扬子地块东段若干橄揽岩包体的温度－压力计算

采自江苏省六合地区的１１个尖晶石相橄榄岩包体，用电子探针和质子探针精确测定其中橄榄石和辉石的主量和微量成分，采用新近校准的适用于尖晶石相包体的橄榄石一单斜辉石地质压力计和二辉石地质温度计，计算了包体中共生矿物对的平衡温度和压力。其中ＢＭ８５计算的温度比ＢＫＮ９０的约低５０℃左右。而经Ｂｒｅｙ和Ｋｏｈｌｅｒ修改的ＢＭ８５温度计得到的结果与ＢＫＮ９０的几乎相同。假定压力为１．５ＧＰａ，用ＢＫＮ９０计算，１１个包体样品的温度范围为７２２℃～１１９３℃，它大体上反映了扬子地块东段大陆岩石圈地使尖晶石相部分的温度状态。橄榄石一单斜辉石地质压力计用于本样品组计算，仅部分样品获得合理的结果。由于该压力计自身的误差较大，尚不能精确确定尖晶石相橄榄岩的压力。     

地幔岩矿物压力计评述

适用于地幔岩石的矿物压力计有石榴石-斜方辉石压力计、石榴石-单斜辉石压力计、橄榄石-单斜辉石压力计、铬尖晶石压力计、二辉石压力计等有限几类.本文通过将这些压力计应用于岩石学相平衡实验数据,检验了其精确度.再将它们应用到天然地幔岩石样品,包括石榴石相二辉橄榄岩、尖晶石相二辉橄榄岩、石榴石-尖晶石过渡相二辉橄榄岩、含金刚石和石墨的地幔岩石,检验了其准确度.初步结论是,现有的石榴石-斜方辉石压力计(Nickel and Green,1985;Taylor,1998;Brey et al．,2008)质量相对最优,石榴石-单斜辉石压力计(Nimis and Taylor,2000;Simakov and Taylor,2000)次之.在应用这些压力计时,可配合二辉石温度计(Brey et al．,1990;Taylor,1998)或石榴石-橄榄石温度计(Wu and Zhao,2007),来同时估算平衡压力和温度.其余的压力计精确度和准确度都还很不够,需要更精确深入的实验研究来标定质量优良的压力计.     

中国东部及西秦岭地区新生代岩石圈地幔中的相转变带及其温压条件

五相(橄榄石 斜方辉石 单斜辉石 石榴石 尖晶石)共存的地幔橄榄岩捕虏体是来自岩石圈地幔相转变带的直接样品。中国东部及西秦岭地区晚第三至第四纪碱性火山岩携带的少量五相共存的地幔橄榄岩捕虏体为探讨这些地区新生代岩石圈地幔中相转变带提供了宝贵的样品。本文根据地幔橄榄岩捕虏体中石榴石和尖晶石的产出状况,将这些橄榄岩捕虏体分为三类:第一类橄榄岩中尖晶石为粒状残核,尖晶石外缘被石榴石的反应边包围。这种橄榄岩捕虏体代表尖晶石一石榴石相转变带的上限,故称为尖晶石带橄榄岩;第二类橄榄岩中尖晶石和石榴石以单颗粒零散分布为特征,二者共存但未见明显的相转变关系。这类橄榄岩多位于相转变带中部,拟称为尖晶石-石榴石过渡带橄榄岩;第三类橄榄岩中以石榴石为主,尖晶石和辉石等微晶构成石榴石反应边。这类橄榄岩代表尖晶石-石榴石相转变带的下限,故称为石榴石带橄榄岩。因此,根据不同类型橄榄岩捕虏体中矿物的组成,结合温度压力估算即可确定岩石圈地幔中相转变带的深度和厚度。本文通过对中国东部及西秦岭地区晚第三至第四纪碱性火山岩携带的尖晶石-石榴石二辉橄榄岩捕虏体的温度压力估算来进一步厘定中国东部新生代岩石圈地幔中的相转变带深度和厚度。     

地幔橄榄岩部分熔融及相转变（尖晶石相→斜长石相）过程中的固相化学成分演化──Ⅱ．在自然岩石中的应用

分析了全球一些有代表性的上地幔尖晶石橄榄岩和斜长石橄榄岩中各矿物的化学成分变化特征。发现在斜长石橄榄岩中，尖晶石和斜方辉石富Ｔｉ，且Ｔｉ含量随Ｃｒ／（Ｃｒ＋Ａｌ）的增大而增大；单斜辉石富Ｔｉ贫Ｎａ，其Ｔｉ含量随Ｎａ含量的增大而减少。据此，结合实验结果，可以肯定世界各地大多数斜长石二辉橄榄岩在斜长石相域内未经受部分熔融。岩体所曾经受的部分熔融只发生在尖晶石或石榴石相。它们的相对熔融度可以用下面两个指标来估计：（１）最贫Ｔｉ尖晶石的Ｃｒ／（Ｃｒ＋Ａｌ）；（２）单斜辉石的最高Ｎａ含量。对于尖晶石橄榄岩，从二辉橄榄岩、方辉橄榄岩到纯橄榄岩，其尖晶石和斜方辉石的Ｃｒ／（Ｃｒ＋Ａｌ）逐渐增大，而含量很低的Ｔｉ或Ｎａ在尖晶石、斜方辉石及单斜辉石中保持不变或趋向逐渐减小。尖晶石橄榄岩的相对熔融度可据尖晶石的Ｃｒ／（Ｃｒ＋Ａｌ）和单斜辉石的Ｎａ含量来判断。     

碱性玄武岩中幔源岩石包体内尖晶石成分特征及其岩石学成因意义

通过对我国东部北起黑龙江省南至海南省３１个产地的新生代碱性玄武岩中橄榄岩类 （纯橄岩、方辉橄榄岩及二辉橄榄岩） 包体和辉石岩类包体中的１６０ 多个尖晶石电子探针分析数据, 论述了尖晶石的Ｃｒ－Ａｌ, Ｆｅ－Ｍｇ, Ｎｉ－Ｍｇ 主元素及有关比值和端员组分之间的关系, 分析研究了不同岩类包体中尖晶石的颜色、成分及成因之间的联系。并利用所分析的有关橄榄石、斜方辉石、单斜辉石共生矿物的电子探针分析数据, 采用新的、较合理的Ｂｒｅｙ－Ｋｏｈｌｅｒ温度计及Ｋｏｈｌｅｒ－Ｂｒｅｙ 压力计和Ｂａｌｌｈａｕｓ ｅｔａｌ． 氧逸度计算方法进行了计算, 探讨了尖晶石成分与其形成温度、压力和氧逸度状态的关系, 指出了尖晶石成分所反映的地幔亏损程度及部分熔融程度的变化规律及尖晶石 （相） 稳定的温度、压力和氧逸度范围。     

胶东—苏北石榴石二辉橄榄岩形成条件及年代

在胶东—苏北地区,由石榴石二辉橄榄岩、尖晶石二辉橄榄岩、石榴石辉石岩、榴辉岩、斜辉辉橄岩和纯橄岩组成的杂岩成群和成带分布,延长590km。该岩带越过郯庐断裂带延伸至大别山,全长约1200km。岩带内石榴石二辉橄榄岩与尖晶石橄榄岩伴生,组成较大的岩块,并且与榴辉岩伴生,曾被作者确定为一种有层序的岩套。石榴石二辉橄榄岩的Sm-Nd同位素年龄为925±53Ma,矿物地质温度计和压力计表明其形成于115—160km深部,温度为800—1371℃。该石榴石二辉橄榄岩平衡温度和压力符合大陆地温线,而不同于中国东部沿海地区玄武岩中包体石榴石二辉橄榄岩,后者的平衡温度压力符合于大洋地温线。     

金川超镁铁质岩体矿物化学特征及矿物地质温度计、压力计研究

根据金川超镁铁质岩体主要造岩矿物和副矿物的共生组合关系及各种矿物的化学成分特点；选用５种较成熟、使用较方便的矿物地质温度计、压力计（主要是辉石温压计和角闪石压力计），对岩体形成的温、压条件进行了估算，其结果为：成岩温度为１０００～１３００℃（上限可到１４００～１５００℃），成岩压力约为５×１０￣８～１１×１０￣８ｐａ。金川超镁铁质岩体的主要岩石类型为尖晶石二辉橄榄岩，这一岩石类型在复杂体系相关系图中的稳定区域大致处于５×ｌ０￣８～１５×１０￣８ｐａ的范围，这与矿物温压计估算的成岩温压条件是一致的。     

扬子地块东段若干橄榄岩包体的温度—压力计算

采自江苏省六合地区的１１个尖晶石相橄榄岩包体，用电子探针和质子地精确测定其中橄榄石和辉石的主量和向量成分，采用新近校准的适用于尖晶石相包石的橄榄石－单斜辉石地质压力坟和二辉石地质温度计，计算了包体中共生矿物的平衡温度和压力，其中ＢＭ８５计算的温度比ＢＫＮ９０的约低５０℃左右，而经Ｂｒｅｙ和Ｋｏｈｌｅｒ修改的ＢＭ８５温度计得到的结果与ＢＫＮ９０的几乎相同。     

大兴安岭中部第四纪火山岩中石榴石橄榄岩捕虏体的初步研究

大兴安岭中部的绰尔河-哈拉河地区分布有近30座第四纪火山,初步分为更新世火山和全新世火山两期。火山岩中含有丰富的尖晶石橄榄岩和石榴石橄榄岩捕虏体,石榴石橄榄岩的类型主要是石榴石二辉橄榄岩。根据绰尔河新鲜的石榴石二辉橄榄岩P-T平衡条件估计（1164℃,2．36GPa）,其形成深度约76km。这与中国东部其它地方四相共存的石榴石二辉橄榄岩类似,区别于五相共存的尖晶石／石榴石二辉橄榄岩形成条件（〈70km）,证实它们是来自尖晶石二辉橄榄岩与石榴石二辉橄榄岩相转变带之下深度超过70km的石榴石橄榄岩稳定区。     

中国东北地区上地幔组成、结构及热状态

本文通过对中国东北地区新生代玄武岩中超镁铁质包体的研究,根据地质压力计所估算的包体形成深度、玄武岩浆及辉石岩浆起源的深度等,建立了中国东北地区上地幔组成模式:1.壳幔过渡带;2.尖晶石二辉橄榄岩层;3.含有痕量硅酸盐熔体的低速层;4.尖晶石方辉橄榄岩层;5.石榴石二辉橄榄岩层。与此同时,根据地质温度计与地质压力计推算资料,作者认为中国东北地区上地幔属大洋地温。与典型克拉通地温相比,低速层位置较浅,上地幔处于过热状态,这与大陆裂谷的发育有关。     

适用于尖晶石相橄榄岩的第一个定量地质压力计

The historic development of the first geobarometer for spinel lherzolite based on the distribution of calcium between existing olivine and clinopyroxene is reported here.
Kohler and Brey(1990) suggested the geobarometer as follows:
P(10⁸Pa)=(−TlnD_Ca−11982+361T)/56.2 for T≥ (1275.25+2.827P) (K),
P(10⁸Pa)=( −TlnD_Ca−5792−1.25T)/42.5 for T≤(1275.25+2.827P) (K).
Based on their calibrated experiments for calcium exchange between olivine and clinopyroxene from wide temperature-pressure range.     

Lattice-preferred orientation of olivine found in diamond-bearing garnet peridotites in Finsch,South Africa and implications for seismic anisotropy

Seismic anisotropy in the upper mantle provides important constraints on mantle dynamics, continental evolution and global tectonics and is believed to be produced by the flow-induced lattice-preferred orientation (LPO) of olivine. Recent experimental studies at high pressure and temperature have suggested that the LPO of olivine is affected by pressure in addition to water and stress. However, there has been no report yet for the pressure-induced LPO of natural olivine because samples from the deep upper mantle are rare and often unsuitable for study due to ambiguous foliation and lineation. Here we show evidence of the pressure-induced LPO of natural olivine in diamond-bearing garnet peridotites from Finsch, South Africa. We found that the [010] axes of olivine are aligned subnormal to foliation and that the [001] axes are aligned subparallel to lineation, which is known as B-type LPO of olivine. The equilibrium pressure of the samples, as estimated using geobarometer, was greater than 4 GPa, indicating that the samples originated from a depth greater than ∼120 km. In addition, FTIR spectroscopy of the olivine showed that the samples are dry, with a water content of less than 90 ± 20 ppm H/Si (5.5 ± 1.2 ppm wt. H₂O). These data suggest that the samples are the first natural examples of olivine displaying B-type LPOs produced due to high pressure under dry condition. Our data indicate that the trench-parallel seismic anisotropy observed in many subduction zones in and below subducting slabs at depths greater than ∼90 km under dry condition may be attributed to the pressure-induced olivine fabrics (B-type LPO) and may be interpreted as the entrainment of the sub-lithospheric mantle in the direction of subduction rather than anomalous trench-parallel flow.     

Calcium zoning in olivine and its relationship to silica activity and pressure

Microprobe analyses of olivine phenocrysts from nephelinite and basanite lavas show strong zoning toward calcium enrichment. Tholeiitic and other more siliceous lavas show little or no such calcium enrichment, but more extensive magnesium to iron zoning. Consideration of reactions between clinopyroxene and olivine indicate that silica activity as well as pressure is an important variable. Zoning trends toward calcium enrichment in olivine could be interpreted as a response to pressure release during crystallization. A normal, magnesium to iron, trend with no increase in calcium would, then, reflect crystallization with stable pressure conditions.     

A recalibration of the garnet-olivine geothermometer and a new geobarometer for garnet peridotites and garnet-olivine-plagioclase-bearing granulites

The garnet-olivine Fe-Mg exchange geothermometer and the garnet-olivine-plagioclase geobarometer have been simultaneously calibrated using reversed experimental data based on the model reactions and between 900 and 1500 °C at 9.1–95.0 kbar and between 4.7 and 7.0 kbar at 750–1050 °C, respectively. The resulting garnet-olivine thermometer reproduces experimental temperatures mostly within ±75 °C and the garnet-olivine-plagioclase barometer reproduces experimental pressures well within ±0.19 kbar. These new thermobarometers use the same garnet and olivine activity models and are thermodynamically consistent. Application of these thermobarometers to garnet peridotites from mantle xenoliths, orogenic garnet peridotites over the world and the Adirondack olivine-bearing metagabbros yielded reasonable P–T results. The present garnet-olivine thermometer can be used to measure medium-high-grade to ultrahigh-grade, low-pressure to ultrahigh–high-pressure garnet peridotites and metagabbros, whereas the garnet-olivine-plagioclase barometer has limited application to garnet-olivine-plagioclase-bearing granulites.     

Cations in olivine,Part 2: Diffusion in olivine xenocrysts,with applications to petrology and mineral physics

Diffusivities for calcium, iron, magnesium, manganese and aluminum have been measured for St. John's olivine undergoing cation exchange with synthetic basaltic melts. The variety of temperature, pressure and fO₂ conditions under which the diffusivities were measured complement the equilibrium-partitioning study of calcium in olivine-bearing basalts by Jurewicz and Watson, 1988. Olivine was found to be anisotropic with respect to the diffusion of calcium, iron, magnesium and manganese. This anisotropy is a weak function of temperature, but strongly dependent upon oxygen fugacity.Because diffusion is independent of olivine composition over the small range of compositions used in this study, it could be shown that the absolute values of the diffusion coefficients were also functions of temperature and fO₂. At near-atmospheric total pressure and an oxygen fugacity of 10^–8atm, D _Fe>D _Mn>D _Ca and D _MgD _Mn for a range of geologically reasonable temperatures. These relative diffusivities were shown to change with oxygen fugacity. The power-law dependence of diffusion on oxygen partial-pressure was determined for each cation and the results are consistent with the range of values given by Stocker (1978) and by other workers.For Ca and Fe, the effect of hydrostatic pressure on diffusion appears to be weak, at least for transport parallel to the c crystallographic direction. Unfortunately, no true activation volumes (or other pressure-related parameters) could be computed because the oxygen fugacity was not held constant over changes in pressure, and because accurate post-experiment reconstruction of sample orientation was not possible. Al was found to enter high-pressure olivines at concentrations of up to 0.14 weight percent, thus allowing aluminum diffusion to be characterized. The diffusivity of aluminum is, within error, the same as iron at 20 kb at 1430° C at the ambient fO₂ of our piston-cylinder cells. This correspondence suggests that diffusion of Al may depend on transport of either Fe or of Fe ⁺³ defects. While the results of these experiments are generally consistent with results published elsewhere, there are important inconsistencies. Tracer diffusion and interdiffusion in pure, ordered, olivine endmembers (e.g., tephroite and forsterite) showed significantly higher activation energies. This discrepancy could reflect the role of Fe⁺³ defects in diffusion; however, it may also suggest that order-disorder phenomena may be significant factors influencing diffusion in analog systems.The results of this study are applied to four petrologic problems: (1) calculation of rates of equilibration for olivine xenocrysts; (2) calculation of closure temperatures for the CaO/MgO olivine/basalt geothermometer (Jurewicz and Watson 1988); (3) delineation of an intrinsic-/O₂ geobarometer; and (4) investigation of the dependence of olivine dissolution upon crystallographic orientation. In addition, it is demonstrated that diffusion-exchange experiments are useful for studying the dominant point-defect mechanisms for cation diffusion.Currently, a visiting scientist with Air Force Wright Aeronautical Laboratories Materials Laboratory (MLLM), Wright-Patterson AFB, OH 45433     

内蒙古四子王旗东八号中新世含深源捕虏体富钾橄榄玄武岩的发现及其意义

内蒙古四子王旗东八号地区最近发现含有深源捕虏体的富钾橄榄玄武岩。玄武岩为灰黑色致密块状,以富碱(K2O+Na2O5．91％～6．47％)、高钾(K2O2．82％～3．12％)和较高的钛(TiO2 2．22％—2．36％)为特征,属钾玄岩系列,全岩K—Ar年龄为21．9±1．7Ma。捕虏体主要为尖晶石二辉橄榄岩、二辉橄榄岩等。根据矿物平衡温压计算表明：捕虏体形成温度为1100—1250℃,压力为1．7—2．0GPa,应源自于岩石圈地幔。四子王旗橄榄玄武岩较高的TiO2和K2O,暗示其岩浆可能源于幔柱作用。推测华北板块北缘自中生代开始可能受到来自深部的幔柱作用,大量上升的岩浆因受到阻挡而保留在岩石圈底部,底侵作用和部分继续上升的岩浆,将岩石圈地幔的捕虏体携出地表。     

一种新的地质压力计——单斜辉石-石英-斜长石-钠钙质角闪石地质压力计

根据超高压岩石的退变质反应20Jd 3Di H2O=12Ab 2An Tar 3Na2O和18Jd 3Di 2Aeg H2O=12Ab 2An Fe-Tar 3Na2O,利用拟合的绿闪石和铁质绿闪石的热力学数据,在平衡热力学原理的基础上,建立了两个反应的压力计表达式:p=0.001 6(t 273)-0.028lnK 0.321K = (aPlNaAlSi3O8)12·(aPlCaAl2Si2O8)2·(aTarNa2CaMg3Al2[Si6Al2O22](OH)2·(aSodNa2O)3/aNCpxNaAlSi2O6)20·(aCpxCaMgSi2O6)3·aWatH2O经中国安徽省潜山县双河和西阿尔卑斯高压超高压变质带的验证及与角闪石-斜长石温度计的对比,其计算结果基本合理,表明这一新的压力计具有较好的应用价值.     

Novel amphibole geobarometer for high-magnesium andesite and basalt magmas

Experimental data on amphibole crystallization in water-saturated high-Mg andesite from Shiveluch volcano, Kamchatka, at 2, 3, and 5 kbar were used to calibrate a new geobarometer. The main parameters chosen to indicate the crystallization pressure of equilibrium amphibole is the ratio of tetrahedrally coordinated Al to the sum (Ti⁴⁺ + Fe³⁺), which is calculated by the 13eCNK technique with regard for crystal chemical considerations. The newly derived geobarometer is designed to evaluate pressure in the range of 2–12 kbar using amphibole from high-Mg andesite and basalt. The accuracy and reliability of the pressure estimates by the new geobarometer were tested by applying this geobarometer in studying amphibolized ultramafic xenoliths from the Dish Hill dike, California; magmatic amphibole hosted in cortlandite from the Shanuch intrusion, Kamchatka; and magmatic amphibole in the Pekul’ney Bay area, Chukotka. All estimates made with the newly developed geobarometer were reasonably close to values obtained by independent techniques.     

Sodium betpakdalite and conditions of its formation

Because orthopyroxenes do not occur in nephelinites, the widely used methods of calculating f(O₂) based on the olivine + orthopyroxene + spinel paragenesis are not applicable in this case. The authors present new methods of calculation, three of which are based on published data detailing exchange reactions between two pyroxenes and the melt. The activities of MgSiO₂ and FeSiO₂ are calculated from the composition of the groundmass of effusives in equilibrium with clinopyroxenes, making it possible (considering the activities of olivine and titanomagnetite components of the rocks) to normalize f(O₂) with regard to the quartz-fayalite-magnetite (QFM) buffer. In another version, the activities of enstatite are calculated considering the calcium content in rock olivines, using experimental data on the equilibrium of olivine with the two pyroxenes on which the well-known olivine geobarometer is based (Koehler and Brey, 1990). Still another method involves calculation of aFe.0 using the composition of the groundmass of nephelinites on the basis of equilibria of silicate melts with metallic iron (Ariskin et al., 1992), which then, in conjunction with magnetite, yields f (O₂).

The five methods of estimating f (O₂) by use of different sets of experimental data and thermodynamic constants for various solid phases yield a maximum spread that does not exceed 0.8 logarithmic units. The average value of log₁₀ f(O₂) for phenocryst and microphenocryst associations of nephelinites, obtained using all five methods, ranged from +1.6 to +1.8 above the level of the QFM buffer. These estimates support the conclusion that the mantle is in a relatively oxidized state in regions of intra-plate oceanic islands (Amundsen and Neumann, 1992). Coexisting microlites of titanomagnetite and ilmenite from the nephelinite groundmass point to an appreciably lower relative f(O₂) (below the QFM), which evidently is explained by a drop in the redox potential under the conditions of a relatively closed system, with intensive deposition of titanomagnetite.

The phenocryst associations of phonolites yield f(O₂) values normalized with respect to the QFM buffer that are close to analogous values for the phenocrysts and microphenocrysts of nephelinites (on average, 1.5 logarithmic units above the QFM on the basis of constants of the reaction between the components of titanomagnetite, clinopyroxene, nepheline, K-feldspar, and sphene). In all probability, differentiation in the magma chamber that led to the appearance of phonolite magmas in late stages occurred in a system that was open (with regard to oxygen). In this case, more intensive removal of magnetite resulted in silica activities in the residual magmas that were higher than in a closed system (phenocrysts of sphene are present in phonolites, but perovskite is observed in some cases in the groundmass of nephelinites, with sphene being absent).     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).