Quantifying annual groundwater recharge and storage in the central Sierra Nevada using naturally occurring 35S

Identifying aquifer vulnerability to climate change is of vital importance in the Sierra Nevada and other snow‐dominated basins where groundwater systems are essential to water supply and ecosystem health. Quantifying the component of new (current year's) snowmelt in groundwater and surface water is useful in evaluating aquifer vulnerability because significant annual recharge may indicate that streamflow will respond rapidly to annual variability in precipitation, followed by more gradual decreases in recharge as recharge declines over decades. Hydrologic models and field‐based studies have indicated that young (<1 year) water is an important component of streamflow. The goal of this study was to utilize the short‐lived, naturally occurring cosmogenic isotope sulfur‐35 (³⁵S) to quantify new snowmelt contribution to groundwater and surface waters in Sagehen Creek Basin (SCB) and Martis Valley Groundwater Basin (MVGB) located within the Tertiary volcanics of the central Sierra Nevada, CA. Activities of ³⁵S were measured in dissolved sulfate (³⁵SO₄^2?) in SCB and MVGB snowpack, groundwater, springs, and streamflow. The percent of new snowmelt (PNS) in SCB streamflow ranged from 0.2 ± 6.6% during baseflow conditions to 14.0 ± 3.4% during high‐flow periods of snowmelt. Similar to SCB, the PNS in MVGB groundwater and streamflow was typically <30% with the largest fractions occurring in late spring or early summer following peak streamflow. The consistently low PNS suggests that a significant fraction of annual snowmelt in SCB and MVGB recharges groundwater, and groundwater contributions to streamflow in these systems have the potential to mitigate climate change impacts on runoff.     

Isotopic time series partitioning of streamflow components under regional climate change in the Urumqi River,northwest China

ABSTRACT

We investigated the isotopic composition of the Urumqi River and documented seasonal variability attributable to the mixing of various flow sources. Next, we applied these isotopic signals to partition the sources and studied their temporal variability in summer. The isotope hydrology separation results indicated that groundwater is the dominant streamflow source (approximately 62.7%) in the Urumqi River. Precipitation is an important source for the Urumqi River; approximately 19.1–20.7% of the runoff came from precipitation during summer and early autumn. In summer, approximately 21.1% of the runoff is derived from glacial meltwater. In summer, with the increasing distance to the glacier front, groundwater accounts for a larger and larger percentage of the river water, and the contributions of precipitation and glacial meltwater gradually diminish. Throughout 2012, the proportions of precipitation and glacial meltwater in the streamflow were 17.6% and 14.7%, respectively, and only 5% of the streamflow was derived from snowmelt.

Editor Z. W. Kundzewicz; Associate editor not assigned     

Paired‐basin comparison of hydrological response in harvested and undisturbed hardwood forests during snowmelt in central Ontario: I. Streamflow,groundwater and flowpath behaviour

Impacts of forest harvesting on groundwater properties, water flowpaths and streamflow response were examined 4 years after the harvest using a paired‐basin approach during the 2001 snowmelt in a northern hardwood landscape in central Ontario. The ability of two metrics of basin topography (Beven and Kirkby's ln(a/tan β) topographic index (TI) and distance to stream channel) to explain intra‐basin variations in groundwater dynamics was also evaluated. Significant relationships between TI and depth to potentiometric surface for shallow groundwater emerged, although the occurrence of these relationships during the melt differed between harvested and control basins, possibly as a result of interbasin differences in upslope area contributing to piezometers used to monitor groundwater behaviour. Transmissivity feedback (rapid streamflow increases as the water table approaches the soil surface) governed streamflow generation in both basins, and the mean threshold depths at which rapid streamflow increases corresponded to small rises in water level were similar for harvested (0·41 ± 0·05 m) and forested (0·38 ± 0·04 m) basins. However, topographic properties provided inconsistent explanations of spatial variations in the relationship between streamflow and depth to water at a given piezometer for both basins. Streamflow from the harvested basin exceeded that from the forested basin during the 2001 melt, and hydrometric and geochemical tracer results indicated greater runoff from the harvested basin via surface and near‐surface pathways. These differences are not solely attributable to harvesting, since the difference in spring runoff from the harvested basin relative to the forested control was not consistently larger than under pre‐harvest conditions. Nevertheless, greater melt rates following harvesting appear to have increased the proportion of water delivery to the stream channel via surface and near‐surface pathways. Copyright © 2005 John Wiley & Sons, Ltd.     

Seasonal changes in runoff generation in a small forested mountain catchment

This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.     

The role of run-on for overland flow and the characteristics of runoff generation in the Loess Plateau,China

Abstract

The Loess Plateau in China is overlain by deep and loose soil. As in other semi-arid regions, convective precipitation produces storms, typically of short duration, relatively high intensity and limited areal extent. Infiltration excess (Hortonian mechanism) of precipitation is conventionally assumed to be more prominent than saturation excess (Dunne mechanism) for storm runoff generation. This assumption is true at a point during the storm. However, the runoff generation mechanism is altered when the runoff is conditioned by a lateral redistribution movement of water, i.e. run-on, as the spatial scale increases. In the Loess Plateau, the effects of run-on may be significant, because of the deep and loose surface soil layer. In this study, the role of run-on for overland flow in the Upper Wei River basin, located in the Loess Plateau, is evaluated by means of a simple numerical model at the hillslope scale. The results show that almost all the Hortonian overland flow infiltrates into the soil along the flat hillslope and dry gully before it reaches the river channel. Most of the runoff is generated from the saturated soil near the river channel and from the subsurface. The run-on process takes much longer than the infiltration, facilitating rainfall–runoff modelling at a daily time step. A hydrological model is employed to investigate the characteristics of runoff generation in the Upper Wei River basin. The analysis shows that the subsurface flow contribution to total streamflow is more than 53% from October to March, while the overland flow contribution exceeds 72% from April to September.

Editor D. Koutsoyiannis; Associate editor Dawen Yang

Citation Liu, D.F., Tian, F.Q., Hu, H.C., and Hu, H.P., 2012. The role of run-on for overland flow and the characteristics of runoff generation in the Loess Plateau, China. Hydrological Sciences Journal, 57 (6), 1107–1117.     

Snowmelt runoff and soil moisture dynamics on steep subalpine hillslopes

Snowmelt water supplies streamflow and growing season soil moisture in mountain regions, yet pathways of snowmelt water and their effects on moisture patterns are still largely unknown. This study examined how flow processes during snowmelt runoff affected spatial patterns of soil moisture on two steep sub‐alpine hillslope transects in Rocky Mountain National Park, CO, USA. The transects have northeast‐facing and east‐facing aspects, and both extend from high‐elevation bedrock outcrops down to streams in valley bottoms. Spatial patterns of both snow depth and near‐surface soil moisture were surveyed along these transects in the snowmelt and summer seasons of 2008–2010. To link these patterns to flow processes, soil moisture was measured continuously on both transects and compared with the timing of discharge in nearby streams. Results indicate that both slopes generated shallow lateral subsurface flow during snowmelt through near‐surface soil, colluvium and bedrock fractures. On the northeast‐facing transect, this shallow subsurface flow emerged through mid‐slope seepage zones, in some cases producing saturation overland flow, whereas the east‐facing slope had no seepage zones or overland flow. At the hillslope scale, earlier snowmelt timing on the east‐facing slope led to drier average soil moisture conditions than on the northeast‐facing slope, but within hillslopes, snow patterns had little relation to soil moisture patterns except in areas with persistent snow drifts. Results suggest that lateral flow and exfiltration processes are key controls on soil moisture spatial patterns in this steep sub‐alpine location. Copyright © 2014 John Wiley & Sons, Ltd.     

Model estimates of runoff in the closed,semiarid Estancia basin,central New Mexico,USA

Abstract

The 5000 km² topographically closed Estancia basin in central New Mexico has been the focus of several palaeoclimatic studies based on changes in the level of late Pleistocene Lake Estancia. A large, unknown volume of surface runoff and groundwater from adjacent mountains contributed to the hydrological balance during highstands and lowstands. The US Department of Agriculture hydrological model SWAT (Soil and Water Assessment Tool) and the US Geological Survey groundwater flow model MODFLOW, with the LAK2 package, were used in this study to estimate runoff and water balance under present climate. A Geographic Information Systems (GIS) interface was used for SWAT, digitized data were applied for soils and vegetation, and limited streamflow data were used to obtain an approximate calibration for the model. Simulated streamflow is generally within 30% of observed values, and simulated runoff for the entire basin is about 8% of the annual inflow volume needed to support lowstands of the former Lake Estancia. Results from the combined models suggest application to other palaeoclimate investigations in semiarid lake basins.     

Hydrological dynamics of snowmelt induced streamflow in a high mountain catchment of the Pyrenees under contrasting snow accumulation and duration years

Snowmelt drives a large portion of streamflow in many mountain areas of the world. However, the water paths from snowmelt to the arrival of the water in the streams are still largely unknown. This work analyzes for first time the influence of snowmelt on spring streamflow with different snow accumulation and duration, in an alpine catchment of the central Spanish Pyrenees. This study presents the water balance of the main melting months (May and June). Piezometric values, water temperature, electrical conductivity and isotope data (δ¹⁸O) allow a better understanding of the hydrological functioning of the basin during these months. Results of the water balance calculations showed that snow represented on average 73% of the water available for streamflow in May and June while precipitation during these months accounted for only 27%. However, rainfall during the melting period was important to determine the shape of the spring hydrographs. On average, 78% of the sum of both the snow water equivalent (SWE) accumulated at the beginning of May and the precipitation in May and June converted into runoff during the May–June melting period. The average evaporation-sublimation during the 2 months corresponded to 8.4% of the accumulated SWE and rainfall, so that only a small part of the water input was ultimately available for soil and groundwater storage. When snow cover disappeared from the catchment, soil water storage and streamflow showed a sharp decline. Consequently, streamflow electrical conductivity, temperature and δ¹⁸O showed a marked tipping point towards higher values. The fast hydrological response of the catchment to snow and meteorological fluctuations, as well as the marked diel fluctuations of streamflow δ¹⁸O during the melting period, strongly suggests short meltwater transit times. As a consequence of this hydrological behaviour, independently of the amount of snow accumulated and of melting date, summer streamflow remained always low, with only small runoff peaks driven by rainfall events.     

A hydrological model for the Negev Desert Highlands: effects of infiltration,runoff and ancient agriculture / Modèle hydrologique pour les régions montagneuses du Negev: les effets d'infiltration,d'écoulement et de l'agriculture ancienne

Abstract

A digital computer model of basin regime was developed for the Negev Desert Highlands, a region which experiences a mean annual rainfall of about 100 mm. The model was based on 13 years of rainfall and runoff records. Relationships obtained from experiments were used to determine areal distribution of rainfall, infiltration rates of soils, effects of slope angle on runoff, stone cover, rainfall intensity, antecedent rainfall, basin size, soil crust, overland flow and channel losses. These relationships also explain how ancient civilizations were able to collect ample water from small basins in order to establish stable agricultural settlements.     

Influence of snow accumulation and snowmelt on streamflow in the central Spanish Pyrenees / Influence de l’accumulation et de la fonte de la neige sur les écoulements dans les Pyrénées centrales espagnoles

Abstract

Abstract Results of studies related to the effect of snow accumulation and snowmelt on river regimes of the central Spanish Pyrenees are presented. Streamflow of the Pyrenean rivers is characterized by low and constant discharges during winter because of accumulation of snow in the basins above 1600 m a.s.l., and high and fluctuating discharges during spring due to snowmelt and rainfall. Regional discharge contrasts have been assessed in relation to the Atlantic influence and the percentage of high altitude areas in each basin. In most of the Pyrenean basins, snowmelt contributes more to the discharge than rainfall in the spring. The analysis of data shows a decrease in winter precipitation in the last 50 years causing a decrease in both winter and spring discharges and introducing changes in the distribution of streamflow throughout the year.     

Impacts of spatially and temporally varying snowmelt on subsurface flow in a mountainous watershed: 1. Snowmelt simulation

Abstract

The dominant source of streamflow in many mountainous watersheds is snowmelt recharge through shallow groundwater systems. The hydrological response of these watersheds is controlled by basin structure and spatially distributed snowmelt. The purpose of this series of two papers is to simulate spatially varying snowmelt and groundwater response in a small mountainous watershed. This paper examines the spatially and temporally variable snowmelt to be used as input to the groundwater flow modelling described in the second paper. Snowmelt simulation by the Simultaneous Heat and Water (SHAW) model (a detailed process model of the interrelated heat, water and solute movement through vegetative cover, snow, residue and soil) was validated by applying the model to two years of data at three sites ranging from shallow transient snow cover on a west-facing slope to a deep snow drift on a north-facing slope. The simulated energy balances for several melt periods are presented. Snow depth, density, and the magnitude and timing of snow cover outflow were simulated well for all sites.     

Influence of landscape aggregation in modelling snow-cover ablation and snowmelt runoff in a sub-arctic mountainous environment

Abstract

Appropriate representation of landscape heterogeneity at small to medium scales is a central issue for hydrological modelling. Two main hydrological modelling approaches, deductive and inductive, are generally applied. Here, snow-cover ablation and basin snowmelt runoff are evaluated using a combined modelling approach that includes the incorporation of detailed process understanding along with information gained from observations of basin-wide streamflow phenomena. The study site is Granger Basin, a small sub-arctic basin in the mountains of the Yukon Territory, Canada. The analysis is based on the comparison between basin-aggregated and distributed landscape representations. Results show that the distributed model based on “hydrological response” landscape units best describes the observed magnitudes of both snow-cover ablation and basin runoff, whereas the aggregated approach fails to represent the differential snowmelt rates and to describe both runoff volumes and dynamics when discontinuous snowmelt events occur.     

Controls of streamflow generation in small catchments across the snow–rain transition in the Southern Sierra Nevada,California

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snow‐dominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca²⁺, Mg²⁺, K⁺ and Cl^? behaved conservatively in the streamflow at all catchments, reflecting mixing of three endmembers. Using endmember mixing analysis, the endmembers were determined to be snowmelt runoff (including rain on snow), subsurface flow and fall storm runoff. In seven of the eight catchments, streamflow was dominated by subsurface flow, with an average relative contribution (% of streamflow discharge) greater than 60%. Snowmelt runoff contributed less than 40%, and fall storm runoff less than 7% on average. Streamflow peaked 2–4 weeks earlier at mixed rain–snow than snow‐dominated catchments, but relative endmember contributions were not significantly different between the two groups of catchments. Both soil water in the unsaturated zone and regional groundwater were not significant contributors to streamflow. The contributions of snowmelt runoff and subsurface flow, when expressed as discharge, were linearly correlated with streamflow discharge (R² of 0.85–0.99). These results suggest that subsurface flow is generated from the soil–bedrock interface through preferential pathways and is not very sensitive to snow–rain proportions. Thus, a declining of the snow–rain ratio under a warming climate should not systematically affect the processes controlling the streamflow generation at these catchments. Copyright © 2012 John Wiley & Sons, Ltd.     

HYDROCHEMICAL DECIPHERING OF STREAMFLOW GENERATION IN SEMI-ARID EAST AFRICA

There is a critical lack of knowledge regarding the dynamics of streamflow generation in the semi-arid tropics, particularly in Africa. In this project runoff mechanisms in forested and non-forested degraded catchments in northern Tanzania were studied using combined hydrometrical and hydrochemical methods. Following the hydrochemical identification of several flowpaths contributing to runoff, hydrograph separation by an end-member model based on K and Ca was undertaken. Results from the forested catchment indicate that stormflow was dominated by event water (about 75%), via overland flow and throughflow. The proportion of pre-event water (groundwater) displaced into the stream by a suggested riparian groundwater ridge mechanism varied, depending on the rainfall characteristics. In the non-forested, degraded catchment, nearly all stormflow was event water, and groundwater discharge was unaffected by rainfall. It is suggested that macropore flow is pivotal to the transmission of rainfall to runoff via throughflow, particularly in semi-arid tropical areas.     

Hydrogeologic controls on streamflow sensitivity to climate variation

Climate models project warmer temperatures for the north‐west USA, which will result in reduced snowpacks and decreased summer streamflow. This paper examines how groundwater, snowmelt, and regional climate patterns control discharge at multiple time scales, using historical records from two watersheds with contrasting geological properties and drainage efficiencies. In the groundwater‐dominated watershed, aquifer storage and the associated slow summer recession are responsible for sustaining discharge even when the seasonal or annual water balance is negative, while in the runoff‐dominated watershed subsurface storage is exhausted every summer. There is a significant 1 year cross‐correlation between precipitation and discharge in the groundwater‐dominated watershed (r = 0·52), but climatic factors override geology in controlling the inter‐annual variability of streamflow. Warmer winters and earlier snowmelt over the past 60 years have shifted the hydrograph, resulting in summer recessions lasting 17 days longer, August discharges declining 15%, and autumn minimum discharges declining 11%. The slow recession of groundwater‐dominated streams makes them more sensitive than runoff‐dominated streams to changes in snowmelt amount and timing. Copyright © 2008 John Wiley & Sons, Ltd.     

Simulating low and high streamflow driven by snowmelt in an insufficiently gauged alpine basin

Snowmelt and water infiltration are two important processes of the hydrological cycle in alpine basins where snowmelt water is a main contributor of streamflow. In insufficiently gauged basins, hydrologic modeling is a useful approach to understand the runoff formation process and to simulate streamflow. In this study, an existing hydrologic model based on the principles of system dynamics was modified by using the effective cumulative temperature (>0 °C) to calculate snowmelt rate, and the soil temperature to adjust the influence of the soil’s physical state on water infiltration. This modified model was used to simulate streamflows in the Kaidu River basin from 1982 to 2002, including normal, high, and low flows categorized by the Z index. Sensitivity analyses, visual inspection, and statistical measures were employed to evaluate the capability of the model to simulate various components of the streamflow. Results showed that the modified model was robust, and able to simulate the three categories of flows well. The model’s ability to reproduce streamflow in low-flow and normal-flow years was better than that in high-flow years. The model was also able to simulate the baseflow. Further, its ability to simulate spring-peak flow was much better than its ability to simulate the summer-peak flow. This study could provide useful information for water managers in determining water allocations as well as in managing water resources.     

The cold rain‐on‐snow event of June 2013 in the Canadian Rockies — characteristics and diagnosis

The June 2013 flood in the Canadian Rockies featured rain‐on‐snow (ROS) runoff generation at alpine elevations that contributed to the high streamflows observed during the event. Such a mid‐summer ROS event has not been diagnosed in detail, and a diagnosis may help to understand future high discharge‐producing hydrometeorological events in mountainous cold regions. The alpine hydrology of the flood was simulated using a physically based model created with the modular cold regions hydrological modelling platform. The event was distinctive in that, although at first, relatively warm rain fell onto existing snowdrifts inducing ROS melt; the rainfall turned to snowfall as the air mass cooled and so increased snowcover and snowpacks in alpine regions, which then melted rapidly from ground heat fluxes in the latter part of the event. Melt rates of existing snowpacks were substantially lower during the ROS than during the relatively sunny periods preceding and following the event as a result of low wind speeds, cloud cover and cool temperatures. However, at the basin scale, melt volumes increased during the event as a result of increased snowcover from the fresh snowfall and consequent large ground heat contributions to melt energy, causing snowmelt to enhance rainfall–runoff by one fifth. Flow pathways also shifted during the event from relatively slow sub‐surface flow prior to the flood to an even contribution from sub‐surface and fast overland flow during and immediately after the event. This early summer, high precipitation ROS event was distinctive for the impact of decreased solar irradiance in suppressing melt rates, the contribution of ground heat flux to basin scale snowmelt after precipitation turned to snowfall, the transition from slow sub‐surface to fast overland flow runoff as the sub‐surface storage saturated and streamflow volumes that exceeded precipitation. These distinctions show that summer, mountain ROS events should be considered quite distinct from winter ROS and can be important contributors to catastrophic events. Copyright © 2016 John Wiley & Sons, Ltd.     

Identification and quantification of streamflow trends on the Canadian Prairies

Abstract

Trend analysis was performed on streamflow data for a collection of stations on the Canadian Prairies, in terms of spring and summer runoff volumes, peak flow rates and peak flow occurrences, as well as an annual volume measure, for analysis periods of 1966–2005, 1971–2005, and 1976–2005. The Mann-Kendall statistical test for trend and bootstrap resampling were used to identify the trends and to determine the field significance of the trends. Partial correlation analysis was used to identify relationships between hydrological variables that exhibit a significant trend and meteorological variables that exhibit a significant trend. Noteworthy results include decreasing trends in the spring snowmelt runoff event volume and peak flow, decreasing trends (earlier occurrence) in the spring snowmelt runoff event peak date and decreasing trends in the seasonal (1 March–31 October) runoff volume. These trends can be attributed to a combination of reductions in snowfall and increases in temperatures during the winter months.     

The identification of runoff-production mechanisms using environmental isotopes in a tussock grassland catchment,eastern otago,New Zealand

A previous hydrometric study of runoff production in tussock grassland drainage basins in Otago (45°50′S, 169°45′E), New Zealand, revealed a marked change of slope in storm hydrograph recessions. An environmental isotope study was initiated to investigate the runoff mechanisms operating and to test specific hypotheses to explain this break in the hydrograph recession. The results indicated that for quickflow volumes in excess of 10mm, the first part of the storm hydrograph can be attributed to two separate sources, namely, ‘old’ water from a shallow, unconfined groundwater reservoir and ‘new’ water from saturation overland flow on the lower wetlands of concave slopes. Despite the extensive area of wetlands, ‘old’ water runoff from the unconfined groundwater reservoir is delivered more rapidly to the stream than ‘new’ water from saturation overland flow. Substantial surface storage in the wetlands has first to be exceeded before rain becomes a significant part of stream discharge. For quickflow volumes less than 10mm, only ‘old’ water from groundwater contributes to the first part of the hydrograph recession. This means that only the largest 7 per cent of storms (in terms of quickflow volume) generate quickflow containing significant amounts of ‘new water’. The second part of the recession of the storm hydrograph consists of ‘old’ water derived from a remarkably well-mixed shallow unconfined groundwater body.     

Hydrological and hydrochemical response of a small canadian shield catchment to late winter rain-on-snow events

A study was undertaken during the winter of 1990–1991 in a small (3.7 ha) Canadian Shield catchment to examine the hydrological and hydrochemical response during rain-on-snow events. The results are presented of two large (37.9 and 34.6 mm) rain-on-snow events occurring in early and late March 1991. Peak and total runoff and the groundwater response from the two events are significantly different. Hydrological data indicate that these differences can be attributed to a combination of meteorological (temperature) and physical conditions (antecedent snowpack ripeness, soil moisture and groundwater levels). An immature snowpack (low temperature and density) combined with low antecedent soil moisture conditions significantly reduced the magnitude of the net hydrological input and runoff from the catchment during the early March event, whereas a more mature snowpack and high antecedent soil moisture conditions led to a large runoff event during late March. During both rain-on-snow events a significant portion of the pre-event snowpack chemical load was lost. Based on the maximum snowpack chemical load measured before the events, the two large rain-on-snow events and a brief mid-March warm period during which there were two much smaller rain-on-snow events removed 78% of the hydrogen ion and 63% of the sulphate and nitrate load from the snowpack, while only reducing snowpack water equivalence by 7%. A two-component (rain and snowmelt) isotopic (δ¹⁸O SMOW %₀) separation of snowmelt lysimeter water during the two events indicated that snowmelt was an important (50 and 65%, respectively) water source available for infiltration and runoff at the snow-soil interface. Considering the high hydrogen ion loadings to the catchment during these two events (3.3 and 3.0 mequiv.m^?2, respectively) streamflow pH was not significantly reduced due to an increase in the discharge of well-buffered groundwater. A two-component isotopic hydrograph separation of peak stream discharge during the 2–3 March event indicated that 75% of the total flow was groundwater. In mid-latitude acid-sensitive catchments, winter rain-on-snow events are an important hydrological occurrence due to their ability to elute much of the chemical load (H⁺, SO₄, NO₃) from the snowpack before the onset of spring melt when the maximum annual hydrological input typically occurs.