滇西龙陵地区花岗岩LA-ICP-MSU-Pb定年及其地质意义

在详细区域地质调查的基础上,对滇西龙陵地区花岗质糜棱岩样品中的锆石进行了阴极发光图像、微区原位LA-ICP-MS微量元素分析和U-Pb定年。结果表明,梁河地区钾长花岗岩锆石显示振荡环带的内部结构,指示其岩浆成因。样品的锆石~(206)Pb/~(238)U加权平均年龄为(504.1±2.9)Ma,属中寒武世花岗岩。结合区域地质特征,龙陵地区在寒武纪存在岩浆作用,说明怒江缝合带以西的变质基底岩石经历过泛非造山运动,为青藏高原南部的构造演化提供了新资料。     

滇西梁河地区闪长岩LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义

对滇西梁河地区早白垩世闪长岩岩株中的花岗闪长岩和闪长岩进行了LA-ICP-MS锆石U-Pb年龄测试,获得206Pb/238U年龄分别为118.7Ma±1.5Ma和119.8Ma±1.0Ma,表明它们与早白垩世花岗岩体基本同时形成。其中在闪长岩中发现1颗约140Ma的岩浆锆石,可能指示梁河地区早白垩世初期的岩浆事件,2颗晚三叠世锆石继承核的年龄分别为208.2Ma±6.7Ma和221.9Ma±2.4Ma,记录了印支期的岩浆活动。花岗闪长岩和闪长岩具有相似的全岩εNd(t)值(-8.03、-7.70),但却表现出不均一的锆石εHf(t)值(118.7Ma:-5.60~-3.28;119.8Ma:-6.73~-3.09),表明它们来自于结晶基底重熔的长英质岩浆与幔源岩浆的混合。不同锆石的Hf同位素组成显示,与北冈底斯带相比,滇西梁河地区早白垩世幔源组分参与花岗质岩石形成的程度较低。滇西梁河地区花岗闪长岩和闪长岩的形成,可能与地壳加厚的构造背景有关。     

滇西腾冲-梁河地块早白垩世岩浆作用

滇西腾冲-梁河地区分布有大量的花岗岩。本文对梁河地区二长花岗岩进行了锆石LA-ICPMS U-Pb测年和Hf同位素分析,研究表明,锆石具有清晰的韵律环带,其Th/U值为0.34～1.65,为典型的岩浆锆石;锆石U-Pb年龄显示,花岗岩有三个年龄峰值(139.6±2.3Ma、129.7±5.2 Ma和118.8±4.2 Ma),表明该区早白垩世经历了多期岩浆作用;εHf(t)值为-20.15～-30.65,tCDM为2458～3083Ma,暗示花岗岩源自古老地壳部分熔融。该区片麻岩中具有2503Ma的碎屑锆石年龄,据此推测可能存在新太古宙基底。上述研究说明,该区早白垩世花岗岩的形成可能与班公湖-怒江洋的俯冲作用有关。     

滇西梁河三叠纪花岗岩的锆石微量元素、U-Pb和Hf同位素组成

在详细的区域地质调查基础上,分析了滇西梁河三叠纪花岗岩中锆石微区微量元素、U-Pb年龄和Hf同位素。花岗岩中大部分锆石具有振荡环带,为典型岩浆锆石,并发现独特的双核结构锆石,具有核幔边结构,双核锆石继承核与本文岩浆锆石有类似的微量元素特征,而双核锆石增生边(低轻稀土、轻微负Ce异常、高重稀土、低Th、高U、Ti、P)与它们不同。注意到双核锆石外围有一圈灰白色热液蚀变边,认为双核锆石增生边的微量元素特征可能是自身结晶生长过程和后期蚀变影响的综合结果,继承核和增生边同为岩浆成因。双核锆石继承核的206Pb/238U年龄分别为302.5±2.9Ma和289.9±2.5Ma,双核锆石增生边和其他岩浆锆石的206Pb/238U加全平均年龄为213.1±1.7Ma(MSWD=7.7),晚三叠世花岗岩的锆石具有负的εHf(213Ma)值(-9.6～-6.7),并且其tDM2Hf值(1.6～1.8Ga)远大于其结晶年龄,结合大地构造演化,认为花岗岩的形成可能与后碰撞伸展背景下古老地壳熔融相关。     

海拉尔盆地三期花岗岩的锆石U-Pb年龄及其意义

针对海拉尔盆地霍尔坡山岩体、阿浪托洛果伊岩体以及嵯岗岩体的花岗质岩石进行岩石学和锆石LA-ICP-MS U-Pb年代学研究,以便精确限定盆地内花岗岩的形成时代及盆地与区域构造演化的关系。分别采自各岩体的3个花岗岩样品的锆石均呈半自形-自形柱状,显示典型的岩浆生长环带,Th/U比值为0.26~2.08,具有典型的岩浆成因特征。嵯岗岩体细粒钾长花岗岩中锆石的~(206)Pb/238 U加权平均年龄为226.2Ma±2.3Ma,表明其形成时代为晚三叠世,而不是前人确定的石炭世,霍尔坡山岩体钾长花岗岩和阿浪脱洛果依岩体的斜长花岗岩锆石的206Pb/238 U加权平均年分别为155.8 Ma±1.8 Ma和131.5 Ma±1.8 Ma,代表两个岩体的形成时代分别为晚侏罗世和早白垩世,并非同属晚侏罗世。综合分析:嵯岗岩体钾长花岗岩的形成可能为古亚洲洋闭合后伸展作用的产物;霍尔坡山岩体钾长花岗岩的形成应与蒙古-鄂霍茨克洋造山后伸展作用有关;阿浪脱洛果依岩体的斜长花岗岩形成于板内裂谷环境,其形成与蒙古-鄂霍茨克洋的演化密切相关。     

新疆西准噶尔拉巴花岗岩地球化学特征及年代学研究

新疆西准噶尔玛依勒地区的拉巴岩体侵入于下石炭统包古图组中,由花岗闪长岩、石英闪长岩、英云闪长岩、花岗岩组成,以花岗岩为主。其中花岗岩和花岗闪长岩属钙碱性、高钾钙碱性系列,为偏铝质至过铝质岩石,并具有轻稀土-大离子亲石元素富集、Nb-Ta-Ti等高场强元素亏损的地球化学特征。该岩体两个代表样品的锆石La-ICP-MS法206Pb/238U加权平均年龄分别为287±5Ma和295.1±2.3Ma,表明岩体的结晶年龄为早二叠世,与西准噶尔地区后碰撞花岗岩的时代(年龄峰值310～295Ma)相近。综合岩体的地质、地球化学特征和区域地质特征,认为拉巴花岗岩体为准噶尔地区后碰撞阶段伸展期的岩浆活动产物。     

滇西腾冲—梁河古近纪花岗岩锆石U-Pb定年、Hf同位素及地球化学

滇西腾冲—梁河地区发育古近纪二长花岗岩和钾长花岗岩,记录了印度-欧亚大陆碰撞的岩浆活动信息。二长花岗岩的锆石U-Pb年龄为51.4±0.4 Ma,其176 Hf/177 Hf值为0.282554~0.282592,εHf(t)=-6.65~-5.30,其二阶段模式年龄为1.46~1.55Ga。腾冲—梁河古近纪花岗岩以高SiO2(68.96%~78.68%)、高K2O(4.56%~6.29%)和高Al2O3(12.40%~16.42%)为特征,K2O/Na2O值为0.93~7.24,Al2O3(K2O+Na2O),A/CNK值为0.99~2.31,属于富钾钙碱性偏铝—强过铝质花岗岩;绝大多数样品具有强烈的负Eu异常(Eu/Eu*为0.19~0.51),富集Cs、Rb,亏损Sr、P、Ti、Ba、Nb、Ta,具有Pb的正异常。元素地球化学特征指示,其主要源于区域上地壳变质杂砂岩的部分熔融;结合区域地质,认为腾梁地区62~51Ma的花岗岩是对印度-欧亚大陆碰撞高峰期的岩浆响应。     

滇西腾冲-梁河地区花岗岩锆石稀土元素组成和U-Pb同位素年龄

在详细的区域地质调查基础上,对滇西腾冲-梁河地区花岗岩的锆石进行了阴极发光观察,并通过LA-ICP-MS分析了其稀土元素组成和U-Pb同位素年龄。花岗岩中大部分锆石具有振荡环带,锆石稀土元素表现为亏损轻稀土、阶梯式富集重稀土、强烈正Ce异常及强烈负Eu异常,表明锆石为典型的岩浆锆石。花岗岩（D0053）锆石的²⁰⁶Pb/²³⁸U加权平均年龄为（127.9±1.0） Ma (MSWD=2.9,27个点),花岗岩（D4310）锆石的²⁰⁶Pb/²³⁸U加权平均年龄为（58.3±0.5） Ma (MSWD=1.8,21个点),表明腾冲-梁河地区存在大量早白垩世和早第三纪花岗岩浆活动,它们是特提斯演化过程的岩浆响应。     

内蒙古东乌旗索纳嘠铅锌银矿区花岗岩地球化学特征及其构造与成矿意义

内蒙古东乌旗索纳嘎铅锌银矿区赋矿侵入岩为一由中粗粒花岗岩、细粒黑云母花岗岩和似斑状钾长花岗岩组成的杂岩体.三种岩石的锆石U-Pb同位素年龄依次为(319.6±4.1)Ma、(172.5±1.4)Ma和(165.5±1.8)Ma.三者均以高钾、富碱、贫镁为特征,均属钙碱性、准铝质-弱过铝质岩石,分异程度较高.岩石稀土总量较高,轻稀土相对富集,均具负铕异常;均富集U、Th,Rb/Sr值大于壳源Rb/Sr值,应属S型花岗岩.根据花岗岩地球化学和区域地质特征分析认为,中粗粒花岗岩形成于晚石炭世后碰撞伸展构造环境;中侏罗世细粒黑云母花岗岩和似斑状钾长花岗岩产于板内伸展构造环境,为同源岩浆演化不同阶段的产物.似斑状钾长花岗岩富含成矿元素Pb和Zn,而且其成岩年龄与辉钼矿(163.4±2.4) Ma～(166.6±2.4) Ma的Re-Os同位素年龄基本一致,可能为成矿母岩.     

滇西澜沧江南段小湾地区崇山岩群LA-ICP-MS锆石U-Pb年龄及其地质意义

滇西崇山岩群一直被认为是元古宙的大陆地壳-结晶基底,但至今无精确的年龄依据。对滇西澜沧江南段小湾地区崇山岩群的5件样品(糜棱岩化斜长变粒岩、黑云斜长角闪岩、片麻岩、糜棱岩化花岗质片麻岩、糜棱岩化黑云斜长变粒岩)进行锆石U-Pb定年。5件样品的锆石阴极发光图像显示,锆石有明显的生长振荡环带,指示岩浆成因。5件样品锆石的206Pb/238U年龄加权平均值分别为239.4±3.8Ma、248.4±4.3Ma、237.1±5.7Ma、268.7±3.2Ma、238.4±5.5Ma。根据野外地质特征和年龄数据,认为滇西澜沧江南段小湾地区崇山岩群是不同时代、不同岩性的岩体/地层(二叠系、三叠系)经后期变质作用形成的一套正变质岩,并不全是古老基底岩石出露。     

不同成因锆石阴极发光及微量元素特征:以新疆阿尔泰地区花岗岩和伟晶岩为例

新疆阿勒泰可可托海地区出露大量花岗岩和伟晶岩脉,利用阴极发光显微照相(CL)、电子探针背散射(BSE)和激光剥蚀电感耦合等离子质谱技术(LA-ICP-MS),观察和分析岩石中锆石的内部结构、稀土元素及Th,U含量后结果表明:该区花岗岩锆石具振荡环带和强烈的阴极发光特征,Th/U比值较高(Th/U=0.16～0.99),轻稀土亏损、重稀土富集,具较大的Ce正异常,为典型岩浆成因锆石。伟晶岩(KP-08-11)锆石为热液锆石,不具振荡环带和阴极发光,具低的Th/U比值(0.01～0.13),强烈富集稀土元素,尤其是轻稀土元素较花岗岩锆石高一个数量级,Ce的正异常相对较低。伟晶岩(KP3-08-1)锆石为变质重结晶锆石,Th/U比值分布范围较广(0.01～0.78),强烈亏损稀土元素,稀土元素配分模式存在显著的"REE四分组效应"。微量元素特征表明,伟晶岩(KP-08-11)锆石可能结晶自富U贫Th的残余岩浆流体,而伟晶岩(KP3-08-1)的锆石经历了蜕晶质化和变质重结晶作用,但依然保持了共存伟晶岩熔体的微量元素特征。     

大兴安岭中部柴河地区钾长花岗岩的成因及构造背景:岩石地球化学、锆石U-Pb同位素年代学的制约

对大兴安岭中部柴河林场地区钾长花岗岩进行了系统的地球化学及锆石U-Pb同位素年代学研究,并对其岩石成因及构造意义进行讨论.研究结果表明,柴河林场地区钾长花岗岩中锆石具有典型的岩浆振荡生长环带和较高的Th/U比值(0.44 ～ 1.42),反映了岩浆成因特征.LA-ICP-MS锆石U-Pb定年结果为133±3Ma.岩石具有富硅、稀土元素含量较高、相对富集轻稀土元素亏损重稀土元素的特征,Eu负异常较为明显,稀土元素配分图解具有右斜“V”字型的特征,并相对富集高场强元素和大离子亲石元素.以上特征表明,柴河林场地区钾长花岗岩为铝质A型花岗岩,是地壳岩石部分熔融的产物,具有典型A1型(裂谷或板内)花岗岩的特征,代表了伸展的构造环境.     

内蒙古科右前旗大石寨组火山岩锆石LA-ICP-MSU-Pb年龄及其形成背景

对大石寨组火山岩的形成时代和形成背景的认识存在较大的分歧。对采自建组剖面底部英安岩样品中的锆石进行阴极发光照相、微区原位LA-ICP-MS微量元素分析和U-Pb测年。锆石U-Pb同位素分析结果显示,锆石发育典型的岩浆震荡环带, 高Th/U(0.51~1.57),轻稀土元素亏损,重稀土元素富集,具有强烈的正Ce异常和强烈的负Eu异常等特征,表明锆石均属于岩浆成因。22个分析点获得的谐和年龄为(314±1)Ma(MSWD=0.88),代表了大石寨组火山岩的形成时代。结合前人的资料,认为大石寨组火山岩为裂陷早期的产物,而晚古生代的沉积岩石组合为在这一基础上发展起来的具有裂陷盆地性质的沉积组合。     

吉林省大石头镇北部青茶馆-元宝山花岗斑岩锆石U-Pb年龄及地球化学特征

青茶馆-元宝山花岗斑岩具有高硅、富铝、稀土元素含量较高、相对富集轻稀土元素、亏损重稀土元素的特征,负Eu异常明显,稀土元素配分图解具有右倾"V"字形的特征,并相对富集大离子亲石元素。锆石具有典型的岩浆振荡生长环带和较高的Th/U值(0.49~1.07),反映了岩浆成因特征。测得LA-ICP-MS锆石U-Pb年龄为116.8±1.5Ma(n=13,MSWD=1.13)。以上特征表明,青茶馆-元宝山花岗斑岩为高钾钙碱性高分异I型花岗岩,为后造山花岗岩,其形成可能与古太平洋板块俯冲作用有关。     

First data on chemical composition of zircon from lithium-fluorine granite of the Severnyi pluton, Chukchi Peninsula

The chemical composition of zircons from lithium-fluorine granite of the Severny pluton in the Chaun region, Chukchi Peninsula, has been studied. The magmatic origin of zircons has been established. Elevated LREE, Li, and Nb contents; moderate enrichment in Hf; and deep Eu anomalies are characteristic of zircons from rare-metal granite. The contents and distribution of chemical elements in studied zircons differ from those of biotite granite. Zircons from lithium-fluorine granite of the Severny pluton also differ from the worldwide analogs in moderate Hf, Y, and REE concentrations and extremely low contents of U, Th, and other incompatible elements.     

内蒙古科右前旗大石寨组火山岩锆石LA—ICP—MSU—Pb年龄及其形成背景

对大石寨组火山岩的形成时代和形成背景的认识存在较大的分歧。对采自建组剖面底部英安岩样品中的锆石进行阴极发光照相、微区原位LA—ICP—MS微量元素分析和U-Pb测年。锆石U—Pb同位素分析结果显示,锆石发育典型的岩浆震荡环带,高Th／U（0．51～1．57）,轻稀土元素亏损,重稀土元素富集,具有强烈的正Ce异常和强烈的负Eu异常等特征,表明锆石均属于岩浆成因。22个分析点获得的谐和年龄为（314±1）Ma（MSWD=0．88）,代表了大石寨组火山岩的形成时代。结合前人的资料,认为大石寨组火山岩为裂陷早期的产物,而晚古生代的沉积岩石组合为在这一基础上发展起来的具有裂陷盆地性质的沉积组合。     

辽西医巫闾山地区晚侏罗世花岗岩脉中热液锆石的成因与定年

辽西医巫闾山变质核杂岩经历过两阶段演化,晚侏罗世发育了围绕核部医巫闾山岩体周缘展布的长环形韧性剪切带(称为医巫闾山剪切带),早白垩世西侧叠加了北北东走向瓦子峪伸展韧性剪切带.在医巫间山剪切带及其变形下盘中侵入了大量的晚侏罗世花岗岩脉,其所含的锆石包括古老继承锆石、新生岩浆锆石、热液锆石等多种类型.根据锆石阴极发光图像、...     

大兴安岭北段龙江盆地光华组碱流岩LA-ICP-MS锆石U-Pb年龄及其地质意义

对大兴安岭北段龙江盆地光华组碱流岩进行了岩石地球化学及锆石U-Pb年龄研究,并对其岩石成因及构造意义进行了讨论。结果表明,龙江盆地碱流岩的锆石具有典型的岩浆振荡生长环带和较高的Th/U值(0.71~2.12),反映了岩浆成因特征,LAICP-MS锆石U-Pb年龄为122.4±1.7Ma(n=19,MSWD=0.77)。岩石富硅、富碱,贫Mg、Ca;稀土元素配分曲线呈现右倾"V"字形特征,显示强烈的负Eu异常;微量元素显示具有较低的Sr和Ba丰度,以及较高的Rb、Th、U、Zr等特点。以上特征表明,龙江盆地碱流岩类似于铝质A1型花岗岩,为长英质地壳部分熔融及其后斜长石和Ti、Fe氧化物分离结晶作用的产物,代表了伸展的构造环境。     

Metamorphic growth and recrystallization of zircons in extremely O-depleted rocks during eclogite-facies metamorphism: Evidence from U-Pb ages, trace elements, and O-Hf isotopes

A combined in situ SIMS and LA-(MC)-ICPMS study of U-Pb ages, trace elements, O and Lu-Hf isotopes was conducted for zircon from eclogite-facies metamorphic rocks in the Sulu orogen. The two microbeam techniques sampled various depths of zircon domains, revealing different element and isotope relationships between residual magmatic cores and new metamorphic rims and thus the geochemical architecture of metamorphic zircons which otherwise cannot be recognized by the single microbeam technique. This enables discrimination of metamorphic growth from different subtypes of metamorphic recrystallization. Magmatic cores with U-Pb ages of 769 ± 9 Ma have positive δ¹⁸O values of 0.1-10.1‰, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high REE contents, and steep MREE-HREE patterns with negative Eu anomalies. They are interpreted as crystallizing from positive δ¹⁸O magmas during protolith emplacement. In contrast, newly grown domains have concordant U-Pb ages of 204 ± 4 to 252 ± 7 Ma and show negative δ¹⁸O values of −10.0‰ to −2.2‰, low Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, low REE contents, and flat HREE patterns with weak to no Eu anomalies. They are interpreted as growing from negative δ¹⁸O fluids that were produced by metamorphic dehydration of high-T glacial-hydrothermally altered rocks during continental subduction-zone metamorphism. Differences in δ¹⁸O between different domains within single grains vary from 0.8‰ to 12.5‰, suggesting different degrees of O isotope exchange between the positive δ¹⁸O magmatic core and the negative δ¹⁸O metamorphic fluid during the metamorphism. The magmatic zircons underwent three subtypes of metamorphic recrystallization, depending on their accessibility to negative δ¹⁸O fluids. The zircons recrystallized in solid-state maintained positive δ¹⁸O values, and REE and Lu-Hf isotopes of protolith zircon, but their U-Pb ages are lowered. The zircons recrystallized through dissolution exhibit negative δ¹⁸O values similar to the metamorphic growths, almost completely reset U-Pb ages, and partially reset REE systems. The zircons recrystallized through replacement show variably negative δ¹⁸O values, and partially reset REE, and U-Pb and Lu-Hf isotopic systems. Therefore, this study places robust constraints on the origin of metamorphic zircons in eclogite-facies rocks and provides a methodological framework for linking the different types of metamorphic zircons to petrological processes during continental collision.     

General relations in the trace-element composition of zircons from eclogites with implications for the age of eclogites in the belomorian mobile belt

Analysis of currently available data (877 individual high-precision zircon analyses) on the composition of zircons from eclogite complexes worldwide reveals general relations in the zircon composition: an anomalous decrease in the Th concentration (no higher than 3 ppm on average) and the Th/U ratio (0.33 on average), a significant decrease in the concentrations of all REE (to 22 ppm) and particularly LREE (<2 ppm), and relatively low concentrations of Y (34 ppm), U (100 ppm), and P (41 ppm) at an elevated Hf concentration (11 400 ppm on average). The REE patterns of eclogitic zircons are noted for pronounced flat HREE patterns, poorly pronounced (if any) negative Eu anomalies, strongly reduced positive Ce anomalies (Ce/Ce* = 11 on average), and U-shaped configurations of LREE patterns up to the development of negative Nd anomalies. The relations detected in the distribution of trace elements and REE in eclogitic zircons are of universal nature and occur irrespective of the rock type (metabasites, metaultrabasites, or gneisses) and the metamorphic pressure (eclogites of high and ultrahigh pressure). The application of the aforementioned criteria makes it possible to reliable distinguish eclogitic zircons from those of magmatic or metamorphic genesis (not related to high-pressure metamorphism). Eclogites in the Belomorian Mobile Belt (in the Salma and Gridino areas) were determined to contain zircons in metagabbro eclogites; the cores of these zircons have an age of 2.8?C2.9 Ga and are of magmatic genesis, whereas their outer metamorphic zones have an age of 1.9 Ga and a trace-element composition typical of eclogitic zircons. Hence, the Belomorian Mobile Belt was affected only by single (Svecofennian, at ??1.9 Ga) episode of eclogite metamorphism of Archean rocks.