The carbon isotope composition of C<Superscript>3</Superscript> herbaceous plants in loess area of northern China

¹³C of 367 C₃ herbaceous plants was measured in loess area in northern China. Their δ¹³C values vary between −21.7%. and −30.0%., with a mean of −26.7%.. In the center of Loess Plateau (semimoist area) with annual precipitation of 400–600 mm, the δ¹³ C values of C₃ herbaceous plants range from −24.4%. to −28.5%., with a mean of −27.5%.. In the west of Loess Plateau (semiarid and arid area) with annual precipitation less than 400 mm, they range between −21.7%. and −30.0%., with a mean of −26.2%.. Annual precipitation is the main factor that makes δ¹³C values of C₃ herbaceous plants in the west greater than those in the central Loess Plateau. The composition of δ¹³C in C₃ plants increases with deceasing annual precipitation, and the mean change is −49%./100 mm.     

Carbon isotope ratios of C_4 plants in loess areas of North China

Recent stable carbon isotope studies have shown that the occurrence of C4 plants on the Earth was much later than that of C3 plants and there was a global ex-pansion of C4 biomass around 5―8 million years ago[1]. Although far fewer species use the C4 pat…     

贵州草海湖泊系统碳循环简单模式

本文分析了贵州草海湖泊系统中的主要含碳物质－湖水DIC、表层沉积物有机质、水生植物的稳定碳同位素组成,其δ^13C值分别为：－3．70‰至－10．60‰,－20．90‰至－21．60％,－16．10‰至－17．40,通过质量平衡计算,建立了草海区域碳循环的简单模式,结果表明：对于草海这样一个水生植物茂盛的浅水富氧湖而言,光合一呼吸作用和有机质的降解对整个湖泊体系的稳定碳同位素组成具有决定性的作用。     

Distribution and sources of sedimentary organic matter in a tropical estuary,south west coast of India (Cochin estuary): A baseline study

Surface sediments samples were collected from 9 stations of the Cochin estuary during the monsoon, post-monsoon and pre-monsoon seasons and were analyzed for grain size, total organic carbon (OC), total nitrogen (TN) and stable isotopic ratios of carbon (δ¹³C) and nitrogen (δ¹⁵N) to identify major sources of organic matter in surface sediments. Sediment grain size is found to be the key factor influencing the organic matter accumulation in surface sediments. The δ¹³C values ranges from ?27.5‰ to ?21.7‰ in surface sediments with a gradual increase from inner part of the estuary to the seaward side that suggest an increasing contribution of marine autogenous organic matter towards the seaward side. The δ¹⁵N value varies between 3.1‰ and 6.7‰ and it exhibits complex spatial and seasonal distributions in the study area. It is found that the dynamic cycling of nitrogen through various biogeochemical and organic matter degradation processes modifies the OC/TN ratios and δ¹⁵N to a considerable degree. The fraction of terrestrial organic matter in the total organic matter pool ranges from 13% to 74% in the surface sediments as estimated by δ¹³C based two end member mixing model.     

天山黄土区与黄土高原表土磁性特征对比及环境意义

本文对黄土高原和天山黄土区表土进行系统的岩石磁学和粒度测试分析,探讨了表土磁性特征及其环境意义,结果表明表土中的强磁性矿物均为磁铁矿和磁赤铁矿,弱磁性矿物为赤铁矿和纤铁矿或针铁矿,黄土高原黄土地层中的磁赤铁矿至少有部分属于风积成因.黄土高原表土中磁化率与频率磁化率呈良好的正相关,气候作用是主导黄土高原表上磁化率增强的主...     

Moisture origin and stable isotope characteristics of precipitation in southeast Siberia

The paper presents oxygen and hydrogen isotopes of 284 precipitation event samples systematically collected in Irkutsk, in the Baikal region (southeast Siberia), between June 2011 and April 2017. This is the first high-resolution dataset of stable isotopes of precipitation from this poorly studied region of continental Asia, which has a high potential for isotope-based palaeoclimate research. The dataset revealed distinct seasonal variations: relatively high δ¹⁸O (up to −4‰) and δD (up to −40‰) values characterize summer air masses, and lighter isotope composition (−41‰ for δ¹⁸O and −322‰ for δD) is characteristic of winter precipitation. Our results show that air temperature mainly affects the isotope composition of precipitation, and no significant correlations were obtained for precipitation amount and relative humidity. A new temperature dependence was established for weighted mean monthly precipitation: +0.50‰/°C (r² = 0.83; p <.01; n = 55) for δ¹⁸O and +3.8‰/°C (r² = 0.83, p < 0.01; n = 55) for δD. Secondary fractionation processes (e.g., contribution of recycled moisture) were identified mainly in summer from low d excess. Backward trajectories assessed with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model indicate that precipitation with the lowest mean δ¹⁸O and δD values reaches Irkutsk in winter related to moisture transport from the Arctic. Precipitation originating from the west/southwest with the heaviest mean isotope composition reaches Irkutsk in summer, thus representing moisture transport across Eurasia. Generally, moisture transport from the west, that is, the Atlantic Ocean predominates throughout the year. A comparison of our new isotope dataset with simulation results using the European Centre/Hamburg version 5 (ECHAM5)-wiso climate model reveals a good agreement of variations in δ¹⁸O (r² = 0.87; p <.01; n = 55) and air temperature (r² = 0.99; p <.01; n = 71). However, the ECHAM5-wiso model fails to capture observed variations in d excess (r² = 0.14; p < 0.01; n = 55). This disagreement can be partly explained by a model deficit of capturing regional hydrological processes associated with secondary moisture supply in summer.     

Carbon isotopic composition of modern soil and paleosol as a response to vegetation change on the Chinese Loess Plateau

The relationship between the carbon isotopic composition of paleosols and pale-ovegetation on the Loess Plateau is still unclear. One of the main reasons is that we are short of knowledge about the characteristics of the carbon isotopic composition of modern soil in this area. A preliminary investigation of the carbon isotopic compositions of the modern soil and the loess/paleosol sequence on the Loess Plateau shows that the carbon isotopic composition of modern soil is consistent with the distribution of modern plants on the Loess Plateau, where the ecosystem is dominated by a mixture of C4 and C3 plants. Comparing the δ13C values of modern soil and loess-paleosol sequences from the Xunyi profile, we conclude that C3 plants dominated the landscape during loess sediment stages, while C4 plants expanded during paleosol stages.     

Water isotopes and hydrograph separation in different glacial catchments in the southeast margin of the Tibetan Plateau

Snow and glaciers are known to be important sources for freshwater; nevertheless, our understanding of the hydrological functioning of glacial catchments remains limited when compared with lower altitude catchments. In this study, a temperate glacial region located in the southeast margin of the Tibetan Plateau is selected to analyse the characteristics of δ¹⁸O and δD in different water sources and the contribution of glacier–snow meltwater to streamflow. The results indicate that the δ¹⁸O of river water ranges from ?16.2‰ to ?10.2‰ with a mean of ?14.1‰ and that the δD values range from ?117.0‰ to ?68.0‰ with a mean of ?103.1‰. These values are more negative than those of glacier–snow meltwater but less negative than those of precipitation. The d ‐excess values are found to decrease from meltwater to river to lake/reservoir water as a result of evaporation. On the basis of hydrograph separation, glacier–snow meltwater accounts for 51.5% of river water in the Baishui catchment in the melting season. In the Yanggong catchment, snow meltwater contributes 47.9% to river water in the premonsoon period, and glacier meltwater contributes only 6.8% in the monsoon period. The uncertainty in hydrograph separation is sensitive to the variation of tracer concentrations of streamflow components. The input of meltwater to a water system varies with local climate and glacier changes. The results confirm that hydrograph separation using water isotopes is valuable for evaluating the recharge sources of rivers, especially in ungauged glacial regions. This study provides insights into the hydrological processes of glacial catchments on the Tibetan Plateau, which is important for water resource management.     

Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.     

Estimating the criterion for determining water vapour sources of summer precipitation on the northern Tibetan Plateau

According to the precipitation and δ¹⁸O data obtained during the GEWEX Asian Monsoon Experiment–Tibet Intensive Observation Period, based on the knowledge that δ¹⁸O is lower in precipitation formed from ocean air mass vapour than that from local evaporation vapour, the water vapour sources can be identified from the δ¹⁸O values in precipitation. We attempt to give the identification criterion of δ¹⁸O values in precipitation. The threshold values chosen to distinguish between ocean and local sources are δ¹⁸O < ?20‰ and δ¹⁸O > ?13‰ respectively. According to this criterion, the proportion of local evaporation‐formed precipitation and ocean air‐mass‐formed precipitation in total precipitation was estimated. The average value of precipitation at three sites (NODA, Amdo and AQB) is 249·76 mm. Among this, precipitation formed directly by the ocean air mass vapour is 80·08 mm at most. Precipitation formed by water vapour evaporated from local places is 117·05 mm at least. That is to say that precipitation formed directly by the ocean air mass vapour accounts for 32·06% of the total precipitation at most. Precipitation formed by water vapour evaporated from local places accounts for 46·86% of the total precipitation at least. At least 21·8% of the total precipitation came from water vapour that was evaporated on the way and transported by the monsoon circulation. Copyright © 2005 John Wiley & Sons, Ltd.     

Tropical precipitation anomalies and d‐excess evolution during El Niño 2014‐16

The last 2014‐16 El Niño event was among the three strongest episodes on record. El Niño considerably changes annual and seasonal precipitation across the tropics. Here, we present a unique stable isotope data set of daily precipitation collected in Costa Rica prior to, during, and after El Niño 2014‐16, in combination with Lagrangian moisture source and precipitation anomaly diagnostics. δ²H composition ranged from ‐129.4 to +18.1 (‰) while δ¹⁸O ranged from ‐17.3 to +1.0 (‰). No significant difference was observed among δ¹⁸O (P=0.186) and δ²H (P=0.664) mean annual compositions. However, mean annual d‐excess showed a significant decreasing trend (from +13.3 to +8.7 ‰) (P<0.001) with values ranging from +26.6 to ‐13.9 ‰ prior to and during the El Niño evolution. The latter decrease in d‐excess can be partly explained by an enhanced moisture flux convergence across the southeastern Caribbean Sea coupled with moisture transport from northern South America by means of an increased Caribbean Low Level Jet regime. During 2014‐15, precipitation deficit across the Pacific domain averaged 46% resulting in a very severe drought; while a 94% precipitation surplus was observed in the Caribbean domain. Understanding these regional moisture transport mechanisms during a strong El Niño event may contribute to a) better understanding of precipitation anomalies in the tropics and b) re‐evaluate past stable isotope interpretations of ENSO events in paleoclimatic archives within the Central America region.     

Variations of δ18O in precipitation from the Muztagata Glacier, East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ18O in precipitation displays a wide range, varying from -17.40‰ to +1.33‰ in June-September 2002 and from -22.31‰ to +4.59‰ in May-August 2003. The δ18O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ18O and tem- perature suggests that δ18O can be used as an indicator of temperature in this region. The δ18O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong "altitude effect", with a ratio of nearly -0.40‰ per 100 m from 5500 m to 7450 m.     

Feedbacks between vegetation restoration and local precipitation over the Loess Plateau in China

The implementation of large-scale vegetation restoration over the Chinese Loess Plateau has achieved clear improvements in vegetation fraction, as evidenced by large areas of slopes and plains being restored to grassland or forest.However, such large-scale vegetation restoration has altered land-atmosphere exchanges of water and energy, as the land surface characteristics have changed. These variations could affect regional climate, especially local precipitation. Quantitatively evaluating this feedback is an important scientific question in hydrometeorology. This study constructs a coupled land-atmosphere model incorporating vegetation dynamics, and analyzes the spatio-temporal changes of different land use types and land surface parameters over the Loess Plateau. By considering the impacts of vegetation restoration on the water-energy cycle and on land-atmosphere interactions, we quantified the feedback effect of vegetation restoration on local precipitation across the Loess Plateau, and discussed the important underlying processes. To achieve a quantitative evaluation, we designed two simulation experiments, comprising a real scenario with vegetation restoration and a hypothetical scenario without vegetation restoration.These enabled a comparison and analysis of the net impact of vegetation restoration on local precipitation. The results show that vegetation restoration had a positive effect on local precipitation over the Loess Plateau. Observations show that precipitation on the Loess Plateau increased significantly, at a rate of 7.84 mm yr~(-2), from 2000 to 2015. The simulations show that the contribution of large-scale vegetation restoration to the precipitation increase was about 37.4%, while external atmospheric circulation changes beyond the Loess Plateau contributed the other 62.6%. The average annual precipitation under the vegetation restoration scenario over the Loess Plateau was 12.4% higher than that under the scenario without vegetation restoration. The above research results have important theoretical and practical significance for the ecological protection and optimal development of the Loess Plateau, as well as the sustainable management of vegetation restoration.     

13C/12C ratios of rocks and inclusions in popping rocks of the Mid-Atlantic Ridge and their bearing on the problem of isotopic composition of deep-seated carbon

CO₂-rich inclusions recovered from “popping” and related tholeiitic rocks from the Mid-Atlantic Ridge have δ¹³C values of ?7.6 ± 0.5%. relative to PDB. δ¹³C values of total carbon in the same rocks range from ?12 to ?13.7‰. These values are discussed in the light of the known δ¹³C variations in rocks of deep-seated origin. The ?7.6‰ value is interpreted as a reasonable estimate of the primary value of δ¹³C of deep-seated carbon in the ridge area.     

Spatiotemporal characteristics of precipitation and extreme events on the Loess Plateau of China between 1957 and 2009

Spatiotemporal trends in precipitation may influence vegetation restoration, and extreme precipitation events profoundly affect soil erosion processes on the Loess Plateau. Daily data collected at 89 meteorological stations in the area between 1957 and 2009 were used to analyze the spatiotemporal trends of precipitation on the Loess Plateau and the return periods of different types of precipitation events classified in the study. Nonparametric methods were employed for temporal analysis, and the Kriging interpolation method was employed for spatial analysis. The results indicate a small decrease in precipitation over the Loess Plateau in last 53 years (although a Mann–Kendall test did not show this decrease to be significant), a southward shift in precipitation isohyets, a slightly delayed rainy season, and prolonged return periods, especially for rainstorm and heavy rainstorm events. Regional responses to global climate change have varied greatly. A slightly increasing trend in precipitation in annual and sub‐annual series, with no obvious shift of isohyets, and an evident decreasing trend in extreme precipitation events were detected in the northwest. In the southeast, correspondingly, a more seriously decreasing trend occurred, with clear shifts of isohyets and a slightly decreasing trend in extreme precipitation events. The result suggests that a negative trend in annual precipitation may have led to decreased soil erosion but an increase in sediment yield during several extreme events. These changes in the precipitation over the Loess Plateau should be noted, and countermeasures should be taken to reduce their adverse impacts on the sustainable development of the region. Copyright © 2013 John Wiley & Sons, Ltd.     

Extreme short‐term stable isotope variability revealed by continuous rainwater analysis

The continuous real‐time analysis, at 30‐s intervals, of precipitation at an Australian tropical location revealed extreme and rapidly changing δ¹⁸O and δD values related to variations in moisture source areas, transport paths and precipitation histories. The range of δ¹⁸O (?19.6‰ to +2.6‰) and δD (?140‰ to +13‰) values from 5948 measurements of nine rain events over 15 days during an 8‐month period at a single location was comparable with the range measured in 1532 monthly samples from all seven Australian Global Network of Isotopes in Precipitation stations from 1962 to 2002. Extreme variations in δ¹⁸O (?8.7‰ to ?19.6‰) and δD (?54‰ to ?140‰) were recorded within a single 4‐h period. Real‐time stable isotope monitoring of precipitation at a high temporal resolution enables new and powerful tracer applications in climatology, hydrology, ecophysiology and palaeoclimatology. Copyright © 2012 John Wiley & Sons, Ltd.     

An isotopic calibration study of precipitation,cave dripwater,and climate in west‐central Florida

A calibration study of oxygen and hydrogen isotopic composition from precipitation and cave dripwater was conducted in west‐central Florida at Legend Cave during 2007–2008. This study was performed to better understand how modern precipitation patterns can be discerned through examination of cave dripwater and speleothem calcite for paleoclimate reconstruction. The ‘amount effect’ was shown to be a dominant control on the oxygen isotopic composition of precipitation for the study area. A meteoric water line with a slope of 6·7 suggests evaporative effects occur either during precipitation or subsequent hydrological processes. However, δ¹⁸O values of cave dripwater averaged near the mean annual amount‐weighted average of precipitation, suggesting that the isotopic composition of dripwater tracks the long‐term average of rainfall. An observed weak seasonal influence occurred in the d‐excess values, with summer precipitation being more enriched due to increased evaporative effects. Comparison of precipitation δ¹⁸O values to synoptic weather data shows the dominant amount effect influence occurs due to strong convective storms producing highly ¹⁸O‐depleted rainfall at greater amounts during the year. Constant δ¹⁸O values of the dripwater indicate that paleoclimate reconstructions using speleothems from this area would record changes in annual to interannual shifts in precipitation amount above the cave. Copyright © 2011 John Wiley & Sons, Ltd.     

若尔盖盆地兴措湖沉积记录揭示的近代气候与环境

依据湖泊沉积记录进行古气候环境要素定量的是过去全球变化研究的重要内容,本文通过若尔盖盆地兴措湖近代湖泊沉积特征、沉积物总有机碳及其同位素指标分析,并与器测气象资料进行比较,对兴措湖泊近代湖泊沉积物中有机碳及其同位素指标所代表的气候环境信息进行了定量研究,在此基础上,建立了兴措湖沉积物总有机碳及其同位素记录与对应的降水和气温间的函数关系,为定量恢复该区长尺度历史时期古气候环境特征提供了基础。     

Hydrological responses to conservation practices in a catchment of the Loess Plateau,China

Since the late 1950s a series of soil conservation practices have been implemented in the Loess Plateau. It is important to assess the impact of these practices on hydrology at the catchment scale. The Jialuhe River catchment, a tributary of the Yellow River, with a drainage area of 1117 km² in the Loess Plateau, was chosen to investigate the hydrological responses to conservation practices. Parametric and non‐parametric Mann–Kendall tests were utilized to detect trends in hydrological variables or their residuals. Relationships between precipitation and hydrological variables were developed to remove the impact of precipitation variability. Significant linear decreasing trends in annual surface runoff and baseflow were identified during the treated period from 1967 to 1989, and the rate of reduction was 1·30 and 0·48 mm/year, respectively. As result, mean annual surface runoff and baseflow decreased by 32% over the period of 1967 to 1989. Seasonal runoff also decreased during the treated period with the greatest reduction occurring in summer and the smallest reduction in winter. The response of high and low daily flow to conservation practices was greater than average flows. Copyright © 2004 John Wiley & Sons, Ltd.     

Fluid mixing as the mechanism of formation of the Dajing Cu-Sn-Ag-Pb-Zn ore deposit,Inner Mongolia ——Fluid inclusion and stable isotope evidence

Since the 1990s, interest in the magmatic fluids and their relation to mineralization has been re-aroused[1—6]. Studies on stable isotopes of low-sulfidation deposits commonly show the predominance of meteoric water[7]. Paradoxically, the evidence for me…