Discharge of Salt Groundwater in the Estuary of the Razdol’naya River (Amur Bay) in February 2020

Water Resources - In February 2020, geochemical tracers along with hydrochemical and hydrological characteristics were used to reveal a discharge site of salt groundwaters in the head of the...     

Influence of volcanic glass on the magnetic signal of different paleosols in Córdoba,Argentina

This contribution comprises geological and magnetic results obtained in loess and paleosols profiles outcropped in the Pampean plain (Argentina). The sedimentary sequence exposed in Córdoba province is represented by four profiles Corralito I, Corralito II, Monte Ral815o and Lozada, 32°S 64°14'W (Argentina). These profiles were mineralogically described and magnetically analyzed. The sediments that compound the profiles contain volcanic glass between 20 and 90%. The results of two paleosols with different percentage of volcanic glass in the parent material (correlated to Marine Isotope Stage 5, MIS 5) exposed at Corralito I and Lozada, were compared; an important relationship between environmental magnetism signal and volcanic glass content was observed. All the results suggest that there are variations between different paleosols of the same area and age; such variations are attributed to content of volcanic glass in parent material; time of exposure of the parent material to pedogenic processes; and geomorphological place of each profile. At present, it is not possible to quantify certainly the paleo-precipitation index. Only qualitative interpretation can be done taking into account many variables of the geological system.     

A re-appraisal of the stratigraphy and volcanology of the Cerro Galán volcanic system,NW Argentina

From detailed fieldwork and biotite ⁴⁰Ar/³⁹Ar dating correlated with paleomagnetic analyses of lithic clasts, we present a revision of the stratigraphy, areal extent and volume estimates of ignimbrites in the Cerro Galán volcanic complex. We find evidence for nine distinct outflow ignimbrites, including two newly identified ignimbrites in the Toconquis Group (the Pitas and Vega Ignimbrites). Toconquis Group Ignimbrites (~5.60–4.51 Ma biotite ages) have been discovered to the southwest and north of the caldera, increasing their spatial extents from previous estimates. Previously thought to be contemporaneous, we distinguish the Real Grande Ignimbrite (4.68 ± 0.07 Ma biotite age) from the Cueva Negra Ignimbrite (3.77 ± 0.08 Ma biotite age). The form and collapse processes of the Cerro Galán caldera are also reassessed. Based on re-interpretation of the margins of the caldera, we find evidence for a fault-bounded trapdoor collapse hinged along a regional N-S fault on the eastern side of the caldera and accommodated on a N-S fault on the western caldera margin. The collapsed area defines a roughly isosceles trapezoid shape elongated E-W and with maximum dimensions 27 × 16 km. The Cerro Galán Ignimbrite (CGI; 2.08 ± 0.02 Ma sanidine age) outflow sheet extends to 40 km in all directions from the inferred structural margins, with a maximum runout distance of ~80 km to the north of the caldera. New deposit volume estimates confirm an increase in eruptive volume through time, wherein the Toconquis Group Ignimbrites increase in volume from the ~10 km³ Lower Merihuaca Ignimbrite to a maximum of ~390 km³ (Dense Rock Equivalent; DRE) with the Real Grande Ignimbrite. The climactic CGI has a revised volume of ~630 km³ (DRE), approximately two thirds of the commonly quoted value.     

Geochemistry of the volcano-hydrothermal system of El Chichón Volcano, Chiapas, Mexico

 The 1982 eruption of El Chichón volcano ejected more than 1 km³ of anhydrite-bearing trachyandesite pyroclastic material to form a new 1-km-wide and 300-m-deep crater and uncovered the upper 500 m of an active volcano-hydrothermal system. Instead of the weak boiling-point temperature fumaroles of the former lava dome, a vigorously boiling crater spring now discharges  / 20 kg/s of Cl-rich (∼15 000 mg/kg) and sulphur-poor ( / 200 mg/kg of SO₄), almost neutral (pH up to 6.7) water with an isotopic composition close to that of subduction-type magmatic water (δD=–15‰, δ¹⁸O=+6.5‰). This spring, as well as numerous Cl-free boiling springs discharging a mixture of meteoric water with fumarolic condensates, feed the crater lake, which, compared with values in 1983, is now much more diluted (∼3000 mg/kg of Cl vs 24 030 mg/kg), less acidic (pH=2.6 vs 0.56) and contains much lower amounts of S ( / 200 mg/kg of SO₄, vs 3550 mg/kg) with δ³⁴S=0.5–4.2‰ (+17‰ in 1983). Agua Caliente thermal waters, on the southeast slope of the volcano, have an outflow rate of approximately 100 kg/s of 71  °C Na–Ca–Cl water and are five times more concentrated than before the eruption (B. R. Molina, unpublished data). Relative N₂, Ar and He gas concentrations suggest extensional tectonics for the El Chichón volcanic centre. The ³He/⁴He and ⁴He/²⁰Ne ratios in gases from the crater fumaroles (7.3R_a, 2560) and Agua Caliente hot springs (5.3R_a, 44) indicate a strong magmatic contribution. However, relative concentrations of reactive species are typical of equilibrium in a two-phase boiling aquifer. Sulphur and C isotopic data indicate highly reducing conditions within the system, probably associated with the presence of buried vegetation resulting from the 1982 eruption. All Cl-rich waters at El Chichón have a common source. This water has the appearence of a "partially matured" magmatic fluid: condensed magmatic vapour neutralized by interaction with fresh volcaniclastic deposits and depleted in S due to anhydrite precipitation. Shallow ground waters emerging around the volcano from the thick cover of fresh pumice deposits (Red waters) are Ca–SO₄–rich and have a negative oxygen isotopic shift, probably due to ongoing formation of clay at low temperatures. Received: 21 July 1997 / Accepted: 4 December 1997     

Analysis and interpretation of the seismic response of RC buildings in Concepción during the February 27, 2010, Chile earthquake

Observed trends in the seismic performance of eight severely damaged reinforced concrete (RC) structures after the February 27, 2010, Chile earthquake are presented in this article. After a reconnaissance and surveying process conducted immediately after the earthquake, several aspects not conventionally considered in building design were observed in the field. Most of the considered structures showed extensive localized damage in walls of lower stories and first basements. Several factors indicate that damage was brittle, and occurred mainly in recent RC structures supported on soft soils with some degree of vertical and/or horizontal irregularity. Non-ductile behavior has been inferred due to the lack of evidence of spread damage in the structure, and the fact that very similar structural configurations existed nearby without apparent damage. Some key aspects in understanding the observed damage are: geographical orientation of the building, presence of vertical and horizontal irregularities, wall thickness and reinforcement detailing, and lack of sources for energy dissipation. Additionally, results of a building-code type analysis are presented for the 4 most critical buildings, and Demand/Capacity ratios are calculated and compared with the observed behavior. It is concluded that the design codes must be revised relative to wall design provisions.     

The volcano-tectonic evolution of Concepción,Nicaragua

We describe the evolution of Concepción volcano by integrating regional geology, eruptive activity, morphology, stratigraphy, petrology, structure and active deformation data. This Nicaraguan volcano is set close to the back limb of the northwest-trending Tertiary Rivas anticline, a regional structure that bounds the southwest side of Lake Nicaragua. Concepción rises 1,600 m above a 1-km-thick sequence of Quaternary lacustrine mud-stones. There is no record of volcanism in the lake prior to Concepción. In addition, the only nearby volcano, Maderas volcano, has not deposited material on Concepción because of the trade winds. Thus, Concepción (and Made ras, too) can be considered as pristine volcanic environments, unaffected by other centres. A topographic rise forms an annulus 20 km in diameter around the cone. The rise is created by thrust-related folds at the western base, where the trade winds have accumulated a thick sequence of tephra, and by mud diapirs at the eastern base where only lake mudstones are present. Four magmatic-eruptive episodes exist in the stratigraphic record. The first begins with primitive low-alumina basalt and subsequently evolves to dacitic compositions. The following three episodes begin with high-alumina basalts and evolve only to silicic andesites. The occurrence of the high-alumina basalt after the first episode is indicative of crystal fractionation at lower crustal depths. The first episode may be associated with a compressive phase of volcano evolution. In this phase, the edifice load compresses substrata, allowing a longer magma residence time and differentiation in a shallow reservoir (possibly located at the density contrast between the lake sediments and the Tertiary flysch). During the next three episodes the weak sediments below the volcano started to rupture and yield under its increasing load, beginning a thrusting/diapiring phase of volcano evolution. Because of outward thrusting, vertical and horizontal stresses above the chamber were reduced, allowing magma to erupt more easily and to reach a lesser degree of evolution. If we consider the future evolution of Concepción, the differentiation in the shallow reservoir has probably generated a cumulitic complex, which eventually will start to deform and spread, beginning another, this time plutonic, spreading phase. This phase, which may be beginning now, could allow less evolved magmas to be erupted again. Four components influence the phases of volcano evolution: (1) the regional geology that is the boundary condition of the environment, (2) the substrata rheology that controls deformation, (3) the load of the volcanic edifice and (4) the magma, which provides the input of mass and energy. Our model of volcanic evolution suggests that Concepción is a complex geologic environment. The volcanic activity, tectonics and hazards can only be constrained through a complete knowledge of the many components of this environment. Published online: 20 February 2003 Editorial responsibility: R. Cioni     

Distribution and origin of biologically available phosphorus in the water of the Meiliang Bay in summer

The investigation and continuous monitoring with an innovative iron oxide embedded cellulose acetate membrane (FeO/CAM) on the concentrations of biologically available phosphorus (BAP) were conducted in the Meiliang Bay of the Taihu Lake during summer in 2004. The results showed that the concentrations of dissolved (FeO-DP), particulate (FeO-PP) and total bioavailable phosphorus (FeO-P) had similar horizontal distribution. The BAP concentrations were the highest in those estuaries in the northern bay. With the decrease of the distance to the estuary or long shore, there was little difference between BAP concentrations in an open lake area. During the observation period, algal blooms occurred in most waters of the northern bay, which was reflected from the high concentrations of chlorophyll a (Chl-a). While they were not highest in the estuarine waters of those major rivers, this is the case for the BAP concentrations. The concentrations of Chl-a had a significantly positive correlation with those of bioavailable phosphorus in the open area of the Meiliang Bay. With the sediment resuspension induced by wind and wave, BAP concentrations increased in a short-term, indicating that the riverine P inputs mainly contribute to the concentrations of BAP in the estuarine water while internal P release was the major source of BAP in the open lake area. In the eutrophic shallow lake, the blooms of alga may cause pH increase and further result in internal P release. The above results showed that the new membrane of FeO/CAM can be used to monitor the concentrations of BAP and provide the scientific justifications for the control strategy of the lake eu-trophication.     

Size-fractionated phytoplankton biomass,primary production and respiration in the Nervión–Ibaizabal estuary: A comparison with other nearshore coastal and estuarine ecosystems from the Bay of Biscay

The seasonal pattern of size-fractionated phytoplankton biomass, primary production and respiration was investigated along the longitudinal axis of the Nervión–Ibaizabal estuary (Bay of Biscay) from April 2003 to September 2004. Environmental factors influencing phytoplankton dynamics were also studied. Chlorophyll a biomass showed a longitudinal pattern of increase from the outer Abra bay to the inner estuary. On a seasonal scale, in the intermediate and inner estuary phytoplankton biomass maxima were registered in summer, the warmest and driest season, whereas in the outer bay chlorophyll a peaks occurred in May 2004, but were delayed to August 2003, likely due to a very rainy spring. Data suggest that river flow exerts a marked influence on the timing of phytoplankton biomass maxima in this estuary, decreased river flows providing a lowering of turbidity and an increase in water residence time needed for chlorophyll a to build up. Nutrient concentrations were high enough not to limit phytoplankton growth throughout the annual cycle, except silicate and occasionally phosphate in the outer bay during summer. Silicate concentration correlated positively with river flow, whereas ammonium and phosphate maximum values were generally measured in the mid-estuary, suggesting the importance of allochthonous anthropogenic sources. In the intermediate and inner estuary phytoplankton biomass was generally dominated by >8 μm size-fraction (ca. 60%), but in August 2003 <8 μm size-fraction increased its contribution in the intermediate estuary. It is argued that the lower nutrient concentrations measured in August 2003 than in August 2004 could have played a role. This is the first study in which phytoplankton primary production rates have been measured along the longitudinal axis of the Nervión–Ibaizabal estuary. Throughout the annual cycle these rates ranged from 0.001 to 3.163 g C m^?3 d^?1 and were comparable to those measured in nearby small estuaries of the Basque coast and other larger estuaries on the Bay of Biscay. Surface plankton community respiration rate maxima were measured during the spring 2004 chlorophyll a peak in the Abra bay and in summer months at the mid and inner estuary, coinciding with chlorophyll a biomass and primary production maxima. In general, respiration rates showed a positive correlation with temperature. In order to compare results from the Nervión–Ibaizabal estuary with other nearshore coastal and estuarine ecosystems within the Bay of Biscay a review of existing information on phytoplankton biomass and primary production dynamics was performed.     

Columnar jointing in vapor-phase-altered,non-welded Cerro Galán Ignimbrite,Paycuqui, Argentina

Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10⁻³–8.5 × 10⁻²°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.     

On the relation of variations in the travel times of seismic waves with the changes in the speed of the Earth’s rotation

The results of long-term sounding of the lithosphere by seismic waves from the deep-focus Hindu Kush earthquakes are presented. The travel time series of the first longitudinal wave on a fixed base are constructed for six seismic observation stations (SS) located on the Russian Platform (the Obninsk SS), on the Siberian Platform (the Eltsovka SS), on the Cis-Ural Trough (the Arti SS), in the Central-Ural Megazone (the Sverdlovsk SS), in the Transbaikalia (the Bodaibo SS), and in the Northern Tien Shan (the Przhevalsk SS). The time series duration in years for these stations ranged from 1964–1970 to 2007. The travel time series of seismic waves for the stations indicated are characterized by multi-slope negative linear trends caused by changes in the stress-strain state of rocks. From the comparison of the trend slopes at different stations it follows that the changes in the stress conditions within the lithosphere are relatively weak in the aseismic regions of the Russian and Siberian Platforms and in the Ural Megazone, whereas in the seismically active regions of Tien Shan, Transbaikalia and the Cis-Ural Trough they are more pronounced. The correlation has been observed between the time series trends of the average annual travel times of seismic waves and the time series of the Earth’s rotation speed. The strongest correlation between the series can be seen for the stations, located on the platforms with weak manifestations of both seismicity and active geodynamic processes. Within the long-term periods of deceleration and acceleration of the Earth’s rotation, travel times of seismic waves are decreased and increased, respectively.     

Study of the earthquake of the January 23, 1880, in San Cristóbal,Cuba and the Guane fault

All available data on the January 23, 1880, earthquake near San Cristobal, Western Cuba, are compiled and presented here. The earthquake reached a maximum intensity of eight degrees (MSK) and caused three fatalities. It was accompanied by 65 aftershocks and was felt as far away as the Florida Keys. Twentieth century specialists has associated this event, in its day the strongest recorded (Ms = 6.2) in the region, with the Pinar fault. The Pinar fault is well expressed topographically as the boundary between the Guaniguanico Range in the north and an alluvial plain to the south. Most of the major damage caused by the earthquake was located on the alluvial plain, which in consequence has been considered the epicenter area. In the study presented here, the data compiled from the first reports of Father Benito Vines Martorell, S.J., and Pedro Salteraín y Legarra, indicate that the seismic structure was located in the alluvial plain, and that it was the Guane fault, and not the Pinar fault, that was responsible for the earthquake. The Guane fault, found below the alluvial sediments, extends NE-SW for over 110 km. Its eastern extreme, near San José de las Lajas (La Habana), is linked to another active fault which represents a seismoactive knot responsible for the earthquake of March 9, 1995 (I = 5 degrees, MSK). Seismic events of the Western Cuban region are related to the transpressive interaction of the North American and Caribbean Plates, damped by oceanic structures.     

Estimation of the inland extending length of the freshwater–saltwater interface in coastal unconfined aquifers

ABSTRACT

The inland extending length of the freshwater–saltwater interface toe is useful in studies of seawater intrusion in coastal areas. The submarine fresh groundwater discharge in coastal zones is affected not only by hydraulic conductivity and hydraulic gradient of the aquifer, but also by the position of the interface. Two observation wells at different distances from the coast are required to calculate the fresh groundwater flow rate in coastal unconfined aquifers. By considering that the submarine groundwater discharge is equal to the groundwater flow rate, the length of the interface toe extending inland can be estimated when the groundwater flow is at a steady-flow state. Aquifers with horizontal and sloping confined beds and without/with unique surface vertical infiltration are considered. Examples used to illustrate the application of these methods indicate that the inland extending lengths of the interface toe in aquifers with vertical surface infiltration are much shorter than those in aquifers without vertical surface infiltration, and the length of the interface in aquifers with a horizontal confining lower bed are smaller than those in aquifers with a confining lower bed sloping towards the sea. The extent of the interface on the northwestern coast near the city of Beihai in southern Guangxi, China, on 18 January 2013 was estimated as 471–478 m.

Editor M.C. Acreman Associate editor not assigned     

Does Pumping Volume Affect the Concentration of Micropollutants in Groundwater Samples?

Information on concentrations of micropollutants (such as pharmaceuticals, pesticides, and industrial chemicals) in most highly dynamic riverbank filtration (RBF) systems is lacking, in contrast to data on standard chemical parameters. Sampling protocols have thus far been based on the stabilization of standard chemical parameters in relatively pristine environments. To determine whether groundwater samples for micropollutant analysis can be taken at a similar pumping volume as samples for testing standard chemical parameters in both environments, three groundwater monitoring wells in an RBF system were sampled at two points in time (after pumping of 3 well volumes and after pumping of 15 well volumes). Micropollutant concentrations were not significantly different between the two sampling points; therefore, appropriate samples can be drawn after pumping 3 well volumes. For a specific microbiological parameter (leucin incorporation), a statistically significant difference was found.     

Complex dynamics of small-moderate volcanic events: the example of the 2011 rhyolitic Cordón Caulle eruption,Chile

After decades of repose, Puyehue-Cordón Caulle Volcano (Chile) erupted in June 2011 following a month of continuously increasing seismic activity. The eruption dispersed a large volume of rhyolitic tephra over a wide area and was characterized by complex dynamics. During the initial climactic phase of the eruption (24–30 h on 4–5 June), 11–14-km-high plumes dispersed most of the erupted tephra eastward towards Argentina, reaching as far as the Atlantic Ocean. This first eruptive phase was followed by activity of lower intensity, leading to the development of a complex stratigraphic sequence, mainly due to rapid shifts in wind direction and eruptive style. The resulting tephra deposits consist of 13 main layers grouped into four units. Each layer was characterized based on its dispersal direction, sedimentological features, and on the main characteristics of the juvenile fraction (texture, density, petrography, chemistry). The lowest part of the eruptive sequence (Unit I), corresponding to the tephra emitted between 4 and 5 June, is composed of alternating lapilli layers with a total estimated volume of ca. 0.75 km³; these layers record the highest intensity phase, during which a bent-over plume dispersed tephra towards the southeast-east, with negligible up-wind sedimentation. Products emitted during 5–6 June (Unit II) signaled an abrupt shift in wind direction towards the north, leading to the deposition of a coarse ash deposit in the northern sector (ca. 0.21 km³ in volume), followed by a resumption of easterly directed winds. A third phase (Unit III) began on 7 June and resulted in tephra deposits in the eastern sector and ballistic bombs around the vent area. A final phase (Unit IV) started after 15 June and was characterized by the emission of fine-grained white tephra from ash-charged plumes during low-level activity and the extrusion of a viscous lava flow. Timing and duration of the first eruptive phases were constrained based on comparison of the dispersal of the main tephra layers with satellite images, showing that most of the tephra was emitted during the first 72 h of the event. The analyzed juvenile material tightly clusters within the rhyolitic field, with negligible chemical variations through the eruptive sequence. Textural observations reveal that changes in eruption intensity (and consequently in magma ascent velocity within the conduit) and complex interactions between gas-rich and gas-depleted magma portions during ascent resulted in vesicular clasts with variable degrees of shear localization, and possibly in the large heterogeneity of the juvenile material.     

Using growth measures in the freshwater shrimp Caridina nilotica as biomarkers of Roundup® pollution of South African freshwater systems

There has been global concern about the effect of toxic chemicals on aquatic biota due to the upsurge in contamination of aquatic ecosystems by these chemicals, which includes pesticides. Roundup® and other glyphosate-based herbicides are frequently used in the chemical control of weeds and invading alien plant species in South Africa. These bio-active chemicals ultimately get into water courses directly or indirectly through processes such as drifting, leaching, surface runoff and foliar spray of aquatic nuisance plants. However, there is no South African water quality guideline to protect indigenous freshwater non-target organisms from the toxic effects of glyphosate-based herbicides. This study evaluated the possible use of growth measures in Caridina nilotica as biomarkers of Roundup® pollution as part of developing glyphosate water quality guideline for the protection of aquatic life in South Africa. Using static-renewal methods in a 25-day growth toxicity test, 40 days post hatch shrimps were exposed to different sub-lethal Roundup® concentrations of 0.0 (control), 2.2, 2.8, 3.4, 4.3 and 5.4 mg/L. Shrimps were fed daily with TetraMin® flake food and test solutions changed every third day. Shrimp total lengths and wet weights were measured every fifth day. These data were used to determine the shrimp’s growth performance and feed utilization in terms of percent weight gain (PWG), percent length gain (PLG), specific growth rate (SGR), condition factor (CF), feed intake (FI), feed conversion ratio (FCR) and feed conversion efficiency (FCE). Moulting was observed for 14 days and the data used to determine the daily moult rate for each concentration. Results of growth performance and food utilization indices showed that growth was significantly impaired in all exposed groups compared to control (p < 0.05). Moulting frequency was also higher in all exposed groups than in control (p < 0.05). Although all the tested growth measures proved to be possible biomarkers of Roundup® pollution, moulting frequency gives a clearer indication of the sub-lethal effects of Roundup® toxicity.     

Geochemical homogeneity of a long-lived,large silicic system; evidence from the Cerro Galán caldera,NW Argentina

By applying a number of analytical techniques across a spectrum of spatial scales (centimeter to micrometer) in juvenile components, we show that the Cerro Galán volcanic system has repeatedly erupted magmas with nearly identical geochemistries over >3.5 Myr. The Cerro Galán system produced nine ignimbrites (∼5.6 to 2 Ma) with a cumulative volume of >1,200 km³ (DRE; dense rock equivalent) of calc-alkaline, high-K rhyodacitic magmas (68–71 wt.% SiO₂). The mineralogy is broadly constant throughout the eruptive sequence, comprising plagioclase, quartz, biotite, Fe–Ti oxides, apatite, and titanite. Early ignimbrite magmas also contained amphibole, while the final eruption, the most voluminous Cerro Galán ignimbrite (CGI; 2.08 ± 0.02 Ma) erupted a magma containing rare amphibole, but significant sanidine. Each ignimbrite contains two main juvenile clast types; dominant “white” pumice and ubiquitous but subordinate “grey” pumice. Fe–Ti oxide and amphibole-plagioclase thermometry coupled with amphibole barometry suggest that the grey pumice originated from potentially hotter and deeper magmas (800–840°C, 3–5 kbar) than the more voluminous white pumice (770–810°C, 1.5–2.5 kbar). The grey pumice is interpreted to represent the parental magmas to the Galán system emplaced into the upper crust from a deeper storage zone. Most inter-ignimbrite variations can be accounted for by differences in modal mineralogy and crystal contents that vary from 40 to 55 vol.% on a vesicle-free basis. Geochemical modeling shows that subtle bulk-rock variations in Ta, Y, Nb, Dy, and Yb between the Galán ignimbrites can be reconciled with differences in amounts of crystal fractionation from the “grey” parent magma. The amount of fractionation is inversely correlated with volume; the CGI (∼630 km³) and Real Grande Ignimbrite (∼390 km³) return higher F values (proportion of liquid remaining) than the older Toconquis Group ignimbrites (<50 km³), implying less crystal fractionation took place during the upper-crustal evolution of these larger volume magmas. We attribute this relationship to variations in magma chamber geometry; the younger, largest volume ignimbrites came from flat sill-like magma chambers, reducing the relative proportion of sidewall crystallization and fractionation compared to the older, smaller-volume ignimbrite eruptions. The grey pumice clasts also show evidence of silicic recharge throughout the history of the Cerro Galán system, and recharge days prior to eruption has previously been suggested based on reversely zoned (OH and Cl) apatite phenocrysts. A rare population of plagioclase phenocrysts with thin An-rich rims in juvenile clasts in many ignimbrites supports the importance of recharge in the evolution and potential triggering of eruptions. This study extends the notion that large volumes of nearly identical silicic magmas can be generated repeatedly, producing prolonged geochemical homogeneity from a long-lived magma source in a subduction zone volcanic setting. At Cerro Galán, we propose that there is a zone between mantle magma input and upper crustal chambers, where magmas are geochemically “buffered”, producing the underlying geochemical and isotopic signatures. This produces the same parental magmas that are delivered repeatedly to the upper crust. A lower-crustal MASH (melting, assimilation, storage, and homogenization) zone is proposed to act as this buffer zone. Subsequent upper crustal magmatic processes serve only to slightly modify the geochemistry of the magmas.     

Groundwater supply of lakes: the case of Lake Raduńskie Górne (northern Poland,Kashubian Lake District)

ABSTRACT

The aim of the study was to locate and describe groundwater outflows in a selected lake basin and measure the spring output of water and the physical characteristics of the studied waters (temperature and conductivity). The final aim was to gauge the effects of the spring output on the lake hydrology. The time scope of the work included the period from January 2011 to September 2012. The spatial scope of the work included the area of Lake Raduńskie Górne and its direct catchment located in the Kashubian Lake District in northern Poland. Four groundwater outflows were located in the course of the study. Their total output was 4.6 L s^?1 and ranged between 0.5 and 2.5 L s^?1. This produces an annual yield of about 145 000 m³ year^?1. These results confirm that one of the forms of supply to the lakes are the under-lake springs. For lakes located in the area of young glacial accumulation this can be decisive.

Editor D. Koutsoyiannis Associate editor D. Gerten