Clay minerals in carbonate reservoir rocks and their significance in porosity studies

The writers have been studying the origin of porosity in the Neogene calcareous rocks of Akita, Japan, and in the Mississippian Windsor Group carbonate rocks of Nova Scotia, Canada. The former consist mainly of dolomitic clayey-siliceous marls, derived mainly from opaline skeletal debris of microscopic organisms. These marls were deposited in bathyal to inner-neritic environments. The carbonate rocks of Windsor Group, which include both dolostones and limestones, originated from biogenic carbonate debris and were deposited in inner-shelf to shoal environments.     

Anthracitization of coals in the South Wales coalfield

Investigations by the Institute of Geological Sciences on potential geothermal water sites in the coalfield of South Wales have been reported. They are of considerable interest and revive the controversy about the nature of the heat-source responsible for the anthracitization of some coals in this classic area. In the absence of exposed post-Carboniferous igneous rocks in the coalfield, general opinion has favoured heat generation by friction along faults or “disturbances”. We re-examine the evidence in the light of more recent geophysical and geochemical investigations which suggest the possibility of igneous intrusions at a depth of about 3.5 km or shallower. The likely age of such intrusions is also considered. High seismic velocity basement rocks rise to only 2.5 km beneath the surface of the Carboniferous in the northwestern anthracitized zone of the coalfield and we suggest that anthracitization in South Wales is not the result of depth of burial nor of frictional heat but of proximity to a magmatic heat source associated with crystalline rocks of the basement.     

An historical review of landslide research in the South Wales coalfield

Summary The areal density of landslides in the coalfield of South Wales is one of the highest in the UK. During the past 100 years landsliding has had considerable impact, causing structural damage and loss of life. Most of the landslides were initiated under periglacial conditions but many became reactivated due to the activities of humans, particularly during the late 19 th century when widespread urban and industrial development commenced in the Welsh valleys. A number of the area's larger landslides are first-time slides which occurred during the past 100 years. This paper sets out to chart the history of landslide research in the coalfield, which began through work by mining engineers.     

Ultra-high-pressure metamorphism of carbonate rocks in the Dabie Mountains, central China

Abstract Widespread ultra-high-P assemblages including coesite, quartz pseudomorphs after coesite, aragonite, and calcite pseudomorphs after aragonite in marble, gneiss and phengite schist are present in the Dabie Mountains eclogite terrane. These assemblages indicate that the ultra-high-P metamorphic event occurred on a regional scale during Triassic collision between the Sino-Korean and Yangtze cratons. Marble in the Dabie Mountains is interlayered with coesite-bearing eclogite and gneiss and as blocks of various size within gneiss. Discontinuous boudins of eclogite occur within marble layers. Marble contains an ultra-high-P assemblage of calcite/aragonite, dolomite, clinopyroxene, garnet, phengite, epidote, rutile and quartz/coesite. Coesite, quartz pseudomorphs after coesite, aragonite and calcite pseudomorphs after aragonite occur as fine-grained inclusions in garnet and omphacite. Phengites contain about 3.6 Si atoms per formula unit (based on 11 oxygens). Similar to the coesite-bearing eclogite, marble exhibits retrograde recrystallization under amphibolite–greenschist facies conditions generated during uplift of the ultra-high-P metamorphic terrane. Retrograde minerals are fine grained and replace coarse-grained peak metamorphic phases. The most typical replacements are: symplectic pargasitic hornblende + epidote after garnet, diopside + plagioclase (An₁₈) after omphacite, and fibrous phlogopite after phengite. Ferroan pargasite + plagioclase, and actinolite formed along grain boundaries between garnet and calcite, and calcite and quartz, respectively. The estimated peak P–T conditions for marble are comparable to those for eclogite: garnet–clinopyroxene geothermometry yields temperatures of 630–760°C; the garnet–phengite thermometer gives somewhat lower temperatures. The minimum pressure of peak metamorphism is 27 kbar based on the occurrence of coesite. Such estimates of ultra-high-P conditions are consistent with the coexistence of grossular-rich garnet + rutile, and the high jadeite content of omphacite in marble. The fluid for the peak metamorphism was calculated to have a very low X_CO2 (<0.03). The P–T conditions for retrograde metamorphism were estimated to be 475–550°C at <7 kbar.     

Noble metal specialization of Lower and Middle Riphean terrigenous rocks in the South Urals

Results of the study of noble metal specialization of Lower and Middle Riphean terrigenous rocks in the Bashkir Anticlinorium (South Urals) are reported. The study revealed their genetic differences in the relatively unaltered, i.e., “background” terrigenous rocks in type sections of the Burzyan and Yurmatau groups and in sedimentary rocks of the same stratigraphic levels from tectonic zones subjected to local dynamothermal metamorphism of the greenschist facies and intruded by mafic rocks. It has been established that Ru serves as a geochemical marker of the impact of magmatic processes on sedimentary rocks and the redistribution of noble metals during metamorphism and local metasomatism. A generalized model is proposed for the formation of noble metal geochemical specialization of Lower and Middle Riphean terrigenous rocks in the South Urals.     

Postsedimentation transformation of triassic terrigenous rocks in West Chukotka as an indicator of folding conditions

Postsedimentation alteration and structural assemblies of the Triassic sedimentary complexes of West Chukotka are discussed. Zoning of the alteration is based on examination of newly formed structural and mineral assemblages, the chemical composition, and the polytypes of clay minerals. Three zones of postsedimentation transformation of sandstones are distinguished: (1) the zone of chlorite, illite, and mixed-layer disordered chlorite-smectite; (2) the zone of illite and chlorite; and (3) the zone of phengite and ferroan chlorite. The grade of postsedimentation transformation and the composition of the newly formed micas are correlated with the cleavage type. The development of two-three types of cleavage leads to the highest degree of rock transformation. The assemblages of clay minerals and the crystal chemistry of the authigenic phengite show that the grade of postsedimentation transformation of the Triassic rocks attains the stage of greenschistfacies metamorphism in the zone of development of two cleavage types. Where the second cleavage is not documented or poorly developed, the rocks remain unmetamorphosed. Evidence is given that postsedimentation transformation of terrigenous rocks in the foldbelt is controlled largely by deformation.     

Water deficiency as a factor in metamorphism of rocks

Mineral equilibria in magnesial rocks undergoing metamorphosis in closed systems at different H₂O content but at constant pressures and temperatures may be interpreted as follows: a) if H₂O is excessive, as in pelitic rocks, the metamorphic zonation (an orderly sequence of dehydrations) correctly represents changes in the temperature during the progressive metamorphism; b) if H₂O is deficient, as in the ortho-rocks, the metamorphic zonation may not always be representative of the temperature; however, when H₂O itself is zoned in the rock and the metamorphism is isothermal, the metamorphic zonation may become entirely analogous to the zonation in the presence of excessive H₂O; c) presence of metastable associations and rapid alternations of mineral parageneses, as in certain magmatic rocks, represent variations in H₂O content of the rocks rather than different facies of the metamorphism.     

The impact of tectonic deformation upon coal seams in the South Wales coalfield, UK

Observations on the nature and appearance of coal seams, which were deformed during the late Carboniferous Variscan orogeny, have been made over several years within a number of opencast coal sites located across the South Wales coalfield. The deformation of coal seams was dominated by brittle failure and subsequent movement along fracture planes. Examination of hand specimens and smaller-scale samples using a scanning electron microscope reveals the presence of two distinct types of small-scale, tectonic fracture markings within deformed coals. Striated fracture surfaces with prominent ridges and grooves can bear a superficial resemblance to shatter cones in appearance but are unique to coal in their tectonic setting and appear to have formed by static shear failure, whereas strongly polished fracture surfaces result from movement across fracture planes. Deformed coal seams are also affected by distinctive, large-scale, tectonic fracture sets. The extent of fracturing within coal seams can be assessed using different techniques including measuring fracture frequency directly, performing various strength and hardness tests, making relatively simple subjective assessments on the appearance of the coal or monitoring the size distribution of the coal product. By applying some of these methods within working opencast sites, it can be shown that large amounts of abnormally fractured coal were formed along coal-based thrust flats or detachments but that the distribution of fractured coal along detached seams is rarely homogeneous. Enhanced fracturing often occurred in association with the localised thickening of seams along small-scale thrusts or within coal duplexes. Variable seam thicknesses and pockets of structurally thickened coal are seen as the most efficient means by which the presence and location of significant amounts of fractured coal can be predicted from borehole evidence during prospecting.     

Influence of processes of the formation of authigenic clay minerals of terrigenous rocks on reservoir properties: Evidence from the rocks of the Vartov Arch

Filtration-capacity properties of terrigenous reservoir rocks significantly depend on catagenetic transformations of clay minerals. Results of our research revealed the authigenic nature and formation stages of kaolinite and chlorite. The volume and shape of pore space define the morphology of clay particles. Depending on the pore volume, kaolinite crystallizes either as thick tabular aggregates or as fan-shaped intergrowths. The formation of authigenic clays in pores of terrigenous reservoirs decreases filtration-capacity properties of rocks with low permeability and, conversely, increases filtration-capacity properties of rocks with high primary permeability and large pore volume.     

Petrology of ultramafic rocks and Mg-rich carbonate minerals in southeast of Dehshir,Central Iran

The study area is located southeast of Dehshir between the Urumieh-Dokhtar Magmatic Arc and Nain-Baft Ophiolite Belt comprising the Nain, Dehshir, Shahr Babak, and Baft ophiolite complexes. The Dehshir Ophiolitic Complex which obducted in the Late Cretaceous, consists mainly of ultramafic rocks. These remnants of oceanic crust are extensively faulted and fractured. The severe faulting and brecciating of the ophiolite sequence have undergone high-grade alteration and changed it to the tectonic mélange. The Dehshir colored mélange is bounded to the west by Dehshir fault which is a right-lateral offset of the Nain-Baft suture. In this research, the petrographic studies of the area showed that the ultramafic rocks consist mainly of dunite and harzburgite intruded by diabasic dikes. Syntectonic hydrothermal fluids circulated throughout these rocks. Migration of Mg-rich fluids and hydrothermal brecciating occurred within highly altered and brecciated zones. Magnesite precipitated from hydrothermal solutions and formed the massive, lenticular, and vein-type ore deposits in serpentinized-hosted rocks. Later on, magnesite turned into hydromagnesite due to hydration at the lower depths near the surface. According to the X-ray diffraction and X-ray fluorescence analysis, hydromagnesite is the most dominant and widely occurring Mg-rich carbonate mineral in this area. The main alteration is serpentinization but birbiritization also occurs as a result of interaction between fluids and ultramafic rocks.     

Jointing and minor tectonics of the N. Crop of the South Wales coalfield between kidwelly and black mountain,S. Wales

Joints, minor faults and mineral veins were recorded at 334 stations between Kidwelly and Black Mountain, S. Wales. A systematic pattern occurs with joint sets striking at 360°, 340°, 290°, 250°, and 210°. Minor faults and shear planes exhibit both strike and dip-slip displacements. The jointing is considered to have formed quite early during folding, and both joints and faults can be attributed to a principal compression acting almost N-S and subparallel to bedding. Phases of dilation are recorded by sets of mineral veins. All the deformational structures are considered to be of Armorican age.     

Contact metamorphism of pelitic,psammitic and calcareous sediments in the Southern Highlands of New South Wales

Contact metamorphism has been recognized along a 4 km wide belt adjacent to the shallow‐dipping eastern margin of the Arthursleigh Tonalite, an Early Devonian pluton of the Marulan Batholith, eastern New South Wales. In Ordovician psammitic and pelitic rocks three zones of progressive contact metamorphism range from muscovite + biotite + chlorite assemblages in the outer zone to K‐feldspar + cordierite assemblages adjacent to the pluton and in metasedimentary xenoliths. Retrograde phenomena include extensive replacement of metamorphic minerals by ‘sericite’ and chlorite. Calcareous metasediments adjacent to the tonalite typically contain assemblages of quartz + calcic plagioclase + ferrosalite + sphene, or wollastonite + calcite + diopside with minor grossularite and vesuvianite. Thermal effects in volcanic rocks along the western margin of the pluton are confined to recrystallization of the groundmass.

The regional geology indicates confining pressures of approximately 1 kbar at the time of emplacement of the tonalite. Contact metamorphic temperatures were estimated from two‐feldspar geothermometry to attain a maximum of approximately 590°C for rocks in the innermost zone of the aureole and 700°C for the xenoliths. Fluid compositions attending progressive contact metamorphism were water‐rich (Xco₂<0.2) and, during cooling, these fluids probably account for the extensive retrograde hydration observed in the aureole.     

Relict sulfides in terrigenous rocks of the Upper Kolyma Region

In terrigenous flysch strata of the Upper Kolyma Region in northeastern Russia, microaggregates of sulfides with spherical form are widespread. During dynamic metamorphism, spherical sulfide units were segregated into lenticular aggregates along the cleavage planes, were as seed, or were recrystallized into faceted metacrystals. Further stress on the rock sometimes led to a morphologically expressed particular dissolution of pyrite crystals along the cleavage directions, and to their depletion with admixture elements. A more substantial effect led to transformation of pyrite into pyrrotine with inclusions of chalcopyrite and Fe-Ni-Co-sulfoarsenides. Relict sulfides reflect, to a certain degree, the primary geochemical condition of the sedimentation period and its further evolution. When studying the numerous sulfidization zones, the composition of relict sulfides allows us to predict the geochemical specialization and the degree of inheritance of post-sedimentation mineralization.     

Isotope systematics of secondary minerals from the Prospect Intrusion,New South Wales

The differentiated Mesozoic alkali dolerite Prospect Intrusion contains a wide range of secondary minerals, including carbonates (primarily calcite), laumontite, prehnite and heulandite, whose stability relationships imply a formation temperature of <200°C. The δ¹⁸O data for carbonates define a higher temperature (160 – 195°C) suite, and a lower temperature (51 – 73°C) suite. The δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr isotope systematics for these carbonates suggest derivation of the higher temperature group from magmatic fluids, whereas the other group had a major meteoric component that probably originated from porewater in the country rock. Source fluids for prehnite were meteoric rather than magmatic in origin based on their δD and δ¹⁸O ratios. Early in the intrusion's emplacement, CO₂-rich hydrothermal fluids formed a carbonate rind sealing the upper part of the hydrothermal system and produced the higher temperature carbonates (calcite) and laumontite. Later, cooler fluids with a meteoric component infiltrated vesicles and fractures, depositing the lower temperature carbonates (calcite, aragonite), heulandite and prehnite.     

Prograde and retrograde fluid flow during contact metamorphism of siliceous carbonate rocks from the Ballachulish aureole,Scotland

 Siliceous dolomites and limestones contain abundant retrograde minerals produced by hydration-carbonation reactions as the aureole cooled. Marbles that contained periclase at the peak of metamorphism bear secondary brucite, dolomite, and serpentine; forsterite-dolomite marbles have retrograde tremolite and serpentine; wollastonite limestones contain secondary calcite and quartz; and wollastonite-free limestones have retrograde tremolite. Secondary tremolite never appears in marbles where brucite has replaced periclase or in wollastonite-bearing limestones. A model for infiltration of siliceous carbonates by CO₂-H₂O fluid that assumes (a) vertical upwardly-directed flow, (b) fluid flux proportional to cooling rate, and (c) flow and reaction under conditions of local equilibrium between peak temperatures and ≈400 °C, reproduces the modes of altered carbonate rocks, observed reaction textures, and the incompatibility between tremolite and brucite and between tremolite and wollastonite. Except for samples from a dolomite xenolith, retrograde time-integrated flux recorded by reaction progress is on the order of 1000 mol fluid/cm² rock. Local focusing of flow near the contact is indicated by samples from the xenolith that record values an order of magnitude greater. Formation of periclase, forsterite, and wollastonite at the peak of metamorphism also required infiltration with prograde time-integrated flux approximately 100–1000 mol/cm². The comparatively small values of prograde and retrograde time-integrated flux are consistent with lack of stable isotope alteration of the carbonates and with the success of conductive thermal models in reproducing peak metamorphic temperatures recorded by mineral equilibria. Although isobaric univariant assemblages are ubiquitous in the carbonates, most formed during retrograde metamorphism. Isobaric univariant assemblages observed in metacarbonates from contact aureoles may not record physical conditions at the peak of metamorphism as is commonly assumed. Received: 19 September 1995 / Accepted: 14 March 1996     

Facies sequences on a carbonate ramp: the Carboniferous Limestone of South Wales

During early Carboniferous times a major sea-level rise led to the development of an extensive carbonate ramp over what is now South Wales. Differential subsidence and sea-level changes resulted in distinctive facies sequences in the ramp succession and a model is offered which recognizes three distinct geomorpho-tectonic settings; inner, mid- and outer ramp. The inner ramp zone occurs in the more landward part of the province and was an area undergoing little or no subsidence. The sequence is dominated by oolitic grainstones and peritidal limestones representing shoal and back shoal environments. The peritidal units are transgressive deposits consisting of stacked asymmetrical shallowing-up cycles. The sequence contains many subaerial breaks and tectonic uplift resulted in base-level changes and fluvial incision. The mid-ramp zone sequence is intermediate in thickness between the inner and outer ramp successions and consists mainly of bioclastic limestones deposited below fairweather wave base. Sedimentation periodically exceeded sea-level rise and subsidence, and regressive (progradational) oolitic sand bodies developed, the thickest of which are stacked units with up to four individual sand bodies. Storm processes were of major importance in this setting. The outer ramp zone is represented by a thick sequence of muddy bioclastic limestones deposited below storm wave base and major Waulsortian reef-mounds also developed. None of the shallowing phases seen in the other ramp zones can be detected in this sequence. Subsidence and eustatic sea-level rise seem to have been the major controls on deposition but the recognition of eustatic sea-level falls is difficult. The detailed facies model for ramp carbonates presented here may be applicable elsewhere in the geological record.     

Wall-rock metasomatism of carbonaceous terrigenous rocks in the Lena gold district

The Lena gold district is situated in the fold-and-shear belt of the southern framework of the Siberian Platform. The gold deposits are hosted in the Riphean-Vendian Khomolkho and Aunakit formations, revealing the strict control of ore mineralization by folding and shearing. The microstructure of metasomatically altered ore-bearing carbonaceous sedimentary rocks at the Sukhoi Log, Golets Vysochaishy, and Verninsky deposits (the latter includes the Pervenets vein zone) testifies to parallelism in the development of shearing, foliation, and ore-forming metasomatism. The local pressure gradients are marked by removal of silica from pressured zones into opened cleavage fractures and pockets. Two metasomatic stages are recognized: (1) early sodic metasomatism, which is characterized by the assemblage of magnesian siderite and paragonite, and (2) late potassic metasomatism, with formation of muscovite in association with sideroplesite and ankerite. The rocks altered at the early stage are distinguished by elevated Ni, Cr, and probably PGE contents. The second stage, close in age to the emplacement of Hercynian granitic plutons, was accompanied by the gain of chalcophile metals and deposition of the bulk of gold. In mineral composition, the metasomatic rocks are close to beresites, but the alteration differed in somewhat elevated alkalinity, so that microveinlets of albite and potassium feldspar occur in the ore zone together with muscovite. The ratio of modal muscovite to paragonite contents in orebodies is substantially higher than in the surrounding metasomatized rocks. This ratio directly depends on the degree of rock permeability and the intensity of the flow of ore-forming solutions. Carbonaceous matter (CM) in the ore zone underwent reworking and redeposition. CM is graphitized to a lesser extent than in the rocks affected by regional metamorphism. The spatial distribution of CM containing nitro and amino groups indicates more oxidizing conditions in the zone of ore deposition than at a distance from this zone. The temperature of metasomatic processes estimated from the muscovite, muscovite-paragonite, and chlorite mineral thermometers and fluid inclusions in quartz was 300–350°C at a pressure of about 1 kbar. The S, O, and C isotopic compositions of ore-forming fluids that pertain to the second stage of metasomatism (δ³⁴S= +8.5‰, δ¹⁸O = +10‰, and δ¹³C= ?11 to ?18‰) indicate their crustal origin. The generally similar conditions and products of the ore-forming metasomatic process at the giant Sukhoi Log deposit and at the small Golets Vysochaishy deposit are combined with some differences. The formation of the described deposits was related to the deep convection of fluids along shear zones followed by more local flows of postmagmatic solutions derived from the emplaced granitic magma.     

Eclogitic metamorphism in carbonate rocks: the example of impure marbles from the Sesia-Lanzo Zone,Italian Western Alps1

The impure marbles of the internal Sesia-Lanzo Zone underwent a multi-stage metamorphic evolution of Alpine age and retain early-Alpine eclogitic assemblages, partially recrystallized under blueschist to greenschist facies conditions. These high-P assemblages consist of carbonates, phengite, quartz, omphacite, grossular-rich (locally spessartinic) garnet, zoisite and Al-rich titanite. Retrogressive stages are characterized by the growth of glaucophane, paragonite, phlogopite, tremolite and albite. Halogen-rich biotite and amphibole are also present. P-T estimates of the early-Alpine metamophism have been calculated from these unique high-P assemblages, in order to test the applicability of some calibrations to impure carbonate systems. In particular, some Gt-Cpx calibrations and the phengite geobarometer give results (T= 575 ± 45° C at 15 kbar for the eclogitic climax and T≤ 500° C at PH₂O ≤ 9 kbar for early-Alpine retrogressive stages) which are within the range obtained from the surrounding lithologies. Phase relationships in P-T-XCO₂ space indicate that mineral assemblages in the impure marbles coexisted with H₂O-rich fluids (XCO₂ <0.03) during their entire Alpine evolution.