Guidelines for assessing the petroleum potential of coaly source rocks using Rock-Eval pyrolysis

Coaly source rocks are sufficiently different from marine and lacustrine source rocks in their organic matter characteristics to warrant separate guidelines for their assessment using Rock-Eval pyrolysis. The rank threshold for oil generation is indicated by the increase in BI (S1/TOC) at Rank(S_r)9–10 (T_max 420–430 °C, R_o 0.55–0.6%), and the threshold for oil expulsion is indicated by the peak in QI ([S1+S2]/TOC) at Rank(S_r)11–12.5 (T_max 430–440 °C, R_o 0.65–0.85%). The pronounced rank-related increase in HI (S2/TOC) prior to oil expulsion renders the use of immature samples inappropriate for source rock characterisation. A more realistic indication of the petroleum generative potential and oil expulsion efficiency of coaly source rocks can be gained from samples near the onset of expulsion. Alternatively, effective HI′ values (i.e. HIs near the onset of expulsion) can be estimated by translating the measured HIs of immature samples along the maturation pathway defined by the New Zealand (or other defined) Coal Band. Coaly source rocks comprise a continuum of coaly lithologies, including coals, shaly coals and coaly mudstones. Determination of the total genetic potential of coaly source rock sequences is best made using lithology-based samples near the onset of expulsion.     

Constraining models of the tectonic setting of the giant Olympic Dam iron oxide–copper–gold deposit, South Australia, using deep seismic reflection data

In the Gawler Craton, the completeness of cover concealing the crystalline basement in the region of the giant Olympic Dam Cu–Au deposit has impeded any sufficient understanding of the crustal architecture and tectonic setting of its IOCG mineral-system. To circumvent this problem, deep seismic reflection data were recently acquired from  250 line-km of two intersecting traverses, centered on the Olympic Dam deposit. The data were recorded to 18 s TWT ( 55 km). The crust consists of Neoproterozoic cover, in places more than 5 km thick, over crystalline basement with the Moho at depths of 13–14 s TWT ( 40–42 km). The Olympic Dam deposit lies on the boundary between two distinct pieces of crust, one interpreted as the Archean–Paleoproterozoic core to the craton, the other as a Meso–Neoproterozoic mobile belt. The host to the deposit, a member of the  1590 Ma Hiltaba Suite of granites, is situated above a zone of reduced impedance contrast in the lower crust, which we interpret to be source-region for its  1000 °C magma. The crystalline basement is dominated by thrusts. This contrasts with widely held models for the tectonic setting of Olympic Dam, which predict extension associated with heat from the mantle producing the high temperatures required to generate the Hiltaba Suite granites implicated in mineralization. We use the seismic data to test four hypotheses for this heat-source: mantle underplating, a mantle-plume, lithospheric extension, and radioactive heating in the lower crust. We reject the first three hypotheses. The data cannot be used to reject or confirm the fourth hypothesis.     

Structural and stratigraphical constraints on the kinematics history of the Southern Tan–Lu Fault Zone during the Mesozoic Anhui Province, China

The Tan–Lu Fault Zone (TLFZ) extends in a NNE–SSW direction for more than 2000 km in Eastern China. It has been considered either as a major sinistral strike-slip fault, as a suture zone or as a normal fault. We have conducted a structural analysis of the southern segment of this fault zone (STLFZ) in the Anhui Province. The ages (Triassic to Palaeocene) of the formations affected by the faults have been re-appraised taking into account recent stratigraphical studies to better constraint the ages of the successive stages of the kinematics of the STLFZ. Subsequently, the kinematics of the faults is presented in terms of strain/stress fields by inversion of the striated fault set data. Finally, the data are discussed in the light of the results obtained by previous workers.We propose the following history of the STLFZ kinematics during the Mesozoic. At the time of collision, a  NNE orientated Tan–Lu margin probably connected two margins located north of the Dabie and Sulu collision belts. During the Middle–Late Triassic, the SCB has been obliquely subducted below the NCB along this margin which has acted as a compressional transfer zone between the Dabie and Sulu continental subduction zones. The STLFZ has been initiated during the Early Jurassic and has acted as a sinistral transform fault during the Jurassic, following which the NCB/SCB collision stopped. A  NW-trending extension related to metamorphic domes was active during the basal Early Cretaceous ( 135–130 Ma); it has been followed by a NW–SE compression and a NE–SW tension during the middle–late Early Cretaceous ( 127 to  105 Ma, possibly  95 Ma); at that time the TLFZ was a sinistral transcurrent fault within the eastern part of the Asian continent. During the Late Cretaceous–Palaeocene, the STLFZ was a normal fault zone under a WNW–ESE tension.     

Taconic Orogeny in Pennsylvania: A 15 –20 m.y. Apennine-style Ordovician event viewed from its Martic hinterland

In Pennsylvania, the Taconic Orogeny lasted from 461 to 443 Ma as Cambro-Ordovician slope deposits were deformed into mountains edging the Laurentian craton at the same time that materials from an adjacent deep-water basin were being transported 50 –70 km across a carbonate platform into foreland basins. This paper focuses on shelf-edge hinterland features, mostly the Martic Zone as a folded, stack of imbricate thrust sheets of slope materials that corresponds to Vermont's Taconic Mountains and Southern Quebec's zone of Taconic allochthons. Work of the last century is summarized, corrected, and combined with a new 450 Ma radiometric date and fluid inclusion data from the Pequea Mine within the Martic Zone. These and abundant new graptolite and conodont dates in the foreland paint a revised Pennsylvania picture differing from the northern Taconic areas. Differences are: (1) transport of very large allochthonous masses of deep-water material, the Dauphin Formation, far across the carbonate platform, and (2) deformation migrating progressively across that platform during a 15 –20 m.y. period, incorporating it and its foreland cover into alpine-scale, recumbent folds and thrusts. The scenario has many analogies to Italy's modern Apennine Mountains minus the Latian volcanics.     

Brittle–ductile–brittle deformation during cooling of tonalite (Adamello, Southern Italian Alps)

Late- to post-magmatic deformation in slightly diachronous contiguous intrusions of the north-western Adamello batholith (Southern Alps, Italy) is recorded as, from oldest to youngest: (i) joints, (ii) solid-state ductile shear zones, (iii) faults associated with epidote-K-feldspar veins and (iv) zeolite veins and faults. Structures (ii) to (iv) are localized on the pervasive precursory network of joints (i), which developed during the earliest stages of pluton cooling. High temperature ( 500 °C), ductile overprinting of joints produced lineations, defined by aligned biotite and hornblende, on the joint surfaces and highly localized mylonites. The main phase of faulting, producing cataclasites and pseudotachylytes, occurred at  250 °C and was associated with extensive fluid infiltration. Cataclasites and pseudotachylytes are clustered along different E–W-striking dextral strike-slip fault zones correlated with the activity of the Tonale fault, a major tectonic structure that bounds the Adamello batholith to the north. Ductile deformation and cataclastic/veining episodes occurred at P = 0.25–0.3 GPa during rapid cooling of the batholith to the ambient temperatures ( 250 °C) that preceded the exhumation of the batholith. Timing of the sequence of deformation can be constrained by ³⁹Ar–⁴⁰Ar ages of  30 Ma on pseudotachylytes and various existing mineral ages. In the whole composite Adamello batholith, multiple magma pulses were intruded over the time span 42–30 Ma and each intrusive body shows the same ductile-to-brittle structural sequence localized on the early joint sets. This deformation sequence of the Adamello might be typical of intrusions undergoing cooling at depths close to the brittle–ductile transition.     

Probing fault zone heterogeneity on the Nojima fault: Constraints from zircon fission-track analysis of borehole samples

Fission-track (FT) thermochronologic analysis was performed on zircon separates from rocks in and around the Nojima fault, which was activated during the 1995 Kobe earthquake. Samples were collected from the University Group 500 m (UG-500) borehole and nearby outcrops. FT lengths in zircons from localities > 25 m away from the fault plane as well as one 0.1 m away from the fault in the footwall are characterized by concordant mean values of  10–11 μm and unimodal distributions with negative skewness, which showed no signs of appreciable reduction in FT length. In contrast, those adjacent (< 3 m) to the fault at depths on the hanging wall side showed significantly reduced mean track lengths of  6–8 μm and distributions having a peak around 6–7 μm with rather positive skewness. The former pattern is interpreted to reflect cooling through the zircon partial annealing zone (ZPAZ), without later, partial thermal overprints. The latter indicates substantial track shortening due probably to secondary heating by a thermal event(s) that locally perturbed the geothermal structure. Modeled zircon FT length and age data of partially annealed samples from the UG-500 borehole revealed a cooling episode in the ZPAZ that started at  4 Ma within  3 m from the fault plane, whereas those from the Geological Survey of Japan 750 m borehole record cooling started at  31–38 Ma within  25 m from the fault. On the basis of one-dimensional heat conduction modeling as well as the consistency between the degree of FT annealing and the degree of deformation/alteration of borehole rocks, these cooling ages in both boreholes are interpreted as consequences of ancient thermal overprints by heat transfer or dispersion via fluids in the fault zone. Together with the zircon FT data of a pseudotachylyte layer recently analyzed, it is suggested that the present Nojima fault system was reactivated in the Middle Quaternary from an ancient fault initiated at  56 Ma at mid-crustal depths. Also shown is a temporal/spatial variation in terms of the thermal anomalies recorded in the fault rocks, implying heterogeneity of hot fluid flows in the fault zone.     

Holocene activity of the Scilla Fault, Southern Calabria: Insights from coastal morphological and structural investigations

Integration of on-land and offshore geomorphological and structural investigations coupled to extensive radiometric dating of co-seismically uplifted Holocene beaches allows characterization of the geometry, kinematics and seismotectonics of the Scilla Fault, which borders the eastern side of the Messina Strait in Calabria, Southern Italy. This region has been struck by destructive historical earthquakes, but knowledge of geologically-based source parameters for active faults is relatively poor, particularly for those running mostly offshore, as the Scilla Fault does. The  30 km-long normal fault may be divided into three segments of  10 km individual length, with the central and southern segments split in at least two strands. The central and northern segments are submerged, and in this area marine geophysical data indicate a youthful morphology and locally evidence for active faulting. The on-land strand of the western segment displaces marine terraces of the last interglacial (124 to 83 ka), but seismic reflection profiles suggest a full Quaternary activity. Structural data collected on bedrock faults exposed along the on-land segment provide evidence for normal slip and  NW-SE extension, which is consistent with focal mechanisms of large earthquakes and GPS velocity fields in the region. Detailed mapping of raised Holocene marine deposits exposed at the coastline straddling of the northern and central segments supplies evidence for two co-seismic displacements at  1.9 and  3.5 ka, and a possible previous event at  5 ka. Co-seismic displacements show a consistent site value and pattern of along-strike variation, suggestive of characteristic-type behaviour for the fault. The  1.5–2.0 m average co-seismic slips during these events document M_e  6.9–7.0 earthquakes with  1.6–1.7 ka recurrence time. Because hanging-wall subsidence cannot be included into slip magnitude computation, these slips reflect footwall uplift, and represent minimum average estimates. The palaeoseismological record based on the palaeo-shorelines suggests that the last rupture on the Scilla Fault during the February 6, 1783 M_w = 5.9–6.3 earthquake was at the expected time but it may have not entirely released the loaded stress since the last great event at  1.9 ka. Comparison of the estimated co-seismic extension rate based on the Holocene shoreline record with available GPS velocities indicates that the Scilla Fault accounts for at least  15–20% of the contemporary geodetic extension across the Messina Strait.     

Timing of thermal stabilization of the Zimbabwe Craton deduced from high-precision Rb–Sr chronology, Great Dyke

Dating low temperature events such as magmatic cooling or (hydro-)thermal surges in Archean and Proterozoic terranes is crucial in defining cratonal thermal stabilization after episodic continental growth during the Archean and Early Proterozoic. Rubidium–Sr chronology is potentially a powerful tool in this regard because of its low closure temperature, i.e., <400 °C in most minerals, but has until now been hampered by its relatively low precision compared to high-temperature chronometers. Consequently, Rb–Sr age investigations have so far failed to provide high-precision age constraints on the cooling of rocks older than 2 Ga. Here, it is demonstrated that internal Rb–Sr microchrons can yield important, high-precision age constraints on the cooling history of Archean intrusions. After careful mineral selection and chemical treatment, a Rb–Sr age of 2543.0 ± 4.4 Ma was obtained from the Archean Great Dyke, Zimbabwe Craton, in contrast to the intrusion age of 2575.8 ± 1 Ma, yielding an ambient average cooling of 5 ± 2 °C/Ma. The non-disturbed magmatic Rb–Sr cooling age of the Great Dyke marks the final stage of Zimbabwe craton stabilization and that the greater craton area did not experience any intensive later reheating event during metamorphic or tectonic events.     

Cretaceous and Cenozoic cooling history across the ultrahigh pressure Tongbai–Dabie belt, central China, from apatite fission-track thermochronology

The crystalline terrane of the Tongbai–Dabie region, central China, comprising the Earth's largest ultrahigh-pressure (UHP) exposure was formed during Triassic collision between the Sino–Korean and Yangtze cratons. New apatite fission-track (AFT) data presented here from the UHP terrane, extends over a significantly greater area than reported in previous studies, and includes the (eastern) Dabie, the Hong'an (northwestern Dabie) and Tongbai regions. The new data yield ages ranging from 44 ± 3 to 142 ± 36 Ma and mean track lengths between 10 and 14.4 μm. Thermal history models based on the AFT data taken together with published ⁴⁰Ar/³⁹Ar, K–Ar, apatite and zircon (U–Th)/He and U–Pb data, exhibit a three-stage cooling pattern that is similar across the study region, commencing with an Early Cretaceous rapid cooling event, followed by a period of relative thermal stability during which rocks remained at temperatures within the AFT partial annealing zone (60–110 °C) and ending with a possible renewed phase of accelerated cooling during Pliocene to Recent time. The first cooling phase followed large-scale transtensional deformation between 140 and 110 Ma and is related to Early Cretaceous eastward tectonic escape and Pacific back arc extension. Between this phase and the subsequent slow cooling phase, a transition period from 120 to 80 Ma (to 70 to 45 Ma along the Tan–Lu fault) was characterised by a relatively low cooling rate (3–5 °C/Ma). This transition is likely related to a tectonic response associated with the mid-Cretaceous subduction of the Izanagi–Pacific plate as well as lithospheric extension and thinning in eastern Asia. The present regional AFT age pattern is therefore basically controlled by the Early Cretaceous rapid cooling event, but finally shaped through active Cenozoic faulting. Following the transition phase the subsequent slow cooling phase pattern implies a net reduction in horizontal compressional stress corresponding to increased extension rates along the continental margin due to the decrease in plate convergence. Modelling of the AFT data suggests a possible Pliocene–Recent cooling episode, which may be supported by increased rates of sedimentation observed in adjacent basins. This cooling phase may be interpreted as a response to the far-field effects of the frontal India–Eurasia collision to the west. Approximate estimates suggest that the total amount of post 120 Ma denudation across the UHP orogen ranged from 2.4 to 13.2 km for different tectonic blocks and ranged from 0.8 to 9.7 km during the Cretaceous to between 1.7 and 3.8 km during the Cenozoic.     

SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt

There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas.     

Changes in Zn speciation during soil formation from Zn-rich limestones

In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH₄-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.     

Archean greenstone-tonalite duality: Thermochemical mantle convection models or plate tectonics in the early Earth global dynamics?

Mantle convection and plate tectonics are one system, because oceanic plates are cold upper thermal boundary layers of the convection cells. As a corollary, Phanerozoic-style of plate tectonics or more likely a different version of it (i.e. a larger number of slowly moving plates, or similar number of faster plates) is expected to have operated in the hotter, vigorously convecting early Earth. Despite the recent advances in understanding the origin of Archean greenstone–granitoid terranes, the question regarding the operation of plate tectonics in the early Earth remains still controversial. Numerical model outputs for the Archean Earth range from predominantly shallow to flat subduction between 4.0 and 2.5 Ga and well-established steep subduction since 2.5 Ga [Abbott, D., Drury, R., Smith, W.H.F., 1994. Flat to steep transition in subduction style. Geology 22, 937–940], to no plate tectonics but rather foundering of 1000 km sectors of basaltic crust, then “resurfaced” by upper asthenospheric mantle basaltic melts that generate the observed duality of basalts and tonalities [van Thienen, P., van den Berg, A.P., Vlaar, N.J., 2004a. Production and recycling of oceanic crust in the early earth. Tectonophysics 386, 41–65; van Thienen, P., Van den Berg, A.P., Vlaar, N.J., 2004b. On the formation of continental silicic melts in thermochemical mantle convection models: implications for early Earth. Tectonophysics 394, 111–124]. These model outputs can be tested against the geological record. Greenstone belt volcanics are composites of komatiite–basalt plateau sequences erupted from deep mantle plumes and bimodal basalt–dacite sequences having the geochemical signatures of convergent margins; i.e. horizontally imbricated plateau and island arc crust. Greenstone belts from 3.8 to 2.5 Ga include volcanic types reported from Cenozoic convergent margins including: boninites; arc picrites; and the association of adakites–Mg andesites- and Nb-enriched basalts.Archean cratons were intruded by voluminous norites from the Neoarchean through Proterozoic; norites are accounted for by melting of subduction metasomatized Archean continental lithospheric mantle (CLM). Deep CLM defines Archean cratons; it extends to  350 km, includes the diamond facies, and xenoliths signify a composition of the buoyant, refractory, residue of plume melting, a natural consequence of imbricated plateau-arc crust. Voluminous tonalites of Archean greenstone–granitoid terranes show a secular trend of increasing Mg#, Cr, Ni consistent with slab melts hybridizing with thicker mantle wedge as subduction angle steepens. Strike-slip faults of 1000 km scale; diachronous accretion of distinct tectonostratigraphic terranes; and broad Cordilleran-type orogens featuring multiple sutures, and oceanward migration of arcs, in the Archean Superior and Yilgarn cratons, are in common with the Altaid and Phanerozoic Cordilleran orogens. There is increasing geological evidence of the supercontinent cycle operating back to  2.7 Ga: Kenorland or Ur  2.7–2.4 Ga; Columbia  1.6–1.4 Ga; Rodinia  1100–750 Ma; and Pangea  230 Ma. High-resolution seismic reflection profiling of Archean terranes reveals a prevalence of low angle structures, and evidence for paleo-subduction zones. Collectively, the geological–geochemical–seismic records endorse the operation of plate tectonics since the early Archean.     

Cretaceous–Tertiary geology of the Gangdese Arc in the Linzhou area, southern Tibet

Knowledge of the Cretaceous–Tertiary history of upper crustal shortening and magmatism in Tibet is fundamental to placing constraints on when and how the Tibetan plateau formed. In the Lhasa terrane of southern Tibet, the widely exposed angular unconformity beneath uppermost Cretaceous–lower Tertiary volcanic-bearing strata of the Linzizong Formation provides an excellent geologic and time marker to distinguish between deformation that occurred before vs. during the Indo-Asian collision. In the Linzhou area, located  30 km north of the city of Lhasa, a > 3-km-thick section of the Linzizong Formation lies unconformably on Cretaceous and older rocks that were shortened by both northward- and southward-verging structures during the Late Cretaceous. The Linzizong Formation dips northward in the footwall of a north-dipping thrust system that involves Triassic–Jurassic strata and a granite intrusion in the hanging wall. U–Pb zircon geochronologic studies show that the Linzizong Formation ranges in age from 69 Ma to at least 47 Ma and that the hanging wall granite intrusion crystallized at  52 Ma, coeval with dike emplacement into footwall Cretaceous strata. ⁴⁰Ar/³⁹Ar thermochronologic studies suggest slow cooling of the granite between 49 and 42 Ma, followed by an episode of accelerated cooling to upper crustal levels beginning at  42 Ma. The onset of rapid cooling was coeval with the cessation of voluminous arc magmatism in southern Tibet and is interpreted be a consequence of either (1) Tertiary thrusting in this region or (2) regional rock uplift and erosion following removal of overthickened Gangdese arc lower crust and upper mantle or break-off of the Neo-Tethyan oceanic slab.     

Age constraints on the formation and emplacement of Neoproterozoic ophiolites along the Allaqi–Heiani Suture, South Eastern Desert of Egypt

Ophiolites are key components of the Neoproterozoic Arabian–Nubian Shield (ANS). Understanding when they formed and were emplaced is crucial for understanding the evolution of the ANS because their ages tell when seafloor spreading and terrane accretion occurred. The Yanbu–Onib–Sol Hamed–Gerf–Allaqi–Heiani (YOSHGAH) suture and ophiolite belt can be traced  600 km across the Nubian and Arabian shields. We report five new SHRIMP U–Pb zircon ages from igneous rocks along the Allaqi segment of the YOSHGAH suture in southernmost Egypt and use these data in conjunction with other age constraints to evaluate YOSHGAH suture evolution. Ophiolitic layered gabbro gave a concordia age of 730 ± 6 Ma, and a metadacite from overlying arc-type metavolcanic rocks yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 733 ± 7 Ma, indicating ophiolite formation at  730 Ma. Ophiolite emplacement is also constrained by intrusive bodies: a gabbro yielded a concordia age of 697 ± 5 Ma, and a quartz-diorite yielded a concordia age of 709 ± 4 Ma. Cessation of deformation is constrained by syn- to post-tectonic granite with a concordia age of 629 ± 5 Ma. These new data, combined with published zircon ages for ophiolites and stitching plutons from the YOSHGAH suture zone, suggest a 2-stage evolution for the YOSHGAH ophiolite belt ( 810–780 Ma and  730–750 Ma) and indicate that accretion between the Gabgaba–Gebeit–Hijaz terranes to the south and the SE Desert–Midyan terranes to the north occurred as early as 730 Ma and no later than 709 ± 4 Ma.     

Neoproterozoic adakitic plutons in the northern margin of the Yangtze Block, China: Partial melting of a thickened lower crust and implications for secular crustal evolution

Numerous Neoproterozoic felsic and mafic–ultramafic intrusions occur in the Hannan region at the northern margin of the Yangtze Block. Among these, the Wudumen and Erliba plutons consist of granodiorites and have SHRIMP zircon U–Pb ages of  735 Ma. The rocks have high K₂O (0.8–3.6 wt.%) and Na₂O (4.4–6.4 wt.%) and low MgO (0.4–1.7 wt.%). They also have high Sr/Y (32–209) and (La/Yb)_n ratios (4.4–38.6). Their εNd values range from − 0.41 to − 0.92 and zircon initial ¹⁷⁶Hf/¹⁷⁷Hf ratios from 0.282353 to 0.282581. These geochemical features are similar to those of adakitic rocks produced by partial melting of a thickened lower crust. Our new analytical results, combined with the occurrence of voluminous arc-related mafic–ultramafic intrusions emplaced before 740 Ma, lead us to propose that the crustal evolution in the northern margin of the Yangtze Block during Neoproterozoic involved: (1) rapid crustal growth and thickening by underplating of mafic magmas from the mantle which was modified by materials coming from the subducting oceanic slab from  1.0 to  0.74 Ga, and (2) partial melting of the thickened lower crust due to a thermal anomaly induced by upwelling of asthenosphere through an oceanic slab window, producing the  735 Ma adakitic Wudumen and Erliba plutons. Our model suggests that the crustal thickness was more than 50 km at the northern margin of the Yangtze Block at  735 Ma, and rule out the possibility of a mantle plume impact causing the > 735 Ma magmatism in the region.     

The thermal evolution of Corsica as recorded by zircon fission-tracks

New zircon fission-track (ZFT) ages from Corsica record multiple thermal events that can be tied to the structural evolution of the western Mediterranean region. The Corsican zircons have a wide scatter of ZFT grain ages (243–14 Ma), which together define several age domains. Western Corsica consists largely of stable Hercynian basement characterized by ZFT ages in the range 161–114 Ma. We interpret these ages (Late Jurassic–Early Cretaceous) as the product of a long-lived Tethyan thermal event related to continental rifting and subsequent drifting during the separation of the European and African plates and the formation of the Liguro–Piemontese ocean basin. In contrast to Hercynian Corsica, Alpine Corsica (northeast Corsica) experienced widespread deformation and metamorphism in Late Cretaceous(?)–Tertiary time. Dated samples from Alpine Corsica range in age from 112 to 19 Ma and all are reset or partially reset by one or more Alpine thermal events. The youngest ZFT grain ages are from the northernmost Alpine Corsica and define an age population at  24 Ma that indicates cooling after Tertiary thermal events associated with the Alpine metamorphism and the opening of the Liguro–Provençal basin. A less well-defined ZFT age population at  72 Ma is present in both Alpine Corsica and Hercynian basement rocks. The thermal history of these rocks is not clear. One interpretation is that the ZFT population at  72 Ma reflects resetting during a Late Cretaceous event broadly synchronous with the early Alpine metamorphism. Another interpretation is that this peak is related to variable fission-track annealing and partial resetting during the Tertiary Alpine metamorphic event across central to north-eastern Corsica. This partial age resetting supports the presence of a fossil ZFT partial annealing zone and limits the peak temperature in this area below 300 °C, for both the affected pre-Alpine and Alpine units.     

Kinematics of the Iberia–Maghreb plate contact from seismic moment tensors and GPS observations

The Iberian Peninsula and the Maghreb experience moderate earthquake activity and oblique,  NW–SE convergence between Africa and Eurasia at a rate of  5 mm/yr. Coeval extension in the Alboran Basin and a N35°E trending band of active, left-lateral shear deformation in the Alboran–Betic region are not straightforward to understand in the context of regional shortening, and evidence complexity of deformation at the plate contact. We estimate 86 seismic moment tensors (M_W 3.3 to 6.9) from time domain inversion of near-regional waveforms in an intermediate period band. Those and previous moment tensors are used to describe regional faulting style and calculate average stress tensors. The solutions associated to the Trans-Alboran shear zone show predominantly strike-slip faulting, and indicate a clockwise rotation of the largest principal stress orientation compared to the regional convergence direction (σ₁ at N350°E). At the N-Algerian and SW-Iberian margins, reverse faulting solutions dominate, corresponding to N350°E and N310°E compression, respectively. Over most of the Betic range and intraplate Iberia, we observe predominately normal faulting, and WSW–ENE extension (σ₃ at N240°E). From GPS observations we estimate that more than 3 mm/yr of African (Nubian)–Eurasian plate convergence are currently accommodated at the N-Algerian margin,  2 mm/yr in the Moroccan Atlas, and  2 mm/yr at the SW-Iberian margin. 2 mm/yr is a reasonable estimate for convergence within the Alboran region, while Alboran extension can be quantified as  2.5 mm/yr along the stretching direction (N240°E). Superposition of both motions explains the observed left-lateral transtensional regime in the Trans-Alboran shear zone. Two potential driving mechanisms of differential motion of the Alboran–Betic–Gibraltar domain may coexist in the region: a secondary stress source other than plate convergence, related to regional-scale dynamic processes in the upper mantle of the Alboran region, as well as drag from the continental-scale motion of the Nubian plate along the southern limit of the region. In the Atlantic Ocean, the  3.5 mm/yr, westward motion of the Gibraltar Arc relative to intraplate Iberia can be accommodated at the transpressive SW-Iberian margin, while available GPS observations do not support an active subduction process in this area.     

Insights into Wasatch fault vertical slip rates using the age of sediments in Timpanogos Cave, Utah

Timpanogos Cave, located near the Wasatch fault, is about 357 m above the American Fork River. Fluvial cave sediments and an interbedded carbonate flowstone yield a paleomagnetic and U–Th depositional age of 350 to 780 ka. Fault vertical slip rates, inferred from calculated river downcutting rates, range between 1.02 and 0.46 mm yr^− 1. These slip rates are in the range of the 0–12 Ma Wasatch Range exhumation rate ( 0.5–0.7 mm yr^− 1), suggesting that the long-term vertical slip rate remained stable through mid-Pleistocene time. However, the late Pleistocene (0–250 ka) decelerated slip rate ( 0.2–0.3 mm yr^− 1) and the accelerated Holocene slip rate ( 1.2 mm yr^− 1) are consistent with episodic fault activity. Assuming that the late Pleistocene vertical slip rate represents an episodic slowing of fault movement and the long-term (0–12 Ma) average vertical slip rate, including the late Pleistocene and Holocene, should be  0.6 mm yr^− 1, there is a net late Pleistocene vertical slip deficit of  50–75 m. The Holocene and late Pleistocene slip rates may be typical for episodes of accelerated and slowed fault movement, respectively. The calculated late Pleistocene slip deficit may mean that the current accelerated Wasatch fault slip rate will extend well into the future.     

Mesozoic plutons of the Yidun Arc, SW China: U/Pb geochronology and Hf isotopic signature

The Yidun Arc is a Triassic volcanic arc located between the Songpan Garzê Fold Belt and the Qiangtang Block, southwest China. To constrain the age of a number of the major granitic plutons from the Yidun Arc, laser ablation ICP-MS U/Pb analysis of zircon was conducted. Hafnium isotope data was also acquired through laser-ablation multicollector ICPMS analysis of zircon, with the aim of gaining insight into the age and nature of the source region of the plutons. Three age groups have been identified from seven granite samples: Early–Middle Triassic ( 245 to 229 Ma), Late Triassic ( 219 to 216 Ma) and Cretaceous ( 105 to 95 Ma). Hafnium analysis shows the Triassic granites to have negative and variable ε_Hf values and Mesoproterozoic ( 1.6 Ga) depleted-mantle model ages, which is interpreted to reflect derivation from an isotopically heterogeneous, largely crustal source. The Cretaceous granite shows higher and less variable ε_Hf values and slightly younger model ages ( 1.3 Ga), and is interpreted to be derived from melting of a more homogeneous crustal source. A depleted-mantle model age of  1.5 Ga is calculated from the pooled Triassic and Cretaceous samples. The source region for these magmas may be tentatively correlated with Mesoproterozoic material of the Yangtze Craton, which has been suggested to underlie the Yidun Arc; however, further work is necessary to demonstrate this suggestion.     

Kinematic variations across Eastern Cordillera at 24°S (Central Andes): Tectonic and magmatic implications

The Eastern Cordillera (Central Andes,  24°S) consists of a basement-involved thrust system, resulting from Miocene–Quaternary eastward migrating compression, separating the Puna plateau from the Santa Barbara System foreland. The inferred Tertiary strains arising from shortening in the Eastern Cordillera and Santa Barbara System are similar, higher than in the Puna. Slip data collected on the major  N–S trending faults of Eastern Cordillera show a westward progression from dip-slip (contraction) to dextral and sinistral motions. This, consistently with established tectonic models, may result from partitioning due to the oblique Mio-Quaternary underthrusting of the Brazilian Shield north of 24°S. This strain partitioning has three main implications. (1) As the dextral and sinistral shear in the Eastern Cordillera are  62% and 29% of the compressive strain respectively, the Eastern Cordillera results more strained than Santa Barbara System foreland, contrary to previous estimates. (2) The partitioning in the Eastern Cordillera may find its counterpart in that to the west of the Central Andes, giving a possible structural symmetry to the Central Andes. (3) The easternmost N–S strike-slip structures in the Eastern Cordillera coincide with the easternmost Mio-Pliocene magmatic centres in the Central Andes, at  24°S. Provided that, further to the east, the crust is partially molten, the absence of magmatic centres may be explained by the presence of pure compressive structures in this portion of the Eastern Cordillera.