U–Pb ages and Hf isotopic record of zircons from the late Neoproterozoic and Silurian–Devonian sedimentary rocks of the western Yangtze Block: Implications for its tectonic evolution and continental affinity

The relationship of the Yangtze Block with other continental blocks of the Rodinia and Gondwana supercontinents is hotly debated. Here we report U–Pb and Lu–Hf isotopic data for zircons from the latest Neoproterozoic Yanjing Group and the overlying Silurian–Devonian rocks on the western margin of Yangtze Block, which provide critical constraints on the provenance of these sediments and further shed light on the crustal evolution and tectonic affinity of the western Yangtze Block in the context of Rodinia and the subsequent Gondwanaland. Mica schist from the middle part of the Yanjing Group contains dominant Neoproterozoic detrital zircons (0.72–0.80 Ga) with a pronounced age peak at 0.75 Ga. Based on the euhedral to subhedral shapes, high Th/U ratios and exclusively positive εHf(t) values (+ 6 to + 14) for the zircon crystals, and the lack of ancient zircons, we consider the sediments as products of proximal deposition near a Neoproterozoic subduction system in western Yangtze. Combined with the age of rhyolite from the lower part of the Yanjing Group, these strata were estimated to have been deposited in a period between 0.72 and 0.63 Ga. In contrast, the Silurian–Devonian sediments exhibit dominant Grenvillian ages (0.9–1.0 Ga), with middle Neoproterozoic (0.73–0.85 Ga), Pan-African (0.49–0.67 Ga) and Neoarchean (~ 2.5 Ga) age populations, suggesting a significant change of sedimentary provenance and thus a different tectonic setting. Although the shift occurred in the Silurian, the age spectra turn to be consistent along the western margin of the Yangtze Block until the Devonian, indicating persistence of the same sedimentary environment. However, the related provenance of these Paleozoic sediments cannot be found in South China. The presence of abundant Grenvillian, Pan-African and Neoarchean ages, along with their moderately to highly rounded shapes, indicates the possibility of exotic continental terrane(s) as a possible sedimentary provenance. Considering the potential source areas around the Yangtze Block when it was part of the Rodinia or Gondwana, we suggest that the source of these Paleozoic sediments had typical Gondwana affinities such as the Himalaya region, north India, which is also supported by their stratigraphic similarity, newly published paleomagnetic data and the tectono-thermal events of northwestern fragments of Gondwana. This implies that after a prolonged subduction in the Neoproterozoic, the western margin of the Yangtze Block began to incorporate into the assembly of the Gondwana supercontinent and was able to accept sediments from northwestern margin of Gondwanaland as a result of early Paleozoic orogeny.     

Tracing the position of the South China block in Gondwana: U–Pb ages and Hf isotopes of Devonian detrital zircons

U–Pb detrital zircon geochronology from Lower Devonian quartz arenites of the northwestern margin of the Yangtze block yields dominant early Neoproterozoic (0.85–1.0 Ga), Pan-African (0.5–0.65 Ga) and middle Neoproterozoic (0.68–0.8 Ga) age populations and minor Mesoproterozoic to middle Mesoarchean (1.0–3.0 Ga) ages. Middle Mesoarchean to Mesoproterozoic rocks, however, are widespread in the South China block. Although Hf isotopic compositions show both juvenile crustal growth and crustal reworking for all the age groupings, the crust growth, essentially mantle-derived, occurred mainly around 3.1 Ga, 1.9 Ga and 1.0 Ga, respectively. Zircon typology and youngest grain ages indicate that this suite of quartz arenites was the product of multiphase reworking. Abundant magmatic zircon detritus with concordant U–Pb Grenvillian and Pan-African ages, together with accompanying various ε_Hf(t) values, indicate an exotic provenance for the quartz arenite external to the South China block. Qualitative comparisons of age spectra for the late Neoproterozoic sediments of the Cathaysian Block, early Paleozoic sediments of pre-rift Tethyan Himalaya sequence in North India and lower Paleozoic sandstone from the Perth Basin in West Australia, show that they all have two the largest age clusters representing Grenvillian and Pan-African orogenic episodes. The resemblance of these age spectra and zircon typology suggests that the most likely source for the Lower Devonian quartz arenites of the South China block was the East African Orogen and Kuunga Orogen for their early Grenvillian and Pan-African populations, whereas the Hannan–Panxi arc, Jiangnan orogen, and the Yangtze block basements might have contributed to the detrital zircon grains of the Neoproterozoic and Pre-Grenvillian ages. Hf isotopic data indicate that the crustal evolution of the drainage area matches well with the episodic crust generation of Gondwana. These results imply that the previously suggested position of the SCB in Gondwana should be re-evaluated, and the South China block should be linked with North India and West Australia as a part of East Gondwana during the assembly of Gondwana, rather than a discrete continent block in the paleo-Pacific.     

Early Cambrian palaeogeography and the probable Iberia–Siberia connection

The end of the Proterozoic–beginning of the Cambrian is marked by some of the most dramatic events in the history of Earth. The fall of the Ediacaran biota, followed by the Cambrian Explosion of skeletonised bilaterians, a pronounced shift in oceanic and atmospheric chemistry and rapid climatic change from ‘snowball earth’ to ‘greenhouse’ conditions all happened within a rather geologically short period of time. These events took place against a background of the rearrangement of the prevailing supercontinent; some authors view this as a sequence of individual supercontinents such as Mesoproterozoic Midgardia, Neoproterozoic Rodinia and Early Cambrian Pannotia. Assembled in the Mesoproterozoic, this supercontinent appears to have existed through the Neoproterozoic into the Early Cambrian with periodic changes in configuration. The final rearrangement took place during the Precambrian–Cambrian transition with the Cadomian and related phases of the Pan-African orogeny. The distribution of Early Cambrian molluscs and other small shelly fossils (SSF) across all continents indicates a close geographic proximity of all major cratonic basins that is consistent with the continued existence of the supercontinent at that time. Subsequently, Rodinia experienced breakup that led to the amalgamation of Gondwana, separation of Laurentia, Baltica, Siberia and some small terranes and the emergence of oceanic basins between them. Spreading oceanic basins caused a gradual geographic isolation of the faunal assemblages that were united during the Vendian–Early Cambrian.     

African, southern Indian and South American cratons were not part of the Rodinia supercontinent: evidence from field relationships and geochronology

We discuss the question whether the late Mesoproterozoic and early Neoproterozoic rocks of eastern, central and southern Africa, Madagascar, southern India, Sri Lanka and South America have played any role in the formation and dispersal of the supercontinent Rodinia, believed to have existed between about 1000 and 750 Ma ago. First, there is little evidence for the production of significant volumes of ˜1.4–1.0 Ga (Kibaran or Grenvillian age) continental crust in the Mozambique belt (MB) of East Africa, except, perhaps, in parts of northern Mozambique. This is also valid for most terranes related to West Gondwana, which are made up of basement rocks older than Mesoproterozoic, reworked in the Brasiliano/Pan-African orogenic cycle. This crust cannot be conclusively related to either magmatic accretion processes on the active margin of Rodinia or continental collision leading to amalgamation of the supercontinent. So far, no 1.4–1.0 Ga rocks have been identified in Madagascar. Secondly, there is no conclusive evidence for a ˜1.0 Ga high-grade metamorphic event in the MB, although such metamorphism has been recorded in the presumed continuation of the MB in East Antarctica. In South America, even the Sunsas mobile belt, which is correlated with the Grenville belt of North America, does not include high-grade metamorphic rocks. All terranes with Mesoproterozoic ages seem to have evolved within extensional, aulacogen-type structures, and their compressional deformation, where observed, is normally much younger and is related to amalgamation of Gondwana. This is also valid for the Trans-Saharan and West Congo belts of West Africa.Third, there is also no evidence for post-1000 Ma sedimentary sequences that were deposited on the passive margin(s) of Rodinia. In contrast, the MB of East Africa and Madagascar is characterized by extensive structural reworking and metamorphic overprinting of Archaean rocks, particularly in Tanzania and Madagascar, and these rocks either constitute marginal parts of cratonic domains or represent crustal blocks (terranes or microcontinents?) of unknown derivation. This is also the case for most terranes included in the Borborema/Trans-Saharan belt of northeastern Brazil and west-central Africa, as well as those of the Central Goíás Massif in central Brazil and the Mantiqueira province of eastern and southeastern Brazil.Furthermore, there is evidence for extensive granitoid magmatism in the period ˜840 to <600 Ma whose predominant calc-alkaline chemistry suggests subduction-related active margin processes during the assembly of the supercontinent Gondwana. The location of the main Neoproterozoic magmatic arcs suggests that a large oceanic domain separated the core of Rodinia, namely Laurentia plus Amazonia, Baltica and West Africa, from several continental masses and fragments now in the southern hemisphere, such as the São Francisco/Congo, Kalahari and Rio de La Plata cratons, as well as the Borborema/Trans-Saharan, Central Goiás Massif and Paraná blocks. Moreover, many extensional tectonic events detected in the southern hemisphere continental masses, but also many radiometric ages of granitois that are already associated with the process of amalgamation of Gondwana, are comprised within the 800–1000 age interval. This seems incompatible with current views on the time of disintegration of Rodinia, assumed to have occurred at around 750 Ma.     

Supercontinent evolution and the Proterozoic metallogeny of South America

The cratonic blocks of South America have been accreted from 2.2 to 1.9 Ga, and all of these blocks have been previously involved in the assembly and breakup of the Paleoproterozoic Atlantica, the Mesoproterozoic to Neoproterozoic Rodinia, and the Neoproterozoic to Phanerozoic West Gondwana continents. Several mineralization phases have sequentially taken place during Atlantica evolution, involving Au, U, Cr, W, and Sn. During Rodinia assembly and breakup and Gondwana formation, the crust-dominated metallogenic processes have been overriding, responsible for several mineral deposits, including Au, Pd, Sn, Ni, Cu, Zn, Mn, Fe, Pb, U, P₂O₅, Ta, W, Li, Be and precious stones. During Rodinia breakup, epicontinental carbonate-siliciclastic basins were deposited, which host important non-ferrous base metal deposits of Cu–Co and Pb–Zn–Ag in Africa and South America. Isotope Pb–Pb analyses of sulfides from the non-ferrous deposits unambiguously indicate an upper crustal source for the metals. A genetic model for these deposits involves extensional faults driving the circulation of hydrothermal mineralizing fluids from the Archean/Paleoproterozoic basement to the Neoproterozoic sedimentary cover. These relations demonstrate the individuality of metal associations of every sediment-hosted Neoproterozoic base-metal deposit of West Gondwana has been highly influenced by the mineralogical and chemical composition of the underlying igneous and metaigneous rocks.     

Neoproterozoic crustal growth: The solid Earth system during a critical episode of Earth history

The behavior of the solid Earth system is often overlooked when the causes of major Neoproteozoic (1000–542 Ma) climate and biosphere events are discussed although  20% of the present continental crust formed or was remobilized during this time. Processes responsible for forming and deforming the continental crust during Neoproterozoic time were similar to those of the modern Earth and took place mostly but not entirely at convergent margin settings. Crustal growth and reworking occurred within the context of a supercontinent cycle, from breakup of Rodinia beginning  830 Ma to formation of a new supercontinent Greater Gondwana or Pannotia,  600 Ma. Neoproterozoic crust formation and deformation was heterogeneous in space and time, and was concentrated in Africa, Eurasia, and South America during the last 300 million years of Neoproterozoic time. In contrast, the solid Earth system was relatively quiescent during the Tonian period (1000–850 Ma). The vigor of Cryogenian and Ediacaran tectonic and magmatic processes and the similar timing of these events and development of Neoproterozoic glaciations and metazoa suggest that climate change and perhaps increasing biological complexity was strongly affected by the solid Earth system.     

东南极普里兹带多期变质作用及其对罗迪尼亚和冈瓦纳超大陆重建的启示

东南极普里兹带是一条经受格林维尔期和泛非期高级构造热事件影响的多相变质带,其构造演化过程与罗迪尼亚和冈瓦纳超大陆的形成密切相关.新的岩石学和年代学资料表明,普里兹带中的格林维尔期高级变质作用是区域性的,并经历了>970Ma和930～900Ma两个演化阶段(期),变质条件达到相对高温高压的麻粒岩相.格林维尔期造山作用起始于活动大陆边缘或岛弧环境下的岩浆增生,最后发展到陆陆碰撞,从而使印度、东南极西陆块和非洲的卡拉哈里克拉通拼合在一起,构成了罗迪尼亚超大陆的重要组成部分之一.普里兹带中的泛非期高级变质作用并不象前人认为的那样只发生在中低压麻粒岩相条件下,而是达到高压麻粒岩相,并具有近等温减压的顺时针P-T演化轨迹.格林维尔期变质先驱的普遍存在说明泛非期碰撞造山事件主要叠加在印度-南极陆块东缘的基底杂岩之上,所以其主缝合线的位置应该在现今普里兹带的东南方向,并可能向南极内陆延伸到甘布尔采夫冰下山脉.对不同类型岩石的精细定年揭示,普里兹带中泛非期造山作用过程从570Ma一直持续到490Ma,这与东非造山带的晚期碰撞阶段大致相吻合.因此,冈瓦纳超大陆的最后拼合可能是通过西冈瓦纳、印度-南极陆块和澳大利亚-南极陆块等三个陆块的近于同期碰撞来完成的.     

Early Neoproterozoic events in East Greenland

East Greenland forms one of the least understood of the orogenic belts formed during the amalgamation of Rodinia during late Mesoproterozoic times. Recent U–Pb zircon SHRIMP dating on the widespread Krummedal supracrustal succession and associated granites from central East Greenland has shown that metamorphism and intrusion affected the region at around 0.95–0.92 Ga, approximately 150 m.y. later than the main phase of Grenvillian orogenesis (s.s.). These early Neoproterozoic ages may indicate a link with metamorphism and igneous activity in the Sveconorwegian Belt of Scandinavia rather than true ‘Grenvillian’ events on the eastern margin of Laurentia. Previous plate tectonic reconstructions which link Laurentia and Baltica by a collisional margin extending through central East Greenland at 1.1 Ga were based on early conventional U–Pb zircon dating in central East Greenland, and can no longer be considered viable. Instead, new detrital zircon SHRIMP U–Pb dating studies show that the Krummedal supracrustal succession was deposited between ca. 1.0 Ga and no later than 0.95 Ga, during a time of major sediment deposition widely preserved elsewhere in the North Atlantic region. Erosion associated with post-1.1 Ga collapse of the Grenville–Sunsas orogeny is the most likely source for the majority of the detritus, since the corresponding Baltic margin was dominated by A-type magmatism for much of the period 1.4–1.1 Ga material, which is the age of the bulk of detrital zircons in the Krummedal supracrustal succession. We suggest that the Krummedal supracrustal succession was deposited east or south-east of its present location, and was thrust onto Archaean–Palaeoproterozoic orthogneisses, which in turn were displaced across the parautochthonous foreland during the Caledonian orogeny. The early Neoproterozoic orogenic events recorded in central East Greenland therefore involved the metamorphism of a metasedimentary package of Laurentian–Amazonian affinity during the Sveconorwegian orogeny in the final stages of the collision of Baltica and Laurentia.     

The U–Pb ages and Hf isotopes of detrital zircons from Hainan Island,South China: implications for sediment provenance and the crustal evolution

In situ U–Pb dating and Hf isotopic of detrital zircons from beach sediments of Yalong Bay were analyzed to trace sedimentary provenance and reveal the crustal evolution of Hainan Island in South China. The grain size distribution of the sediments displays a clear single-peak feature, indicating the sediments were formed under the same condition of hydrodynamic force. The detrital zircons had Th/U ratios of greater than 0.1, and REE pattern displayed a positive Ce anomaly and a negative Eu anomaly, indicating that these zircons are predominantly of magmatic origin. The U–Pb spectrum of detrital zircons mainly peaked at the Yanshanian (96–185 Ma), Hercynian–Indosinian (222–345 Ma) and Caledonian (421–477 Ma). A portion of the detrital zircons were of Neoproterozoic origin (728–1,003 Ma), which revealed that the basement in the eastern region of Hainan Island was mainly of Neoproterozoic, with rare Archean materials. The positive ε _Hf(t) values (0 to +10.1) of the Neoproterozoic detrital zircons indicated that the juvenile crust grew in the southeastern Hainan Island mainly during the Neoproterozoic period. The Neoproterozoic orogeny in the southeastern part of the island (0.7–1.0 Ga) occurred later than in the northwestern region of the island (1.0–1.4 Ga). Importantly, the Grenvillian orogeny in the southeastern area of Hainan Island shared the same timing with that of the western Cathaysia Block; i.e., both areas concurrently underwent this orogenic event, thereby forming a part of the Rodinia supercontinent. Afterwards, the crust experienced remelting and reworking during the Caledonian Hercynian–Indosinianand Yanshanian accompanied by the growth of a small amount of juvenile crust.     

青藏高原东北缘早古生代造山系中前寒武纪微陆块的再认识——兼谈原特提斯洋的起源

在青藏高原东北缘的祁连-阿尔金-昆仑早古生代造山系中,夹杂有一些前寒武纪大陆块体,这些地块的组成、性质和演化既蕴含有超大陆聚散的重要信息,也对原特提斯体系的洋陆格局、造山类型和造山机制有重要启示意义.本文综合近年来这些前寒武纪微陆块的研究进展,结合我们所获得的新的研究资料,梳理了这些前寒武纪微陆块变质基底的岩石组成、构...     

辽东岫岩地区下古生界碎屑锆石定年:罗迪尼亚和冈瓦纳超大陆在华北遗留的痕迹？

超大陆演化是地质研究的重要内容,华北克拉通与不同地质历史时期超大陆汇聚与裂解的联系对反演华北克拉通构造演化历史具有重要意义。本文在辽吉古元古代造山带中段的原划分为辽河群地层中首次识别出一套早古生代沉积建造。这套沉积建造与华北克拉通以浅海相的碳酸盐岩为主的早古生代沉积并不一致,以发育大量的陆源碎屑沉积为特征。我们对2件细砂岩分别进行了锆石LA-ICP-MS和SHRIMP U-Pb定年。定年结果显示,2件样品的最小年龄分别为～482Ma和～498Ma,反映了它们的最大沉积时代。2件样品的碎屑锆石年龄主要介于1600～500Ma,缺乏亲华北的物源信息,表明它们的物源主要来自于华北之外。2件样品年龄谱中最重要的峰值出现在格林威尔期和泛非期,表明华北克拉通曾与罗迪尼亚超大陆和冈瓦纳大陆存在联系。格林威尔期碎屑锆石可能来自于罗迪尼亚超大陆时期波罗地古陆物质在华北克拉通东缘的再循环;泛非期碎屑锆石可能来自于东冈瓦纳大陆的北缘造山带。     

High-pressure metamorphism in Antarctica from the Proterozoic to the Cenozoic: A review and geodynamic implications

The survey of high-P metamorphic rocks in Antarctica can help clarify the geodynamic evolution of the continent by pointing out palaeo-suture zones and constraining the age of subduction and collision events. There are eclogite-facies rocks along the eastern margin of the ‘Mawson block’ (e.g., in the Nimrod Glacier region and George V Land). Some of these have been long forgotten (George V Land; Eyre Peninsula in Australia). Stillwell (1918) described rocks from George V Land containing glaucophane, lawsonite, garnet coronas and symplectites possibly after omphacite. These high-P rocks were apparently involved in the Nimrod-Kimban orogenic cycle and therefore provide a record of convergence along the eastern margin of the Mawson block at ~ 1700 Ma; they could represent one of the oldest blueschist-facies imprint. Many terranes in East Antarctica underwent a tectonometamorphic evolution during the Grenvillian (1300–900 Ma) and/or the Pan-African (600–500 Ma) orogenies, corresponding to the amalgamation of Rodinia and Gondwana, respectively. High-P relicts have been described or are suspected to occur in these terranes. Garnet-bearing coronitic metagabbros, in some cases possibly containing omphacite, are common in Dronning Maud Land and the Rayner Complex. They formed under high-P granulite-facies or eclogite-facies conditions and recall similar metabasites from the Grenville mobile belt of Canada. Note that some reconstructions of the Rodinia supercontinent consider these two Antarctic regions as an extension of the Grenvillian belt of Canada. Other eclogite-facies metamorphic rocks and ophiolites (Shackleton Range and possibly Sverdrupfjella) belong to the Pan-African mobile belt extending from Tanzania to East Antarctica. Since the Cambrian, the terranes of West Antarctica have been accreted along the palaeo-Pacific margin of Gondwana/Antarctica during several subduction-accretion orogenies. The ultrahigh-P metamorphic rocks of Northern Victoria Land formed through the accretion of an arc-backarc system during the Cambrian-Ordovician Ross orogeny; eclogites of the same orogeny also exist in Tasmania and Australia. Lastly, on the western edge of the Antarctic Peninsula, the Mesozoic–Cenozoic Andean orogeny generated a subduction-accretionary complex containing blueschist-facies rocks.     

History of crustal growth and recycling at the Pacific convergent margin of South America at latitudes 29°–36° S revealed by a U–Pb and Lu–Hf isotope study of detrital zircon from late Paleozoic accretionary systems

Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The ¹⁷⁶Hf/¹⁷⁷Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic ¹⁷⁶Hf/¹⁷⁷Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system.     

Evolution of the Western Margin of Australia during the Rodinian and Gondwanan Supercontinent Cycles

The proto-Darling Fault zone and its successor, the Darling Fault, extend for 1, 000 km along the western continental margin of Australia and appear to have been active at several periods during the geological past. Deformation commenced at 2,570 Ma and affected Late Archaean granitoids along the western margin of the Yilgarn Craton. Much of the later activity reflects events related to the accretion and breakup associated with the Rodinia and Gondwanaland supercontinent cycles.In the north, rocks of the Northampton and Mullingarra Complexes form part of a high-grade Grenvillian orogenic belt lying to the west of the Darling Fault, referred to as the Pinjarra Orogen. They underwent granulite facies metamorphism 1080 Ma ago and form part of the global collisional event that resulted in the amalgamation of Rodinia. These rocks extend southward beneath Phanerozoic sedimentary cover (the Perth Basin), where they are constrained to the east by the Darling Fault and to the west by the Dunsborough Fault, the latter marking the eastern boundary of the Leeuwin Complex.The Leeuwin Complex is a fragment of Pan-African crust that has traditionally been considered part of the Pinjarra Orogen. It is composed predominantly of upper amphibolite to granulite facies felsic orthogneisses derived from A-type, anorogenic granitoids. Conventional and SHRIMP U-Pb zircon geochronology has established that the granitoids evolved between 780 Ma and 520 Ma and were metamorphosed at 615 Ma. These events are equated with rifting associated with the breakup of Rodinia. Sm-Nd whole rock data support the juvenile nature of the crust and provide no evidence for the involvement of pre-existing Archaean continental material.During the Phanerozoic, the Dunsborough and Darling Faults were reactivated, as normal faults defining the inner arm of a major rift system within Eastern Gondwanaland and controlling sedimentation in the Perth Basin that now overlies the Grenvillian terrane. Major normal movement on the Darling Fault ceased by the Late Jurassic and it appears that continental breakup in the Early Cretaceous occurred along fractures closely related to the western boundary of the Leeuwin Complex that defined the eastern margin of the outer arm of the rift system. Breakup between Australia and Greater India commenced at 132 Ma and was followed by eruption of the Bunbury Basalt at 130 Ma and 123 Ma. This possibly resulted from hot spot activity beneath Eastern Gondwanaland and may have been a reflection of the Kerguelen plume, though the evidence is equivocal.It is argued from the petrographic, geochemical and isotopic characteristics, together with the likely contiguity of the Eastern Gondwanaland continents since the assembly of Rodinia, that the Leeuwin Complex evolved within an intracrustal rift and is not an exotic terrane. It is distinct from adjacent portions of the Pinjarra Orogen and should be considered a separate terrane. It is recommended that use of the term ‘Pinjarra Orogen’ be confined to rocks recording the Grenvillian events, thereby excluding those rocks (the Leeuwin Complex) that evolved during the later Pan-African orogeny.     

Superplume, supercontinent, and post-perovskite: Mantle dynamics and anti-plate tectonics on the Core–Mantle Boundary

The Western Pacific Triangular Zone (WPTZ) is the frontier of a future supercontinent to be formed at 250 Ma after present. The WPTZ is characterized by double-sided subduction zones to the east and south, and is a region dominated by extensive refrigeration and water supply into the mantle wedge since at least 200 Ma. Long stagnant slabs extending over 1200 km are present in the mid-Mantle Boundary Layer (MBL, 410–660 km) under the WPTZ, whereas on the Core–Mantle Boundary (CMB, 2700–2900 km depth), there is a thick high-V anomaly, presumably representing a slab graveyard. To explain the D″ layer cold anomaly, catastrophic collapse of once stagnant slabs in MBL is necessary, which could have occurred at 30–20 Ma, acting as a trigger to open a series of back-arc basins, hot regions, small ocean basins, and presumably formation of a series of microplates in both ocean and continent. These events were the result of replacement of upper mantle by hotter and more fertile materials from the lower mantle.The thermal structure of the solid Earth was estimated by the phase diagrams of Mid Oceanic Ridge Basalt (MORB) and pyrolite combined with seismic discontinuity planes at 410–660 km, thickness of the D″ layers, and distribution of the ultra-low velocity zone (ULVZ). The result clearly shows the presence of two major superplumes and one downwelling. Thermal structure of the Earth seems to be controlled by the subduction history back to 180 Ma, except in the D″ layer. The thermal structure of the D″ layer seems to be controlled by older slab-graveyards, as expected by paleogeographic reconstructions for Laurasia, Gondwana and Rodinia back to 700 Ma.Comparison of mantle tomography between the Pacific superplume and underneath the WPTZ suggests the transformation of a cold slab graveyard to a large-scale mantle upwelling with time. The Pacific superplume was born from the coldest CMB underneath the 1.0–0.75 Ga supercontinent Rodinia where huge amounts of cold slabs had accumulated through collision-amalgamation of more than 12 continents. A high velocity P-wave anomaly on a whole-mantle scale shows stagnant slabs restricted to the MBL of circum-Pacific and Tethyan regions. The high velocity zones can be clearly identified within the Pacific domain, suggesting the presence of slab graveyards formed at geological periods much older than the breakup of Rodinia. We speculate that the predominant subduction occurred through the formation period of Gondwana, presumably very active during 600 to 540 Ma period, and again from 400 to 300 Ma during the formation of the northern half of Pangea (Laurasia). We correlate the three dominant slab graveyards with three major orogenies in earth history, with the emerging picture suggesting that the present-day Pacific superplume is located at the center of the Rodinian slab graveyard.We speculate the mechanism of superplume formation through a comparison of the thermal structure of the mantle combined with seismic tomography under the Western Pacific Triangular Zone (WPTZ), Laurasia (Asia), Gondwana (Africa), and Rodinia (Pacific). The coldest mantle formed by extensive subduction to generate a supercontinent, changes with time of the order of several hundreds of million years to the hottest mantle underneath the supercontinent. The Pacific superplume is tightly defined by a steep velocity gradient on the margin, particularly well documented by S-wave velocity. The outermost region of the superplume is characterized by the Rodinia slab graveyard forming a donut-shape. We develop a petrologic model for the Pacific superplume and show how larger plumes are generated at shallower depths in the mantle. We link the mechanism of formation of the superplume to the presence of the mineral post-perovskite, the phase transformation of which to perovskite is exothermic, and thus aids in transporting core heat to mantle, and finally to planetary space by plumes.We summarize the characteristics of tectonic processes operating at the CMB to propose the existence of an “anti-crust” generated through “anti-plate tectonics” at the bottom of the mantle. The chemistry of the anti-crust markedly contrasts with that of the continental crust overlying the mantle. Both the crust and the anti-crust must have increased in volume through geologic time, in close relation with the geochemical reservoirs of the Earth. The process of formation of a new superplume closely accompanies the process of development of anti-crust at the bottom of mantle, through the production of dense melt from the partial melting of recycled MORB, observed now as the ULVZ. When CMB temperature is recovered to near 4000 K through phase transformation, the recycled MORB is partially melted imparting chemical buoyancy of the andesitic residual solid which rises up from CMB, leaving behind the dense melt to sink to CMB and thus increase the mass of anti-crust. These small-scale plumes develop to a large-scale superplume through collision and amalgamation with time. When all recycled MORBs are consumed, it is the time of demise of superplume. Immediately above the CMB, anti-plate tectonics operates to develop anti-crust through the horizontal movement of accumulated slab and their partial melting. Thus, we speculate that another continent, or even a supercontinent, has developed through geologic time at the bottom of the mantle.We also evaluate the heating vs. cooling models in relation to mantle dynamics. Rising plumes control not only the rifting of supercontinents and continents, but also the Atlantic stage as seen by anchored ridge by hotspots in the last 200 Ma in the Atlantic. Therefore, we propose that the major driving force for the mantle dynamics is the heat supplied from the high-T core, and not the slab pull force by cooling. The best analogy for this is the atmospheric circulation driven by the energy from Sun.     

SHRIMP zircon U–Pb geochronological and whole-rock geochemical evidence for an early Neoproterozoic Sibaoan magmatic arc along the southeastern margin of the Yangtze Block

It has been generally accepted that the South China Block was formed through amalgamation of the Yangtze and Cathaysia Blocks during the Proterozoic Sibaoan orogenesis, but the timing and kinematics of the Sibao orogeny are still not well constrained. We report here SHRIMP U–Pb zircon geochronological and geochemical data for the Taohong and Xiqiu tonalite–granodiorite stocks from northeastern Zhejiang, southeastern margin of the Yangtze Block. Our data demonstrate that these rocks, dated at 913 ± 15 Ma and 905 ± 14 Ma, are typical amphibole-rich calc-alkaline granitoids formed in an active continental margin. Combined with previously reported isotopic dates for the  1.0 Ga ophiolites and  0.97 Ga adakitic rocks from northeastern Jiangxi, the timing of the Sibao orogenesis is thus believed to be between  1.0 and  0.9 Ga in its eastern segment. It is noted that the Sibao orogeny in South China is in general contemporaneous with some other early Neoproterozoic (1.0–0.9 Ga) orogenic belts such as the Eastern Ghats Belt of India and the Rayner Province in East Antarctica, indicating that the assembly of Rodinia was not finally completed until  0.9 Ga.     

新疆库鲁克塔格成矿带主要矿床类型及成矿系列划分

库鲁克塔格是新疆前寒武纪出露较全的地区,然而该区区域成矿规律研究程度非常低.通过对研究区已有资料进行总结分析,系统阐述研究区矿床类型,并对其成矿系列进行划分.研究区从太古代到早古生代形成了7个主要的岩浆构造演化阶段:古太古代陆核形成阶段(3.3~3.0 Ga)、新太古代-古元古代陆壳增生改造阶段(2.6~2.3 Ga)、古元古代中晚期陆壳改造阶段(2.1~1.8 Ga)、中元古代晚期-新元古代早期造山运动阶段(1.1~0.86 Ga)、新元古代中期后碰撞伸展阶段(830~800 Ma)、新元古代中晚期陆内裂解阶段(770~600 Ma)和早古生代造陆运动阶段.成矿作用主要发生在古元古代、新元古代及早古生代.依据各构造演化阶段、含矿建造特征及矿床成因特征,将库鲁克塔格成矿作用类型总结为以下6个主要成矿系列,即形成于古元古代陆壳增生改造环境下的Fe-P-Cu-Au系列、新元古代俯冲碰撞环境下的Cu-Au系列、新元古代后碰撞环境下的Cu-Mo-Au-Fe-P-REE系列、新元古代裂解环境下的Cu-Ni系列、早古生代沉积盆地中Ag-V-Mo-Au-U-P系列和早古生代俯冲岛弧环境下的Cu-Au系列.      

Tectonic evolution,superimposed orogeny,and composite metallogenic system in China

Continental China is a mosaic of numerous tectonic blocks, which amalgamated from Neoarchean to Cenozoic broadly coeval with the cycles of global supercontinents such as Kenorland, Columbia, Rodinia, Gondwana, and Pangaea. By reviewing the long-lasting geological evolution in the different tectonic blocks, it reveals that more than two episodes of tectonic events, including accretionary and collisional orogeny, and dismantling, as well as mantle plume, occurred successively or simultaneously within a single tectonic belt. This is called superimposed orogeny in this study. Examples of the dominant types of superimposed orogeny in China include: (1) Cenozoic continental collision superimposed on Paleo- to Mesozoic accretionary orogeny in the Tibet and Sanjiang orogenic belts; (2) Reactivation of Paleozoic accretionary orogen in later Mesozoic oceanic subduction in the eastern part of Qinling–Qilian–Kunlun and Central Asian orogenic belts; (3) Mesozoic oceanic subduction under the paleo-suture in the South China Block; (4) Mesozoic demantling along the Paleo- and Neoproterozoic, and Paleozoic sutures in the eastern part of North China Craton; and (5) mantle plume rising through metasomatized lithospheric mantle or stagnant oceanic slab in the Emeishan large igneous province. A comprehensive review of the spatial-temporal distribution of ore deposits and their salient features shows that the superimposed orogeny has exerted significant control on metallogeny in China. The giant porphyry and skarnore deposits, as well as orogenic gold deposits were preferentially formed along previous tectonic suture, craton margin, and arc during later orogenesis due to the remobilization of previously enriched metals. Superimposed orogeny has reworked the lithospheric structure with concomitant granitoid-associated metallogeny. The mixing of magmas from juvenile lower crust, ancient lower crust, and middle crust, which tends to induce the different mineralization of Cu–Au, Mo, and Pb–Zn–W–Sn deposits respectively, was considered to generate a wide variety of combinations of metal species. The superimposed orogeny caused the overlapping of diverse genetic types of deposit formed in different tectonic periods in the same tectono-metallogenic belt. The stratiform ore deposit, including BIF, VMS, SEDEX, or sedimentary sulfide layers, formed from Neoarchean to Paleozoic, were modified by later mineralization, resulting in the enrichment of the various metal species and enhancement of ore resources. This study brings up the concept of composite metallogenic system to summarize the regional metallogeny driven by superimposed orogeny. The composite metallogenic system was dominantly characterized by the multi-episodic and diverse mineralization concomitant with one or more features, including mineralization evolved from the previous metal enrichment, later overlapping or modification on previous ore belt, and diversifying of metal species derived from reworked lithosphere.     

Models on Snowball Earth and Cambrian explosion: A synopsis

During the late Proterozoic from 1000 to 542 Ma, the Earth is thought to have been frozen at least during two times: in the Sturtian (715–680 Ma) and in the Marinoan (680–635 Ma) global glaciations. Following the Marinoan Snowball Earth, large multi-cellular animals of the Ediacara fauna flourished as a prelude to the Phanerozoic world. Here we summarize the most popular models on the cause and cessation of Snowball Earth. Episodic decrease of greenhouse gas occurs through the effect of erosion and weathering promoted by either mountain building or by an increase in the coastlines during the break-up of supercontinents. Effects on the globe caused by true polar wander, eruption of voluminous flood basalts, or dramatic reduction in planetary obliquity can also lead to ice ages and mass extinction. A radically revised concept based on Earth's magnetic intensity has also been proposed, which explains the true polar wander through a quasi-polar dynamo model. The ‘switch-on’ and ‘switch-off’ of the Earth's strong dynamo can lead to the onset and disappearance of the Snowball Earth. The galactic model infers that gamma ray burst associated with starburst creates huge amounts of clouds which would cut off sun rays and freeze the Earth.The Snowball Earth event is considered to have exerted a significant control on the subsequent revolutionary changes in the evolution of life forms. Although according to the biological clock, extensive re-organisation of genome is thought to have been completed by around 900 Ma, the evolution of modern life in Cambrian occurred only after the geochemical bridge was in place with elevated oxygen and nutrient levels in lakes that developed within continental rifts where the hydrothermal system in the granitic basement created the chemical environment enriched in Ca²⁺, Fe²⁺, V, Mo, HCO₃, phosphate and other elements required for building the skeleton and bone of the first modern animals. With cosmic radiation exerting a significant control on the mutation, the Neoproterozoic Earth history illustrates the possible link from Galaxy to the genome level.     

Neoproterozoic—Early Paleozoic evolution of peri-Gondwanan terranes: implications for Laurentia-Gondwana connections

Neoproterozoic tectonics is dominated by the amalgamation of the supercontinent Rodinia at ca. 1.0 Ga, its breakup at ca. 0.75 Ga, and the collision between East and West Gondwana between 0.6 and 0.5 Ga. The principal stages in this evolution are recorded by terranes along the northern margin of West Gondwana (Amazonia and West Africa), which continuously faced open oceans during the Neoproterozoic. Two types of these so-called peri-Gondwanan terranes were distributed along this margin in the late Neoproterozoic: (1) Avalonian-type terranes (e.g. West Avalonia, East Avalonia, Carolina, Moravia-Silesia, Oaxaquia, Chortis block that originated from ca. 1.3 to 1.0 Ga juvenile crust within the Panthalassa-type ocean surrounding Rodinia and were accreted to the northern Gondwanan margin by 650 Ma, and (2) Cadomian-type terranes (North Armorica, Saxo-Thuringia, Moldanubia, and fringing terranes South Armorica, Ossa Morena and Tepla-Barrandian) formed along the West African margin by recycling ancient (2–3 Ga) West African crust. Subsequently detached from Gondwana, these terranes are now located within the Appalachian, Caledonide and Variscan orogens of North America and western Europe. Inferred relationships between these peri-Gondwanan terranes and the northern Gondwanan margin can be compared with paleomagnetically constrained movements interpreted for the Amazonian and West African cratons for the interval ca. 800–500 Ma. Since Amazonia is paleomagnetically unconstrained during this interval, in most tectonic syntheses its location is inferred from an interpreted connection with Laurentia. Hence, such an analysis has implications for Laurentia-Gondwana connections and for high latitude versus low latitude models for Laurentia in the interval ca. 615–570 Ma. In the high latitude model, Laurentia-Amazonia would have drifted rapidly south during this interval, and subduction along its leading edge would provide a geodynamic explanation for the voluminous magmatism evident in Neoproterozoic terranes, in a manner analogous to the Mesozoic-Cenozoic westward drift of North America and South America and subduction-related magmatism along the eastern margin of the Pacific ocean. On the other hand, if Laurentia-Amazonia remained at low latitudes during this interval, the most likely explanation for late Neoproterozoic peri-Gondwanan magmatism is the re-establishment of subduction zones following terrane accretion at ca. 650 Ma. Available paleomagnetic data for both West and East Avalonia show systematically lower paleolatitudes than predicted by these analyses, implying that more paleomagnetic data are required to document the movement histories of Laurentia, West Gondwana and the peri-Gondwanan terranes, and test the connections between them.