Retrograded textures and associated mass transfer: evidence for aqueous fluid action during exhumation of the Qinglongshan eclogite, Southern Sulu ultrahigh pressure metamorphic terrane, eastern China

The Qinglongshan eclogites in the Southern Sulu ultrahigh pressure metamorphic (UHPM) terrane show very different retrograded textures from their counterparts in the Northern Sulu terrane, implying a different thermal history. Scanning electron and optical microscope observations indicate that the peak assemblage of the Qinglongshan eclogite is anhydrous, composed of Grt + OmpI + Rt + (Ky + coesite). These primary minerals were replaced by second and third stage minerals, resulting in symplectite pseudomorphs or coronas. The following relationships are inferred: OmpI → OmpII + Ab + Fe‐oxide symplectite (type I) and Rt → Rt + Ilm intergrowth; and, Ky → Pg, OmpII (+Pl) → Amp (+Pl) symplectite (type II), and Grt → Prg (+Fe‐oxide). Mineral chemistry and mass‐balance demonstrate that the pseudomorphed textures were developed by metasomatism involving dissolution and precipitation intensified by fluids along grain boundaries. The formation of symplectite type I produced Fe, Mg and Na but consumed Ca and Si. The Mg and Fe diffused to garnet where exchange of (Mg, Fe) with Ca of the garnet resulted in compositional zonation with decreased Ca towards the edge of garnet grains where Ca was consumed during symplectite formation. The replacement of kyanite by paragonite consumed the extra Na. In the later stage, fluid infiltration partially transformed symplectite type I to type II, and narrow rims of pargasite resorbed garnet from their boundaries. Mass balance suggests that the transformation and resorption would have been coupled during fluid infiltration. In the latest stage, epidote and quartz were precipitated at very late stage as a result of fluid activity along microfractures. Tentative P–T conditions based on mineral reactions and thermocalc software suggest that the retrograded eclogite did not record the granulite facies retrograde evolution characteristic of eclogites from the Northern Sulu terrane. The difference in retrograde evolution between the Southern and Northern Sulu eclogites suggests a different exhumation history.     

SHRIMP U–Pb dating of coesite-bearing zircon from the ultrahigh-pressure metamorphic rocks, Sulu terrane, east China

This paper provides further evidence for the ongoing discussion as to whether the Dabie UHPM belt formed in Triassic or Palaeozoic time, and whether the Sulu UHPM belt formed in Triassic or Neoproterozoic time. Combined use of laser Raman spectrometer (LR), cathodoluminescence imaging (CL), and ion probe U–Pb in‐situ dating (SHRIMP) provided accurate ages of UHPM from rocks collected from Weihai, NE Sulu UHPM belt. LR was used to identify coesite and other UHP minerals as inclusions in zircon separates from an amphibolized peridotite and an eclogite. CL was used to examine the zoning structure of these zircon, and SHRIMP dating was performed on specific spots on zircon to obtain ages of different geological events. An age of 221 ± 12 Ma was obtained for coesite‐bearing zircon from the amphibolized peridotite; an age of 228 ± 29 Ma for eclogite was obtained from the lower intercept of a concordia plot. These ages are interpreted as the time of UHPM in the Weihai region. Ultramafic rocks to the east of Weihai yield a magmatic age at 581 ± 44 Ma. The zircon in the ultramafic rocks possibly also records a thermal event at c. 400 Ma, but no independent geological evidence for this event has been found. The eclogite protolith formed in the Middle Proterozoic (1821 ± 19 Ma), which is similar to the age of country rock gneisses of 1847–1744 Ma. The new geochronological data confirm that UHPM occurred in the Triassic in the Sulu area when subduction took the ultramafic body and the eclogite protolith, together with the adjacent supracrustal rocks, to mantle depths.     

Partial transformation of gabbro to coesite-bearing eclogite from Yangkou, the Sulu terrane, eastern China

An ultra-high-pressure (UHP) metamorphic slab at Yangkou Beach near Qingdao in the Sulu region of China consists of blocks of eclogite facies metagabbro, metagranitoid, ultramafic rock and mylonitic orthogneisses enclosed in granitic gneiss. A gradational sequence from incipiently metamorphosed gabbro to completely recrystallized coesite eclogite formed at ultra-high-pressures was identified in a single 30 m block; metagabbro is preserved in the core whereas coesite eclogite occurs along the block margins. The metagabbro contains an igneous assemblage of Pl+Aug+Opx+Qtz+Bt+Ilm/Ti-Mag; it shows relict magmatic textures and reaction coronas. Fine-grained garnet developed along boundaries between plagioclase and other phases; primary plagioclase broke down to Ab+Ky+Ms+Zo±Grt±Amp. Augite is rimmed by sodic augite or omphacite, whereas orthopyroxene is rimmed by a corona of Cum±Act and Omp+Qtz layers or only Omp+Qtz. In transitional rocks, augite and orthopyroxene are totally replaced by omphacite, and the lower-pressure assemblage Ab+Ky+Phn+Zo+Grt coexists with domains of Omp (Jd_70–73)+Ky±Phn in pseudomorphs after plagioclase. Both massive and weakly deformed coesite-bearing eclogites contain Omp+Ky+Grt+Phn+Coe/Qtz+Rt, and preserve a faint gabbroic texture. Coesite inclusions in garnet and omphacite exhibit limited conversion to palisade quartz; some intergranular coesite and quartz pseudomorphs after coesite also occur. Assemblages of the coronal stage, transitional and UHP peak occurred at about 540±50 °C at c. 13 kbar, 600–800 °C at ≥15–25 kbar and 800–850 °C at >30 kbar, respectively. Garnet from the coronal- through the transitional- to the eclogite-stage rocks show a decrease in almandine and an increase in grossular±pyrope components; garnet in low-grade rocks contains higher MnO and lower pyrope components. The growth textures of garnet within pseudomorphs after plagioclase or along grain boundaries between plagioclase and other phases are complex; the application of garnet zoning to estimate P–T should be carried out with caution. Some garnet enclosing quartz aggregates as inclusions shows radial growth boundaries; these quartz aggregates, as well as other primary and low-P phases, persisted metastably at UHP conditions due to sluggish reactions resulting from the lack of fluid during prograde and retrograde P–T evolution.     

Metamorphic evolution of the coesite-bearing ultrahigh-pressure terrane in the North Qaidam, Northern Tibet, NW China

Widespread evidence for ultrahigh‐pressure (UHP) metamorphism is reported in the Dulan eclogite‐bearing terrane, the North Qaidam–Altun HP–UHP belt, northern Tibet. This includes: (1) coesite and associated UHP mineral inclusions in zircon separates from paragneiss and eclogite (identified by laser Raman spectroscopy); (2) inclusions of quartz pseudomorphs after coesite and polycrystalline K‐feldspar + quartz in eclogitic garnet and omphacite; and (3) densely oriented SiO₂ lamellae in omphacitic clinopyroxene. These lines of evidence demonstrate that the Dulan region is a UHP metamorphic terrane. In the North Dulan Belt (NDB), eclogites are characterized by the peak assemblage Grt + Omp + Rt + Phn + Coe (pseudomorph) and retrograde symplectites of Cpx + Ab and Hbl + Pl. The peak conditions of the NDB eclogites are P = 2.9–3.2 GPa, and T = 631–687 °C; the eclogite shows a near‐isothermal decompression P–T path suggesting a fast exhumation. In the South Dulan Belt (SDB), three metamorphic stages are recognized in eclogites: (1) a peak eclogite facies stage with the assemblage Grt + Omp + Ky + Rt + Phn at P = 2.9–3.3 GPa and T = 729–746 °C; (2) a high‐pressure granulite facies stage with Grt + Cpx (Jd < 30) + Pl (An24–29) + Scp at P = 1.9–2.0 GPa, T = 873–948 °C; and (3) an amphibolite facies stage with the assemblage Hbl + Pl + Ep/Czo at P = 0.7–0.9 GPa and T = 660–695 °C. The clockwise P–T path of the SDB eclogites is different from the near‐isothermal decompression P–T path from the NDB eclogites, which suggests that the SDB was exhumed to a stable crustal depth at a slower rate. In essence these two sub‐belts formed in different tectonic settings; they both subducted to mantle depths of around 100 km, but were exhumed to the Earth's surface separately along different paths. This UHP terrane plays an important role in understanding continental collision in north‐western China.     

Petrological investigation of the Ganyu peridotite in the Sulu ultrahigh-pressure terrane, eastern China

The ultramafic body sampled in the Chinese Continental Scientific Drilling (CCSD) Hole PP3 is located in the eastern part of the Dabie-Sulu UHP metamorphic belt near Donghai County. It is about 480 m thick, and consists chiefly of garnet peridotite, dunite and serpentinite. The principal minerals include olivine, chromium spinel, diopside, enstatite, garnet with minor secondary augite, phlogopite and amphibole. Both the olivine and orthopyroxene are highly magnesian, and the garnet is pyropic with 5.4-6.4% CaO and 0.3-3.3% Cr₂O₃. Two generations of clinopyroxene are present; an early diopside followed by augite. Chromium spinels are highly variable with Cr#s (100Cr / (Cr + Al)) between 51 and 89, and their compositions reflect different processes of formation, namely partial melting and eclogite, amphibole and greenschist facies metamorphism. The Mg#s (100 Mg / (Mg + Fe²⁺))of the spinels correlate positively with the Cr#s but negatively with oxygen fugacity. Based on the spinel compositions the ultramafic rocks originated in the shallow mantle, then subducted to depths of more than 100 km and finally exhumed to the surface. They underwent partial melting at shallow depths, mostly in the spinel facies, and were later transformed into garnet peridotites during deep subduction. All of the rocks were weakly metasomatized during exhumation and were subjected to retrograde metamorphism.     

Petrogenesis of the garnet peridotite and garnet-free peridotite of the Zhimafang ultramafic body in the Sulu ultrahigh-pressure metamorphic belt, eastern China

The CCSD‐PP1 drillhole penetrated a 110‐m‐thick sequence of the Zhimafang ultramafic body in the Sulu ultrahigh‐pressure (UHP) metamorphic belt, east China. The sequence consists of interlayered garnet‐bearing (Grt) and garnet‐free (GF) peridotite. Eleven layers of Grt‐peridotite, ranging from 1.2 to 9.5 m in thickness, have an aggregate thickness of 54.49 m, whereas eight layers of GF‐peridotite, ranging from 2.2 to 14.2 m in thickness, have a total thickness of 57.53 m. The boundaries between the two rock types are gradational. The Grt‐peridotites have slightly higher contents of Al₂O₃, CaO and SiO₂, and lower Mg^#s (0.90–0.92) than the GF‐peridotites (Mg^#s 0.91–0.93). Both contain low TiO₂ (<0.05 wt%) and have higher modal abundances of enstatite (average 10 vol.%) than diopside (1–5 vol.%), typical of depleted‐type upper mantle. The diopside in these rocks has high and relatively uniform Mg^# members (0.93–0.95), but highly variable Al₂O₃ (0.2–2.3 wt%), Na₂O (0.5–2.5 wt%) and Cr₂O₃ (0.38–2.09 wt%). Enstatite (En_92?93) contains very low Al₂O₃ (0–0.3 wt%). Both porphyroblastic and equigranular garnet are present. The equigranular varieties are zoned, from core to rim in Cr₂O₃ (3.4–4.2 wt%), MgO (18.4–17.5 wt%) and Al₂O₃ (21.1–20.1 wt%). Titania is very low in all the garnet, mostly <0.05 wt%. Chromite or chromium (Cr)‐spinel occur both in the Grt‐ and GF‐peridotite, and are characterized by high contents of Cr₂O₃ (49–58 wt%) and FeO (24–43 wt%), similar to that in iron‐rich Alpine‐type peridotites. Based on the bulk‐rock MgO–FeO compositions, the Zhimafang Grt‐peridotite probably underwent 20–30% partial melting, whereas the GF‐peridotite may have undergone as much as 35–40% partial melting, suggesting that the two rock types owe their differences to different degrees of partial melting rather than to pressure differences during metamorphism.     

石榴石辉石岩的单斜辉石中韭闪石和钛铁矿出溶结构及地质意义

本文首次报道了在苏鲁超高压变质带胡家岭地区石榴石辉石岩中发现的韭闪石出溶结构。该石榴石辉石岩是由石榴子石、单斜辉石以及镁铝尖晶石、钛铁矿和磁铁矿组成。在石榴子石巨斑晶中有单斜辉石包体，单斜辉石包体中又有石榴子石包体以及大量韭闪石出溶片晶和钛铁矿( 磁铁矿)出溶棒。单斜辉石中韭闪石出溶片晶呈平行条带状，其宽度在1～10μm之间。透射电子显微镜(TEM)观察韭闪石的(010)面平行于主晶透辉石的(010)面，且两者的界面在纳米尺度上是连续过渡的，证明韭闪石是出溶形成的。大量钛铁矿出溶棒的定向排列也显示出它们是自然出溶形成的。从单斜辉石出溶的矿物组合推测其原始单斜辉石成分中应富含H2O、Na和Ti，属高压型单斜辉石。该石榴石辉石岩经历了超高压变质作用后，在抬升减压过程中形成这些出溶结构。大量钛铁矿出溶棒均斜切韭闪石出溶片晶，表明该超高压岩石在减压过程中至少经历了两期以上导致温压明显变化的地质事件。     

Protolith and metamorphic ages of the Haiyangsuo Complex, eastern China: a non-UHP exotic tectonic slab in the Sulu ultrahigh-pressure terrane

Summary The Haiyangsuo Complex in the NE Sulu ultrahigh-pressure (UHP) terrane has discontinuous, coastal exposures of Late Archean gneiss with amphibolitized granulite, amphibolite, Paleoproterozoic metagabbroic intrusives, and Cretaceous granitic dikes over an area of about 15 km². The U–Pb SHRIMP dating of zircons indicates that theprotolith age of a garnet-biotite gneiss is >2500 Ma, whereas the granulite-facie metamorphism occurred at around 1800 Ma. A gabbroic intrusion was dated at ∼1730 Ma, and the formation of amphibolite-facies assemblages in both metagabbro and granulite occurred at ∼340–460 Ma. Petrologic and geochronological data indicate that these various rocks show no evidence of Triassic eclogite-facies metamorphism and Neoproterozoic protolith ages that are characteristics of Sulu-Dabie HP-UHP rocks, except Neoproterozoic inherited ages from post-collisional Jurassic granitic dikes. Haiyangsuo retrograde granulites with amphibolite-facies assemblages within the gneiss preserve relict garnet formed during granulite-facies metamorphism at ∼1.85 Ga. The Paleoproterozoic metamorphic events are almost coeval with gabbroic intrusions. The granulite-bearing gneiss unit and gabbro-dominated unit of the Haiyangsuo Complex were intruded by thin granitic dikes at about 160 Ma, which is coeval with post-collisional granitic intrusions in the Sulu terrane. We suggest that the Haiyangsuo Complex may represent a fragment of the Jiao-Liao-Ji Paleoproterozoic terrane developed at the eastern margin of the Sino-Korean basement, which was juxtaposed with the Sulu terrane prior to Jurassic granitic activity and regional deformation.     

Deep subduction of mantle-derived garnet peridotites from the Su-Lu UHP metamorphic terrane in China

Garnet peridotites from the southern Su‐Lu ultra‐high‐pressure metamorphic (UHPM) terrane, eastern China, contain porphyroblastic garnet with aligned inclusions comprising a low‐P–T mineral assemblage (chlorite, hornblende, Na‐gedrite, Na‐phlogopite, talc, spinel and pyrite). Orthopyroxene porphyroblasts show fine exsolution lamellae of clinopyroxene and minor chromite. A clinopyroxene inclusion in garnet shows some orthopyroxene exsolution lamellae. Both the rims of porphyroblastic pyroxene and garnet and the matrix pyroxene and garnet crystallized at the expense of olivine. This is interpreted as a result of metasomatism of the peridotites by an SiO₂‐rich melt at UHP conditions. A chromian garnet further overgrew on the rims of the garnet. The X_Mg values (Mg/(Mg+Fe)) of porphyroblastic garnet decrease from core to rim and vary in different peridotite samples, while the compositions of both the porphyroblastic and the matrix pyroxene are similar in terms of Ca–Mg–Fe. The Mg‐rich cores of porphyroblastic garnet and orthopyroxene record high temperatures and pressures (c. 1000 °C, ≥5.1 GPa), whereas the matrix minerals, including the rims of porphyroblasts, record much lower P–T (c. 4.2 GPa, c. 760 °C). Sm–Nd data give apparent isochron ages of c. 380 Ma and negative ε_Nd(0) values (c.?9). These dates are considered meaningless due to isotopic disequilibrium between garnet cores and the rest of the rocks. The isotopic disequilibrium was probably caused by metasomatism of the peridotites by melt/fluids derived from the coevally subducted crustal materials. On the other hand, the Rb–Sr isotopic systems of phlogopite and clinopyroxene appear to have reached equilibrium and record a cooling age of c. 205 Ma. It is suggested that the garnet peridotites were originally emplaced into a low‐P–T environment prior to the c. 220 Ma continental collision, during which they were subducted together with crustal rocks to mantle depth and subjected to UHP metamorphism. An important corollary is that at least some of the coevally subducted crustal rocks in the Su‐Lu terrane have been subjected to peak metamorphism at P–T conditions much higher than presently estimated (≥2.7 GPa, ≤800 °C).     

Ultra-high-pressure (UHP) marble and eclogite in the Su-Lu UHP terrane, eastern China

A large mass of dolomitic marble including many eclogite blocks occurs in orthogneisses of the Rongcheng area of the Su-Lu province, eastern China. The marble consists mainly of dolomite, calcite (formerly aragonite), graphite, forsterite, diopside, talc, tremolite and phlogopite. Aggregates of talc and calcite occur at the boundary between dolomite and diopside. Tremolite is a reaction product between talc and calcite. Eclogite blocks are rimmed by dark green amphibolite. The primary mineral assemblage in the core of eclogite is Na-bearing garnet (up to 0.2  wt% Na₂O), omphacitic pyroxene, clintonite and rutile. Secondary minerals are pargasitic/edenitic amphibole, plagioclase, sodic diopside, chlorite, zoisite and titanite. The peak metamorphic conditions, based on stability of the dolomite+forsterite+aragonite (now calcite)+graphite assemblage, under conditions where tremolite is unstable, are estimated at T  =610–660 °C and P =2.5–3.5  GPa (for X _{CO=0.001). A reaction between dolomite and diopside to form talc under tremolite-unstable conditions indicates a temperature decrease under ultra-high-pressure conditions (} P >2.4  GPa, X _{CO<0.0013). The formation of secondary tremolite is consistent with a nearly adiabatic pressure decrease post-dating the ultra-high-pressure metamorphism. The temperature decrease under ultra-high-pressure conditions preceding decompression may reflect the underplating of a cold slab, and the rapid decompression probably corresponds to the upwelling stage promoted by the delamination of a downwelling lithospheric root. The} P – T  conditions of the amphibolitization stage are estimated at <0.9  GPa and <460 °C, and are similar to conditions recorded by the surrounding orthogneisses.     

Petrogenesis of Maobei rutile eclogites from the southern Sulu ultrahigh-pressure metamorphic belt, eastern China

The Maobei complex in the southern Sulu ultrahigh‐pressure (UHP) metamorphic belt, eastern China, mainly consists of layered eclogites, garnet peridotites and orthogneisses. Based on the modal mineral and whole‐rock compositions, eclogites from the Maobei complex are divided into quartz eclogite, quartz‐rich eclogite, rutile eclogite, rutile‐rich eclogite and eclogite. The distinct spatial changes in the lithology and related chemical compositions indicate that this complex includes 10 rhythmic layers. The rutile eclogites have high TiO₂ (2.4–5.9 wt%), commonly coupled with high P₂O₅ (up to 4.1 wt%) contents; most show fractionated REE patterns with slight positive Eu anomalies. The rutile‐rich eclogites have very high TiO₂ (3.3–5.7 wt%), FeO^T (17.5–25.3 wt%), V (126–1163 ppm) and Co (14–132 ppm), and very low SiO₂ (38.0–42.3 wt%), Zr (24–85 ppm), Nb (0.3–6.9 ppm), Ta (<0.1–0.6 ppm) and total REE (10.7–334.0 ppm) contents, variable degree of LREE depletion, and positive Eu anomalies (Eu/Eu* = 1.1–2.9), and the Ti is decoupled from other high‐field‐strength elements. These characteristics are consistent with Fe‐Ti gabbros of typical layered intrusions, implying a cumulate of plagioclase, clinopyroxene and abundant accessory magnetite in an evolved basaltic magmatic chamber. Based on a normal stratigraphic sequence, the Maobei complex shows an iron‐enrichment trend, followed by alkaline enrichment with increasing fractionated crystallization and stratigraphic height. These facts, together with SHRIMP U‐Pb zircon ages of 773.7 ± 8.0 Ma, indicate that the protolith of the Maobei complex is a Neoproterozoic layered intrusion consisting of a base of peridogabbro, a main body of gabbro and minor granodiorite. Unusually high Ti, V and P contents in three rutile eclogite layers suggest that they are potential economic ore deposits.     

北苏鲁荣成地区超高压变质带大理岩中石榴辉石岩的退变质过程

北苏鲁荣成地区超高压变质带大理岩中的退变质石榴辉石岩包裹体具有“核-幔-边”结构,核部主要由石榴子石与单斜辉石组成,幔部含有由细小角闪石与绿帘石组成的后成合晶以及颗粒较大的角闪石与单斜辉石,通过详细的岩相学分析以及矿物成分分析,认为这些后成合晶是由石榴子石、单斜辉石以及来自围岩的流体共同反应而产生,大颗粒的角闪石主要是由辉石转变而来的,在幔部这个转变并不彻底,仍有一些残余辉石颗粒。边部主要由角闪石和绿帘石组成。该石榴辉石岩曾经历榴辉岩相超高压变质阶段。没有柯石英超高压代表性矿物（采样处的其他类型岩石都含有柯石英）的原因是石榴辉石岩的原岩为超基性岩。     

Ultrahigh-pressure metamorphism in the forbidden zone: the Xugou garnet peridotite, Sulu terrane, eastern China

The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo₉₁), enstatite (En_92?93), garnet (Alm_20?23Prp_53?58Knr_6?9Grs_12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al₂O₃ and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp_44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm_29?34Prp_32?50Grs_15?39) + omphacite (Jd_24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km^?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.     

南苏鲁造山带毛北超高压变质岩体的成因与成矿作用

毛北超高压变质岩体位于苏鲁造山带南部,是由石榴石橄榄岩、榴辉岩、硬玉石英岩和石榴石多硅白云母石英片岩组成的层状岩体.富金红石榴辉岩和富钛铁矿榴辉岩在岩体中呈连续的层状产出,总厚度达200m,深度＞700m,构成了一个大型的钛矿床.岩石学、地球化学和年代学研究表明,毛北岩体的原岩形成在新元古代Rodinia超大陆裂解过程中,基性岩浆经历了强烈的分异结晶作用,形成了由橄榄辉长岩-辉长岩-闪长岩-花岗岩组成的复杂层状侵入体,并在新元古代的全球冰期与高纬度大气降水发生强烈的水-岩交换作用.在印支期的大陆深俯冲过程中,经历了超高压变质作用,其峰期变质温度＞800℃,压力＞4.5GPa,富钛磁铁矿辉长岩转变成了富金红石榴辉岩,形成了超高压变质的钛矿床.     

SHRIMP U–Pb ages of ultrahigh-pressure and retrograde metamorphism of gneisses, south-western Sulu terrane, eastern China

Laser Raman spectroscopy and cathodoluminescence (CL) images reveal that most zircon separated from paragneiss and orthogneiss in drillhole CCSD‐PP2 at Donghai, south‐western Sulu terrane, retain low‐P mineral‐bearing inherited cores, ultrahigh‐pressure (UHP) mineral‐bearing mantles and low‐P mineral‐bearing (e.g. quartz) rims. SHRIMP U–Pb analyses of these zoned zircon identify three discrete and meaningful age groups: Proterozoic protolith ages (> 680 Ma) are recorded in the inherited cores, the UHP metamorphic event in the coesite‐bearing mantles occurred at 231 ± 4 Ma, and the late amphibolite facies retrogressive overprint in the quartz‐bearing rims was at 211 ± 4 Ma. Thus, Neoproterozoic supracrustal protoliths of the Sulu UHP rocks were subducted to mantle depths in the Middle Triassic, and exhumed to mid‐crustal levels in the Late Triassic. The exhumation rate deduced from the SHRIMP data and metamorphic P–T conditions is 5.0 km Ma^?1. Exhumation of the Sulu UHP terrane may have resulted from buoyancy forces after slab break‐off at mantle depths.     

苏鲁超高压变质带中海阳所地区变基性岩的地球化学性质及变质演化特征

苏鲁超高压变质带的海阳所地区广泛分布各类变基性岩,它们主要由"红眼圈"结构的变辉长岩、(石榴)斜长角闪岩组成,且以透镜状或似层状赋存于片麻岩中。根据主量元素和微量元素特征,可将海阳所地区变基性岩划分为两种类型:第一类(A组)样品轻稀土相对富集,其稀土元素配分曲线具有右倾型的特征,微量元素具有Nb、Ta、Zr、Hf、Ti的明显负异常,其蛛网图配分曲线微弱右倾,类似于岛弧玄武岩IAB的特征;第二类(B组)样品稀土元素配分曲线和微量元素蛛网图配分曲线均相对平坦,Nb、Ta、Zr、Hf、Ti略微亏损,与洋中脊玄武岩E-MORB具有一定的相似性。所有变基性岩样品均属于拉斑玄武岩系列,成因类型部分与岛弧环境相关,另一部分则可能与洋中脊环境关系密切。根据岩相学、矿物相转变、变质反应以及温压条件估算的综合研究结果,识别出海阳所变基性岩可能经历了两期变质作用,其中第一期中-高压麻粒岩相变质作用(M1)的标志性矿物组合以基质中保存的粗粒石榴石(Grt1)+粗粒单斜辉石(Cpx1)+粗粒斜长石(Pl1)±石英(Qtz)组合为特征,形成的温压条件为T=725~845℃、P=9.5~12.4kbar;第二期峰期高压麻粒岩相变质阶段(M12)以发育"红眼圈"结构为特征,典型的矿物组合为新生的细粒石榴石(Grt12)+单斜辉石(Cpx12)+斜长石(Pl12)±石英(Qtz),形成的温压条件为T=765~845℃、P=14.8~17.5kbar,而峰后角闪岩相退变质阶段(M12)以形成低温退变质矿物组合绿色角闪石(Amp22)+斜长石(Pl22)±石英(Qtz)±石榴石(Grt22)为特征,形成的温压条件为T=575~680℃、P=6.0~8.0kbar。第二期变质演化P-T轨迹具有近等温降压至减压冷却的顺时针型式。海阳所变基性岩记录的多期变质演化的信息及其P-T条件与苏鲁-大别超高压变质带存在明显差异。结合以往变基性岩新太古代-古元古代原岩年龄信息,可以判断海阳所地区的变基性岩可能来自于华北克拉通东南缘胶北地体的古老变质基底,并卷入苏鲁-大别地体中-晚三叠世造山事件中。这一重要成果对于揭示海阳所及其邻区变基性岩和围岩的成因、胶北地体古老基底的形成演化过程以及重塑苏鲁-大别超高压变质带的构造演化模式具有重要的科学意义。     

Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.     

苏鲁超高压变质带胡家林超镁铁质岩成因及构造意义

胡家林超镁铁质杂岩体产于苏鲁超高压变质带中部,纯橄岩和(石榴)单斜辉石岩呈不连续透镜体产于蛇纹石化橄榄岩中。纯橄岩遭受了部分蛇纹石化(烧失量=6.6%～13.2%),全岩富集强相容元素(Ni、Cr、Co)和Ir族PGE(IPGE;Ir、Os、Ru)及高IPGE/PPGE值,亏损Al、Ti、V,具高Mg~#橄榄石(Fo=91.7～92.4)和高Cr~#(0.68～0.76)尖晶石。纯橄岩高耐熔地球化学及矿物化学特征和古老的大陆岩石圈地幔相一致,表明其原岩来源于弧前地幔,代表了华北克拉通古老的大陆岩石圈地幔残留。(石榴)单斜辉石岩全岩呈相对低含量的强相容元素(Cr、Ni、Co)和IPGE,高含量的Al、Ti、V和流体迁移元素(Sr、Pb和Ba),球粒陨石标准化REE配分图呈明显"上凸"型,具低Mg~#橄榄石(Fo=76.6～76.8)和低Al_2O_3(2.76%)和高SiO_2(54.56%～56.87%)的单斜辉石。全岩组成和矿物化学表明其原岩为俯冲带内超镁铁质火成堆晶岩,最初岩浆由地幔岩高程度部分熔融的熔体和俯冲带中富H_2O流体和/或熔体构成。(石榴)单斜辉石岩原岩曾被地幔流带入扬子大陆俯冲板片和上覆地幔楔之间的俯冲通道,经历了超高压变质作用和生成大量石榴石。(石榴)单斜辉石岩在折返过程中,与大陆岩石圈地幔楔剥离的蛇纹石化橄榄岩及纯橄岩相结合,形成超镁铁质杂岩体,整体被低密度的俯冲板片(主要由花岗质片麻岩和变质沉积岩组成)裹挟,折返至地壳浅部。     

Mineral isograds and metamorphic zones of the Anglesey blueschist belt, UK: implications for the metamorphic development of a Neoproterozoic subduction–accretion complex

The 560–550 Ma blueschists and associated rocks in Anglesey, UK were derived from a subduction–accretion complex. The blueschist unit is divided into three mineral zones by two newly mapped metamorphic isograds; zone I sub-greenschist facies, (crossite isograd), zone II blueschist facies, (barroisite isograd), zone III epidote-amphibolite facies. The zones and isograds dip gently to the east, and decrease in metamorphic grade from the central high-pressure zone III to lower grade zones II and I to the west and east. The P – T conditions estimated from zoned amphibole indicate an anticlockwise P – T path following adjustment to a cold geotherm. This path is well preserved in the compositional zoning of Na–Ca amphibole that have a core of barroisite surrounded by a rim of crossite, although this is only locally developed. The sense of subduction was to the east and exhumation to the west, as indicated by the metamorphic isograds. The symmetrical arrangement of the metamorphic zones with the deepest high-pressure rocks in the middle suggests an isoclinal antiformal structure that formed by wedge extrusion during exhumation in the subduction zone.     

A transitional eclogite- to high pressure granulite-facies overprint on coesite–eclogite at Taohang in the Sulu ultrahigh-pressure terrane, Eastern China

A transitional eclogite- to high-pressure granulite-facies paragenesis (Omp+Pl+Qtz±Grt) after peak coesite–eclogite facies metamorphism and predating the later amphibolite-facies overprint is identified in coesite–eclogite from the Taohang area of the Sulu ultrahigh-pressure (UHP) terrane in eastern China. These minerals were equilibrated at 17 kbar and 820°C. This reveals that fluid infiltration might activate retrograde recrystallisation even at a deep level during the exhumation process of the UHP rocks. The tectono-metamorphic significance of the unusually high pressure overprint is also discussed.