Electrical resistivity and hydrochemical indicators distinguishing chemical characteristics of subsurface pollution at Cuddalore coast,Tamil Nadu

Electrical resistivity methods are applied extensively for shallow sub-surface objectives but it has constraints in distinguishing the chemical characteristics of the medium. However, this complexity can be resolved by integrated investigations where geophysical anomaly would be validated with hydro-geochemical data. The present study highlights the notable importance of integrated geophysical and hydrogeological investigations in demarcating sub-surface pollution due to saline water intrusion and industrial effluents at Cuddalore coast in India. Geophysical scanning encompassing a total of 35 vertical electrical sounding (VES) were validated with drilling lithologs, water level and water quality parameters from a network of 125 observation wells at a test site of 17 km². To understand the spatial variation of sub-surface contamination, two profiles of apparent resistivity sections were generated covering VES points parallel to the coast. Results revealed that, the low order of resistivity range 3 to 10 Ω-m (up to 30–40 m depth) and total dissolved solids range 2000 to 10,000 mg/l of groundwater reflects sub-surface contamination but cannot distinguish kind of salinity which is further verified by chemical analysis of Ca²⁺ (1200–2041 mg/l), SO₄ ^2? (3000–9480 mg/l) which confirms the gypsum pollution and Na⁺ (750–1000 mg/l), Cl^? (1000–2000 mg/l) designate the marine water contamination. Further, static groundwater head measurements demarcate the study area into above mean sea level (MSL) and below MSL zones. This study has provided a rapid and comprehensive picture about spatial variations of groundwater contamination which can help in planning, protection and safe management of coastal aquifers in India and worldwide.     

Anthropogenic impact on Andaman coast monitoring with benthic foraminifera,Andaman Sea,India

The concept of anthropogenic impact is extremely important to be considered while analysing the ecology of coast and shelf zones. For centuries, these zones have been the epicentres for various human activities, including urbanisation, construction of sea ports and harbours, development of natural reservoirs (including oil production and fishing), marine aquaculture, shipping, recreation and many others. Many of the activities in progress on both sides of the shoreline provide 50% or more of the gross State/UT (Union Tertiary) product for surrounding states. The data shows that land-based and atmospheric sources account for about two-thirds of the total contamination found in the marine environment, constituting 44 and 33%, respectively. The greatest anthropogenic pollution pressure undoubtedly falls on the shelf zones and coastal areas. To prove this theory, a total of 25 bottom sediment samples were collected within the depth zone of 5 fathoms from the South Andaman coastal fringe for sediment geochemistry studies and foraminiferal analysis. The samples were further analysed for heavy metal pollutants like Co, Cu, Mn, Pb and Zn. The study yielded 20 benthic foraminiferal species. Of these, five benthic species were living including Ammonia beccarii, Calcarine calcar, Elphidium crispum, Operculina complanata and Nonion deppresula. The presence of deformed specimens and the domination of Ammonia spp. are indications of a polluted environment. Sampled coral reefs had high abundances of Operculina spp. The highest counts of benthic microbiota were found in finer sediment. Species diversity is very limited along the coastal fringe of South Andaman Island in comparison with fauna from the coast of India. This first report of benthic foraminifera from South Andaman Island will allow us to assess future impacts of marine pollution because foraminiferal deformations are positively correlated to the concentrations of heavy metals (Cr, Cu, Mn, Pb and Zn).     

Hydrogeochemistry and microbial contamination of groundwater from Lower Ponnaiyar Basin, Cuddalore District, Tamil Nadu, India

Groundwater is the major source of fresh water in regions where there is inadequate surface water resources. Forty-seven groundwater samples were collected from Lower Ponnaiyar basin, Cuddalore District, south India, during the premonsoon (PRM) and postmonsoon (POM) seasons of 2005. Out of 47 groundwater samples, 15 samples showing higher nitrate concentration were those collected during PRM 2005. Microbial analysis of these samples was carried out by employing 16S rRNA gene sequence tool. Detailed analysis was conducted to determine the hydrogeochemical processes and microbial contamination responsible for deterioration of quality. The abundance of the ions during PRM and POM are in the following order: Na?>?Ca?>?Mg?>?K?=?Cl?>?HCO₃?>?SO₄?>?CO₃. The dominant water types in PRM are in the order of NaCl?>?CaMgCl?>?mixed CaNaHCO₃, whereas during POM NaCl?>?CaMgCl?>?mixed CaNaHCO₃, and CaHCO₃. However, NaCl and CaMgCl are major water types in the study area. The quality of groundwater in the study area is mainly impaired by surface contamination sources, mineral dissolution, ion exchange and evaporation. Groundwater chemistry was used to assess quality to ensure its suitability for drinking and irrigation, based on BIS and WHO standards. Suitability for irrigation was determined on the basis of the diagram of US Salinity Laboratory (USSL), sodium absorption ratio (SAR), residual sodium carbonate (RSC), and Na%. According to SAR and USSL classification, 27.66% (PRM) and 40.43% (POM) of samples fall under C3S2 category, indicating high salinity and medium sodium hazard, which restrict its suitability for irrigation. Microbiological analysis and its effects on the water quality were also addressed. The 16S rRNA gene sequences of 11 bacterial contaminants exhibited five groups with 11 operational taxonomic units with aerobic and facultatively anaerobic organisms. The presence of aerobic organisms in the groundwater samples reflects the active conversion of ammonia to nitrite by Nitrosomonas sp. which is further converted to nitrates by other organisms. Further the presence of nitrate reducers could also play a role in the process of conversion of nitrate to ammonia and nitrate to molecular nitrogen.     

Anthropogenic influences on toxic metals in water and sediment samples collected from industrially polluted Cuddalore coast,Southeast coast of India

The present study was carried out to investigate the impact of anthropogenic influences on Cuddalore coast, Southeast coast of India, with regard to physicochemical parameters and heavy metal concentration in the surface water and sediment samples of the study area. The samples were collected in different seasons of the year (January–December 2010) and analysed for physicochemical parameters (Temperature, pH, salinity, nitrate, nitrite, ammonia, phosphate and silicate) and heavy metals (Cd, Cu, Pb and Zn) using standard methods. Results showed that physicochemical characteristics and heavy metals concentration in the samples of the study area were varied seasonally and spatially. The concentrations of heavy metals in water and sediment samples of the study area were higher in the monsoon season compared with those of other seasons. The heavy metal concentration in collected samples was found to be above WHO standards. The order of heavy metals in water and sediment samples was Pb > Cu > Cd > Zn. The heavy metal data were analysed through widely using multivariate statistical methods including principle component analysis (PCA) and cluster analysis (CA). CA classified the sampling sites into three clusters based on contamination sources and season. The PCA revealed that the season has a huge impact on the levels, types and distribution of metals found in water and sediment samples. The study also shows the main basis of heavy metals pollution at Cuddalore coast is land based anthropogenic inputs as a result of discharging of waste from industries, municipal, agricultural activities and sewage into estuarine regions, which carries the wastes into coastal area during tidal action. Statistical analyses and experimental data revealed that the Cuddalore coast may cause health risk to the recreational users and fisher folk, ultimately warrants environmental quality management to control heavy metal contamination.     

A study on hydrochemical characteristics of surface and sub-surface water in and around Perumal Lake,Cuddalore district,Tamil Nadu,South India

Hydrogeochemical investigations are carried out in and around Perumal Lake, Cuddalore district, South India in order to assess its suitability in relation to domestic and agricultural uses. The water samples (surface water = 16; groundwater = 12) were analyzed for various physicochemical attributes like pH, electrical conductivity (EC), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), magnesium (Mg²⁺), chloride (Cl⁻), bicarbonate (HCO₃ ⁻), sulfate (SO₄ ²⁻), phosphate (PO₄), silica (H₄SiO₄) and total dissolved solids (TDS). Major hydrochemical facies were identified using Piper trilinear diagram. Hydrogeochemical processes controlling the water chemistry are water–rock interaction rather than evaporation and precipitation. Interpretation of isotopic signatures reveals that groundwater samples recharged by meteoric water with few water–rock interactions. A comparison of water quality in relation to drinking water quality standard proves that the surface water samples are suitable for drinking purpose, whereas groundwater in some areas exceeds the permissible limit. Various determinants such as sodium absorption ratio (SAR), percent sodium (Na%), residual sodium carbonate (RSC) and permeability index (PI) revealed that most of the samples are suitable for irrigation.     

Metal pollution in coarse sediments of Tuticorin coast,Southeast coast of India

Indian coastal waters are subjected to considerable pressure from sewage and industrial wastes, which are responsible for the contamination of the coastal sediments with consequent loss in biosphere. The present investigation attempts to study the significance of coarse material (Sand fraction) in the distribution of metals in polluted marine sediments. The study revealed that coarse Sand component contains a relatively significant proportion of the anthropogenic metals (Cd, Cu, Pb and Zn) and therefore it cannot be neglected in metal pollution studies of coastal sediments. Further, the distribution of anthropogenic metals in both Silt + Clay and Sand fraction follow the same suit indicating similar pollution sources. From the total sediment type (Silt + Clay and Sand fraction) all anthropogenic metals had a noticeable amount (>50%) in the acid extractable (and potentially bio-available) fraction. This article stresses the importance of coarse fraction in metal pollution studies in Indian coastal system.     

Charnockite bedrock,Chennai coast,Tamil Nadu: Micromorphology and geochemical signatures in stages of the weathering processes

Occurrences of landslide are most common and critical issue in North-East India. The various types of slope failures have been affected most part of slopes and road section between Malidor to Sonapur area (approx 30 Km) along NH-44 within Jaintia hills district, Meghalaya, India. These slope failures causes considerable loss of life and property along with many inconveniences such as disruption of traffic along highways. The unscientific excavations of rock slopes for road widening or construction purposes may weaken the stability of the slopes. The rocks exposed in the area are highly jointed sandstone and shale of Barail Group of Oligocene age. The Sonapur landslide is most dangerous and destructive rock fall-cum debris flow. The present study includes the kinematic analysis of the slope to assess the potential failure directions as the rocks are highly jointed in some parts of road cut sections. The continuous slope mass rating (CSMR) technique has been applied for slope stability analysis at five vulnerable locations. Kinematic analysis indicates mainly wedge type of failure along with few toppling and planar failures. These failure required immediate treatment to prevent the slide and long term stability of the slope.     

First report of some Recent benthic foraminifera from the east coast of India

Twelve Recent benthic foraminiferal species hitherto not reported from the east and west coasts of India are presented and illustrated. They are, namely- Bolivina semicostata, Elphidium subgranulosum, Hanzawaia nipponica, Planorbulina variabilis, Pseudononion japponicum, Reussella haizumensis, Rosalina bradyi, Adelosina sp., Lagina sp. A, Lagina sp. B, Uvigerina sp. A and Uvigerina sp. B.     

Magnetic,chemical and x-ray studies of magnetites from Tamil Nadu,India

Natural intensity, susceptibility, and Koenigsberger ratio were determined and studies of Rayleigh loops, and high field hysteresis, and variation of susceptibility with temperature from ?196° C to Curie temperature were made on a number of magnetite-quartzite and pyroxene, granulite samples from Tamil Nadu. FeO, Fe₂O₃, and TiO₂ proportions were estimated and cell dimensions were determined. From the magnetic studies it is inferred that in general the samples contain predominantly multidomain grains. In a few cases single-domain particles are detected, while in a few other samples a mixture of superparamagnetic particles and single domain states could be inferred. The relative remanence ratio is found to increase with coercive force. The ferromagnetic mineral in magnetite-quartzites is pure magnetite with a little alteration to hematite while in pyroxene granulites it is a titaniferous magnetite with a small percentage of TiO₂. It is probable that the cell dimensions are dependent on oxidation in magnetites, and on the content of TiO₂ in titaniferous magnetites.     

Coastal morphology and beach stability along Thiruvananthapuram,south-west coast of India

Shoreline changes are largely dependent on coastal morphology. South-west coast of India is a high energy coast characterised by monsoon high waves, steep beach face and medium-sized beach sand. Waves are generally from west and west south-west during rough monsoon season and from south-west during fair weather season. Shoreline change along this coast is studied with reference to coastal morphological features. Various morphological features, modifications and chronological positions of shoreline are analysed with the information derived from multidated satellite imageries, toposheets and GPS shoreline mapping along with extended field survey. Image processing and GIS techniques have been used for the analysis of data and presentation of results. Sediment accumulation on the leeward side of artificial structures such as harbour breakwaters and groynes is used as a sediment transport indicator. Artificial structures such as seawalls, groynes and harbour breakwaters modify morphology. Shoreline south of headlands/promontories and breakwaters are stable or accreting due to net northerly longshore sediment transport while erosion tendency is observed on the north side. Lateritic cliffs fronting the sea or with seasonal beach undergo slumping and cliff edge retreat as episodic events. Spits adjoining tidal inlets are prone to shoreline variations due to oscillations of inlet mouth. Interventions in the form of inlet stabilization and construction of coastal protection structures trigger erosion along adjoining coasts. Seawalls constructed along highly eroding coasts get damaged, whereas those constructed along monsoon berm crest with frontal beaches for protection against monsoon wave attack are retained. Fishing gaps within seawalls are areas of severe temporary erosion during rough monsoon season. Accretion or erosion accompanies construction of harbour breakwaters in a stable coastal plain. Close dependence of shoreline changes on morphology necessitates detailed understanding of impacts on morphology prior to introducing any intervention in the coastal zone.     

Hydrogeochemical assessment of groundwater quality along the coastal aquifers of southern Tamil Nadu,India

Hydrogeochemical investigation of groundwater has been carried out in the coastal aquifers of southern Tamil Nadu, India. Seventy-nine dug well samples were collected and analyzed for various physicochemical parameters. The result of the geochemical analysis indicates the groundwater in the study area is slightly alkaline with moderate saline water. The cation and anion concentrations confirm most of the groundwater samples belong to the order of Na⁺ > Mg²⁺ > Ca²⁺ > K⁺ and Cl^? > SO₄ ^2? > HCO₃ ^?. Thereby three major hydrochemical facies (Ca–Cl, mixed Ca–Mg–Cl and Na–Cl) were identified. Based on the US Salinity diagram, majority of the samples fall under medium to very high salinity with low to high sodium hazard. The cross plot of Ca²⁺ + Mg²⁺ versus chloride shows 61 % of the samples fall under saline water category. Higher EC, TDS and Cl concentrations were observed from Tiruchendur to Koodankulam coastal zone. It indicates that these regions are significantly affected by saltwater contamination due to seawater intrusion, saltpan deposits, and beach placer mining activities.     

Wave-induced nearshore circulation along the Calangute-Candolim beach,Goa, west coast of India

The wave-induced nearshore circulation model suggested by Noda has been modified and applied for three small segments along the coast of Goa. The present model incorporates the prevailing bottom topography and considers its variation along with the radiation stress as the driving force for the circulation. We find that the flow pattern is strongly dependent on bottom topography. While normal incidence of waves results in a cellular pattern of flow, meandering flows prevail for oblique incidence along the coast. The shoreward flows are always located over shoals while the rip currents prevail over channels. The onshore/offshore flows show magnitudes as high as 3·1 m/s, while those alongshore reach a maximum of 1·1 m/s. When compared with field observations these values are slightly higher.     

Evaluation of geochemical impact of tsunami on Pichavaram mangrove ecosystem,southeast coast of India

The 26 December 2004-tsunami has deposited sediments in the Pichavaram mangrove ecosystem, east coast of India. Ten surface and three core sediment samples were collected within 30 days of the event and analyzed for nutrients. Water samples were also analyzed to see the impact of tsunami on the geochemical behavior of nutrients. An increase in the concentration of various nutrients namely nitrate and phosphate was observed. The geochemistry of the mangrove forest was observed to be influenced by a number of factors like rapid increase of aquaculture farms, agricultural practices and the anthropogenic discharge from the nearby-inhabited areas. Further the sediment column was disturbed due to energetic tsunami waves, which has caused a sheer increase in the dissolved oxygen in water. As a result, the change in the redox potential has resulted in change in the nutrients absorbed/associated with the sediments. In addition, role of retreating water after tsunami on the nutrient geochemistry was also evaluated.     

Recent benthic foraminifera and their distribution between Tuticorin and Tiruchendur, Gulf of Mannar, south-east coast of India

Foraminifera have been successful inhabitants of every aquatic environment from deep oceans to brackish water lagoons, estuaries and even rarely in freshwater streams, lakes, etc. In order to know their distribution in different offshore habitats, the present study has been undertaken between Tuticorin and Tiruchendur, wherein 31 bottom sediment and water samples were collected. Benthic foraminiferal taxa belonging to four suborders (Textulariina, Miliolina, Lagenina and Rotaliina), 14 superfamilies, 25 families, 45 genera and 66 species have been identified; three planktonic species (suborder Globigerinina) have also been identified. An increase in total foraminiferal distribution with depth has been observed, except off Tiruchendur. Living/dead ratios range from 1.57% to 10.02%, indicating a low to moderate rate of sedimentation in this region. Off Punnaikayal and Tiruchendur, the rate of sedimentation is more at greater depths; at other stations, however, it is higher at relatively shallower depths. Based on this study, it is concluded that fluctuations in the distribution of foraminifera are mainly controlled by coastal morphology, wave dynamics, bathymetry and environmental parameters.     

GPR studies over the tsunami affected Karaikal beach,Tamil Nadu,south India

In this study, results of GPR profiling related to mapping of subsurface sedimentary layers at tsunami affected Karaikal beach are presented . A 400 MHz antenna was used for profiling along 262 m stretch of transect from beach to backshore areas with penetration of about 2.0 m depth (50 ns two-way travel time). The velocity analysis was carried out to estimate the depth information along the GPR profile. Based on the significant changes in the reflection amplitude, three different zones are marked and the upper zone is noticed with less moisture compared to other two (saturated) zones. The water table is noticed to vary from 0.5 to 0.75 m depth (12–15 ns) as moving away from the coastline. Buried erosional surface is observed at 1.5 m depth (40–42 ns), which represents the limit up to which the extreme event acted upon. In other words, it is the depth to which the tsunami sediments have been piled up to about 1.5 m thickness. Three field test pits were made along the transect and sedimentary sequences were recorded. The sand layers, especially, heavy mineral layers, recorded in the test pits indicate a positive correlation with the amplitude and velocity changes in the GPR profile. Such interpretation seems to be difficult in the middle zone due to its water saturation condition. But it is fairly clear in the lower zone located just below the erosional surface where the strata is comparatively more compact. The inferences from the GPR profile thus provide a lucid insight to the subsurface sediment sequences of the tsunami sediments in the Karaikal beach.