层,暗示这些滑塌岩块是发育于火山弧边缘的或其上的局部的碳酸盐岩台地(主要为潮坪-潟湖相)沉积。与全球不同造山带弧前盆地对比表明,这些滑塌堆积是一种发育于构造活动强烈的弧前盆地边缘的特殊的事件沉积,可作为识别弧前域大地构造相单元的普适性沉积标志,也可用以分析断定俯冲增生造山极性。本文对碳酸盐岩滑塌块体的原始层理和软沉积变形的滑塌褶皱轴面方位测量统计揭示火山弧斜坡大体向南西方向(232°~240°)倾斜,滑塌堆积远端浊积岩古水流测量与校正结果揭示沉积物搬运方向为南或南西向,这表明华南地块与北越地块之间的古特提斯分支洋盆在早三叠世期间是向北俯冲消化减的。     

Phosphorus in foraminiferal sediments from North Atlantic Ridge cores and in pure limestones

Samples of foraminiferal ooze from two North Atlantic cores were cleaned and progressively dissolved. Most of the P, Fe, and Mn was released during the first of two reductive cleaning steps. Most of the remainder of these elements and most of the Ca were released during the final acid dissolution step. The P in these samples is present largely in Fe- and Mn-rich coatings, not as a constituent of the foraminiferal shells themselves. Our results are consistent with those of earlier studies.The concentration of P in carbonate oozes in which it is clearly associated with coatings is similar to that of modern calcareous sediments in general, and with that of reasonably pure limestones of all ages. Phosphorus is apparently associated with (Fe, Mn)-oxide coatings in many carbonate sediments. The rate of removal of P from the oceans as a constituent of such sediments depends on the rate of formation of (Fe, Mn) coatings, not on the rate of incorporation of P into calcium carbonate.     

Age assignment of a diatomaceous ooze deposited in the western Amundsen Sea Embayment after the Last Glacial Maximum

Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is challenging because of the rarity of calcareous (micro‐) fossils and the recycling of fossil organic matter. Consequently, radiocarbon (¹⁴C) ages of the acid‐insoluble organic fraction (AIO) of the sediments bear uncertainties that are difficult to quantify. Here we present the results of three different methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional ¹⁴C dating of the AIO in bulk samples yielded age reversals down‐core, but at all sites the AIO ¹⁴C ages obtained from diatomaceous ooze within the diatom‐rich unit yielded similar uncorrected ¹⁴C ages between 13 517 ± 56 and 11 543 ± 47 years before present (a BP). Correction of these ages by subtracting the core‐top ages, which probably reflect present‐day deposition (as indicated by ²¹⁰Pb dating of the sediment surface at one core site), yielded ages between ca. 10 500 and 8400 cal. a BP. Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1300 a indicated deposition of the diatom‐rich sediments between 14 100 and 11 900 cal. a BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka for the diatom‐rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves. As a third dating technique we applied conventional radiocarbon dating of the AIO included in acid‐cleaned diatom hard parts extracted from the diatomaceous ooze. This method yielded uncorrected ¹⁴C ages of only 5111 ± 38 and 5106 ± 38 a BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the diatom hard parts prior to sample graphitisation and combustion for ¹⁴C dating. The deposition of the diatom‐rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes elsewhere on the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related. Copyright © 2009 John Wiley & Sons, Ltd.     

Deposition and derivation of clastic carbonates on a Mesozoic continental margin, Othris, Greece

The Othris Mountains of eastern Greece contain a calcareous continental margin/ocean basin sequence exposed in a stack of Cretaceous thrust sheets. Upper Triassic to Lower Cretaceous shelf, submarine fan and basinal successions overlie shallow marine units of Lower Triassic and Permian age. In off-shelf sequences the older sediments are separated from the younger by a horizon of alkaline ‘early-rifting’ basalts. Ophiolites overthrust the marginal sequence. Pre-rifting sediments are represented by a varied suite of limestones and clastics resting on metamorphic basement and include distinctive, green lithic arenites. In the thrust sheet immediately over the para-autochthonous shelf sequence, pre-rifting sediments are separated from the rift basalts by an intermittent horizon of calcareous sandstones and conglomerates reworked from uplifted basement and older sediments. Textural and petrographic immaturity suggests that these are probably deposits derived from fault scarps, produced in an early phase of rifting. Above the basalts in the same sheet is a suite of calciclastic sediment-gravity-flow deposits, apparently sedimented on a submarine fan. Progressive downslope modification of calcirudites suggests deposition from evolving, high concentration flows. Massive calcarenite facies (? grain flows) are unusually abundant; a possible reflection of a shallow palaeo-shelf break since provenance and palaeocurrent evidence proves the clastic carbonates to have been derived from a calcareous shelf. In addition to limestone lithoclasts the calcirudites, but not the massive calcarenites, contain fragments of pre-rifting lithologies including the distinctive arenites. Since the shelf sequence in Othris is totally nondetrital these clasts imply derivation of coarse sediment from an off-shelf position; probably the walls of a submarine canyon. This may have occurred either by direct erosion of wall rock, or by reworking of material from an older clastic sequence. In the latter case the inferred fault-scarp deposits are a likely source.     

Holocene deposits in the Mangyshlak Peninsula,North Caspian Sea region

Comprehensive analysis of the data of high-precision seismoacoustic profiling, drilling and sampling of deposits using seabed corers, biostratigraphic studies, and radiocarbon age data was performed for the first time for Mangyshlak sediments in several bottom sites of the North Caspian. It was found that the Mangyshlak sediments comprise numerous linearly stretched depressions of 5–10 m in depth (morphologically similar to modern substeppe ilmen areas in the Volga River delta), which are covered by the Novocaspian sedimentary cover, and river incisions (among them the largest Volga River valley). In addition, the Mangyshlak sediments comprise the deltaic alluvial fans of different sizes along the shelf zone of the North Caspian. Analysis of mollusks and biogenic remains indicates that accumulation of the Mangyshlak sediments occurred in freshwater and slightly salty water environments under various hydrodynamic and hydrochemical conditions. According to radiocarbon dating of organic matter, the Mangyshlak sediments formed during sea regression in the range of 10-8 ka (isotopic age) or 11.5-8.5 ka (calendar age). Several types of sediments are distinguished: clayey-carbonate sediments, enriched with organic matter up to the formation of sapropel and peat, accumulated at the lowest sea level; weakly calcareous silty-clayey silts, formed during the subsequent intense filling of paleodepressions with terrigenous material. The features of the mineral composition of sediments are as follows: polymineral composition of clayey material with a high proportion of hydromica and disordered mixed-layered formations, a high content of minerals of the epidote group, amphiboles, and other accessory minerals. All of this indicates a genetic relationship between the Mangyshlak sediments and the Volga terrigenous material.     

Regional tectonic framework,structure and evolution of the western marginal basins of India

The Kutch-Saurashtra, Cambay and Narmada basins are pericontinental rift basins in the western margin of the Indian craton. These basins were formed by rifting along Precambrian tectonic trends. Interplay of three major Precambrian tectonic trends of western India, Dharwar (NNW-SSE), Aravalli-Delhi (NE-SW) and Satpura (ENE-WSW), controlled the tectonic style of the basins. The geological history of the basins indicates that these basins were formed by sequential reactivation of primordial faults. The Kutch basin opened up first in the Early Jurassic (rifting was initiated in Late Triassic) along the Delhi trend followed by the Cambay basin in the Early Cretaceous along the Dharwar trend and the Narmada basin in Late Cretaceous time along the Satpura trend. The evolution of the basins took place in four stages. These stages are synchronous with the important events in the evolution of the Indian sub-continent—its breakup from Gondwanaland in the Late Triassic-Early Jurassic, its northward drifting during the Jurassic-Cretaceous and collision with the Asian continent in the Early Tertiary. The most important tectonic events occurred in Late Cretaceous time. The present style of the continental margins of India evolved during Early Tertiary time.The Saurashtra arch, the extension of the Aravalli Range across the western continental shelf, subsided along the eastern margin fault of the Cambay basin during the Early Cretaceous. It formed an extensive depositional platform continuous with the Kutch shelf, for the accumulation of thick deltaic sediments. A part of the Saurashtra arch was uplifted as a horst during the main tectonic phase in the Late Cretaceous.The present high thermal regime of the Cambay-Bombay High region is suggestive of a renewed rifting phase.     

Carbonate ramp-to-deeper shale shelf transitions of an Upper Cambrian intrashelf basin, Nolichucky Formation, Southwest Virginia Appalachians

The Nolichucky Formation (0–300 m thick) formed on the Cambrian pericratonic shelf in a shallow intrashelf basin bordered along strike and toward the regional shelf edge by shallow water carbonates and by nearshore clastics toward the craton. Lateral facies changes from shallow basinal rocks to peritidal carbonates suggest that the intrashelf basin was bordered by a gently sloping carbonate ramp. Peritidal facies of the regional shelf are cyclic, upward-shallowing stromatolitic carbonates. These grade toward the intrashelf basin into shallow ramp, cross-bedded, ooid and oncolitic, intraclast grain-stones that pass downslope into deeper ramp, subwave base, ribbon carbonates and thin limestone conglomerate. Ribbon limestones are layers and lenses of trilobite packstone, parallel and wave-ripple-laminated, quartzose calcisiltite, and lime mudstone arranged in storm-generated, fining upward sequences (1–5 cm thick) that may be burrowed. Shallow basin facies are storm generated, upward coarsening and upward fining sequences of green, calcareous shale with open marine biota; parallel to hummocky laminated calcareous siltstone; and intraformational flat pebble conglomerate. There are also rare debris-flow paraconglomerate (10–60 cm thick) and shaly packstone/wackestone with trace fossils, glauconite horizons and erosional surfaces/hardgrounds. A 15-m thick tongue of cyclic carbonates within the shale package contains subtidal digitate algal bioherms which developed during a period of shoaling in the basin. Understanding the Nolichucky facies within a ramp to intrashelf basin model provides a framework for understanding similar facies which are widely distributed in the Lower Palaeozoic elsewhere. The study demonstrates the widespread effects of storm processes on pericratonic shelf sedimentation. Finally, recognition of shallow basins located on pericratonic shelves is important because such basins influence the distribution of facies and reservoir rocks, whose trends may be unrelated to regional shelf-edge trends.     

Manganese Sources and Sinks in the Arctic Ocean with Reference to Periodic Enrichments in Basin Sediments

Between 1990 and 2007, twenty-nine box cores were recovered within the Arctic Ocean spanning shelf, slope and basin locations, and analyzed for aluminum (Al), manganese (Mn), other inorganic components and organic carbon (C_Org). Using these core data together with literature values, we have constructed budgets for Al and Mn in the Arctic Ocean. Most of the Al and Mn entering the Arctic comes from rivers or coastal erosion, and almost all of these two elements is trapped within the Arctic. Total Mn distributions in sediments reflect the recycling and loss of much of the Mn from shelf sediments with ultimate burial over the slopes and in basins. Mn enrichments observed as bands in long cores from the basins appear to co-occur with inter-glacial periods. Our Mn budget suggests that change in sea level associated with the accumulation and melting of glaciers is a likely cause for the banding. The Arctic Ocean, which presently contains as much as 50% shelf area, loses most of that when global sea level falls by?~120?m during glacial maxima. With lower sea level, Mn input from rivers and coastal erosion declines, and inputs become stored in permafrost on the sub-aerial shelves or at the shelf margin. Sea-level rise re-establishes coastal erosion and large riverine inputs at the margin and initiates the remobilization of Mn stored on shelves by turning on algal productivity, which provides the C_Org required to reduce sedimentary Mn oxyhydroxides.     

Sedimentation of the northwestern Gulf of Mexico

Six years of intensive study of the shallow water sediments of the northwestern Gulf of Mexico have indicated that there are many criteria by which ancient sediments deposited under similar conditions can be recognized. Thus the presence of echinoid fragments and of glauconite-filled Foraminifera tests favors marine shelf deposition over bay deposits; calcareous aggregates and grains of gypsum suggest high salinity bay deposits; abundance of wood fibers, high mica content, ferruginous aggregates, and well laminated sediments all are suggestive of deposition near river mouths; greater roundness distinguishes dunes from adjacent beach sands; and coarser grain size distinguishes beach sands from shallow shelf sands in the vicinity.Faunal assemblages of Foraminifera, Ostracoda, and Mollusca all serve to distinguish between bay and shelf deposits. Within the bays the faunas show a close relationship to salinity conditions whereas on the shelf the faunas are arranged in bands parallel to the shore and to the depth contours. Certain generalizations concerning the relation of faunas to environment can be made without detailed knowledge of the species.Contribution from the Scripps Institution of Oceanography, New Series No. 997. Investigation supported by a grant from American Petroleum Institute, Project 51.     

Lithology and late postglacial stratigraphy of bottom sediments in isolated basins of the White Sea coast exemplified by a small lake in the Chupa settlement area (Northern Karelia)

The complex lithological, geochemical, geochronological, and micropaleontological (diatoms, spores, pollen) investigations of stratified bottom sediments that constitute facies-variable sedimentary sequences in a small isolated lake located near the upper limit of the sea on the White Sea coast made it possible to define lithostratigraphic units (LSU) forming the complete sedimentary succession in deep parts of isolated basins. It is shown that stratigraphy of heterogeneous sequences is determined by two regional transgressive–regressive cycles in relative sea level fluctuations: alternating late Glacial and Holocene transgressions and regressions. The lower part of a clastogenic clayey–sandy–silty sequence successively composed of freshwater (LSU 1) and brackish-water (LSU 2) sediments of the ice-marginal basins and marine postglacial facies (LSU 3) was formed during the late Glacial glacioeustatic marine transgression. Its upper part formed in different isolated basins at different stages of the Holocene is represented depending on its altimetric position on the coastal slope by costal marine sediments (LSU 4) and facies of the partly isolated inlet (LSU 5). The organogenic sapropelic sequence, which overlies sediments of the marine basin and partly isolated bay, corresponds to lithostratigraphic units represented by Holocene sediments accumulated in the meromictic lake (LSU 6), onshore freshwater basin (LSU 7), and freshwater basin with elevated water mineralization (LSU 8) deposited during maximum development of Holocene transgression and lacustrine sediments (LSU 9) formed in coastal environments during terminal phases of the Holocene. The defined lithostratigraphic units differ from each other in lithological, micropaleontological, and geochemical features reflected in structural and textural properties of their sediments, their composition, inclusions, and composition of paleophytocoenoses and diatom assemblages.     

Alkane and PAH biomarkers as tracers of terrigenous organic carbon in Arctic Ocean sediments

We present the first sedimentary biomarker study encompassing the entire Arctic Ocean. A large data set of organic markers for terrigenous, petroleum and combustion inputs [alkanes, hopanes and steranes, parent and alkyl polycyclic aromatic hydrocarbons (PAHs)] is examined for patterns in space and time using principal components analysis (PCA) and partial least squares (PLS). Biomarker patterns reveal the central Arctic Ocean basin sediments to be compositionally distinct from those of the Mackenzie River/Beaufort Sea and Barents Sea, but similar to those of the Laptev Sea. PAH distributions reflected in PAH ratios and PCA projections demonstrate that Arctic Ocean sediment is dominated by natural inputs to the extent that anthropogenic combustion PAHs are not significant. We find only modest changes between the glacial and post-glacial sediments for atmospherically transported hydrocarbon biomarkers, while particle associated biomarkers were captured strongly at basin edges during the glacial period, and much more evenly transported across basins during the post-glacial period. The orders of magnitude decreases in particle associated petrogenic alkanes and PAHs in central basins during glacial times, coupled with the uniformity of most petrogenic biomarker parameters for most basin and shelf locations, reflect a massive reduction in ice transport that makes the margins the most likely source of petrogenic material for the Pleistocene/Holocene central Arctic basins. The proximity of large coal deposits of various maturity levels along the Lena River, the overlap in PAH and biomarker composition of the Laptev Sea and surficial sediments from the central Arctic Ocean and the location of the Laptev Sea at the origin of the main Transpolar Drift all point to eroded coals from the Lena River/Laptev Sea as the likely source of petrogenic hydrocarbons to the central Arctic Ocean. The ubiquitous presence of allochthonous coal in Arctic Ocean surface sediments provides a major constraint on the use of petrogenic biomarkers to infer the presence of subsurface petroleum reserves.     

Geochemistry of surface sediments in tsunami-affected Sri Lankan lagoons regarding environmental implications

The December 26, 2004 Indian Ocean tsunami was one of the largest in human history, devastating the coastal wetlands of surrounding countries. This study present the chemical analyses of tsunamigenic and pre-tsunami sediments from Hikkaduwa and Hambantota lagoons in southern Sri Lanka, to assess their geochemical composition, their source, and subsequent environmental impacts. Principal component analysis of the tsunami sediments shows that 42% of the total variance is accounted for calcium oxide and Sr. That is, the tsunami deposits are rich in biogenic phases derived from shallow marine sediments. High organic matter contents of the tsunami sediments of up to 80 wt% also support this interpretation. The association of chlorine (<9.4 wt%), brome (<170?mg/kg), arsenic (<17?mg/kg), iron (III) oxide (<12.9 wt%) and sulfur (<7.6 wt%) accounts for 33% of the variance, reflecting higher salinity. This further suggests that the sediments were mainly derived from a marine environment, rather than from non-marine sands and/or soils. Immobile element contents and relations (thorium, scandium and zirconium) suggest that the tsunami sediment source was mostly felsic in composition, with some mafic component, and mixed with predominantly shallow marine shelf or slope sediments. Additional compositional variations in the tsunami sediments in both lagoons may be associated with variations of wave strength along the coast and by the morphology of the continental shelf. Lower elemental abundances in Hambantota lagoon sediments compared to Hikkaduwa equivalents may thus reflect a greater non-marine component in the former, and greater shelf sediment component in the latter.