Uniformity in sulfur isotope composition in the orogenic gold deposits from the Dharwar Craton,southern India

The sulfur isotope composition of sulfides (mainly pyrite and arsenopyrite) from gold deposits/prospects of the Dharwar Craton such as Hutti, Hira-Buddini, Uti, Kolar (Chigargunta), Ajjanahalli, and Jonnagiri has a narrow range (δ³⁴S = +1.1 to +7.1‰). Such craton-scale uniformity of the above gold camps is noteworthy, in spite of the wide diversity in host rock compositions and their metamorphic conditions, and suggests a magmatic or average crustal source of sulfur for all deposits studied. In addition, our study points towards gold precipitation from reduced ore fluids, with near-homogeneous sulfur isotope compositions.     

Relative timing of deformation and two-stage gold mineralization at the Hutti Mine, Dharwar Craton, India

Gold mineralization at Hutti is confined to a series of nine parallel, N–S to NNW–SSE trending, steeply dipping shear zones. The host rocks are amphibolites and meta-rhyolites metamorphosed at peak conditions of 660±40°C and 4±1 kbar. They are weakly foliated (S₁) and contain barren quartz extension veins. The auriferous shear zones (reefs) are typically characterized by four alteration assemblages and laminated quartz veins, which, in places, occupy the entire reef width of 2–10 m, and contain the bulk of gold mineralization. A <1.5 m wide distal chlorite-sericite (+biotite, calcite, plagioclase) alteration zone can be distinguished from a 3–5 m wide proximal biotite-plagioclase (+quartz, muscovite, calcite) alteration zone. Gold is both spatially and temporally associated with disseminated arsenopyrite and pyrite mineralization. An inner chlorite-K-feldspar (+quartz, calcite, scheelite, tourmaline, sphene, epidote, sericite) alteration halo, which rims the laminated quartz veins, is characterized by a pyrrhotite, chalcopyrite, sphalerite, ilmenite, rutile, and gold paragenesis. The distal chlorite-sericite and proximal biotite-plagioclase alteration assemblages are developed in microlithons of the S₂–S₃ crenulation cleavage and are replaced along S₃ by the inner chlorite-K-feldspar alteration, indicating a two-stage evolution for gold mineralization. Ductile D₂ shearing, alteration, and gold mineralization formed the reefs during retrograde evolution and fluid infiltration under upper greenschist to lower amphibolite facies conditions (560±60°C, 2±1 kbar). The reefs were reactivated in the D₃ dextral strike-slip to oblique-slip environment by fault-valve behavior at lower greenschist facies conditions (ca. 300–350°C), which formed the auriferous laminated quartz veins. Later D₄ crosscutting veins and D₅ faults overprint the gold mineralization. The alteration mineralogy and the structural control of the deposit clearly points to an orogenic style of gold mineralization, which took place either during isobaric cooling or at different levels of the Archean crust. From overlaps in the tectono-metamorphic history, it is concluded that gold mineralization occurred during two tectonic events, affecting the eastern Dharwar craton in south India between ca. 2550 – 2530 Ma: (1) The assemblage of various terranes of the eastern block, and (2) a tectono-magmatic event, which caused late- to posttectonic plutonism and a thermal perturbation. It differs, however, from the pre-peak metamorphic gold mineralization at Kolar and the single-stage mineralization at Ramagiri. Notably, greenschist facies gold mineralization occurred at Hutti 35–90 million years later than in the western Dharwar craton. Editorial handling: G. Beaudoin     

Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton

Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include(1) the famous Kolar mine and the world class Hutti deposit;(2) small mines at HiraBuddini, Uti, Ajjanahalli, and Guddadarangavanahalli;(3) prospects at Jonnagiri; and(4) old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous(H_2O + CO_2 ± CH_4 + NaCl) ore fluids,which precipitated gold and altered the host rocks in a narrow P-T window of 0.7-2.5 kbar and 215-320℃. While the calculated fluid O-and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs.magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite, pyrite and arsenopyrite point toward operation of fault-valves that caused pressure fluctuation-induced fluid phase separation, which acted as the dominant process of gold precipitation,apart from fluid-rock sulfidation reactions. Therefore, results from geochemistry of hydrothermal minerals and those from fluid inclusion microthermometry corroborate in constraining source of ore fluid,nature of gold transport(by Au-bisulfide complex) and mechanism of gold ore formation in the Dharwar Craton.     

黑龙江乌拉嘎金矿的次火山岩浆-热液成矿:熔体-流体包裹体证据

黑龙江乌拉嘎金矿是我国陆相火山岩区的重要金矿之一。构造位置处于古亚洲构造域与滨太平洋构造域交接复合部位的东北缘,矿体主要分布于团结沟斜长花岗斑岩接触带部位的隐爆角砾岩带和黑龙江群变质岩的层间裂隙中。斜长花岗斑岩的石英斑晶中发育3类包裹体:熔体包裹体、原生的L-V包裹体(及少量的L-V-S包裹体)和次生的L-V包裹体。玻璃质熔体包裹体相当于酸性殘浆的成分(SiO2达69.5%～73.8%),其捕获温度大于800℃。石英斑晶中次生L-V包裹体均一温度集中在210～350℃、盐度5%～7%NaCleqv,代表了次火山岩浆热液的特征,与黄铁矿-早期白色玉髓状石英阶段中Q1的包裹体均一温度范围很接近,而盐度略高于白色玉髓状石英Q1的。乌拉嘎金矿的金成矿可划分3个成矿阶段,发育盐水溶液包裹体:(1)黄铁矿-早期白色玉髓状石英阶段,包裹体均一温度为154～355℃,集中在190～330℃,盐度为1.3%～8.2%NaCleqv,密度为0.53～0.88g/cm3。(2)烟灰色玉髓状石英-多金属硫化物阶段,石英中包裹体均一温度为159～196℃,集中在170～190℃,盐度为2.2%～3.2%NaCleqv,密度0.79～0.92g/cm3。(3)碳酸盐-石英阶段,方解石中包裹体均一温度集中在170～270℃;盐度0.5%～2.9%NaCleqv。成矿流体以中低温、低盐度、贫CO2的盐水体系为特征,与国内外陆相火山-次火山热液矿床十分相似。石英斑晶中熔体、流体包裹体及其共存反映了次火山岩浆活动晚期,由硅酸盐熔体通过不混溶产生含矿的盐水溶液的可能,说明了金成矿与斑岩的成因联系,乌拉嘎金矿应该属于陆相火山-次火山活动有关的中低温浅成热液金矿床。     

Precambrian mafic magmatism in the Western Dharwar Craton,southern India

Mafic rocks of Western Dharwar Craton (WDC) belong to two greenstone cycles of Sargur Group (3.1–3.3 Ga) and Dharwar Supergroup (2.6–2.8 Ga), belonging to different depositional environments. Proterozoic mafic dyke swarms (2.4, 2.0–2.2 and 1.6 Ga) constitute the third important cycle. Mafic rocks of Sargur Group mainly constitute a komatiitic-tholeiite suite, closely associated with layered basic-ultrabasic complexes. They form linear ultramaficmafic belts, and scattered enclaves associated with orthoquartzite-carbonate-pelite-BIF suite. Since the country rocks of Peninsular Gneiss intrude these rocks and dismember them, stratigraphy of Sargur Group is largely conceptual and its tectonic environment speculative. It is believed that the Sargur tholeiites are not fractionated from komatiites, but might have been generated and evolved from a similar mantle source at shallower depths. The layered basic-ultrabasic complexes are believed to be products of fractionation from tholeiitic parent magma. The Dharwar mafic rocks are essentially a bimodal basalt-rhyolite association that is dominated by Fe-rich and normal tholeiites. Calc-alkaline basalts and andesites are nearly absent, but reference to their presence in literature pertains mainly to carbonated, spilitized and altered tholeiitic suites. Geochemical discrimination diagrams of Dharwar lavas favour island arc settings that include fore-, intra- and back-arcs. The Dharwar mafic rocks are possibly derived by partial melting of a lherzolite mantle source and involved in fractionation of olivine and pyroxene followed by plagioclase. Distinctive differences in the petrography and geochemistry of mafic rocks across regional unconformities between Sargur Group and Dharwar Supergroup provide clinching evidences in favour of distinguishing two greenstone cycles in the craton. This has also negated the earlier preliminary attempts to lump together all mafic volcanics into a single contemporaneous suite, leading to erroneous interpretations. After giving allowances for differences in depositional and tectonic settings, the chemical distinction between Sargur and Dharwar mafic suites throws light on secular variations and crustal evolution. Proterozoic mafic dyke swarms of three major periods (2.4, 2.0–2.2 and 1.6 Ga) occur around Tiptur and Hunsur. The dykes also conform to the regional metamorphic gradient, with greenschist facies in the north and granulite facies in the south, resulting from the tilt of the craton towards north, exposing progressively deeper crustal levels towards the south. The low-grade terrain in the north does not have recognizable swarms, but the Tiptur swarm consists essentially of amphibolites and Hunsur swarm mainly of basic granulites, all of them preserving cross-cutting relations with host rocks, chilled margins and relict igneous textures. There are also younger dolerite dykes scattered throughout the craton that are unaffected by this metamorphic zonation. Large-scale geochemical, geochronological and palaeomagnetic data acquisition through state-of-the-art instrumentation is urgently needed in the Dharwar craton to catch up with contemporary advancements in the classical greenstone terrains of the world.     

Carbonic fluid inclusions in ultrahigh-temperature granitoids from southern India

The granite plutons of Vattamalai (VT), Gangaikondan (GK) and Pathanapuram (PT) intruding granulite facies rocks in southern India were emplaced during the Late Neoproterozoic tectonothermal event. Feldspar thermometry of mesoperthites from the granites yield temperatures of 800–1000?°C indicating high- to ultrahigh-temperature conditions, comparable to similar estimates derived from some of the host granulite facies rocks in the region. This study reports results from a detailed investigation of fluid inclusions in the three granite plutons. Carbonic inclusions characterize the major fluid species in all the cases and their unique abundance in some of these plutons indicates up to 1 wt.% CO₂. In most of the cases, the inclusions show a near-pure CO₂ composition as deduced from melting temperatures which cluster close to $?56.6°$C, and as confirmed by laser Raman spectroscopy. The VT granite preserves the highest density CO₂ fluids among all the three plutons with a density up to 0.912 g?cm^?3 (molar volume of 48.25 cm³?mol^?1). A combination of CO₂ isochores, feldspar thermometry data and dehydration melting curves, and liquidus for water-undersaturated granitic systems clearly bring out a genetic link between these granites and granulitic lower crust. The ultimate origin of the CO₂-rich fluids is linked to sub-lithospheric mantle sources through tectonic processes associated with the assembly of the Gondwana supercontinent. To cite this article: M. Santosh et al., C. R. Geoscience 337 (2005).     

大青山东段九龙湾银-多金属矿床的次火山热液成因——流体包裹体证据

九龙湾银矿床位于内蒙古大青山东段，是近年来发现的有潜力的银多金属矿床。流体包裹体的岩相学、显微测温、激光拉曼探针及扫描电钐能谱分析研究表明，主成矿阶段的成矿流体以中低温（150-310℃）、中低盐度（3-17wt％NaCl）、较低密度（0．75～1．0g／cm^3）的盐水体系为特征，与造山型金矿床的富CO2流体有很大的差别。蚀变硅化阶段的流体相对富CO2、CH4、N2等挥发分，但在银铅锌主成矿阶段演化成贫CO2的盐水流体。九龙湾成矿流体的这种性质与国内外陆相火山一次火山热液型银矿床的成矿流体特征非常相似。矿床地质特征（与石英斑岩的关系、断裂控矿、围岩蚀变、矿石矿物共生组合）、稳定同位素地球化学特征均说明九龙湾银-多金属矿床应属与陆相次火山岩有关的中低温浅成热液矿床。     

Arc‐nascent back‐arc signature in metabasalts from the Neoarchaean Jonnagiri greenstone terrane,Eastern Dharwar Craton,India

The Neoarchaean Jonnagiri greenstone terrane (JGT) is located at the centre of the arcuate Hutti–Jonnagiri–Kadiri–Kolar composite greenstone belt in the eastern Dharwar Craton. High MgO (MgO = ~14 wt.%; Nb = 0.2 ppm), low Nb (LNB) (MgO = 7.8–12 wt.%; Nb = 0.1–5.1 ppm) and high Nb basalts (HNB) (MgO = 5.6–10.1 wt.%; Nb = 9.0–10.6 ppm) metamorphosed to lower amphibolite facies are identified based on their geochemical compositions. These metabasalts exhibit depleted HFSE (Nb–Ta, Zr–Hf), pronounced LREE and LILE enrichments suggesting contribution from subduction‐related components during their genesis. Th and U enrichment over Nb–Ta indicates influx of fluids dehydrated from subducted oceanic lithosphere. The high MgO basalts with higher Mg# (51) than that of the associated LNB and HNB (Mg# = 34–47) represent early fractionated melts of subduction‐modified mantle peridotite. The LNB were produced by partial melting of mantle wedge metasomatized by slab‐dehydrated fluids, whereas the HNB represents melts of subducted oceanic crust and hybridized mantle wedge. Lower Dy/Yb and variable La/Yb ratios suggest their generation at shallower depth within spinel peridotite stability field. The low Ce–Yb trend of these metabasalts reflects intraoceanic type subduction which straddles the fields of arc and back‐arc basin basalts, resembling the Mariana‐type arc basalts. The Jonnagiri metabasalts were derived in a paired arc‐back‐arc setting marked by nascent back‐arc rift system that developed in the proximity of an intraoceanic arc. Copyright © 2014 John Wiley & Sons, Ltd.     

Continental lithospheric evolution: Constraints from the geochemistry of felsic volcanic rocks in the Dharwar Craton,India

Felsic magmatism associated with ocean–ocean and ocean–continent subduction processes provide important evidence for distinct episodes of crust-generation and continental lithospheric evolution. Rhyolites constitute an integral component of the tholeiitic to calc-alkaline basalt–andesite–dacite–rhyolite (BADR) association and contribute to crustal growth processes at convergent plate margins. The evolution of the Dharwar Craton of southern peninsular India during Meso- to Neoarchean times was marked by extensive development of greenstone belts. These granite-greenstone terranes have distinct volcano-sedimentary associations consistent with their geodynamic setting. The present study deals with geochemistry of rhyolites from the Chitradurga-Shimoga greenstone belts of western (WDC) and the Gadwal-Kadiri greenstone belts of eastern (EDC) sectors of Dharwar Craton to compare and evaluate their petrogenesis and geodynamic setting and their control on the continental lithospheric evolution of the Dharwar Craton. At a similar range of SiO₂, Al₂O₃, Fe₂O₃, the rhyolites of WDC are more potassic, whereas the EDC rhyolites are more sodic and less magnesian with slight increase in TiO₂. Minor increase in MgO content of WDC rhyolites reflects their ferromagnesian trace elements which are comparatively lower in the rhyolites of EDC. The relative enrichment in LILE (K, Rb) and depletion in HFSE (Nb, Ta, Zr, Hf) marked by negative Nb–Ta, Zr–Hf and Ti anomalies endorse the convergent margin processes for the generation of rhyolites of both the sectors of Dharwar Craton. The high silica potassic rhyolites of Shimoga and Chitradurga greenstone belts of WDC showing prominent negative Eu and Ti anomalies, flat HREE patterns correspond to Type 3 rhyolites and clearly point towards their generation and emplacement in an active continental margin environment. The geochemical characteristics of Gadwal and Kadiri rhyolites from eastern Dharwar Craton marked by aluminous compositions with low and fractionated HREE patterns and minor negative Eu anomalies are in conformity with Type 1 rhyolites and suggest that they were erupted in an intraoceanic island arc system. The overall geochemical systematics of the rhyolites from both the sectors of Dharwar Craton suggest a change in the geodynamic conditions from intraoceanic island arc of eastern Dharwar Craton and an active continental margin of western Dharwar marked by ocean–ocean subduction and migration of oceanic arc towards a continent followed by arc-continent collision that contributed for the evolution of continental lithosphere in the Dharwar Craton.     

Geological setting and chemistry of kimberlite clan rocks in the Dharwar Craton, India

Diamond exploration in India over the past decade has led to the discovery of over 80 kimberlite-inferred and lamproite-related intrusions in three of the four major Archean cratons that dominate the subcontinent. These intrusions are Proterozoic (1.1 Ga), and are structurally controlled: locally (at the intersections of faults); regionally (in a 200 km wide, 1000 km long diamond corridor); and globally (in the reconstructed supercontinent of Rodinia). The geochemistry of 57 samples from 13 intrusions in the southern Dharwar Craton of Andhra Pradesh has been determined by XRF spectrometry. The bodies are iron-rich with mg#=50–70 and are neither archetypal kimberlites nor ideal lamproites; this may be the underlying reason that conventional exploration techniques have thus far failed to locate the primary sources of India's historically famous diamonds. The two major fields of kimberlite-clan rocks (KCR) in the Dharwar Craton, Wajrakur and Narayanpet, are separated by a NW–SE trending, transcontinental (Mumbai-Chennai) gravity lineament. About 80% of intrusions in Wajrakur are diamondiferous, but diamonds have not yet been reported in Narayanpet. The gravity anomaly may mark the boundary of an architectural modification in the keel of the sub-continental lithosphere, a suggestion that is supported by differences in kimberlite mineralogy, chemistry, mantle xenoliths, structural setting and crustal host rocks.     

Mafic and ultramafic magmatism and associated mineralization in the Dharwar craton,southern India

Evidence of mafic and ultramafic magmatism exists in many parts of the Dharwar craton which is divided into two blocks, the West Dharwar Craton (WDC) and the East Dharwar Craton (EDC). The mafic-ultramafic rocks occur in supracrustal/greenstone belts and in numerous enclaves and slivers in the WDC. The oldest recorded maficultramafic rocks, which are mainly komatiitic in nature, are preserved in the Sargur Group which is more than 3.3–3.4 Ga old, the youngest being manifested by 63–76 Ma old mafic dyke magmatism, possibly related to Deccan volcanism. In the Sargur Group, ultramafics rocks greatly dominate over mafic lithological units. Both extrusive and intrusive varieties, the latter in the form of differentiated layered complexes, occur. Mafic volcanics exists in all the greenstone belts of the eastern block and in the Bababudan and Western Ghats belts of the western block. In addition to the Sargur Group where stratigraphic sequences are unclear, mafic magmatism is recorded in three different formations of the Bababudan Group and two sub-divisions of the Shimoga and Chitradurga Groups where basaltic flows are conspicuous. In the well studied greenstone belts of Kolar and Hutti in the EDC, three to four different Formations of mafic volcanic rocks have been mapped. Isotopic dating has indicated that while mafic magmatism in the greenstone belts of the EDC covers only a short time span of between 2.65 to 2.75 Ga, those in the Dharwar Supergroup of the WDC cover a much longer time span from 3.35 to 2.5 Ga. Mafic dyke magmatism has taken place repeatedly from 2.45 Ga to about 1.0 Ga, but, the peak of emplacement was between 1.8 and 1.4 Ga when the densely developed swarms on the western and south western portions of the Cuddapah Basin and in the central part of Karnataka, were intruded. Emplacement of potassic ultramafic magma in the form of kimberlite-lamproite which is confined to the EDC, is a later magmatic event that took place between 1.4 Ga and 0.8 Ga. From a mineralization perspective, mafic magmatism of the supracrustal groups of the WDC and the greenstone belts of the EDC are the most important. V-Ti-magnetite bands constitute the most common deposit type recorded in the mafic-ultramafic complexes of the Sargur Group with commercially exploitable chromite deposits occurring in a number of belts. PGE mineralization of possible commercial value has so far been recorded in a single mafic-ultramafic complex, while copper-nickel mineralization occurs at certain localities in the Sargur and Chitradurga Groups. Gold mineralization hosted by mafic (occasionally ultramafic) rocks has been noted in many of the old workings located in supracrustal groups of rocks in the WDC and in the greenstone belts of EDC. Economically exploitable mineralization, however, occurs mainly in the greenstone belts of the Kolar, Ramagiri-Penkacherla and Hutti-Maski and along the eastern margin of the Chitradurga belt, where it is associated with a major N-S striking thrust zone separating the WDC from the EDC. Gold deposits of the eastern greenstone belts are comparable to those of the younger greenstone belts of Canada, Zimbabwe and Australia where the mineralization is associated with quartz carbonate veins often in iron-rich metabasic rocks. The gold was emplaced as hydrothermal fluids, derived from early komatiitic and tholeiitic magmas, and injected into suitable dilatent structures. The other common type of mineralization associated with the ultramafic rocks of the Sargur Group and supracrustal belts, particularly of the WDC, are asbestos and soapstone, related to autometamorphism/metasomatism. Ruby/sapphire deposits occur in places at the contacts of ultramafic rocks with the Peninsular Gneiss, and are related to contact metamorphism and metasomatism. Mineable magnesite deposits related to low-temperature hydrothermal/lateritic alteration exist in the zone of weathering, particularly in the more olivine-rich rocks. Recent spurt in diamond exploration is offering promise of discovering economically workable diamondiferous kimberlite/lamproite intrusions in the EDC.     

Hydrothermal gold mineralization at the Hira Buddini gold mine,India: constraints on fluid evolution and fluid sources from boron isotopic compositions of tourmaline

We determined the boron isotope and chemical compositions of tourmaline from the Hira Buddini gold deposit within the Archean Hutti-Maski greenstone belt in southern India to investigate the evolution of the hydrothermal system and to constrain its fluid sources. Tourmaline is a minor but widespread constituent in the inner and distal alteration zones of metabasaltic and metadacite host rocks associated with the hydrothermal gold mineralization. The Hira Buddini tourmaline belongs to the dravite–schorl series with variations in Al, Fe/(Fe+Mg), Ca, Ti, and Cr contents that can be related to their host lithology. The total range of δ¹¹B values determined is extreme, from −13.3‰ to +9.0‰, but 95% of the values are between −4 and +9‰. The boron isotope compositions of metabasalt-hosted tourmaline show a bimodal distribution with peak δ¹¹B values at about −2‰ and +6‰. The wide range and bimodal distribution of boron isotope ratios in tourmaline require an origin from at least two isotopically distinct fluid sources, which entered the hydrothermal system separately and were subsequently mixed. The estimated δ¹¹B values of the hydrothermal fluids, based on the peak tourmaline compositions and a mineralization temperature of 550°C, are around +1 and +10‰. The isotopically lighter of the two fluids is consistent with boron released by metamorphic devolatilization reactions from the greenstone lithologies, whereas the ¹¹B-rich fluid is attributed to degassing of I-type granitic magmas that intruded the greenstone sequence, providing heat and fluids to the hydrothermal system. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Synplutonic mafic dykes from late Archaean granitoids in the Eastern Dharwar Craton,southern India

We present a first overview of the synplutonic mafic dykes (mafic injections) from the 2.56–2.52 Ga calcalkaline to potassic plutons in the Eastern Dharwar Craton (EDC). The host plutons comprise voluminous intrusive facies (dark grey clinopyroxene-amphibole rich monzodiorite and quartz monzonite, pinkish grey porphyritic monzogranite and grey granodiorite) located in the central part of individual pluton, whilst subordinate anatectic facies (light grey and pink granite) confined to the periphery. The enclaves found in the plutons include highly angular screens of xenoliths of the basement, rounded to pillowed mafic magmatic enclaves (MME) and most spectacular synplutonic mafic dykes. The similar textures of MME and adjoining synplutonic mafic dykes together with their spatial association and occasional transition of MME to dismembered synplutonic mafic dykes imply a genetic link between them. The synplutonic dykes occur in varying dimension ranging from a few centimeter width upto 200 meters width and are generally dismembered or disrupted and rarely continuous. Necking of dyke along its length and back veining of more leucocratic variant of the host is common feature. They show lobate as well as sharp contacts with chilled margins suggesting their injection during different stages of crystallization of host plutons in magma chamber. Local interaction, mixing and mingling processes are documented in all the studied crustal corridors in the EDC. The observed mixing, mingling, partial hybridization, MME and emplacement of synplutonic mafic dykes can be explained by four stage processes: (1) Mafic magma injected during very early stage of crystallization of host felsic magma, mixing of mafic and felsic host magma results in hybridization with occasional MME; (2) Mafic magma introduced slightly later, the viscosities of two magmas may be different and permit only mingling where by each component retain their identity; (3) When mafic magma injected into crystallizing granitic host magma with significant crystal content, the mafic magma is channeled into early fractures and form dismembered synplutonic mafic dykes and (4) Mafic injections enter into largely crystallized (>80% crystals) granitic host results in continuous dykes with sharp contacts. The origin of mafic magmas may be related to development of fractures to mantle depth during crystallization of host magmas which results in the decompression melting of mantle source. The resultant hot mafic melts with low viscosity rise rapidly into the crystallizing host magma chamber where they interact depending upon the crystallinity and viscosity of the host. These hot mafic injections locally cause reversal of crystallization of the felsic host and induce melting and resultant melts in turn penetrate the crystallizing mafic body as back veining. Field chronology indicates injection of mafic magmas is synchronous with emplacement of anatectic melts and slightly predates the 2.5 Ga metamorphic event which affected the whole Archaean crust. The injection of mafic magmas into the crystallizing host plutons forms the terminal Archaean magmatic event and spatially associated with reworking and cratonization of Archaean crust in the EDC.     

Multi-stage crustal growth and Neoarchean geodynamics in the Eastern Dharwar Craton,southern India

The Dharwar Craton is a composite Archean cratonic collage that preserves important records of crustal evolution on the early Earth. Here we present results from a multidisciplinary study involving field investigations, petrology, zircon SHRIMP U–Pb geochronology with in-situ Hf isotope analyses, and whole-rock geochemistry, including Nd isotope data on migmatitic TTG (tonalite-trondhjemite-granodiorite) gneisses, dark grey banded gneisses, calc-alkaline and anatectic granitoids, together with synplutonic mafic dykes along a wide Northwest – Southeast corridor forming a wide time window in the Central and Eastern blocks of the Dharwar Craton. The dark grey banded gneisses are transitional between TTGs and calc-alkaline granitoids, and are referred to as ‘transitional TTGs’, whereas the calc-alkaline granitoids show sanukitoid affinity. Our zircon U–Pb data, together with published results, reveal four major periods of crustal growth (ca. 3360-3200 Ma, 3000-2960 Ma, 2700-2600 Ma and 2570-2520 Ma) in this region. The first two periods correspond to TTG generation and accretion that is confined to the western part of the corridor, whereas widespread 2670-2600 Ma transitional TTG, together with a major outburst of 2570–2520 Ma juvenile calc-alkaline magmatism of sanukitoid affinity contributed to peak continental growth. The transitional TTGs were preceded by greenstone volcanism between 2746 Ma and 2700 Ma, whereas the calc-alkaline magmatism was contemporaneous with 2570–2545 Ma felsic volcanism. The terminal stage of all four major accretion events was marked by thermal events reflected by amphibolite to granulite facies metamorphism at ca. 3200 Ma, 2960 Ma, 2620 Ma and 2520 Ma. Elemental ratios [(La/Yb)_N, Sr/Y, Nb/Ta, Hf/Sm)] and Hf-Nd isotope data suggest that the magmatic protoliths of the TTGs emplaced at different time periods formed by melting of thickened oceanic arc crust at different depths with plagioclase + amphibole ± garnet + titanite/ilmenite in the source residue, whereas the elemental (Ba–Sr, [(La/Yb)_N, Sr/Y, Nb/Ta, Hf/Sm)] and Hf-Nd isotope data [εHf_(T) = −0.67 to 5.61; εNd_(T) = 0.52 to 4.23; ] of the transitional TTGs suggest that their protoliths formed by melting of composite sources involving mantle and overlying arc crust with amphibole + garnet + clinopyroxene ± plagioclase + ilmenite in the residue. The highly incompatible and compatible element contents (REE, K–Ba–Sr, Mg, Ni, Cr), together with Hf and Nd isotope data [εHf_(T) = 4.5 to −3.2; εNd_(T) = 1.93 to −1.26; ], of the sanukitoids and synplutonic dykes suggest their derivation from enriched mantle reservoirs with minor crustal contamination. Field, elemental and isotope data [εHf_(T) = −4.3 to −15.0; εNd_(T) = −0.5 to −7.0] of the anatectic granites suggest their derivation through reworking of ancient as well as newly formed juvenile crust. Secular increase in incompatible as well as compatible element contents in the transitional TTGs to sanukitoids imply progressive enrichment of Neoarchean mantle reservoirs, possibly through melting of continent-derived detritus in a subduction zone setting, resulting in the establishment of a sizable continental mass by 2700 Ma, which in turn is linked to the evolving Earth. The Neoarchean geodynamic evolution is attributed to westward convergence of hot oceanic lithosphere, with continued convergence resulted in the assembly of micro-blocks, with eventual slab break-off leading to asthenosphere upwelling caused extensive mantle melting and hot juvenile magma additions to the crust. This led to lateral flow of hot ductile crust and 3D mass distribution and formation of an orogenic plateaux with subdued topography, as indicated by strain fabric data and strong seismic reflectivity along an E-W crustal profile in the Central and Eastern blocks of the Dharwar Craton.     

New Data on the Mineralogy of Chromite from the Nuggihalli Schist Belt, Western Dharwar Craton, Karnataka, India: Petrogenetic Implications

The occurrence of rhythmic layering of chromite and host serpentinites in the deformed layered igneous complexes has been noticed in the Nuggihalli schist belt (NSB) in the western Dharwar craton, Karnataka, South India. For this study, the chromitite rock samples were collected from Jambur, Tagadur, Bhakatarhalli, Ranganbetta and Byrapur in the NSB. Petrography and ore microscopic studies on chromite show intense cataclasis and alteration to ferritchromite. The ferritchromite compositions are characterized by higher Cr number (Cr/[Cr+Al]) (0.68–0.98) and lower Mg number (Mg/[Mg+Fe]) (0.33–0.82) ratios in ferritchromite compared to that of parent chromite. The formation process for the ferritchromite is thought to be related to the exchange of Mg, Al, Cr, and Fe between the chromite, surrounding silicates (serpentines, chlorites), and fluid during serpentinization.     

Genesis of the Maanqiao gold deposit in the western Qinling orogen,central China: Constraints from fluid inclusions and in-situ sulfur isotopes

The western Qinling orogen (WQO) is one of the most important prospective gold provinces in China. The Maanqiao gold deposit, located on the southern margin of the Shangdan suture, is a representative gold deposit in the WQO. The Maanqiao deposit is hosted by the metasedimentary rocks of the Upper Devonian Tongyusi Formation. The EW-trending brittle-ductile shear zone controls the orebodies; they occur as disseminated, and auriferous quartz–sulfide vein. The ore-related hydrothermal alteration comprises silicification, sulfidation, sericitization, chloritization, and carbonatization. Native gold is visible and mainly associated with pyrite and pyrrhotite. Mineralization can be classified into the following three stages: bedding-parallel barren quartz–pyrite–(pyrrhotite) (early-stage), auriferous quartz–polymetallic (middle-stage), and carbonate–(quartz)–sulfide (late-stage).Detailed fluid inclusion (FI) studies revealed three types of inclusions in quartz and calcite: aqueous (W-type), CO₂–H₂O (C-type), and pure carbonic (PC-type) FIs. The primary FIs in the early-stage quartz are C- and PC-type, in the middle-stage quartz are mainly W- and C-type, and in the late-stage calcite are only W-type. During gold mineralization, the total FI homogeneous temperatures evolved from 189–375 °C (mostly 260–300 °C) to 132–295 °C (mostly 180–240 °C) to 123–231 °C (mostly 130–150 °C), and the salinities varied among 2.2–9.1 wt.% NaCl equiv. (mostly 5–8 wt.%) to 0.2–9.0 wt.% NaCl equiv. (mostly 3–6 wt.%) to 0.3–3.6 wt.% NaCl equiv. (mostly 2–4 wt.%). The ore-forming fluid was characterized as an H₂O–NaCl−CO₂−CH₄–(N₂) system with medium-low temperature and low salinity. The fluid immiscibility and fluid-rock interaction may be responsible for the precipitation of the sulfides and gold at the Maanqiao gold deposit. Three types of pyrite corresponding to the three mineralization stages, as well as pyrrhotite and arsenopyrite in the middle stage, are micro-analyzed for in-situ sulfur isotopic composition by LA-ICP-MS. Py1 yield near-zero δ³⁴S values of −2.5‰ to 3.0‰, which are somewhat lower than that of the granite hosted pyrites (Py-g, 4.8‰ to 6.6‰). The result suggests a mixed sulfur source from magmatic-hydrothermal fluids and the metamorphism of diagenetic pyrite. Pyrite + pyrrhotite + arsenopyrite assemblages in the middle-stage have relatively higher δ³⁴S values (6.6‰ to 12.3‰) and are mainly developed due to the metamorphism of the ore-host and underlying Devonian sedimentary sequences. The low δ³⁴S values of the late-stage fracture-filled Py3 (−21.9‰ to −17.0‰) resulted from an increasing oxygen fugacity, which was caused by the inflow of oxidized meteoric waters.Based on our studies, the Maanqiao gold deposit is considered to be an orogenic type and closely related to the Indosinian Qinling orogeny.     

Hydrothermal fluid geochemistry at the Chah-Firuzeh porphyry copper deposit,Iran: Evidence from fluid inclusions

The Chah-Firuzeh porphyry copper deposit is located in 35 km north of Shahre Babak (Kerman province). It is associated with granodioriteic intrusive of Miocene age which intruded Eocene volcanosedimentary rocks. Copper mineralization was accompanied by both potassic and phyllic alteration. Field observations and petrographic studies demonstrate that the emplacement of Chah-Firuzeh pluton took place in several intrusive pulses, each with associated hydrothermal ore fluid formation that was also associated with hydrostatic pressure increasing respect to that of lithostatic pressure (and fracturing development-relative boiling) by circulated fluid. Copper is concentrated as a very early hydrothermal mineralized phase in the evolution of the hydrothermal system. Early hydrothermal alteration produced a potassic assemblage (orthoclase–biotite) in the central deep part of the stock. Alteration ore fluids could be classify into two groups of liquid-reach, containing solid phases, high temperature (390 to 500 °C) high salinity (more than 60 wt.% NaCl equiv.) and gas-rich, high temperature (311 to 570 °C), no solid phase and with low salinities. These magmatic source fluids illustrate sever boiling process and also are the responsible for the both potassic alteration, quartz group I and II veins and chalcopyrite deposition. Propylitic alteration occurred by the liquid-rich, low temperature (241 to 390 °C) and Ca-rich fluid with meteoric origin. Continuous decreasing temperature let the meteoric water diffusion into the system, mixed with magmatic fluids and descending the salinities down to the 1 wt.% NaCl equiv. and leaching the Cu from vein groups II and III by sever thermodynamic anarchies from potassic to the phyllic alteration zones. Phyllic alteration and copper leaching resulted from the inflow of oxidized and acidic meteoric waters with decreasing temperature of the system followed by the incursion of this fluid into and its convection in upper part of the system. A late episode of boiling occurred in the apical the phyllic zone, and was associated with significant copper deposition. Based on the field observation on sharp alteration and related mineralization, it is possible to conclude that all these procedures have been controlled by local faults that could be active even before the pluton injection. These faults and the new form ones (which have been formed after injection), could crash the hosted rocks, and act as physical dams to restrict and limit the mineralization in special strikes and zones within the Cah-Firuzeh ore deposit.     

The drift history of the Dharwar Craton and India from 2.37 Ga to 1.01 Ga with refinements for an initial Rodinia configuration

Coupled paleomagnetic and geochronologic data derived from mafic dykes provide valuable records of continental movement. To reconstruct the Proterozoic paleogeographic history of Peninsular India, we report paleomagnetic directions and U-Pb zircon ages from twenty-nine mafic dykes in the Eastern Dharwar Craton near Hyderabad. Paleomagnetic analysis yielded clusters of directional data that correspond to dyke swarms at 2.37 Ga, 2.22 Ga, 2.08 Ga, 1.89–1.86 Ga, 1.79 Ga, and a previously undated dual polarity magnetization. We report new positive baked contact tests for the 2.08 Ga swarm and the 1.89–1.86 Ga swarm(s), and a new inverse baked contact test for the 2.08 Ga swarm. Our results promote the 2.08 Ga Dharwar Craton paleomagnetic pole (43.1° N, 184.5° E; A95 = 4.3°) to a reliability score of R = 7 and suggest a position for the Dharwar Craton at 1.79 Ga based on a virtual geomagnetic pole (VGP) at 33.0° N, 347.5° E (a95 = 16.9°, k = 221, N = 2). The new VGP for the Dharwar Craton provides support for the union of the Dharwar, Singhbhum, and Bastar Cratons in the Southern India Block by at least 1.79 Ga. Combined new and published northeast-southwest moderate-steep dual polarity directions from Dharwar Craton dykes define a new paleomagnetic pole at 20.6° N, 233.1° E (A95 = 9.2°, N = 18; R = 5). Two dykes from this group yielded 1.05–1.01 Ga ²⁰⁷Pb/²⁰⁶Pb zircon ages and this range is taken as the age of the new paleomagnetic pole. A comparison of the previously published poles with our new 1.05–1.01 Ga pole shows India shifting from equatorial to higher (southerly) latitudes from 1.08 Ga to 1.01 Ga as a component of Rodinia.     

西藏邦布石英脉型金矿床的成因: 流体包裹体及氢-氧同位素证据

西藏邦布石英脉型金矿床是产于印度-亚洲板块陆-陆造山主碰撞汇聚环境下、与大洋俯冲无关的新型造山型金矿床。该矿床位于雅鲁藏布江缝合带南侧朗杰学增生楔的东段南缘,矿体受区域内EW向金地-鲁农复向斜和错古-折木朗壳型脆-韧性剪切带及其次级构造的控制。金矿化主要与石英脉密切相关,并包裹于脉内细粒/粗粒硫化物中。矿区内主要分布有3期石英脉:成矿前钩状石英脉、成矿期石英大脉和成矿后陡立状石英脉。文章对3期石英脉流体包裹体形态、形成温度、密度及H-O同位素等方面进行了详细的对比研究,试图查明成矿流体来源以及金的沉淀机制等问题。研究表明,钩状石英脉内包裹体主要为液相(L)包裹体,成分主要为H₂O溶液,其流体可能为早期区域变质的产物;石英大脉内包裹体主要为含CO₂气液(VL)两相包裹体,体积较大,成分主要为H₂O+CO₂+CH₄±N₂,成矿流体为深源变质流体,并与变质地层中的有机质发生强烈反应;陡立状石英脉内包裹体主要为气液两相包裹体,体积较小,其主要成分为H₂O+CO₂,流体主要与后期区域变质事件有关,为成矿后变质作用的产物。邦布金矿的主要成矿流体源自深部变质流体,流体不混溶作用可能是导致金矿沉淀的主要原因。     

晚期折返过程含石墨流体包裹体及其意义：以印度两个不同地体为例

Archean greenstone belts and Proterozoic granulite mobile belts are products of fundamentally different tectonic processes that culminated in different levels of crustal incision.The present study focuses on graphite-bearing fluid inclusions from two such terrains in India,the Angul domain of Eastern Ghats Mobile Belt and Hutti-Maski schist belt of the eastern Dharwar greenstone-granite belt.In beth cases,a high population of such inclusions within the fluid inclusion assemblage rules out the possibility of graphite being a captive phase,and instead confirms that it was deposited by the fluid within the inclusion cavity.Graphite is usually observed to be occurring with either pure water or a pure carbonic( CO_2 only)liquid,or with a CH_4 dominated carbonic liquid without vapor at room temperature.Graphite precipitation in inclusions is brought about by reaction of the CO2 and CH4 trapped as a homogeneous fluid to give rise to H_2O and C(graphite).Molar volume calculations for the CO_2-CH_4 mixture assuming an appropriate PVTX relationship indicates that there is a substantial increase in volume with decreasing pressure at a given temperature.The reaction producing graphite and H_2O from CH_4 and CO_2 involves substantial volume reduction,and hence would be favored when the rock undergoes rapid exhumation.Graphite-beating inclusions in quartz in a late-stage leucosome from migmatites in the Angul domain of the EGMB are accompanied by other fluid inclusion evidence for isothermal decompression.In the Hutti-Maski schist belt of the eastern Dharwar Craton,graphite-bearing inclusions occur in structurally controlled quartz veins(often auriferous)within metamorphosed mafic volcanics(schists and amphibolites).The Raman spectra indicate that graphites in fluid inclusions from the Hutti-Maski schist belt have both ordered(O)and the disordered(D)peaks,whereas those from the Angul area of EGMB lack the disordered(D)peaks, with both having perfectly symmetrical‘S’peak.This implies that in both belts,exhumation from the burial depth maxima was a rapid process.However,the Hutti-Maski schist belt experienced a lower amount of uplift than the Angul domain,where the driving mechanism led to a deeper level of incision.This difference in the extent and rate of exhumation is speculated to be related to a fundamental difference in the nature of tectonism.A more detailed comparative study of the fluid inclusion characteristics would possibly throw more light on the changing tectonic style from the Archean to the Proterozoic,a topic that is extensively debated.