甘肃阳山金矿岩(矿)石中金的化学相态分析

本文采用石墨炉原子吸收光度计测定了甘肃阳山金矿岩（矿）石中金的5种化学相态（可溶相、游离自然金、碳酸盐相、硫化物相和硅酸盐相）的质量分数,并分析了其在不同类型的岩（矿）石和不同时代地层中的分布特征。结果表明：区域岩石中的金主要以硅酸盐相存在,占总量的57.6%;矿石中的金主要以硫化物相存在,占总量的56.9%;与岩石中金的相态分布对比,矿石中硫化物相金、游离自然金和碳酸盐相金所占比例明显偏高;可溶相、游离自然金、碳酸盐相和硫化物相是阳山金矿成矿有利相态;赋矿地层金的成矿有利相态所占比例明显高于其他地层,即使金的合计与其他地层相近甚至较低。可根据成矿有利相态所占比例判断地层成矿潜力,这为岩石地球化学的异常评价提供了新的依据。     

金活动态提取ICP-MS法测定王家坪金矿床深穿透地球化学样品中的金

金属活动态测量方法是寻找隐伏矿的有效手段之一，但在方法应用过程中发现不同地球化学景观条件下金元素的有效活动态类型不尽相同，并且提取过程中固液比、温度、时间等条件会对活动态提取数据产生较大影响。为了探讨金元素活动态选择性提取及方法在秦岭地区的指示效果等问题，本文利用电感耦合等离子体质谱（ICP-MS）分析技术对秦岭地区王家坪金矿床金元素活动态提取的不同实验条件及不同粒级样品进行对比研究，确定了针对金元素水提取态、黏土吸附态、有机结合态和铁锰氧化物结合态的最佳提取条件为：固液比1：5，提取时间24h，提取温度35℃，采样粒级为-80目。金元素四个相态的方法检出限分别为：水提取态0.03ng/g，黏土吸附态0.03ng/g，有机结合态0.04ng/g，铁锰氧化物结合态0.05ng/g，精密度（RSD）为7.25%～9.02%。该方法应用于王家坪金矿床23线，经分析金元素各形态平均含量为：水提取态0.19×10^-9，黏土吸附态0.30×10^-9，有机结合态11.16×10^-9，铁锰氧化物结合态0.20×10^-9，其中有机结合态为矿区土壤中金元素赋存的主要活动相态，金的有机结合态异常与隐伏金矿体位置一致。     

黑龙江省特殊景观区化探土壤样品中钼的相态分析方法及应用

多年来通过化探扫面的全量异常分析结果发现的矿床并不多,在表生条件下,不同的元素随着区域景观条件的不同,其迁移、沉积规律以及元素原始的赋存状态也不同,化探分析给出元素的全量分析结果并不能完全准确地反映成矿情况,因而元素的存在形式和存在状态对于判断是否是成矿异常至关重要。本文建立了黑龙江地质景观特点的化探土壤样品中钼的相态分析方法,将钼的相态分为五相:水提取相、弱有机结合相、氧化物结合相、铁结合相、残渣相。采用ICP-MS测定钼元素各相态的检出限分别为:水提取相0.0011μg/g,弱有机结合相0.020μg/g,氧化物结合相0.100μg/g,铁结合相0.100μg/g,残渣相0.100μg/g。利用该方法分析了黑龙江某地有钼全量异常的样品,结果表明钼主要以铁结合相存在,属脉型产状,符合钼矿床的类型之一,研究结果提高了利用化探异常找矿的准确性。     

中子活化分析方法测量金的活动态

探讨了金的活动态各相态（水浸出态，粘土吸附态，有机链合态，铁锰氧化物态）提取操作和中子活化分析测定的条件。列出了部分样品中金活动态分析结果和其测定精度范围，各相态的空白值和RSD（n=5)分别为：水浸出态0.030ng/g,4.5%-26.0%；粘土吸附态0.05ng/g,11.6%-25.2%；有机链合态0.06ng/g,3.7%-26.8%；铁锰氧化物态0.05ng/g,5.9%－31.6％。     

金矿石的化学物相分析方法研究

根据金的主要矿物类型及其化学性质,确定了金的化学物相分析的相态,并选择适当的相态分离溶剂和测定方法,分离和测定各相态中的金,查明了样品中金呈游离自然金状态以及在各载体矿物中呈连生或包裹状态的量。使用国家标准物质对方法进行评价,本法火焰原子吸收法测定金的检出限是0.05×10^-6,石墨炉原子吸收法测定金的检出限是0.17×10^-9,方法的精密度为0.70%,准确度为1.32%;同时进行了样品重复分析,各相中金量测定结果的精密度符合测试质量规范要求。     

氢化物-原子荧光法快速测定化探样品中微量硒和碲

在沸水浴中用王水分解样品，以盐酸为还原剂，三价铁盐为干扰元素抑制剂（一般化探样品均含有铁，故无须另外加入），直接用氢化物一原子荧光光谱法测定化探样品中微量硒和碲。方法检出下限分别为：LD（Se）=0．1ng／L；LD（Te）=0．01ng／L。方法准确、简便、快速，可满足大批量化探样品中微量硒和碲的测定要求。用本分析方法测定不同基体成分的六个国家级化探标样中的硒、碲，测定结果与标准值基本一致，8次测定的标准偏差（RSD）分别为RSD（Se）=6．6％～9．5％，RSD（Te）=3．6％～8．4％。     

川西白马地区地表地球化学油气勘探方法的探索与实践

川西白马地区在开展前期试验和环境调查的基础上，选定了土壤吸附戏（Ｃ１－Ｃ５），后生碳酸盐（△Ｃ）、会相态汞、二价铁和电导率等五类九种化探指标这些指标的异常形态一般呈半环状或断续的条带状；各种化探异常在平面上的分布具相似性或相嵌性；所有指标的异常与工区内沙溪庙组底面主要构造高部位的平面位置吻合较好。圈定了九个化探远景区，在白马庙和松华镇两个远景区所钻的五口井，化探预测与钻探结果的符合率达７５％。实践     

二苯硫脲－甲基异丁酮泡塑富集液珠萃取比色法测定化探样品中的金银

在１０％ＨＣＩ介质中，采用二苯硫脲（ＤＰＴＵ）－甲基异丁酮（ＭＩＢＫ）泡沫塑料富集，以金试剂液珠萃取比色法测定了化探样品中的Ａｕ和Ａｇ。方法的检出限：Ａｕ０．５×１０￣－９；Ａｓ５×１０￣－９（１０ｇ称样）。利用此方法制备了“野外快速分析箱”，可在野外简陋条件下进行现场测定。     

泡塑富集-石墨炉原子吸收光谱法测定痕量金

介绍在Fe3 存在下,用泡沫塑料分离富集,以抗坏血酸和硝酸铵为基体改进剂,采用斜坡升温和长寿命石墨管技术进行化探样品中痕量金的石墨炉原子吸收光谱法测定方法。该方法已应用于化探样品中金的分析工作中,取得了令人满意的结果。     

不同景观区表生介质中金的赋存相态对比研究及其找矿意义

不同景观区内金矿床(点)上覆土壤中金的含量取决于该区金的丰度、赋存相态、地球化学活性以及风化成土作用聚集金的能力。本在对4类不同景观区内金矿(点)上覆土壤同一层位中金的赋存相态对比研究的基础上,对表生介质中金的不同相态提取方法应用于金矿勘查及其表生地球化学异常评价进行了探讨。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861